KR20020083103A - An carbonizing apparatus and carbonizing method of condensed dust using the apparatus - Google Patents

An carbonizing apparatus and carbonizing method of condensed dust using the apparatus Download PDF

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Publication number
KR20020083103A
KR20020083103A KR1020010061997A KR20010061997A KR20020083103A KR 20020083103 A KR20020083103 A KR 20020083103A KR 1020010061997 A KR1020010061997 A KR 1020010061997A KR 20010061997 A KR20010061997 A KR 20010061997A KR 20020083103 A KR20020083103 A KR 20020083103A
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South Korea
Prior art keywords
combustion furnace
carbonization
trough
sludge
carbonizing
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KR1020010061997A
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Korean (ko)
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난바마사히로
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마사나미 뎃코 가부시기가이샤
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Publication of KR20020083103A publication Critical patent/KR20020083103A/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F23G5/0273Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using indirect heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/12Waste feed arrangements using conveyors
    • F23G2205/125Vibrating conveyor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/12Sludge, slurries or mixtures of liquids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/50009Furnace with progressive waste movements in vertical or steeply inclined direction

Abstract

PURPOSE: To provide a carbonizing device and a carbonizing method using the same, by which device, even coagulated sludge containing fire-resistant inorganic materials and water can be carbonized without additional oil or powdered coal. CONSTITUTION: The method for carbonizing the coagulated sludge and the device therefor are characterized in that the coagulated sludge is fed to the higher end of a closed and inclined type trough 2 disposed in a combustion furnace 1 and that the coagulated sludge on the closed and inclined type trough 2 is carbonized in a reducing atmosphere by heating with the combustion furnace 1 while the coagulated sludge is moving downward to an outlet 6 of the carbonized product at the lower end by vibrating the closed and inclined type trough.

Description

탄화장치와 그것을 이용한 응집오니의 탄화방법{AN CARBONIZING APPARATUS AND CARBONIZING METHOD OF CONDENSED DUST USING THE APPARATUS}CARBONIZING APPARATUS AND CARBONIZING METHOD OF CONDENSED DUST USING THE APPARATUS}

본 발명은 연소되기 어려운 무기물이나 수분을 포함하는 응집오니 등의 탄화가 가능한 탄화장치와 그것을 이용한 응집오니의 탄화방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a carbonization apparatus capable of carbonizing an agglomerated sludge containing inorganic matter or moisture that is difficult to burn, and a carbonization method of agglomerated sludge using the same.

제거해야 하는 유기물을 다량으로 포함하는 배수(폐수)정화처리의 한 수단으로서 무기 또는 유기응집제의 첨가에 의한 방법이 있다. 이 응집처리에 의해 응집오니가 탈수덩어리로서 대량으로 발생하고 있다. 응집오니의 대부분은 탄소나 질소로 이루어지는 유기물이지만 철 또는 알루미늄계 등의 무기응집제가 이용된 경우에는 이들의 무기물이 응집오니의 탈수덩어리안에 수% 함유되는 예가 많다. 하수오니의 탈수처리에 있어서는 탈수조제로서 석탄, 철염을 하수오니에 첨가하고, 그 하수오니를 필터 프레스 등의 가압탈수기에 있어서 탈수하고 있다. 이 탈수조제로서 석탄, 철염을 사용할 경우에는 조제첨가에 의해 탈수덩어리량의 발생량이 증가하여 용량을 줄이는 것이 곤란하다. 또 석탄, 철염이 무기제이기 때문에 오니가 갖고 있던 열량이 탈수덩어리에 있어서 반감하게 되어 소각, 용융 등에 있어서 조연재(助燃材)로서 오일을 사용하는 예가 많다.There is a method by addition of an inorganic or organic coagulant as a means of wastewater (wastewater) purification treatment containing a large amount of organic matter to be removed. By this flocculation process, flocculation sludge generate | occur | produces in large quantities as a dehydrated mass. Most of the flocculated sludge is an organic substance composed of carbon or nitrogen, but in the case where an inorganic coagulant such as iron or aluminum is used, many of these inorganic substances are contained in the dehydrated mass of the flocculated sludge. In the dewatering treatment of sewage sludge, coal and iron salts are added to the sewage sludge as a dehydration aid, and the sewage sludge is dewatered in a pressurized dehydrator such as a filter press. When coal and iron salts are used as this dehydration aid, the amount of dehydration mass generated by the addition of preparation increases, making it difficult to reduce the capacity. In addition, since coal and iron salts are made of inorganic materials, the amount of heat that sludge has is reduced by half in dewatering masses, and in many cases, oil is used as a supporting material in incineration and melting.

일본국 특개평 8-119782호에는 저탄화도립도 조정미분탄을 이용하여 얻은 함탄오니응집물과, 저탄화도 조정미분탄을 이용하여 얻은 함탄함유덩어리와, 저탄화도립도 조정미분탄을 이용하여 얻은 함탄가축분농축물과, 다공질의 셀룰로스 내지 그 저탄화물로 이루어지는 섬유질 흡착제 또는 무함탄오니 응집물과 폐유 또는 기름을 함유하고 있는 배수와의 혼합물에 저탄화도립도 조정미분탄 및 발효숙성된 후민산화바크분 및 건류피트모스분을 각각 혼합하고, 이들의 혼합물을 건조 내지 건류한 다음 이 건조 내지 건류물을 입상성형체에 가압성형하여 연료 및 비료로 제품화하는 방법이 제안되고 있다.Japanese Patent Application Laid-Open No. 8-119782 discloses a coal sludge agglomerate obtained using low carbon inverted coarse pulverized coal, a coal containing mass obtained using a low carbon fine coarse pulverized coal, and a carbonaceous livestock concentrate obtained using a low carbon inverted coarse pulverized coal. Low carbonization incorporation finely pulverized coal and fermented aged minced bark flour and dried puff moss powder in a mixture of water and a fibrous adsorbent consisting of porous cellulose or its low carbides or agglomerations without carbon sludge and waste oil or wastewater containing oil. Are mixed, the mixture is dried or dried, and then the dried or dried product is press-molded into a granulated body to produce a fuel and fertilizer.

본 발명자는 상기와 같은 연소되기 어려운 무기물이나 수분을 포함하는 응집오니라도 오일이나 미분탄을 가하지 않고 탄화가 가능한 장치와 그것을 이용한 탄화방법에 대해 검토했다.The present inventors have studied the above-mentioned apparatus capable of carbonization without adding oil or pulverized coal, even if it is a flocculant containing inorganic matter or moisture which is difficult to burn, and a carbonization method using the same.

도 1은 본 발명의 탄화장치의 측면도.1 is a side view of the carbonization device of the present invention.

도 2는 도 1안 A-A 사시단면 확대도.Figure 2 is an enlarged perspective view A-A perspective view in FIG.

※도면의 주요부분에 대한 부호의 설명※※ Explanation of symbols about main part of drawing ※

1: 연소로2: 경사홈통1: combustion furnace 2: inclined gutter

3: 가진(加振)수단4: 원료공급구3: excitation means 4: raw material supply port

5: 호퍼6: 탄화물제품 취출구5: Hopper 6: carbide outlet

7: 냉각쟈켓8: 버너7: Cooling jacket 8: Burner

9: 왕복운동 실린더10: 롤러9: reciprocating cylinder 10: roller

11: 배기구11: air vent

상기 과제를 검토한 결과 연소로내에 배치한 경사홈통과, 이 홈통에 진동을 부여하는 가진수단으로 이루어지는 탄화장치를 발명하는 데 이르렀다. 경사홈통의 양단은 각각 연소로밖에 배치되어 경사홈통의 연소로밖 고위측에 원료공급구, 연소로밖 저위측에 탄화물제품 취출구를 배치한 탄화장치로 한 것이다. 경사홈통을 따르게 하여 냉각쟈켓을 배치함으로써 고열에 의한 변형을 방지하도록 한 것이다.As a result of examining the above problem, it has come to invent a carbonization apparatus comprising an inclined trough disposed in a combustion furnace and an excitation means for imparting vibration to the trough. Both ends of the inclined trough are respectively disposed outside the combustion furnace, and the carbonization device is provided with a raw material supply inlet on the upper side outside the incinerator of the inclined trough and a carbide product outlet on the lower side outside the incinerator. By arranging the cooling jacket along the inclined gutter to prevent deformation due to high heat.

경사홈통은 원료공급구와 탄화물제품 취출구를 제거하여 밀폐상태로 하고 있다. 진동하는 홈통안을 응집오니 등의 원료가 탄화물제품 취출구방향으로 이동하면서 환원(건류)상태에서 탄화처리되는 탄화장치이다.The inclined gutter is sealed by removing the raw material supply port and the carbide product outlet. It is a carbonization device in which a raw material such as agglomerated sludge is moved in the direction of a carbide product outlet in a vibrating trough, and carbonized in a reduced (dry) state.

홈통안의 원료 또는 제품을 이동시키기 위한 가진수단으로서는 경사홈통에 연결한 왕복이동 실린더, 회전하는 원동기에 연결된 클랭크, 캠, 진동식의 바이브레이터 등을 들 수 있다.Examples of the excitation means for moving the raw materials or products in the gutters include a reciprocating cylinder connected to an inclined gutter, a crank connected to a rotating prime mover, a cam, a vibratory vibrator, and the like.

본 발명의 응집오니의 탄화방법은 연소로안에 배치한 밀폐형 경사홈통의 일단 고위측에 응집오니를 공급하고, 밀폐형 경사홈통을 진동시켜 저위의 제품취출구 방향으로 이동시키면서 연소로에 의한 가열에 의해 밀폐경사 홈통안의 응집오니를 환원상태로 탄화시키는 것을 특징으로 한다.In the carbonization method of the flocculation sludge of the present invention, the flocculation sludge is supplied to one upper side of the sealed inclined gutter disposed in the combustion furnace, and the sealed inclined gutter is vibrated to move in the direction of the lower product outlet while being sealed by heating by the combustion furnace. It characterized in that the flocculation sludge in the inclined trough is carbonized in a reduced state.

다음 본 발명을 실시예에 의해 상세하게 설명한다. 도 1은 본 발명의 탄화장치의 측면도, 도 2는 도 1안 A-A 시시단면 확대도이다. 이들의 도면에서 보는 것과 같이 본 발명의 탄화장치는 연소로(1)안에 경사진 홈통(2)이 배치되고, 이 홈통(2)에 진동을 부여하는 가진수단(3)을 배치하고 있다. 경사홈통(2)은 통모양으로 그 양단은 각각 연소로(1)밖에 있다. 경사홈통(2)의 연소로밖 고위측단부(2a)에 원료공급구(4)가 있고, 그 상부에 호퍼(5)가 있다. 연소로(1)의 외부 저위측에는 탄화물제품 취출구(6)를 배치하고 있다. 경사홈통(2)을 따르게 하여 가운데가 빈 관모양의 냉각쟈켓(7)(7)을 배치하고 있다. 쟈켓안을 주로 하여 물의 냉매가 통과하고 경사홈통(2)의 고열에 의한 변형을 방지하고 있다. 연소로(1)에는 아래쪽에 버너(8)가 있어 로내를 가열한다. 이 버너(8)에는 경사홈통(2)에서 탄화시에 발생하는 탄화배기가스도 이끌려 연소처리된다. 따라서 환원분위기에서의 탄화에 따르는 악취나 유해물이 외부로 배출되지 않는다. 연소로(1)의 배기구(11)로부터의 배기는 응집오니 등의 원료의 건조의 열원으로서 사용할 수 있다.Next, the present invention will be described in detail by way of examples. 1 is a side view of a carbonization device of the present invention, Figure 2 is an enlarged cross-sectional view A-A in FIG. As shown in these figures, in the carbonization apparatus of the present invention, an inclined trough 2 is disposed in the combustion furnace 1, and an excitation means 3 for imparting vibration to the trough 2 is disposed. The inclined gutters 2 are tubular and both ends thereof are outside the combustion furnace 1, respectively. There is a raw material supply port 4 at the high end side 2a outside the combustion furnace of the inclined gutter 2, and a hopper 5 at the upper portion thereof. A carbide product outlet 6 is disposed at the outer low side of the combustion furnace 1. The inclined gutters 2 are arranged along the hollow tube cooling jackets 7 and 7. The inside of the jacket is mainly used to prevent the refrigerant from passing through and deforming due to the high heat of the inclined trough (2). The combustion furnace 1 has a burner 8 at the bottom to heat the furnace. The burner 8 is also led to combustion treatment by carbonization exhaust gas generated during carbonization in the inclined trough 2. Therefore, odors or harmful substances resulting from carbonization in the reducing atmosphere are not discharged to the outside. The exhaust from the exhaust port 11 of the combustion furnace 1 can be used as a heat source for drying raw materials such as flocculated sludge.

홈통(2)은 원료공급구(4)와 탄화물제품 취출구(6)를 제거하여 밀폐상태로 하고 있다. 따라서 진동하는 홈통(2)안을 응집오니 등의 원료가 탄화물제품 취출구(6)방향으로 이동하면서 환원(건류)상태에서 탄화처리되는 것이다.The trough 2 is sealed to remove the raw material supply port 4 and the carbide product outlet 6. Therefore, the raw material, such as agglomerated sludge, moves in the vibrating gutter 2 in the direction of the carbide product outlet 6, and is carbonized in a reduced (dry) state.

홈통(2)안의 원료 또는 제품을 이동시키기 위한 가진수단(3)으로서 이 실시예에서는 경사홈통(2)에 왕복이동 실린더(9)를 연결하고 있다. 왕복이동 실린더(9)의 구조는 피스톤의 스트로크범위의 전후에 가압공기의 공급 또는 배기를 위한 변환밸브를 배치한 구조이다. 경사홈통(2)을 왕복이동시킬 수 있으면 다른가진수단을 채용할 수도 있다. 경사홈통(2)에는 왕복이동을 원활하게 하는 롤러(10)(10)를 배치하고 있다.The reciprocating cylinder 9 is connected to the inclined gutter 2 in this embodiment as the excitation means 3 for moving the raw materials or products in the gutter 2. The structure of the reciprocating cylinder 9 is a structure in which a switching valve for supplying or exhausting pressurized air is arranged before and after the stroke range of the piston. Other vibrating means may be employed as long as the inclined gutter 2 can be reciprocated. The inclined trough 2 is provided with rollers 10 and 10 for smooth reciprocating movement.

다음 상기 장치를 이용하여 탄화를 행한 실시예를 도시한다. 연소로(1)안에 배치한 밀폐형 경사홈통(2)의 사이즈를 폭 600mm x 높이 230mm x 길이 5.5mm로 하고, 이 일단 고위측에 호퍼(5)에서 농업집락 폐수응집오니의 탈수덩어리를 378Kg/H로 공급하며, 밀폐형 경사홈통(2)을 진동시켜 저위의 제품취출구방향으로 이동시키면서 연소로에 의한 가열에 의해 밀폐형 경사홈통안의 응집오니를 환원상태로 탄화시켰다. 농업집락폐수 응집오니의 탈수덩어리안의 주성분은 탄소 30%, 질소 5.1%, 인 2.6%, 알루미늄 2.7%, 철 2.1%, 나트륨 1.0%, 탄산칼륨 0.5%이다. 경사 홈통(2)안의 응집오니의 퇴적높이는 30mm이고 로내에서 10분간 체류시켜 환원상태로 탄화시켰다.Next, the embodiment which carbonized using the said apparatus is shown. The size of the sealed inclined gutter (2) disposed in the combustion furnace (1) was 600mm wide x 230mm high x 5.5mm long, and the dewatering lump of agricultural colony wastewater agglutination sludge was removed from the hopper 5 on the upper side. The flocculation sludge in the hermetically sealed inclined trough was carbonized in a reduced state by heating with a combustion furnace while supplying H and vibrating the hermetically inclined trough 2 in the direction of the lower product outlet. The main components of dehydrated lumps in agglomerated sludge of agricultural colonies are 30% carbon, 5.1% nitrogen, 2.6% phosphorus, 2.7% aluminum, 2.1% iron, 1.0% sodium and 0.5% potassium carbonate. The deposition height of the flocculated sludge in the inclined gutter 2 was 30 mm, and carbonized in a reduced state by staying in the furnace for 10 minutes.

상기 탄화에 의해 210Kg/H의 능력에서 제품의 탄화물이 얻어졌다. 경사홈통(2)안에서 탄화에 의해 발생하는 가스는 연소로(1)안에서 재연소되어 탄화를 위한 열원으로서 다시 응집오니의 건조용으로서 이용되므로 버너(8)나 건조기의 연료의 사용량을 수 %정도 삭감할 수 있었다.By carbonization, carbides of the product were obtained at a capacity of 210 Kg / H. The gas generated by carbonization in the inclined trough 2 is re-burned in the combustion furnace 1 and used again for drying the flocculated sludge as a heat source for carbonization, so that the amount of fuel of the burner 8 or the dryer is about several%. Could cut.

본 발명의 탄화장치는 종래 농업집락폐수 응집오니와 같이 무기물, 수분 등을 많이 포함하여 탄화가 곤란한 오니 등을 오일이나 석탄의 보조연료 없이 탄화시킬 수 있게 되었다. 또 탄화에 필요한 가열용 연료의 절감을 가능하게 하였다.덧붙여 악취를 발생시키지 않고 탄화를 가능하게 하였다. 또한 얻어진 제품의 탄화물이 토양개량, 흡착재, 단열재 그 외 각종 재료로서 이용할 수 있는 특징이 있다.The carbonization apparatus of the present invention can carbonize sludge, which is difficult to carbonize, including a large amount of inorganic matter and moisture, such as agglomeration sludge of agricultural colony wastewater, without oil or coal auxiliary fuel. In addition, it was possible to reduce the heating fuel required for carbonization. In addition, carbonization was possible without generating odors. Moreover, the carbide of the obtained product has the characteristics that it can be used as soil improvement, an adsorbent, a heat insulating material, and other various materials.

Claims (6)

연소로내에 배치한 경사홈통과, 이 홈통에 진동을 부여하는 가진수단으로 이루어지는 것을 특징으로 하는 탄화장치.And an inclined trough disposed in the combustion furnace, and an excitation means for applying vibration to the trough. 제 1항에 있어서,The method of claim 1, 경사홈통의 양단이 각각 연소로밖에 배치되고, 경사홈통의 연소로밖 고위측에 원료공급구, 연소로밖 저위측에 탄화물제품 취출구를 배치한 것을 특징으로 하는 탄화장치.Both ends of the inclined trough are respectively disposed outside the combustion furnace, the carbonization device characterized in that the raw material supply port on the upper side outside the combustion furnace of the inclined trough, and the carbide product outlet on the lower side outside the combustion furnace. 제 1항에 있어서,The method of claim 1, 경사홈통을 따르게 하여 냉각 쟈켓을 배치한 것을 특징으로 하는 탄화장치.A carbonization apparatus characterized by arranging a cooling jacket along an inclined gutter. 제 1항 내지 제 3항 중 어느 한 항에 있어서,The method according to any one of claims 1 to 3, 경사홈통이 원료공급구와 탄화물제품 취출구를 제거하여 밀폐상태인 것을 특징으로 하는 탄화장치.Carbonized device characterized in that the inclined gutter is sealed by removing the raw material supply port and the carbide product outlet. 제 1항에 있어서,The method of claim 1, 가진수단이 경사홈통에 연결한 왕복실린더, 크랭크, 캠, 바이브레이터 중 어느 하나 인것을 특징으로 하는 탄화장치.Carbonization device, characterized in that any one of the reciprocating cylinder, crank, cam, vibrator connected to the inclined trough. 연소로내에 배치한 밀폐형 경사홈통의 일단 고위측에 응집오니를 공급하고, 밀페형 경사 홈통를 진동시켜 저위의 제품취출방향으로 이동시키면서 연소로에 의한 가열에 의해 밀폐형 경사홈통안의 응집오니를 환원상태로 탄화시키는 것을 특징으로 하는 응집오니의 탄화방법.Agglomerated sludge is supplied to the upper end of the sealed inclined gutter arranged in the combustion furnace, and the coagulated sludge in the sealed inclined gutter is reduced by heating by the combustion furnace while vibrating the sealed inclined gutter to move to the lower product extraction direction. Carbonization method of agglomerated sludge, characterized in that the carbonization.
KR1020010061997A 2001-04-26 2001-10-09 An carbonizing apparatus and carbonizing method of condensed dust using the apparatus KR20020083103A (en)

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