KR20010060916A - Overlay-welding bare rod containg tungsgen carbide - Google Patents
Overlay-welding bare rod containg tungsgen carbide Download PDFInfo
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- KR20010060916A KR20010060916A KR1019990063375A KR19990063375A KR20010060916A KR 20010060916 A KR20010060916 A KR 20010060916A KR 1019990063375 A KR1019990063375 A KR 1019990063375A KR 19990063375 A KR19990063375 A KR 19990063375A KR 20010060916 A KR20010060916 A KR 20010060916A
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- overlay
- tungsten carbide
- added
- carbide
- welding rod
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/32—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
- B23K35/327—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C comprising refractory compounds, e.g. carbides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
- B23K35/0261—Rods, electrodes, wires
Abstract
Description
본 발명은 텅스텐 탄화물을 다량첨가한 오버레이 용접봉에 관한 것으로 상세하게는 산업설비중 연삭마모가 심한 부품의 표면에 산소아세틸렌 용접으로 고팅층을 형성함으로써 부품의 수명을 연장시켜주는 오버레이 용접봉에 관한 것이다.The present invention relates to an overlay electrode in which a large amount of tungsten carbide is added, and more particularly, to an overlay electrode that extends the life of a part by forming a coating layer by oxygen acetylene welding on the surface of a heavy abrasive wear part in an industrial facility.
일반적으로 텅스텐 탄화물은 연삭마모에 대한 저항이 극히 우수하여 연삭마모되는 기계부품에는 텅스텐 탄화물을 주성분으로 하는 합금이 주로 사용되고 있으며 상술한 연삭마모부가 마모시 부품의 수명을 연장하기 위한 수단으로 행해지는 산소아세틸렌 용접시 오버레이 용접봉에도 텅스텐 탄화물이 다량함유된 오버레이 용접봉을 사용하고 있다.In general, tungsten carbide has a very good resistance to grinding wear, and the alloy mainly composed of tungsten carbide is used for grinding wear, and the above-mentioned grinding wear is used as a means for extending the life of the component when worn. In acetylene welding, an overlay electrode containing a large amount of tungsten carbide is used for the overlay electrode.
특히 제철소에서는 소결공장의 마모개소, 소결광 파쇄기해머, Scraper 등에 사용되고 있으며 텅스텐 탄화물의 크기는 2㎛∼3㎛ 입도를 가지는 분말들을 혼합하여 사용하고 있다.In particular, steel mills are used for wear parts of sinter plants, sintered ore crushers, hammers, scrapers, etc., and tungsten carbide is used by mixing powders having a particle size of 2 μm to 3 μm.
상술한 오버레이 용접봉 제조와 관련딘 일본국공개특허 61-219497에 의하면 큰입도의 주조공정으로 제조된 텅스텐 탄화물과 작은입도의 텅스텐 카바이드를 혼합하여 제조함을 용이하게 알 수 있으며 사용환경에 따라 비율은 변경되나 일반적으로는 넓은 입도범위를 포함하는 것이 내마모성 측면에서 바람직한 것으로 알려져 있다.According to Japanese Patent Laid-Open Publication No. 61-219497 related to the manufacture of overlay electrodes described above, it is easy to manufacture a mixture of tungsten carbide prepared by a large-sized casting process and tungsten carbide of a small particle size. In general, it is known to include a wide range of particle sizes in terms of wear resistance.
상술한 내용중 작은 입도의 텅스텐 카바이드 분말은 분말야금용으로 널리 사용되는 재료로써 용이하게 구할 수 있다. 그러나 입도가 큰 카바이드 분말은 용도가 제한적으로 구하기도 어려우며 제조비용이 고가로 오버레이 용접봉의 제조비용을 높이는 원인이 되었다.Tungsten carbide powder of small particle size in the above description can be easily obtained as a material widely used for powder metallurgy. However, carbide particles of large particle size are difficult to obtain in limited use, and the manufacturing cost is high, resulting in an increase in the manufacturing cost of the overlay electrode.
따라서 본 발명이 이루고자 하는 기술적 과제는 상술한 문제를 해소할 수 있도록 고가의 제조비용을 요하는 입도가 큰 카바이드 분말 대용품을 이용하여 동일한 마모특성을 갖는 오버레이 용접봉을 제조하는데 있다.Therefore, the technical problem to be achieved by the present invention is to manufacture an overlay electrode having the same wear characteristics by using a carbide powder substitute having a large particle size that requires a high manufacturing cost to solve the above problems.
도 1은 본 발명에 의한 용접봉 사용시 오버레이층 조직도1 is an overlay layer organization chart when using a welding electrode according to the present invention
도 2는 종래 방법에 의한 용접봉 사용시 오버레이층 조직도Figure 2 is an overlay layer organization chart when using a welding rod according to the conventional method
상술한 기술적 과제를 성취시키기 위한 구성은 고가의 입도가 큰 주조텅스텐 분말을 대신하여 상대적으로 저가인 파쇄 텅스텐 분말을 이용하여 오버레이 용접봉을 제조하는 것으로 중량비로 WC : 40∼80%, Mn, Si, Ni 총량의 함유량이 0∼10% 잔여분은 철의 제조시 함유되는 불순물이 포함된 철이 10∼60%로 구성되어 제조되는 종래 텅스텐 탄화물 오버레이 용접봉 제조방법에 있어서 상기 WC중 중량비로40%∼60%를 파쇄된 텅스텐 탄화물 소결품을 사용하여 텅스텐 탄화물 오버레이 용접봉을 제조하는 것으로 구성된다.In order to achieve the above technical problem, an overlay electrode is manufactured by using a relatively inexpensive crushed tungsten powder in place of an expensive particle tungsten powder, and the weight ratio is WC: 40 to 80%, Mn, Si, In the conventional method of manufacturing a tungsten carbide overlay electrode, in which the total content of Ni is 0 to 10%, the iron containing impurities contained in the production of iron is composed of 10 to 60%, and 40% to 60% by weight of the WC. It consists of manufacturing a tungsten carbide overlay electrode using the crushed tungsten carbide sintered article.
이하 상세히 설명하면 다음과 같다.Hereinafter will be described in detail.
WC는 오버레이 용접재료의 목적인 내마모성을 지니게하는 가장 중요한 성분으로 중량비로 40%이하 첨가시 내마모성이 급격히 감소하여 내마모재로써 첨가효과가 적으며 80%이상 첨가시 재료의 인성이 낮아 외부충격에 쉽게 파단되어 바람직하지 않다.WC is the most important component to have abrasion resistance, which is the purpose of overlay welding material, and when it is added below 40% by weight, the wear resistance is sharply decreased, so it is less effective as a wear-resistant material. It is not desirable to break.
따라서 WC 첨가량은 40∼80%로 제한하였다. 또한 WC의 입도는 2∼3000㎛의 넓은 범위를 갖는 것이 바람직하다고 알려져 있으며 이는 긁힘마모에서는 연삭입자의 크기와 접촉 압력에 따라 WC와 같은 강화성의 적정크기가 달라지는데, 실제사용시에는 일반적으로 연삭입자의 크기가 일정하지 않고 변동이 심하며 접촉압력도 일정치 않아 WC의 입도분포가 넓은 것이 이러한 마모조건 변화에 관계없이 내마모성을 일정하게 유지할 수 있어 바람직하다.Therefore, the amount of WC added was limited to 40 to 80%. In addition, the particle size of WC is known to have a wide range of 2 ~ 3000㎛ It is known that the appropriate size of the reinforcement, such as WC, depending on the size of the abrasive particles and the contact pressure in the wear abrasion, in actual use in general It is desirable to have a wide particle size distribution of the WC because the size is not constant, fluctuates and the contact pressure is not constant.
따라서 대개의 WC를 포함한 오버레이 용접재는 넓은 범위의 입도분포를 가지고 있으며 본 발명에서도 3∼20㎛의 미세한 WC와 100∼300㎛의 조대한 입자는 갖는 WC를 혼합한 분말을 용접봉 내부에 충진시켰다.Therefore, most of the overlay welding material including WC has a wide range of particle size distribution, and in the present invention, a powder mixed with fine WC of 3 to 20 μm and WC having coarse particles of 100 to 300 μm is filled into the electrode.
조대한 WC와 미세한 WC의 혼합비율은 대상 오버레이 육성부품의 사용환경에 영향을 받는 것으로 알려져 있으며 연삭입자의 크기가 큰 경우에는 조대한 WC의 비율이 높게 되고 반대경우에는 미세한 WC의 비율이 높아야 내마모성에 효율이 있다.The mixing ratio of coarse WC and fine WC is known to be influenced by the use environment of the target overlay-grown parts, and when the size of the grinding particles is large, the coarse WC ratio is high, and in the opposite case, the fine WC ratio is high and wear resistance Is efficient.
상술한 내용과 제철소에서 사용되는 대상 오버레이 육성부품의 사용환경을연관시킨결과 조대한 WC의 비율이 적어도 40%이상 60% 이하인 경우가 효과적인 내마모성을 갖는 것으로 판단되어 조대한 WC의 비율을 40∼60%로 제한하였다. Mn, Si등은 합금성분에 있어서 부수적인 것으로 첨가되는 경우 기지중에 고용되어 고용강화 효과와 응고시 용강중의 용존산소를 제거해주는 역활을 담당하며 필요에 따라 10%이하에서 첨가할 수 있다.As a result of associating the above contents with the use environment of the target overlay fabricating parts used in steel mills, the ratio of coarse WC is at least 40% to 60% is considered to have effective wear resistance. Limited to%. Mn, Si, etc., when added as an ancillary in the alloying component, is dissolved in the base and plays a role of removing the dissolved oxygen in the molten steel during solidification and solidifying effect, and may be added below 10% if necessary.
Ni은 기지중에 고용되어 오스테나이트상을 안정시킴으로 Mn과 더불어 기지조직의 연성을 향상시킨다. 따라서 필요에 따라 10% 이하의 범위에서 첨가할 수 있다.Ni is dissolved in the matrix and stabilizes the austenite phase, thereby improving the ductility of the matrix along with Mn. Therefore, it can add in 10% or less of range as needed.
상술한 내용중 Mn, Si, Ni의 첨가량은 총합이 10% 이하를 의미하는 것으로 필요시 Ni이 10% 첨가시 Mn, Si는 첨가되지 않는 것이나 대개의 경우 Ni이 주로 첨가되며 미량의 Mn, Si가 첨가된다.In the above description, the amount of Mn, Si, and Ni added means 10% or less in total. If necessary, Mn and Si are not added when 10% Ni is added. However, Ni is mainly added and a small amount of Mn and Si is added. Is added.
이하 실시예에 의해 상세히 설명하면 다음과 같다.When described in detail by the following examples.
(실시예)(Example)
WC 입도별 배합비를 달리한 합금분말을 이용하여 플럭스코어드 와이어를 제작한후 일정길이로 절단하여 용접봉을 제작하였다.Flux cored wires were prepared using alloy powders with different WC particle sizes and then cut to a certain length to produce welding rods.
물론 조대한 WC의 분말중 일정비율은 파쇄된 텅스텐을 사용하였으며 제작된 용접봉을 사용하여 SS400 모재위에 산소 아세틸렌 용접법으로 오버레이 용접을 행한후 저응력 건식 긁힘마모 시험기에서 하중 20kg 회전속도 300rpm 시험시간 30분 사용모래 직경 0.15-0.3mm로 시험을 실시하였다.Of course, a certain proportion of coarse WC powder was made of crushed tungsten, and overlay welding was performed on the SS400 base material by oxygen acetylene welding using a manufactured electrode. Sand was tested with a diameter of 0.15-0.3mm.
또한 종래 사용되는 상용재 즉 파쇄된 텅스텐을 사용하지 않은 용접봉을 이용하여 동일 조건하에서 용접하고 시험하여 표 1과 같은 용접봉 충진물의 성분 및 마모량에 대한 비교치를 얻었다.In addition, welding and testing were performed under the same conditions using conventional commercially available electrodes, ie, crushed tungsten, to obtain a comparison of the composition and wear amount of the electrode filler as shown in Table 1.
표 1 용접봉 충진물의 성분 및 마모량Table 1 Composition and Wear of Welding Rod Fill
표 1에 도시된 바와 같이 조대 WC를 충진물 조성중 40∼60% 범위에서 실시하였으며 Mn 및 Ni은 총합이 10% 이하로 첨가하였다.As shown in Table 1, coarse WC was carried out in the range of 40-60% of the fill composition and the total amount of Mn and Ni was added to 10% or less.
시험결과치인 마모감량을 종래의 상용재와 비교하면 실시예에서는 마모감량이 0.012∼0.017g으로 판명되었으며 상용재의 마모감량은 0.011∼0.015g으로 판명되어 거의 동등한 수준임을 알수 있게 한다.When the wear loss, which is a test result, is compared with a conventional commercial material, the wear loss was found to be 0.012 to 0.017g in the embodiment, and the wear loss of the commercial material was found to be 0.011 to 0.015g, indicating almost the same level.
따라서 저가의 텅스텐 탄화물 소결품을 분쇄사용한 경우에도 동등한 내마모성을 유지함을 알 수 있어 원자재비의 절감이 가능하게 되는 것이다.Therefore, even when inexpensive tungsten carbide sintered products are used, it can be seen that the same wear resistance is maintained, thereby reducing raw material costs.
또한 도 1 도 2에 도시된 그림은 본 발명에 NO3와 상용재 NO4의 오버레이층 표면을 전자현미경으로 관찰한 것으로 두재료 모두 조대한 텅스텐 탄화물과 미세한 텅스텐 탄화물이 섞여 있음을 알수 있다.In addition, FIG. 1 is an electron microscope of the overlay layer surface of NO3 and commercially available NO4 in the present invention. It can be seen that coarse tungsten carbide and fine tungsten carbide are mixed in both materials.
본 발명의 효과로는 텅스텐 탄화물이 다량첨가된 오버레이 용접봉 제조에 있어서 주조공정으로 제조된 고가의 조대한 텅스텐 탄화물 대용으로 저가의 파쇄 텅스텐 탄화물 소결품을 사용하여 동등한 기계적 성질을 갖는 오버레이 용접봉을 제조함으로써 원가절감 효과가 있다.The effect of the present invention is to manufacture an overlay electrode having equivalent mechanical properties by using a low cost fractured tungsten carbide sintered product in place of the expensive coarse tungsten carbide produced by the casting process in the manufacture of overlay electrodes with a large amount of tungsten carbide added. Cost reduction effect
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106180971A (en) * | 2016-08-25 | 2016-12-07 | 辽宁工程技术大学 | Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method |
CN115365706A (en) * | 2022-09-23 | 2022-11-22 | 浙江吉利控股集团有限公司 | Flux-cored wire, preparation method of flux-cored wire, welding method and application of flux-cored wire |
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1999
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106180971A (en) * | 2016-08-25 | 2016-12-07 | 辽宁工程技术大学 | Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method |
CN106180971B (en) * | 2016-08-25 | 2019-01-22 | 辽宁工程技术大学 | Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method |
CN115365706A (en) * | 2022-09-23 | 2022-11-22 | 浙江吉利控股集团有限公司 | Flux-cored wire, preparation method of flux-cored wire, welding method and application of flux-cored wire |
CN115365706B (en) * | 2022-09-23 | 2023-12-12 | 浙江吉利控股集团有限公司 | Flux-cored wire, preparation method of flux-cored wire, welding method and application of flux-cored wire |
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