KR20010056613A - Process for preparing polyester/polyamide composit yarn having the property of drawn yarn - Google Patents

Process for preparing polyester/polyamide composit yarn having the property of drawn yarn Download PDF

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Publication number
KR20010056613A
KR20010056613A KR1019990058157A KR19990058157A KR20010056613A KR 20010056613 A KR20010056613 A KR 20010056613A KR 1019990058157 A KR1019990058157 A KR 1019990058157A KR 19990058157 A KR19990058157 A KR 19990058157A KR 20010056613 A KR20010056613 A KR 20010056613A
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South Korea
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yarn
polyester
polyamide
hot tube
composite
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KR1019990058157A
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Korean (ko)
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김용섭
이민석
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조 정 래
주식회사 효성
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Priority to KR1019990058157A priority Critical patent/KR20010056613A/en
Publication of KR20010056613A publication Critical patent/KR20010056613A/en

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/084Heating filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

PURPOSE: A process for preparing a polyester/polyamide composite yarn capable of expressing physical properties of a drawn yarn by only first-stage process without passing through separate drawing processes is provided, which has the advantages of reduction of manufacturing costs, increase of yield and reduction of installation costs of a drawing machine. CONSTITUTION: In manufacturing a composite yarn by composite-spinning polyamide and polyester in a weight ratio of 15:85 to 85:15, filaments are heat-treated by passing through a hot tube(4) in the range of 100 to 200deg.C before winding at a speed of 3,000 to 4,500m/min after spinning. The hot tube having an inner diameter of 20 to 100mm is installed between a spinning nozzle(1) and an oiling guide(6).

Description

연신사의 물성이 발현되는 폴리에스테르/폴리아미드 복합사의 제조방법 및 그 장치{Process for preparing polyester/polyamide composit yarn having the property of drawn yarn}Process for preparing polyester / polyamide composite yarn expressing physical properties of stretched yarn and its device {Process for preparing polyester / polyamide composit yarn having the property of drawn yarn}

본 발명은 폴리아미드와 폴리에스테르를 원료로 하여 복합 방사함에 있어서 방사노즐과 POY(Partially Oriented Yarn, 부분배향사)용 와인더 사이에 핫튜브(Hot Tube)를 장착하여 권취함으로서 부분배향사 물성이 아닌 연신사의 물성이 발현되는 폴리에스테르/폴리아미드 복합사를 1 단계 공정으로 제조하는 방법 및 그 장치에 관한 것이다.The present invention provides a partial orientation of yarn properties by mounting a hot tube between a spinning nozzle and a winder for POY (Partially Oriented Yarn) in composite spinning with polyamide and polyester as raw materials. It relates to a method and a device for producing a polyester / polyamide composite yarn in which the physical properties of the drawn yarn is expressed in a one step process.

일반적으로 폴리아미드와 폴리에스테르를 복합방사하여 권취하면, 미연신사나 부분배향사가 얻어진다.In general, when polyamide and polyester are wound by composite spinning, an undrawn yarn or a partially oriented yarn is obtained.

이렇게 얻어진 복합섬유는 별도의 연신 공정이나 가연공정을 거쳐야만 연신사의 물성을 지니게 된다.The composite fiber thus obtained will have the properties of the drawn yarn only through a separate drawing process or a twisting process.

그런데 기존의 방법으로 생산된 미연신사나 부분배향사는 시간의 경과에 따라 물성이 취약되게 되므로 장기간 보관할 수 없고 별도의 연신 공정을 거쳐야 하므로 제조 경비의 상승 및 수율 저하를 초래한다.However, undrawn yarn or partial oriented yarn produced by the conventional method becomes vulnerable over time, so it cannot be stored for a long time and requires a separate drawing process, which leads to an increase in manufacturing cost and a decrease in yield.

본 발명의 목적은 상기와 같은 문제점을 해결하기 위한 것으로, 폴리아미드 /폴리에스테르 복합사를 제조함에 있어서, 별도의 연신공정을 거치지 않더라도 1 단계 공정만으로 연신사의 물성을 발현시키는 폴리에스테르/폴리아미드 복합사를 제조할 수 있는 방법 및 그 장치를 제공하는데 있는 것이다.An object of the present invention is to solve the above problems, in the production of polyamide / polyester composite yarns, polyester / polyamide composites to express the physical properties of the stretched yarn in a one-step process only without a separate stretching process It is to provide a method and apparatus for manufacturing the yarn.

도 1 은 본 발명의 제조공정 개략도.1 is a manufacturing process schematic diagram of the present invention.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

1 : 방사노즐, 2 : 냉각풍, 3 : 복합사 필라멘트, 4 : 핫튜브(Hot Tube),1: spinning nozzle, 2: cooling wind, 3: composite yarn filament, 4: hot tube,

4' : 핫튜브 인입구, 5 : 열원(Heat Source), 6 : 오일링 가이드,4 ': hot tube inlet, 5: Heat Source, 6: oiling guide,

7 : 권취기7: winder

본 발명은 폴리아미드와 폴리에스터를 15 : 85 ∼ 85 : 15의 중량비로 복합 방사하여 복합사의 단면을 갖도록 노즐 구금(1)을 통과시키고 냉각풍(2)으로 고화시킨 후에 100 ∼ 200℃의 열이 가해진 핫튜브(Hot Tube)(4)를 통과시킨 다음 3000 ∼ 4500m/분의 속도로 권취기(7)에서 권취함으로서 연신사의 물성이 발현되도록 하는 방법 및 그 장치에 관한 것이다.The present invention is a composite spinning of polyamide and polyester at a weight ratio of 15: 85 to 85: 15 to pass through the nozzle cap (1) to have a cross-section of the composite yarn and to solidify with a cooling wind (2) heat of 100 ~ 200 ℃ The present invention relates to a method and an apparatus for causing physical properties of a stretched yarn to be expressed by winding the applied hot tube 4 and then winding it in the winder 7 at a speed of 3000 to 4500 m / min.

본 발명에서 핫튜브 인입구(4')의 위치를 필라멘트의 고화점보다 높게 설치하면 필라멘트간에 융착이 발생되어 원하는 결과를 얻을 수 없으며, 핫튜브(4)의 내부온도가 100℃ 미만이면 연신사의 물성 발현이 미흡하며, 200℃를 넘게 되면 핫튜브(4) 내부에서 필라멘트의 융착이 발생한다.In the present invention, if the position of the hot tube inlet 4 'is set higher than the filament's solidification point, fusion occurs between the filaments, and the desired result cannot be obtained. If the internal temperature of the hot tube 4 is less than 100 ° C, When the expression is insufficient, fusing of filament occurs inside the hot tube 4 when it exceeds 200 ° C.

핫튜브(4)의 내부온도가 높을수록 연신사의 물성에 가깝게 근접하게 되는 결과를 얻을 수 있었으나 온도를 일정 수준 이상으로 올리게 되면 핫튜브(4) 내에서 필라멘트의 융착이 발생하게 되므로 온도 상승에는 한계가 있게 된다.The higher the internal temperature of the hot tube 4 was, the closer the physical properties of the drawn yarn were. However, if the temperature is raised above a certain level, the filament is fused in the hot tube 4, so the temperature rise is limited. Will be.

또한 본 발명에 있어서 권취속도가 높을수록 연신사의 물성에 가깝게 근접시킬 수 있는 결과를 얻을 수 있었다.In addition, the higher the winding speed in the present invention was able to obtain a result that can be closer to the physical properties of the drawn yarn.

그러나 권취속도가 3000m/분보다 작으면 신도가 높게되어 연신사의 물성이 발현되지 않으며, 4500m/분 보다 크게 되면 강도와 신도가 동시에 떨어져서 물성이 취약하게 된다.However, if the winding speed is less than 3000m / min, the elongation is high, the physical properties of the stretched yarn is not expressed, and if it is larger than 4500m / min, strength and elongation fall at the same time, the physical properties are vulnerable.

본 발명에 있어서 핫튜브(4)의 내부 직경은 20 ∼100㎜로서 방사되는 섬유의 굵기 및 필라멘트 수에 따라서 조절할 수 있다.In the present invention, the inner diameter of the hot tube 4 can be adjusted according to the thickness and the number of filaments of the fiber spun as 20 to 100mm.

그러나 20㎜ 미만에서는 핫튜브(4) 내부에서 필라멘트의 융착 발생이 심해지며, 100㎜를 넘게되면 핫튜브(4)의 중심부를 통과하는 필라멘트와 핫튜브(4) 내벽과의 거리가 멀어져서 신속한 열전달이 이루어지지 않기 때문에 연신사의 물성 발현이 어렵게 된다.However, if less than 20mm, the filament fusion occurs in the hot tube (4), and if it exceeds 100mm, the distance between the filament passing through the center of the hot tube (4) and the inner wall of the hot tube (4) is rapidly Since the heat transfer is not made, it is difficult to express the physical properties of the drawn yarn.

실시예 1Example 1

폴리에스터와 폴리아미드를 8:2(중량비)의 비율로 복합방사하여 75데니어/36필라멘트의 복합사가 되도록 3200m/분의 속도로 권취함에 있어서, 방사노즐(1) 하부에 설치된 핫튜브(4)의 온도 변화에 따른 물성 변화를 평가하여 그 결과를 표 1 에 나타내었다.A hot tube (4) installed under the spinneret (1), in which the polyester and polyamide are spun at a ratio of 8: 2 (weight ratio) and wound at a speed of 3200 m / min to be a composite yarn of 75 denier / 36 filaments. The change in physical properties according to the temperature change of and the results are shown in Table 1.

이때 사용한 핫튜브(4)의 내부 직경은 30㎜이며, 핫튜브 인입구(4')의 위치는 노즐 하부 100㎝ 지점에 설치하였다.The inner diameter of the hot tube 4 used at this time was 30 mm, and the position of the hot tube inlet 4 'was installed at a point 100 cm below the nozzle.

실시예 2Example 2

폴리에스터와 폴리아미드를 8 : 2의 비율로 복합방사하여 180℃로 설정된 내경 30㎜의 핫튜브(4)를 통과시켜 75데니어/36필라멘트의 복합사가 되도록 권취함에 있어서 권취속도의 변화에 따른 물성 변화를 평가하여 그 결과를 표 2 에 나타내었다.Physical properties of the polyester and polyamide in the ratio of 8: 2 and wound through the hot tube 4 having an inner diameter of 30 mm set at 180 ° C. to wind the composite yarn of 75 denier / 36 filaments The change was evaluated and the results are shown in Table 2.

실시예 3Example 3

폴리에스터와 폴리아미드를 8 : 2의 비율로 복합방사하여 170℃로 설정된 내경 60㎜의 핫튜브(4)를 통과시켜 150데니어/72필라멘트의 복합사가 되도록 권취함에 있어서 권취속도의 변화에 따른 물성 변화를 평가하여 그 결과를 표 3 에 나타내었다.Physical properties according to the change of winding speed in winding the composite yarn of polyester and polyamide at a ratio of 8: 2 and passing them through a hot tube 4 having an inner diameter of 60 mm set at 170 ° C. to composite yarn of 150 denier / 72 filaments. The change was evaluated and the results are shown in Table 3.

비교예 1Comparative Example 1

핫튜브를 사용하지 않은 것을 제외하고는 실시예 1과 동일하며 그 결과를 표 1에 함께 나타내었다.Except that the hot tube was not used, the same as in Example 1 and the results are shown in Table 1 together.

비교예 2Comparative Example 2

폴리에스터와 폴리아미드를 8 : 2의 비율로 복합방사하여 230데니어/72필라멘트의 복합사가 되도록 3200m/분에서 권취하고 별도의 연신 공정을 거쳐서 최종적으로 150데니어/72필라멘트의 복합사를 제조하였다.Polyester and polyamide were spun at a ratio of 8: 2 to be wound at 3200 m / min to be a composite yarn of 230 denier / 72 filaments, and finally, a composite yarn of 150 denier / 72 filaments was finally manufactured through a separate drawing process.

그 결과를 표 3에 함께 나타내었다.The results are shown in Table 3 together.

표 1Table 1

실시예 1Example 1 비교예 1Comparative Example 1 핫튜브온도(℃)Hot tube temperature (℃) 140140 160160 180180 미적용Unapplied 강도(g/d)Strength (g / d) 3.53.5 3.73.7 4.14.1 3.13.1 신도()Shinto () 6565 5959 6565 131131 10강도(g/d)10 intensity (g / d) 1.411.41 1.811.81 1.881.88 0.440.44

표 2TABLE 2

실시예 2Example 2 권취속도(m/분)Winding speed (m / min) 34003400 37003700 39003900 45004500 강도(g/d)Strength (g / d) 3.493.49 3.563.56 3.523.52 3.143.14 신도()Shinto () 4848 4242 3838 2626 10강도(g/d)10 intensity (g / d) 1.981.98 2.062.06 2.262.26 2.382.38

표 3TABLE 3

실시예 3Example 3 비교예 2Comparative Example 2 권취속도(m/분)Winding speed (m / min) 39003900 40004000 41004100 42004200 32003200 핫튜브온도(℃)Hot tube temperature (℃) 170170 170170 170170 170170 미적용Unapplied 연신공정Drawing process 불필요Unnecessary 불필요Unnecessary 불필요Unnecessary 불필요Unnecessary 별도적용Separately applied 강도(g/d)Strength (g / d) 3.813.81 3.783.78 3.863.86 3.873.87 4.64.6 신도()Shinto () 5454 5151 5050 4949 4343 10강도(g/d)10 intensity (g / d) 1.991.99 2.042.04 2.192.19 2.192.19 2.382.38

본 발명에 의한 복합사는 방사와 동시에 연신사의 물성이 얻어지므로 미연신사나 부분배향사에서 문제시되는 장기 보존의 문제점을 해결할 수 있고, 별도의 연신 공정을 거치지 않기 때문에 공정 단축에 의한 제조 비용 절감, 수율 상승, 연신기 설치비용의 절감 등의 장점이 있다.The composite yarn according to the present invention obtains the properties of the stretched yarn at the same time as spinning, which can solve the problem of long-term preservation that is a problem in the unstretched or partially oriented yarn. There are advantages such as rising, reducing the installation cost of the drawing machine.

Claims (4)

폴리아미드와 폴리에스터를 15 : 85 ∼ 85 : 15의 중량비로 복합 방사하여 복합섬유를 제조함에 있어서, 방사 후 권취전에 100 ∼ 200℃의 온도범위를 갖는 핫튜브(Hot Tube)(4)에 필라멘트를 통과시켜서 열처리함을 특징으로 하는 연신사의 물성이 발현되는 폴리에스테르/폴리아미드 복합사의 제조방법.In manufacturing composite fiber by composite spinning polyamide and polyester at a weight ratio of 15: 85 to 85: 15, the filament in a hot tube (4) having a temperature range of 100 to 200 ℃ before winding after spinning Method for producing a polyester / polyamide composite yarn characterized in that the physical properties of the drawn yarn characterized in that the heat treatment by passing through. 제 1 항에 있어서, 권취속도는 3000 ∼ 4500m/분임을 특징으로 하는 연신사의 물성이 발현되는 폴리에스테르/폴리아미드 복합사의 제조방법.The method for producing a polyester / polyamide composite yarn according to claim 1, wherein the winding speed is 3000 to 4500 m / min. 폴리에스테르/폴리아미드 복합사의 제조장치로서, 방사노즐(1)과 오일링가이드(6) 사이에 핫튜브(4)가 설치되어 있는 것을 특징으로 하는 연신사의 물성이 발현되는 폴리에스테르/폴리아미드 복합사의 제조장치.An apparatus for producing a polyester / polyamide composite yarn, comprising: a polyester / polyamide composite having a physical property of a drawn yarn characterized in that a hot tube (4) is provided between a spinning nozzle (1) and an oil ring guide (6). Manufacturing equipment. 제 3 항에 있어서, 핫튜브(4)의 내경이 20 ∼ 100㎜임을 특징으로 하는 연신사의 물성이 발현되는 폴리에스테르/폴리아미드 복합사의 제조장치.4. The apparatus for producing polyester / polyamide composite yarn according to claim 3, wherein the physical properties of the drawn yarns are characterized in that the inner diameter of the hot tube (4) is 20 to 100 mm.
KR1019990058157A 1999-12-16 1999-12-16 Process for preparing polyester/polyamide composit yarn having the property of drawn yarn KR20010056613A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013103195A1 (en) * 2012-01-04 2013-07-11 (주)보광 System for manufacturing conjugate yarn and method for doubling conjugate yarn using same
KR101314340B1 (en) * 2011-12-08 2013-10-10 성안합섬주식회사 Preparation method for different shrinkage blended yarn having excellant deep coloration using hot tube system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101314340B1 (en) * 2011-12-08 2013-10-10 성안합섬주식회사 Preparation method for different shrinkage blended yarn having excellant deep coloration using hot tube system
WO2013103195A1 (en) * 2012-01-04 2013-07-11 (주)보광 System for manufacturing conjugate yarn and method for doubling conjugate yarn using same

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