KR20020096214A - Method for preparing photochromic two-way cake - Google Patents
Method for preparing photochromic two-way cake Download PDFInfo
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- KR20020096214A KR20020096214A KR1020010034528A KR20010034528A KR20020096214A KR 20020096214 A KR20020096214 A KR 20020096214A KR 1020010034528 A KR1020010034528 A KR 1020010034528A KR 20010034528 A KR20010034528 A KR 20010034528A KR 20020096214 A KR20020096214 A KR 20020096214A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/438—Thermochromatic; Photochromic; Phototropic
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
Abstract
Description
본 발명은 광호변성 투웨이 케이크의 제조방법에 관한 것으로, 좀 더 구체적으로는 자외선에 변색되며, 자외선 차단 및 기미, 주근깨, 백부 현상을 방지할 수 있는 광발색형(광호변성, photochromic) 투웨이 케이크의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a photochromic two-way cake, and more particularly, a photochromic (photochromic) two-way cake which is discolored by ultraviolet rays and which can prevent ultraviolet rays and prevent blemishes, freckles, and whitening. It relates to a manufacturing method.
메이크업 화장료에 요구되는 기본적 역할로서는 보다 아름답게 보이는 「미적역할」, 심지좋음을 주는 「감각적 역할」, 화장유지·이차부착방지라는 「기능성」등을 들 수가 있다.The basic roles required for makeup cosmetics include the aesthetic role that looks more beautiful, the sensational role that gives a good feeling, and the functionality of makeup maintenance and secondary adhesion prevention.
이 역할 중에서 미적역할을 다하기 위하여서는 일반적으로 운모티탄계 원료를 비롯한 각종 광택안료의 배합에 의해, 안면도포시의 질감을 조정해 왔다. 이들 일반적인 운모티탄계 안료는 화장품 원료기준에도 기재된 것과 같이, 미세한 박편상운모의 표면에 이산화티탄층을 형성시킨 진주광택과 여러 가지의 간섭색을 갖는 것이다. 그 제법으로는 황산티타닐 등과 같은 티탄의 무기염류 수용액을 운모 존재하에서 가수분해하고, 운모 표면에 함수 이산화티탄을 석출한 후에 가열하는 방법이 일반적이다. 이와 같이 생성된 운모티탄계 안료의 간섭색은 운모 표면상의이산화티탄 피복층의 두께에 의하여 다양한색채를 보인다. 그러나, 그 물체색으로는 어느 것도 백색에 가까운 것이었다.In order to play a role in this role, in general, the texture of the facial coating has been adjusted by blending various varnish pigments including mica titanium raw materials. These general mica titanium pigments have pearlescent gloss in which a titanium dioxide layer is formed on the surface of fine flake mica, and various interference colors as described in the cosmetic raw material standard. As the manufacturing method, a method of hydrolyzing an aqueous inorganic salt solution of titanium such as titanium sulfate and the like in the presence of mica, and depositing hydrous titanium dioxide on the surface of the mica is generally heated. The interference color of the mica titanium pigment thus produced shows various colors by the thickness of the titanium dioxide coating layer on the surface of the mica. However, none of the object colors was close to white.
그래서 종래에 있어서도 운모티탄계 안료에 여러 가지의 물체색을 부여하는 방법이 고려되어 왔다. 가장 일반적인 방법으로는, 생성된 운모티탄계 안료의 표면에 산화철, 감청, 산화크롬, 카본블랙, 카민 등의 착색안료를 첨가하는 것을 들 수가 있다. 그러나 이 방법으로는 운모티탄의 투명성을 감소시켜 버린다는 결점이 있었다. 이에 대하여, 운모티탄중의 운모에 각종 금속 또는 금속화합물을 도핑하는 것에 의하여 운모티탄의 투명성을 잃지 않는 착색운모티탄계 안료가 개발되어있다.Therefore, conventionally, the method of giving various object colors to a mica titanium pigment has been considered. The most common method is to add coloring pigments such as iron oxide, blue wire, chromium oxide, carbon black, and carmine to the surface of the resulting mica titanium pigment. However, this method has the disadvantage of reducing the transparency of mica titanium. In contrast, colored mica titanium pigments have been developed that do not lose the transparency of mica titanium by doping various metals or metal compounds to mica in mica titanium.
그런데 최근, 안료에도 각종 기능이 요구되는 것에 의하여, 그 중 한가지로써, 주위의 광 조건의 변화에 따라서 색조 가변화하는 소위 포토크로믹성(또는 포토트로피성)을 갖은 안료가 주목되기 시작하고 있다. 이와 같은 포토크로믹성을 응용한 제품으로는, 조광유리와 가변색 메이크업 화장료 등이 개발되고 있다.By the way, in recent years, the pigment which has what is called photochromic property (or phototropic property) which changes color tone according to the change of the surrounding light conditions is attracting attention because one requires various functions also to a pigment. As products applying such photochromic properties, dimming glass and variable color makeup cosmetics have been developed.
그러나 운모티탄계 안료에 있어서는 단일의 간섭색밖에 얻을 수가 없고, 화운데이션에 배합한 경우 등에 있어서는, 광 강도가 강한 태양광선 하에서는 전체로써 흰빛을 띠게 되고, 한편 광 강도가 낮은 실내에서는 전체로서 노랗고 거무스름해져 버리고 만 것이었다. 이 때문에 광 강도에 따라 자연스러운 연색성(演色性)을 갖는 안료를 개발하는 것이 강하게 희망되어졌다.However, in mica titanium pigments, only a single interference color can be obtained, and when blended with a foundation, it becomes white as a whole under sunlight having a high light intensity, and becomes yellow and blackish as a whole in a low light intensity room. It was only. For this reason, it has been strongly desired to develop pigments having natural color rendering properties in accordance with light intensity.
일본 특개평 9-165532호에서는 운모티탄중의 산화티탄에 포토크로믹성을 부여하면, 운모티탄에 함유되는 산하티탄이 광강도에 따라서 색조를 변화시켜서, 이에 의하여 운모티탄에 생기는 간섭색이 강조되어, 관찰색이 변하는 극히 유용한 진주광택안료로서 기능하고, 빛에 응답하여 관찰색이 변화하는 운모티탄 안료를 개발하였다.In Japanese Patent Laid-Open No. 9-165532, when photochromic properties are given to titanium oxide in mica titanium, the acidic titanium contained in the mica titanium changes color tone according to light intensity, thereby accelerating the interference color generated in mica titanium. A mica titanium pigment has been developed that functions as an extremely useful pearlescent pigment that changes the observation color and changes the observation color in response to light.
아울러, 한국 특허출원 제99-048129호에서는 포토크로믹성 운모티탄을 배합한 메이크업 화장료에 있어서, 배합된 상기 포토크로믹성 운모티탄은 조사된 자외선 강도에 따라서 암색화하는 포토크로믹성을 갖는 산화티탄 또는 산화티탄화합물로 운모표면을 피복하여 이루어지고, 또한 상기 포토크로믹성 운모티탄의 표면 및/또는 내부에 금속 또는 금속화합물이 존재하고, 그 금속 또는 금속화합물의 색이 물체색으로써 관찰되고, 자외선의 조사에 의해 산화티탄 또는 산화티탄화합물로 이루어진 산화티탄층이 암색화하는 것에 의해 포토크로믹성 운모티탄에 발생하는 간섭광을 강조하여, 포토크로믹성 운모티탄의 관찰색을 변화시키는 관찰색 변화형 포토크로믹성 운모티탄이고, 화장료의 색조의 적어도 일부가 상기 관찰색 변화형 포토크로믹성 운모티탄의 관찰색에 의하여 부여되는 광응답성 고연색 메이크업 화장료를 개시하고 있다.In addition, Korean Patent Application No. 99-048129 discloses a makeup cosmetic compounded with photochromic mica, wherein the blended photochromic mica is titanium oxide having photochromic properties which darkens in accordance with the irradiated UV intensity. Made by covering the surface of mica with a titanium oxide compound, and a metal or metal compound is present on the surface and / or inside of the photochromic mica titanium, and the color of the metal or metal compound is observed as the object color, and the irradiation of ultraviolet rays The color change type photochrom which changes the observation color of photochromic mica titanium by emphasizing the interference light which arises in photochromic mica titanium by darkening the titanium oxide layer which consists of a titanium oxide or a titanium oxide compound by It is a mixed mica titanium, and at least one part of the color tone of a cosmetics is said observation color change type photochromic mica A photoresponsive high color rendering makeup cosmetic imparted by the observation color of carbon is disclosed.
그러나, 이러한 화장료는 제조공정이 매우 복잡하고, 경제적으로 불리한 단점이 있었다.However, such cosmetics have a disadvantage in that the manufacturing process is very complicated and economically disadvantageous.
이에 본 발명에서는 포토크로믹 화합물과 펄(은색)을 포함하는 조성물을 별도로 조성하여 혼합한 투웨이 케이크가 자외선에 변색되며, 자외선 차단 및 기미, 주근깨, 백부 현상을 효과적으로 방지할 수 있음을 발견하였고, 본 발명은 이에 기초하여 완성되었다.Therefore, in the present invention, it was found that the two-way cake mixed with a composition containing a photochromic compound and pearl (silver) is discolored by ultraviolet rays, and effectively prevents UV blocking, spots, freckles, and whitening. The present invention has been completed based on this.
따라서, 본 발명의 목적은 얼굴에 자외선을 막아(기미, 주근깨) 하얗게 들떠 보이는 백부현상을 가변학적 색상을 만들어 실내에서는 밝게 보이며 실외에서는 얼굴색이 다른 색상으로 변해 백부현상을 방지할 수 있는 광호변성 투웨이 케이크의 제조방법을 제공하는데 있다. 아울러, 각종 과일향이 나며 흡수력이 뛰어나 염분(땀)을 제거시켜 주어 얼굴에 상쾌함을 줄 수 있는 광호변성 투웨이 케이크의 제조방법을 제공하는데 있다.Therefore, the object of the present invention by blocking the ultraviolet rays (freckle, freckles) on the face to create a variegated color whitish look white in the room to look bright indoors and the color of the face is changed to a different color outdoors to prevent baekbu phenomenon It is to provide a method for producing a cake. In addition, it provides a variety of fruit flavor and excellent absorption ability to remove the salt (sweat) to provide a method of manufacturing a photochromic two-way cake that can give a freshness to the face.
상기 목적을 달성하기 위한 본 발명의 제조방법은 포토크로믹 화합물 12∼20중량부, 펄(은색) 10∼30중량부 및 메틸 하이드로겐 폴리실록산 10∼50중량부로 구성된 제1조성물을 제공하는 단계; 이산화티탄 20∼30중량부, 실리콘 처리 탈크 5∼10중량부, 실리콘 처리 세리사이트 15∼20중량부, 실리콘 마이카 10∼20중량부, 나이론 파우더 5∼15중량부 및 산화철 색소 3.5∼5중량부로 구성된 제2조성물을 제공하는 단계; 유동파라핀 1.5∼3중량부, 라놀린 3∼5중량부, 이소프로필 미리스트에트 0.5∼1중량부 및 향(과일향 색소) 0.1∼0.3중량부로 구성된 제3조성물을 제공하는 단계; 및 상기 제1조성물에 제2조성물을 혼합, 분쇄한 다음, 제3조성물을 분무혼합 후, 실리콘오일 1.0∼2.0중량부를 가열 분무혼합한 후 분쇄시키는 단계를 포함한다.The production method of the present invention for achieving the above object comprises the steps of providing a first composition consisting of 12 to 20 parts by weight of a photochromic compound, 10 to 30 parts by weight of pearl (silver) and 10 to 50 parts by weight of methyl hydrogen polysiloxane; 20 to 30 parts by weight of titanium dioxide, 5 to 10 parts by weight of siliconized talc, 15 to 20 parts by weight of siliconized sericite, 10 to 20 parts by weight of silicon mica, 5 to 15 parts by weight of nylon powder and 3.5 to 5 parts by weight of iron oxide pigment Providing a constructed second composition; Providing a third composition comprising 1.5 to 3 parts by weight of liquid paraffin, 3 to 5 parts by weight of lanolin, 0.5 to 1 part by weight of isopropyl myristate, and 0.1 to 0.3 parts by weight of fragrance (fruit flavored pigment); And mixing and pulverizing the second composition with the first composition, followed by spray mixing the third composition, and then grinding 1.0 to 2.0 parts by weight of silicon oil by heat spray mixing.
이하 본 발명을 좀 더 구체적으로 살펴보면 다음과 같다.Looking at the present invention in more detail as follows.
화학물질 중에는 햇빛이나 자외선을 받으면 발색되었다가 햇빛이나 자외선이차단되면 원래의 무색상태로 되돌아 가는 가역적인 색변화를 일으키는 화합물이 있는데 이러한 화합물을 포토크로믹 화합물(photochromic compound)이라 한다.Among chemicals, there are compounds that cause reversible color change when they are exposed to sunlight or ultraviolet rays and then return to their original colorless state when blocked by sunlight or ultraviolet rays. These compounds are called photochromic compounds.
이러한 포토크로믹 화합물로는 스피로옥사진 유도체를 비롯하여 여러 가지 화합물들이 알려져 있는데 이들은 광발색형 제품으로 이용하기 위해서는 먼저 고분자 재료화하여야 한다. 고분자 재료화하는 방법으로는 포토크로믹 화합물을 모노머에 첨가하여 중합하는 방법, 포토크로믹 화합물을 직접 고분자에 섞어서 용융성형하는 방법 그리고, 포토크로믹 화합물을 고분자로 마이크로 캡슐화하여 포토크로믹 캡슐잉크를 제조하는 방법 등이 있다.As such photochromic compounds, various compounds are known, including spiroxazine derivatives, which must first be polymerized in order to be used as photochromic products. Polymerization methods include adding a photochromic compound to a monomer to polymerize, mixing a photochromic compound directly into a polymer, and forming a melt, and microencapsulating the photochromic compound into a polymer to form a photochromic capsule ink. And the like to prepare a method.
화장료의 색조의 적어도 일부라는 것은 어느 화장료의 색조가 다른 색조를 갖는 수종의 안료에 의하여 구성되고 있을 때에, 그 화장료의 색조를 구성하기 위한 하나의 색요소인 것을 말한다.At least a part of the color tone of the cosmetic means that one color element for constituting the color tone of the cosmetic when the color tone of a cosmetic is composed of several pigments having different color tones.
포토크로믹성 화합물은 주위의 자외선 강도에 따라서 명도 변화를 일으키고, 그에 따라서 펄에 생기는 간섭광을 강조하기 때문에, 명소에서는 간섭광의 색조와 펄의 물체색의 혼합된 색조를 보이고, 암소에서는 주로 물체색의 색조를 보이는 것 같이 포토크로믹성 화합물의 관찰색의 명도와 색상이 동시 변화하는 것이다.The photochromic compound produces a change in brightness depending on the intensity of the surrounding ultraviolet light, thereby accentuating the interference light generated by the pearl, so that the spot shows a mixed color of the interference light color and the pearl's object color, and in the cow, mainly the color of the object color. As shown, the brightness and color of the observed color of the photochromic compound change simultaneously.
본 발명에서는 화장료에 상기 포토크로믹성 안료 및 펄(은색) 안료를 먼저 배합한 다음, 다른 성분들과 혼합했을 때의 자연에서 주위의 빛의 조건에 매치한 연색성을 띠는 화장료로 제조할 수 있다.In the present invention, the photochromic pigment and the pearl (silver) pigment may be first blended with the cosmetic, and then mixed with other components to prepare a cosmetic having a color rendering property that matches the ambient light conditions in nature. .
본 발명의 바람직한 일 실시예에 따르면, 상기 투웨이 케이크는 먼저, 포토크로믹 화합물 12∼20중량부, 펄(은색) 10∼30중량부 및 메틸 하이드로겐 폴리실록산 10∼50중량부로 구성된 제1조성물을 준비한다. 그 다음, 이산화티탄 20∼30중량부, 실리콘 처리 탈크 5∼10중량부, 실리콘 처리 세리사이트 15∼20중량부, 실리콘 마이카 10∼20중량부, 나이론 파우더 5∼15중량부 및 산화철 색소 3.5∼5중량부로 구성된 제2조성물을 준비한다. 부가적으로, 유동파라핀 1.5∼3중량부, 라놀린 3∼5중량부, 이소프로필 미리스트에트 0.5∼1중량부 및 향(과일향 색소) 0.1∼0.3중량부로 구성된 제3조성물을 준비한다. 그 다음, 상기 제1조성물에 제2조성물을 혼합, 분쇄한 다음, 제3조성물을 분무혼합 후, 실리콘오일 1.0∼2.0중량부를 가열 분무혼합한 후 분쇄시켜 제조된다.According to a preferred embodiment of the present invention, the two-way cake is a first composition comprising 12 to 20 parts by weight of a photochromic compound, 10 to 30 parts by weight of pearl (silver) and 10 to 50 parts by weight of methyl hydrogen polysiloxane. Prepare. Next, 20 to 30 parts by weight of titanium dioxide, 5 to 10 parts by weight of siliconized talc, 15 to 20 parts by weight of siliconized sericite, 10 to 20 parts by weight of silicon mica, 5 to 15 parts by weight of nylon powder and 3.5 to iron oxide dyes Prepare a second composition consisting of 5 parts by weight. In addition, a third composition comprising 1.5 to 3 parts by weight of liquid paraffin, 3 to 5 parts by weight of lanolin, 0.5 to 1 part by weight of isopropyl myristate and 0.1 to 0.3 parts by weight of fragrance (fruit flavored pigment) is prepared. Thereafter, the second composition is mixed and pulverized with the first composition, followed by spray mixing of the third composition, and then 1.0 to 2.0 parts by weight of silicone oil is mixed by heating and spraying, followed by pulverization.
본 발명에 따르면, 포토크로믹 화합물은 포토크로믹 마이크로 캡슐 잉크의 형태로 사용하는 것이 바람직하며, 함량은 포토크로믹 화합물은 12∼20중량부이고, 펄(은색)은 10∼30중량부가 바람직하다. 이는 본 발명의 케이크를 얼굴에 화장할 경우, 얼굴에 자외선을 막아(기미, 주근깨) 하얗게 들떠 보이는 백부현상을 가변학적 색상을 만들어 실내에서는 밝게 보이며 실외에서는 얼굴색이 다른 색상으로 변해 백부현상을 방지할 수 있는 최적의 배합조건이다. 또한, 본 발명의 투웨이 케이크는 각종 과일향이 나며 흡수력이 뛰어나 염분(땀)을 제거 시켜주어 얼굴에 상쾌함을 줄 수 있다.According to the present invention, the photochromic compound is preferably used in the form of photochromic microcapsule ink, the content is 12 to 20 parts by weight of the photochromic compound, and 10 to 30 parts by weight of pearl (silver). Do. When the cake of the present invention is applied to the face, it prevents UV rays on the face (blemishes and freckles) to create a whitish white whitish variability color, which makes it look bright indoors and the color of the face is changed to a different color outdoors to prevent whitish phenomenon. Optimum blending conditions. In addition, the two-way cake of the present invention has a variety of fruit flavors and has excellent absorption ability to remove salt (sweat) can give a freshness to the face.
이하 실시예를 통하여 본 발명을 좀 더 구체적으로 살펴보지만, 하기 예에 본 발명의 범주가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following examples, but the scope of the present invention is not limited to the following examples.
실시예Example
포토크로믹 화합물 16중량부, 펄(은색) 20중량부 및 메틸 하이드로겐 폴리실록산 30중량부로 구성된 제1조성물을 준비한다. 이산화티탄 25중량부, 실리콘 처리 탈크 7중량부, 실리콘 처리 세리사이트 15중량부, 실리콘 마이카 15중량부, 나이론 파우더 10중량부 및 산화철 색소 4중량부로 구성된 제2조성물을 준비한다. 유동파라핀 2중량부, 라놀린 4중량부, 이소프로필 미리스트에트 1중량부 및 향(과일향 색소) 0.2중량부로 구성된 제3조성물을 준비한다. 상기 제1조성물에 제2조성물을 혼합, 분쇄한 다음, 제3조성물을 분무혼합 후, 실리콘오일 2중량부를 가열 분무혼합한 후 분쇄시켜 본 발명의 광호변성 투웨이 케이크를 제조하였다.A first composition consisting of 16 parts by weight of a photochromic compound, 20 parts by weight of pearl (silver) and 30 parts by weight of methyl hydrogen polysiloxane is prepared. A second composition consisting of 25 parts by weight of titanium dioxide, 7 parts by weight of siliconized talc, 15 parts by weight of siliconized sericite, 15 parts by weight of silicon mica, 10 parts by weight of nylon powder, and 4 parts by weight of iron oxide dye is prepared. A third composition consisting of 2 parts by weight of liquid paraffin, 4 parts by weight of lanolin, 1 part by weight of isopropyl myristate and 0.2 parts by weight of fragrance (fruit flavored pigment) is prepared. The second composition was mixed and pulverized with the first composition, and the third composition was spray mixed, and then 2 parts by weight of silicone oil was heated and spray mixed and then ground to prepare a photochromic two-way cake of the present invention.
상기 공정을 통하여 제조된 투웨이 케이크를 얼굴에 화장한 결과, 자외선을 막아(기미, 주근깨) 하얗게 들떠 보이는 백부현상을 가변학적 색상을 만들어 실내에서는 밝게 보이며 실외에서는 얼굴색이 다른 색상으로 변해 백부현상을 방지하였다.As a result of applying the two-way cake manufactured through the above process to the face, it prevents ultraviolet rays (blemishes and freckles) to create a whitish white whitish variability color, making it look bright indoors and changing its color to a different color outdoors to prevent whitish phenomenon. It was.
전술한 바와 같이, 본 발명의 투웨이 케이크는 자외선에 변색 자외선 차단 및 기미, 주근깨, 백부 현상을 방지할 수 있다. 본 발명은 얼굴에 자외선을 막아(기미, 주근깨) 하얗게 들떠 보이는 백부현상을 가변학적 색상을 만들어 실내에서는 밝게 보이며 실외에서는 얼굴색이 다른 색상으로 변해 백부현상을 방지할 수 있다. 아울러, 사무실 등 실내에서는 얼굴에 무색투명한 광택만 나게하여 건강미가 있어 보이게 하고, 야외에서 햇빛(자외선)을 받으면 보는 각도에 따라 다양한 색상으로 발색되어 사용자에게 개성미를 부여할 수 있다.As described above, the two-way cake of the present invention can prevent the discoloration of UV rays and spots, freckles, whitening phenomenon. The present invention prevents ultraviolet rays on the face (blemishes, freckles) by making the variegated color of the white whitish phenomenon appear bright in the room and the color of the face in the outdoors changes to a different color. In addition, indoors such as offices can make the face look healthy by giving only a colorless and transparent gloss, and when it is exposed to sunlight (ultraviolet) outdoors, it can be colored in various colors depending on the viewing angle, thereby giving the user a personality.
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| KR101068370B1 (en) * | 2008-11-14 | 2011-09-28 | 한국콜마 주식회사 | Two layer granule pearl powder make-up cosmetic composition and manufacturing method thereof |
| CN108354959A (en) * | 2018-04-28 | 2018-08-03 | 习利辉 | A kind of Chinese medicine composition and preparation method thereof for treating pigmentosa skin disease |
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| EP0998901A1 (en) * | 1998-11-02 | 2000-05-10 | Shiseido Company Limited | Light-responding high color-rendering makeup cosmetic preparation |
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| US5628934A (en) * | 1988-06-01 | 1997-05-13 | Shiseido Co. Ltd. | Photochromic color rendering regulatory composition and cosmetics |
| KR100209815B1 (en) * | 1991-06-10 | 1999-07-15 | 겜마 아키라 | Photochromic ultra-violet ray shield powder method of manufacturing the same and skin external preparation using the same |
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