KR20030043542A - manufacture metal latex and pored pottery - Google Patents

manufacture metal latex and pored pottery Download PDF

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Publication number
KR20030043542A
KR20030043542A KR1020010075575A KR20010075575A KR20030043542A KR 20030043542 A KR20030043542 A KR 20030043542A KR 1020010075575 A KR1020010075575 A KR 1020010075575A KR 20010075575 A KR20010075575 A KR 20010075575A KR 20030043542 A KR20030043542 A KR 20030043542A
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KR
South Korea
Prior art keywords
metal
latex
clay
aluminum
feldspar
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KR1020010075575A
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Korean (ko)
Inventor
최명부
이광덕
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최명부
이광덕
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Priority to KR1020010075575A priority Critical patent/KR20030043542A/en
Publication of KR20030043542A publication Critical patent/KR20030043542A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2207/00—Compositions specially applicable for the manufacture of vitreous enamels
    • C03C2207/10—Compositions specially applicable for the manufacture of vitreous enamels for copper, silver or gold

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

PURPOSE: Provided is a preparation method of metallic glaze applied to pottery by using Au, Ag, Al, Cu, Ni, etc. The metal-glazed pottery is newly adapted to construction and living fields. CONSTITUTION: The Al(or Cu)-glaze contains 5kg of aluminum(copper), 10kg of feldspar, 10kg of white clay, 10kg of clay, 10kg of limestone, 3kg of BaCO3, 2kg of zinc, 5kg of talc, and 100L of water. The Ag-glaze contains 1kg of Ag, 10kg of feldspar, 5kg of talc, 10kg of limestone, 3kg of BaCO3, 2kg of Zn, and 50L of water. The Au-glaze contains 300g of Au, 10kg of feldspar, 10kg of talc, 3kg of clay, 7kg of white clay, 3kg of BaCO3, 2kg of zinc and 50L of water. The metal-glazed pottery is produced by dipping clay products to the above glaze and sintering at 1250deg.C.

Description

금속도자기 유액제조{manufacture metal latex and pored pottery}Manufacturing metal latex and porcelain pottery

본 발명은 도자기 금속 유액제조에 관한 것이다. 본 기술은 현재 생활도자기 또는 건축용타일, 화장실 변기 등에 널리 사용하고 있는 도자기 유액을 완전히 배제하고 새로운 금속 디자인을 만들어 상기 생활도자기 백자나 건축용타이루 건축용 내, 외장제 또는 화장실 변기 등에 본 발명의 도자기 금속 유액을 사용하므로 지금까지 찾아볼 수 없는 새로운 도자기 디자인을 창출하는데 있다. 본 발명에서 새로운 금속 도자기 유액을 제공하기 위해서 먼저 건축용으로 현재 널리 사용하고 있는 타이루 또는 화장실, 변기 등을 살펴볼 것 같으면 다음과 같다. 오랫동안 타이루나 변기가 우리 생활에 응용하면서 상기 디자인이 우리 눈에 고정적으로 박혀오면서 그 변화나 사용용도가 한계에 이르고 있다. 본 발명은 이러한 종래의 타이루나 변기 등에 새로운 디자인을 창출할 수 있는 기술 등을 제공하는데 있다. 먼저 본 발명의 금속 유액 중 알미늄타이루나 건축용 내, 외장제를 만들기 위해 알미늄 분말, 장석, 백토, 점토, 탄산바륨, 석회석, 아연 등을 합성하여 유액을 만들어 타이루나 건축용 내, 외장제를 사용할 경우 알미늄의 우아한 광택과 성능은 지금까지 타이루에서나 알미늄에서 찾아볼 수 없는 새로운 디자인이라고 볼수 있다. 또한 금분을이용하여 상기 알미늄 금속 유액을 제조하듯이 금 유액을 만들어 화장실 변기 등에 사용하여 황금변기 또는 합금타이루 등을 제조했을 때 그 디자인은 물론 최고급 건축 내, 외장제 등을 만들 수 있다. 또한 그릇으로는 최고급 황금색 그릇 장식품을 만들 수 있고 은그릇을 만들어 사용할 수 있다. 은(銀)은 옛날부터 항균금속으로 인자에 안정성이 높아 왕실에서는 귀족들이 많이 즐겨 사용하였다. 은 그릇에 음식물을 담아두면 음식물의 신선도가 오래가고 잘 부폐되지 않는 것이 옛날부터 발견되어 은 그릇을 귀족사회에 높이 평가되어 사용하였다. 근대에 와서는 지상의 모든 병균이나 바이러스가 은(銀)에 접촉되어 6분간 살아 남는 균이나 병균이 없다고 보고되어 은(銀)에 대한 무기 항균성은 높이 평가하고 있다. 또한 본 발명에서 동(同)금속 유액제조 등을 살펴 볼 것 같으면 다음과 같다. 동(同)도 옛날부터 항균 금속으로 널리 사용되었으나 근대에 와서는 유전변이 등을 일으키는 것이 확인되어 동(同)단독으로 그 사용을 규제하고 있다. 동(同)은 살균효과가 높으나 물과 공기 등에 산화되어 아산화동 등을 유발 시키고 있다. 본 발명은 이러한 동의 단점을 보안하고 항균과 살균성을 살리기 위해 동분밀을 장석, 백토, 점토, 탄산바륨, 알미늄, 석회석 등과 유액을 만들어 화장실 변기에 사용할 경우 변기에 항균성이 우수하고 탈취 등이 효과가 있다. 또한 목욕탕 등의 타이루, 동 또는 건축 자재로 사용할 경우 항균성과 탈취효과가 우수하다. 그러나 동이 금속유액을 만들면서 광물질과 무기물이 상기 동분과 합성하여 녹아 물이나 공기 등에 대하여 잘 산화되지 않고 안정성이 높은 것이 확인되고 있다. 또한 본 발명에서 알미늄금속 유액을 만들어 건축자재로 사용할 경우 기존 알미늄 샷쉬 또는 건축용 자재로 사용하는 알미늄보다 안정성이 높을 뿐 아니라 그 사용 용도가 광범위하고 광택이 기존 알미늄보다 우화하고 마모 등이 없고 산화가 잘되지 않는 것이 특징이다. 또한 닉켈 등은 분말을 만들기가 매우 힘들다. 본 발명은 염화 닉켈을 물에 용해하여 염소를 날려보내고 구연산소오다와 환원제 등을 사용하여 장석, 백토, 점토, 석회석, 탄산바륨, 아연 등에 치환시켜 유액을 만들면 닉켈 고유의 도자기 유액을 제공할 수 있는 기술이다. 현재 널리 사용하고 있는 생활도자기의 유액 제조는 공지화 되었기 때문에 더 기론하지 않겠다.The present invention relates to the manufacture of porcelain metal latex. The present technology completely eliminates the latex of ceramics widely used in household ceramics, building tiles, and toilets, and creates a new metal design to make the porcelain metals of the present invention, such as white porcelain, architectural ceramics, interiors, exteriors, or toilets. The use of latex is to create a new ceramic design that has not been found so far. In order to provide a new metal porcelain latex in the present invention, first, the present invention will be described as follows. As the design of Tairu and toilets have been applied to our lives for a long time, the design has been fixed in our eyes, and its changes and uses are reaching its limits. The present invention is to provide a technique that can create a new design, such as a conventional tyre, toilet bowl. First of all, in order to make aluminum tires or architectural interiors and exterior materials in the metal latex of the present invention, aluminum powder, feldspar, clay, clay, barium carbonate, limestone, zinc, etc. are synthesized to form an emulsion to use tyru or architectural interiors and exterior materials. The elegant luster and performance of aluminum is a new design not found in tairu or aluminum so far. In addition, gold powder is used to make the aluminum metal latex, and when the golden latex is used to make a golden toilet or alloy tire, etc., the design, as well as the finest interior and exterior materials can be made. You can also make high-quality golden bowl ornaments or make silver bowls. Silver (銀) has long been used by the nobility in the royal family due to its high stability in antibacterial metals. When the food was put in silver bowls, the freshness of the foods lasted long and was not easily broken, and the silver bowls were highly regarded and used by the aristocracy. In modern times, it is reported that all germs and viruses on the ground are in contact with silver and survive for 6 minutes. Therefore, the inorganic antimicrobial activity against silver is highly appreciated. In addition, if the present invention looks at the production of the same metal emulsion, etc. are as follows. Although copper has been widely used as an antibacterial metal since ancient times, it has been found to cause genetic variation in modern times, and its use is regulated solely. Copper has a high bactericidal effect, but is oxidized in water and air to induce nitrous copper. The present invention is excellent in antibacterial and deodorizing the toilet when using the toilet bowl made of copper powder to feldspar, clay, clay, barium carbonate, aluminum, limestone, etc. in order to secure the disadvantages of this motion and utilize antibacterial and bactericidal. have. In addition, it is excellent in antibacterial and deodorizing effect when used as a tairu, copper or building material such as bath. However, while copper forms a metal emulsion, it has been confirmed that minerals and inorganic substances are synthesized with the copper powder to melt, so that they do not oxidize well with water or air and have high stability. In addition, in the present invention, when the aluminum metal latex is made and used as a building material, it is not only higher in stability than the existing aluminum sash or aluminum used as a building material, but also has a wider use, has a gloss than the existing aluminum, does not wear well, and is well oxidized. It is not characteristic. Nickel and others are also very hard to make powder. In the present invention, nickel chloride is dissolved in water to blow off chlorine, and substituted with feldspar, clay, clay, limestone, barium carbonate, zinc, etc. using sodium citrate and a reducing agent to provide a latex nickel unique porcelain emulsion. It is a skill. The manufacture of latex ceramics, which are widely used at present, is not known because it is known.

본 발명은 기존 도자기유액에서 찾아볼 수 없는 아이디어를 제공하여 새로운 금속도자기 유액을 만들어 생활도자기에 응용하면서 건축자재 등에 본 발명의 유액을 사용하므로 은그릇 황금식기 황금변기 또한 황금타이루 등으로 황금목욕탕 건축 내, 외장제등의 기술을 제공하여 최고급 금속유액을 생활도자기 및 건축자제 등에 새롭게 응용할 수 있는 기술을 개발하여 새로운 도자기 디자인을 개발하는데 있다.The present invention provides an idea that can not be found in the existing porcelain latex to create a new metal ceramic latex and apply it to living ceramics, while using the latex of the present invention for building materials, such as silver bowl golden tableware golden toilet and golden Thai bath It is to develop new ceramic design by developing technology that can newly apply high-quality metal latex to living ceramics and building materials by providing technology such as interior and exterior materials.

본 발명의 도자기 금속 유액제조의 구성을 살펴볼 것 같으면 다음과 같다. 금속도자기 유액을 제조할 수 있는 금속유액은 알미늄 금속유액과 동(同)금속 유액과 닉켈 금속 중 닉켈 금속유액을 제거하고는 그 제조를 살펴보면 다음과 같다. 먼저 은(銀)은 소립 분쇄한 은분말과 금은 시중에 분말로 시판되고 있는 금분말을 사용할 수 있고 또한 알미늄 분말과 동(同)분은 시중에 널리 시판되고 있다. 상기 금속 도자기 유액제조를 간단히 살펴볼 것 같으면 다음과 같다. 먼저 은을 살펴볼 것같으면 은(銀) 1g을 이용하여 1800m의 실을 뽑을 수 있다고 되어 있다. 은이 소립으로 분말될 때 은(銀)이 유액 등에 퍼지는 표면 밀도나 장력은 매우 크다. 먼저 은(銀)분 1000g을 장석 10kg, 백토, 점토 각각 5kg, 석회석 10kg, 탄산바륨 3kg, 아연 2kg, 활석 5kg에 합성하여 물 50 ι에 용해하여 은 금속도자기 유액을 만들어 그릇 등에 상기 유액을 침지시켜 1250℃의 열로 소성시켜 은그릇을 만드는 기술이다. 또한 금도자기 유액을 살펴볼 것 같다면 다음과 같다. 금분 300g 장석, 활석 각각 10kg과 점토 5kg, 백토 7kg과 석회석 5kg, 아연 2kg, 탄산바륨 3kg을 합성하여 물 50 ι에 용해하여 금도자기 유액을 만들어 변기 또는 타이루 및 그릇을 상기 유액에 침지시켜 1250℃로 소성하여 황금변기 황금그릇 황금타이루를 제공할 수 있다. 알미늄 금속 도자기 유액은 알미늄분말 5kg과 장석 10kg, 활석5kg, 점토, 백토 각각 10kg, 탄산바륨 3kg, 아연 2kg을 합성교반하여 물 100 ι에 용해하여 알미늄 금속 유액을 만들어 타이루 및 건축 내, 외장제를 침지시켜 1250℃열로 소성하여 본 발명의 알미늄 유액도자기를 만들 수 있다. 또한 동분금속 유액을 동분의 량이 알미늄과 같이 3kg이 들어가면서 알미늄금속 유액 사용이나 소성온도가 같다. 상기 동유액은 주로 변기 또는 건축자용 등에 응용할 수 있다. 닉켈금속 유액제조를 살펴볼 것 같으면 닉켈을 분말화 하기가 매우 힘들고 분말이 시판되는 것이 없다. 본 발명은 물에 용해가 잘되는 염화틱켈 10kg을 물70ι에 용해하여 100℃열로 20분간 끓여서 염소를 날려보니고 장석 10kg, 활석 10kg, 석회석 10kg, 점토 백토 각각 5kg, 탄산바륨 3kg, 아연 2kg을 합성하여 환원제인 하이드록 신 1 ι와 구연산소오다 500g을 상기 염화닉켈에 합성하여 용해한 후 물60 ι에 상기 재료를 합성하여유액을 만들어 건축용자재 등에 침지하여 1250℃열로 소성하여 닉켈 금속도자기를 제공하는 기술등을 보다 더 실시예에서 상세하게 설명하기로 한다.Looking at the configuration of the ceramic metal latex production of the present invention as follows. The metal latex that can be prepared for the ceramic ceramic latex is aluminum metal latex, the same metal latex and the nickel metal latex of the nickel metal and remove the nickel metal latex and look at the production as follows. First, silver powder which is pulverized silver and gold powder which are commercially available as a powder can be used, and aluminum powder and copper powder are widely marketed in the market. If you look briefly to the manufacture of metal ware latex as follows. If you look at silver first, you can pull 1800m of thread using 1g of silver. When silver is powdered into small particles, the surface density and tension that silver spreads to an emulsion etc. are very large. First, 1000g of silver powder is synthesized into 10kg of feldspar, 5kg of clay, 5kg each of limestone, 10kg of limestone, 3kg of barium carbonate, 2kg of zinc, and 5kg of talc, dissolved in 50ι of water to form a silver metal ceramic emulsion, soaking the emulsion in a bowl or the like. It is a technique of making silverware by baking with heat of 1250 ℃. In addition, if it looks like the gold latex latex is as follows. Gold powder 300g feldspar, talc 10kg and 5kg clay, 7kg clay 7kg, lime 5kg, zinc 2kg, barium carbonate were synthesized and dissolved in 50 ι of water to make a gold porcelain latex. By firing at ℃ it can provide a golden bowl golden bowl golden bowl. Aluminum metal pottery latex is composed of 5kg aluminum powder, 10kg feldspar, 5kg talc, 10kg clay, 10kg clay, 3kg barium carbonate, 2kg zinc and dissolved in 100ι of water to make aluminum metal latex. It can be immersed in and calcined at 1250 ℃ heat to make the aluminum emulsion ceramic of the present invention. In addition, the copper powder contains 3kg of copper powder in the same amount as aluminum, and the use of aluminum metal emulsion and the firing temperature are the same. The oil is mainly applicable to toilets or builders. If you look at Nickel metal emulsion production, it is very difficult to powder Nickel and there is no powder available. The present invention dissolves 10 kg of titanium chloride well dissolved in water in 70ι water and boils for 20 minutes at 100 ° C. heat to blow chlorine and synthesizes 10 kg of feldspar, 10 kg of talc, 10 kg of limestone, 5 kg of clay clay, 3 kg of barium carbonate and 2 kg of zinc. By dissolving 1 ι of reducing agent hydroxy and 500 g of sodium citrate in the nickel chloride, and then dissolving the material in 60 ι of water to make an emulsion, immersing it in building materials, etc. and baking it at 1250 ° C. to provide nickel metal ceramics. Techniques, etc. will be described in more detail in the examples.

[실시예 1]Example 1

도자기금속 유액제조 알미늄, 은, 금, 동(同)금속 제조Pottery Metal Latex Manufacture Aluminum, silver, gold, copper metal

제1공정1st process

알미늄 분말 5kg, 장석 10kg, 백토10kg, 점토10kg, 석회석 10kg, 탄산바륨 3kg, 아연2kg, 활석 5kg을 합성하여 물100 ι 정량하여 알미늄 금속유액을 만든다.Aluminum powder 5kg, feldspar 10kg, white clay 10kg, clay 10kg, limestone 10kg, barium carbonate 3kg, zinc 2kg, talc 5kg is synthesized to determine the aluminum metal latex.

제2공정2nd process

제1공정의 약품 중 알미늄 분말 대신에 동분 5kg을 합성하여 동(同) 금속 유액을 만든다.5 kg of copper powder is synthesized in place of the aluminum powder in the chemical of the first step to form a copper metal emulsion.

제3공정3rd process

은(銀)을 소립 분쇄한 입자 1kg과 장석 10kg, 활석 5kg, 석회석 10kg, 탄산바륨 3kg, 아연2kg을 정량하여 합성하여 물50ι에 용해하여 은금속유액을 만든다.1kg of pulverized silver particles and 10kg of feldspar, 5kg of talc, 5kg of limestone, 10kg of limestone, 3kg of barium carbonate and 2kg of zinc were synthesized and dissolved in 50ι of water to make silver metal emulsion.

제4공정4th process

금분 300g, 장석10kg, 활석 10kg, 점토 3kg, 백토 7kg, 석회석 5kg, 탄산바륨 3kg, 아연2kg을 합성하여 물50ι에 용해 교반하여 금 도자기 유액을 만든다.300 g of gold powder, 10 kg of feldspar, 10 kg of talc, 3 kg of clay, 7 kg of clay, 5 kg of limestone, 3 kg of barium carbonate, and 2 kg of zinc are synthesized and stirred in 50ι of water to form a gold porcelain emulsion.

제5공정5th process

염화닉켈 10kg을 물 20ι에 용해하여 100℃열로 20분간 끓여서 염소를 날려보낸 용액에 구연산소다 500g과 환원제인 하이드록신 1 ι를 용해 교반하여 반응시킨다. 또한 상기 용액에 장석10kg, 활석 10kg, 점토 5kg, 백토 5kg, 석회석 10kg,탄산바륨 3kg, 아연2kg을 합성교반하여 물60ι에 용해하여 닉켈금속 유액을 만든다.10 kg of nickel chloride was dissolved in 20ι of water, boiled for 20 minutes at 100 ° C. heat, and 500 g of sodium citrate and 1 ι of hydroxyxine as a reducing agent were reacted by stirring. In addition, 10 kg of feldspar, 10 kg of talc, 5 kg of clay, 5 kg of clay, 5 kg of limestone, 10 kg of limestone, 3 kg of barium carbonate, and 2 kg of zinc were synthesized and dissolved in 60 ° of water to form a nickel metal emulsion.

실시예 2Example 2

금속유액 사용방법How to use metal latex

제1공정1st process

실시예1의 금속유액의 도자기 제조의 용도별로 도자기에 유액을 침지시켜 1250℃열로 소성가공하여 기능성 금속 도자기를 만드는 기술이다.It is a technique of making a functional metal ware by immersing the emulsion in the ceramics for each use of the metal latex of Example 1 by firing process in 1250 ℃ heat.

본 발명은 기존 도자기 유액에서 찾아 볼 수 없는 금속 유액을 만들어 생활도자기 또는 건축자재 등에 응용하므로 새로운 도자기 디자인을 창출하면서 아름답고 우아한 기능성도자기를 제공할 수 있는 효과가 있다.The present invention has the effect of providing a beautiful and elegant functional ceramics while creating a new ceramic design because it is made of metal latex not found in the existing ceramic latex and applied to living ceramics or building materials.

Claims (1)

금속분말인 알미늄 분말 동(同)분 금, 은 분말을 각각 현재 생활도자기에 (백자)유액으로 널리 사용하고 있는 장석, 활석, 백토, 점토, 탄산바륨, 아연 등을 금속 실시예1의 비율로 합성하여 실시예2 방법으로 금속유액을 만들어 도자기 또는 건축자재 등으로 사용하는 방법Aluminum powder, copper powder, and silver powder, which are metal powders, are feldspar, talc, clay, clay, barium carbonate, zinc, and the like, which are currently widely used as (white porcelain) emulsions in household ceramics, in the proportion of metal Example 1. Synthesis by using the method of Example 2 to create a metal latex to use as a ceramic or building materials
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KR100609990B1 (en) * 2004-12-09 2006-08-08 제일모직주식회사 Composition for Artificial Marble Having Metal Gloss
CN100410197C (en) * 2007-02-02 2008-08-13 南安协进建材有限公司 Method for producing metal enamel
KR101111641B1 (en) * 2009-05-15 2012-02-14 (주)이앤씨 Carrier unit for anaerobic reservoir, carrier for anaerobic reservoir and the method thereof
CN111908792A (en) * 2020-08-17 2020-11-10 深圳市国瓷永丰源瓷业有限公司 Glaze mixture of metal glaze, metal glaze product and preparation process of metal glaze product

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KR890003650A (en) * 1987-08-10 1989-04-17 이나 데루조 Tile glaze, tile glaze method and tile manufacturing method
KR900001543A (en) * 1988-07-22 1990-02-27 가와까미 다께시로 Sheet slide device
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