KR20020045453A - Method for fabricating photo diode by double photo-mask process - Google Patents
Method for fabricating photo diode by double photo-mask process Download PDFInfo
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- KR20020045453A KR20020045453A KR1020000075069A KR20000075069A KR20020045453A KR 20020045453 A KR20020045453 A KR 20020045453A KR 1020000075069 A KR1020000075069 A KR 1020000075069A KR 20000075069 A KR20000075069 A KR 20000075069A KR 20020045453 A KR20020045453 A KR 20020045453A
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- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000005468 ion implantation Methods 0.000 claims abstract description 22
- 229920002120 photoresistant polymer Polymers 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 13
- 229920005591 polysilicon Polymers 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 238000000151 deposition Methods 0.000 claims abstract description 3
- 239000012535 impurity Substances 0.000 claims description 11
- 238000005530 etching Methods 0.000 claims description 4
- 229910021332 silicide Inorganic materials 0.000 claims description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 abstract description 5
- 230000035515 penetration Effects 0.000 abstract description 5
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 abstract description 5
- 229910021342 tungsten silicide Inorganic materials 0.000 abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000059 patterning Methods 0.000 abstract description 4
- 229910052710 silicon Inorganic materials 0.000 abstract description 4
- 239000010703 silicon Substances 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 239000002019 doping agent Substances 0.000 abstract 1
- 230000000452 restraining effect Effects 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14665—Imagers using a photoconductor layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/14609—Pixel-elements with integrated switching, control, storage or amplification elements
- H01L27/1461—Pixel-elements with integrated switching, control, storage or amplification elements characterised by the photosensitive area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/1462—Coatings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/08—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
- H01L31/10—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by at least one potential-jump barrier or surface barrier, e.g. phototransistors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
Abstract
Description
본 발명은 이미지센서 제조방법에 관한 것으로, 특히 CMOS 이미지센서의 포토다이오드 제조 방법에 관한 것이다.The present invention relates to a method of manufacturing an image sensor, and more particularly, to a method of manufacturing a photodiode of a CMOS image sensor.
잘 알려진 바와 같이 CMOS 이미지센서는 핀드포토다이오드를 통해 이미지에 대응되는 전하를 생성하고 모은 다음, 이 전하를 트랜스퍼트랜지스터를 통해 센싱노드로 전달하여 전기적 신호를 검출하는 방식을 사용하게 된다.As is well known, a CMOS image sensor uses a pinned photodiode to generate and collect a charge corresponding to an image, and then transfer the charge to a sensing node through a transfer transistor to detect an electrical signal.
도 1은 종래기술에 따른 CMOS 이미지센서 제조 공정을 보여주는 단면도이다.1 is a cross-sectional view showing a manufacturing process of a CMOS image sensor according to the prior art.
도1을 참조하면, 종래에는 P+실리콘기판(101)상에 P에피층(102)을 형성시키고, 필드산화막(Fox)(103)을 형성한 후, 폴리실리콘막(104)과 텅스텐실리사이드막(105)을 연속적으로 도포하고 패터닝함으로써 폴리사이드 게이트 전극을 형성한다.Referring to FIG. 1, conventionally, after forming a P epi layer 102 on a P + silicon substrate 101, forming a field oxide film (Fox) 103, a polysilicon film 104 and a tungsten silicide film A polyside gate electrode is formed by successively applying and patterning 105.
이후 포토다이오드를 형성하기 위한 이온주입마스크로서 감광막 패턴(106)을 형성한 다음, 고에너지 이온주입(107)을 실시함으로써 저농도의 P에피층(102)에 N형불순물층(108)을 형성한다.Thereafter, the photosensitive film pattern 106 is formed as an ion implantation mask for forming the photodiode, and then the high-energy ion implantation 107 is performed to form the N-type impurity layer 108 in the low concentration P epilayer 102. .
도면에는 도시되지 않았지만, 이후 저에너지 이온주입을 실시하여 N형불순물층(108) 상에 P형불순물층을 형성하므로써 핀드포토다이오드의 제조는 완료된다.Although not shown in the drawings, the manufacture of the pinned photodiode is completed by forming a P-type impurity layer on the N-type impurity layer 108 by performing low energy ion implantation.
한편, 적색광에 대한 광감도를 높히기 위하여 고에너지 이온 주입을 통해 포토다이오드를 형성하게 되는 바, 전하운송효율에 영향을 미치는 트랜스터트랜지스터의 채널부분으로의 불순물의 침투(Penetration)를 방지하기 위하여 트랜스퍼트랜지스터의 게이트 폴리실리콘(104)의 두께(T1)를 일반적인 서브-마이크론기술(Submicron Technology)에서 사용되는 두께보다 두껍게 형성시킨다. (도면의 "A" 참조)On the other hand, the photodiode is formed through high energy ion implantation in order to increase the photosensitivity to the red light, so that the transfer transistor is prevented to prevent the penetration of impurities into the channel portion of the transistor, which affects the charge transport efficiency. The thickness T1 of the gate polysilicon 104 is formed to be thicker than the thickness used in the general submicron technology. (See "A" in the drawing.)
고에너지 이온주입시 인(Phosphorous)을 사용하는 경우, 180keV일때 게이트의 폴리실리콘(104) 두께는 약 4500∼5000Å 정도 필요하다.When phosphorus is used for high energy ion implantation, the thickness of the polysilicon 104 of the gate at about 180 keV is about 4500 to 5000 mW.
그러나 이 방법은 일반적인 서브 마이크론 기술과 상이하기 때문에 공정이 까다로울 뿐만 아니라, 200keV이상의 고에너지 이온주입 공정에는 적용하기 곤란한 제약조건이 따르기 때문에 불편하다.However, this method is not only difficult to process because it is different from the general submicron technology, but also inconvenient because it is difficult to apply to the high energy ion implantation process of 200 keV or more.
만약 200keV 이상의 고에너지로 포토다이오드를 형성하기 위하여 이온주입을 실시한다면 서브마이크론 기술에서 허용할 수 있는 게이트 폴리실리콘 두께로는 이온 침투를 방지할 수 없어 전하운송효율에 영향을 미치는 트랜스퍼트랜지스터의 채널부분으로의 불순물 유입이 발생되고, 이로 인해 원치 않는 열적발생(Thermally Generated) 전하에 의한 암전류(Dark Current)값이 증가하여 CMOS 이미지센서의 특성이 열화하게 된다.If ion implantation is carried out to form photodiodes with high energy of 200 keV or more, the channel portion of the transfer transistor that affects charge transport efficiency cannot be prevented by ion gate penetration with the gate polysilicon thickness that is acceptable in submicron technology. Impurity inflow occurs, which leads to an increase in dark current due to unwanted thermally generated charges, thereby degrading the characteristics of the CMOS image sensor.
본 발명은 상기한 바와 같은 종래기술의 문제점을 해결하기 위하여 안출된 것으로서, 서브마이크론 기술에서 통상 적용하고 있는 게이트 폴리실리콘 두께를 적용하면서도 고에너지 이온주입시 채널영역으로 이온주입이온이 침투하는 것을 방지하여, 공정의 단순화 및 소자 특성을 향상시키는데 적합한 CMOS 이미지센서 제조방법을 제공하는데 그 목적이 있다.The present invention has been made to solve the problems of the prior art as described above, while preventing the penetration of ion implantation ions into the channel region during high energy implantation while applying the thickness of the gate polysilicon commonly applied in submicron technology. Accordingly, an object of the present invention is to provide a method of manufacturing a CMOS image sensor suitable for simplifying the process and improving device characteristics.
도 1은 종래기술에 따른 포토마스크 제조 공정을 보여주는 단면도.1 is a cross-sectional view showing a photomask manufacturing process according to the prior art.
도 2는 본 발명의 바람직한 실시예에 따른 포토마스크 제조 공정을 보여주는 단면도.2 is a cross-sectional view showing a photomask manufacturing process according to a preferred embodiment of the present invention.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
201 : 실리콘기판 202 : 에피층201: silicon substrate 202: epi layer
203 : 필드산화막 204 : 폴리실리콘203: field oxide film 204: polysilicon
205 : 텅스텐실리사이드 206 : 감광막패턴(고에너지 이온주입 마스크)205: tungsten silicide 206: photosensitive film pattern (high energy ion implantation mask)
207 : 고에너지 이온주입 208 : 불순물층207 high energy ion implantation 208 impurity layer
209 : 감광막패턴(게이트 마스크)209 photoresist pattern (gate mask)
상기 목적을 달성하기 위한 본 발명의 CMOS 이미지센서 제조방법은, 기판에 게이트 전도막을 증착하는 단계: 게이트마스크인 제1감광막패턴을 형성하고 상기 게이트전도막을 식각하는 단계: 상기 제1감광막패턴을 잔류한 상태에서 상기 게이트전도막 일측의 상기 제1감광막패턴 및 상기 기판의 일부영역이 오픈된 제2감광막패턴을 형성하는 단계: 상기 제1 및 제2 감광막패턴을 마스크로하여 고에너지 이온주입을 실시하여 상기 기판에 포토다이오드의 불순물층을 형성하는 단계를 포함하여 이루어짐을 특징으로 한다.According to another aspect of the present invention, there is provided a method of manufacturing a CMOS image sensor, the method comprising: depositing a gate conductive film on a substrate: forming a first photoresist film pattern as a gate mask and etching the gate conductive film: retaining the first photoresist pattern Forming a first photoresist pattern on one side of the gate conductive layer and a second photoresist pattern having an open portion of the substrate in one state: high energy ion implantation using the first and second photoresist patterns as a mask And forming an impurity layer of a photodiode on the substrate.
이하, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 본 발명의 기술적 사상을 용이하게 실시할 수 있을 정도로 상세히 설명하기 위하여, 본 발명의 가장 바람직한 실시예를 첨부된 도면을 참조하여 설명하기로 한다.DETAILED DESCRIPTION Hereinafter, exemplary embodiments of the present invention will be described with reference to the accompanying drawings so that those skilled in the art may easily implement the technical idea of the present invention. do.
도2는 본 발명의 바람직한 실시예에 따른 CMOS 이미지센서 제조 공정중의 일부 단면도이다.2 is a partial cross-sectional view of a CMOS image sensor manufacturing process according to a preferred embodiment of the present invention.
도2를 참조하면, P+실리콘기판(201)상에 P에피층(202)을 형성시키고, 필드산화막(Fox)(203)을 형성한 후, 폴리실리콘막(204)과 텅스텐실리사이드막(205)을 연속적으로 도포하고 패터닝함으로써 폴리사이드 게이트 전극을 형성한다.Referring to FIG. 2, after forming the P epitaxial layer 202 on the P + silicon substrate 201 and forming the field oxide film (Fox) 203, the polysilicon film 204 and the tungsten silicide film 205 are formed. ) Is subsequently applied and patterned to form a polyside gate electrode.
이때, 종래와는 다르게 본 발명에서는 게이트 폴리실리콘(204)의 두께(T2)를서브-마이크론 기술에 따른 두께인 약 1500-2000Å로 적용하고, 게이트 패터닝시 사용한 감광막 패턴(209)을 그대로 잔류시킨다는 점에 그 특징을 갖는다.At this time, unlike the prior art, in the present invention, the thickness T2 of the gate polysilicon 204 is applied to about 1500-2000 mm, which is a thickness according to the sub-micron technology, and the photoresist pattern 209 used during the gate patterning is left as it is. It has that characteristic.
즉, 폴리사이드 게이트를 패터닝하는 방법은 텅스텐실리사이드막(205) 상에 감광막을 도포한 다음, 노광 및 현상에 의해 감광막 패턴(209)을 형성하고, 이 감광막 패턴(209)을 식각마스크로하여 텅스텐실리사이드(205) 및 폴리실리콘(204)을 식각한 후, 감광막 패턴(209)을 제거하는 공정으로 이루어지게 되는데, 본 발명에서는 식각 후 감광막 패턴(209)을 제거하지 않고 그대로 잔류시킨다는 것이다.That is, in the method of patterning the polyside gate, a photosensitive film is coated on the tungsten silicide film 205, and then a photosensitive film pattern 209 is formed by exposure and development, and the photosensitive film pattern 209 is used as an etch mask. After etching the silicide 205 and the polysilicon 204, the photoresist pattern 209 is removed. In the present invention, the photoresist pattern 209 is left without being removed after etching.
이렇게, 감광막 패턴(209)이 잔류한 상태에서 포토다이오드를 형성하기 위한 이온주입마스크인 감광막 패턴(206)을 형성한다.Thus, the photosensitive film pattern 206 which is an ion implantation mask for forming a photodiode in the state which the photosensitive film pattern 209 remains is formed.
그 후, 고에너지 이온주입(207)을 실시함으로써 N형불순물층(208)을 형성한다.Thereafter, the high energy ion implantation 207 is performed to form the N-type impurity layer 208.
도면에는 도시되지 않았지만, 이후 저에너지 이온주입을 실시하여 N형불순물층(108) 상에 P형불순물층을 형성하므로써 핀드포토다이오드의 제조는 완료된다.Although not shown in the drawings, the manufacture of the pinned photodiode is completed by forming a P-type impurity layer on the N-type impurity layer 108 by performing low energy ion implantation.
본 발명에서와 같은 방법을 적용함으로써 일반적인 서브마이크론 기술과 동일한 공정을 사용할 수 있을 뿐만 아니라, 게이트 형성용 감광막 패턴(209)과 포토다이오드 형성용 감광막(206)을 포토다이오드 형성후 동시에 제거함으로써 공정도 1 스텝 줄일 수 있고, 포토다이오드 형성용 200keV 이상의 고에너지 이온주입 공정도 얼마든지 적용 가능하다.By applying the same method as in the present invention, not only the same process as in general submicron technology can be used, but also the process diagram by simultaneously removing the gate forming photoresist pattern 209 and the photodiode forming photoresist 206 after photodiode formation. One step can be reduced and a high energy ion implantation process of 200 keV or more for photodiode formation can be applied.
즉, 게이트 상부에 두꺼운 감광막 패턴(209)이 존재하기 때문에, 200KeV 이상의 이온주입에서도 게이트 하부의 채널로 이온이 침투되는 것을 방지할 수 있어이미지센서의 특성 열화를 방지할 수 있다.(도 2의 "B" 참조)That is, since the thick photosensitive film pattern 209 is present on the gate, it is possible to prevent ions from penetrating into the channel under the gate even with ion implantation of 200 KeV or more, thereby preventing deterioration of characteristics of the image sensor. See "B")
본 발명은 핀드포토다이오드 이외에 고에너지 이온주입만을 실시하여 형성된 PN 접합 포토다이오드 공정에서도 적용할 수 있고, 또한 기판은 에피층이 없는 상태에서도 적용할 수 있다.The present invention can be applied to a PN junction photodiode process formed by performing only high energy ion implantation in addition to the pinned photodiode, and the substrate can be applied even in the absence of an epi layer.
이렇듯, 본 발명의 기술 사상은 상기 바람직한 실시예에 따라 구체적으로 기술되었으나, 상기한 실시예는 그 설명을 위한 것이며 그 제한을 위한 것이 아님을 주의하여야 한다. 또한, 본 발명의 기술 분야의 통상의 전문가라면 본 발명의 기술 사상의 범위내에서 다양한 실시예가 가능함을 이해할 수 있을 것이다.As such, although the technical idea of the present invention has been described in detail according to the above-described preferred embodiment, it should be noted that the above-described embodiment is for the purpose of description and not of limitation. In addition, those skilled in the art will understand that various embodiments are possible within the scope of the technical idea of the present invention.
본 발명에서와 같은 방법을 적용함으로써 일반적인 서브마이크론 기술(Submicron Technology)과 동일한 공정을 사용할 수 있어서 수율 향상에 기여할 수 있을 뿐만 아니라, 감광막 스트립(strip) 공정 스텝을 한번 줄일 수 있는 등, 공정 단순화를 이룰 수 있다.By applying the same method as in the present invention, it is possible to use the same process as the general submicron technology, which not only contributes to the yield improvement, but also reduces the process of photosensitive film strip process once. Can be achieved.
또한, 포토다이오드 형성시 200KeV 이상의 고에너지 이온주입 공정도 얼마든지 적용 가능하여 제품의 제조공정 조건의 마진도 충분히 확보할 수 있다.In addition, the high energy ion implantation process of 200KeV or more can be applied when forming the photodiode, thereby ensuring sufficient margin of the manufacturing process conditions of the product.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100745596B1 (en) * | 2004-11-29 | 2007-08-02 | 삼성전자주식회사 | Image sensor and method for forming the same |
KR100898676B1 (en) * | 2002-07-18 | 2009-05-22 | 매그나칩 반도체 유한회사 | Method of forming mask for ion implantation in manufacturing of photo diode |
US9034742B2 (en) | 2013-10-04 | 2015-05-19 | Samsung Electronics Co., Ltd. | Method for fabricating semiconductor device |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100898676B1 (en) * | 2002-07-18 | 2009-05-22 | 매그나칩 반도체 유한회사 | Method of forming mask for ion implantation in manufacturing of photo diode |
KR100745596B1 (en) * | 2004-11-29 | 2007-08-02 | 삼성전자주식회사 | Image sensor and method for forming the same |
US7602034B2 (en) | 2004-11-29 | 2009-10-13 | Samsung Electronics Co., Ltd. | Image sensor and method for forming the same |
US9034742B2 (en) | 2013-10-04 | 2015-05-19 | Samsung Electronics Co., Ltd. | Method for fabricating semiconductor device |
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