KR20020046395A - Natural paints and water-based paints mixed with natural materials and minerals - Google Patents

Natural paints and water-based paints mixed with natural materials and minerals Download PDF

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KR20020046395A
KR20020046395A KR1020000076252A KR20000076252A KR20020046395A KR 20020046395 A KR20020046395 A KR 20020046395A KR 1020000076252 A KR1020000076252 A KR 1020000076252A KR 20000076252 A KR20000076252 A KR 20000076252A KR 20020046395 A KR20020046395 A KR 20020046395A
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powder
natural
based resin
natural material
based resins
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KR1020000076252A
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Korean (ko)
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전효철
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황경원
주식회사 월핀
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE: A natural material and an aqueous paint comprising the natural material and a mineral material are provided, to allow the aqueous paint to be sprayed and to obtain a natural textured appearance. CONSTITUTION: The natural material is wood powder, dried cork powder of the leaves, chaff powder, green tea powder, rice straw, mugwort powder, dry grass powder, charcoal powder, dried herb or their mixtures. The aqueous paint comprises 20-59 wt% of the natural material; and 1-20 wt% of a mineral material selected from the group consisting of vermiculite, mica, diatomite, micro cell and their mixtures; and 40-60 wt% of a binder. The binder is selected from the group consisting of an acryl-based resin, a polyethylene-based resin, an elastic binder, an ethyl-vinyl acetate-based resin, a fluoride-based resin, an ethyl-vinyl acetate urethane-based resin containing a biodegradable surfactant and their mixtures.

Description

천연소재 및 천연소재와 광물질을 혼합한 수성도료{.}Natural paints and aqueous paints mixed with natural materials and minerals {.}

본 발명은 일정한 입자로 분류한 목분( 소나무, 향나무,잣나무, 육송, 백송등의 목재의 목분을 칭함) 및 건조된 그잎, 왕겨분, 녹차분, 볏짚, 쑥분, 콜크분, 건초분, 건수초분,숯분(참숯, 야자숯, 대나무숯의 숯분을 칭함)들꽃, 건조된 허브 식물류, 원두커피분등의 천연소재 및 질석, 편운모, 규조토, 마이크로 셀등 광물질을 목분, 왕겨분,볏짚, 건초분, 건수초분, 숯분과 같은 천연소재와 혼합하여 아크릴계통의 수지, PE계통의 수지, EVA계통의 수지, 불소계통, 생분해성 계면활성제가 포함된 EVA, 우레탄 계통의 수지등을 물과 함께 혼합하여 스프레이건으로 분사 도장할 수 있는 수성도료에 관한 것이다.The present invention is classified as a specific particle wood flour (pine wood, juniper, pine, meat, white pine, etc.) and dried leaf, chaff powder, green tea powder, rice straw, mugwort powder, cork powder, hay powder, dried grass powder , Charcoal powder (called charcoal, coconut charcoal, bamboo charcoal), natural materials such as wild flowers, dried herb plants, coffee beans, and minerals such as vermiculite, mica, diatomaceous earth, and microcells Mixed with natural materials such as dried water powder, charcoal powder, acrylic resin, PE resin, EVA resin, fluorine resin, EVA containing biodegradable surfactant, urethane resin, etc. It relates to an aqueous paint which can be sprayed and sprayed with a spray gun.

기존의 수성 도료는 질감을 표현할 수 없으며, 퍼티종류는 미장용 고대나 문양이 새겨진 롤라, 주걱등으로 질감을 표현하는 방법을 사용하며 유성도료에서는 프라스틱칩이나 금속칩, 화학적으로 형성시킨 칩등을 첨가하여 질감을 표현하고 있다.Conventional water-based paints cannot express the texture, and putty types use the method of expressing the texture with plastering or patterned rolls, spatula, etc.In oil paint, plastic chips, metal chips, and chemically formed chips are added. To express the texture.

이와같은 유성도료에는 원료로 많이 사용되는 TDI 와 MDI란 물질 및 유기용제등을 사용하여 대기오염 및 환경오염을 유발시킨다.For oil paints like this, TDI and MDI, which are frequently used as raw materials, and organic solvents are used to cause air pollution and environmental pollution.

본 발명은 이와같은 문제점을 해결하기 위해 자연 친화적인 천연소재와 자연적인 불연소재인 광물질인 질석, 편운모, 규조토, 마이크로셀 등을 천연 소재와 혼합하여 수성도료를 만들고져 함에 있다.The present invention is to make an aqueous coating by mixing natural materials and natural vermiculite, natural mica, diatomaceous earth, microcells and the like with natural materials to solve such problems.

또한 천연소재와 수성 바인다와 혼합시 통상의 항균제 및 황토, 일라이트, 옥, 맥반석, 게르마늄 등 원적외선 방사 물질을 첨가하여 기능성을 부여할 수 있는 수성도료이다.In addition, when mixed with natural materials and aqueous binders, it is an aqueous coating that can impart functionality by adding conventional antimicrobial agents and far-infrared radiation materials such as ocher, illite, jade, elvan, germanium.

일반적으로 수성도료는 무기광물질인 탄산칼슘, 탈크, TiO2주원료를 사용하며 일부는 미세한 셀로로이스, 미세한 왕겨분 등을 수성 바인다에 혼합하여 생산한다.Generally, water-based paints use inorganic minerals such as calcium carbonate, talc, and TiO 2 main raw materials, and some of them are produced by mixing fine cellulose and fine chaff powder with an aqueous binder.

본 발명은 수성바인다에 천연소재 및 광물질을 탄산칼슘, 탈크,TiO2, 색소등에 혼합시 천연소재와 수성바인다의 비중차에 의한 층간 분리현상 및 천연소재에서 수성바인다 및 물의 수분을 흡수하여 침전 현상의 발생을 방지하기 위해 수성바인다와 천연소재의 비중을 균일하게 하고져 증점제를 사용하여 일정한 점도를 유지시키고 천연소재를 먼저 표면코팅하여 수분침입을 막으며, 천연소재의 섬유사이에 탄산칼슘, 탈크등을 사용하여 엉킴을 방지 하고져 하였다.According to the present invention, when a natural material and a mineral are mixed in an aqueous binder with calcium carbonate, talc, TiO 2 , and a pigment, the separation between layers due to the specific gravity difference between the natural material and the aqueous binder and the absorption of the aqueous binder and water from the natural material are precipitated. In order to prevent the occurrence of water, the specific gravity of the aqueous binder and the natural material is uniformed to maintain a constant viscosity by using a thickener, and the surface coating of the natural material to prevent moisture intrusion, calcium carbonate, talc, etc. between the fibers of the natural material Use it to prevent tangles.

또한 수성바인다와 천연소재 혼합시 불소계통의 난연재 및 염소계통, 부륨계통, 안티몬계통, 인산염 계통, 불소지르코늄 계통의 난연제 등을 첨가하여 난연성을 부여할 수 있도록 하였다.In addition, fluorine-based flame retardant and chlorine-based, fluorine-based, antimony-based, phosphate-based, and fluorine-zirconium-based flame-retardants were added to provide flame retardancy when mixing aqueous binders with natural materials.

본 발명의 실시예를 상세히 설명하면 다음과 같다.An embodiment of the present invention will be described in detail as follows.

1) 먼저 일정한 입자로 분류된 ( 10-20 매쉬, 20-30매쉬, 30-40매쉬, 40-50매쉬, 50-60매쉬, 60-70매쉬, 70-80매쉬등) 목분, 왕겨분, 녹차분, 볏짚분, 쑥분, 건초분, 건수초분, 숯분,건조된 허브 식물류 및 들꽃, 원두커피분 등의 천연소재를 표면 코팅한다.1) First, wood powder, rice husk powder, (10-20 mesh, 20-30 mesh, 30-40 mesh, 40-50 mesh, 50-60 mesh, 60-70 mesh, 70-80 mesh, etc.) Surface coating of natural materials such as green tea powder, rice straw powder, wormwood powder, hay powder, dried vinegar powder, charcoal powder, dried herb plants and wild flowers and coffee beans.

( 이때 표면코팅은 절대적으로 하여야 하는 사항은 아니다.(The surface coating is not absolutely necessary.

예 : 목분에 표면코팅에 색소를 사용하여 착색을 하기 위해서 일수도 있으며 착색후 탈색을 방지하기 위해 자외선 차단제등을 사용하며 색소의 착상이 목분에 안정적으로 이루어 지게 하기 위해 표면코팅제로 아크릴계통의 수지, PE나 EVA 계통의 수지, 우레탄 계통의 수지, 불소계통의 수지, 생분해성 계면활성제가 포함된 EVA계통의 수지, 탄성바인다 등을 사용한다.)Example: It may be used for coloring by using pigment for surface coating on wood powder, and using sunscreen to prevent discoloration after coloring and acrylic resin as surface coating agent to make pigmentation stable on wood powder. , PE or EVA resin, urethane resin, fluorine resin, EVA resin containing biodegradable surfactant, elastic binder, etc.).

실시예1) 천연소재 표면 코팅 및 착색시 혼합비 ( 중량%)Example 1) Mixing ratio (wt%) for surface coating and coloring of natural materials

※ 상기 조성비율은 작업 조건에 따라 변할 수 있다.※ The composition ratio may change depending on working conditions.

2) 일정한 입자로 분류된 목분, 왕겨분, 볏짚분, 콜크분등 천연소재 및 상기실시예1)에서 표면코팅된 목분, 왕겨분, 볏짚분을 아래와 같이 (실시예2) 혼합된 밀베이스에 혼합한다.2) Wood powder, rice husk powder, rice straw powder, rice straw powder, and cork powder classified as certain particles and wood powder, rice husk powder, rice straw powder coated in Example 1) as shown below (Example 2) Mix.

실시예 2)Example 2)

※ 상기 조성비율은 작업조건 및 질감 표현에 따라 변할 수 있다.※ The composition ratio may change according to working conditions and texture expression.

이때 기본 베이스에 천연소재를 혼합할 때 실시예2)의 A.B.C의 배합비에는 일정한 입자로 분류된 목분, 왕겨분, 볏짚분, 콜크분을 배합하여 바탕색상과 목분의 색상( 자체 착색현상이 일어남)을 동일하게 가져가며 실시예2)의 D.E.F의 배합비에서는 실시예1)의 A.B.C등으로 착색 및 코팅된 원료를 사용한다.At this time, when mixing the natural material on the base base, the blending ratio of ABC of Example 2) is mixed with wood powder, rice husk powder, rice straw powder, and cork powder classified as certain particles, and the color of the ground color and wood powder (self-coloring phenomenon occurs). In the same manner, in the compounding ratio of DEF of Example 2), raw materials colored and coated with ABC of Example 1) are used.

이때 혼합되는 천연소재의 량은 실시예2)의 혼합비 대비 20∼60% 중량부 (%)로 조성함이 바람직하다.At this time, the amount of the natural material to be mixed is preferably composed of 20 to 60% by weight (%) relative to the mixing ratio of Example 2).

또한 상기 실시예2)의 배합비에 황토, 일라이트, 옥, 맥반석, 게르마늄, 세라믹, 통상의 항균제를 첨가하여 기능성을 부여 하고져 할때는 실시예2)의 혼합비 대비 1∼10 중량(%)를 첨가하여 기능성을 부여할 수 있다.In addition, when adding the ocher, illite, jade, ganban stone, germanium, ceramics, ordinary antimicrobial agent to the compounding ratio of Example 2) to give functionality, adding 1 to 10% by weight (%) compared to the mixing ratio of Example 2) Functionality can be given.

3) 상기에서 사용되는 바인더는 천연소재를 접착시키고져 하는 피착물에 견실하게 부착되어 있게하는 접착 특성을 가진 아크릴계수지 및 PE. EVA. 불소계통의 수지, 우레탄 계통의 수지, 탄성바인더. 생분해성 계면활성제가 포함된 EVA계통의 수지등 어느 하나를 설정하여 사용하여도 무방하다.3) The binder used above is an acrylic resin and PE having an adhesive property to be firmly attached to the adherend to be bonded to the natural material. EVA. Fluorine resin, urethane resin, and elastic binder. Any of the EVA-based resin containing a biodegradable surfactant may be used.

또 상기에서 사용된 황토, 일라이트, 옥, 맥반석, 게르마늄, 세라믹 등의 광물질 들을 첨가하는 이유는 인체에 유익한 원적외선과 같은 물질을 방사 하도록 첨가한 것인데 상기 물질들은 원적외선이 방사됨은 주지된 사실이다.In addition, the reason for adding minerals such as ocher, illite, jade, elvan, germanium, and ceramics used in the above is added to radiate materials such as far infrared rays, which are beneficial to the human body.

또 상기 일라이트는 점토질 연질 운모광물로 삼층 인편상 구조를 하고 있는데 물에 풀었을때에는 견사 현상을 나타내는 독특한 성질이 있고, 그 구성분은 SiO2, AlO2, K2O, FeO2등으로 이루어진 황백색 합성광물이며, 물리적 화학적 성질은 수중에서 다량의 용존 산소를 발산하는 효능이 있고, 또 수중에 용존하는 동금속이온 유기질이온, 부패 유기질의 악취등을 흡착하는 흡착 특성이 있다.In addition, the illite is a clay soft mica mineral having a three-layer scaly structure, and when unwrapped in water, has a unique property of showing silkiness, and its components are composed of SiO 2 , AlO 2 , K 2 O, FeO 2 , and the like. It is an off-white synthetic mineral, and its physical and chemical properties are effective in dissipating a large amount of dissolved oxygen in water, and have adsorption characteristics to adsorb copper metal ion organic ions, decaying organic odors, etc. dissolved in water.

이 흡착성은 공기중에서도 발휘되어 유독가스나 악취 제거를 효과적으로 하는데 이에 대한 효과는 국내특허공보 제4623호에 게재된 공고번호 96-12091호에 자세히 개시되어 있다.This adsorption is exerted in the air to effectively remove toxic gases and odors, the effect of which is disclosed in detail in Publication No. 96-12091 published in Korean Patent Publication No. 4603.

또 상기 일라이트에는 무기 켈마늄이 150PPM이상 함유되어 있어서 인체의 신진대사를 촉진시켜 주는데에 우수한 효능을 발휘함은 이미 널리알려져 있다. 맥반석은 SiO2, FeO3, Al2O3, CaO, MgO, K2O, Na2O, TiO2, MnO, P2P5를 주성분으로 하는 광물질로서, 우수한 원적외선 방사 효능 및 특히 다공 무기질체이기 때문에 항균 작용과 중화 작용에서 우수한 효능을 발휘한다.In addition, since the illite contains more than 150PPM of inorganic keelium, it is widely known to exert an excellent effect in promoting the metabolism of the human body. Elvanite is a mineral composed mainly of SiO 2 , FeO 3 , Al 2 O 3 , CaO, MgO, K 2 O, Na 2 O, TiO 2 , MnO, P 2 P 5 , and has excellent far-infrared radiation efficiency and especially porous inorganic material. Because of this, it exhibits excellent efficacy in antibacterial and neutralizing effects.

4) 상기 작업시 난연의 기능성을 부여하고져 할 때는 아래의 혼합비로 난연제를 첨가하면 난연성을 부여할 수 있다.4) When imparting the functionality of flame retardant in the above operation, flame retardant can be imparted by adding flame retardant in the following mixing ratio.

실시예3) 난연제 첨가시 배합비 (중량%)Example 3) Mixing ratio when adding flame retardant (wt%)

상기에서 사용되는 난연제는 불소계통의 난연제 및 염소계통, 부륨계통, 인산염계통, 안티몬계통, 불소지르코늄계통등의 난연제중 어느 하나를 선정하여 사용하거나 2종류를 중합하여 사용하여도 무방하며 합성수지의 증가에 따라 난연제의 투입 비율을 증가하여 사용한다.The flame retardant used above may be selected from fluorine-based flame retardants and flame retardants such as chlorine-based, burium-based, phosphate-based, antimony-based and fluorine-zirconium-based, or may be used by polymerizing two types. In accordance with the increase of the flame retardant input ratio is used.

5) 질석, 편운모, 규조토, 마이크로셀등 광물질은 상기 실시예 2)의 30∼69% 중량부에 목분, 왕겨분,볏짚분을 20∼60 중량부(%)에 선별 분류된 광물질 ( 20∼30매쉬, 30∼40메쉬, 40∼50메쉬, 50∼60메쉬, 60∼80메쉬 등) 1∼10 중량부 (%)로 조성함이 바람직하다.5) Minerals such as vermiculite, mica, diatomaceous earth, microcell, and the like are classified into 20 to 60 parts by weight of wood flour, rice husk powder and rice straw powder in 30 to 69% by weight of Example 2). 30 mesh, 30-40 mesh, 40-50 mesh, 50-60 mesh, 60-80 mesh, etc.) 1-10 weight part (%) is preferable.

실시예4) 밀베이스와 천연소재 및 광물질의 혼합비 중량%Example 4 Mixing Weight Percentage of Mill Base, Natural Materials, and Minerals

※ 상기 조성비율은 작업조건에 따라 변할 수 있다.※ The composition ratio may change depending on working conditions.

( 상기 밀베이스란 실시예 2)의 혼합비를 칭함)(The mill base refers to the mixing ratio of Example 2)

또한 상기 조성비율에서 실시예 2)의 A.B의 혼합비중 하나를 선택하여 A의 혼합비 50중량(%), 목분 ( 실시예1의 A) 30중량(%), 볏짚10 중량부(%), 편운모 10 중량부(%)등으로 조성할 수도 있으며 현출되는 문양이나 칼라 배정은 상기 각 조성분들의 증감에 따라서 임의로 변형이 가능하다.In addition, in the above composition ratio, one of the mixing ratios of AB of Example 2) is selected, and the mixing ratio of A is 50% by weight (%), wood meal (A of Example 1) 30% by weight (%), rice straw 10% by weight (%), piece Mica may be formed in 10 parts by weight (%) and the like, and the appearance of the pattern or color assignment may be arbitrarily modified according to the increase and decrease of the respective components.

이상과 같이 본 발명에 의하면 수성도료에 자연분해성이 우수한 천연소재와 광물질을 원적외선 방사와 항균 및 방충 특성의 물질로 배합된 바인더와 혼합하여 구성한것에 의해 도료로 부터는 다량의 원적외선이 방사되는 효능을 얻게되는 효과가 있고 천연소재들은 모두 1차적으로 사용되고 남겨지는 잔존물이므로 자원 재활용의 효과도 크고 그 비용이 저렴하게 되어 도료의 제조원가를 절감할 수 있는 효과가 있다.As described above, according to the present invention, by mixing a natural material and a mineral having excellent natural degradability in an aqueous paint and a binder mixed with a material having far infrared radiation and antibacterial and insect repellent properties, a large amount of far infrared rays are emitted from the paint. Natural materials are all used and left as a primary residue, so the effect of resource recycling is large and its cost is low, thereby reducing the manufacturing cost of the paint.

또, 천연소재에 의한 무늬 형상 및 입체감 표현은 종래의 도료에서 공해 요인이 되는 합성 광물질 사용을 없게하는 효과가 있다.In addition, the pattern shape and three-dimensional representation by the natural material has the effect of eliminating the use of synthetic minerals, which is a pollution factor in conventional paints.

또 도료에 함유된 원적외선 방사물질은 공기등의 유독가스, 악취등을 흡착 제거하는 성질 즉, 기존 주택의 벽면을 구성하는 이면도가 지니고 있는 PH13정도의 강알칼리성 성분이 난방등에 휘산 될 때에 이를 흡착하여 등화 시키는 성질과 음이온을 발산하는 성질과 무기켈마늄과 원적외선을 방사하는 효과로 보다 쾌적한 주거환경을 제공하는 효과가 있고, 또 항균 물질에 의해서는 도료에 발생되는 바이러스, 박태리아, 및 곰팡이 등의 세균번식을 억제하여 결과적으로는 도료의 부식을 방지함으로써 사용 수명을 길게하는 효과가 있다.In addition, the far-infrared radiation contained in the paint absorbs and removes toxic gases such as air and odors, that is, when a strong alkaline component such as PH13 having the back surface constituting the wall of an existing house is volatilized by heating. It provides the pleasant living environment by the property of equalizing, releasing anions, and the effect of radiating inorganic nickel and far infrared rays. Also, antibacterial substances such as viruses, bacteria, and fungi generated in paints By suppressing the bacterial growth of the consequently it has the effect of prolonging the service life by preventing corrosion of the paint.

Claims (3)

일정한 입자로 분류된 목분, 왕겨분, 콜크분, 녹차분, 볏짚분, 쑥분, 건초분,건수초분, 숯분, 건조된 허브 식물류 및 들꽃, 원두커피분 등의 천연소재와 아크릴 계통의 수지, PE계통의 수지, 탄성바인더, EVA 계통의 수지, 불소계통의 수지, 우레탄계통의 수지, 생분해성 계면 활성제가 포함된 EVA 계통의 수지와 혼합하여 스프레이건으로 분사할수 있는 수성도료.Natural materials such as wood flour, rice husk flour, cork flour, green tea powder, rice straw powder, mugwort powder, hay powder, dried dry grass powder, charcoal powder, dried herb plants and wild flowers, coffee beans powder, PE resin Aqueous paint that can be sprayed with spray guns by mixing with resins, elastic binders, EVA-based resins, fluorine-based resins, urethane-based resins, and EVA-based resins containing biodegradable surfactants. 상기 천연소재 20∼59 중량(%)에 질석, 편운모, 규조토, 마이크로 셀등 광물질을 1∼20 중량(%) 상기에 기재된 바인더 40∼60 중량부(%)로 혼합된 수성도료.An aqueous coating material containing 20 to 59 weight% of the natural material, and 1 to 20 weight% of minerals such as vermiculite, mica, diatomaceous earth, and microcells. 청구항1 및 청구항2에 황토, 옥, 맥반석, 일라이트, 게르마늄, 세라믹, 통상의 항균제를 첨가하여 기능성을 부여할 수 있는 수성도료.An aqueous coating capable of imparting functionality by adding ocher, jade, elvan, illite, germanium, ceramics, and common antibacterial agents to claims 1 and 2.
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KR20020000854A (en) * 2001-11-02 2002-01-05 홍순식 Ceramic dyes for hand-painting
KR20020079314A (en) * 2001-04-04 2002-10-19 주식회사 지메터텍 Charcoal paint
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KR20020079314A (en) * 2001-04-04 2002-10-19 주식회사 지메터텍 Charcoal paint
KR20020096056A (en) * 2001-06-14 2002-12-31 이영환 Method for manufacturing long wave infrared radiation & electromagnetic absorption paint
KR20010100122A (en) * 2001-10-08 2001-11-14 (주)파워바이오 The method of making the paint that it happens oxygen anion.
KR20020000854A (en) * 2001-11-02 2002-01-05 홍순식 Ceramic dyes for hand-painting
KR100515014B1 (en) * 2002-01-10 2005-09-15 (주)프리바이오 bio interior finishing paint
KR20040003965A (en) * 2002-07-05 2004-01-13 장일준 Polymethylmetaacrylate resin composition and preparation thereof
KR20040014104A (en) * 2002-08-09 2004-02-14 최명부 The Manufacture of antibacterial water tankc using charcoal and silver
KR100484405B1 (en) * 2002-09-02 2005-04-22 조남일 A composite of paint having multi-function
KR100651265B1 (en) * 2005-04-19 2006-12-01 대한민국 Coating materials for surface finishing of construction
EP1871850A1 (en) * 2005-04-22 2008-01-02 LG Chem, Ltd. Functional uv paint, construction material using the same, and method of preparing the paint
WO2006112623A1 (en) 2005-04-22 2006-10-26 Lg Chem, Ltd. Functional uv paint, construction material using the same, and method of preparing the paint
EP1871850A4 (en) * 2005-04-22 2010-01-20 Lg Chemical Ltd Functional uv paint, construction material using the same, and method of preparing the paint
KR100674443B1 (en) * 2005-08-29 2007-01-25 박원식 Functional water paint composite annexing charcoal
KR100736417B1 (en) * 2005-10-17 2007-07-09 주식회사 유니텍 Ultra Violet Curing Paint Composition Radiating Far Infrared Ray for Plastics
KR100852094B1 (en) * 2008-04-02 2008-08-13 주효연 Natural paint having antifungal function and method of manufacturing the same
KR100869586B1 (en) * 2008-04-02 2008-11-21 (주)한국신화 Inside member of pillow or cushion and method of manufacturing the same
KR100867230B1 (en) * 2008-05-27 2008-11-06 주식회사 건정종합건축사사무소 Method of manufacturing painting composite and the composite thereof
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