KR20030021100A - Poster remover of liquid polymer composition - Google Patents

Poster remover of liquid polymer composition Download PDF

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Publication number
KR20030021100A
KR20030021100A KR1020010054602A KR20010054602A KR20030021100A KR 20030021100 A KR20030021100 A KR 20030021100A KR 1020010054602 A KR1020010054602 A KR 1020010054602A KR 20010054602 A KR20010054602 A KR 20010054602A KR 20030021100 A KR20030021100 A KR 20030021100A
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weight
polymer composition
cellulose
paper
liquid
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KR1020010054602A
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Korean (ko)
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김기현
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김기현
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F19/00—Advertising or display means not otherwise provided for
    • G09F19/22—Advertising or display means on roads, walls or similar surfaces, e.g. illuminated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide

Abstract

PURPOSE: A liquid synthetic polymer composition for removing a bill or a poster and its preparation method are provided, to reduce the removing time and effect by improving the paper degrading and dissociating performance. CONSTITUTION: The liquid synthetic polymer composition comprises an alkali base; an ether-based polyoxyethylene penetrating agent; an alcohol; a cellulose degrading agent; an organic material; a nonionic surfactant; and purified water. Preferably the liquid synthetic polymer composition comprises 5-10 wt% of an alkali base; 0.5-5 wt% of an ether-based polyoxyethylene penetrating agent; 2-3 wt% of an alcohol; and 5-10 wt% of a cellulose degrading agent. Preferably the content of the nonionic surfactant is 0.01-2 wt%, and the nonionic surfactant is selected from lauryl, amide or sulfate-based surfactants.

Description

벽보, 포스터 제거에 우수한 액상의 합성 polymer 조성물{Poster remover of liquid polymer composition}[Poster remover of liquid polymer composition}

본 발명은 벽보, 포스터 제거에 우수한 액상의 합성 polymer 조성물에 관한 것으로, 더욱 상세하게는 현재 벽보에 사용되고 있는 종이의 재질은 그 표면이 눈, 비에 맞더라도 젖지 않도록 그 표면에 그라우팅 공법등 특수 코팅, 더블 코팅된 polymer type의 film을 사용합니다.The present invention relates to a liquid synthetic polymer composition that is excellent for removing posters and posters, and more particularly, the material of paper used in wall coverings is a special coating such as a grouting method on the surface of the paper so that the surface does not get wet even if it is hit by snow or rain. Use double coated polymer type film.

그로 인하여 기존의 작업방식인 물을 사용하여 제거할 경우 종이의 표면에 물이 침투하기 어렵고 그 표면에 wetting 되기 어려운 문제가 발생하여 벽보, 포스터 제거에 많은 시간 (벽보 1장 제거에 평균 15분이상 소요)과 노동력에 막대한 손실을 가져왔습니다. 여러 종류의 벽보, 포스터에 범용성을 가진 종이에 대한 강한 침투력을 가진 계면활성제 및 cellulose 분해제, wetting agent 등의 상호 보완 작용으로 종이의 조직 표면을 쉽게 분해, 해리시키는 원리로 벽보, 포스터 제거에 걸리는 시간을 현저히 줄일 수 있는 액상의 벽보, 포스터 제거용 액상 polymer 조성물입니다.As a result, when water is removed using the conventional working method, water penetrates into the surface of paper and it is difficult to get wet on the surface. Therefore, it takes a lot of time to remove the posters and posters. And huge labor losses. It is a principle that easily dissolves and dissociates the surface of paper tissues by removing the posters and posters by complementary action of various kinds of wall papers, surfactants, cellulose disintegrators, wetting agents, etc. Liquid polymer composition for removing wall paper and posters that can significantly reduce time.

이 분야의 종래 기술은 대한민국 특허 출원 2000-017464호에서는 버려지는폐식용유나 식물성 유액체를 이용하여 벽보나 포스터가 잘 붙지 않도록 하는 부착의 방지 개념으로 이미 붙어있는 불법 벽보나 포스터에는 실용적이지 못합니다. 대한민국 특허 제 1997-053920호에서는 유효기간이 지난 벽보나 불법 부착 벽보를 제거하는 기구로 액체 분무 탱크와 노즐을 연결하여 가압된 물을 분사하여 제거하는 방식이나 이는 물을 종이 표면에 묻혀서 제거하는 방법보다는 가압된 물을 사용하는 진보된 방법이지만 벽보나 포스터에 사용되는 특수 코팅, 더블 코팅된 종이 표면에는 침투가 용이하지 않아 벽보, 포스터 제거에 효율이 떨어지는 단점이 있습니다. 또한 일본 특허 1998-219038호에서는 불법 벽보에 대응책으로 공중전화 Box나 유리면에 불소 수지를 발라줌으로써 잘 붙지 않게 하는 이 방법도 예방 차원의 특허입니다.The prior art in this field is not practical for illegal wall papers or posters, which are prevented from sticking to walls or posters by using waste cooking oil or vegetable fluid, which is discarded in Korean Patent Application No. 2000-017464. Korean Patent No. 1997-053920 is a mechanism for removing expired wall beams or illegally attached wall beams by connecting a liquid spray tank and a nozzle to spray pressurized water to remove them. It is an advanced method of using pressurized water, but it is not easy to penetrate into the surface of special coated or double coated paper used for wall paper or poster. In addition, Japanese Patent No. 1998-219038 is a preventive patent that prevents sticking by applying fluorine resin to public telephone boxes or glass as a countermeasure against illegal wall coverings.

이에 본 발명에서는 상기와 같은 종래 기술의 문제점을 해결하기 위하여 여러 가지 방법을 연구하였고, 그 결과 기존의 물만을 사용하는 방식과는 비교가 되지 않는 우수한 표면장력을 부여함으로써, 보다 더 많은 양의 물이 빠르고 쉽게 종이에 습윤되도록 하여 종이 조직 표면을 쉽게 분해, 해리시키는 액상의 polymer 조성물인 본 발명을 완성하였다.Therefore, in the present invention, various methods have been studied to solve the problems of the prior art, and as a result, by providing excellent surface tension that is not comparable to the conventional method using only water, a greater amount of water The present invention is a liquid polymer composition which is easily and quickly dissolves and dissociates paper tissue surface by allowing the paper to wet the paper quickly and easily.

본 발명의 목적은 우리의 일상에서 흔히 보게되는 벽면이나 전신주 등에 무질서하게 붙어있는 불법 벽보, 포스터를 쉽게 제거하여 아름다운 도시 미관 조성에 기여되는 벽보, 포스터를 제거하는 액상의 polymer 조성물을 제조함으로써 벽보, 포스터 부착물의 제거에 상당한 유용성을 줄수 있다.An object of the present invention is to remove the illegal wall, irregularly attached to the wall or telephone poles commonly seen in our daily life, posters by making a liquid polymer composition to remove the poster, contributing to the beautiful urban aesthetic composition by removing the poster, It can be very useful for removing poster attachments.

실시예 1Example 1

상온에서 수산화칼륨 1% 중량부, 수산화마그네슘, 수산화나트륨 혼합물 3% 중량부 (알칼리 성분 1∼20% 중량부) 와 폴리 ether 계열 침투제인 폴리옥시 에틸렌 0.1∼1.0% 중량부, 염기 계열의 cellulose 분해성분 물질 1∼5% 중량부, 유기계 물질 1∼5% 중량부, 알코올 2∼3% 중량부, 비이온 계면활성제 0.01∼2% 중량부 그리고 혼합물 100% 중 나머지 중량부에 대하여 정제된 물을 혼합하여 600 RPM으로 15분간 혼합 제조하였다. 제조된 알칼리 base의 벽보, 포스터 제거용 액상의 합성 polymer 조성물을 사용하여 현재 벽보, 포스터에 가장 많이 사용되고 있는 10여종의 코팅된 벽보지를 구하여 sample test를 실시하였다.At room temperature, 1% by weight of potassium hydroxide, magnesium hydroxide, 3% by weight of sodium hydroxide mixture (1-20% by weight of alkali component) and 0.1-1.0% by weight of polyoxyethylene, a polyether penetrant, and decomposition of base cellulose 1 to 5% by weight of the component material, 1 to 5% by weight of organic material, 2 to 3% by weight of alcohol, 0.01 to 2% by weight of nonionic surfactant, and 100 parts of the mixture of purified water Mixing was prepared for 15 minutes at 600 RPM. Using the prepared alkaline base wall poster, liquid synthetic polymer composition for removing posters, a sample test was performed to obtain about 10 types of coated wall papers that are currently used for wall posters and posters.

실시예 2Example 2

상온에서 수산화칼륨 5% 중량부, 수산화마그네슘, 수산화나트륨 혼합물 10% 중량부 (알칼리 성분 1∼20% 중량부)와 폴리 ether 계열 침투제인 폴리옥시 에틸렌 0.1∼1.0% 중량부, 염기 계열의 cellulose 분해성분 물질 1∼5% 중량부, 유기계 물질 1∼5% 중량부, 알코올 2∼3% 중량부, 비이온 계면활성제 0.01∼2% 중량부 그리고 혼합물 100% 중 나머지 중량부에 대하여 정제된 물을 혼합하여 600 RPM으로 15분간 혼합 제조하였다. 제조된 알칼리 base의 벽보, 포스터 제거용 액상의 합성 polymer 조성물을 사용하여 현재 벽보, 포스터에 가장 많이 사용되고 있는 10여종의 코팅된 벽보지를 구하여 sample test를 실시하였다.5% by weight of potassium hydroxide, magnesium hydroxide, 10% by weight of sodium hydroxide mixture (1-20% by weight of alkali component) and 0.1-1.0% by weight of polyoxyethylene, a polyether penetrant, cellulose decomposition of base 1 to 5% by weight of the component material, 1 to 5% by weight of organic material, 2 to 3% by weight of alcohol, 0.01 to 2% by weight of nonionic surfactant, and 100 parts of the mixture of purified water Mixing was prepared for 15 minutes at 600 RPM. Using the prepared alkaline base wall poster, liquid synthetic polymer composition for removing posters, a sample test was performed to obtain about 10 types of coated wall papers that are currently used for wall posters and posters.

실시예 3Example 3

상온에서 수산화칼륨 1% 중량부, 수산화마그네슘, 수산화나트륨 혼합물 3%중량부(알칼리 성분 1∼20% 중량부)와 폴리 ether 계열 침투제인 폴리옥시 에틸렌 0.5∼5% 중량부, 염기 계열의 cellulose 분해성분 물질 1∼5% 중량부, 유기계 물질 1∼5% 중량부, 알코올 2∼3% 중량부, 비이온 계면활성제 0.01∼2% 중량부 그리고 혼합물 100% 중 나머지 중량부에 대하여 정제된 물을 혼합하여 600 RPM으로 15분간 혼합 제조하였다. 제조된 알칼리 base의 벽보, 포스터 제거용 액상의 합성 polymer 조성물을 사용하여 현재 벽보, 포스터에 가장 많이 사용되고 있는 10여종의 코팅된 벽보지를 구하여 sample test를 실시하였다.At room temperature, 1% by weight of potassium hydroxide, magnesium hydroxide, 3% by weight of sodium hydroxide mixture (1-20% by weight of alkali component) and 0.5-5% by weight of polyoxyethylene, a polyether penetrant, and decomposition of base cellulose 1 to 5% by weight of the component material, 1 to 5% by weight of organic material, 2 to 3% by weight of alcohol, 0.01 to 2% by weight of nonionic surfactant, and 100 parts of the mixture of purified water Mixing was prepared for 15 minutes at 600 RPM. Using the prepared alkaline base wall poster, liquid synthetic polymer composition for removing posters, a sample test was performed to obtain about 10 types of coated wall papers that are currently used for wall posters and posters.

실시예 4Example 4

상온에서 수산화칼륨 5% 중량부, 수산화마그네슘, 수산화나트륨 혼합물 10% 중량부 (알칼리 성분 1∼20% 중량부) 와 폴리 ether 계열 침투제인 폴리옥시 에틸렌 0.5∼5% 중량부, 염기 계열의 cellulose 분해성분 물질 1∼5% 중량부, 유기계 물질 1∼5% 중량부, 알코올 2∼3% 중량부, 비이온 계면활성제 0.01∼2% 중량부 그리고 혼합물 100% 중 나머지 중량부에 대하여 정제된 물을 혼합하여 600 RPM으로 15분간 혼합 제조하였다. 제조된 알칼리 base의 벽보, 포스터 제거용 액상의 합성 polymer 조성물을 사용하여 현재 벽보, 포스터에 가장 많이 사용되고 있는 10여종의 코팅된 벽보지를 구하여 sample test를 실시하였다.5% by weight of potassium hydroxide, magnesium hydroxide, 10% by weight of sodium hydroxide mixture (1-20% by weight of alkali component) and 0.5-5% by weight of polyoxyethylene, a polyether penetrant, and decomposition of cellulose of base 1 to 5% by weight of the component material, 1 to 5% by weight of organic material, 2 to 3% by weight of alcohol, 0.01 to 2% by weight of nonionic surfactant, and 100 parts of the mixture of purified water Mixing was prepared for 15 minutes at 600 RPM. Using the prepared alkaline base wall poster, liquid synthetic polymer composition for removing posters, a sample test was performed to obtain about 10 types of coated wall papers that are currently used for wall posters and posters.

실시예 5Example 5

상온에서 수산화칼륨 1% 중량부, 수산화마그네슘, 수산화나트륨 혼합물 3% 중량부 (알칼리 성분 1∼20% 중량부) 와 폴리 ether 계열 침투제인 폴리옥시 에틸렌 0.1∼1.0% 중량부, 염기 계열의 cellulose 분해성분 물질 5∼10% 중량부, 유기계 물질 1∼5% 중량부, 알코올 2∼3% 중량부, 비이온 계면활성제 0.01∼2% 중량부 그리고 혼합물 100% 중 나머지 중량부에 대하여 정제된 물을 혼합하여 600 RPM 으로 15분간 혼합 제조하였다. 제조된 알칼리 base의 벽보, 포스터 제거용 액상의 합성 polymer 조성물을 사용하여 현재 벽보, 포스터에 가장 많이 사용되고 있는 10여종의 코팅된 벽보지를 구하여 sample test를 실시하였다.At room temperature, 1% by weight of potassium hydroxide, magnesium hydroxide, 3% by weight of sodium hydroxide mixture (1-20% by weight of alkali component) and 0.1-1.0% by weight of polyoxyethylene, a polyether penetrant, and decomposition of base cellulose 5 to 10% by weight of the component material, 1 to 5% by weight of organic substance, 2 to 3% by weight of alcohol, 0.01 to 2% by weight of nonionic surfactant, and 100 parts of the mixture of purified water Mixing was prepared for 15 minutes at 600 RPM. Using the prepared alkaline base wall poster, liquid synthetic polymer composition for removing posters, a sample test was performed to obtain about 10 types of coated wall papers that are currently used for wall posters and posters.

실시예 6Example 6

상온에서 수산화칼륨 5% 중량부, 수산화마그네슘, 수산화나트륨 혼합물 10% 중량부 (알칼리 성분 1∼20% 중량부) 와 폴리 ether 계열 침투제인 폴리옥시 에틸렌 0.5∼5% 중량부, 염기 계열의 cellulose 분해성분 물질 5∼10% 중량부, 유기계 물질 1∼5% 중량부, 알코올 2∼3% 중량부, 비이온 계면활성제 0.01∼2% 중량부 그리고 혼합물 100% 중 나머지 중량부에 대하여 정제된 물을 혼합하여 600 RPM 으로 15분간 혼합 제조하였다. 제조된 알칼리 base의 벽보, 포스터 제거용 액상의 합성 polymer 조성물을 사용하여 현재 벽보, 포스터에 가장 많이 사용되고 있는 10여종의 코팅된 벽보지를 구하여 sample test를 실시하였다.5% by weight of potassium hydroxide, magnesium hydroxide, 10% by weight of sodium hydroxide mixture (1-20% by weight of alkali component) and 0.5-5% by weight of polyoxyethylene, a polyether penetrant, and decomposition of cellulose of base 5 to 10% by weight of the component material, 1 to 5% by weight of organic substance, 2 to 3% by weight of alcohol, 0.01 to 2% by weight of nonionic surfactant, and 100 parts of the mixture of purified water Mixing was prepared for 15 minutes at 600 RPM. Using the prepared alkaline base wall poster, liquid synthetic polymer composition for removing posters, a sample test was performed to obtain about 10 types of coated wall papers that are currently used for wall posters and posters.

비교예 1Comparative Example 1

일반물과 합성 조성물을 각각 0.5㎖ 씩 취하여 1차 코팅된 전단지와 2차 코팅된 전단지 (가로×세로 = 5.0cm×5.0cm) 에 점적을 하여 습윤과 침투되는 정도를 시간별로 비교한 것이다.0.5 ml each of the general and synthetic compositions were taken and the first coated leaflets and the second coated leaflets (width × length = 5.0cm × 5.0cm) were compared to the degree of wetting and penetration per hour.

각각의 1차 코팅된 전단지를 비교한 것인데 표 1 를 보면 알 수 있듯이 1차 코팅된 전단지에서는 일반 물의 경우 3분이 지나서야 50% 정도의 흡수율을 보이기시작하지만 합성 조성물의 경우는 1.0분 정도만에 92% 의 흡수율을 보이고 있다.Each primary coated leaflet is compared. As can be seen in Table 1, the primary coated leaflet starts to show absorption of 50% after 3 minutes in general water, but in the synthetic composition, it is 92% in 1.0 minute. The absorption rate is shown.

2차코팅된 전단지의 경우에는 일반물의 경우 5분 이상 경과해도 침투, 흡수되지 못하고 15분이 지나서야 25% 정도의 흡수율 만을 보이고 있어 침투효과가 극히 미약하다고 할 수 있다. 합성 조성물의 경우에는 1분 정도 지나면 30% 정도의 흡수율을 보이기 시작하다가 2분이 경과하면 70% 이상의 흡수율을 나타내고 있어 침투와 흡수력이 뛰어남을 볼 수 있다.In the case of secondary coated leaflets, the penetration of ordinary products is not penetrated and absorbed even after 5 minutes, but only 15% of absorption rate is passed after 15 minutes, so the penetration effect is extremely weak. In the case of the synthetic composition, after about one minute, the absorption rate began to be about 30%, and after 2 minutes, the absorption rate was 70% or more, indicating excellent penetration and absorption.

[그림 1][Figure 1]

비교예 2Comparative Example 2

비교예 2 의 테스트 항목은 종이 표면에 물을 점적시킨 sample 1과 벽보, 포스터 제거용 액상의 합성 sample 2를 서로 비교 테스트하였다.In the test item of Comparative Example 2, a sample 1 having dripping water on a paper surface was compared with a sample 2 for synthesizing a liquid for removing a poster and a poster.

결과는 다음 표 2에 나타내었다.The results are shown in Table 2 below.

[그림 2][Figure 2]

PH의 변화에 따른 벽보, 포스터 등의 종이 조직의 분해, 해리되는 정도를 각각의 PH별로 나타내었다. 강산의 경우도 조직을 와해시키기에는 한계가 보임을 알 수 있고 PH가 9이상의 알칼리 하에서 조직의 분해와 해리가 급격히 발생함을 보인다. 결과는 그림 2에 나타내었다.The degree of disintegration and dissociation of paper tissues such as wall papers and posters according to the pH change is shown for each PH. In the case of strong acid, it can be seen that there is a limit to disintegrate the tissue, and the decomposition and dissociation of the tissue rapidly occurs when the pH is above 9 alkali. The results are shown in Figure 2.

위의 사진은 종이조직의 합성조성물을 처리전과 처리후를 비교하여 나타낸 사진이다.The above picture is a photograph showing the composite composition of paper tissue before and after treatment.

(SEM : ×10,000)(SEM: × 10,000)

본 발명은 종이에 침투하여 종이의 조직을 분해시키는 침투 분해제 조성물을 중량%별로 첨가하여 혼합물을 만든다. 상온에서 알칼리 물질 5∼10 중량%, 폴리 Ether 계열의 침투제 0.5∼5 중량%, 알코올 2∼3 중량%, 염기 계열의 cellulose 분해성 물질 5∼10중량%, 유기계물질 1∼5 중량%, 비이온 계면활성제 0.01∼0.5중량% 그리고 혼합물 100%의 중량부에 대하여 정제된 물을 함유하여 종이의 조직에 쉽게 침투, 습윤되어 분해, 해리를 촉진시키는 성능이 우수한 벽보, 포스터 제거에 뛰어난 물성의 액상 합성 polymer 조성물을 그 특징으로 한다.The present invention forms a mixture by adding a permeation degrading agent composition that penetrates the paper and degrades the tissue of the paper by weight. 5 to 10% by weight of alkaline substances, 0.5 to 5% by weight of polyether penetrants, 2 to 3% by weight of alcohols, 5 to 10% by weight of cellulose degradable substances of bases, 1 to 5% by weight of organic substances, nonionic It contains liquid purified from 0.01 to 0.5% by weight of surfactant and 100% by weight of mixture, so that it easily penetrates and wets paper tissues, and has excellent performance to promote decomposition and dissociation. It is characterized by a polymer composition.

이와 같은 본 발명을 자세히 설명하면 다음과 같다.The present invention will be described in detail as follows.

본 발명에 따른 조성물에 함유되는 기본 물질을 산 보다는 알칼리하에서 세정능력이 탁월하다는 관점 아래 알칼리 계열의 나트륨, 칼륨, 마그네슘 등 염기성 물질과 암모니아 등 독성이 강한 물질로 종이를 침지하여 분해되는 시간과 모양을 관찰하였다. 또한 부식성이 강한 황산, 염산, 인산 등 산 계열의 물질로서 희석비에 따른 양을 조절하여 종이를 침지시켜 같은 방법으로 분해되는 시간과 모양을 관찰 시험하였다.The time and shape of the basic material contained in the composition according to the present invention is degraded by immersing the paper into basic substances such as sodium, potassium, magnesium, and alkaline toxic substances, such as ammonia, in view of superior cleaning ability under alkali rather than acid. Was observed. In addition, acid-based substances such as sulfuric acid, hydrochloric acid, and phosphoric acid, which are highly corrosive, were immersed in paper by adjusting the amount according to the dilution ratio to observe the time and shape of decomposition in the same way.

수산화칼륨, 수산화마그네슘, 수산화나트륨 5∼10% 중량부와 염기 계열의 cellulose 분해성물질이 5∼10% 중량부일 때 종이의 분해력이 양호한 편이며 암모니아는 종이의 분해력에 큰 영향력이 없으며 특유의 강한 냄새로 사용의 어려움이 따라 본 발명에서는 첨가하지 않았다. 산 계열의 경우 황산, 염산, 인산, 붕산 등도 희석비가 30∼40% 중량부 일때만 그 효과를 나타내었으나 위험성이 큰 관계로산 계열의 성분은 제품 사용자의 안전을 고려하여 배제하였다.When 5-10% by weight of potassium hydroxide, magnesium hydroxide, and sodium hydroxide and 5-10% by weight of base cellulose decomposable substances are decomposable, the degradability of the paper is good. As it was difficult to use, it was not added in the present invention. In the case of acid series, sulfuric acid, hydrochloric acid, phosphoric acid, and boric acid showed an effect only when the dilution ratio was 30 to 40% by weight. However, due to the high risk, acid-based components were excluded in consideration of the safety of product users.

본 발명의 주된 내용은 침투성 계면활성제와 cellulose 분해제, wetting agent 부분인데 침투제는 폴리옥시 에틸렌 계열의 침투제가 효과적이며 바람직하다. 일반 벽보나 포스터와 같은 종이의 경우 기존의 사용 방법으로는 일반 물만을 사용하여 벽보, 포스터 종이 표면에 습윤되기 어려우며 표면 위를 흘러내려 잘 침투되지 못하는데 비하여 폴리 옥시에틸렌의 경우 0.5∼5% 중량부 범위 내에서 습윤되어 침투하는데 효과적이다. 또한 종이의 주성분인 cellulose의 분해 성분인 cellulose 분해제의 경우 나트륨, 칼륨,마그네슘 계열의 물질이 침투제와 병행되어 침투되면 1∼5분 이내로 분해제의 분해 능력을 발휘하게 되어 종이의 cellulose 조직 자체를 파괴, 와해시켜 종이의 성질을 잃게 된다. 사용 중량 %는 5∼10% 중량부이고 이상을 넘게되면 물속에 녹아 있지 않고 석출되어 그 물성이 저하됨을 초래하게 된다.The main contents of the present invention are permeable surfactants, cellulose decomposers, and wetting agents, which are effective and preferred polyoxyethylene-based penetrants. In case of paper such as general wall paper or poster, it is difficult to wet the surface of wall paper and poster paper using only ordinary water using conventional water, and it does not penetrate well by flowing down on the surface, whereas 0.5 to 5% by weight of polyoxyethylene It is effective to wet and penetrate within the range. In the case of cellulose decomposer, which is a decomposition component of cellulose, which is a major component of paper, when sodium, potassium, and magnesium-based substances penetrate in parallel with the penetrant, they decompose the decomposing agent within 1 to 5 minutes. It destroys and disintegrates and loses the nature of the paper. The use weight% is 5-10% by weight, and if it exceeds, it will not dissolve in water but will precipitate, resulting in deterioration of its physical properties.

알코올의 경우 Isopropylacohol (IPA)과 Ethanol (EtOH) 등을 2∼3% 중량부로 첨가하여 침투제와 분해제의 용해 능력을 높이는데 이용하였다. 5∼10% 중량부 이상을 함유하게 될 경우 휘발 문제가 발생되어 본 발명 조성물을 사용하는데 작업의 어려움을 유발시키므로 바람직하지 못하다. 유기계 물질과 계면활성제의 경우에는 종이 표면에 wetting능력을 높여주기 위해 유기계의 폴리에틸렌 계열과 폴리비닐 알코올 계열을 이용하여 1∼5% 중량부로 첨가하였고 계면활성제는 0.01∼0.5% 중량부를 첨가하여 wetting 능력을 향상시켜 침투제와 분해제의 상호 보완 역할을 돕도록 하였다.In the case of alcohol, Isopropylacohol (IPA) and Ethanol (EtOH) were added in an amount of 2-3% by weight to increase the dissolving ability of the penetrant and the disintegrant. When it contains 5 to 10% by weight or more, volatilization problems occur, which is not preferable because it causes difficulty in using the composition of the present invention. In the case of organic materials and surfactants, wetting was added in an amount of 1 to 5% by weight using organic polyethylene and polyvinyl alcohol, and the surfactant was added in 0.01 to 0.5% by weight to improve the wetting ability on the paper surface. In order to improve the performance of the penetrant and the disintegrator, it is to be complemented.

상기한 이와 같은 각 조성 성분은 리본블렌더 (Ribbon Blender)나 V형 블렌더, 헨셀 믹서 (Henchel Mixer)등을 이용하여 혼합한 후 인터널 믹서 (Internal Mixer), 반바리 믹서 (Banbury Mixer)등으로 혼합하여 본 발명의 목적으로 하는 벽보, 포스터 제거에 우수한 액상의 합성 polymer 조성물을 얻는다.Each of the above composition components is mixed using a ribbon blender, a V-type blender, a Henschel mixer, etc., and then mixed with an internal mixer, a Banbury mixer, or the like. To obtain a liquid synthetic polymer composition excellent in removing the wall and posters aimed at the present invention.

이와 같은 본 발명은 다음 실시예와 비교예에 의거하여 더욱 상세한 설명을 하겠지만 본 발명이 이에 한정되는 것은 아니다.Such the present invention will be described in more detail based on the following examples and comparative examples, but the present invention is not limited thereto.

이상의 결과로부터 알수 있듯이 본 발명에 따라 제조된 액상의 합성 polymer 조성물은 벽보, 포스터 등의 종이 조직 내로 물이 손쉽게 침투하여 cellulose 분해제, wetting agent 등의 효율적인 조화로 특히 wetting력을 높여 기존의 물만을 사용하는 방식과는 비교가 되지 않은 우수한 표면장력을 부여함으로써, 보다 더 많은 양의 물이 빠르고 쉽게 종이에 습윤되어 종이 조직을 쉽게 분해, 해리시키는 액상의 polymer 조성물로서 벽보, 포스터 부착물의 제거에 매우 유용하다.As can be seen from the above results, the liquid synthetic polymer composition prepared according to the present invention easily penetrates water into paper tissues such as wall papers and posters, so that wetting ability is particularly enhanced by efficient coordination of cellulose disintegrator and wetting agent. It is a liquid polymer composition that dissolves and dissociates paper tissues quickly and easily because more water is wetted on paper quickly and easily by giving excellent surface tension that is not comparable to the method used. useful.

Claims (6)

벽보, 포스터 제거제인 효과적인 액상의 합성 polymer 조성물 및 합성방법으로 알칼리 성분과 poly ether 계열의 폴리옥시 에틸렌 침투제, 알코올, cellulose 분해성분 물질, 유기계물질, 비이온 계면활성제 그리고 혼합물 100% 중량부에 대하여 정제된 물을 함유하여 종이 조직에 침투하여 표면을 분해, 해리시키는 성질을 갖는 조성물을 합성한다.Effective liquid synthetic polymer composition and synthesis method that is a wall cloth and poster remover. Purification based on 100% by weight of alkali and poly ether polyoxyethylene penetrant, alcohol, cellulose decomposition substance, organic substance, nonionic surfactant and mixture It contains synthetic water and penetrates into paper tissue to decompose and dissociate the surface. 제 1항에 있어서 알칼리 base 5∼10% 중량부 및 ether 계열의 폴리옥시 에틸렌 침투제 0.5∼5% 중량부와 알코올 2∼3% 중량부, cellulose 분해 성분 물질 5∼10% 중량부를 사용하여 제조된 액상의 혼합 조성물 및 합성방법According to claim 1, which is prepared using 5 to 10% by weight of an alkali base, 0.5 to 5% by weight of an ether-based polyoxyethylene penetrant, 2 to 3% by weight of alcohol, and 5 to 10% by weight of cellulose decomposition component material. Mixed liquid composition and synthesis method 제 1항에 있어서 알칼리 성분과 종이 성분의 침투 분해 성질을 갖는 계면활성제 0.01∼2% 중량부 (Lauryl계, Amide계, Sulfate계의 음이온과 비이온 계열의 계면활성계) 와의 액상의 혼합 조성물 및 합성방법The liquid mixed composition according to claim 1, wherein 0.01 to 2% by weight of a surfactant having a permeation decomposition property of an alkaline component and a paper component (anionic and nonionic surfactants of Lauryl-, Amide- and Sulfate-based) and Synthesis method 제 1항에 있어서 알칼리 성분과 염기 계열의 cellulose 분해성질(질산, 인산의 dilute solution 과 알칼리 또는 sulfate 계로 된 유도체 물질) 을 갖는 액상의 혼합 조성물 및 합성방법The mixed liquid composition and synthesis method according to claim 1, which have an alkaline component and a base cellulose degrading property (a dilute solution of nitric acid and phosphoric acid and an alkali or sulfate-based derivative material). 제 1항에 있어서 수산화칼륨, 수산화마그네슘, 수산화나트륨 성분을 포함하며 침투성 계면활성제, cellulose 분해성질, wetting agent와의 액상 혼합 polymer 조성물 및 합성방법The composition according to claim 1, comprising potassium hydroxide, magnesium hydroxide and sodium hydroxide, and a permeable surfactant, cellulose degradability, a liquid mixed polymer composition with a wetting agent and a synthesis method. 제 1항에 있어서 수산화칼륨, 수산화마그네슘, 수산화나트륨 성분과 염기계열의 cellulose 분해제, 침투성 계면활성제, wetting agent인 유기계 polyethylene 계열의 폴리비닐알코올 계열을 혼합한 액상의 polymer 조성물 및 합성방법A liquid polymer composition and a method for synthesizing a mixture of potassium hydroxide, magnesium hydroxide, sodium hydroxide components and an organic polyethylene-based polyvinyl alcohol series, which is a base cellulose decomposing agent, a permeable surfactant, and a wetting agent.
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JPH01215898A (en) * 1988-02-24 1989-08-29 Kao Corp Detergent composition
US5002686A (en) * 1988-09-01 1991-03-26 Ciba-Geigy Corporation Aqueous, hard water-resistant wetting agent and detergent composition, and the preparation and use thereof in textile pretreatment
JPH0841495A (en) * 1994-08-03 1996-02-13 Kao Corp Bleaching agent composition for hard surface
KR20010049155A (en) * 1997-01-13 2001-06-15 옷산나 오 에이 A combination of a nonionic silicone surfactant and a nonionic surfactant in a solid block detergent

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