KR20020070167A - Producting method of give out ultrared rays padding for a necktie - Google Patents

Producting method of give out ultrared rays padding for a necktie Download PDF

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KR20020070167A
KR20020070167A KR1020020028657A KR20020028657A KR20020070167A KR 20020070167 A KR20020070167 A KR 20020070167A KR 1020020028657 A KR1020020028657 A KR 1020020028657A KR 20020028657 A KR20020028657 A KR 20020028657A KR 20020070167 A KR20020070167 A KR 20020070167A
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South Korea
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yarn
ceramic
tie
treated
far infrared
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KR1020020028657A
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Korean (ko)
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KR100456429B1 (en
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문홍희
문성태
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문홍희
문성태
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Priority to KR10-2002-0028657A priority Critical patent/KR100456429B1/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/02Wool
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments
    • D10B2501/045Neckties

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  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

PURPOSE: Provided is a manufacturing method of tie lining radiating far infrared ray which is characterized by maintaining a radiating effect of far infrared ray continuously, not transforming because of adding dimensional stability, being good for the health and giving off a fragrant odor because various perfumes are added. CONSTITUTION: The tie lining is obtained by a process containing the steps of: diluting 15-25wt.% of ceramic radiating far infrared ray into 50deg.C of warm water to make a stock solution for dipping grey yarn; heating the stock solution into 90deg.C; dipping 30's/2 of grey yarn comprised of polyester and wool for 20-50minutes in a ratio of 10:80 - 90:20(wt.%), followed by dewatering and drying; mixed-weaving grey yarn not treated with ceramic as warp and the grey yarn treated with ceramic as weft to manufacture textile; tentering the textile at 180deg.C, and simultaneously surface-treating with 3-5wt.% of a melamine resin solution; passing through a high temperature furnace; and then blowing, followed by leaving on cooling.

Description

원적외선을 발산하는 넥타이 심지의 제조방법{Producting method of give out ultrared rays padding for a necktie}Manufacturing method of give out ultrared rays padding for a necktie}

본 발명은 원적외선을 발산하는 넥타이 심지의 제조방법에 관한 것으로 보다 구체적으로는 오늘날 많은 사람들이 일상생활에서 착용하는 넥타이의 제조시에 사용되는 넥타이 심지에 원적외선 발산물질인 액상의 바이오세라믹을 흡착 가공하여 인체에 유익한 원적외선을 항시 발산시키기 위한 넥타이 심지의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a tie wick that emits far infrared rays, more specifically, by adsorbing and processing a liquid bioceramic, which is a far infrared emitting substance, to a tie wick used in the manufacture of a tie worn by many people today. It relates to a method for producing a tie wick for emanating far-infrared rays, which is beneficial to the human body at all times.

원적외선이 인체에 극히 유익하다는 것은 이미 잘 알려진 사실이며, 또한 바이오 세라믹이 원적외선을 다량으로 방출한다는 것도 잘 알려진 사실로서 이를 인간의 생활에 활용하기 위한 여러 가지 연구활동이 전개되고 있는 것이다.It is well known that far infrared rays are extremely beneficial to the human body, and it is also well known that bioceramic emits large amounts of far infrared rays, and various research activities are being developed to apply them to human life.

종래에도 직물 등에 원적외선 발산물질을 흡착시켜 침구, 의류 또는 여러 가지 가전제품에 이용하기도 하고, 식품용기나 일상 생활용품의 제조에도 이용하여 대중적인 질병예방물질로 이용되고 있었으나, 이들의 제조방법은 직물류나 종이와 같은 지류의 표면에 접착제가 혼입된 원적외선 발산 세라믹 물질을 코팅하는 방법이 있었지만 이는 이형지 등의 보호막이 필요하고, 따라서 그 용도가 스티커 등으로 한정되어 사용되었으며 보호막이 없는 경우 마찰 등에 의하여 세라믹층이 탈리되어 그 수명이 극히 짧아지게 되는 단점이 있었으며, 이를 개량한 것으로는 원적외선 발산 세라믹물질을 액상으로 하여 직물 또는 부직포를 일정시간 침지하여 제조하는 방법이 있었으나, 이 역시 직물 표면에만 세라믹물질이 흡착되어 있으므로 그 수명이 길지 못할 뿐만 아니라 직물 또는 부직포의 원료에 따라 그 흡착 효과가 달라지게 되는 단점이 있었으며, 따라서 전자의 것은 일반적인 라벨로 주로 이용되고 있으며, 후자의 것은 그 용도가 다소 다양하기는 하나 처리된 직물로 의류를 제조하는 경우 그 가격이 고가로 되는 단점이 있을 뿐만 아니라, 특히, 이들은 모두 의류용 또는 가전제품용이기 때문에 그 두께 등이 넥타이 심지로 이용되기에는 부적합하였다.Conventionally, the far-infrared radiating material is adsorbed on fabrics and used in bedding, clothing or various home appliances, and also used in the manufacture of food containers and daily household products, and has been used as a popular disease prevention material. There was a method of coating a far-infrared emitting ceramic material with an adhesive mixed on the surface of a feeder such as paper, but this requires a protective film such as a release paper, and thus its use is limited to stickers. There was a disadvantage in that the lifespan was extremely short due to the detachment of the layer. The improvement was a method of manufacturing by immersing a fabric or a nonwoven fabric for a predetermined time by using a far-infrared emitting ceramic material as a liquid. Its life is not long because it is adsorbed In addition, the adsorption effect is different depending on the raw material of the woven or non-woven fabric, so the former is mainly used as a general label, the latter is used in the manufacture of garments of the treated fabric, although its use is somewhat different In addition to the disadvantage that the price is expensive, in particular, because they are all for clothing or home appliances, the thickness and the like are not suitable to be used as a tie wick.

본 발명의 목적은 상기한 바와 같은 종래 기술의 단점을 보완하고 넥타이 심지용으로 적합한 원적외선 발산 원단을 얻기 위한 것으로, 넥타이 심지용 사(絲)의 제조공정에서 액상의 세라믹물질을 흡착시켜 원적외선을 발산할 수 있도록 하며,특히 인체에 유익한 넥타이 심지를 제공하기 위한 것이다.The object of the present invention is to compensate for the disadvantages of the prior art as described above and to obtain a far-infrared emitting fabric suitable for tie wicks, which emits far infrared rays by adsorbing a liquid ceramic material in the manufacturing process of the tie wick yarns. It is to provide a tie wick, which is particularly beneficial to the human body.

본 발명의 또 다른 목적은 상기의 넥타이 심지의 두께가 균일하고 변형이 일어나지 않으므로 미려한 넥타이를 제공하기 위한 것이다.Still another object of the present invention is to provide a beautiful tie because the thickness of the tie wick is uniform and deformation does not occur.

도 1은 본 발명의 공정을 설명하기 위한 플로우 차트1 is a flow chart for explaining the process of the present invention

도 2는 본 발명품을 한국원적외선응용평가연구원에서 시험한 방사율에 대한 시험 성적서Figure 2 is a test report for the emissivity of the present invention tested in the Korea Far Infrared Application Evaluation Institute

도 3은 본 발명품을 한국원적외선응용평가연구원에서 시험한 방사에너지에 대한 시험성적서이다.3 is a test report on the radiant energy of the present invention tested in the Korea Far Infrared Application Evaluation Institute.

본 발명은 장기간 사용하여도 변형이 안되어 그 형상을 미려하게 유지하면서 원적외선을 발산하여 인체의 건강에 유익한 넥타이를 제공하기 위한 넥타이 심지의 제조방법에 관한 것으로 이를 첨부된 플로우 차트에 의하여 구체적으로 설명하면 다음과 같다.The present invention relates to a manufacturing method of a tie wick for providing a tie beneficial to the health of the human body by emitting far infrared rays while maintaining its beautiful shape without being deformed even after long-term use. As follows.

1) 원액 제조1) Stock Solution

50℃ 내외의 온수에 통상적인 액상의 원적외선 발산 세라믹을 15∼25중량% 함유하도록 원사 침지 원액을 제조한다.Yarn immersion stock solution is manufactured so that 15-25 weight% of normal liquid far-infrared-emitting ceramics may be contained in the hot water of 50 degreeC.

상기 원액에서 액상의 원적외선 발산 세라믹이 15중량% 미만이면 섬유에 흡착되는 세라믹의 양이 적기 때문에 원적외선 발산 효과가 적으며, 25중량%를 초과하면 섬유를 침지시키기가 어려울 뿐만 아니라, 점도가 높아져 세라믹이 균일하게 흡착시키기 어려우며, 과도하게 세라믹이 섬유에 흡착되어도 더 큰 효과를 일으키지도 않으며 제조 원가의 상승만 초래하게 되는 것이다.If the liquid far-infrared light-emitting ceramic in the stock solution is less than 15% by weight, the amount of ceramic adsorbed to the fiber is small, and thus the far-infrared light-emitting effect is less.If it exceeds 25% by weight, the fiber is difficult to be immersed, and the viscosity is high so that the ceramic It is difficult to adsorb this uniformly, and excessive ceramic adsorption to the fiber does not cause a greater effect and only results in an increase in manufacturing cost.

2) 원사의 제조2) manufacture of yarn

심지용 원사는 폴리에스터(PE)와 양모(W)의 혼방사로 하되 그 혼방비율은 10∼80 : 90∼20(중량%), 섬도는 30수/2로 제조한다.The wicking yarn is a blended yarn of polyester (PE) and wool (W) with a blend ratio of 10 to 80:90 to 20 (wt%) and fineness of 30 water / 2.

상기한 PE의 함량이 10중량% 미만, 즉 W의 함량이 90중량%를 초과하는 경우에는 단가만 상승될 뿐, 더 이상의 품질 향상을 기대하기 어려울 뿐만 아니라 제품의 강도가 저하되는 단점이 더 많고, PE의 함량이 80중량% 초과, 즉 W의 함량이 20중량% 미만일 경우에는 제품의 강도는 강해지지만 품질이 조악해질 뿐만 아니라, 최종 제품인 넥타이의 사용도중에 다림질 등의 열에 의하여 변형을 야기할 염려도 있다.When the content of PE is less than 10% by weight, that is, the content of W is more than 90% by weight, only the unit price is increased, it is difficult to expect further quality improvement, and there are more disadvantages that the strength of the product is lowered. When the content of PE is more than 80% by weight, that is, the content of W is less than 20% by weight, the strength of the product becomes stronger, but the quality is poor, and there is a fear of causing deformation by heat such as ironing during the use of the final product, the tie. There is also.

3) 침지3) dipping

상기한 원액을 침지 탱크에 넣고 90℃ 내외로 유지시키면서 상기한 원사를 20∼50분간 침지시켜 원적외선 발산 세라믹을 원사에 흡착시킨다. 흡착시간은 양모의 함량이 증가할수록 짧은 시간에도 가능하며, PE는 흡착성이 낮기 때문에 그 함량이 증가할수록 흡착시간을 늘리는 것이 바람직하다.The stock solution is placed in an immersion tank, and the yarn is immersed for 20 to 50 minutes while maintaining the temperature at about 90 ° C to adsorb the far-infrared emitting ceramic to the yarn. Adsorption time is possible even in a short time as the content of wool increases, PE is preferred to increase the adsorption time as the content increases because the adsorption is low.

세라믹이 흡착된 원사를 통상적인 방법으로 탈수하고 상온에서 건조시켜 제직공정으로 이송한다.The ceramic adsorbed yarn is dehydrated in a conventional manner, dried at room temperature, and transferred to a weaving process.

4) 제직공정4) Weaving Process

원적외선을 발산하는 넥타이 심지를 얻기 위한 제직공정에서 세라믹이 흡착되지 않은 상기한 미처리 원사를 경사로하고, 흡착처리된 원사를 위사로하여 일반적인 교직으로서 넥타이 심지 원단을 제직하여 180℃ 정도의 고온에서 텐터링하면서 3∼5중량%의 멜라민수지 수용액으로 표면처리하여 고온로를 통과시킴으로서 흡착된 세라믹 성분의 탈리를 방지한다.In the weaving process for obtaining a tie wick that emits far infrared rays, the above-mentioned untreated yarn with no ceramic adsorbed is inclined, and as a general teaching, weaving the tie wick fabric as a weaving yarn is tentered at a high temperature of about 180 ° C. While surface treatment with a 3-5% by weight aqueous solution of melamine resin is passed through a high temperature furnace to prevent detachment of the adsorbed ceramic components.

멜라민수지의 함량이 3중량% 미만인 경우에는 그 효과가 급격하게 저하되며, 5중량%를 초과하면 멜라민수지가 과도하게 피복되므로 원적외선 발산효과가저하된다.If the content of the melamine resin is less than 3% by weight, the effect is sharply lowered. If the content of the melamine resin is more than 5% by weight, the far-infrared divergence effect is reduced because the melamine resin is excessively coated.

한편, 본 제직공정에서 경사와 위사를 흡착 처리사와 미처리사로 바꿀수도 있지만 세라믹 흡착 처리사를 경사로 사용하면 제직중 세라믹이 탈리될 염려가 있음으로 바람직하지 않으며, 또한, 위사에 세라믹 흡착 처리한 원사와 미처리 원사를 교호로 사용하여도 가능하며, 이때에는 제조단가가 저렴하다는 장점도 있지만 원적외선 발산 량이 적어질 우려도 있으므로 신중을 기해야 한다.On the other hand, in the weaving process, the warp and weft yarns may be changed to the adsorption treated yarn and the untreated yarn, but it is not preferable to use the ceramic adsorption treated yarn as the warp yarn because the ceramic may be detached during weaving. It is also possible to use untreated yarn alternately. At this time, there is an advantage that the manufacturing cost is low, but there is a fear that the amount of far-infrared radiation is reduced.

또한, 멜라민수지 처리시에 통상적인 캅슐 향료를 혼입하면 원적외선 발산 효과와 함께 은은한 향기를 발하므로 상쾌한 기분을 일으키는 효과도 얻을 수 있다.In addition, in the case of melamine resin treatment, incorporating a conventional capsule fragrance gives off a far-infrared radiating effect and a subtle fragrance, so that a refreshing feeling can be obtained.

5) 마무리공정5) Finishing process

상기한 멜라민수지 처리가 된 넥타이 심지용 원단을 블로잉 기(Blowing machine)에서 압박상태에서 고온의 증기를 이용하여 5∼8분간 증열 처리한 후 약 20분간 방냉 처리하므로서 원하는 넥타이 심지 원단이 완료된다.The melamine resin-treated tie wick fabric is heat-treated for 5 to 8 minutes using a high-temperature steam under pressure in a blowing machine and then cooled for about 20 minutes to complete the desired tie wick fabric.

증열 처리를 하는 것은 원단에 칫수 안정성을 부여하여 제품의 변형을 방지하여 고부가가치의 제품을 얻기 위한 것이며, 그 시간이 5분 미만이면 완전한 칫수 안정성이 발휘되지 않으며, 8분을 초과하면 함유된 폴리에스터 섬유가 고온에 의하여 손상을 입을 염려가 있을 뿐만 아니라, 칫수 안정성의 효과는 더 상승되지 않고 에너지와 물자와 시간만 낭비하게 되기 때문이다.The steaming treatment is to give a dimensional stability to the fabric to prevent the deformation of the product to obtain a high value-added product, if the time is less than 5 minutes, the complete dimensional stability is not exhibited, if the content exceeds 8 minutes Not only can the ester fibers be damaged by high temperatures, but the effectiveness of the dimensional stability is not enhanced and only wastes energy, material and time.

또한, 방냉 처리는 증열 처리시에 스며든 고온의 증기가 발산되어 건조되도록 하기 위한 것이며, 일반적으로 20분 정도이면 증기의 발산이 완료되는 것이다.In addition, the cold-cooling treatment is to allow the high-temperature steam penetrated during the heat treatment treatment to be diverted and dried, and in general, the steam divergence is completed in about 20 minutes.

(실시예)(Example)

50℃의 온수에 액상의 원적외선 발산 세라믹을 희석시켜서 세라믹의 함량이 20중량%가 되도록 원사 침지용 원액을 제조하여 90℃로 승온 하였다. 여기에 폴리에스터와 양모의 혼방 비율이 50 : 50(중량%)이 되도록 하여 30수/2 로 혼방한 혼방사를 30분간 침지한 후 탈수기에서 탈수하여 상온에서 건조시켰다. 건조된 상기 원사를 위사로 하고 세라믹 처리를 하지 않은 상기한 혼방사를 경사로하여 교직으로 제직한 후 텐터기(tenter frame)에서 텐터링(tentering)하면서 180℃의 고온에서 4중량%의 멜라민수지 용액에 일반적인 소나무 향 캡슐을 혼합하여 분무하여 표면처리를 하고 이를 블로잉 기(blowing machine)에서 100℃의 스팀(증기)으로 7분간 블로잉(blowing) 처리하여 상온에서 20분간 방냉(放冷)하여 넥타이용 심지를 제조하였다.After diluting the liquid far-infrared emitting ceramics in hot water at 50 ° C., a raw material for yarn immersion was prepared such that the content of the ceramic was 20% by weight, and the temperature was increased to 90 ° C. Here, the blend ratio of polyester and wool was 50:50 (wt%), and the mixed yarn blended with 30 water / 2 was immersed for 30 minutes, then dehydrated in a dehydrator and dried at room temperature. After weaving the blended yarn with the inclined yarn as a weft yarn and not being treated with ceramics in a warp yarn, and then tentering in a tenter frame, 4 wt% melamine resin solution at a high temperature of 180 ° C General pine flavored capsules are mixed and sprayed for surface treatment and blown with a steaming machine at 100 ° C. for 7 minutes, followed by cooling for 20 minutes at room temperature to wick the tie. Was prepared.

이 넥타이용 심지는 은은한 소나무 향을 발하면서 변형이 일어나지 않을 뿐만 아니라 5∼20㎛의 빛의 파장, 37℃에서의 반사율이 0.904, 즉90.4%이고 3.49×10²(W/㎡·㎛, 37℃)를 나타내어 그 성능이 매우 우수하였다.(한국원적외선응용평가연구원 시험성적서 참조)This tie wick not only deforms while giving a soft pine scent, but also has a light wavelength of 5 to 20 µm and a reflectance at 37 ° C of 0.904, or 90.4%, and 3.49 × 10² (W / m 2 · µm, 37 ° C). ), And its performance was very good. (Refer to the test report of Korea Far Infrared Application Evaluation Institute.)

본 발명은 원사를 원적외선 발산 세라믹 용액에 직접 침지하고 텐터링 공정에서 멜라민 수지 용액으로 표면처리 하였기 때문에 원적외선 발산 효과가 지속적으로 유지되며, 또한 블로잉 처리에 의하여 칫수 안정성을 부여하였기 때문에 변형이 발생하지 않으므로 인체에 유익하면서도 안정된 형태를 유지할 수 있는 고부가가치의 넥타이 심지를 제공하는 매우 유용한 발명인 것이다.In the present invention, since the yarn is directly immersed in the far-infrared emitting ceramic solution and surface treated with the melamine resin solution in the tentering process, the far-infrared radiating effect is continuously maintained, and since the dimension stability is given by the blowing treatment, no deformation occurs. It is a very useful invention that provides a high-value tie wick that can be beneficial to the human body and maintain a stable form.

또한, 멜라민 수지용액에 의한 표면 처리시에 여러 가지 향료를 혼입함으로써 착용자 뿐만 아니라 함께 있는 사람들의 기분도 상쾌하게 하는 부수적인 효과도 있는 것이다.In addition, by incorporating various fragrances during the surface treatment with the melamine resin solution, there is a side effect of refreshing the mood of not only the wearer but also those with them.

Claims (3)

넥타이 심지를 제조함에 있어서, 50℃ 내외의 온수에 통상적인 액상의 원적외선 발산 세라믹을 15∼25중량%함유하도록 원사 침지용 원액을 만들고, 이 원액을 90℃ 내외로 유지하여 폴리에스터와 양모의 비율이 10 : 80∼90 : 20(중량%) 이고 30 /2인 원사를 20∼50분간 침지하여 탈수, 건조시키고 세라믹을 처리하지 않은 미처리 원사를 경사로하고, 세라믹 처리된 상기 원사를 위사로 교직하여 원단을 제직하고, 180℃ 정도의 고온에서 텐터링하면서 3∼5중량%의 멜라민 수지 수용액으로 표면처리하여 고온로를 통과시킨 후 이를 블로잉 처리하여 방냉시킴을 특징으로 하는 원적외선을 발산하는 넥타이 심지의 제조방법.In preparing the tie wick, a raw material for yarn dipping is made to contain 15 to 25% by weight of a conventional liquid far-infrared emitting ceramic in hot water of about 50 ° C, and the ratio of polyester and wool is maintained at about 90 ° C. This 10: 80 to 90: 20 (% by weight) of 30/2 yarn was immersed for 20 to 50 minutes, dehydrated and dried, and the ceramic-treated untreated yarn was inclined, and the ceramic-treated yarn was weaved with a weft yarn. Weaving the fabric, and tentering at a high temperature of about 180 ℃ while surface treatment with an aqueous solution of melamine resin of 3 to 5% by weight, passing through a high temperature furnace and blowing it to cool it by the blowing treatment of the tie wick, characterized in that Manufacturing method. 청구항 1에 있어서, 블로잉 처리는 폴리에스터와 양모의 혼합 비율에 따라 5∼8분간 증열처리한 후 방냉 처리하는 것을 특징으로 하는 원적외선을 발산하는 넥타이 심지의 제조방법.The method of manufacturing a tie wick as claimed in claim 1, wherein the blowing treatment is carried out by heat treatment for 5 to 8 minutes according to the mixing ratio of polyester and wool, followed by cooling. 청구항 1에 있어서, 멜라민 수지 수용액에 자연 향을 발하는 향료를 혼입하여 표면처리 하는 것을 특징으로 하는 원적외선을 발산하는 넥타이 심지의 제조방법.The method for producing a tie wick according to claim 1, wherein the melamine resin aqueous solution is mixed with a fragrance that gives a natural scent and surface-treated.
KR10-2002-0028657A 2002-05-23 2002-05-23 Producting method of give out ultrared rays padding for a necktie KR100456429B1 (en)

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