KR20030069274A - Composition for aiding ironing - Google Patents

Composition for aiding ironing Download PDF

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Publication number
KR20030069274A
KR20030069274A KR1020020008747A KR20020008747A KR20030069274A KR 20030069274 A KR20030069274 A KR 20030069274A KR 1020020008747 A KR1020020008747 A KR 1020020008747A KR 20020008747 A KR20020008747 A KR 20020008747A KR 20030069274 A KR20030069274 A KR 20030069274A
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South Korea
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oil
composition
ironing
fibers
present
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KR1020020008747A
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Korean (ko)
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김인환
김병현
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주식회사 엘지생활건강
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Priority to KR1020020008747A priority Critical patent/KR20030069274A/en
Publication of KR20030069274A publication Critical patent/KR20030069274A/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel

Abstract

PURPOSE: A composition of an ironing supplement agent is characterized by having excellent heat resistance, not damaging natural fibers and synthetic fibers, having light fastness, sterilizing bacteria lived on the fibers and giving out fragrance. CONSTITUTION: The composition of the ironing supplement agent is comprised of: 0.001-1wt.% of essential oil ingredients and residual selected from the group containing basil oil, marjoram oil, lemon grass oil, clover oil, bay oil, cumin oil and thyme oil; water; and 0.1-10wt.% of C1-C4 low alcohol.

Description

다림질 보조제 조성물{Composition for aiding ironing}Composition for aiding ironing

본 발명은 의류 및 섬유 제품의 다림질시 분사되는 다림질 보조제 조성물에 관한 것으로, 더욱 상세하게는 천연식물에서 추출한 특정 정유를 사용함으로써 의류 및 섬유제품의 변색이나 탈색을 방지할 수 있으며, 인체에 안전한 동시에 우수한 방향 및 항균효과를 갖는 다림질 보조제 조성물에 관한 것이다.The present invention relates to an ironing aid composition that is sprayed when ironing clothing and textile products, and more particularly by using a specific essential oil extracted from natural plants can prevent discoloration or discoloration of clothing and textile products, The present invention relates to an iron adjuvant composition having excellent fragrance and antibacterial effect.

통상적으로, 세탁·건조 후 다림과정 중에 구김제거효과를 더욱 향상시키기 위하여 가공전분 또는 산화전분 등을 함유하는 다림질 보조제가 사용되고 있으며, 이들에 관하여는 일본 특허공개 제58-18476호, 제88-4294호, 제87-288644호 등에 출원된 바 있다. 그러나, 이러한 가공전분 또는 산화전분 등의 풀성분은 고온하에서 눌러 붙기 쉽고, 황변 또는 얼룩의 원인이 되므로 울이나 고급 레이온 계통의 의류에 사용할 수 없으며, 스팀다리미 사용시에는 사용할 수 없는 단점이 있다.In general, ironing aids containing processed starch or oxidized starch are used to further improve the wrinkle removal effect during the ironing process after washing and drying, and Japanese Patent Application Laid-Open No. 58-18476, 88-4294. No. 87-288644 and the like. However, the paste such as processed starch or oxidized starch is easy to press under high temperature, and can cause yellowing or staining, so it can not be used for clothing of wool or high-grade rayon system, and can not be used when using a steam iron.

이에, 의류 및 섬유제품의 변색이나 탈색 등의 손상과 인체에의 안전성 우려가 없는 다림질 보조제 조성물이 요구되어 왔다.Accordingly, there has been a demand for an ironing aid composition which is free from damages such as discoloration and discoloration of clothing and textile products and safety concerns to the human body.

아울러, 가정에서 세탁과정 중에 섬유 및 의류에 방향효과를 부여하기 위하여 섬유유연제를 사용하고 있으며, 최근에는 의류용 소취제에도 방향효과를 부여한제품이 점차 증가되고 있고, 위생에 대한 관심이 높아짐에 따라 의류 및 섬유와 관련된 세탁세제에서 항균 및 살균과 관련된 제품들이 늘어나고 있다. 그러나, 이러한 제품들은 방향이 장시간 지속되지 않거나 주로 합성원료들을 사용하므로 섬유에 손상을 주는 경향이 있으며, 개인에 따라 정도의 차이는 있지만 알레르기, 피부 반점 등의 인체에 해를 끼칠 우려가 있고, 제품 자체의 안정성에도 문제를 일으킬 우려가 있다.In addition, fabric softeners are used to give fragrance effects to textiles and clothing during the washing process at home. Recently, products that give fragrance effects to clothing deodorants are gradually increasing, and as the interest in hygiene increases, And products related to antibacterial and sterilization are increasing in laundry detergents related to textiles. However, these products tend to damage fibers because the fragrance does not last for a long time or mainly uses synthetic raw materials, and there is a risk of harming the human body such as allergies and skin spots, although the degree varies depending on the individual. There is a risk of causing problems with its own stability.

이에, 본 출원인은 상기한 다림질 보조제 조성물의 문제점을 개선하는 동시에 상기한 문제점을 갖는 섬유유연제 등을 사용하는 대신에 다림질 과정중에 항균 및 방향 기능을 부여할 수 있는 다림질 보조제 조성물을 완성하게 되었다.Accordingly, the present applicant has completed the ironing aid composition which can impart antimicrobial and fragrance functions during the ironing process instead of improving the problems of the ironing aid composition and at the same time using the fabric softener having the above problems.

본 발명은 앞서 설명한 바와 같은 종래 기술의 문제점을 효율적으로 해결하기 위하여 제공된 것으로서, 그 목적은 의류 및 섬유제품에 변색이나 탈색 등의 손상과 인체에의 안전성 우려가 없으며 항균 및 방향효능을 갖는 다림질 보조제 조성물을 제공하고자 하는 것이다.The present invention has been provided to efficiently solve the problems of the prior art as described above, the object of the ironing aid having antibacterial and fragrance efficacy without damages such as discoloration or discoloration in clothing and textile products and safety to the human body It is to provide a composition.

상기한 목적을 달성하기 위하여 본 발명에 따른 다림질 보조제 조성물은, 바질오일, 마조람오일, 레몬그라스오일, 클로버오일, 베이오일, 큐민오일, 타임오일 또는 이들 중 2이상의 혼합물로 이루어지는 그룹 중에서 선택되는 성분 0.001 내지 1중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 한다.In order to achieve the above object, the iron adjuvant composition according to the present invention includes a component selected from the group consisting of basil oil, marjoram oil, lemongrass oil, clover oil, bay oil, cumin oil, time oil or a mixture of two or more thereof. 0.001 to 1% by weight and the balance comprises water.

또한, 본 발명의 다림질 보조제 조성물은 탄소수 1 내지 4의 저급알코올 0.1내지 10중량%를 더 포함하는 것을 특징으로 한다.In addition, the ironing aid composition of the present invention is characterized in that it further comprises 0.1 to 10% by weight of lower alcohol having 1 to 4 carbon atoms.

이하, 본 발명에 대하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

본 발명의 다림질 보조제 조성물은 바질오일, 마조람오일, 레몬그라스오일, 클로버오일, 베이오일, 큐민오일, 타임오일 또는 이들 중 2이상의 혼합물로 이루어지는 그룹 중에서 선택되는 성분과 물을 필수적으로 포함하도록 구성되며 그 외 에탄올을 부가적으로 더 첨가하도록 구성될 수 있다.The ironing aid composition of the present invention is configured to include essentially water and ingredients selected from the group consisting of basil oil, marjoram oil, lemongrass oil, clover oil, bay oil, cumin oil, time oil or a mixture of two or more thereof. Other ethanol may be additionally added.

상기 오일성분들은 다양한 천연식물을 압출 또는 스팀증류함으로써 추출되는 휘발성 오일(이하, "정유; 精油, Essential oil"라 함) 중 특히 항균력이 우수한 정유만을 엄선한 것이다. 이들은 다양한 화학물질들의 천연혼합물로서 지방성오일과는 달리 찌꺼기를 남기지 않고 증발한다. 또한, 향취가 있고 원래의 식물이나 꽃의 향 특성을 지니며 잔가지, 뿌리, 열매, 열매껍질, 나무껍질, 씨, 나무, 잎, 꽃, 줄기 등에서 추출된다. 일반적으로 300여 종이 향으로 사용되며, 일종의 천연식물의 정유 중에는 평균 100여개의 화합물이 포함되어 있으며, 테르펜, 알코올, 에스테르, 알데히드, 케톤, 페놀계 등이 대표적인 성분이다.The oil components are selected only from volatile oils extracted by extruding or steam distillation of various natural plants (hereinafter referred to as "essential oils"), especially essential oils having excellent antibacterial properties. These are natural mixtures of various chemicals and, unlike fatty oils, evaporate without leaving residue. In addition, it has a scent and has the characteristic of the original plant or flower and is extracted from twigs, roots, fruits, fruit bark, bark, seeds, trees, leaves, flowers, stems, and the like. Generally, it is used as a fragrance of about 300 species, and an essential oil of a kind of natural plant contains about 100 compounds, and terpene, alcohol, ester, aldehyde, ketone, and phenolic are typical components.

이하, 바질오일, 마조람오일, 레몬그라스오일, 클로버오일, 베이오일, 타임오일 및 큐민오일을 시험재로 하고, 각 시험재에 대하여 대장균, 포도상구균 및 녹농균에 대한 항균력을 측정한 후, 그 결과를 하기 표 1에 나타내었다.Hereafter, basil oil, marjoram oil, lemongrass oil, clover oil, bay oil, thyme oil and cumin oil were used as test materials, and the antibacterial activity against Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa was measured for each test material, and the results were obtained. It is shown in Table 1 below.

항균력은 마루젤의 방법에 의한 페이퍼 디스크법에 의해 측정된 것으로서, 직경 80㎜인 시계접시에 세균현탁액 1㎖를 넣은 후 배지 10㎖와 혼합한 다음 정치하여 배지를 만든 후, 이 배지의 중앙에 직경 6㎜이고 두께 0.68㎜인 정유를 넣은원형여지를 넣은 다음, 37℃의 온도에서 24시간동안 배양한 후 성장 저지환의 직경을 측정함으로써 판단된다.The antimicrobial activity was measured by the paper disc method by Maruzel's method. 1 ml of bacterial suspension was added to a 80 mm diameter watch plate, mixed with 10 ml of medium, and left to form a medium. It is determined by inserting a circular filter with an essential oil having a diameter of 6 mm and a thickness of 0.68 mm, incubating for 24 hours at a temperature of 37 ° C., and then measuring the diameter of the growth inhibiting ring.

(단위: ㎜)(Unit: mm) 대장균Escherichia coli 포도상구균Staphylococcus 녹농균Pseudomonas aeruginosa 바질오일Basil oil 1.51.5 2.52.5 1.91.9 마조람오일Marjoram oil 1.21.2 1.71.7 0.80.8 레몬그라스오일Lemongrass Oil 1.21.2 3.03.0 1.31.3 클로버오일Clover oil 1.61.6 1.91.9 0.90.9 베이오일Bay oil 1.61.6 2.02.0 1.01.0 타임오일Time oil 2.22.2 5.05.0 1.01.0 큐민오일Cumin oil 1.01.0 1.61.6 2.02.0

상기 표 1의 결과로부터 알 수 있는 바와 같이, 상기 정유들은 대장균, 포도상구균 및 녹농균에 대한 항균력이 우수하였다.As can be seen from the results of Table 1, the essential oils were excellent in antibacterial activity against Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa.

한편, 에탄올은 상기 정유를 더 잘 가용화시켜 투명하고 안정한 다림질 보조제 조성물을 얻기 위하여 첨가할 수 있다.Ethanol, on the other hand, may be added to better solubilize the essential oil to obtain a transparent and stable ironing aid composition.

이하에는 이러한 구성에 따른 본 발명의 다림질 보조제 조성물의 작용 효과를 상세히 설명한다.Hereinafter, the effect of the ironing aid composition of the present invention according to this configuration will be described in detail.

본 발명의 바질오일, 마조람오일, 레몬그라스오일, 클로버오일, 베이오일, 큐민오일, 타임오일 또는 이들 중 2이상의 혼합물로 이루어지는 그룹 중에서 선택되는 정유성분은 조성물 총 중량에 대하여 0.001중량% 미만의 양으로 사용되는 경우 섬유손상 방지 및 항균·방향효과가 거의 없으며, 1중량% 초과의 양으로 사용되는 경우 가용화가 곤란한 문제점이 있을 수 있다. 따라서, 본 발명 중 상기 정유성분은 조성물 총 중량에 대하여 0.001 내지 1중량%의 양으로 포함되는 것이 바람직하다.The essential oil component selected from the group consisting of basil oil, marjoram oil, lemongrass oil, clover oil, bay oil, cumin oil, thyme oil or a mixture of two or more thereof is less than 0.001% by weight based on the total weight of the composition. When used in the absence of fiber damage prevention and antibacterial and aromatic effects, when used in an amount of more than 1% by weight solubilization may be difficult. Therefore, the essential oil component of the present invention is preferably included in an amount of 0.001 to 1% by weight based on the total weight of the composition.

한편, 본 발명 중 탄소수 1 내지 4의 저급알코올이 선택적으로 사용될 수 있으며, 이들 중 에탄올을 사용하는 것이 더욱 바람직하다. 한편, 본 발명 중 선택적으로 함유되는 상기 알코올은 조성물 총 중량에 대하여 0.1중량% 미만의 양으로 사용되는 경우 정유를 가용화시키는 효과가 거의 없으며, 10중량% 초과의 양으로 사용되는 경우 전체 조성물 중 다른 성분들의 함량을 감소시켜 조성물의 물성에 영향을 줄 수 있다. 따라서, 본 발명 중 상기 알코올은 조성물 총 중량에 대하여 0.1 내지 10중량%의 양으로 포함되는 것이 바람직하다.Meanwhile, among the present invention, lower alcohols having 1 to 4 carbon atoms may be selectively used, and among them, ethanol is more preferable. On the other hand, the alcohol optionally contained in the present invention has little effect of solubilizing essential oil when used in an amount of less than 0.1% by weight based on the total weight of the composition, when used in an amount of more than 10% by weight of the other composition Reducing the content of the components can affect the physical properties of the composition. Therefore, the alcohol in the present invention is preferably included in an amount of 0.1 to 10% by weight relative to the total weight of the composition.

이하, 다림질 보조제 조성물을 실시예 및 비교예를 들어 보다 구체적으로 설명하지만 본 발명이 이들예로만 한정되는 것은 아니다.Hereinafter, the ironing aid composition will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited only to these examples.

[실시예 1∼4 ]EXAMPLES 1-4

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 레몬그라스오일Lemongrass Oil 0.0010.001 0.100.10 0.500.50 1.01.0 에탄올ethanol 2.002.00 2.002.00 3.003.00 5.005.00 정제수Purified water 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount

상기 표 2에 기재된 바와 같은 성분 함량을 갖도록 각 성분을 혼합한 후, 통상의 방법에 따라 상기 실시예 1 내지 4의 다림질 보조제 조성물을 제조하였다.After mixing each component to have a component content as described in Table 2, to prepare the ironing aid composition of Examples 1 to 4 according to a conventional method.

[시험예 1][Test Example 1]

동일 재질의 섬유 5장을 준비한 후 일반인 20명을 피시험자로 하여, 상기 실시예 1 내지 4의 다림질 보조제 조성물을 각각 분무하여 다림질한 후 24시간 경과시의 섬유와 방향성분으로서 레몬그라스오일을 적용하여 제조된 섬유유연제(비교예 1)를 처리한 후 24시간 건조시킨 섬유의 향취강도를 평가하게 한 후, 그 결과를 하기 표 3에 나타내었다. 또한, 향취 지속성을 평가하기 위해 상기 향취강도를 2일, 3일, 4일, 5일 경과시에도 각각 측정하였다. 이때, 섬유유연제는 일반 시중제품임을 감안하여 0.5%의 부향율을 적용하였다.After preparing five pieces of fibers of the same material, 20 people were tested, and the iron supplement composition of Examples 1 to 4 was sprayed and ironed, respectively, and lemongrass oil was applied as a fiber and an aromatic component after 24 hours. After the fabric softener (Comparative Example 1) was prepared and evaluated for the fragrance intensity of the fiber dried for 24 hours, the results are shown in Table 3 below. In addition, in order to evaluate the scent persistence, the scent intensity was measured after 2 days, 3 days, 4 days, 5 days, respectively. At this time, considering that the fabric softener is a commercial product, a fragrance of 0.5% was applied.

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 비교예 1Comparative Example 1 1일1 day 3.23.2 3.73.7 4.24.2 4.54.5 4.84.8 2일2 days 33 3.53.5 4.04.0 4.24.2 4.74.7 3일3 days 2.62.6 3.53.5 3.73.7 44 4.54.5 4일4 days 22 3.33.3 3.73.7 3.83.8 4.54.5 5일5 days 1.61.6 33 3.53.5 3.83.8 4.54.5

*향취평가기준** Flavor Evaluation Criteria *

1 : 무향1: no fragrance

2 : 향취가 약함2: weak odor

3 : 향취가 보통임3: The smell is normal

4 : 향취가 적절함4: Appropriate smell

5 : 향취가 매우 적절함5: very good odor

상기 표 3에서 알 수 있는 바와 같이, 본 발명의 다림질 보조제 조성물인 실시예 1 내지 4는 섬유유연제인 비교예 1에 비하여 향취강도 및 지속성이 우수한 것으로 나타났다.As can be seen in Table 3, Examples 1 to 4 of the ironing aid composition of the present invention was found to be excellent in odor strength and durability compared to Comparative Example 1, a fabric softener.

[시험예 2][Test Example 2]

4.2×4.2㎠ 크기의 100표준 면포 3장을 준비한 후, 2장의 면포에는 각 실시예 1 및 실시예 4의 보조제 조성물을 0.25㎖/장을 처리하고 나머지 1장의 면포에는 무처리한 상태(비교예 2)에서 황색포도상구균을 24시간동안 접촉시킨 후 직물의 항균도 시험방법인 KS K0693-1990에 따라 균수 및 사멸율을 측정하고, 그 결과를 하기 표 4에 나타내었다.After preparing three 100 standard cotton cloths having a size of 4.2 × 4.2 cm 2, two cotton cloths were treated with 0.25 ml / sheet of the adjuvant compositions of Examples 1 and 4, and the other one cotton cloth was not treated (Comparative Example). 2) in contact with Staphylococcus aureus for 24 hours, the number of bacteria and the killing rate was measured according to the antimicrobial test KS K0693-1990 method of the fabric, the results are shown in Table 4 below.

실시예 1Example 1 실시예 4Example 4 비교예 2Comparative Example 2 대조편(초기)Contrast edition (initial) 균수(cfu/㎖)Number of bacteria (cfu / ml) 2.05E042.05E04 6.00E026.00E02 2.10E092.10E09 1.00E061.00E06 사멸율(%)% Mortality 97.9597.95 99.9499.94 00 --

*항균평가기준** Antimicrobial Evaluation Criteria *

사멸율≥90 : 항균효과 우수Mortality ≥ 90: excellent antibacterial effect

상기 표 4에서 알 수 있는 바와 같이, 무처리제인 비교예 2는 항균효능이 전혀 없는 반면 본 발명의 다림질 보조제 조성물인 실시예 1 및 4는 항균효능이 우수한 것으로 나타났다. 따라서, 합성 살균제나 방부제를 별도로 첨가할 필요가 없으며 땀이나 오염에 의한 세균의 번식을 막아 냄새발생을 억제하는 기능을 발휘할 수 있다.As can be seen in Table 4, Comparative Example 2, which is a non-treatment agent has no antimicrobial effect, while Examples 1 and 4 of the ironing aid composition of the present invention was shown to have excellent antibacterial effect. Therefore, it is not necessary to add a synthetic fungicide or preservative separately, and it can exert a function of suppressing odor generation by preventing the growth of bacteria due to sweat or contamination.

이상에서 알 수 있는 바와 같이, 본 발명의 다림질 보조제 조성물은 내열성이 우수하고 각종 면 등의 천연섬유류나 폴리에스테르 등의 합성섬유에 대하여 변색이나 염착, 탈색 등의 섬유손상이 없고 일광에 노출되어도 섬유의 형태나 색상의변퇴색 및 염착 등의 섬유손상을 주지 않으므로 안전하게 사용할 수 있을 뿐만 아니라, 섬유에 서식하는 세균들을 살균하고 생성을 억제하며 방향효과로 좋지 않은 냄새를 차단할 수 있다.As can be seen from the above, the ironing aid composition of the present invention has excellent heat resistance and is free from fiber damage such as discoloration, dyeing, or discoloration of natural fibers such as various cottons or synthetic fibers such as polyester, and is exposed to sunlight. It does not give fiber damages such as discoloration and dyeing of the form and color, so it can be used safely, and sterilizes the bacteria inhabiting the fiber, suppresses the production, and blocks the bad smell by the aroma effect.

Claims (3)

바질오일, 마조람오일, 레몬그라스오일, 클로버오일, 베이오일, 큐민오일, 타임오일 또는 이들 중 2이상의 혼합물로 이루어지는 그룹 중에서 선택되는 정유성분 0.001 내지 1중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 하는 다림질 보조제 조성물.0.001 to 1% by weight of essential oils selected from the group consisting of basil oil, marjoram oil, lemongrass oil, clover oil, bay oil, cumin oil, thyme oil or a mixture of two or more thereof, and water as a balance. Iron adjuvant composition. 제 1항에 있어서,The method of claim 1, 탄소수 1 내지 4의 저급알코올 0.1 내지 10중량%를 더 포함하는 것을 특징으로 하는 다림질 보조제 조성물.Ironing aid composition, characterized in that it further comprises 0.1 to 10% by weight of lower alcohol having 1 to 4 carbon atoms. 제 2항에 있어서,The method of claim 2, 상기 저급알코올이 에탄올임을 특징으로 하는 다림질 보조제 조성물.Iron lowering aid composition, characterized in that the lower alcohol.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030090120A (en) * 2002-05-21 2003-11-28 주식회사 에이프로스 엔터프라이즈 Hydrophobic aid composition for ironing and method of preparing same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0597618A (en) * 1991-10-04 1993-04-20 Osaka Seiyaku:Kk Mothproofing agent for clothes moth
JP2001031516A (en) * 1999-07-15 2001-02-06 Murata Makoto Antibacterial, deodorizing and antioxidation composition produced by using component originated from mosla chinensis maxim. and its processed product
US6346281B1 (en) * 2000-05-05 2002-02-12 Scentsible Life Products, A Division Of Laid Back Designs Ltd. Antimicrobial composition formulated with essential oils

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0597618A (en) * 1991-10-04 1993-04-20 Osaka Seiyaku:Kk Mothproofing agent for clothes moth
JP2001031516A (en) * 1999-07-15 2001-02-06 Murata Makoto Antibacterial, deodorizing and antioxidation composition produced by using component originated from mosla chinensis maxim. and its processed product
US6346281B1 (en) * 2000-05-05 2002-02-12 Scentsible Life Products, A Division Of Laid Back Designs Ltd. Antimicrobial composition formulated with essential oils

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030090120A (en) * 2002-05-21 2003-11-28 주식회사 에이프로스 엔터프라이즈 Hydrophobic aid composition for ironing and method of preparing same

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