KR20030017797A - Fluoride-releasing filter material for protecting carious teeth and its application - Google Patents

Fluoride-releasing filter material for protecting carious teeth and its application Download PDF

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KR20030017797A
KR20030017797A KR1020010050820A KR20010050820A KR20030017797A KR 20030017797 A KR20030017797 A KR 20030017797A KR 1020010050820 A KR1020010050820 A KR 1020010050820A KR 20010050820 A KR20010050820 A KR 20010050820A KR 20030017797 A KR20030017797 A KR 20030017797A
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South Korea
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water
filter material
fluorine
fluoride
cartridge
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KR1020010050820A
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Korean (ko)
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강경석
김태일
홍다윗
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(주) 시온텍
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2068Other inorganic materials, e.g. ceramics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D35/00Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
    • B01D35/02Filters adapted for location in special places, e.g. pipe-lines, pumps, stop-cocks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2055Carbonaceous material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • C02F1/766Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2201/00Details relating to filtering apparatus
    • B01D2201/29Filter cartridge constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing

Abstract

PURPOSE: A fluorine ion release filter material for preventing tooth decay and a method for applying the same are provided to obtain a drinking water capable of preventing tooth decay by correcting fluorine ion content in drinking water to a level of 0.8 to 1.2 ppm (mg/L) suitable for preventing tooth decay using fluorine releasing mineral. CONSTITUTION: In a method for manufacturing drinking water for preventing tooth decay, a method for manufacturing a fluorine ion release filter material for preventing tooth decay is characterized in that a filter material from which an appropriate amount of fluorine ion is continuously released is manufactured by mixing, milling and washing natural apatite and an aqueous fluorine compound solution, wherein the aqueous fluorine compound solution is sodium fluoride, silicon fluoride, or a composite thereof having a concentration of 5 to 30%, and wherein the filter material is mixed with veinstone, activated carbon for water purification, and ion exchange fiber or resin to manufacture a cartridge for ordinary water purifier and a cartridge for featured water purifier.

Description

치아우식증(충치)예방을 위한 불소이온 용출 필터소재 및 그 응용방법{Fluoride-releasing filter material for protecting carious teeth and its application}Fluoride-releasing filter material for protecting carious teeth and its application for preventing dental caries

현재 수돗물 불소화 사업이 일부 정수장에서 실시되고 있고 이를 전국적으로 확대하고자 하는 가운데 찬반양론이 뜨겁다. 찬성측은 치아우식증 예방을 위해 필요하다는 것이고 반대 측은 치아우식증 예방에 좋다 해도 다른 어떤 불소로 인한 부작용이 있을까 우려를 하고 있다. 그래서 수돗물 전체를 불소화하기보다 필요한 물만 또 필요한 사람에게 필요한 양만큼 불소화된 음용수를 만들 수 있도록 하고 이를 이용하도록 한다면 찬반 양측의 문제를 동시에 해결하는 것이므로 아주 적절하다 여겨진다. 이 발명은 치아우식증을 예방하는 불소이온 보정 음용수를 만드는 방법에 관한 것으로 가정에서 쉽게 사용할 수 있도록 정수기용 카트리지를 만들거나 다른 정수용물질, 활성탄, 이온교환수지등과 함께 사용하여 정수기 기능을 갖춘 것도 제조가 가능하며 가정에서 쉽게 불소 보정 음용수를 얻을 수 있고 이를 마시므로 치아우식증을 예방할 수 있도록 하기 위함이다.The tap water fluoridation project is currently being carried out in some water treatment plants and the nation intends to expand it nationwide. Pros are needed to prevent dental caries, while opposing parties are concerned about what other fluoride side effects may be, even if they are good for preventing dental caries. Therefore, rather than fluoridating the entire tap water, it is considered to be appropriate because it is possible to make only the necessary water and fluorinated drinking water as much as necessary for the person who needs it. The present invention relates to a method of making fluoride ion-corrected drinking water to prevent dental caries, and to produce a water purifier cartridge for easy use at home or to use it with other water purification materials, activated carbon, ion exchange resin, etc. In order to prevent dental caries, it is possible to obtain fluoride-corrected drinking water at home and drink it easily.

본 발명은 치아우식증을 예방하기 위해 불소 이온를 첨가시킨 음용수를 제조하는 방법으로, 불소는 치아에 직접 작용하여 미세하게 생긴 치아우식증을 원상회복시켜 준다, 즉 탈화된 치질을 재 석회화하고 또한 불소이온이 위장에서 흡수되어 혈액을 통해 턱뼈 내에서 치질과 결합하여 치아우식증에 강한 치질을 만들어 준다. 특히 치아우식증 발생에 관여하는 S.mutans 라는 세균의 증식을 억제한다.The present invention is a method for producing drinking water containing fluoride ions to prevent dental caries, fluorine acts directly on the teeth to restore finely formed dental caries, that is, remineralized demineralized hemorrhoids and fluoride ion It is absorbed from the stomach and combined with hemorrhoids in the jawbone through the blood, making hemorrhoids strong against dental caries. In particular, it inhibits the growth of a bacterium called S.mutans, which is involved in the development of dental caries.

국내에서는 현재 몇 지방자치 단체에서 수돗물을 불소화하여 공급하고 있으나 전국적으로 찬반여론이 확대되어 있어 대부분의 지역에서 불소화된 물의 혜택을 받지 못하고 있다. 수돗물의 불소화에 사용되는 화약약품인 불화나트륨(NaF)과 불화규산(H2SiF6) 등은 대부분 독극물로 규정되어 취급이 어려우므로 개인적으로 불소화 물을 얻기는 어려운 실정이다. 개인적으로나 각 가정에서 불소화된 물이나 음료를 공급받는 방법은 아직 없으며, 불소처리 효과를 얻을 수 있는 방법은 치약이나 불소함유 치아세척액 정도로 한정되어 있다.In Korea, some local governments currently supply fluoridated tap water, but there is widespread controversy over the country, and most regions do not benefit from fluoridated water. Sodium fluoride (NaF) and silicate fluoride (H 2 SiF 6 ), which are chemicals used for fluoridation of tap water, are mostly prescribed as poisons and are difficult to handle, making it difficult to obtain fluoride personally. There is no way to receive fluoridated water or beverages, either individually or at home, and the fluoridation effect is limited to toothpaste or fluoride-containing toothpaste.

본 발명에 의한 불소이온 보정 음료수는 치아우식증 예방에 좋은 음용수 기준치 이하의 불소화 음용수를 제조하는 미네랄 제조 방법에 관한 것으로서 이를 이용하여 누구나 손쉽게 불소화 음용수를 제조하여 마시거나 이용할 수 있도록 하는 제품으로서, 먼저 활성화한 인회석과 같이 불소 포함 광석만 단독으로 사용하거나 맥반석과 게르마늄과 같은 광물을 조합하여 사용할 수 있다. 이 경우 불소화는 물론 게르마늄이나 맥반석이 갖는 특성을 부가적으로 첨가시켜 기능화된 물을 제조할 수 있도록 하는 것으로서 제조방법을 보면 먼저 인회석을 처리하여 용출되어 나올수 있는 불소의 농도를 적당히 조절하고, 적당량의 광물을 카트리지에 넣어 정수기 후단 에 설치하여 정수된 후 불소이온 보정 음용수를 얻도록 한 것이다. 활성 인회석만 단독으로 사용하든지 활성탄 이온교환수지등을 함께 사용하여 정수기능을 갖춘 카트리지를 만들어 피쳐형 정수기겸용 카트리지로 사용할 수 있다.The fluoride ion-corrected beverage according to the present invention relates to a mineral manufacturing method for producing fluorinated drinking water below the drinking water standard value which is good for preventing dental caries, by which anyone can easily prepare and drink or use fluorinated drinking water, and activate it first. As with apatite, only fluorine-containing ores can be used alone or in combination with minerals such as ganbanite and germanium. In this case, it is possible to prepare functionalized water by additionally adding the characteristics of germanium or elvan, as well as fluorination. In the manufacturing method, first, the concentration of fluorine that can be eluted by treating apatite is appropriately adjusted. Minerals were placed in the cartridge and installed at the rear of the water purifier to obtain fluorine ion-corrected drinking water after purification. Only active apatite can be used alone or activated carbon ion exchange resin can be used to make a cartridge with water purification function.

광석의 크기는 지름이 0.5∼1.5mm 정도이며 비중은 약 1.3 정도 되며 물에 녹거나 분해되지 않고 단지 불소만 소량씩 용출되어 적정 농도를 유지할 수 있게 하였다.The size of the ore is about 0.5 ~ 1.5mm in diameter and its specific gravity is about 1.3. It is not dissolved or decomposed in water, and only a small amount of fluorine is eluted to maintain an appropriate concentration.

정수기 후단에 연결하여 정수된 물이 이 불소화 카트리지를 통과할 때 카트리지속의 광물에서 불소가 적당량 용출되어 불소화된 음용수를 어느 때든지 필요에 따라 얻을 수 있고 이 음용수를 마시는 것 뿐 만아니라 양치 시, 치아 세척 시, 평상시에 탄산음료를 마신 뒤에 마시거나 가글할 때에도 사용할 수 있다. 특히 어린이들이 여름철 탄산수를 많이 마시게 되므로 치아우식증이 많이 발생하는데 이 불소화 물을 마시게 하거나 가글하게 되면 치아우식증을 사전에 예방할 수 있다.When the purified water is connected to the back of the water purifier and passes through this fluorinated cartridge, an appropriate amount of fluorine is eluted from the mineral in the cartridge so that fluorinated drinking water can be obtained at any time as needed, and not only drinking this drinking water, When washing, you can also drink or goggle after drinking a soda. In particular, children drink a lot of carbonated water in summer, so dental caries occurs a lot, and drinking or gargled water can prevent dental caries in advance.

[도 1] 일반 정수기형 카트리지1 is a general water purifier type cartridge

[도 2] 피쳐 정수기형 카트리지2 is a water purifier cartridge

[발명의 배경][Background of invention]

98년 조사에 따르면 우리나라 국민들의 95% 이상이 치아우식증을 겪고 있으며 특히 어린이에서는 그 수가 급격히 증가하는 상태이다. 이로 인해 치아우식증을 치료하는 비용과 치아우식증으로 인해 빠진 치아를 치료하는 비용으로 보험으로만 한해에도 2조원을 사용하고 있으며, 보험 혜택을 받지 못하는 비용을 포함하면 실로 엄청난 금액이 지출되고 있다. 이러한 치아우식증은 불소를 이용하여 쉽게 예방할 수 있는데, 특히 식수의 불소화로 치아우식증을 40∼60%까지 예방할 수 있다. 외국 사례의 경우 1945년 미국의 그랜드래피드시에서 처음으로 수돗물을 불소화시켜 현재까지 50년간 지속적으로 공급해 왔는데, 주민들의 치아우식증 예방효과가 높고, 인체에 대한 부작용이 거의 없으며 경제성이 있고 실천성이 있다고 판단되어 미국, 호주, 뉴질랜드, 홍콩과 북유럽 여러 지역으로 확대 실시되었다. 무엇보다 불소화된 물을 음용수로 사용하는 것은 불소를 이용한 여러 치아우식증 예방법 중에서도 가장 예방 효과가 높기 때문에, 세계보건기구에서는 수돗물의 불소화를 가장 효과적이고 경제적이며 안전한 치아우식증 예방사업으로 공인하고 적극적으로 장려하고 있다.According to a 1998 survey, more than 95% of Koreans suffer from dental caries, especially in children. Because of this, the cost of treating dental caries and the treatment of missing teeth due to dental caries is being used for 2 trillion won only by insurance. Such dental caries can be easily prevented by using fluorine. In particular, dental caries can be prevented by 40 to 60% by fluoridation of drinking water. In the case of foreign cases, tap water was fluoridated for the first time in the city of Grand Rapids, USA in 1945, and has been continuously supplied for 50 years.It has high effectiveness in preventing dental caries, little side effects on human body, economical and practical. Judging from that, it was extended to the United States, Australia, New Zealand, Hong Kong, and various parts of Northern Europe. Above all, the use of fluoridated water as drinking water is the most preventive among the various methods of preventing dental caries, so the World Health Organization recognizes and actively promotes fluoridation of tap water as the most effective, economical and safe dental caries prevention program. Doing.

우리나라의 경우 1981년에 청주와 진해시를 시범 상수도수 불소화 대상 도시로 정하여, 0.7∼0.8ppm(mg/L)정도의 농도로 불소화를 시작한 결과 불소화 혜택을 입은 아동들은 평균 50∼65%정도의 치아우식증이 예방된 것으로 집계되었고, 음식물 섭취시 가장 많은 일을 하는 앞쪽에 있는 큰 어금니를 뽑는 율도 불소화지역에서 낮게 나타났다. 국내 치과협의회에서도 불소화된 물을 마시는 것을 치아 우식증을 예방할 수 있는 최선의 방법으로 적극 격려 하고 있다. 그러나, 수돗물의 불소화 사업은 지방단체들에 의한 끊임없는 찬반 논쟁으로 대부분의 지역이 불소화된 물의 혜택을 받지 못하고 있는 실정이다. 수돗물의 불소화에 사용되는 화약약품인 불화나트륨(NaF)과 불화규산(H2SiF6) 등은 대부분 독극물로 규정되어 있어 음용수의 불소화를 위해 일반인이 위의 약품들을 다루기는 어려운 문제이다.In Korea, in 1981, Cheongju and Jinhae were designated as target cities for fluoridation of tap water, and when fluoridation began at a concentration of 0.7 to 0.8 ppm (mg / L), children receiving fluoridation benefited an average of 50 to 65% of teeth. Caries was prevented, and the rate of pulling large molars in the front, which do most of the work when eating, was also low in fluoridated areas. Domestic dental councils are also encouraging drinking fluoridated water as the best way to prevent dental caries. However, the fluoridation of tap water has not been benefited from fluoridated water due to the constant debate by local groups. Sodium fluoride (NaF) and silicate fluoride (H 2 SiF 6 ), which are chemicals used for fluoridation of tap water, are mostly prescribed as poisons, making it difficult for the general public to handle the above drugs for fluoridation of drinking water.

본 발명은 인회석과 같은 불소를 함유하고 있는 광물을 불화나트륨과 불화 규산을 이용하여 기능화 시킨 후 정수기 카트리지 형태로 가공하여 일반 정수기의 필터 카트리지 중 마지막 단계에 연결하거나 피쳐형 정수기의 카트리지 내부 성분에 포함시킴으로써, 일반인들이 쉽게 불소화된 음용수를 얻을 수 있도록 개발되었다.The present invention is functionalized by using sodium fluoride and fluoride silicic acid minerals containing fluorine such as apatite and processed into a water purifier cartridge form connected to the last stage of the filter cartridge of the general water purifier or included in the cartridge internal components of the feature type water purifier By making it easy for the public to get fluoridated drinking water.

불소화 구성물을 카트리지에 넣어 물이 통과 될 때 광물에서 불소이온이 용출되어 불소 이온 농도가 적정 권장 농도인 0.8ppm에서 1.2ppm 정도가 되고 1.5ppm이 넘지 않아야 음용수로서 적당하고 치아세척용이나 가글용으로 쉽게 사용할 수 있다.When fluorinated constituents are placed in a cartridge, water flows through the fluoride ions, and the concentration of fluoride ions is 0.8ppm to 1.2ppm, which is the recommended recommended concentration, and should not be more than 1.5ppm, suitable for drinking water and gargle. Easy to use

이러한 적정 농도를 유지하도록 하는 인회석과 같은 불소를 함유하고 있는 광물과 5∼30% 농도의 불화나트륨 또는 불화규산 수용액 혼합물을 Ball Mill 내에넣고 일정한 크기로 분쇄한 후, 분쇄된 혼합물을 정수된 물로 세척하고 오븐 상에서 건조한다. 이는 인회석의 결정 내부의 구성물을 활성화하는 것으로 매우 중요하다.A mixture of fluorine-containing minerals such as apatite and a 5-30% sodium fluoride or silicate fluoride aqueous solution to maintain the proper concentration is put into a ball mill, ground to a constant size, and the crushed mixture is washed with purified water. Dry on oven. This is very important as it activates the components inside the crystal of apatite.

정수기용으로 사용하기 위해서는 카트리지를 통과는 물의 유속이 중요하다.For use in water purifiers, the flow rate of water through the cartridge is important.

표 3의 실험결과는 정수된 물이 불소화 카트리지를 통과하였을 때 물의 불소이온 농도를 측정한 것이다. 표 4은 불소화 카트리지를 통과한 후, 물의 성분 변화를 나타낸다. 실험 결과에서 나타난 것과 같이 불소성분의 증가외에 다른 성분들의 변화에 영향을 미치지 않았음을 알 수 있다. 이와 같이 필터 카트리지를 통과한 물이 적정 불소 농도인 0.8∼1.2ppm을 유지하도록 물을 활성화시키는 것과 순수하게불소 이온성분만 용출시켜 내기는 것이 본 기술의 핵심이다.The experimental results in Table 3 measured the fluorine ion concentration of water when purified water passed through the fluorination cartridge. Table 4 shows the component changes in water after passing through the fluorination cartridge. As shown in the experimental results, it can be seen that it did not affect the change of other components besides the increase of fluorine component. As such, the key is to activate the water so that the water passing through the filter cartridge maintains an appropriate fluorine concentration of 0.8 to 1.2 ppm and elute only fluorine ions.

불소가 치아우식증(충치) 예방에 꼭 필요하다는 것을 알지만 수돗물을 불소화할 때 생길 수 있는 막연한 두려움 문제로 인해 수돗물 불소화가 어려워지고 있다. 상기 우려를 없애는 방법은 필요에 따라 필요한 물만 불소화하여 음용한다면 최선이다. 이러한 문제를 해결할 수 있는 불소이온 보정 카트리지는 일반 정수기에 쉽게 부착하여 사용할 수 있기 때문에 적은 비용으로 쉽게 불소 보정 음용수를 얻을 수 있는 획기적인 발명이다. 특히 치아우식증 예방에 있어 불소화된 물을 음용수로 마시는 것이 50-65%의 예방 효과가 있어 기타 불소 치약 사용, 불소도포(20-30%의 예방효과)에 비해 그 효과가 월등하여 어린이는 물론 대부분의 사람들에게 필요한 것이다. 또한, 치아우식증 치료에 소요되는 연간 76,240억원의 진료 비용(1996년도 기준)을 절반 이하로 감소시킬 수 있다.I know that fluoride is essential for preventing dental caries, but the vague fear that can occur when fluoridating tap water makes it difficult to fluoride tap water. The method of eliminating the above concern is best if the water is fluorinated and only needed for drinking. The fluorine ion correction cartridge that can solve this problem is an innovative invention that can easily obtain fluorine-corrected drinking water at low cost because it can be easily attached to a normal water purifier. In particular, drinking fluorinated water with drinking water has a prophylactic effect of 50-65%, which is superior to other fluoride toothpaste and fluoride application (20-30%). Is necessary for people. In addition, the annual medical expenses (76.24 billion won) for treating dental caries can be reduced to less than half.

Claims (3)

치아우식증 예방용 음용수를 제조하는 방법에 있어서, 천연 인회석과 불소화합물 수용액을 혼합, 분쇄 및 세척 처리하여 적당량의 불소 이온이 연속적으로 용출하는 필터소재 및 이를 이용한 카트리지 제조방법.A method for producing drinking water for preventing dental caries, comprising: mixing, pulverizing, and washing a natural apatite and an aqueous solution of a fluorine compound to continuously dissolve an appropriate amount of fluorine ions and a method of manufacturing a cartridge using the same. 제 1항에 있어서, 불소화합물 수용액은 불화나트륨 또는 불화규산 중에 하나 또는 그 복합물로 수용액 중에 농도가 5-30%인 것을 특징으로 하는 필터소재 제조방법.The method of claim 1, wherein the aqueous solution of the fluorine compound is one or a combination of sodium fluoride and silicate fluoride, the concentration of the filter material in the aqueous solution is 5-30%. 제 1항에 있어서, 필터소재를 다른 맥반석이나 기타 정수용 활성탄, 이온교환섬유(또는 수지) 등을 함께 넣어 만든 일반 정수기용 카트리지 및 피쳐 정수기형 카트리지의 제조방법.The method according to claim 1, wherein the filter material is made of other gantholites, other activated carbon for water purification, ion exchange fibers (or resins), and the like.
KR1020010050820A 2001-08-22 2001-08-22 Fluoride-releasing filter material for protecting carious teeth and its application KR20030017797A (en)

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US4923683A (en) * 1987-06-27 1990-05-08 Kabushiki Kaisha Sangi Compositions for preventing tooth decay
US5204398A (en) * 1992-03-17 1993-04-20 Essential Dental Systems, Inc. Composite dental cement composition containing a lanthanide series compound
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160135578A (en) * 2015-05-18 2016-11-28 주식회사 이노켐텍 Preparation and application methods of Hybrid filter catridge materials for multi-functional water using Natural mineral ion releasing material and extract with protecting carious teeth and cleaning mouth

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