KR20030066087A - A water-soluble mold release agent of tire - Google Patents

A water-soluble mold release agent of tire Download PDF

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Publication number
KR20030066087A
KR20030066087A KR1020020006252A KR20020006252A KR20030066087A KR 20030066087 A KR20030066087 A KR 20030066087A KR 1020020006252 A KR1020020006252 A KR 1020020006252A KR 20020006252 A KR20020006252 A KR 20020006252A KR 20030066087 A KR20030066087 A KR 20030066087A
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South Korea
Prior art keywords
tire
release agent
water
weight percent
mold release
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KR1020020006252A
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Korean (ko)
Inventor
장문수
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장문수
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Priority to KR1020020006252A priority Critical patent/KR20030066087A/en
Publication of KR20030066087A publication Critical patent/KR20030066087A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/0601Vulcanising tyres; Vulcanising presses for tyres
    • B29D30/0662Accessories, details or auxiliary operations

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

PURPOSE: A water-soluble release agent for a tire is provided to improve work efficiency, and to prevent the injury of a worker by using harmless paraffin oil as the release agent for the tire. CONSTITUTION: A water-soluble release agent for a tire is composed of paraffin oil of 1-40 weight percent, oleic acid of 0.01-10 weight percent, stearic acid of 0.01-10 weight percent, an emulsifying agent of 0.01-10 weight percent, antifoaming agent of 0.01-10 weight percent, a thickener of 0.01-10 weight percent, and water of 60-95 weight percent.

Description

타이어 수용성 성형 이형제 {A WATER-SOLUBLE MOLD RELEASE AGENT OF TIRE}Tire Water Soluble Mold Release Agent {A WATER-SOLUBLE MOLD RELEASE AGENT OF TIRE}

본 발명은 타이어 수용성 성형 이형제에 관한 것으로서, 화장품 원료를 주원료로 인체에 대한 유해성을 제거함에 따라 작업성의 향상과 환경오염의 우려가 없는 타이어 수용성 성형 이형제에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-soluble mold release agent for tires, and relates to a tire water-soluble mold release agent without the possibility of improvement of workability and environmental pollution by removing harmful substances to the human body as a cosmetic raw material.

기존의 타이어 제조 공정중 인체에 유해한 물질이 발생하여 작업자 및 환경에 지대한 영향을 미치고 있는 성형 이형제를 환경친화적인 것과 더욱 상세하게는 인체에 무해한 파라핀 오일을 사용하였다. 기존의 성형 이형제에서는 작업성만을 고려한 것으로 작업자의 건강과 환경 적인 측면을 고려하지 않아 큰 단점으로 부각되고 있어, 작업성 향상과 위의 조건에 만족하는 타이어 수용성 성형 이형제를 특징으로 한다.In the existing tire manufacturing process, a mold release agent having harmful effects on humans and the environment due to harmful substances to the human body is used, and in particular, paraffin oil which is harmless to the human body is used. In the existing mold release agent, only workability is considered, and it is a big disadvantage because it does not consider the health and environmental aspects of the worker, and it is characterized by the water-soluble mold release agent which improves workability and satisfies the above conditions.

본 발명의 이루고자하는 기술적 과제는 환경친화적인 타이어 수용성 성형 이형제를 만들어 작업자의 건강과 환경친화적인 물질로 대체 함에 따라 보다 질 좋은 타이어 제품 생산을 목표로 하고있다.The technical problem to be achieved of the present invention aims to produce a better tire product by replacing the environmentally friendly tire water-soluble mold release agent with a worker's health and environmentally friendly materials.

본 발명의 타이어 수성계 성형 이형제 조성물의 파라핀오일은 화장품의 원료로 사용하고 있어 환경친화적이고 인체에 무해하다. 특히 타이어 제품 생산에도 좋은 것으로 실험되었다.The paraffin oil of the aqueous tire-based mold release agent composition of the present invention is used as a raw material for cosmetics and is environmentally friendly and harmless to humans. In particular, it was tested to be good for tire products.

타이어 수성계 성형 이형제에 제조 방법에 있어서 중요한 것은 온도와 파라핀오일과 유화제의 비율이다. 이 방법은 파라핀 오일을 유화시킨 것으로 온도 50 ~ 99℃, 온도가 낮으면 유화가 되지 않고, 높으면 산화가 일어나 색깔의 변화와 냄새가 발생하여 제품으로서의 가치가 없어진다. 또한 파라핀오일과 유화제의 비율에 따라 유화성이 달라지므로 아래 표 1에 나타난 것과 교반속도가 중요한 인자로 작용하는 것을 특징으로 한다. 이러한 조건이 이루어지지 않으면 층분리 현상이 빨리 일어나 보관성이 없어져 제품으로서 가치를 상실하게 된다.What is important in the manufacturing method for the tire-based molding release agent is the temperature, the ratio of paraffin oil and emulsifier. This method is emulsified paraffin oil. If the temperature is 50 ~ 99 ℃, and the temperature is low, it is not emulsified. If the temperature is high, oxidation occurs and color change and odor are generated, thus losing its value as a product. In addition, since the emulsification properties vary depending on the ratio of paraffin oil and emulsifier, it is characterized in that the stirring speed as shown in Table 1 below acts as an important factor. If these conditions are not met, delamination will quickly occur, resulting in loss of shelf life and loss of value as a product.

더욱 상세한 제조방법은 파라핀오일, 올레인산, 스테아린산을 70 ~ 90℃로 가열한 다음 유화제를 넣어 충분한 교반(5~10분)후, 최대 교반 속도로 이루어지고 있는 상태에서 물(70 ~ 99℃)을 적하, 반응이 끝난 후 30분간 추가 교반, 소포제를 넣은 후 아주 천천히 교반, 점증제를 넣어 제조하는 방법를 특징으로 하는 타이어 성형 수성계 이형제 이다.More detailed manufacturing method is to heat the paraffin oil, oleic acid, stearic acid to 70 ~ 90 ℃ and then add sufficient emulsifier (5 ~ 10 minutes), water (70 ~ 99 ℃) at the maximum stirring speed It is a tire-forming aqueous-based releasing agent, characterized in that the addition of the stirring, 30 minutes after the reaction is completed, the antifoaming agent is added, and then very slowly stirring, adding a thickener.

[실시예 ]EXAMPLE

하기 표 1의 조성에 따라, 최적의 타이어 수성계 성형 이형제를 제조하게 되는 것을 특징으로 한다.According to the composition of Table 1, it is characterized in that to produce the optimum tire-based molding release agent.

실시예에서, 파라핀 오일과 점증제를 변화시켜 최적의 타이어 수성계 성형 이형제를 만드는 조건을 나타낸 것으로 실시예 1∼2는 파라핀 오일과 점증제의 양이 적어 표 2 에서와 같이 저장성이 떨어진다. 실시예 4∼5는 파라핀 오일과 점증제의 양이 많아지므로 표 2에서와 같이 금형 표면의 오염이 나타나 제품의 질이 떨어진다.In the Examples, paraffin oil and thickener are changed to show the conditions for making an optimum tire-based molding release agent. Examples 1 to 2 show a low amount of paraffin oil and a thickener, so that storage is poor as shown in Table 2. In Examples 4 to 5, since the amount of paraffin oil and thickener increases, contamination of the mold surface appears as shown in Table 2, resulting in poor product quality.

[표 1]TABLE 1

(단위 : 중량%)(Unit: weight%)

성분ingredient 실시예1Example 1 실시예2Example 2 실시예3Example 3 실시예4Example 4 실시예5Example 5 파라핀오일Paraffin oil 22 55 1010 1515 2525 올레인산Oleic acid 1One 1One 1One 1One 1One 스테아린산Stearic acid 22 22 22 22 22 계면활성제Surfactants CA- 2CA-2 0.60.6 0.60.6 0.60.6 0.60.6 0.60.6 CA- 5CA-5 0.60.6 0.60.6 0.60.6 0.60.6 0.60.6 CA-13CA-13 0.60.6 0.60.6 0.60.6 0.60.6 0.60.6 CA-20CA-20 0.60.6 0.60.6 0.60.6 0.60.6 0.60.6 water 소포제Antifoam 1One 1One 1One 1One 1One TEATEA 0.50.5 0.50.5 0.50.5 0.50.5 0.50.5 점증제(SN-920)Incremental Agent (SN-920) 0.50.5 1One 1.51.5 22 2.52.5 합계Sum 100100 100100 100100 100100 100100

위의 표1의 조건으로 만든 것을 측정한 결과 표 2와 같이 실시예 3이 최적의 이형제로 나타난 것이 특징이다.As a result of measuring the conditions made in the conditions of Table 1 above, as shown in Table 2, Example 3 is characterized by the optimum release agent.

[표 2]TABLE 2

구분division 실시예1Example 1 실시예2Example 2 실시예3Example 3 실시예4Example 4 실시예5Example 5 PH(25℃)PH (25 ℃) 8.248.24 8.368.36 8.398.39 8.458.45 8.568.56 층분리속도Layer Separation Rate 10일이상More than 10 days 20일이상20 days or more 30일이상30 days or more 37일이상More than 37 days 49일이상49 days or more 분사균일성Spray uniformity 불량Bad 양 호Good 가장양호The best 양 호Good 양 호Good 고무-고무간의 접착력Rubber-rubber adhesion 양 호Good 양 호Good 가장양호The best 양 호Good 양 호Good 금형 표면의오염도Contamination degree of mold surface 양 호Good 양 호Good 가장양호The best 불량Bad 불량Bad

이상에서 설명된 바와 같이, 본 발명의 타이어 수성계 성형 이형제에 사용된 파라핀 오일은 화장품의 원료로 사용하고 있어 인체에 무해하고 수용성이라 작업자의 건강과 환경 적인 측면에서 선호도가 높을 것으로 기대된다.As described above, the paraffin oil used in the tire-based molding release agent of the present invention is used as a raw material for cosmetics, so it is expected to have high preference in terms of health and environment of the worker because it is harmless to the human body and water-soluble.

Claims (1)

파라핀오일(65~100%) 1 ~ 40중량%, 올레인산 0.01 ~ 10중량%, 스테아린산 0.01 ~ 10중량%, 유화제 0.01 ~ 10중량%, 소포제 0.01 ~ 10중량%, TEA 0.01 ~ 10중량%, 증점제 0.01 ~ 10중량%, 물 60 ~ 95량%의 조성물를 포함 하는 것을 특징으로 하는 타이어 수용성 성형 이형제.Paraffin oil (65-100%) 1-40 wt%, oleic acid 0.01-10 wt%, stearic acid 0.01-10 wt%, emulsifier 0.01-10 wt%, defoamer 0.01-10 wt%, TEA 0.01-10 wt%, thickener A tire water-soluble molding release agent comprising a composition of 0.01 to 10% by weight, water 60 to 95% by weight.
KR1020020006252A 2002-02-04 2002-02-04 A water-soluble mold release agent of tire KR20030066087A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102432390B1 (en) * 2021-04-01 2022-08-11 이덕우 Water soluble releasing agent composition for casting of quartz sand

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR930009730A (en) * 1991-11-28 1993-06-21 유채준 Tire Release Agent Composition
JPH05309663A (en) * 1992-05-13 1993-11-22 Ebi Shoji Kk Releasant for molding resin product
KR19980077542A (en) * 1997-04-21 1998-11-16 홍건희 Release agent composition for tire vulcanization
KR100211907B1 (en) * 1997-06-19 1999-08-02 신형인 Silicon release material for tyre flap
KR100237586B1 (en) * 1995-10-12 2000-01-15 와다 아끼히로 Parting agent for die-casting
JP2001096541A (en) * 1999-09-30 2001-04-10 Neos Co Ltd Aqueous mold release agent for urethane foam
KR20010071311A (en) * 1998-05-28 2001-07-28 추후보정 Relaese agent, its use and method for producing same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR930009730A (en) * 1991-11-28 1993-06-21 유채준 Tire Release Agent Composition
JPH05309663A (en) * 1992-05-13 1993-11-22 Ebi Shoji Kk Releasant for molding resin product
KR100237586B1 (en) * 1995-10-12 2000-01-15 와다 아끼히로 Parting agent for die-casting
KR19980077542A (en) * 1997-04-21 1998-11-16 홍건희 Release agent composition for tire vulcanization
KR100211907B1 (en) * 1997-06-19 1999-08-02 신형인 Silicon release material for tyre flap
KR20010071311A (en) * 1998-05-28 2001-07-28 추후보정 Relaese agent, its use and method for producing same
JP2001096541A (en) * 1999-09-30 2001-04-10 Neos Co Ltd Aqueous mold release agent for urethane foam

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102432390B1 (en) * 2021-04-01 2022-08-11 이덕우 Water soluble releasing agent composition for casting of quartz sand

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