KR20020000613A - Ascon manufacturing method with abandoned - Google Patents
Ascon manufacturing method with abandoned Download PDFInfo
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- KR20020000613A KR20020000613A KR1020000035422A KR20000035422A KR20020000613A KR 20020000613 A KR20020000613 A KR 20020000613A KR 1020000035422 A KR1020000035422 A KR 1020000035422A KR 20000035422 A KR20000035422 A KR 20000035422A KR 20020000613 A KR20020000613 A KR 20020000613A
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- waste lime
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- asphalt
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/12—Waste materials; Refuse from quarries, mining or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/04—Heat treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
Description
본 발명은 아스콘의 제조방법에 관한 것으로, 더욱 상세하게는 폐기 및 처리가 어렵고 환경오염을 가중시키는 폐석회를 아스콘을 제조하는데 재활용할 수 있도록 한 폐석회를 이용한 아스콘의 제조방법에 관한 것이다.The present invention relates to a method for producing ascon, and more particularly, to a method for producing ascon using waste lime that can be recycled to produce ascon waste lime that is difficult to dispose and processing, and adds environmental pollution.
일반적으로 폐석회는 소다회 및 벤토나이트, 백시멘트 등을 생산하는 과정에서 발생되는 부산물로서 년간 250만톤에 달하고 있다. 이렇게 막대한 량으로 발생되는 폐석회는 현재 재활용되지 못하고 전량 매립하고 있어 이의 처리 및 폐기가 심각한 실정에 있으며, 그 매립된 폐석회는 토양오염이나 침출수의 유출로 인해 수질 및 환경을 크게 오염시킬 뿐만 아니라 일단 상기 폐석회로 오염된 토양은 복원이 불가능하므로 이에 대한 대책이 시급하다.In general, waste lime is a by-product generated in the production of soda ash, bentonite, and white cement, which amounts to 2.5 million tons per year. The waste lime generated in such a large amount is not recycled at present and is completely buried, so its disposal and disposal is serious. The landfilled lime lime not only significantly pollutes the water quality and the environment due to soil pollution or leachate discharge. Once the soil contaminated with the waste-rock can not be restored, it is urgent to take measures against this.
이에 따라 근래에는 상기한 바와같은 문제점을 해결하기 위해서 화학처리 방법이 제안된 바 있으나, 이는 부지확보 및 설비투입, 운용에 따른 막대한 비용으로 영세하고 정부의 지원이 전무한 상태인 우리의 대부분 폐석회 배출업체에서는 현실적으로 적용이 거의 불가능할 뿐만 아니라 어쩔 수 없이 환경법을 위반해가면서 계속해서 막대한 량으로 배출되는 폐석회를 땅에 매립할 수 밖에 없는 실정에 있다.Therefore, in recent years, a chemical treatment method has been proposed to solve the above problems, but most of our waste lime discharges are very small and have no governmental support due to the site cost, facility input and operation. In reality, companies are not only able to apply practically, but they are forced to bury the waste lime which is discharged in huge quantities continuously while violating environmental law.
한편, 아스콘 제조시에는 채움재로써 탄산칼슘, 즉 고가의 석회석분이 요구된다. 이에 따라 아스콘 제조업체에서는 상기 석회석분의 구입에 따른 비용부담으로 불량 식회석분을 구입해 사용하거나 정량투입하지 않고 아스콘을 제조하는 경우가 많아 도로포장의 부실시공을 초래하는 문제점이 있었다.On the other hand, when manufacturing ascon, calcium carbonate, that is, expensive limestone powder, is required as a filler. As a result, ascon manufacturers often use as a cost burden for the purchase of the limestone powder to produce ascon without purchasing or using poorly fed limestone powder.
이에 본 발명은 상기한 바와같은 종래의 제반 문제점을 해소하기 위해서 창안된 것으로, 그 목적은 막대한 량으로 배출되면서 이의 폐기 및 처리가 어려워 환경오염의 주요인으로 작용하는 폐석회를 공해없이 처리하여 아스콘의 원료로 재활용할 수 있도록 하는데 있다. 본 발명의 다른 목적은 아스콘을 보다 저렴하게 제조할 수 있도록 하여 도로포장의 부실시공을 방지할 수 있도록 하는데 있다.Therefore, the present invention was devised to solve the conventional problems as described above, the purpose of which is to discharge the enormous amount of the waste lime, which is a major factor of environmental pollution because it is difficult to dispose and process the pollution of ascon It is to be recycled as a raw material. Another object of the present invention is to be able to manufacture ascon cheaper to prevent the secondary pavement of the road pavement.
이러한 본 발명의 목적을 달성하기 위하여 폐석회를 1000℃ 이상의 고온에서 가열하여 함유된 일산화탄소분을 제거하여 백색의 분말형태로 된 채움재를 얻는 제1공정과; 상기 채움재를 140∼160℃의 온도에서 아스팔트와 혼합하여 혼합물을 얻는 제2공정과; 상기 혼합물에 ψ19mm 이하로 분쇄되는 돌과 석분 및 모래를 혼합하는 제3공정으로 이루어진 것을 특징으로 한 폐석회를 이용한 아스콘의 제조방법이 제공된다.In order to achieve the object of the present invention and the waste lime is heated at a high temperature of 1000 ℃ or more to remove the carbon monoxide content contained in the first step of obtaining a filler in the form of a white powder; A second step of mixing the filler with asphalt at a temperature of 140 to 160 ° C. to obtain a mixture; There is provided a method for producing ascon using waste lime, which comprises a third step of mixing stone, stone powder, and sand which are pulverized to ψ19 mm or less in the mixture.
이하 본 발명에 의한 아스콘의 제조방법을 공정별로 좀더 상세히 설명하면 다음과 같다.Hereinafter, a method of manufacturing ascon according to the present invention will be described in more detail by processes.
제1공정1st process
이 공정은 수거된 폐석회를 아스콘의 채움재로써 사용할 수 있도록 백색의 분말 형태로 가공하는 공정으로서, 최초 수거된 폐석회는 집진장치가 되어 있는 고온의 회전가마 내부에 투입된다. 이 투입된 폐석회는 1000℃ 이상의 고온으로 가열되고, 이 가열로 폐석회 자체에 함유된 미연소의 일산화탄소분이 완전연소 및 제거됨으로써 325메쉬(mesh)의 고운 백색 분말형태의 채움재를 얻을 수 있게 되는 것이다.This process is to process the collected waste lime into a white powder form to be used as a filling material for ascon, the first collected waste lime is put into the hot rotary kiln as a dust collector. The injected waste lime is heated to a high temperature of 1000 ° C. or more, and thus, the unburned carbon monoxide content contained in the waste lime itself is completely burned and removed, thereby obtaining a fine white powder form of 325 mesh.
제2공정2nd process
이공정은 제1공정에서 얻어진 채움재에 아스콘의 주원료가 되는 아스팔트를 투입하여 혼합시키는 공정이다. 이렇게 상기 아스팔트를 투입하여 혼합함에 있어, 140℃ 이하이면 아스팔트가 쉽게 고화되어 혼합이 잘이루어지지 않는 반면에, 160℃ 이상이면 아스팔트가 열에 의해 쉽게 입자분리가 이루어져 겔(G디) 상태가 아닌 액체화가 되어 혼합이 잘않되므로 이를 고려해야만 된다.This step is a step of mixing by mixing asphalt, which is the main raw material of ascon, to the filler obtained in the first step. When the asphalt is added and mixed in this way, when the temperature is 140 ° C. or less, the asphalt is easily solidified and difficult to mix. On the other hand, when the temperature is 160 ° C. or more, the asphalt particles are easily separated by heat, thereby liquefying the gel (G-D). This is not mixed well, so you have to consider this.
제3공정3rd process
이공정은 제2공정에서 얻어진 혼합물에 ψ19mm 이하로 분쇄된 돌과, 돌을 분쇄하는 과정에서 발생되는 석분과 모래를 혼합하여 일련의 아스콘 제조를 완료하는 공정으로서, 이의 충분한 혼합 및 교반을 위해 믹싱플랜트 믹서가 사용된다.This process is to complete the series of ascon production by mixing the stone crushed to φ19mm or less with the mixture obtained in the second process and the stone powder and sand generated in the process of crushing the stone, and mixing for sufficient mixing and stirring thereof. Plant mixers are used.
다음은 상기한 바와같은 공정에 의해서 제조되는 본 발명에 의한 아스콘 제조방법을 실시예에 따라 상세히 설명한다.Next, the ascon production method according to the present invention manufactured by the process as described above will be described in detail according to the embodiment.
실시예 1Example 1
상기와 같이 처리된 폐석회 144g과 아스팔트(AP-3)198g을 150℃로 가열하면서 서서히 교반시켜 완전히 혼합시키고 같은 온도에서 직경19mm 이하의 분쇄된 돌을 1238g, 돌을 분쇄하는 과정에서 생긴 석분 1694g, 고운모래 326g을 혼합하여 충분히 혼합시켰다.144 g of waste lime treated as described above and 198 g of asphalt (AP-3) were heated to 150 ° C. and slowly mixed to complete mixing. 1238 g of crushed stone having a diameter of 19 mm or less at the same temperature, and 1694 g of stone powder produced in the process of crushing stone 326 g of fine sand were mixed and mixed well.
상기 혼합물을 내경101.6mm, 높이 76.2mm의 원통형 형틀에 장입시키고 해머로 양면 50회를 다진 다음 상온까지 방냉한 후 형틀에서 분리하여 꺼내고 60℃(±1℃)의 항온 수조에 투입 30분간 침지후 안정도 시험을 행하였다.The mixture was charged into a cylindrical mold having an inner diameter of 101.6 mm and a height of 76.2 mm, chopped on both sides with a hammer and chopped 50 times, cooled to room temperature, separated from the mold, and removed from the mold and immersed in a constant temperature water bath at 60 ° C. (± 1 ° C.) for 30 minutes. A stability test was done.
실시예 2Example 2
아스팔트 216g, 폐석회 144g, 직경이 19mm 이하의 분쇄된 돌 1231g 돌을 분쇄하는 과정에서 생긴 석분 1685g, 모래 324g을 사용하여 상기 실시예 1에서와 같이 제조하여 시험을 행하였다.216 g of asphalt, 144 g of waste lime, 1231 g of crushed stone having a diameter of 19 mm or less were prepared and tested in the same manner as in Example 1, using 1685 g of stone powder and 324 g of sand produced during the grinding process.
상기 실시예에서 사용된 재료의 성분 비율을 비교하면 다음의 표 1과 같다.Comparing the component ratio of the material used in the above embodiment is shown in Table 1 below.
[표 1]단위: % [Table 1] Unit:%
상기 표의 배합비율에 의하여 제조된 시료의 시험결과를 하기의 표 2에 나타내었다.The test results of the samples prepared according to the mixing ratios of the tables are shown in Table 2 below.
[표 2]TABLE 2
상기 표 2에서 나타낸 수치는 마샬시험(KSF 2337)에 의한 실험결과 아스팔트 5.5%인 경우(제1실시예)와 아스팔트가 6.0%인 경우(제2실시예) 모두 KS기준치를 상회하거나 비슷한 정도로서 좋은 결과가 얻어졌다.The numerical values shown in Table 2 are better than or equal to the KS standard value when the results of the Marshall test (KSF 2337) are 5.5% asphalt (first example) and 6.0% asphalt (second example). The result was obtained.
이와같은 상기한 실시예에서 얻어진 본 발명에 의한 아스콘과 종래에서와 같이 채움재로서 석회석분을 사용하여 아스콘을 제조하여 그 성능을 비교하여 보았다.Ascon according to the present invention obtained in the above-described examples and ascon was prepared using limestone powder as a filler as in the prior art and compared the performance thereof.
아스팔트 216g, 채움재로서 탄산칼슘 144g, 19mm 이하의 분쇄된 돌 1231g, 돌을 분쇄하는 과정에서 발생하는 석분 1685g, 모래 324g을 종래의 아스콘 제조방법에 의하여 시료를 제조하여 상기에서와 같은 방법에 의하여 시험하여 보았다.216 g of asphalt, 144 g of calcium carbonate as a filler, 1231 g of crushed stone of 19 mm or less, 1685 g of stone powder generated in the process of crushing the stone, and 324 g of sand were prepared by the conventional ascon production method, and tested by the same method as described above. I saw it.
상기 실시예 2 및 종래의 아스콘과의 성분비를 대비하면 다음의 표 3과 같다.In comparison with the component ratio of Example 2 and the conventional ascon is as Table 3 below.
[표 3]단위: % [Table 3] Unit:%
상기 표의 배합비율에 의하여 제조된 시료의 시험결과를 하기의 표 4에 나타내었다.The test results of the samples prepared according to the mixing ratios of the tables are shown in Table 4 below.
[표 4]TABLE 4
상기 표 4에서 나타낸 수치는 표 3의 성분비에 의한 시험결과로서 채움재를 폐석회 4%로 사용하는 경우(실시예 2)와 탄산칼슘 4%로 사용하는 경우(비교예)를 대비하여 거의 같은 결과로 나타남을 볼 수 있다.The numerical values shown in Table 4 are almost the same as the test results based on the component ratios of Table 3 in comparison with the case where the filler is used at 4% of waste lime (Example 2) and when the sample is used at 4% of calcium carbonate (Comparative Example). It can be seen as.
상술한 바와같이 본 발명은 년간 막대한 량으로 배출되면서 이의 폐기 및 처리가 어려워 전량 매립되어 수질 및 환경을 크게 오염시켰왔던 폐석회를 자원화하여 아스콘의 제조원료로 재활용할 수 있도록 함으로써 상기 폐석회의 폐기 및 처리에 따른 비용을 상당히 절감할 수 있는 효과를 갖게 될 뿐만 아니라 매립에 따른 수질 및 환경오염을 해소할 수 있는 효과가 있다.As described above, the present invention disposes and recycles waste lime, which is recycled as a raw material of ascon, by recycling waste lime, which has been largely landfilled and greatly contaminated water quality and environment while being discharged in huge amounts for years. It not only has the effect of significantly reducing the cost of treatment, but also has the effect of eliminating water pollution and environmental pollution caused by landfill.
또한 아스콘 제조시 고가의 석회석분 대신에 가격이 상당히 저렴하면서도 그 물리적인 특성, 즉 밀도, 안정도, 공극율, 포화도 등의 특성면에서도 기존의 아스콘보다 우수한 효과를 나타내는 폐석회를 사용함으로써 아스콘 제조원가를 현저하게 낮출 수 있을 뿐만 아니라 이로인해 환경오염 방지와 아스콘의 제조원가 절감의 이중의 효과를 얻을 수 있는 이점이 있다.In addition, the cost of ascon production is remarkable by using waste lime, which is significantly cheaper in the manufacture of ascon instead of expensive limestone powder, which has superior effect to conventional ascon in terms of physical properties such as density, stability, porosity, and saturation. Not only can it be lowered, but it also has the advantage of achieving the dual effect of preventing environmental pollution and reducing the manufacturing cost of ascon.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100486413B1 (en) * | 2002-10-14 | 2005-05-03 | 한국건설기술연구원 | Asphalt mixture using by-product waste lime and manufacturing method thereof |
KR100727293B1 (en) * | 2002-03-29 | 2007-06-12 | 기근서 | Packaging container with contents mixing structure |
KR20190009734A (en) | 2016-05-19 | 2019-01-29 | 요하치 야마시타 | Ultrasonic Irradiation Apparatus and System and Ultrasonic Irradiation Method |
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JPH07313950A (en) * | 1994-05-27 | 1995-12-05 | Mitsubishi Materials Corp | Granular material made from waste and waste treatment method |
KR960011331A (en) * | 1994-09-19 | 1996-04-20 | 사토 후미오 | Air conditioner |
KR19980076866A (en) * | 1997-04-11 | 1998-11-16 | 서승석 | A method of manufacturing ascon by recycled sand using only waste instead of sand used for manufacturing ascon |
KR19990003732A (en) * | 1997-06-17 | 1999-01-15 | 최세균 | High-strength material manufactured by processing agricultural vinyl, non-recyclable plastic and waste stone |
KR19990031805A (en) * | 1997-10-14 | 1999-05-06 | 강창우 | Lightweight Building Material Using Waste Lime |
-
2000
- 2000-06-26 KR KR1020000035422A patent/KR20020000613A/en not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07313950A (en) * | 1994-05-27 | 1995-12-05 | Mitsubishi Materials Corp | Granular material made from waste and waste treatment method |
KR960011331A (en) * | 1994-09-19 | 1996-04-20 | 사토 후미오 | Air conditioner |
KR19980076866A (en) * | 1997-04-11 | 1998-11-16 | 서승석 | A method of manufacturing ascon by recycled sand using only waste instead of sand used for manufacturing ascon |
KR19990003732A (en) * | 1997-06-17 | 1999-01-15 | 최세균 | High-strength material manufactured by processing agricultural vinyl, non-recyclable plastic and waste stone |
KR19990031805A (en) * | 1997-10-14 | 1999-05-06 | 강창우 | Lightweight Building Material Using Waste Lime |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100727293B1 (en) * | 2002-03-29 | 2007-06-12 | 기근서 | Packaging container with contents mixing structure |
KR100486413B1 (en) * | 2002-10-14 | 2005-05-03 | 한국건설기술연구원 | Asphalt mixture using by-product waste lime and manufacturing method thereof |
KR20190009734A (en) | 2016-05-19 | 2019-01-29 | 요하치 야마시타 | Ultrasonic Irradiation Apparatus and System and Ultrasonic Irradiation Method |
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