KR20010087815A - Oil Manufacture System by Used Plastic - Google Patents

Oil Manufacture System by Used Plastic Download PDF

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Publication number
KR20010087815A
KR20010087815A KR1020010034196A KR20010034196A KR20010087815A KR 20010087815 A KR20010087815 A KR 20010087815A KR 1020010034196 A KR1020010034196 A KR 1020010034196A KR 20010034196 A KR20010034196 A KR 20010034196A KR 20010087815 A KR20010087815 A KR 20010087815A
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KR
South Korea
Prior art keywords
heating
waste plastics
raw materials
kerosene
temperature
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KR1020010034196A
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Korean (ko)
Inventor
김동준
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김동준
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Application filed by 김동준 filed Critical 김동준
Priority to KR1020010034196A priority Critical patent/KR20010087815A/en
Publication of KR20010087815A publication Critical patent/KR20010087815A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

PURPOSE: Provided is a system to produce gasoline and kerosene and other crude raw materials from thermoplastics such polyethylene, polyvinyl chloride, polystyrene, polypropylene, nylon and waste plastics from home and industry. CONSTITUTION: The system and the manufacturing process comprise: drying and pulverizing waste plastics into the size of 1cm; heating them at 220-300deg.C in heating vessel (1a) and generating gases with emulsifying agents of Y-NH+4 type for pyrolysis; cooling the gas to 54deg.C through condensing equipment (3a) to get crude oil and heating with emulsifying agents of Y-NH+4 type in the reactor to produce gasoline, diesel and kerosene according to each temperature. This temperature is controlled by cooling fan (7) and the system is run under atmospheric pressure without many moving parts and raw materials is fed to input entrance (5) with dust collection equipment (1b).

Description

폐 플라스틱을 이용한 원유 제조 시스템 {Oil Manufacture System by Used Plastic}Oil manufacturing system using waste plastics {Oil Manufacture System by Used Plastic}

본 발명은 플라스틱류의 모든 석유(원유) 원소인 C·H 두개원소로 합성된 고분자 화합물로써 석유 중 탄소(C)는 84~85%, 수소(H)는12~14% 정도가 함유 되어 있으며 이를 사용하는 용도가 다양하나 크게 나눈다면 두 분류로 나눌 수 있겠다.The present invention is a polymer compound synthesized from two C · H elements, all petroleum (petroleum) elements of plastics, containing 84 to 85% of carbon (C) and 12 to 14% of hydrogen (H). There are many uses for this, but it can be divided into two categories.

첫째는 열가소성 플라스틱인 폴리에틸렌(Polyethlene), 폴리명화비닐(Pvc), 폴리스티렌(Polystrene), 폴리프로필렌(Polypropylene), 나이론(Nylon) 등등이며,First is thermoplastic plastics such as Polyethlene, Polyvinyl Pvc, Polystyrene, Polypropylene, Nylon, etc.

둘째는 열경화성 플라스틱인 에폭시(Epoxy) 수지, 페놀알레히드(Phenolic Aldenhyde), 불능화 폴리 에스테르(Polyester)등을 들 수 있다.Second, thermosetting plastics such as epoxy resin, phenol aldehyde (Phenolic Aldenhyde), disable polyester (Polyester) and the like.

본 발명 시스템은 열가소성 플라스틱류를 분쇄하여 직접 증류 및 열화등의 가공을 걸쳐 가솔린, 경유, 등유와 플라스틱 원료, 화학 섬유 등을 물질불멸의 원리를 이용하여 재 생산을 이루러 낼 수 있다.The system of the present invention can achieve the production of gasoline, diesel, kerosene and raw materials of plastics, chemical fibers and the like through the process of direct distillation and deterioration by grinding the thermoplastics using the principle of material immortality.

본 발명의 목적은 현재 플라스틱류를 생산하여 사용 용도를 다한 플라스틱류는 재활용을 하고 있다. 그러나 재활용 이후 처리에 있어서 소각이나 매립 등의 방법으로 처리하고 있는바 이를 재처리 하여 환경을 보호하고 원료에너지로 재활용하는 목적에 있다.It is an object of the present invention to produce plastics and recycle plastics that have finished their use. However, in the post-recycling process, it is treated by incineration or landfill, and this is to reprocess it to protect the environment and recycle it as raw material energy.

도면은 본 발명의 생산 설비 표시도로써 1a와 2a는 열화 가마이고. 3a는 응결기구이며, 4는 원유 탱크, 5는 원료 주입기, 1b는 고온 자동 집진기, 6은 믹서기, 7은 냉각 FAN이다.The drawings show the production equipment of the present invention 1a and 2a are deteriorating kilns. 3a is a condensation mechanism, 4 is a crude oil tank, 5 is a raw material injector, 1b is a high temperature automatic dust collector, 6 is a blender, and 7 is a cooling fan.

상기의 목적을 달성하기 위해 플라스틱류를 건조와 함께 1Cm이내 크기로 분쇄(가열 에너지를 줄이기 위함)하여 열화 반응 가마(1a)에 최화제(Y-NH+ 4계열)와 함께 넣어 220~300℃로 가열을 하면 분해 작용이 일어나면서 나타나는 혼합 기체가 발생되는데 이를 응결기구(3a)를 통해 섭씨54℃ 이내로 냉각을 시키면 원유로 변환되고 이를 분류 반응가마(2a)에 최화제(Y-NH+ 4계열)를 넣고 가솔린, 경유, 등유 분류 점(분류 온도와 평균 분자량이 같지 않음)에 이르도록 가열을 하면 가솔린, 디젤, 석유등으로 분류된다.In order to achieve the above purpose, the plastics are dried and pulverized to a size within 1 cm (to reduce heating energy) and put together with the minimizing agent (Y-NH + 4 series) in a deterioration reaction kiln (1a) at 220-300 ° C. When heated to, it generates a mixed gas which occurs as decomposition occurs, and when it is cooled to within 54 ° C through the condensation mechanism (3a), it is converted into crude oil and converted into crude oil (Y-NH + 4). And the gas is heated to reach the gasoline, diesel, and kerosene fractionation points (classification temperature and average molecular weight are not the same).

분류 온도는 냉각 FAN(7)으로 조정이 가능하며, 본 시스템은 평상 기압설비로써 무 기압차를 이용하며 기계 전동 부분이 적고 고온 자동 집진기(1b)와 연속 원료 주입기(5)로 주입하므로 안정성과 효율성이 높으며 설비 전체가 밀폐형이므로 제2차 오염(대기 오염, 악취)과 산·알카리등 참여 반응이 없고 화학 부식성이 적은 특징이다.The sorting temperature can be adjusted by the cooling fan (7). This system uses the pressure difference as a normal air pressure facility. As it is highly efficient and the entire facility is hermetic, it does not have secondary reactions (air pollution, odor), acid, alkali, etc.

전술한 기술 내용으로부터 자명하듯이, 본 발명의 연료 제조 시스템은 매장 시 부식 또는 분해로 인해 토양 및 수질오염을 유발하고 직접 연소 시 HCL, HCN등의 유해기체 발생으로 대기오염 등의 제2차 오염을 유발하는 폐단을 극소화하고 재활용 연료를 만드는 유익한 개발로써 특징은 평상 기압에 저온 분열 작용으로 생산하므로 안정성이 뛰어나고 완전 밀폐형으로써 제2차 환경 오염을 차단하고 촉매제(Y-NH+ 4계열)를 이용하므로 적은 비용과 정제 과정에서 나온 폐기물 또한 오염이 없고 산업용 원 자료로 사용하며 쓰레기에서 보물을 캐내는 시스템이라고 할 수 있다.As is apparent from the foregoing description, the fuel production system of the present invention causes soil and water pollution due to corrosion or decomposition at the time of burial, and secondary pollution such as air pollution due to generation of harmful gases such as HCL and HCN during direct combustion. It is a profitable development that minimizes the waste-causing waste and makes recycled fuel. It is characterized by producing at low temperature and cleavage at normal pressure, so it is excellent in stability and completely enclosed to block secondary environmental pollution and uses catalyst (Y-NH + 4 series). Therefore, the low cost and refining wastes are also pollution-free, industrial raw materials, and treasures from the waste.

Claims (2)

폐 플라스틱을 분쇄하여 열화 가마 분열 가마와 응결 기구를 통한 원유 제조.Crude waste plastics are produced by crushing waste plastics and by means of a condensation apparatus. 최화제(Y-NH+ 4계열)을 이용한 가솔린, 경유, 등유를 분류하는 시스템.System to classify gasoline, diesel, kerosene using optimizing agent (Y-NH + 4 series).
KR1020010034196A 2001-06-16 2001-06-16 Oil Manufacture System by Used Plastic KR20010087815A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR830007794A (en) * 1981-09-18 1983-11-07 박율 Petroleum manufacturing method using waste of petrochemical product
KR970042958A (en) * 1995-12-26 1997-07-26 여기본 Fuel manufacturing method and apparatus using waste plastic
KR20000029307A (en) * 1998-10-29 2000-05-25 니시무로 타이죠 System and method for reclaiming oil from waste plastic
KR20020068574A (en) * 2001-02-21 2002-08-28 (주)그린테크 Devided furnance of emulsion equipment for waste plastic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR830007794A (en) * 1981-09-18 1983-11-07 박율 Petroleum manufacturing method using waste of petrochemical product
KR970042958A (en) * 1995-12-26 1997-07-26 여기본 Fuel manufacturing method and apparatus using waste plastic
KR20000029307A (en) * 1998-10-29 2000-05-25 니시무로 타이죠 System and method for reclaiming oil from waste plastic
KR20020068574A (en) * 2001-02-21 2002-08-28 (주)그린테크 Devided furnance of emulsion equipment for waste plastic

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