KR20020010844A - A Covering Material for Steel-Frame Containing Perlite - Google Patents

A Covering Material for Steel-Frame Containing Perlite Download PDF

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KR20020010844A
KR20020010844A KR1020000044379A KR20000044379A KR20020010844A KR 20020010844 A KR20020010844 A KR 20020010844A KR 1020000044379 A KR1020000044379 A KR 1020000044379A KR 20000044379 A KR20000044379 A KR 20000044379A KR 20020010844 A KR20020010844 A KR 20020010844A
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soil
steel
perlite
coating materials
present
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KR1020000044379A
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Korean (ko)
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KR100388330B1 (en
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박재학
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박재학
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • C04B14/18Perlite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00525Coating or impregnation materials for metallic surfaces
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00577Coating or impregnation materials applied by spraying

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Building Environments (AREA)

Abstract

PURPOSE: Steel coating materials containing perlite, being harmless to the human, as a main component are provided for use construction fields demanding insulation, damp-proof, and sound absorbance. Also, the resultant coating materials prevent environmental pollution and have good workability. CONSTITUTION: The steel coating materials comprise 60-75vol.% of perlite, 20-30vol.% of inorganic binding materials containing sodium silicate, borax(Na2B4O7·10H2O) and earth mixed with yellow earth and sand soil in a weight ratio of 3.5 : 3.5 : 1, additives such as soil stabilizer. The resultant coating materials excluding harmful materials(asbestos, rock wool, etc.) for person are applied to ceilings and walls by spraying.

Description

퍼라이트를 함유한 철골 피복재{ A Covering Material for Steel-Frame Containing Perlite}Steel Covering Material Containing Perlite {A Covering Material for Steel-Frame Containing Perlite}

본 발명은 건축 및 토목 구조물의 미장재료인 철골 피복재에 관한 것으로, 보다 상세하게는 인체에 무해한 퍼라이트를 주재료로 구성하고 규산소다, 붕사 및 흙을 혼합하여 제조한 환경 친화적인 철골 피복재의 조성물에 관한 것이다.The present invention relates to a steel cladding material which is a plastering material for construction and civil engineering structures, and more particularly, to a composition of an environmentally friendly steel cladding material which is manufactured by mixing a ferrite which is harmless to the human body as a main material and mixing sodium silicate, borax and soil. will be.

가장 이상적인 건축자재로 알려져 있는 흙이 현대에 이르러서는 높은수축률과 팽창율로 인해 건축재로 사용될 경우 치수안정성을 보장할 수 없고 그 자체로는 강도가 약하며 시멘트나 다른 골재 등과 혼화성이 열악한 문제점, 화재의 위험성 및 현대적 감각에 맞지 않는다는 문제점이 있어 건축재로 사용하기를 기피하고 있다. 또한 시중에 시판되고 있는 피복재는 벤토나이트 등의 충진제나 전분, 페놀 수지, 펄프 등의 유기질 결합제 및 에멀젼 왁스, 황산반토, 폴리아크릴아마이드 등의 결합조재로 이루어진 것으로 고온이나 특히 습기가 많은 우절기에 사용될 때에는 처짐 물성을 만족시켜 주지 못하는 문제점이 있었고 강도, 단열성, 방음성 및 내화성 등이 낮다는 문제점 뿐만 아니라, 인체에 유해한 석면, 암면, 질석, 발포폴리스틸렌 등이 함유되어 있어 시공시 작업자의 피부와 접촉하는 경우 자극을 유발하여 인체에 유해한 결점이 있었다.Soil, known as the most ideal building material, can not guarantee dimensional stability when used as a building material due to its high shrinkage and expansion rate in modern times, its strength is weak in itself, and its miscibility with cement or other aggregates is poor. There is a problem that it does not fit the risk and modern sense, so it is avoided to be used as a building material. Commercially available coating materials are made of fillers such as bentonite, organic binders such as starch, phenol resins, and pulp, and bonding aids such as emulsion wax, alumina sulfate, and polyacrylamide. At the time, there was a problem that it could not satisfy sag properties, and low strength, heat insulation, sound insulation and fire resistance, as well as harmful asbestos, rock wool, vermiculite, and foamed polystyrene, etc. In case of irritation, there was a defect that is harmful to the human body.

본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위해 안출된 것으로, 본 발명자는 인체에 무해하며 경량인 퍼라이트(Perlite)를 주성분으로 하여 무기질 결합재 및 각종 첨가재를 혼합하여 철골 피복재를 제조하고, 제조된 철골 피복재를 건축 및 토목 구조물에 뿜칠하여 단열성과 이음새 없는 균일한 마감층이 조화를 이루어 내화, 열손실방지 및 결로방지에 우수한 효과가 있는 것을 확인하고 본 발명을 완성하게 되었다.The present invention has been made to solve the problems of the prior art as described above, the present inventors produce a steel cladding material by mixing an inorganic binder and various additives as a main component of harmless and lightweight Perlite (harm) The fired steel cladding was applied to the building and civil engineering structures to confirm that the thermal insulation and seamless uniform finish layer is in harmony, and thus has an excellent effect on fire resistance, heat loss prevention and condensation prevention.

결국, 본 발명의 목적은 퍼라이트를 포함한 철골 피복재를 제공하는 것이다.After all, it is an object of the present invention to provide a steel cladding comprising perlite.

본 발명의 다른 목적은 전기 철골 피복재의 가장 바람직한 조성을 제공하는 것이다.Another object of the present invention is to provide the most preferred composition of the electrical steel cladding.

제1도는 본 발명의 철골 피복재를 시공하는 순서도1 is a flow chart for constructing the steel cladding material of the present invention

제2도는 본 발명의 철골 피복재를 시공한 사진2 is a photograph of the steel cladding material of the present invention

♣ 도면의 주요 부분에 대한 부호의 설명 ♣♣ Explanation of symbols for the main parts of the drawing ♣

P1: 운반공정 P2: 기계설치공정P1: Transport Process P2: Machine Installation Process

P3: 작업장설치공정 P4: 바탕면 점검공정P3: Workplace Installation Process P4: Ground Surface Inspection Process

P5: 분사작업공정 P6: 완성검사공정P5: Spraying Process P6: Complete Inspection Process

이하, 본 발명을 보다 구체적으로 설명하기로 한다.Hereinafter, the present invention will be described in more detail.

본 발명의 목적을 달성하기 위한 건축 및 토목 구조물의 미장재료인 철골 피복재는 75∼60 부피%의 퍼라이트를 주성분으로 하여 30∼20부피%의 무기질 결합재 및 각종 첨가제를 혼합하여 제조되는 것을 특징으로 한다.Steel coating material, which is a plastering material for building and civil engineering structures, is manufactured by mixing 30 to 20% by volume of an inorganic binder and various additives based on 75 to 60% by volume of perlite as a main component to achieve the object of the present invention. .

상기에서, 무기질 결합재로는 규산소다, 붕사 및 흙을 사용하는 것이 바람직하고 그혼합비율은 3.5 : 3.5 : 1의 중량비인 것이 보다 바람직하며, 또한 흙은 황토흙 및 마사흙을 사용하는 것이 바람직하다.In the above, it is preferable to use sodium silicate, borax and soil as the inorganic binder, the mixing ratio is more preferably a weight ratio of 3.5: 3.5: 1, and the soil is preferably using ocher and martha soil. .

본 발명에서 퍼라이트는 내화, 단열, 흡음 및 결로방지에 효과를 주기 위해 사용하는 것으로, 마그마가 지표의 호수나 바다로 흘러들어 급속히 냉각되면서 내부에 휘발성분이 농집되어 생성된 비정질의 광물을 적절한 입도로 분쇄하여 1000℃ 이상의 고온에서 급속하게 가열·팽창시킨 초경량의 순수 무기소재의 퍼라이트를 사용하며 무독, 무균, 무취의 특성을 지닌 건축자재이다. 본 발명에서 사용되는 퍼라이트는 삼손사의 제품을 사용하였으며 물리적 특성은 표1에 그리고 화학적특성은 표2에 나타내었다.In the present invention, the perlite is used to effect the fire, heat insulation, sound absorption and condensation prevention, while the magma flows into the surface lake or the sea and rapidly cools, while volatile matter is concentrated inside the amorphous mineral produced at an appropriate particle size. It is a building material that is toxic, sterile, and odorless. Perlite used in the present invention was used as Samson's product and physical properties are shown in Table 1 and chemical properties in Table 2.

본 발명에서 사용하는 규산소다는 주식회사 일신화학사의 제품으로 탄산소다와 석영 가루를 융해하여 얻는 물질로 색깔은 희고 냄새가 없는 고체이고 긴급공사가 필요한 경우 시멘트의 급결성을 주기 때문에 첨가제로 사용하고 있고 내산 및 내화성이 우수하여 점결용 재료로 이용된다.Sodium silicate used in the present invention is a product obtained by melting soda carbonate and quartz powder as a product of Ilshin Chemical Co., Ltd. It is used as an additive because the color is white and odorless solid and gives cement quickness when emergency work is needed. It has excellent acid and fire resistance and is used as caking material.

붕사(硼砂)는 방부제, 소독제의 약품, 광학유리, 유약원료, 비누 향료, 도료의 원료로 사용되고 그 특성은 나트륨의 결정으로 흰색을 띠며 굳고 단단한 단사정계(單斜晶系)의 결정으로 천연으로는 온천의 침전물, 화산지대의 호소(湖沼)침전물에서 산출되며, 인공적으로는 다른 붕산염 광물이나 붕산에 탄산(炭酸)소다를 가하여 중화(中和)시켜 제조한다. 본 발명에서 사용하는 붕사의 비중은 1.69∼1.72, 경도는 2∼2.5 범위에 있고, 무색에서 백색, 반투명에서 불투명, 반자성 등의 특성을 갖고 용해도는 20℃의 온도에서 4.7g/100g H2O 이며 붕사를 물에 용해하였을 때 수용액은 강알칼리성을 나타낸다.Borax is used as a raw material for preservatives, disinfectants, optical glass, glazes, soaps, and paints. Is produced from hot spring sediment and volcanic lake sediment, and is artificially produced by adding sodium carbonate to other borate minerals or boric acid. Borax used in the present invention has a specific gravity of 1.69 to 1.72, hardness of 2 to 2.5, colorless to white, semitransparent to opaque, semimagnetic, and solubility at a temperature of 20 ° C. 4.7 g / 100 g H 2 O When borax is dissolved in water, the aqueous solution shows strong alkalinity.

흙은 원시시대부터 기초적인 건축원자재로 사용된 것으로 본 발명에서 사용하는 흙은 통상의 점토 뿐 아니라 황토흙 및 마사흙을 포함하는 넓은 의미의 흙을 의미한다. 황토는 가장 이상적인 천연소재의 건축자재로 불연제로 산화과정에서 발생하는 에너지는 인체에 독을 제거하는 유익한 작용을 하는 것으로 알려져 있으며 흙 미립자틈 속으로 바람이 통해서 환풍 기능을 한다.Soil has been used as a basic building material from the primitive age, and the soil used in the present invention means soil in a broad sense including not only ordinary clay but also ocher soil and martha soil. Ocher is the most ideal building material of natural materials. It is a nonflammable and the energy generated during the oxidation process is known to have a beneficial effect of removing poison from the human body.

이하 실시예에 의하여 본 발명을 보다 구체적으로 설명하고자 한다. 이들 실시예는 오로지 본 발명을 설명하기 위한 것으로, 본 발명의 요지에 따라 본 발명의 범위가 이들 실시예에 국한되지 않는다는 것은 당업계에서 통상의 지식을 가진 자에게 자명할 것이다.Hereinafter, the present invention will be described in more detail with reference to the following examples. These examples are only for illustrating the present invention, and it will be apparent to those skilled in the art that the scope of the present invention is not limited to these examples according to the gist of the present invention.

[실시예 1]Example 1

퍼라이트 75부피%와 규산소다, 붕사, 황토흙을 3.5 : 3.5 :1의 중량비로 혼합한 무기질 결합재를 20부피% 및 토양안정재 등의 첨가재를 연속식 교반기에 첨가하여 1시간 동안 교반한 후 제조된 철골 피복재를 스프레이 장치를 이용한 뿜칠로 건축물의 천장에 시공하였다.20 vol% of the inorganic binder mixed with 75% by volume of ferrite, sodium silicate, borax and ocher soil in a weight ratio of 3.5: 1, and additives such as soil stabilizer were added to a continuous stirrer and stirred for 1 hour. Steel cladding was applied to the ceiling of the building by spraying with a spray device.

[실시예 2]Example 2

퍼라이트를 70부피% 사용하고 규산소다, 붕사, 황토흙을 3.5 : 3.5 :1의 중량비로 혼합한 무기질 결합재를 25부피% 사용한다는 점을 제외하고는 실시예 1과 동일하게 시험하였다.The test was carried out in the same manner as in Example 1 except that 70 vol% of ferrite was used and 25 vol% of an inorganic binder mixed with sodium silicate, borax, and loess soil at a weight ratio of 3.5: 3.5: 1 was used.

[실시예 3]Example 3

무기질 결합재의 황토흙 대신 마사흙을 사용한다는 점을 제외하고는 실시예 2와 동일하게 시험하였다.The test was carried out in the same manner as in Example 2, except that marsa soil was used instead of the loess soil of the inorganic binder.

[실시예 4]Example 4

퍼라이트를 60부피% 사용하고 규산소다, 붕사, 황토흙을 3.5 : 3.5 :1의 중량비로 혼합한 무기질 결합재를 30부피% 사용한다는 점을 제외하고는 실시예 1과 동일하게 시험하였다.The test was carried out in the same manner as in Example 1 except that 60 vol% of ferrite was used and 30 vol% of an inorganic binder mixed with sodium silicate, borax, and loess soil at a weight ratio of 3.5: 3.5: 1 was used.

이상의 각 실시예로 제조된 철골 피복재의 성능을 평가하기 위하여 KS L 5113, ASTM E 605, ASTM E 736, KS F2271, ASTM E 937, KS F 2271에 의거하여 성능시험을 실시하였으며, 그 결과를 다음의 표 3에 나타내었다.In order to evaluate the performance of the steel cladding material prepared in each of the above examples, the performance test was conducted according to KS L 5113, ASTM E 605, ASTM E 736, KS F2271, ASTM E 937, KS F 2271, and the results are as follows. It is shown in Table 3.

또한 본 발명의 실시예에 의한 KS F 2805에 의거한 흡음실험 결과를 표4에나타내었다.In addition, the results of the sound absorption experiment based on KS F 2805 according to the embodiment of the present invention are shown in Table 4.

흡음율계수의 계산은 다음의 식을 이용하여 계산하였으며 본 발명에 의한 철골 피복재의 흡음율계수는 0.75를 나타내었다.The sound absorption coefficient was calculated using the following equation, and the sound absorption coefficient of the steel cladding material according to the present invention was 0.75.

NRC = (250Hz + 500 Hz + 1KHz + 2KHz) / 4NRC = (250Hz + 500 Hz + 1KHz + 2KHz) / 4

NRC는 Noise Reduction Coefficient의 약어로 주파수 250, 500, 1K, 2K일때 흡음계수의 산술평균값을 나타낸다.NRC stands for Noise Reduction Coefficient and represents the arithmetic mean of sound absorption coefficients at frequencies 250, 500, 1K, and 2K.

또한 실시예에 의한 철골 피복재의 내화구조 특성을 다음의 표5에 나타내었다.In addition, the fire resistant structure characteristics of the steel cladding according to the embodiment is shown in Table 5.

상기 표3, 4 및 5에서 알 수 있듯이, 본 발명의 제품은 내화성과 단열효과가 뛰어날 뿐만 아니라, 시공밀도와 접착강도 및 부식성이 매우 양호한 것으로 판명되었고 또한 미세한 원료가 균일하게 집속하여 흡음효과가 뛰어나 도심지의 소음 공해로부터 조용하고 쾌적한 주거공간을 보장받을 수 있게 되었다. 또한 퍼라이트가 적절한 입도로 분포되어 색감과 질감이 알맞게 조화를 이루며 착색이 자유롭고 마감처리 기눙이 뛰어나 시공면의 미적효과를 극대화 시킬 수 있게 되었다.As can be seen from Tables 3, 4 and 5, the product of the present invention is not only excellent in fire resistance and heat insulation effect, but also found to be very good in construction density, adhesive strength and corrosion resistance, and fine materials are uniformly focused to absorb sound effect. It is excellent and can guarantee a quiet and comfortable living space from the noise pollution of the downtown area. In addition, the perlite is distributed in an appropriate particle size, so that the color and texture are appropriately harmonized, and the coloring is free and the finishing technique is excellent to maximize the aesthetic effect of the construction surface.

이상에서 살펴본 바와 같이 본 발명에 의한 철골 피복재는 건물의 천장 및 벽의 단열, 내화, 결로방지제, 미장마감제 및 습식굴합 피복재로 사용할 수 있고 보일러실, 기계실, 공작실 등 소음이 발생하는 장소의 흡음제로도 유용하다. 또한 석면, 암면, 질석, 발포폴리스틸렌 등이 포함되어 있지 않아 건축물의 안전은 물론 환경공해를 유발할 요인이 적고 그 사용방법이 용이하여 작업성이 우수한 효과가 있다.As described above, the steel cladding material according to the present invention can be used as heat insulation, fireproofing, anti-condensing agent, plastering agent and wet-curing cladding material of ceiling and wall of a building, and as sound absorbing material in places where noise occurs in boiler room, machine room, workshop, etc. Also useful. In addition, asbestos, rock wool, vermiculite, foamed polystyrene, etc. are not included, so the safety of the building is less likely to cause environmental pollution, and the method of use is easy, and thus the workability is excellent.

Claims (3)

75∼60 부피%의 퍼라이트와 30∼20부피%의 무기질 결합재 및 각종 첨가재를 혼합하여 제조되는 것을 특징으로 하는 철골 피복재.A steel coating material, which is prepared by mixing 75 to 60 vol.% Of perlite, 30 to 20% by volume of an inorganic binder, and various additives. 제 1항에 있어서, 무기질 결합재로 사용하는 규산소다, 붕사 및 흙의 혼합비율은 3.5 : 3.5 : 1의 중량비로 구성되는 것을 특징으로 하는 철골 피복재.The steel cladding material according to claim 1, wherein the mixing ratio of sodium silicate, borax and earth used as the inorganic binder is comprised of a weight ratio of 3.5: 3.5: 1. 제 2항에 있어서, 흙은 황토흙 및 마사흙으로 구성되는 것을 특징으로 하는 철골 피복재.The steel cladding material according to claim 2, wherein the soil is composed of loess soil and martha soil.
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