KR20020005082A - Agricultural Chemicals Compusition for Prevention and Extermination of Anthracnose and Virosis - Google Patents
Agricultural Chemicals Compusition for Prevention and Extermination of Anthracnose and Virosis Download PDFInfo
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- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
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Abstract
Description
본 발명은 농작물 및 과수에 흔히 발병하는 탄저병 및 바이러스병(일명, 오갈병)을 예방 및 치료할 수 있는 농약조성물에 관한 것이다.The present invention relates to a pesticide composition capable of preventing and treating anthrax and virus diseases (aka, augal disease) commonly occur in crops and fruit trees.
탄저병은 토마토, 고구마, 사과, 복숭아, 딸기, 참외, 고추 등 육질이 많은 과실등에 생기는 병으로서 암갈색이나 황갈색의 반점이 생겨 썩어들어가는 병으로서, 흔히 보르도액을 살포하여 예방조치를 취하나 별다른 효과를 보지 못하고 있으며 일단 발병하면 치료되지 않는 것으로 알려져 있다.Anthrax is a disease caused by fleshy fruits such as tomatoes, sweet potatoes, apples, peaches, strawberries, melons, and red peppers. Dark brown or yellowish brown spots are rotted and decayed. It is known that once it develops, it is not cured.
한편, 바이러스병은 과수나 채소, 담배 등이 모종상태에서 발생하는 경우 까맣게 썩어들어가고 줄기와 잎이 시들게 되며 성장한 후에는 잎이 심하게 오그라들게 되는 병으로서 이러한 병이 발생하면 전염성이 강하여 한해 농사를 그르치는 예가 허다하다.On the other hand, virus disease is a disease in which fruit trees, vegetables, tobacco, etc. occur in the seedling state, which rots black, the stems and leaves become wilted, and after growth, leaves become severely decayed. There are many examples.
농민들은 이러한 병에 대비하기 위하여 여러 가지 농약을 살포하고 있으나 예방은 물론 전혀 치료효과를 보지 못하고 있으므로 현재로서는 탄저병과 바이러스병에는 특효약이 없는 것으로 알려져 있다.Farmers are spraying various pesticides in order to prepare for these diseases, but there are no effective drugs for anthrax and viral diseases since they are not prevented or treated at all.
현재까지 알려진 탄저병의 치료제로서는 코퍼 설페이트 베이직 수화제 (상표명: 네오보르도/영일화학), 옥시-프로수 화제 (상표명: 산도팡에이/동부한농), 가벤다 가스신 수화제 (상표명: 고추탄/ 동방아그로) 등이 알려져 있으나 치료효과는 미미하다. 또한 바이러스병의 치료제는 없고 예방차원에서 과수 및 농작물 보호를 해오고 있는 실정이다.The known therapeutic agents for anthrax are Copper Sulfate Basic Hydrating (trade name: Neo Bordeaux / Youngil Chem), Oxy-Prohydrating (trade name: Sandopangei / Eastern), Gabenda Gassin Hydrating (trade name: Capsicum / Oriental Agro) ) Is known, but the therapeutic effect is insignificant. In addition, there is no cure for viral diseases, and the situation is protecting fruit and crops as a preventive measure.
탄저병과 바이러스병이 예방 및 치료가 되지 않는 것은 그 발명원인을 규명하지 못한데 가장 큰 원인이 있다고 보며 다음으로는 현재까지 개발된 어떠한 농약도 이들 질병에 대해서는 별다른 효과를 거두지 못할 뿐만 아니라 예방 및 치료를 위한 조성물이 발견되지 못한 점도 지적될 수 있다. 그러므로 농민들은 탄저병이나 바이러스병이 발병하지 않기를 기원할 뿐 일단 발병이 되면 한해 농사의 전체를 포기할 수 밖에 없는 실정에 있다.The inability to prevent and treat anthrax and viral diseases is the most likely cause of the problem. The pesticides developed to date have no effect on these diseases as well as prevention and treatment. It can also be pointed out that no composition for was found. Therefore, farmers only hope that anthrax or viral diseases do not develop, but once they do, they have no choice but to give up the whole of farming.
본 발명자는 과수나 채소를 재배하는 농민들로부터 탄저병과 바이러스병에 효과가 있는 예방,치료제의 처방을 요청받고 현재 인체에 사용하는 의약품을 중심으로 하여 약제의 선택과 배합비를 십수년간 연구하고 실험해 본 결과 모든 농작물과 과수에 발생하는 탄저병과 바이러스병을 치료할 수 있을 뿐만 아니라 예방할 수 있는 약제를 찾아내기에 이른 것이다.The present inventors have been asked to prescribe preventive and therapeutic agents that are effective against anthrax and virus diseases from farmers who grow fruit or vegetables, and have studied and experimented with the selection and combination of drugs based on medicines currently used in humans. As a result, it is possible to cure not only anthrax and virus diseases that occur in all crops and fruit trees, but also to find preventable drugs.
본 발명을 상세하게 설명하면 다음과 같다.The present invention will be described in detail as follows.
본 발명의 조성물에 사용한 약제는 일반 의약품으로서 중금속이 함유된 일반농약과 달리 인체에 거의 무해하여 따라서 농약의 공해로부터 안전하다.The medicament used in the composition of the present invention is almost harmless to the human body, unlike general pesticides containing heavy metals as a general medicine, and thus is safe from pollution of pesticides.
본 발명에 의한 농약조성물은 3종의 약제로 조성되며 Diamino diphenyl sulfone(dapsone)을 유효성분으로 하는 설폰제를 기본으로하여 이에 설파제와 아미노글리코사이드(aminoglycoside)계 항생제가 혼합된다.The pesticide composition according to the present invention is composed of three kinds of medicaments, and is based on a sulfone agent having diamino diphenyl sulfone (dapsone) as an active ingredient.
본 발명의 농약조성물에 사용되는 Diamino diphenyl sulfone은 흔히 DDS라고도 하며 연쇄상 구균, 폐렴구균과 같은 미생물에 유효하며 결핵균과 나병균에 대하여 살균작용이 있는 것으로 알려저 있는 바, 분자구조는 아래와 같다.Diamino diphenyl sulfone used in the pesticide composition of the present invention is also known as DDS and effective for microorganisms such as Streptococcus and pneumococcus.
본 발명의 농약조성물에 사용되는 설파제는 Sulfamethoxazole 과 Trimethoprim을 유효성분으로 하는 협동작용성 혼합제제 또는 Norfloxacin을 유효성분으로 하는 약제로서, 전자는 세균에 대해서는 상승효과를 나타내며 급,만성기관지염, 폐렴, 후두염, 요도염, 장염 등에 사용되고 후자는 포도상구균속, 연쇄상구균속, 장구균, 폐렴구균, 대장균 등에 효과가 있는 것으로 알려져 있다.The sulfa agent used in the pesticide composition of the present invention is a co-operative mixed agent comprising Sulfamethoxazole and Trimethoprim as an active ingredient or a drug containing Norfloxacin as an active ingredient. The former has a synergistic effect against bacteria and has acute, chronic bronchitis, pneumonia and laryngitis. The latter is known to be effective for staphylococcus, streptococci, enterococci, pneumococci, and coliforms.
또한 아미노글리코사이드계 항생제는 스트렙토마이신(Streptomycin) 군에 속하는 황산 스트렙토마이신(Streptomycin sulfate) 또는 황산 가나마이신(Ganamycinsulfate)을 유효성분으로 하는 항생제로서 미생물의 단백합성 억제제이며 결핵균에 대하여 항균효과가 있는 것으로 알려져 있다.In addition, aminoglycoside antibiotics are antibiotics containing streptomycin sulfate or ganamycinsulfate as an active ingredient belonging to the group Streptomycin. Known.
본 발명에 의한 농약조성물은 Diamino dipheny1 sulfone을 유효성분으로 하는 설폰제와 Sulfamethoxazole 과 Trimethoprim 의 혼합물 또는 Norfloxacin을 유효성분으로 하는 설파제 및 황산 스트렙토마이신 또는 황산 가나마이신을 유효성분으로 하는 항상제가 20-30 : 35-50 : 25-40의 중량비(ｗ/ｗ%)로 조성되며, 보다 바람직하게는 설폰제 : 설파제 : 스트렙토마이신군 항생제가 23-27 : 36-47 : 28-36 의 중량비(ｗ/ｗ%)로 조성된다.The pesticide composition according to the present invention is a sulfonic agent containing diamino dipheny1 sulfone as an active ingredient, a mixture of Sulfamethoxazole and Trimethoprim, or a sulfa agent containing Norfloxacin as an active ingredient, and a antagonist containing streptomycin sulfate or kanamycin sulfate as an active ingredient. 35-50: 25-40 weight ratio (ｗ / ｗ%), and more preferably, the sulfon agent: sulfa agent: streptomycin group antibiotics 23-27: 36-47: 28-36 weight ratio (ｗ / ｗ%) %).
Norfloxacin을 유효성분으로 하는 제제와 황산 가나마이신을 유효성분으로 하는 제제는 Sulfamethoxazole 과 Trimethoprim을 유효성분으로 하는 제제 및 황산 스트렙토마이신을 유효성분으로 하는 제제에 비하여 고가의약품으로 경제성은 떨어지나 효능은 월등하다.The formulations containing Norfloxacin as an active ingredient and kanamycin sulfate as an active ingredient are more expensive than pharmaceuticals containing Sulfamethoxazole and Trimethoprim as active ingredients, and are more economically effective than the formulations containing streptomycin sulfate as an active ingredient.
본 발명에 의한 농약조성물은 제형이 수화제로서 물 20ℓ당 10-20ｇ을 첨가하여 사용하며 사용량은 평당 150~180㏄가 바람직하다. 사용량이 많으면 수화제가 흘러내려 약제의 손실이 발생하며 사용량이 불충분하면 충분한 예방 및 치료효과를 기대하기 어렵다. 사용시기는 발병 전,후 어느 때라도 무방하며 1회의 살포로 예방 및 치료가 이루어진다.살포방법은 농약분무기를 이용하여 발병한 과수나 채소의 잎사귀 전,후면에 고르게 분무한다.Pesticide composition according to the present invention is used as the formulation is added to 10-20g per 20L of water as a hydrating agent, the amount is preferably 150 ~ 180㏄ per pyeong. If the amount is large, the hydration flows down and the drug is lost. If the amount is insufficient, sufficient prevention and treatment effect is difficult. It can be used at any time before or after the onset, and is prevented and treated by one spray. Spraying method is sprayed evenly before and after the leaves of fruit trees or vegetables, which are caused by pesticide spraying.
본 발명자는 수많은 약제의 선택과 배합비의 조성, 배합으로 인한 약효의 상승작용을 시험한 결과 최적의 조성물 및 조성비를 얻게 되었는데 본 발명에 의한농약조성물이 과수 및 작물의 탄저병과 바이러스병(일명 오갈병)에 효과가 탁월한 이유는 밝혀지지 않고 있으나 조성성분들의 상호작용에 의한 상승효과에 의한 것으로 추측된다.The present inventors have obtained the optimum composition and composition ratio by testing the selection of a number of drugs, the composition of the composition ratio, and the effect of the combination. The pesticide composition according to the present invention is anthrax and virus diseases of fruit trees and crops. The reason why the effect is excellent is not known, but it is presumed to be due to the synergistic effect of the interaction of the components.
이하, 본 발명에 의한 농약조성물의 최적 조성비 및 약효를 다음의 실시예 및 시험예를 통하여 보다 상세히 설명한다. 그러나 본 발명이 이들 실시예 및 시험예에 국한되는 것은 아니다.Hereinafter, the optimum composition ratio and efficacy of the pesticide composition according to the present invention will be described in more detail through the following examples and test examples. However, the present invention is not limited to these examples and test examples.
< 실시예 1 ><Example 1>
※물 20ℓ에 첨가하는 양임※ The amount to add to 20ℓ of water
< 실시예 2 ><Example 2>
※물 20ℓ에 첨가하는 양임※ The amount to add to 20ℓ of water
< 시험예 1 > 사과탄저병에 대한 방제 및 예방효과<Test Example 1> Control and prevention effect on apple anthrax
사과가 숙성하여 당도가 증가할 무렵 탄저병이 발생한 이병과 20주를 1구로 하여 3반복으로 실시예 1의 용액을 평당 170㏄의 양으로 1회 살포하고 약제처리전을 100으로 하여 약제처리구와 대조구의 병반진행도를 2-3일 간격으로 육안관찰하였는 바, 이병과에 대한 탄저병의 병반진행이 중단되었고 그후 전혀 투약하지 아니하였어도 탄저병이 재발되지 아니하므로 본 조성물은 탄저병의 치료는 물론 예방에도 탁월한 효과가 있음을 알수 있었다. 시험결과는 표1에 나타내었다.At the time of ripening of the apples and the increase in the sugar content, two bottles of anthrax and 20 strains were used in three portions, and the solution of Example 1 was sprayed once at an amount of 170 평 / 평 and 100 before treatment. Visually observed the progress of the disease at 2-3 days intervals, the progress of the anthrax disease to the etiology was stopped and the anthrax disease did not recur even if not administered at all, so the composition is excellent for treating and preventing anthrax. It was found to be effective. The test results are shown in Table 1.
표 1. 사과 이병과의 탄저병반 진행도 (단위:%)Table 1. Progression of Anthrax Class with Apple Blight (Unit:%)
< 시험예 2 > 참외 바이러스병에 대한 방제 및 예방효과<Test Example 2> Control and prevention effect on melon virus disease
비닐하우스의 참외 모종에 바이러스병이 번져 모종이 시들고 일부는 마르는 현장에 임하여 확인한 결과 뿌리가 까맣게 썩어가고 있었다.The virus was spreading on the melon seedlings of the plastic house, so that the seedlings were wilted and some were dried.
실시예1 및 실시예2의 조성물 용액을 하우스마다 구분하여 바이러스병에 걸린 참외 모종 20주를 1구로 하여 3반복으로 실시예1 및 실시예2의 조성물 용액을 1회 살포한 후 3일후 육안관찰에 의하여 회생율을 조사한 결과 참외 이병주가 회생되었는 데 그 시험결과를 표2에 나타내었다.The composition solutions of Example 1 and Example 2 were separated for each house, and 20 weeks of melon seedlings with virus disease were used in three spheres, and the composition solution of Example 1 and Example 2 was sprayed once, and then visually observed after 3 days. As a result of examining the recovery rate, the melon byeongju was recovered. The test results are shown in Table 2.
표 2. 참외 바이러스 이병모종의 회생율 (단위 : %)Table 2. Regeneration rate of melon virus disease seedlings (unit:%)
< 시험예 3 > 담배 오갈병에 대한 방제 및 예방효과<Test Example 3> Control and prevention effect on tobacco leg disease
담배의 성장기에 오갈병이 발생하여 담배잎이 쭈그러지고 말리는 현장에 임하여 이병엽 20주를 1구로 하여 3 반복으로 실시예 1 및 실시예 2의 조성물 용액을 각각 별도로 살포하고 8일이 경과한 후 육안관찰에 의해 이병엽의 회생율을 조사한 결과 80% 정도의 이병엽이 정상으로 회복되었는 데 시험결과는 표3에 나타내었다.During the growing season of tobacco, the leaves of the tobacco are crushed and dried. On the spot where 20 leaves of Lee Byeong-yeop were used as 1 sphere, the composition solution of Example 1 and Example 2 was sprayed separately, and visual observation was observed after 8 days. As a result of examining the regeneration rate of Lee Byung-yeop, 80% of Lee Byung-yeop was restored to normal. The test results are shown in Table 3.
표 3. 담배 오갈병 이병엽의 회생율 (단위 : %)Table 3. Regeneration Rate of Tobacco Lactobacillus Lee Byung-yeop
< 시험예 4 > 고추 탄저병에 대한 방제 및 예방효과<Test Example 4> Control and prevention effect of pepper anthrax
탄저병이 10%, 20%, 60% 및 80% 발생한 고추 이병과 20주를 각각 1구로 총 4구에 대하여 실시예 1의 용액을 평당 170㏄의 양으로 1회 살포하고 4일후 약제처리전을 0으로 하여 약제처리구와 대조구의 회생율을 육안관찰하였는 바, 고추 이병과의 탄저병의 진행이 중단되면서 고추가 정상으로 회복되었다. 이미 발병상태가 심한 고추의 이병과는 회복되지 않았으나 발병초기의 이병과는 발병이 중단되었고 발병되지 아니한 고추에는 더 이상 발병되지 않았다.1 bottle of red pepper disease and 20 weeks of 10%, 20%, 60%, and 80% of anthrax were sprayed once with the solution of Example 1 at a dose of 170㏄ / 평 for 4 balls. The regeneration rate of the treatment and control group was visually observed at 0, and the red pepper was restored to normal as anthrax progressed. The disease did not recover from the disease, but the disease did not recover from the disease.
표 4. 고추 탄저병 이병과의 회생율 (단위 : %)Table 4. Regeneration Rate of Red Pepper Anthrax Disease (Unit:%)
이상의 시험예에서 알 수 있는 바와 같이, 본 발명의 조성물은 농작물의 탄저병 및 바이러스병의 치료 및 예방에 뛰어난 효과를 나타내며 일반 농약에 비하여 가격은 비싸나 1회의 살포만으로 소기의 효과를 거둘 수 있으므로 농약살포에 소요되는 인력이 절감되고 전체적인 살포량이 감소되는 경제성을 가진다.As can be seen in the above test example, the composition of the present invention exhibits an excellent effect on the treatment and prevention of anthrax and virus diseases of crops and pesticide spraying because it is expensive compared to general pesticides but can achieve the desired effect by only one spraying. It is economical that manpower is reduced and overall spreading amount is reduced.
더욱이, 본 발명의 조성물은 중금속을 함유하지 아니한 의약품으로 조성되므로 농약공해를 피할 수 있으며 효과가 탁월하여 농사의 병충해를 획기적으로 구제할 수 있게 될 것이다.In addition, the composition of the present invention is composed of a drug that does not contain heavy metals can avoid pesticide pollution and excellent effect will be able to remedy the pests of farming.
Claims (3)
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| KR100771530B1 (en) * | 2005-02-12 | 2007-10-30 | 서화수 | Agricultural Chemicals Composition for Prevention and Extermination of Anthracnose and Virosis |
| CN103548908A (en) * | 2013-09-26 | 2014-02-05 | 崔孟镐 | Pesticide composition for preventing anthracnose and virosis |
| WO2014038914A1 (en) * | 2012-09-10 | 2014-03-13 | Suh Hwa Soo | Agrichemical composition for preventive treatment for anthracnose disease and viral disease |
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| WO2014038914A1 (en) * | 2012-09-10 | 2014-03-13 | Suh Hwa Soo | Agrichemical composition for preventive treatment for anthracnose disease and viral disease |
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