CN106180971A - Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method - Google Patents

Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method Download PDF

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Publication number
CN106180971A
CN106180971A CN201610716067.4A CN201610716067A CN106180971A CN 106180971 A CN106180971 A CN 106180971A CN 201610716067 A CN201610716067 A CN 201610716067A CN 106180971 A CN106180971 A CN 106180971A
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tungsten carbide
based self
fluxing alloy
welding material
resurfacing welding
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CN106180971B (en
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孟媛媛
高志玉
李明伟
任瑞晨
王鹏
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Liaoning Technical University
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Liaoning Technical University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/04Welding for other purposes than joining, e.g. built-up welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/16Arc welding or cutting making use of shielding gas

Abstract

The invention discloses a kind of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method, described resurfacing welding material is the mixture of the tungsten carbide of Fe-based self-fluxing alloy and 20% 30% weight portions, and overlay cladding microscopic structure is by polygon tungsten carbide and eutectic composition.Overlaying method includes: the mix homogeneously in automatic mixing machine by Fe-based self-fluxing alloy and tungsten-carbide powder;Mixed-powder is mixed with waterglass, cold-press moulding, obtain coating;Coating is coated in matrix surface, puts into oven for drying, the most in atmosphere natural cooling;Utilizing carbon dioxide gas arc welding as thermal source, at mixed-powder described in matrix surface built-up welding, overlay cladding microscopic structure is by polygon tungsten carbide and a small amount of eutectic composition.Instant invention overcomes existing resurfacing welding material case hardness and the problem worn no resistance, it is thus achieved that high case hardness and wearability.

Description

Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method
Technical field
The invention belongs to alloy welding deposit field of material technology, specifically, relate to a kind of tungsten carbide Fe-based self-fluxing alloy heap Wlding material and overlaying method.
Background technology
Numerous parts life-time service and be on active service during the heavy wear of generating material surface and lost efficacy.Built-up welding is a kind of table Face modification processing method, refers to will have the alloy material of certain serviceability by certain thermal source means cladding at fertile material Surface, with give mother metal Special use performance or make part recover original geomery process.It can improve zero Part service life, common material surface is made to obtain wear-resisting, corrosion-resistant, the overlay cladding of high rigidity.Resurfacing welding material has iron-based from fusion Gold, nickel-based self-fluxing alloy, cobalt base self-fluxing alloy etc..But there is case hardness and the problem worn no resistance in existing resurfacing welding material.
Summary of the invention
In view of this, the present invention is directed to above-mentioned problem, it is provided that a kind of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and Overlaying method, overcomes existing resurfacing welding material case hardness and the problem worn no resistance, it is thus achieved that high case hardness and wearability.
In order to solve above-mentioned technical problem, the invention discloses a kind of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material, described Resurfacing welding material is the mixture of the tungsten carbide of Fe-based self-fluxing alloy and 20%-30% weight portion, and the granularity of tungsten carbide is 100-200 Mesh, overlay cladding microscopic structure is by polygon tungsten carbide and eutectic composition.
Further, described resurfacing welding material is 2-3mm at matrix surface overlay cladding thickness.
Further, described matrix is Q235 steel.
Further, described surfacing hardness value is 65.7HRC.
Further, described overlay cladding wear extent is 11.7mg.
Further, described Fe-based self-fluxing alloy is Fe314.
The invention also discloses the overlaying method of a kind of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material, including:
By tungsten-carbide powder mix homogeneously in automatic mixing machine of Fe-based self-fluxing alloy and 20%-30% weight portion, Mixed-powder;
Described mixed-powder is mixed with waterglass, cold-press moulding, obtain the mixed powder with regular shape, uniform thickness End coating;
Described coating is coated in matrix surface, puts into oven for drying, the most in atmosphere natural cooling;
Utilize carbon dioxide gas arc welding as thermal source, in mixed powder coat described in matrix surface built-up welding, it is thus achieved that Overlay cladding microscopic structure is by polygon tungsten carbide and a small amount of eutectic composition.
Further, described coating is coated in the thickness of matrix surface is 2-3mm.
Further, described flow of carbon dioxide gas amount controls as 10L/min.
Further, the technological parameter of described built-up welding is: wire feed rate is 0.35m/min, and welding current is 180A, electric arc Voltage is 25V, and electric power polarity is straight polarity direct current.
Compared with prior art, the present invention can obtain and include techniques below effect:
(1) present invention adds the carbon with characteristics such as high rigidity, high-wearing feature, high-melting-points in fe-based self-fluxing alloy powder Change tungsten, as resurfacing welding material, utilizes carbon-dioxide arc welding to carry out built-up welding as thermal source, overcomes existing resurfacing welding material case hardness With the problem worn no resistance, thus obtain high case hardness and wearability;Overlay cladding microscopic structure by polygon tungsten carbide and A small amount of eutectic composition, this type of organization can obtain high hardness and little wear extent.
(2) being 3mm when coating layer thickness, WC content reaches 30%, and overlay cladding microscopic structure is by polygon carbide (carbonization Tungsten) and a small amount of eutectic composition, hardness number reaches to be up to 65.7HRC, the minimum 11.7mg of wear extent.
Certainly, the arbitrary product implementing the present invention it is not absolutely required to reach all the above technique effect simultaneously.
Accompanying drawing explanation
Accompanying drawing described herein is used for providing a further understanding of the present invention, constitutes the part of the present invention, this Bright schematic description and description is used for explaining the present invention, is not intended that inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 is the overlay cladding metallographic structure of comparative example 1 of the present invention;
Fig. 2 is the overlay cladding metallographic structure of comparative example 2 of the present invention;
Fig. 3 is overlay cladding metallographic structure × 400 of the embodiment of the present invention 1;
Fig. 4 is overlay cladding metallographic structure × 400 of the embodiment of the present invention 2.
Detailed description of the invention
Embodiments of the present invention are described in detail, thereby to the present invention how application technology hands below in conjunction with embodiment Section solves technical problem and reaches the process that realizes of technology effect and can fully understand and implement according to this.
The present invention provides a kind of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material, described resurfacing welding material be Fe-based self-fluxing alloy and The mixture of the tungsten carbide of 20%-30% weight portion, the granularity of tungsten carbide is 100-200 mesh, and overlay cladding microscopic structure is by polygonal Shape tungsten carbide and a small amount of eutectic composition.
Wherein, the weight portion of tungsten-carbide powder is the weight relative to Fe-based self-fluxing alloy, adds WC and can make metal material Material case hardness, wearability improve, and can be applicable to hardness and wearability and require high occasion, but the too high meeting of tungsten carbide content Causing overlay cladding and mother metal i.e. Fe314 metallurgical binding bad, therefore tungsten carbide consumption selects 20%-30%.The granularity of tungsten carbide OK range, the excessive or too small wearability that all can reduce, the therefore granularity selection 100-200 mesh of tungsten carbide need to be selected.
Preferably, resurfacing welding material is 2-3mm at matrix surface overlay cladding thickness.Wherein, thickness is the least causes overlay cladding to be subject to The impact of mother metal dilution rate is big, reduces performance, and thickness causes the most greatly not weld penetration or overlay cladding bad with mother metal metallurgical binding, because of This thickness selects 2-3mm.
Preferably, described surfacing hardness value is 65.7HRC.
Preferably, described overlay cladding wear extent is 11.7mg.
Matrix material used in the present embodiment is Q235 steel, and specimen size is processed into 100mm × 40mm × 10mm, composition Such as table 1.
Table 1Q235 composition of steel (mass fraction, %)
Used by the present embodiment, the Fe base self-fluxing alloy trade mark is Fe314 (composition is shown in Table 2), is high-chromium cast iron-type iron-based self-fluxing nature Alloy powder, belongs to Fe-Cr-B-Si system self-fluxing alloy, is interpolation B, Si, Ni on the basis of rich chromium cast iron antifriction alloy composition Develop Deng element.
The self-fluxing alloy composition (mass fraction, %) of table 2Fe314
The present invention also provides for the overlaying method of a kind of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material, comprises the following steps:
Step 1: the tungsten-carbide powder (granularity is 100-200 mesh) of Fe-based self-fluxing alloy and 20%-30% weight portion is existed Mix homogeneously in automatic mixing machine, obtains mixed-powder;Wherein the weight portion of tungsten-carbide powder is relative to Fe-based self-fluxing alloy Weight.
Step 2: mixed with a certain amount of waterglass by described mixed-powder, cold-press moulding, obtains having regular shape, all The mixed powder coat of even thickness;Wherein waterglass plays the effect of bonding, and its consumption is moderate, and waterglass consumption is with mixed-powder Can be advisable by bulk.
Owing to using CO 2 gas-shielded built-up welding, the alloy powder granularity relatively little Yi quilt being deposited in before striking on mother metal Air-flow dispels.After striking, carbon dioxide gas arc welding blow force of arc is relatively big, when welding torch moves, can will be coated on specimen surface Powder push ahead, cause weld overlay alloy component distributing uneven, therefore mixed-powder and a certain amount of waterglass mixed, Cold-press moulding, obtains the mixed powder coat with regular shape, uniform thickness.
Step 3: described coating is coated in matrix surface, puts into oven for drying, the most in atmosphere natural cooling;
Step 4: utilize carbon dioxide gas arc welding as thermal source, in mixed powder coat described in matrix surface built-up welding, The overlay cladding microscopic structure obtained is by polygon tungsten carbide and a small amount of eutectic composition.Wherein polygon tungsten carbide and a small amount of eutectic Type of organization can obtain high hardness and little wear extent.
Further, described coating is coated in the thickness of matrix surface is 2-3mm.
Further, described flow of carbon dioxide gas amount controls as 10L/min.
Further, the hardness number of overlay cladding is 65.7HRC to the maximum, the minimum 11.7mg of wear extent.
Further, the technological parameter of described built-up welding is: welding wire is high manganese welding wire H08Mn2SiA, and gage of wire is 1.0mm, wire feed rate is 0.35m/min, and welding current is 180A, and arc voltage is 25V, and electric power polarity is straight polarity direct current.
Embodiment 1
Step 1: the tungsten-carbide powder of Fe-based self-fluxing alloy Fe314 and 20% weight portion is mixed all in automatic mixing machine Even, obtain mixed-powder;
Step 2: mixed with a certain amount of waterglass by described mixed-powder, cold-press moulding, obtains having regular shape, all The mixed powder coat of even thickness;
Step 3: described coating is coated in matrix Q235 steel surface, and applied thickness is 3mm, puts into oven for drying, then Natural cooling in atmosphere;
Step 4: utilizing carbon dioxide gas arc welding as thermal source, controlling flow of carbon dioxide gas amount is 10L/min, Mixed powder coat described in matrix Q235 steel surface overlaying, overlay cladding microscopic structure is by polygon tungsten carbide and a small amount of eutectic group Become.The technological parameter of built-up welding is: welding wire is high manganese welding wire H08Mn2SiA, and gage of wire is 1.0mm, and wire feed rate is 0.35m/ Min, welding current is 180A, and arc voltage is 25V, and electric power polarity is straight polarity direct current.
Embodiment 2
Step 1: the tungsten-carbide powder of Fe-based self-fluxing alloy Fe314 and 30% weight portion is mixed all in automatic mixing machine Even, obtain mixed-powder;
Step 2: mixed with a certain amount of waterglass by described mixed-powder, cold-press moulding, obtains having regular shape, all The mixed powder coat of even thickness;
Step 3: described coating is coated in matrix Q235 steel surface, and applied thickness is 3mm, puts into oven for drying, then Natural cooling in atmosphere;
Step 4: utilizing carbon dioxide gas arc welding as thermal source, controlling flow of carbon dioxide gas amount is 10L/min, Mixed powder coat described in matrix Q235 steel surface overlaying, overlay cladding microscopic structure is by polygon tungsten carbide and a small amount of eutectic group Become.The technological parameter of built-up welding is: welding wire is high manganese welding wire H08Mn2SiA, and gage of wire is 1.0mm, and wire feed rate is 0.35m/ Min, welding current is 180A, and arc voltage is 25V, and electric power polarity is straight polarity direct current.
Embodiment 3
Step 1: the tungsten-carbide powder of Fe-based self-fluxing alloy Fe314 and 20% weight portion is mixed all in automatic mixing machine Even, obtain mixed-powder;
Step 2: mixed with a certain amount of waterglass by described mixed-powder, cold-press moulding, obtains having regular shape, all The mixed powder coat of even thickness;
Step 3: described coating is coated in matrix Q235 steel surface, and applied thickness is 2mm, puts into oven for drying, then Natural cooling in atmosphere;
Step 4: utilizing carbon dioxide gas arc welding as thermal source, controlling flow of carbon dioxide gas amount is 10L/min, Mixed powder coat described in matrix Q235 steel surface overlaying, overlay cladding microscopic structure is by polygon tungsten carbide and a small amount of eutectic group Become.The technological parameter of built-up welding is: welding wire is high manganese welding wire H08Mn2SiA, and gage of wire is 1.0mm, and wire feed rate is 0.35m/ Min, welding current is 180A, and arc voltage is 25V, and electric power polarity is straight polarity direct current.
Embodiment 4
Step 1: the tungsten-carbide powder of Fe-based self-fluxing alloy Fe314 and 25% weight portion is mixed all in automatic mixing machine Even, obtain mixed-powder;
Step 2: mixed with a certain amount of waterglass by described mixed-powder, cold-press moulding, obtains having regular shape, all The mixed powder coat of even thickness;
Step 3: described coating is coated in matrix Q235 steel surface, and applied thickness is 3mm, puts into oven for drying, then Natural cooling in atmosphere;
Step 4: utilizing carbon dioxide gas arc welding as thermal source, controlling flow of carbon dioxide gas amount is 10L/min, Mixed powder coat described in matrix Q235 steel surface overlaying, overlay cladding microscopic structure is by polygon tungsten carbide and a small amount of eutectic group Become.The technological parameter of built-up welding is: welding wire is high manganese welding wire H08Mn2SiA, and gage of wire is 1.0mm, and wire feed rate is 0.35m/ Min, welding current is 180A, and arc voltage is 25V, and electric power polarity is straight polarity direct current.
Comparative example 1
By Fe-based self-fluxing alloy Fe314, without tungsten carbide, carrying out built-up welding on matrix Q235 steel surface, coating layer thickness is 2mm, remaining condition is same as in Example 1.
Comparative example 2
By Fe-based self-fluxing alloy Fe314, without tungsten carbide, carrying out built-up welding on matrix Q235 steel surface, coating layer thickness is 3mm, remaining condition is same as in Example 1.
The sample of heap postwelding is polished, polishing, then the nital corrosion sample with 4%, vertical in XJL-024 type Overlay cladding microscopic structure is observed on metallurgical microscope.Utilize the Rockwell hardness of HR150-A type Rockwell hardness machine test overlay cladding, often Three numerical value surveyed by individual sample, then calculate the meansigma methods Rockwell hardness as this sample.Disc type abrasive test is sold at ML-100 Carry out abrasive grain wear test on machine, the sample before and after abrasion is placed on electronic balance weighing, calculates wear extent.
Test result:
(1) overlay cladding Metallographic Analysis
Fig. 1 is the Fe314 overlay cladding microscopic structure of comparative example 1 coating layer thickness 2mm, and it is organized as primary austenite and is added few Amount eutectic, is a kind of hypoeutectic structure;Fig. 2 is the Fe314 surfacing layer of comparative example 2 coating layer thickness 3mm, and it is typical mistake Eutectic structure, has a small amount of alloyed cementite (white strip phase) on a large amount of eutectic structure matrixes, and alloyed cementite should For (Fe, Cr)3C, remaining tissue should be the eutectic of Various Complex compound, such as carbide and boride etc., the most relatively, Fig. 2 surfacing layer is similar with Fe314, is still high-chromium alloy cast-iron type, and this increases heap mainly due to along with coating layer thickness The reason that layer tissue is reduced by mother metal diluting effect.Fig. 3 is embodiment 1 coating layer thickness 3mm, the overlay cladding group containing 20%WC Knitting, have a small amount of nascent solid solution dendrite and a large amount of eutectic structure in tissue, this explanation dilution rate is less, overlay cladding composition close to The primitive component of self-fluxing alloy, may melt due to the highest WC of WC content again in weld deposit process;Fig. 4 is that embodiment 2 is coated with Layer thickness 3mm, the surfacing layer containing 30%WC, this tissue is the most typical, is by polygon carbide (tungsten carbide) and a small amount of Eutectic composition, according to relevant information analysis, polygonal for tungsten carbide, strip for alloyed cementite, and these compounds It is to separate out under solid phase and grow up.
(2) surfacing hardness analysis
Surfacing hardness value when table 3 is different coating thickness and different WC content, from table 3 it is observed that work as alloyed powder End increases with the increase of coating layer thickness without the hardness of overlay surface during WC, it can be seen that work as and be coated with from metallograph When layer thickness is 3mm, surfacing layer is hypereutectic tissue, has (Fe, Cr) in tissue3C-type carbide and austenite and carbon boron The eutectic structure of compound, therefore when coating layer thickness is 3mm, hardness is higher;When coating layer thickness is that 3mm is constant, Fe314 adds When entering WC, the hardness of overlay surface increases along with the increase of WC content, has part WC particle in built-up welding when WC content is less Shi Fasheng melts, and has a large amount of eutectic in its metallographic structure, and therefore hardness number is the highest.When WC content reaches 30%, by gold Phase constitution it can be seen that there is a large amount of WC particle in Zu Zhi, the dispersion-strengthened action of these hard particles, make alloy welding deposit layer have Higher wearability, red hardness and non-oxidizability, therefore when WC content is 30%, surfacing hardness value is 65.7HRC to the maximum.
Table 3 surfacing hardness
(3) overlay cladding Analysis on Wear
The abrasion value of overlay cladding when table 4 is different coating thickness and different WC content, generally, material is the hardest, Wearability is the best, from table it can also be seen that, when in alloy powder without WC, during coating layer thickness 3mm, hardness number is the highest, wear extent Minimum, when coating layer thickness 3mm is constant, when WC content reaches 30%, hardness number is the highest, and wear extent is minimum.WC is superhard hard Matter phase, the hard phase WC in overlay cladding can make the hardness of sample overlay surface increase substantially, and wear extent drastically declines.
Table 4 overlay cladding wear extent
In sum, when coating layer thickness is 3mm, and WC content reaches 30%, and overlay cladding microscopic structure is by polygon carbide (tungsten carbide) and a small amount of eutectic composition, hardness number reaches to be up to 65.7HRC, the minimum 11.7mg of wear extent.
The present invention adds the carbonization with characteristics such as high rigidity, high-wearing feature, high-melting-points in fe-based self-fluxing alloy powder Tungsten, as resurfacing welding material, utilizes carbon-dioxide arc welding to carry out built-up welding as thermal source, overcomes existing resurfacing welding material case hardness With the problem worn no resistance, it is thus achieved that high case hardness and wearability.
Described above illustrate and describes some preferred embodiments of invention, but as previously mentioned, it should be understood that invention is not It is confined to form disclosed herein, is not to be taken as the eliminating to other embodiments, and can be used for other combinations various, amendment And environment, and can be carried out by above-mentioned teaching or the technology of association area or knowledge in invention contemplated scope described herein Change.And the change that those skilled in the art are carried out and change are without departing from the spirit and scope of invention, the most all should weigh appended by invention In the protection domain that profit requires.

Claims (10)

1. tungsten carbide Fe-based self-fluxing alloy resurfacing welding material, it is characterised in that described resurfacing welding material is Fe-based self-fluxing alloy and 20%- The mixture of the tungsten carbide of 30% weight portion, the granularity of tungsten carbide is 100-200 mesh, and overlay cladding microscopic structure is by polygon carbonization Tungsten and eutectic composition.
2. tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 1, it is characterised in that described resurfacing welding material is at base Surface overlay cladding thickness is 2-3mm.
3. tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 2, it is characterised in that described matrix is Q235 Steel.
4. tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 2, it is characterised in that described surfacing hardness value For 65.7HRC.
5. the tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as described in claim 2 or 4, it is characterised in that described overlay cladding grinds Damage amount is 11.7mg.
6. tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 1, it is characterised in that described Fe-based self-fluxing alloy For Fe314.
7. the overlaying method of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material, it is characterised in that including:
By tungsten-carbide powder mix homogeneously in automatic mixing machine of Fe-based self-fluxing alloy and 20%-30% weight portion, obtain mixing Powder;
Described mixed-powder is mixed with waterglass, cold-press moulding, obtain the mixed-powder painting with regular shape, uniform thickness Layer;
Described coating is coated in matrix surface, puts into oven for drying, the most in atmosphere natural cooling;
Utilize carbon dioxide gas arc welding as thermal source, in mixed powder coat described in matrix surface built-up welding, it is thus achieved that built-up welding Layer microscopic structure is by polygon tungsten carbide and a small amount of eutectic composition.
8. the overlaying method of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 7, it is characterised in that described painting It is 2-3mm that layer is coated in the thickness of matrix surface.
9. the overlaying method of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 7, it is characterised in that described two Carbon oxide gas flow-control is 10L/min.
10. the overlaying method of tungsten carbide Fe-based self-fluxing alloy resurfacing welding material as claimed in claim 7, it is characterised in that described The technological parameter of built-up welding is: wire feed rate is 0.35m/min, and welding current is 180A, and arc voltage is 25V, and electric power polarity is Straight polarity direct current.
CN201610716067.4A 2016-08-25 2016-08-25 Tungsten carbide Fe-based self-fluxing alloy resurfacing welding material and overlaying method Expired - Fee Related CN106180971B (en)

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CN107175388A (en) * 2017-05-17 2017-09-19 苏州南尔材料科技有限公司 A kind of overlaying method of carbon doping composite hardfacing materials
CN108385104A (en) * 2018-03-30 2018-08-10 燕山大学 A kind of restorative procedure of automobile castellated shaft
CN112839757A (en) * 2018-10-17 2021-05-25 株式会社神户制钢所 Method for laminating hardened layer and method for manufacturing laminated molded article
CN111843106A (en) * 2020-06-23 2020-10-30 苏州优霹耐磨复合材料有限公司 Overlaying welding dilution compensation process
CN113118603A (en) * 2021-04-07 2021-07-16 南京理工大学 Method for manufacturing high-hardness impact-resistant structure by utilizing wire multi-heat-source heating

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