KR20010069638A - A rayon treat method of textile for manufacturing Acetate, a textile for manufacturing the rayon treat method - Google Patents

A rayon treat method of textile for manufacturing Acetate, a textile for manufacturing the rayon treat method Download PDF

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KR20010069638A
KR20010069638A KR1020010022115A KR20010022115A KR20010069638A KR 20010069638 A KR20010069638 A KR 20010069638A KR 1020010022115 A KR1020010022115 A KR 1020010022115A KR 20010022115 A KR20010022115 A KR 20010022115A KR 20010069638 A KR20010069638 A KR 20010069638A
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fabric
acetate
weight
rayon
heat
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KR1020010022115A
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Korean (ko)
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이돈순
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이돈순
주식회사 뉴비스
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/70Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
    • D06M15/71Cooling; Steaming or heating, e.g. in fluidised beds; with molten metals

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

PURPOSE: A process for preparing rayon fabric by coating a mixture having a specified viscosity on fabric prepared by acetate or acetate mixtures and heat-treating is provided, which increases productivity and causes no pollution because of its low sewage and waste. CONSTITUTION: This rayon fabric is prepared by the process consisting of: coating a mixture(AP) on the surface of fabric using acetate yarn in a ratio of 0.01<£a weight of AP attached to 1m¬2 fabric÷a weight of 1m¬2 fabric|x100<500 and heat treating under conditions of 50deg.C<dry heat(T) and steam heat(T1)<250deg.C, wherein the mixture contains material(P) having a pH value of 7.0 or more and compatible material in a ratio of 0.1<(a weight of P÷a weight of A)x100<2,000.

Description

아세테이트로 제조된 원단의 레이온화방법, 이에 의해 제조된 원단{ A rayon treat method of textile for manufacturing Acetate, a textile for manufacturing the rayon treat method }A rayon treat method of textile for manufacturing Acetate, a textile for manufacturing the rayon treat method}

본 발명은 아세테이트로 제조된 원단의 레이온화에 관한 것으로, 특히 아세테이트로 제조된 원단에 일정한 점도를 갖는 혼합물질을 도포함과 더불어 열처리함으로써 일부 또는 전부를 간단히 레이온화시킬 수 있도록 한 아세테이트로 제조된 원단의 레이온화방법, 이에 의해 제조된 원단에 관한 것이다.FIELD OF THE INVENTION The present invention relates to rayonization of fabrics made of acetate, and in particular, to the fabrication made of acetate, which includes a mixture having a constant viscosity and is heat-treated to make it easy to rayon part or all. It relates to a rayonization method of a fabric, and a fabric produced thereby.

일반적으로 레이온(Rayon)섬유란 나무에서 축출한 재생섬유를 말하는 것으로, 일명은 인견. 비스코스 섬유, 구리 아모니아법섬유, 초산법 섬유 등의 섬유소계의 화학섬유를 총칭한 때도 있다. 좁은 의미로는 재생 인조섬유중에서 셀룰로우스계에 속하는 비스코스 레이온을 가리키며, 필라멘트와 스테이플로 구별한다.In general, Rayon fiber refers to regenerated fiber that has been evicted from trees. In some cases, fibrous chemical fibers such as viscose fibers, copper ammonia fibers and acetic acid fibers are collectively named. In a narrow sense, it refers to a viscose rayon belonging to the cellulose system among the regenerated man-made fibers, and is distinguished by filament and staple.

그러나 이러한 레이온섬유는 처리과정에서 공해가 많이 발생하는 문제점이 있었다.However, these rayon fibers had a problem that a lot of pollution occurs during the treatment.

이에 아세테이트(Acetate)를 레이온화하는 방법이 제시되었는바, 아세테이트는 염료로 분산염료만 사용할 수 있었는데, 레이온화에 의해 반응성직접염료로 염색이 가능하게 되었다.Thus, a method of rayonating acetate has been proposed. Acetate could be used only as a disperse dye as a dye, and dyeing with a reactive direct dye was possible by rayonization.

즉, 이는 아세테이트로 제조된 원단을 1차로 세척하고, 원단무게에 일정비율로 알카리를 투입한 통에 원단을 투입하여 3시간여를 100℃이상에서 처리한 뒤, 정련수세공정에서 비누를 넣은 50 ~ 200℃물에 120분간 쌈게 되면 아세테이트가 레이온화된 원단을 얻을 수 있었다.In other words, this is the first wash the fabric made of acetate, put the fabric in the barrel with a certain ratio to the weight of the fabric, and after 3 hours of treatment at 100 ℃ or more, the soap 50 in the refined washing process When squeezed in water at ~ 200 ℃ for 120 minutes was able to obtain a rayon fabricated acetate.

여기에 필요한 염색가공공정에서 반응성직접염료를 넣어 한가지 색상으로 염색을 하게 되어 원단을 얻게 된다.In the required dyeing process, the reactive direct dye is added to dye one color to obtain a fabric.

그러나 이러한 레이온화는 원단의 전체를 레이온화 함으로써 특정부분을 선택적으로 레이온화할 수는 없는 문제점이 있었다.However, such rayonization has a problem that it is not possible to selectively rayon a specific part by rayonizing the entire fabric.

또 상기 레이온화에 따른 공정이 라인과는 별도로 마련된 공간에서 3시간여를 처리해야 하므로 생산성이 저하되는 문제점이 있었다.In addition, since the process according to the rayonization has to be processed for about 3 hours in a space provided separately from the line, there is a problem that productivity is lowered.

이에 본 발명은 상기와 같은 제반 문제점을 해소하기 위해 안출된 것으로, 아세테이트 또는 아세테이트혼용으로 제조된 원단에 일정한 점도를 갖는 혼합물질을 도포함과 더불어 열처리함으로써 원단의 일부 또는 전부를 간단히 레이온화시킬 수 있도록 한 아세테이트로 제조된 원단의 레이온화방법을 제공함에 그 목적이 있다.Accordingly, the present invention has been made to solve the above problems, it is possible to simply rayon some or all of the fabric by heat treatment, including a mixture having a constant viscosity in the fabric prepared for acetate or acetate blends and heat treatment. It is an object of the present invention to provide a rayonization method of a fabric made of acetate.

또 다른 목적은, 아세테이트로 제조된 원단에 일정한 점도를 갖는 혼합물질을 도포함과 더불어 열처리함으로써 일부 또는 전부가 레이온화된 원단을 제공하는데 있다.Still another object is to provide a fabric which is partially or completely rayoned by coating and heat-treating a mixture having a constant viscosity on a fabric made of acetate.

상기와 같은 목적을 달성하기 위한 본 발명의 아세테이트로 제조된 원단의 레이온화방법, 이에 의해 제조된 원단은, 아세테이트를 사용한 원단을 정련수세한 후 염색공정 및 드라잉과 텐더링등의 가공공정등을 통해 제조하도록 된 아세테이트로 원단을 제조함에 있어서, 상기 원단의 정련수세전에 레이온화물질 즉, 수용액의 pH측정방법을 기준으로 하여 pH>7.0의 물질(이하 P라 칭함)과 상용성이 가능한 물질(이후 A이라 칭함)이 0.1 < (P의 중량 ÷A의 중량) ×100 < 2,000의 비율로 혼합한 물질(이후 AP라 칭함)을 점도(이후 L이라 칭함)가 300 < L < 50,000의 범위로 한 물질을, 상기 아세테이트(Di-Acetate)원사를 사용한 원단표면에 0.01<[원단 1㎡에 부착된 AP의 중량(g) ÷원단 1㎡의 중량(g)] ×100 < 500의 비율로 도포시켜 건열(T)이나 증기열(T1)에서 50℃ < T,T1 < 250℃의 조건으로 열처리하여 제조하는 것이다.Rayonization method of the fabric made of acetate of the present invention, the fabric produced by the present invention to achieve the above object, after washing the fabric using acetate, dyeing process and processing process such as drying and tendering, etc. In manufacturing the fabric with acetate, which is to be prepared through the material, the material which is compatible with a material of pH> 7.0 (hereinafter referred to as P) on the basis of the method of measuring the pH of the rayon material, that is, the aqueous solution before washing the fabric. A substance (hereinafter referred to as AP) mixed in a proportion of 0.1 <(weight of P ÷ A weight) x 100 <2,000 (hereinafter referred to as A) has a viscosity (hereinafter referred to as L) in a range of 300 <L <50,000 The material was obtained in the ratio of 0.01 <[weight of the AP attached to 1m 2 ÷ weight of g of 1m 2 of the fabric (g)] x 100 <500 on the fabric surface using the acetate (Di-Acetate) yarn. Apply to dry heat (T) or steam heat (T1) under 50 ℃ <T, T1 <250 ℃ It is prepared by heat treatment.

상기에서 pH<7인 경우 아세테이트의 검화(레이온화)가 부족하게 된다.If pH <7 in the above, there is a lack of saponification (rayonization) of acetate.

또 상기 (P의 중량÷A의 중량) ×100 < 0.1인 경우 P량이 너무 미약하여 본 특성의 효과가 부족하게 발현된다.When (weight of P ÷ A by weight) x 100 <0.1, the amount of P is so weak that the effect of this characteristic is insufficiently expressed.

한편, (P의 중량÷A의 중량) ×100 > 2,000일 경우 레이온화가 뚜렷하게 발현되나 정련수세 및 염색가공공정에서 욕중 및 원단에 AP가 잔류하여 얼룩이 발생할 수 있고 염색색상재현성이 불량 할 수 있다.On the other hand, if (weight of P ÷ A weight) × 100> 2,000, rayonization is clearly expressed, but AP may remain in baths and fabrics during scouring and dyeing processes and stains may occur, and staining color reproducibility may be poor.

또 L<300인 경우 AP를 원단에 도포시키기가 어려우며 또한 AP가 불균일하게 원단표면에 번지고 원단내부로 불균일하게 흡수되어 색상얼룩등이 발생할 수 있다.In addition, if L <300, it is difficult to apply the AP to the fabric, and the AP may be unevenly spread on the fabric surface and absorbed into the fabric unevenly, causing color stains and the like.

또 L>50,000인 경우 AP를 원단에 부착시키는 공정의 작업성이 불량하여 생산성이 나쁠수 있으며 또한 AP가 불균일하게 도포되어 색상얼룩과 형태가 선명하게 나타나지 않을 수 있다.In addition, if L> 50,000, the workability of the process of attaching the AP to the fabric may be poor, and the productivity may be poor. Also, the AP may be unevenly applied, and the color stain and shape may not be clearly displayed.

또한 [원단 1㎡에 부착된 AP의 중량(g) ÷원단 1㎡의 중량(g)]×100<0.01인 경우 원단표면에 부분적인 형태 및 점무늬등을 아주 약하게는 발현시킬 수 있겠으나 본 레이온화의 특성을 발현하는데 부족하다.In addition, if [weight of AP attached to fabric 1㎡ ÷ weight of fabric 1㎡ (g)] × 100 <0.01, partial shapes and spots may be expressed on the fabric surface very weakly. It is not enough to express the characteristics of anger.

또 > 500인 경우 본 발명의 원단특성은 충분히 발현될 수 있으나 제조비용이 높아지며 정련수세공정과 염색공정에서 AP가 잔류하여 색상재현성과 품질재현성이 불량하게 된다.In the case of> 500, the fabric characteristics of the present invention may be sufficiently expressed, but the manufacturing cost increases, and the AP remains in the scouring and dyeing processes, resulting in poor color reproducibility and quality reproducibility.

한편 T,T1 < 50℃인 경우 열처리 시간이 오래걸림으로 인해 제조비용이 상승하며 또한 AP의 불균일건조가 발생할 수 있기 때문에 염색얼룩이 발생될 수 있다.On the other hand, if T, T1 <50 ° C, the manufacturing cost increases due to the long heat treatment time, and also uneven drying of the AP may cause dyed stains.

또 T,T1 > 250℃인 경우 원단에 열경화 현상이 발생하여 촉감이 딱딱한 불량한 품질이 발생할 수 있다.In addition, when T, T1> 250 ° C., a thermosetting phenomenon occurs in the fabric, which may result in poor quality of hard touch.

한편 상기 (P의 중량 ÷A의 중량) ×100 은 반복 실험의 결과 원단을 검토하였을 경우 '10'이고, L은 '5,500'이며, [원단 1㎡에 부착된 AP의 중량(g) ÷원단 1㎡의 중량(g)] ×100이 '17'의 비율로 도포되어 120℃에서 열처리할 때 최적의 상태를 얻을 수 있다고 판단된다.On the other hand, the (weight of P ÷ A of weight) × 100 is '10' when the fabric is examined as a result of the repeated experiments, L is '5,500', [weight (g) ÷ fabric of the AP attached to the fabric 1㎡ Weight (g) of 1 m &lt; 2 &gt;] is applied at a ratio of '17' and it is judged that an optimum state can be obtained when heat-treated at 120 캜.

이하 본 발명에 따른 아세테이트로 제조된 원단의 레이온화에 따른 실시예를 설명한다.Hereinafter, an embodiment according to rayonization of a fabric made of acetate according to the present invention will be described.

[실시예1]Example 1

실시예1은 셀루로우즈(Cellulose)계 섬유호료와 소다회(Na2co3)를 10:70의 중량비율로 혼합하여 점도가 6,000인 혼합물을 디아세테이트와 폴리에스테르소재를 사용한 교직물 및 편물에 원단 1㎡중량(g)의 12%를 엠보싱(Embossing)공정, 코팅(Coating)공정, 프린트(Printing)공정 각각에서 원단에 도포시킨 후 건열 150℃와 증기열 120℃에서 각각 처리하여 가공을 진행하였다.In Example 1, a cellulose fiber cloth and soda ash (Na2co3) were mixed at a weight ratio of 10:70, and a mixture having a viscosity of 6,000 was mixed with a diacetate and a polyester material. 12% of (g) was applied to the fabric in each of the embossing process, the coating process, and the printing process, followed by processing at dry heat 150 ° C. and steam heat 120 ° C., respectively.

그 결과 처리전에 아세테이트와 폴리에스테르의 색상 및 품질특성만을 발현하였으나, 본 가공을 실시한 후에는 아세테이트와 폴리에스테르 및 레이온의 색상 및 품질특성을 발현할 수 있는 신규한 원단을 제조하게 되었다.As a result, only the color and quality characteristics of acetate and polyester were expressed before the treatment, but after this process, new fabrics capable of expressing the color and quality characteristics of acetate, polyester, and rayon were prepared.

[실시예2]Example 2

실시예2는 폴리에스테르(Polyester)계 섬유호료와 소다회(Na2co3)를 15:65의 중량비율로 혼합하여 점도가 7,000인 혼합물을 디아세테이트와 나이론소재를 사용한 교직물 및 편물에 원단 1㎡중량의 18%를 텐더링(Tentering)공정, 드라잉(Drying)공정, 라미네이팅(Laminating)공정, 포일링(Foiling)공정 각각에서 원단에 부착시킨 후 건열 140℃와 증기열 110℃에서 각각 처리하여 가공을 진행하였다.In Example 2, a polyester fiber cloth and a soda ash (Na2co3) were mixed at a weight ratio of 15:65, and a mixture having a viscosity of 7,000 was mixed with a diacetate and nylon material. % Is attached to fabric in the tendering process, drying process, laminating process, and foiling process, and then processed at dry heat 140 ℃ and steam heat 110 ℃ respectively. It was.

그 결과 처리전에 아세테이트와 나이론의 색상 및 품질특성만을 발현하였으나, 본 가공을 실시한 후에는 아세테이트와 나이론 및 레이온의 색상 및 품질특성를 발현할 수 있는 원단을 얻을 수 있었다.As a result, only the color and quality characteristics of acetate and nylon were expressed before the treatment, but after this process, a fabric capable of expressing the color and quality characteristics of acetate, nylon and rayon was obtained.

즉, 종전에 원단을 50℃ ~ 250℃의 물에 넣어서 베치(batch)식이나 연속식등으로 정련수세하고 난 후 코팅, 엠보싱, 텐더링, 드라잉, 프린팅, 포일링가공등의 염색/가공공정을 통해 제조하던 것에서, 정련수세공정의 전에 염색/가공공정에서 사용하는 각각의 코팅, 엠보싱, 텐더링, 드라잉, 프린팅, 포일링가공등에 이용하는 장치들을 이용하여 본 발명의 혼합물질(AP)을 도포한 후 50℃~250℃에서 건조함으로써 레이온화를 달성하게 되는 것이다.In other words, the fabrics were previously rinsed in a batch or continuous manner by putting the fabric in water at 50 ° C to 250 ° C and then dyed / processed such as coating, embossing, tendering, drying, printing, and foiling. In the manufacturing process, the mixture of the present invention (AP) using the apparatus used for each coating, embossing, tendering, drying, printing, foiling, etc. used in the dyeing / processing process before the scouring washing process After the coating, the rayonization is achieved by drying at 50 ° C to 250 ° C.

이때 상기 아세테이트 또는 아세테이트혼용의 원단에는 분산염료로만 염색이 가능하게 되고, 레이온화 된 부분은 반응성직접염료만 가능하게 되어 다양한 색상의 발현이 가능하게 되는 것이다.At this time, the fabric of the acetate or acetate mixture can be dyed only with a disperse dye, and the rayonized portion will only be a reactive direct dye to enable the expression of various colors.

따라서 상기 혼합물질(AP)을 가공공정에서 사용하는 장치를 응용하여 원단에 도포함으로써, 원단에 특정부분을 선택적으로 레이온화 시키는 것과 전체를 레이온화하는 것이 가능하게 된다.Therefore, by applying the apparatus used in the processing process the mixture (AP) to the fabric, it is possible to selectively rayon a specific portion to the fabric and to rayon the whole.

즉, 상기 코팅과 엠보싱 및 프린팅과 같은 가공 장치를 이용하여 다양한 레이온화된 특정무늬를 형성할 수 있게 된다.That is, it is possible to form a variety of rayonized specific patterns using the coating and processing devices such as embossing and printing.

이에 따라 원단에 레이온화하는 것이 단순화 됨은 물론, 원단의 제조라인에서 도포가 가능하여 생산성이 향상되는 한편, 종래와 같이 나무에서 레이온섬유를 축출할 때는 물론 아세테이트를 베치식통에 넣고 알카리용액을 풀어서 레이온화 할 때 보다 오/폐수가 적어 공해문제가 거의 발생하지 않게 된다.Accordingly, the rayonization of the fabric is simplified, and the productivity can be improved by being applied in the fabrication line. On the other hand, when extracting the rayon fiber from the tree as in the prior art, the acetate is put into a batch container and the alkali solution is released to release the rayon. There is less pollution / waste than toxic waste, so there is little pollution problem.

상기와 같이 설명한 바에 의하면, 아세테이트 또는 아세테이트혼용으로 제조된 원단에 일정한 점도를 갖는 상기 혼합물질(AP)을 도포함과 더불어 열처리함으로써 아세테이트와 아세테이트혼용의 품질특성에 원단의 일부 또는 전부를 간단히 레이온화시켜 레이온의 품질특성도 발현할 수 있어 다양한 소비자의 요구에 대응할 수 있는 효과가 있다.As described above, the rayon is simply rayonized to some or all of the fabrics in the quality characteristics of the acetate and acetate mixtures by coating and heat-treating the mixture (AP) having a constant viscosity on the fabrics prepared for the acetate or acetate mixture. It can also express the quality characteristics of the rayon has an effect that can respond to the needs of various consumers.

한편 본 발명의 바람직한 실시예에 의거 설명하였으나, 당해 기술분야의 업자라면 본 발명의 사상과 기술적수단으로 부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음은 물론이다.On the other hand, although described based on the preferred embodiment of the present invention, those skilled in the art can be variously modified and changed within the scope of the invention without departing from the spirit and technical means of the present invention.

Claims (3)

아세테이트원사를 사용한 원단을 정련수세한 후 염색/가공등을 실시하여 원단을 제조함에 있어서,In the manufacture of fabrics by rinsing fabrics using acetate yarns and then dyeing / processing, 상기 원단의 정련수세전에 레이온화물질 즉, 수용액의 pH측정방법을 기준으로 하여 pH > 7.0의 물질(P)과 상용성이 가능한 물질(A)이 0.1 < ( P의 중량 ÷A의 중량) ×100 < 2,000의 비율로 혼합한 물질(AP)을 점도(L)가 300 < L < 50,000의 범위로 하여, 상기 아세테이트원사를 사용한 원단표면에 0.01 < [원단 1㎡에 부착된 AP의 중량 ÷원단 1㎡의 중량] ×100 < 500의 비율로 도포시켜 건열(T)이나 증기열(T1)에서 50℃ < T,T1 < 250℃의 조건으로 열처리하여 제조하는 것을 특징으로 하는 아세테이트로 제조된 원단의 레이온화방법.Before the rinsing of the fabric, the material (A) that is compatible with the material (P) having a pH> 7.0 based on the pH measuring method of the aqueous solution, that is, 0.1 <(weight of P ÷ A) × A material (AP) mixed at a ratio of 100 <2,000, the viscosity (L) in the range of 300 <L <50,000, the weight of the AP attached to 0.01 <[fabric 1m 2 on the fabric surface using the acetate yarn ÷ fabric Weight of 1 ㎡] × 100 <500 is applied to the ratio of dry heat (T) or steam heat (T1) made of acetate fabric, characterized in that the heat treatment under the conditions of 50 ℃ <T, T1 <250 ℃ Rayonization method. 제 1항에 있어서,The method of claim 1, 상기 (P의 중량 ÷A의 중량) ×100 은 10이고, L은 '5,500'이며, [원단 1㎡에 부착된 AP의 중량(g) ÷원단 1㎡의 중량(g)] ×100이 17의 비율로 도포되어 120℃에서 열처리된 것을 특징으로 하는 아세테이트로 제조된 원단의 레이온화방법.The weight (weight of P ÷ A weight) × 100 is 10, L is '5,500', [weight (g) of AP attached to fabric 1 m 2 ÷ weight (g) of fabric 1 m 2)] × 100 is 17 Rayonization method of the fabric made of acetate, characterized in that the heat treatment at 120 ℃ applied at a rate of. 제 1항의 레이온화방법에 의해 제조된 원단.Fabric prepared by the rayonization method of claim 1.
KR1020010022115A 2001-04-24 2001-04-24 A rayon treat method of textile for manufacturing Acetate, a textile for manufacturing the rayon treat method KR20010069638A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06184949A (en) * 1992-12-22 1994-07-05 Mitsubishi Rayon Co Ltd Modified acetate fiber fabric and its production
JPH06316873A (en) * 1993-05-06 1994-11-15 Mitsubishi Rayon Co Ltd Modification of conjugate yarn
JPH06330470A (en) * 1993-05-25 1994-11-29 Mitsubishi Rayon Co Ltd Production of novel woven or knitted fabric containing acetate fiber
JPH10259568A (en) * 1997-03-18 1998-09-29 Mitsubishi Rayon Co Ltd Modified acetate fiber woven or knitted fabric and its production
KR20010100245A (en) * 2000-03-27 2001-11-14 조민호 Rayon fiber, fiber product, film and preparations thereof
KR20020061824A (en) * 2001-01-18 2002-07-25 에스케이케미칼주식회사 The preparation of hollow-rayon fiber

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06184949A (en) * 1992-12-22 1994-07-05 Mitsubishi Rayon Co Ltd Modified acetate fiber fabric and its production
JPH06316873A (en) * 1993-05-06 1994-11-15 Mitsubishi Rayon Co Ltd Modification of conjugate yarn
JPH06330470A (en) * 1993-05-25 1994-11-29 Mitsubishi Rayon Co Ltd Production of novel woven or knitted fabric containing acetate fiber
JPH10259568A (en) * 1997-03-18 1998-09-29 Mitsubishi Rayon Co Ltd Modified acetate fiber woven or knitted fabric and its production
KR20010100245A (en) * 2000-03-27 2001-11-14 조민호 Rayon fiber, fiber product, film and preparations thereof
KR20020061824A (en) * 2001-01-18 2002-07-25 에스케이케미칼주식회사 The preparation of hollow-rayon fiber

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