KR20010083821A - The mixture component method of functional glue - Google Patents

The mixture component method of functional glue Download PDF

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KR20010083821A
KR20010083821A KR1020010039204A KR20010039204A KR20010083821A KR 20010083821 A KR20010083821 A KR 20010083821A KR 1020010039204 A KR1020010039204 A KR 1020010039204A KR 20010039204 A KR20010039204 A KR 20010039204A KR 20010083821 A KR20010083821 A KR 20010083821A
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zeolite
weight ratio
flour
functional
charcoal
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KR1020010039204A
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Korean (ko)
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KR100436856B1 (en
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이청
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김경자
(주)새롬
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J1/00Adhesives based on inorganic constituents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J199/00Adhesives based on natural macromolecular compounds or on derivatives thereof, not provided for in groups C09J101/00 -C09J107/00 or C09J189/00 - C09J197/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks

Abstract

PURPOSE: Provided is a method of preparing functional adhesives which combines glue of flour or starch powder with functional materials such as zeolite, loess or char, individually or by a combination of suitable proportion. CONSTITUTION: The combining method contains the step of mixing the glue of flour or starch powder and functional materials in the weight ratio of 65-35:35-70, wherein the functional materials contains zeolite, loess and char mixed in the weight ratio of 60-90:30-5:10-5. The functional materials can be used as a mixture of zeolite and loess having the mixing ratio of 60-90:40-10 or a mixture of zeolite and char having the mixing ratio of 70-90:30- 10. The zeolite is to absorb carbonic acid gas and to generate oxygen. The loess is to control humidity and to block heat. The char is to generate anion and to inhibit the generation of fungus.

Description

기능성 접착제의 배합조성방법 { The mixture component method of functional glue }The mixture component method of functional glue

본 발명은 기능성 접착제의 배합조성방법에 관한 것이며 밀가루 또는 녹말가루를 주재료로 하여 제조된 풀에 제오라이트, 황토, 숯을 적정 혼합하여 제조된 접착제를 골판지 제조시에 공간을 형성하는 중간지의 상지와 하지 사이에 접착제층을 구비하며 중간지를 구성하고 이를 표면상지와 표면하지 사이에 중간지를 굴곡되도록 구성하여 골판지를 제조하고 이를 이용 상자를 제조하게 되면 각종 과일류, 생선류, 채소류등을 수납 보관하면 맛과 향 및 부패되지 않는 상태로 신선도를 늘일수 있게 되고, 건물의 도배지로 사용하게 되면 각 성분의 기능으로 실내환경을 청결히 하는 기능을 갖게 되는 것이다.The present invention relates to a method of formulating a functional adhesive, and the adhesive prepared by mixing zeolite, ocher, and charcoal in a paste prepared with flour or starch powder as the main material, and the upper and lower limbs of the intermediate paper forming a space in the manufacture of corrugated cardboard. It is equipped with an adhesive layer between them and constitutes the intermediate paper, and it is configured to bend the intermediate paper between the upper surface and the lower surface to manufacture the corrugated cardboard, and to manufacture the box using the various fruits, fish, vegetables, etc. The freshness can be increased in the state of incense and decay, and when used as a wallpaper of the building, it will have the function of cleaning the indoor environment with the function of each component.

종래에는 상자용 골판지를 구성함에 있어서 표면상지와 표면하지 사이에 주름 형태의 중간지를 구성하고 중간지의 돌출면에 접착제를 도포시켜 중간지의 돌출면과 표면상지 및 표면하지의 내부면을 접착시켜 제조된다.Conventionally, in constructing cardboard for cardboard, a corrugated intermediate paper is formed between the superficial paper and the subsurface, and an adhesive is applied to the protruding surface of the intermediate paper to bond the protruding surface of the intermediate paper with the inner surface of the superficial paper and the subsurface. .

이에 사용되는 접착제는 밀가루 또는 녹말가루를 주재로 하거나 또는 화학성 접착제를 주재로 한 것이므로 접착성은 좋으나 이와 같은 골판지로 제조된 상자에 각종 과일류, 채소류등을 보관하게 되면 골판지의 주재인 종이가 지니는 흡습성의 기능은 있으나 과일과 채소등이 호흡하는데 필요한 적정 공기량을 공급하지 못하고, 탄산가스를 제거하지 못하며 단열이 이루어지지 못하여 건조 또는 부패가 바르게 되는 결점이 있어 왔다.The adhesive used here is mainly made of flour or starch powder or chemical adhesive, so it has good adhesiveness. However, if various kinds of fruits and vegetables are stored in a box made of such cardboard, the hygroscopicity of paper, which is the main substrate of cardboard, is maintained. Although there is a function of the fruits and vegetables, such as breathing does not supply the proper amount of air, can not remove the carbon dioxide and the insulation has not been made dry or rot has been a defect.

위와 같은 결점을 보완하기 위해 골판지 외면에 형성하는 표면상지와 표면하지 사이에 형성하는 주름 형태의 중간지 사이의 공간에 제오라이트 분말을 충진시켜 골판지를 구성하는 경우가 있는데 이는 제오라이트의 기능에 의해 탄산가스를 흡수하고 산소를 발산하는 기능과 흡착과 흡습기능으로 과일, 채소류 및 생선류의 포장시 신선도를 늘일수는 있으나 단열, 곰팡이균의 생성억제에는 기여하지 못하고 있고, 또 골판지의 특성상 양산되지 못하여 실용화 되지 못하고 있다.In order to compensate for the above drawbacks, the cardboard is filled by filling the zeolite powder in the space between the upper surface formed on the outer surface of corrugated cardboard and the corrugated intermediate paper formed between the lower surface of the cardboard. Absorbing and dissipating oxygen and absorbing and hygroscopic function can increase the freshness of packaging fruits, vegetables and fish, but it does not contribute to the insulation and suppression of mold fungi. I can't.

또 건물의 도배시 벽지 또는 장판지의 도배시에는 녹말풀 또는 화학용 접착제를 사용하게 되는데 이는 접착성이 우수하여 도배를 효율적으로 수행할 수는 있으나 우수기나 건조기 또는 동절기나 하절기에 흡습, 흡착, 탄산가스 제거, 단열,곰팡이균 생성억제등의 기능이 없어 실내의 생활환경이 만족되지 못하였다.In addition, starch paste or chemical adhesive is used when wallpaper or floorboards are used for the papering of buildings, which can be efficiently carried out due to its excellent adhesion, but it can be absorbed, adsorbed, and carbonated in rainy seasons, dryers, or winter or summer. The indoor living environment was not satisfied because there were no functions such as degassing, insulation, and suppressing mold production.

이에 본 발명은 종래의 제반 문제점을 해소하고 밀가루 또는 녹말가루로 제조된 풀에 제오라이트, 황토, 숯을 적정비율로 혼합하여 제조된 기능성 접착제를 골판지의 중간지를 구성하는 상지와 하지 사이에 접착제층을 구비하거나 또는 도배용 풀로 사용하여 골판지 상자의 경우에는 흡습, 흡착, 탄산가스 제거, 산소발산, 단열, 곰팡이균 생성의 억제등의 기능으로 과일, 채소, 생선등의 보존기간을 늘이고, 도배시에는 실내 생활환경을 개선할 수 있는 기능성 접착제를 제공함에 목적이 있다.Therefore, the present invention solves the conventional problems, and the adhesive layer between the upper and lower limbs constituting the middle of the corrugated cardboard with a functional adhesive prepared by mixing zeolite, ocher, and charcoal in an appropriate ratio to the grass made of flour or starch powder. In the case of corrugated cardboard box, it can be used as a paste for spreading, or in the case of corrugated cardboard, to increase the shelf life of fruits, vegetables, fish, etc. The purpose is to provide a functional adhesive that can improve the indoor living environment.

도1은 본 발명의 중간지를 이용하여 제조된 골판지의 종단면도Figure 1 is a longitudinal cross-sectional view of the cardboard produced using the intermediate of the present invention

도2는 골판지용 중간지의 종단면도Figure 2 is a longitudinal sectional view of the intermediate paper for cardboard

※ 도면의 주요부분에 대한 부호 설명※ Explanation of Signs of Major Parts of Drawings

1 : 중간지 2 : 상지1: Middle paper 2: Upper limb

3 : 하지 4 : 접착제층3: not 4: adhesive layer

10 : 골판지10: corrugated cardboard

상자용 골판지의 접착제를 배합조성함에 있어서 밀가루 또는 녹말가루를 주재로 하여 제조된 풀에 제오라이트, 황토, 숯을 적정배합하여 조성하는 것이다.In formulating the adhesive of the cardboard for box, the zeolite, loess, charcoal is appropriately formulated in a paste prepared mainly from flour or starch powder.

보다 구체적으로는More specifically

제오라이트, 황토, 숯을 60~90:30~5:10~5의 중량비율로 혼합한 기능성 소재와 밀가루 또는 녹말가루로 제조된 풀을 65~30:35~70의 중량비율로 혼합하거나,Mix the zeolite, ocher, and charcoal with a weight ratio of 60 to 90:30 to 5:10 to 5, and the grass made of flour or starch powder at a weight ratio of 65 to 30:35 to 70,

또는 제오라이트와 황토를 60~90:40~10의 중량비율로 혼합한 기능성 소재와 밀가루 또는 녹말가루로 제조된 풀을 65~30:35~70의 중량비율로 혼합하거나,Or mix the zeolite and ocher with a weight ratio of 60 to 90:40 to 10, and a grass made of flour or starch powder at a weight ratio of 65 to 30:35 to 70,

또는 제오라이트와 숯을 70~90:30~10의 중량비율로 혼합한 기능성소재와 밀가루 또는 녹말가루로 제조된 풀을 65~30:35~50의 중량비율로 혼합하거나,Or mix the zeolite and charcoal with a weight ratio of 70 to 90:30 to 10 and a weight ratio of 65 to 30:35 to 50;

또는 제오라이트, 황토, 숯의 1종과 밀가루 또는 녹말가루로 제조된 풀을50~30:50~70의 중량비율로 혼합한 것이다.Or a mixture of zeolite, ocher, charcoal and flour made of flour or starch powder is mixed in a weight ratio of 50 to 30:50 to 70.

이와 같은 본 발명을 실시공정에서 상세히 설명하면 다음과 같다.The present invention will be described in detail in the following steps.

[제1공정](제오라이트 소재조성공정)[Step 1] (Zeoolite Material Composition Process)

제오라이트를 0.1~0.5mm의 입자로 분쇄하여 제오라이트 소재를 조성한다.The zeolite is ground into particles of 0.1 to 0.5 mm to form a zeolite material.

[제2공정](황토 소재조성공정)[Second process] (ocher material composition process)

황토를 0.1~0.5mm의 입자로 분쇄하여 3~10일간 물에 숙성시켜 황토소재를 조성한다.Ocher is crushed into particles of 0.1 ~ 0.5mm and aged in water for 3 to 10 days to form an ocher material.

[제3공정](숯소재 조성공정)[3rd process] (charcoal material composition process)

숯을 0.1~0.5mm의 입자로 분쇄하여 숯 소재를 조성한다.The charcoal is pulverized into particles of 0.1 ~ 0.5mm to form a charcoal material.

[제4공정](풀의 제조공정)[Step 4] (Pool Production Process)

공지된 바와 같이 밀가루 또는 녹말가루를 물에 적정량을 풀어서 이를 끓여 풀을 제조한다.As is known, a suitable amount of flour or starch powder is dissolved in water to boil it to prepare a pool.

[제5공정](기능성소재간의 배합공정)[5th process] (mixing process between functional materials)

제1공정의 제오라이트와 제2공정의 황토, 제3공정의 숯을 60~90:30~5:10~5의 중량비율로 혼합하거나 또는 제1공정의 제오라이트와 제2공정의 황토를 60~90:40~10의 중량비율로 혼합하거나,The zeolite of the first step and the loess of the second step and the char of the third step are mixed at a weight ratio of 60 to 90:30 to 5:10 to 5, or the zeolite of the first step and the loess of the second step are 60 to Mix in a weight ratio of 90: 40-10, or

또는 제1공정의 제오라이트와 제3공정의 숯을 70~90:30~10의 중량비율로 혼합하여 기능성 소재를 배합한다.Alternatively, the zeolite of the first step and the char of the third step are mixed at a weight ratio of 70 to 90:30 to 10 to blend the functional material.

[제6공정](기능성 접착제의 조성공정)[Sixth Step] (Step of Composition of Functional Adhesive)

제4공정의 풀과 제5공정으로 배합 조성된 기능성소재에서 1종을 선택하여 35~70:65~30의 중량비율로 하여 30분~2시간을 교반 혼합하거나 또는 제4공정의 풀에 제1공정의 제오라이트, 제2공정의 황토, 제3공정의 숯을 선택하여 50~70:50~30의 중량비율로 하여 30분~2시간을 교반 혼합한다.Select one kind from the functional material blended and prepared in the fourth step and the fifth step, and stir-mix 30 minutes to 2 hours at a weight ratio of 35 to 70:65 to 30, or apply it to the pool of the fourth step. The zeolite of the first step, the loess of the second step, and the char of the third step are selected and stirred and mixed for 30 minutes to 2 hours with a weight ratio of 50 to 70:50 to 30.

[제7공정](포장제품화 공정)[Step 7] (Packaging Productization Process)

제6공정에서 제조된 접착제를 정량 포장하여 제품화한다.The adhesive prepared in the sixth step is packaged and commercialized.

이와 같은 본 발명은 자연소재를 이용하게 되므로 유해성이 없고 특히 기능성 소재인 제오라이트의 경우에는 탄산가스를 흡입하고 산소를 생성하여 발산하게 되면서 수분은 흡습하였다가 건조시 발산되는 교환작용을 갖게 되고, 황토의 경우에는 다공질 물질로서 수분을 흡습하였다가 발산되는 기능과 보온과 단열의 기능을 갖게 되고, 숯의 경우에는 이물질의 흡착기능과 음이온의 발산 및 곰팡이균의 생성을 억제하는 기능을 갖게 되는 것이다.Since the present invention uses natural materials, there is no harmful effect, and in particular, the zeolite, which is a functional material, absorbs carbon dioxide and generates oxygen and emits moisture while absorbing moisture. In the case of the porous material to absorb moisture and has the function of heat dissipation and insulation and heat, and in the case of charcoal will have the function of inhibiting the adsorption function of foreign matter and the emission of anions and the production of fungi.

이와 같이 제조된 본 발명의 기능성 접착제를 이용하여 박스용 골판지의 중간지를 제조할 때 중간지(1)를 구성하는 상지(2)와 하지(3) 사이에 본 발명의 기능성 접착제를 이용하여 접착하면서 접착제층(4)을 구비하고 동 중간지(1)가 내장되는 골판지(10)로 상자를 제조하여 과실류, 채소류, 생선류를 포장하게 되므로 포장상자에 수납된 생물의 호흡작용으로 인하여 발생되는 탄산가스는 제오라이트에서 흡입하고 산소가 생성되어 포장상자내로 산소공급이 이루어져 흡입되고 산소가 생성되어 포장상자내로 산소공급이 이루어져 생물의 호흡작용이 이루어지고 제오라이트 및 황토는 수분을 흡습하였다가 부족시에는 발산하게 되어 습도를 조절하게 되고, 숯에는 음이온의 발생으로 변질을 억제하여 곰팡이균의 생성을 억제하는 기능을 갖게 되어 상자에 수납된 과실류, 채소류 및 생선류의 변질을 억제시켜 신선도를 유지시킬 수 있게 된다.Using the functional adhesive of the present invention prepared in the middle of the cardboard for box using the adhesive between the upper limb (2) and the lower limb (3) constituting the intermediate paper (1) using the functional adhesive of the present invention Carbon dioxide gas generated by the breathing action of the organisms contained in the packaging box is prepared by manufacturing a box with a corrugated cardboard (10) having an adhesive layer (4) and embedded in the intermediate paper (1) Is inhaled in zeolite and oxygen is generated and oxygen is supplied into the box. Inhaled and oxygen is generated and oxygen is supplied into the box. The humidity is controlled, and the charcoal has the function of suppressing the production of fungi by suppressing the deterioration by the generation of negative ions. To suppress deterioration of a leaded fruits, vegetables and fish it is possible to maintain freshness.

또 본 발명의 기능성 접착제를 이용하여 건물의 실내 도배용으로 사용하게 되면 실내에서 인간의 호흡으로 인하여 발생되는 탄산가스와 가구등에서 발생되는 각종의 유해가스는 제오라이트에서 흡입되고 산소를 발산하게 되며 우수기에는 제오라이트와 황토가 습기를 흡습하고 건조기에는 습기를 방출하여 습도조절기능을 갖게 되면서 동절기와 하절기에는 외부 공기의 단열과 보온의 기능을 갖게 된다.In addition, when the use of the functional adhesive of the present invention for the interior of the building, carbon dioxide and various harmful gases generated by human breathing in the room are inhaled in the zeolite and emit oxygen, Zeolite and loess absorb moisture and release moisture to the dryer to control the humidity, so it has the function of heat insulation and insulation of the outside air in winter and summer.

또 실내에서 발생되는 각종의 곰팡이균을 숯에서 발산되는 음이온으로 곰팡이균의 생성을 억제시켜 실내의 공기를 개선할 수 있게 된다.In addition, it is possible to improve the air in the room by inhibiting the production of fungi with anion emitted from the charcoal of various fungi generated in the room.

이와 같은 본 발명에서 접착제의 제오라이트, 황토, 숯을 함유하게 될 경우 과실류, 채소류, 생선류의 포장박스 또는 도배용으로 사용할 수 있게 되며, 풀에 황토와 제오라이트를 함유하게 되는 경우에는 과실류중 바나나, 사과, 배등에서 신선도의 유지기간이 길어지고, 풀에 제오라이트와 숯을 함유하는 경우에는 딸기, 복숭아, 살구, 홍시등 곰팡이균의 생성이 빠른 과실류에서 신선도의 유지기간이 길어지고, 풀에 제오라이트를 함유하는 경우에는 채소류와 생선류에서 신선도의 유지기간이 길어지는 점을 확인하였다.When the zeolite, ocher, and charcoal of the adhesive are contained in the present invention, it can be used for packing boxes or papering of fruits, vegetables, and fish, and if the grass contains ocher and zeolite, bananas, apples, etc. In case of containing fresh zeolite and charcoal in the grass, and in case of containing zeolite and charcoal in the ship, the maintenance period of freshness is long in the fruit which is fast in the production of fungi such as strawberries, peaches, apricots and hongsi, and contains zeolite in the grass. In the case of fresh vegetables, the freshness of the fish was confirmed to be longer.

이와 같이 본 발명은 밀가루 또는 녹말가루로 제조된 풀에 제오라이트, 황토, 숯을 적정 배합하므로서 접착의 기능과 함께 과실류, 채소류, 생선류의 포장용 상자의 접착제로 사용시 신선도의 유지기간을 늘일 수 있게 되고 도배용으로 사용시에는 실내공기를 개선하는 기능을 갖게 되는 것이다.As described above, the present invention is capable of increasing the retention period of freshness when used as an adhesive for packaging boxes of fruits, vegetables, and fish with proper function of zeolite, ocher, and charcoal by appropriately mixing zeolite, ocher, and charcoal in the grass prepared with flour or starch powder. When used for the purpose will have the function to improve the indoor air.

따라서 이상과 같은 본 발명은 접착제에 제오라이트에 의한 탄산가스의 흡수기능과 산소 발산기능, 황토에 의한 습도조절기능과 단열 빛 보온기능, 숯에 의한 음이온 발산과 곰팡이균 생성의 억제기능을 부여하므로서 접착의 기능과 동시에 새로운 기능을 얻을 수 있게 되는 산업상 유용한 발명이다.Therefore, the present invention as described above is attached to the adhesive by providing a function of absorbing carbon dioxide gas by zeolite and oxygen dissipation function, humidity control function and thermal insulation light insulation function by ocher, anion divergence by charcoal and suppression of fungal bacteria production It is an industrially useful invention that allows you to get new features and at the same time.

Claims (5)

상자용 골판지 접착제로 배합조성함에 있어서 밀가루 또는 녹말가루를 주재로 하여 제조된 풀에 제오라이트, 황토, 숯을 각각 또는 적정비율로 배합하여서 조성된 기능성 접착제의 배합조성방법Formulation method of functional adhesive formulated by mixing zeolite, ocher, and charcoal in the appropriate ratios of each paste prepared with flour or starch powder in the composition of the cardboard adhesive for boxes 제1항에 있어서,The method of claim 1, 제오라이트, 황토, 숯을 60~90:30~5:10~5의 중량비율로 혼합한 기능성 소재와 밀가루 또는 녹말가루로 제조된 풀을 65~35:35~70의 중량비율로 혼합하여 조성된 기능성 접착제의 배합조성방법Zeolite, ocher, charcoal mixed with a weight ratio of 60 ~ 90:30 ~ 5:10 ~ 5 functional material and flour made of flour or starch powder at a weight ratio of 65 ~ 35:35 ~ 70 Formulation method of functional adhesive 제1항에 있어서,The method of claim 1, 제오라이트와 황토를 60~90:40~10의 중량비율로 혼합한 기능성 소재와 밀가루 또는 녹말가루로 된 풀을 65~35:35~70의 중량비율로 혼합하여 조성된 기능성 접착제의 배합조성방법Formulation method for mixing functional materials prepared by mixing zeolite and ocher at a weight ratio of 60 to 90:40 to 10 and grass or flour made of starch powder at a weight ratio of 65 to 35:35 to 70 제1항에 있어서The method of claim 1 제오라이트와 숯을 70~90:30~10의 중량비율로 혼합한 기능성소재와 밀가루 또는 녹말가루로 제도된 풀을 65~30:35~70의 중량비율로 혼합하여 조성된 기능성 접착제의 배합조성방법Method of formulating a functional adhesive prepared by mixing a zeolite and charcoal in a weight ratio of 70 to 90:30 to 10 and a paste prepared from flour or starch powder at a weight ratio of 65 to 30:35 to 70 제1항에 있어서,The method of claim 1, 제오라이트:황토:숯중에서 1종과 밀가루 또는 녹말가루로 제조된 풀을 50~30:50~70의 중량비율로 혼합하여 조성된 기능성 접착제의 배합조성방법Zeolite: Ocher: Mixing composition of functional adhesives prepared by mixing one kind of charcoal with flour or starch powder at a weight ratio of 50-30: 50-70
KR10-2001-0039204A 2001-07-02 2001-07-02 The mixture component method of functional glue for making corrugated cardboard of the paper box KR100436856B1 (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010103069A (en) * 2001-08-22 2001-11-23 최명부 Technigue of Making Bio-Glue by Mixrg Ceramix and Clay
KR20020023800A (en) * 2001-12-19 2002-03-29 주식회사 테크피아 Manufacturing method for the paste for making corrugated cardboard and packing paper and box by using the paste
KR20040016757A (en) * 2002-08-19 2004-02-25 최명부 The negatirir ion papering paste
KR20040030730A (en) * 2004-01-06 2004-04-09 권상학 Manufacturing of ion paste by ion powder
KR100453178B1 (en) * 2002-02-18 2004-10-15 김순예 manufacturing method for loess plywood
KR100487679B1 (en) * 2001-12-01 2005-05-06 조남일 Charcoal bond for Wall paper
KR100492894B1 (en) * 2002-05-22 2005-06-03 주식회사 홈코트 A Liquefied Adhesion Goods And The Process Use A Charcoal

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KR100229216B1 (en) * 1997-11-11 1999-12-01 박병현 Corrugated cardboard having a zeolite layer and manufacturing method thereof
KR19990031523U (en) * 1997-12-31 1999-07-26 이동연 Paper wallpaper
KR20000033319A (en) * 1998-11-23 2000-06-15 김옥수 Loess adhesives
KR20010028018A (en) * 1999-09-17 2001-04-06 정종혁 Manufacturing method for paste having charcoal powder and a paste manufacturing the same method
KR20010048836A (en) * 1999-11-30 2001-06-15 안종서 Charcoal
KR100353397B1 (en) * 2000-02-01 2002-09-18 박용선 Anionic paste and method for producing thereof
KR20000054467A (en) * 2000-06-08 2000-09-05 이동찬 a wall paper
KR20010007860A (en) * 2000-10-10 2001-02-05 김환귀 Natural derived construction materials

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010103069A (en) * 2001-08-22 2001-11-23 최명부 Technigue of Making Bio-Glue by Mixrg Ceramix and Clay
KR100487679B1 (en) * 2001-12-01 2005-05-06 조남일 Charcoal bond for Wall paper
KR20020023800A (en) * 2001-12-19 2002-03-29 주식회사 테크피아 Manufacturing method for the paste for making corrugated cardboard and packing paper and box by using the paste
KR100453178B1 (en) * 2002-02-18 2004-10-15 김순예 manufacturing method for loess plywood
KR100492894B1 (en) * 2002-05-22 2005-06-03 주식회사 홈코트 A Liquefied Adhesion Goods And The Process Use A Charcoal
KR20040016757A (en) * 2002-08-19 2004-02-25 최명부 The negatirir ion papering paste
KR20040030730A (en) * 2004-01-06 2004-04-09 권상학 Manufacturing of ion paste by ion powder

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