KR20020055279A - Cold work embrittlement free high strength steel sheet - Google Patents
Cold work embrittlement free high strength steel sheet Download PDFInfo
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- KR20020055279A KR20020055279A KR1020000084700A KR20000084700A KR20020055279A KR 20020055279 A KR20020055279 A KR 20020055279A KR 1020000084700 A KR1020000084700 A KR 1020000084700A KR 20000084700 A KR20000084700 A KR 20000084700A KR 20020055279 A KR20020055279 A KR 20020055279A
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- steel sheet
- strength steel
- high strength
- cold work
- embrittlement
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Abstract
Description
본 발명은 고장력 강판에 관한 것으로, 더욱 상세하게는 강도가 높고 저온 취성이 없어서 자동차 멤버나 보강재로 널리 사용될 수 있는 고장력 강판에 관한 것이다.The present invention relates to a high tensile strength steel sheet, and more particularly, to a high tensile strength steel sheet which can be widely used as an automobile member or a reinforcing material due to its high strength and low temperature brittleness.
종래에 자동차 멤버나 보강재 부품용 소재로 사용 되어온 강판은 대체로 탄소(C)함량이 0.005% 이하, 인(P)이 0.08 내지 0.10%, 망간(Mn)이 1.05 내지 1.25%, 규소(Si)가 0.2 내지 0.3%, 그리고 티타늄(Ti)이 0.04 내지 0.06% 정도 포함되어 있는 IF(Interstitial Free)강판을 주로 사용해 왔다. 즉, P, Mn, Si 를 첨가한 치환형 고용체로서, 강도를 증가시키기 위해 C 의 함량은 극도로 낮추면서 Ti을 첨가한 것이 대부분이었다.Conventionally, steel sheets that have been used as materials for automobile members or reinforcement parts generally have a carbon content of 0.005% or less, phosphorus (P) of 0.08 to 0.10%, manganese (Mn) of 1.05 to 1.25%, and silicon (Si). Interstitial free (IF) steel sheets containing 0.2 to 0.3% and 0.04 to 0.06% of titanium (Ti) have been mainly used. That is, most of the substituted solid solution to which P, Mn, and Si were added were Ti added while the content of C was extremely low in order to increase the strength.
이와 같은 IF 강판은 상온 시효가 없고, 성형성이 좋아 형상이 복잡한 부품에 널리 사용되어 왔지만, 과다한 P 가 첨가되어 있어서 입계에 편석되므로 2 차 프레스 가공시 취약한 입계로 인하여 균열이 발생하거나 저온 충돌 시 부품이 깨져버리는 단점이 있었다.Such IF steel sheets have been widely used in parts with complex shapes, which have no aging at room temperature and have good formability. However, since excessive P is added and segregates at grain boundaries, cracks may occur due to brittle grains during secondary press processing, or at low temperatures. There was a disadvantage that the parts were broken.
이에, 본 발명자들은 상기와 같은 종래 IF강판의 문제점을 개선시키기 위하여 탄소와 티타늄의 함량을 높여서 강도가 높고 저온 취성이 없는 고장력 강판을 개발하게 되었다.Accordingly, the present inventors have developed a high strength steel sheet having high strength and low temperature brittleness by increasing the content of carbon and titanium in order to improve the problems of the conventional IF steel sheet as described above.
본 발명은 탄소함량이 0.01 ∼ 0.04%이고, 인 함량이 0.06 ∼ 0.08%, 망간이 1.2 ∼ 1.5%, 규소가 0.001 ∼ 0.05% 포함된 고장력 강판을 그 특징으로 한다.The present invention is characterized by a high tensile strength steel sheet containing 0.01 to 0.04% of carbon, 0.06 to 0.08% of phosphorus, 1.2 to 1.5% of manganese, and 0.001 to 0.05% of silicon.
또한 본 발명의 고장력 강판은 티타늄 0.03% 이하를 포함 할 수도 있다.In addition, the high-strength steel sheet of the present invention may include 0.03% or less of titanium.
이와 같은 본 발명을 더욱 상세하게 설명하면 다음과 같다.The present invention will be described in more detail as follows.
본 발명에서 탄소는 침입형 고용체를 만들어 강판의 강도를 향상시키고 일부는 결정입계로 이동하여 결정립간의 결합력을 높여서 2차 가공시 균열발생을 방지하는 역할을 한다. 이때 탄소의 함량은 0.01 내지 0.04 %가 되도록 해야 하는데만일 탄소의 함량이 0.01% 이하이면 저온 충돌시 강판이 파열되기 쉬운 단점이 있고, 반대로 0.04% 이상이면 성형성을 해치게 되어 좋지 않다.In the present invention, the carbon makes the intrusion-type solid solution to improve the strength of the steel sheet, and some of them move to the grain boundaries to increase the bonding strength between the grains to serve to prevent the occurrence of cracks during secondary processing. At this time, the carbon content should be 0.01 to 0.04%, but if the carbon content is 0.01% or less, the steel sheet is easily ruptured at low temperature collisions.
인은 치환형 고용체로서 0.06 내지 0.08%의 함량을 갖도록 해야 한다. 인의 함량이 0.06% 이하이면 충분한 강도 증가 효과를 기대 하기 어렵고, 0.08% 이상이면 원하는 입계 석출 방지 효과를 얻을 수 없다.Phosphorus should be content of 0.06 to 0.08% as a substituted solid solution. If the phosphorus content is 0.06% or less, it is difficult to expect a sufficient strength increase effect, and if it is 0.08% or more, the desired grain boundary precipitation prevention effect cannot be obtained.
망간도 치환형 고용체로서 강도 향상을 위해 1.2% 이상 첨가하되, 신율 감소 예방을 위해 1.5% 이하로 제한한다.Manganese is also a substituted solid solution, and is added in an amount of 1.2% or more to improve strength, but is limited to 1.5% or less to prevent elongation reduction.
규소는 강판 내부에 과량 함유되어 있으면 도금강판의 부착성을 해치므로 0.05% 이하로 제한한다.If silicon is contained in the steel sheet excessively, the adhesion of the plated steel sheet is impaired, so it is limited to 0.05% or less.
본 발명에 따른 고장력 강판은 약간의 상온시효가 발생되기는 하지만 차체 내판용 부품 제조에는 아무런 문제가 되지 않는다. 자동차 멤버나 보강재는 굽힘 변형이나 소량의 신장 성형, 드로잉 등의 공정을 거쳐야 하기 때문에 강도가 크게 향상되어 있고 저온 취성이 없는 본 발명의 고장력 강판은 향후 특히 자동차용 강판으로 널리 이용될 것으로 기대 된다.The high-strength steel sheet according to the present invention, although some room temperature aging is generated, there is no problem in the manufacturing of parts for the vehicle body inner plate. Since the automobile member or the reinforcing material has to undergo a process of bending deformation, a small amount of elongation molding, drawing, etc., the high tensile strength steel of the present invention is greatly improved and low temperature brittleness is expected to be widely used as a steel sheet for automobiles in the future.
이와 같은 본 발명을 실시예에 의거 상세히 설명하겠는 바, 본 발명이 실시예에 의해 한정되는 것은 아니다.Although this invention is demonstrated in detail based on an Example, this invention is not limited by an Example.
실시예 1 ∼ 2 및 비교예 1 ∼ 2.Examples 1-2 and Comparative Examples 1-2.
상기 표 1의 화학 조성을 가진 강판을 열간 압연하여 두께 2.8 mm의 열연 강판을 만든다. 산세공정을 거쳐 냉간 압연하여 최종 두께가 1.2 mm가 되도록 한 다음, 820℃에서 연속 소둔을 실시하고 냉각하였다.The steel sheet having the chemical composition of Table 1 is hot rolled to make a hot rolled steel sheet having a thickness of 2.8 mm. The product was cold rolled through a pickling process to a final thickness of 1.2 mm, followed by continuous annealing at 820 ° C., and cooling.
이렇게 하여 제조된 강판으로 KS5호의 인장시편을 만든 후, 쯔빅 인장시험기로 인장시험을 실시하였다. 이때 시험속도는 분당 20mm로 하였으며 항복강도는 0.2% offset 법으로 산출하였다. 인장강도는 시험시 최대하중을 시험편의 단면적으로 나누어 구하였고 신율은 표점거리 50mm에서 파단시까지 늘어난 길이로 구하였다. 또한 강판의 연성취성 천이온도는 각 강판별로 1.92의 drawing ratio를 갖는 원통컵을 만들고, 각각의 온도에 컵을 노출시킨 후 추를 낙하시켜 컵이 깨지는 온도로서 결정하였다.After the tensile test specimen of KS5 was made from the steel sheet thus manufactured, a tensile test was performed with a Zwick tensile tester. The test speed was 20mm / min and yield strength was calculated by 0.2% offset method. Tensile strength was determined by dividing the maximum load by the cross section of the specimen, and the elongation was calculated by increasing the length from breakage to 50mm. In addition, the soft brittle transition temperature of the steel sheet was made as a cylindrical cup having a drawing ratio of 1.92 for each steel sheet, the cup was exposed to each temperature and the weight is dropped to drop the cup.
다음 표 2는 실시예 및 비교예의 강판에 대한 시험결과를 비교하여 나타낸 것이다.Table 2 shows a comparison of the test results of the steel sheets of Examples and Comparative Examples.
상기 표 2에서 알 수 있는 바와 같이 본 발명의 고장력 강판은 원가가 저렴하고 차량의 경량화가 가능하며, 특히 영하 40℃ 이하의 온도에서도 양호한 취성을 나타내기 때문에 저온 충돌시 충격흡수 에너지가 높아 보다 안전한 차량을 개발하는데 크게 이바지할 것으로 기대 된다.As can be seen in Table 2, the high-strength steel sheet of the present invention is inexpensive and light in weight, and is particularly safe due to high impact absorption energy during low temperature collisions because it exhibits good brittleness even at temperatures below 40 ° C. It is expected to contribute greatly to the development of the vehicle.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109825761A (en) * | 2019-01-10 | 2019-05-31 | 邯郸钢铁集团有限责任公司 | 600 μm of thin gauge 250MPa high phosphorus IF steel stable rolling methods |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5819439A (en) * | 1981-07-28 | 1983-02-04 | Sumitomo Metal Ind Ltd | Production of high strength steel pipe having excellent low temperature toughness |
JPS62260043A (en) * | 1986-05-02 | 1987-11-12 | Nippon Steel Corp | Steel for high strength chain of large diameter having superior toughness at low temperature |
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2000
- 2000-12-28 KR KR1020000084700A patent/KR20020055279A/en not_active Application Discontinuation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5819439A (en) * | 1981-07-28 | 1983-02-04 | Sumitomo Metal Ind Ltd | Production of high strength steel pipe having excellent low temperature toughness |
JPS62260043A (en) * | 1986-05-02 | 1987-11-12 | Nippon Steel Corp | Steel for high strength chain of large diameter having superior toughness at low temperature |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109825761A (en) * | 2019-01-10 | 2019-05-31 | 邯郸钢铁集团有限责任公司 | 600 μm of thin gauge 250MPa high phosphorus IF steel stable rolling methods |
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