KR20030018700A - Sterilizer consisting of the vermiculite coated Ag-ion and using method there of - Google Patents

Sterilizer consisting of the vermiculite coated Ag-ion and using method there of Download PDF

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KR20030018700A
KR20030018700A KR1020010053202A KR20010053202A KR20030018700A KR 20030018700 A KR20030018700 A KR 20030018700A KR 1020010053202 A KR1020010053202 A KR 1020010053202A KR 20010053202 A KR20010053202 A KR 20010053202A KR 20030018700 A KR20030018700 A KR 20030018700A
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vermiculite
silver
carrier
solution
powder
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KR1020010053202A
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Korean (ko)
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김인달
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김인달
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00Medicinal preparations containing inorganic active ingredients
    • A61K33/24Heavy metals; Compounds thereof
    • A61K33/38Silver; Compounds thereof

Abstract

PURPOSE: An anti-microbial agent in which ionic silver is attached to vermiculite and the use thereof are provided, therefore it can be useful for prevention and treatment of diseases in domestic animals or plants. CONSTITUTION: The method for producing the anti-microbial agent in which ionic silver is attached to vermiculite comprises the steps of: pulverizing vermiculite to prepare vermiculite powder; dipping the vermiculite powder in a silver solution; and heating the silver solution to evaporate a liquid portion, wherein the diameter of vermiculite powder is 2mm or less; the silver solution is silver nitrate solution; the heating temperature of the mixed solution is 900deg. C or more; the silver concentration of the silver nitrate solution is 10,000ppm. The anti-microbial agent in which ionic silver is attached to vermiculite is added into a feed for domestic animals.

Description

질석을 담체로 하여 은을 결합한 살균제 및 그 사용방법{Sterilizer consisting of the vermiculite coated Ag-ion and using method there of}Sterilizer consisting of silver vermiculite as a carrier and a method of using the same {Sterilizer consisting of the vermiculite coated Ag-ion and using method there of}

본 발명은 질석을 담체로 하여 은을 결합한 살균제에 관한 것으로, 상세하게는 다공성인 질석에 은 화합물을 이용한 은 이온을 부착하여, 항균금속인 은 이온과 이온교환을 통하여 살균하는 질석을 담체로 하는 살균제 및 그 사용방법에 관한 것이다.The present invention relates to a bactericide in which silver is bonded to a vermiculite as a carrier, and in particular, a vermiculite which is sterilized by ion exchange with silver ions, which is an antibacterial metal, is attached to a porous vermiculite by silver ions. It relates to a fungicide and a method of using the same.

종래에는 육용동물 특히, 닭의 질병을 예방하거나 치료하기 위하여 다량의 항생제를 사용하여 왔다.Conventionally, a large amount of antibiotics have been used to prevent or treat diseases of meat animals, especially chickens.

이러한 항생제는 닭의 체내에 축적되며, 이러한 닭을 시식한 사람도 2차적으로 체내에 항생제가 축적된다.These antibiotics accumulate in the body of chickens, and even those who try these chickens accumulate antibiotics in the body.

이러한 항생제의 인체내 축적은 사람이 질병 등에 의해 항생제를 사용하는 경우에는 항상제의 효용이 무효하게 되며, 항생제의 체내 축적에 의한 부작용이 발생된다.The accumulation of such antibiotics in the human body always invalidates the utility of the antibiotics when a person uses the antibiotic due to a disease or the like, and causes side effects due to the accumulation of antibiotics in the body.

또한, 관상용 화초나 나무에도 균이 서식하고 있으며, 화초나 나무의 보호를 위하여 항생제나 또는 다른 약을 화초나 나무에 뿌려주게 되는데, 이 또한 공기를통하거나 인체에 접촉되어 피부병이나 기타 질병의 원인으로 작용하는 문제가 있었다.In addition, fungi are inhabited in ornamental plants and trees, and antibiotics or other medicines are sprayed on plants or trees to protect plants or trees, which are also caused by air or contact with the human body, causing skin diseases and other diseases. There was a problem acting.

한편, 질석은 운모상의 광물질로서 800℃ 이상으로 가열하면 체적의 변화가 약 10배∼15배로 팽챙되어 많은 기공이 형성되어 흡음성 및 흡수성이 높고, 경량성과 화학적 성분이 중성(PH-8)으로 토양개선을 위한 담체로 많이 사용되고 있다.Vermiculite, on the other hand, is a mica-like mineral, when heated to 800 ° C or more, the volume change swells by about 10 to 15 times, forming many pores, which has high sound absorption and absorption, and light weight and chemical composition of neutral (PH-8) soil. It is widely used as a carrier for improvement.

질석을 담체로 사용시에는 흡수성, 흡음성, 및 다기공성을 이용하여 상기 질석에 다른 원소나 물질을 결합시켜 다른 물질과 접촉시킴으로서 소기의 목적을 달성하게 된다.When vermiculite is used as a carrier, the desired purpose is achieved by combining other elements or substances with the vermiculite by using absorbency, sound absorption, and porosity to make contact with other substances.

본 발명은 이러한 질석의 성질을 이용하여, 질석에 항균금속인 은을 결합시켜 살균제로 이용하는 것이다.The present invention utilizes the properties of vermiculite, and combines silver, which is an antimicrobial metal, with vermiculite to be used as a fungicide.

본 발명이 이루고자 하는 기술적 과제는, 질석을 담체로 하고 이에 은을 결합시켜 살균제로 이용하므로써, 질병의 치료나 예방을 위하여 동물에게 투입하는 경우에 동물의 체내에 축적되지 않아 사람에게도 무해하며, 식물에 투입하는 경우에도 인체에 무해한 살균제 및 그 사용방법을 제공함에 있다.The technical problem to be achieved by the present invention is by using vermiculite as a carrier and combining silver with it as a fungicide, which is harmless to humans because it does not accumulate in the body of the animal when it is added to the animal for the treatment or prevention of diseases. Even if it is added to the to provide a fungicide harmless to the human body and its use.

전술한 기술적 과제를 달성하기 위하여, 본 발명은 질석을 분해하여 파우더로 형성하고, 분쇄된 질석 파우더를 은이 용해된 용해액으로 침윤하여 고온에서 가열하여 용액을 증발시킴으로서 구성된다.In order to achieve the above technical problem, the present invention is configured by decomposing vermiculite into a powder, infiltrating the pulverized vermiculite powder into a solution in which silver is dissolved, and heating it at a high temperature to evaporate the solution.

이하 본 발명을 실시예로서 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail with examples.

[실시예 1]Example 1

질석 1㎏을 분쇄하여 입자크기가 2㎜이하인 질석을 200℃에서 2시간 가열하여 건조하고, 질산은 10g을 증류수 1000㏄에 용해하여 10,000PPM 농도의 질산은 용액을 제조하였다.1 kg of vermiculite was pulverized, and vermiculite having a particle size of 2 mm or less was heated at 200 ° C. for 2 hours, dried, and 10 g of silver nitrate was dissolved in 1000 kPa of distilled water to prepare a silver nitrate solution having a concentration of 10,000 PPM.

건조된 질석 500g에 질산은 용액 100㏄를 첨가하여 질석입자를 균일하게 질산은 용액으로 침윤시킨 후 900℃에서 4시간 가열하여 공냉시켰다.100 g of silver nitrate solution was added to 500 g of dried vermiculite, and the vermiculite particles were uniformly infiltrated with silver nitrate solution and heated at 900 ° C. for 4 hours, followed by air cooling.

여기서, 질산은으로 침윤시킨 질석을 900℃이상으로 가열하는 것은 질산은 용액을 증발시키는 목적과, 질석의 다기공성을 향상시키는 목적외에도 질석의 독성을 예방하는 목적이 있다.Here, the heating of vermiculite infiltrated with silver nitrate to 900 ° C. or more has the purpose of preventing the toxicity of vermiculite in addition to the purpose of evaporating the silver nitrate solution and improving the porosity of vermiculite.

이와 같이 제조된 질석 5g을 살모넬라균이 함유된 배지에 투입한 후 균의 증식정도를 관찰하였다.5g of the vermiculite thus prepared was added to a culture medium containing Salmonella, and the growth of the bacteria was observed.

관찰한 결과, 초기에는 살모넬라균 농도가 3 ×107cfu이있으나, 은 이온이 결합된 질석을 투입하고 3시간이 경과된 후에는 배치의 살모넬라균의 농도는 3 ×103cfu로, 균의 숫자가 현저히 감소함을 알 수 있었다.As a result, the Salmonella concentration was 3 × 10 7 cfu initially, but after 3 hours after the addition of silver ion-bound vermiculite, the concentration of Salmonella was 3 × 10 3 cfu. It can be seen that the number is significantly reduced.

[실시예 2]Example 2

실시예 1과 동일한 방법으로 은 이온이 결합된 질석을 제조하고, 식물뿌리에서 흔히 관찰되는 균을 배양하여 균의 농도가 2 ×106cfu인 배지를 제조하였다.In the same manner as in Example 1 was prepared vermiculite with silver ions, and cultured bacteria commonly observed in plant roots to prepare a medium having a concentration of 2 × 10 6 cfu.

상기 배지에 전술한 은 이온이 결합된 질석과 일반 흙을 1:10으로 혼합한 흙을 5g 투입하고 관찰하였다,5 g of soil mixed with vermiculite and general soil 1:10 of the above-described silver ions was added to the medium, and observed.

관찰한 결과, 5시간이 경과된 후에는 균 농도가 6 ×103cfh로 감소됨을 알 수 있었다.As a result, after 5 hours, the bacterial concentration was reduced to 6 × 10 3 cfh.

전술한 실시결과로부터 은 이온이 결합된 질석이 항균 및 살균 작용을 함을 알 수 있다.From the above-described results, it can be seen that vermiculite having silver ions bonded thereto has an antibacterial and bactericidal action.

즉, 질석은 항균제로서의 기능을 발휘하는 항균금속인 은과 이온교환이 되어 항균력과 살균력을 갖게 되며, 은 이온을 함유한 질석은 토양에 존재하는 수분을 흡수하여 은이온을 서서히 토양중에 배출하여 세균을 제거하게 된다. 또한 질석은 자체에 흡입성이 좋은 다기공으로 형성되어 가스나 악취를 흡입함으로 암모니아와 같은 악취도 제거한다.In other words, vermiculite is ion-exchanged with silver, an antimicrobial metal that functions as an antimicrobial agent, and has antibacterial and bactericidal properties. Vermiculite containing silver ions absorbs moisture present in the soil and gradually releases silver ions into the soil, causing bacteria. Will be removed. In addition, vermiculite is formed by itself as a porous multi-pore to inhale gas or odors to remove odors such as ammonia.

또한, 본 발명의 질석은 성분이 광물질이므로 사료와 혼합하여 가축에 투입시 가축의 체내에 축적되지 않고 살균력을 발휘하므로 가축을 식용으로 하는 사람에게는 영향을 주지 않고 가축의 질병을 예방할 수 있다.In addition, since the vermiculite of the present invention is a mineral component, it does not accumulate in the body of the livestock when mixed with feed and exerts sterilizing power, so that the disease of the livestock can be prevented without affecting the person who eats the livestock.

또한, 본 실시예들에서는 질석과 균주의 접촉을 3∼5시간에 걸쳐 관찰하였으나, 접촉시간이 길어지면 살균력이 증가하게 되고 질석의 다기공성에 의해 살균력이 증가하게 된다.In addition, in the present embodiments, the contact between the vermiculite and the strain was observed over 3 to 5 hours, but the longer the contact time, the sterilization power was increased and the sterilization power was increased due to the vermiculite porosity.

본 발명은 광물성의 질석을 가축이나 식물에 투입하여 질병의 치료나 예방을 함으로써, 가축이나 식물의 질병을 예방할수 있을뿐만 아니라 동물이나 식물의 체내에 항생제가 축적되지 않아 사람에게 무해하게 되는 효과가 있다.In the present invention, by injecting mineral vermiculite into livestock or plants to treat or prevent diseases, not only can the disease of livestock or plants be prevented, but also antibiotics do not accumulate in the body of animals or plants, which is harmless to humans. have.

Claims (8)

질석을 본쇄하여 파우더로 형성하고, 분쇄된 질석 파우더에 은이온을 결합한 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.A bactericide which combines silver with vermiculite as a carrier, characterized in that vermiculite is formed by a powder, and silver ions are bonded to the pulverized vermiculite powder. 제1항에 있어서,The method of claim 1, 질석 파우더와 은이온의 결합은, 파우더를 은이 용해된 용해액에 침윤시킨후 가열하여 용해액을 증발시켜서 되는 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.The combination of vermiculite powder and silver ions is a sterilizing agent in which silver is combined with vermiculite as a carrier, characterized in that the powder is infiltrated into a dissolving solution in which silver is dissolved and then heated to evaporate the dissolving solution. 제1항에 있어서,The method of claim 1, 질석 파우더의 입자는 2㎜이하인 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.Particles of vermiculite powder is less than 2 mm, characterized in that the disinfecting agent is a silver bonded to the vermiculite as a carrier. 제1항에 있어서,The method of claim 1, 은 이온결합에 은 화합물을 사용하는 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.A bactericide which combines silver with vermiculite as a carrier, characterized by using a silver compound for silver ion bonding. 제2항에 있어서,The method of claim 2, 은이 용해된 용해액은 질산은 용액인 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.A dissolving agent in which silver is dissolved is a silver nitrate solution, wherein silver is bonded to the vermiculite as a carrier. 제2항에 있어서,The method of claim 2, 용해액을 증발시키는 온도는 900℃ 이상안 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.A temperature for evaporating the dissolved solution is 900 ℃ or more, characterized in that the disinfectant is a silver combined with a vermiculite carrier. 제2항에 있어서,The method of claim 2, 질산은 용액은 10,000PPM인 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제.The silver nitrate solution is 10,000 PPM, characterized in that the bactericide which combines silver with vermiculite as a carrier. 제1항 내지 제7항 중 어느 한 항의 질석을 담체로 하여 은을 결합한 살균제를 가축의 사료에 혼합하는 것을 특징으로 하는, 질석을 담체로 하여 은을 결합한 살균제의 사용방법.A method of using a fungicide in which silver is combined with a vermiculite as a carrier, characterized in that a fungicide in which silver is bound is mixed with a feed of livestock using the vermiculite of any one of claims 1 to 7 as a carrier.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040007190A (en) * 2002-07-15 2004-01-24 배향수 Antibiotic agent comprising a colloidal silver and breeding method of a poultry using the same
WO2005011400A1 (en) * 2003-08-05 2005-02-10 Thomsen Joern Oddershede Supplement preparation
KR100471612B1 (en) * 2002-08-21 2005-02-21 김인달 The germicide that use carrier that is made from vermiculite

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02306904A (en) * 1989-05-22 1990-12-20 Yoshio Ichikawa Antimicrobial sand
JPH03193707A (en) * 1989-12-25 1991-08-23 Toyo Dorai Le-Bu Kk New antibacterial silicate
JPH07330527A (en) * 1994-06-07 1995-12-19 Matsumoto Yushi Seiyaku Co Ltd Antimicrobial ceramic
KR970019873A (en) * 1995-10-04 1997-05-28 박상민 Livestock feed additive manufacturing method
JPH10167919A (en) * 1996-12-10 1998-06-23 Nippon Mizushiyori Giken:Kk Antimicrobial ceramic powder

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02306904A (en) * 1989-05-22 1990-12-20 Yoshio Ichikawa Antimicrobial sand
JPH03193707A (en) * 1989-12-25 1991-08-23 Toyo Dorai Le-Bu Kk New antibacterial silicate
JPH07330527A (en) * 1994-06-07 1995-12-19 Matsumoto Yushi Seiyaku Co Ltd Antimicrobial ceramic
KR970019873A (en) * 1995-10-04 1997-05-28 박상민 Livestock feed additive manufacturing method
JPH10167919A (en) * 1996-12-10 1998-06-23 Nippon Mizushiyori Giken:Kk Antimicrobial ceramic powder

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040007190A (en) * 2002-07-15 2004-01-24 배향수 Antibiotic agent comprising a colloidal silver and breeding method of a poultry using the same
KR100471612B1 (en) * 2002-08-21 2005-02-21 김인달 The germicide that use carrier that is made from vermiculite
WO2005011400A1 (en) * 2003-08-05 2005-02-10 Thomsen Joern Oddershede Supplement preparation

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