KR20010069644A - Manufacturing of highly concentrated Antibiotic Silver Soap - Google Patents

Manufacturing of highly concentrated Antibiotic Silver Soap Download PDF

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KR20010069644A
KR20010069644A KR1020010022184A KR20010022184A KR20010069644A KR 20010069644 A KR20010069644 A KR 20010069644A KR 1020010022184 A KR1020010022184 A KR 1020010022184A KR 20010022184 A KR20010022184 A KR 20010022184A KR 20010069644 A KR20010069644 A KR 20010069644A
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silver
soap
particles
fine
solution
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KR1020010022184A
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Korean (ko)
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오성근
김영곤
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오성근
김우협
주식회사 나노이앤씨
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Publication of KR20010069644A publication Critical patent/KR20010069644A/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06—Inorganic compounds
    • C11D9/18—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/10—Mixing; Kneading
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/225—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/38—Products in which the composition is not well defined

Abstract

PURPOSE: Provided is a process for producing antimicrobial soap containing high concentrated silver by using fine silver particles produced by using a surfactant in a water solution, the antimicrobial soap can improve skin trouble. CONSTITUTION: The process comprises the steps of: melting transparent soap base containing coconuts, a palm oil, glycerin, stearic acid, etc.; adding a colloidal silver solution having the fine silver particles of which the particle size is less than 20nm, chitosan, a moisturizing agent, retinol, jojoba oil, aloes, and herbs to the soap base, wherein the colloidal silver solution is produced by using the surfactant in the water solution; stirring and solidifying. The antimicrobial soap contains more than 100ppm of the fine particles.

Description

고농도의 은이 함유된 항균성 비누의 제조{Manufacturing of highly concentrated Antibiotic Silver Soap}Manufacturing of highly concentrated Antibiotic Silver Soap

은(Ag)은 범용적인 항생제로서 잘 알려진 물질로서 콜로이드 형태의 은은 세균을 비롯한 균류 및 바이러스 등에도 탁월한 효과가 있으면서도 부작용은 없는 것으로 알려져 있다. 특히 은이 극미세의 입자(1-100 nm)로 분산되어진 콜로이드실버 용액의 경우에는 쉽게 세포 속으로 침투하여 바이러스, 박테리아, 곰팡이 균류 등이 호흡할 때 필요한 효소의 기능을 정지시켜 질식시킴으로서 이들을 죽게 한다. 이는 병균의 신진대사를 막아 살균하는 것과 더불어 금속의 은이 방출하는 은의 전기적 부하가 병균의 생식 기능을 억제하기 때문이다.Silver (Ag) is a well-known substance as a general-purpose antibiotic. Colloidal silver is known to have excellent effects on bacteria, fungi, and viruses, but has no side effects. Particularly, colloidal silver solution in which silver is dispersed into very fine particles (1-100 nm) easily penetrates into cells and kills them by suffocating by stopping the function of enzymes necessary for viruses, bacteria, fungi, etc. to breathe. . This is because the germ's metabolism is prevented and sterilized, and the silver's electrical load from the silver inhibits germ's reproductive function.

콜로이드실버는 전기분해법, 액상환원법, grinding 등의 물리적 방법으로 제조되어질 수 있다. 고순도의 안정한 콜로이드실버를 얻기 위해서는 지금까지 주로 전기분해법이 사용되었다. 전기분해법은 증류수에 순수한 은(99.99%)을 넣고 저온에서 저전류를 발생시켜 방전되어 나온 극소 미립자 형태의 은이 용액에 용해되어포함되게 함으로서 얻는다. 그러나 일정 이상의 농도로 은이 함유되도록 하려면 상당한 시간이 요구됨과 더불어 농도가 높아짐에 따라 극소 미립자의 은이 뭉쳐 검은색의 침전이 생기므로 안정한 콜로이드실버를 얻기 위해서는 저농도(주로 20 ppm 이하)로 제조되는 것이 일반적이었다. 따라서 이렇게 얻은 콜로이드실버를 이용하여 비누를 제조할 경우 저농도이므로 이를 이용하여 비누를 제조할 경우 대량제조가 어려워 가격이 비쌀 수 밖에 없었다.Colloidal silver may be prepared by physical methods such as electrolysis, liquid phase reduction, grinding. In order to obtain stable colloidal silver with high purity, electrolysis has been mainly used. The electrolysis method is obtained by adding pure silver (99.99%) to distilled water and generating a low current at low temperature so that the discharged silver particles are dissolved in the solution. However, it requires a considerable time to contain the silver at a certain concentration, and as the concentration increases, very fine silver is agglomerated to form a black precipitate. Therefore, to obtain a stable colloidal silver, it is generally manufactured at a low concentration (usually 20 ppm or less). It was. Therefore, when the soap is manufactured using the colloidal silver thus obtained, the concentration is low, and when the soap is manufactured using this, mass production is difficult and the price is inevitably high.

기존의 비누는 물과 계면활성제, 보습제, 향, 유연성 오일, 살균제, 방부제등이 혼합된 액을 고형화함으로써 제조되었다. 특히 기존의 비누에 사용되었던 피부 보호용 살균제나 부패 방지용 방부제 등은 피부 접촉시 알레르기나 피부 손상의 결점을 지니고 있으며 피부 보호나 피부 트러블 개선이라는 효과에 있어서도 매우 미미한 수준이었다. 한편 이러한 점을 개선하기 위해 전기분해법에 의해 얻어진 은수(silver water)를 이용한 은비누는 가격이 비싸다는 단점을 지니고 있다.Existing soaps were prepared by solidifying a mixture of water, surfactant, moisturizer, fragrance, flexible oil, fungicide, and preservative. In particular, skin protection fungicides and anti-corrosive preservatives used in conventional soaps have allergic or skin damage defects in contact with the skin, and are very insignificant in the effects of skin protection and skin trouble improvement. On the other hand, silver soap using silver water obtained by electrolysis in order to improve this point has a disadvantage that the price is expensive.

본 발명에서는 출원번호 99-54938의 특허 '수용액상에서 계면활성물질을 이용한 미세 금속 입자의 제조방법'을 이용하여 얻은 미세 은입자가 분산된 콜로이드용액을 이용하여 비누를 제조한다. 위의 방법을 사용할 경우 고농도(5-10 wt. %)의 콜로이드 실버 수용액을 제조하여 입자를 회수하는 기술을 바탕으로 은 미립자를 얻기 때문에 고농도의 은이 함유된 항균성 은비누의 대량생산과 원가절감이 가능하다는 장점을 지니고 있다.In the present invention, a soap is prepared using a colloidal solution in which fine silver particles obtained using the patent method 'Preparation method of fine metal particles using a surface active material in an aqueous solution' of the application No. 99-54938. If the above method is used, high-density (5-10 wt.%) Colloidal silver solution is prepared and silver fine particles are obtained based on the technology of recovering particles. Therefore, mass production and cost reduction of antimicrobial silver soap containing high concentration of silver is reduced. It has the advantage of being possible.

본 발명에서는 위에서 언급한 기존 비누의 한계와 전기분해법에 의해 얻은은수를 사용한 은비누의 단점을 보완하기 위해 인체에 무해한 계면활성물질을 사용하여 수용액상에서 은이 환원되어 입자가 형성될 때 입자의 크기를 조절함으로써 얻어진 20 nm 이하의 크기를 지닌 미세 은 입자를 비누에 첨가하여 피부 보호 및 피부트러블을 개선할 수 있는 고기능의 은비누를 제조하는 것을 목적으로 한다.In the present invention, the size of the particles when the particles are formed by reducing the silver in an aqueous solution using a surfactant that is harmless to the human body to compensate for the limitation of the conventional soap and the disadvantage of the silver soap using the mercury obtained by the electrolysis method mentioned above. It is an object of the present invention to prepare a high-performance silver soap which can improve skin protection and skin trouble by adding fine silver particles having a size of 20 nm or less obtained by adjusting the to the soap.

일반적으로 은수라고 불리우는 colloidal silver는 전기분해법으로 제조가 되나 이는 경제성이 낮아 비교적 단가가 높은 단점을 지닌다. 따라서 본 발명에서는 살균, 소독, 여드름, 습진, 무좀, 부스럼, 건선 등에 효과가 있는 colloidal silver를 '수용액상에서 계면활성물질을 이용한 미세 금속 입자의 제조방법'의 특허를 이용하여 대량으로 값싸게 제조함과 동시에 피부보호 및 피부 트러블을 개선하기 위해 레티놀, 호호바(jojoba) 오일, 아보카도(avocado), 코코넛 오일, 키토산등이 첨가된 경제성이 있는 100 ppm 이상의 은이 함유된 고농도의 항균성 은비누를 제조하는 방법을 제공하고자 한다.Colloidal silver, commonly called silver, is manufactured by electrolysis, but it has a disadvantage in that its cost is relatively low due to its low economic efficiency. Therefore, in the present invention, colloidal silver, which is effective in sterilization, disinfection, acne, eczema, athlete's foot, swelling, psoriasis, etc. is produced inexpensively in large quantities using the patent of 'manufacturing method of fine metal particles using surfactants in aqueous solution'. At the same time, a method for producing high concentration of antimicrobial silver soap containing over 100 ppm silver with economical addition of retinol, jojoba oil, avocado, coconut oil, chitosan, etc. to protect skin and improve skin trouble To provide.

도 1은 은비누의 성분 조성표이다.1 is a component composition table of silver soap.

본 발명은 먼저 coconut 및 palm oil 류 등이 함유되어 있는 투명 비누 수지를 녹이고 여기에 글리세린, 음이온 및 비이온 계면활성제, 키토산, 호호바 오일, 레티놀, 아보카도, aloe, herb 등을 첨가한 후 수용액상에서 계면활성물질을 이용하여 제조된 20 nm 이하의 크기를 지닌 미세 은 입자의 colloidal silver 용액을 넣어 혼합한 후 고형화시켜 비누를 제조한다. 이렇게 제조되어진 은비누는 미세 은 입자의 함유로 여드름, 습진, 무좀, 부스럼, 건선 등의 피부 트러블을 개선할 수 있으며, 계면활성제의 함유로 피부세정을 함과 동시에 여기에 첨가되는 coconut 및palm oil 류, 글리세린, 스테아린산, 키토산, 호호바 오일, 아보카도, 레티놀, 알로에 및 허브 등의 함유로 피부 유연성, 보습 효과, 피부 영양, 피부탄력성, 민감성, 피부노화, 방부 효과 및 향긋한 향을 제공할 것이다. 특히 미세 은 입자 제조 공정상의 이점으로 고농도의 은비누를 값싸게 대량으로 제조할 수 있다는 장점을 지닌다.The present invention first melts a transparent soap resin containing coconut and palm oils, and then adds glycerin, anionic and nonionic surfactants, chitosan, jojoba oil, retinol, avocado, aloe, herb and the like to interface with an aqueous solution. Soap is prepared by mixing and solidifying colloidal silver solution of fine silver particles having a size of 20 nm or less prepared using the active material. The silver soap prepared in this way can improve skin troubles such as acne, eczema, athlete's foot, swelling, and psoriasis by containing fine silver particles.Coconut and palm oils added to the skin at the same time it cleans the skin with surfactant Contains glycerin, stearic acid, chitosan, jojoba oil, avocado, retinol, aloe and herbs to provide skin suppleness, moisturizing effect, skin nutrition, skin elasticity, sensitivity, skin aging, antiseptic effect and fragrant aroma. In particular, it has the advantage of being able to manufacture a large amount of high concentration of silver soap inexpensively as an advantage in the process of producing fine silver particles.

본 발명에 따른 실시 예를 설명하면 다음과 같다.An embodiment according to the present invention will be described below.

<실시예><Example>

먼저 colloidl silver는 특허(출원번호 99-54938) '수용액상에서 계면활성물질을 이용한 미세 금속 입자의 제조방법'을 이용하여 다음과 같은 방법으로 제조한다. 질산은염을 순수에 녹이고 여기에 환원제를 넣어 은 미립자로 환원시킴과 동시에 aggregation을 방지하지 위해 계면활성 물질을 적당량을 첨가하여 미립자가 20 nm의 크기로 분산되어진 colloidal silver 용액을 제조한다.First, colloidl silver is manufactured by the following method using the patent (Application No. 99-54938) 'Method for producing fine metal particles using surfactants in aqueous solution'. The silver nitrate salt is dissolved in pure water, and the reducing agent is added to reduce the silver particles. At the same time, an appropriate amount of a surfactant is added to prevent aggregation, thereby preparing a colloidal silver solution in which the particles are dispersed in a size of 20 nm.

은비누는 coconut, palm oil 류, 글리세린, 스테아린산 등이 함유된 투명 비누 base를 120℃ 정도의 온도에서 녹여 완전히 액상화하고 다시 온도를 80℃ 이하로 낮추어 여기에 '수용액상에서 계면활성물질을 이용한 미세 금속 입자의 제조방법'에 의해 얻어진 은 입자의 colloidal silver 용액, 키토산, 보습제, 레티놀, 아보카도, 호호바 오일, pH 조절제, 알로에 및 허브 등을 첨가하고 잘 교반한 다음 이를 고형화하여 은비누를 제조한다. 각 성분의 비율은 도1에 나타내었다.Silver soap is completely liquefied by melting a transparent soap base containing coconut, palm oils, glycerin, stearic acid at a temperature of about 120 ℃, and then lowering the temperature to below 80 ℃. Colloidal silver solution, chitosan, humectant, retinol, avocado, jojoba oil, pH adjuster, aloe and herb, etc., of silver particles obtained by the method of 'preparation' were added, stirred well, and then solidified to prepare a silver soap. The ratio of each component is shown in FIG.

제조된 은비누는 인체에 무해하며 피부의 각종 세균과 바이러스 등을 퇴치시킴으로써 여드름, 습진, 무좀, 부스럼, 건선 등의 피부트러블을 개선하며 피부유연성, 보습 효과, 피부 영양, 피부탄력성 등을 더하여 피부 보호를 할 수 있는 고기능의 제품으로 매우 우수한 효과를 나타낼 것이다. 또한 colloidal silver 용 액의 제조법상의 장점으로 이러한 고농도의 항균성 은비누를 값싼 가격에 공급할 수 있음으로써 모든 사람이 부담없이 구입하여 쓸 수 있을 것으로 기대되어 진다.Manufactured silver soap is harmless to human body, and it removes various bacteria and viruses of the skin and improves skin troubles such as acne, eczema, athlete's foot, swelling, psoriasis, etc. and protects skin by adding skin flexibility, moisturizing effect, skin nutrition, skin elasticity, etc. As a high-performance product that can do a very good effect. In addition, it is expected that everyone can feel free to purchase these high concentrations of antimicrobial silver soap at low prices due to the advantages of the colloidal silver solution.

Claims (4)

Coconut, palm oil 류, 글리세린, 스테아린산 등이 함유된 투명 비누 base를 녹인 다음 수용액상에서 계면활성물질을 이용하여 제조된 20 nm 이하의 크기를 지닌 미세 은 입자의 colloidal silver 용액, 키토산, 보습제, 레티놀, 호호바 오일, 알로에 및 허브 등을 첨가하고 잘 교반하여 고형화시켜 만든 비누로서 20 nm 이하의 크기를 지닌 미세 은 입자가 100 ppm 이상 함유되어 있는 고농도의 항균성 은비누를 제조하는 방법A colloidal silver solution of fine silver particles with a size of 20 nm or less prepared by using a surface active material in a transparent soap base containing coconut, palm oils, glycerin, stearic acid, chitosan, humectant, retinol, A method of preparing a high concentration of antimicrobial silver soap containing 100 ppm or more of fine silver particles having a size of 20 nm or less as a soap made by adding jojoba oil, aloe and herbs and solidifying well. 제 1항에서, 수용액상에서 계면활성물질을 이용하여 제조된 미세 은 입자의 colloidal silver 용액이 첨가된 은비누의 pH를 피부 자극을 줄이기 위해 중성으로 하는 방법The method of claim 1, wherein the pH of the silver soap to which the colloidal silver solution of the fine silver particles prepared by using the surfactant is added in an aqueous solution is neutralized to reduce skin irritation. 제 1항에서, 고농도의 은비누를 제조함에 있어서 피부보호를 위해 colloidal silver와 함께 레티놀을 첨가하여 비누를 제조하는 방법The method of claim 1, wherein the soap is prepared by adding retinol together with colloidal silver to protect the skin in preparing a high concentration of silver soap. 제 1항에서, 수용액상에서 계면활성물질을 이용하여 제조된 미세 입자는 은 뿐만이 아니라 금 또는 이의 복합금속 입자도 해당된다.The method of claim 1, wherein the fine particles produced using the surface active material in the aqueous solution is not only silver but also gold or composite metal particles thereof.
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KR20030083038A (en) * 2002-04-19 2003-10-30 이언섭 The detergent comprising Ag-ion
KR20040040970A (en) * 2002-11-08 2004-05-13 이상건 Method of manufacturing transparent collagen vegetable soap
KR100446542B1 (en) * 2002-02-04 2004-09-01 박상도 Manufacturing method of Red Ginseng Soap
KR20040085132A (en) * 2004-09-14 2004-10-07 이현숙 Functional soap including pearl powder and nano silver and method thereof
WO2004104153A1 (en) * 2003-05-22 2004-12-02 Neb Technologies Co., Ltd Manufacturing method of liquid laundry detergent with nano-sized silver colloid
KR100465450B1 (en) * 2002-06-27 2005-01-13 주해영 Natural aroma soap and its production methods
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KR20160062431A (en) 2014-11-25 2016-06-02 주식회사 지엘머티리얼즈 method for manufacturing soap having finely dispersed rare metal nano-particles, and soap manufactured using the same
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* Cited by examiner, † Cited by third party
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KR100446542B1 (en) * 2002-02-04 2004-09-01 박상도 Manufacturing method of Red Ginseng Soap
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KR20040085132A (en) * 2004-09-14 2004-10-07 이현숙 Functional soap including pearl powder and nano silver and method thereof
KR100876914B1 (en) * 2007-01-30 2009-01-09 이수정 Compostion for Fuctional Soap Comprising Silver Nanoparticle and Organic Germanium, and Production Method Thereof
US10144908B2 (en) 2013-04-16 2018-12-04 Conopco, Inc. Liquid soap having enhanced antibacterial activity
US10370622B2 (en) 2013-04-16 2019-08-06 Conopco, Inc. Soap bar having enhanced antibacterial activity
WO2016021754A1 (en) * 2014-08-08 2016-02-11 아더비젼 주식회사 Method and apparatus for preparing soap by using silver solution
KR20160062431A (en) 2014-11-25 2016-06-02 주식회사 지엘머티리얼즈 method for manufacturing soap having finely dispersed rare metal nano-particles, and soap manufactured using the same

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