KR20010041159A - 유기 금속액 흡수제를 사용하는 열펌프 - Google Patents
유기 금속액 흡수제를 사용하는 열펌프 Download PDFInfo
- Publication number
- KR20010041159A KR20010041159A KR1020007009209A KR20007009209A KR20010041159A KR 20010041159 A KR20010041159 A KR 20010041159A KR 1020007009209 A KR1020007009209 A KR 1020007009209A KR 20007009209 A KR20007009209 A KR 20007009209A KR 20010041159 A KR20010041159 A KR 20010041159A
- Authority
- KR
- South Korea
- Prior art keywords
- liquid
- gas
- heat
- desorber
- cooling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 227
- 239000002250 absorbent Substances 0.000 title claims abstract description 73
- 230000002745 absorbent Effects 0.000 title claims abstract description 72
- 125000002524 organometallic group Chemical group 0.000 title claims abstract description 47
- 238000001816 cooling Methods 0.000 claims abstract description 74
- 239000006096 absorbing agent Substances 0.000 claims abstract description 65
- 238000000034 method Methods 0.000 claims abstract description 35
- 230000008569 process Effects 0.000 claims abstract description 24
- 238000000926 separation method Methods 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 178
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 85
- 238000010521 absorption reaction Methods 0.000 claims description 61
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 52
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 42
- 239000000112 cooling gas Substances 0.000 claims description 37
- 238000001179 sorption measurement Methods 0.000 claims description 31
- 229910052758 niobium Inorganic materials 0.000 claims description 26
- 239000010955 niobium Substances 0.000 claims description 26
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 26
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 23
- 239000003446 ligand Substances 0.000 claims description 23
- 239000003638 chemical reducing agent Substances 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 239000007858 starting material Substances 0.000 claims description 12
- 238000003795 desorption Methods 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 5
- 239000012043 crude product Substances 0.000 claims description 5
- 238000010408 sweeping Methods 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- 238000004378 air conditioning Methods 0.000 claims description 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 4
- -1 methylcyclopentadienyl Chemical group 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 238000007791 dehumidification Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 150000002596 lactones Chemical class 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000009972 noncorrosive effect Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 231100001261 hazardous Toxicity 0.000 abstract 1
- 239000003570 air Substances 0.000 description 13
- 239000006193 liquid solution Substances 0.000 description 11
- 239000011572 manganese Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 208000024780 Urticaria Diseases 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000002441 reversible effect Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 238000006467 substitution reaction Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003507 refrigerant Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
- 230000009931 harmful effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 239000000110 cooling liquid Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 229910052987 metal hydride Inorganic materials 0.000 description 2
- 150000004681 metal hydrides Chemical class 0.000 description 2
- 230000003071 parasitic effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 235000006520 Borassus flabellifer Nutrition 0.000 description 1
- 244000208235 Borassus flabellifer Species 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000000147 hypnotic effect Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000007040 multi-step synthesis reaction Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/16—Materials undergoing chemical reactions when used
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/12—Sorption machines, plants or systems, operating continuously, e.g. absorption type with resorber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B25/00—Machines, plants or systems, using a combination of modes of operation covered by two or more of the groups F25B1/00 - F25B23/00
- F25B25/02—Compression-sorption machines, plants, or systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B30/00—Heat pumps
- F25B30/04—Heat pumps of the sorption type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/16—Sorption machines, plants or systems, operating continuously, e.g. absorption type using desorption cycle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/62—Absorption based systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Sorption Type Refrigeration Machines (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7541398P | 1998-02-20 | 1998-02-20 | |
| US60/075,413 | 1998-02-20 | ||
| PCT/US1998/024364 WO1999042538A1 (en) | 1998-02-20 | 1998-11-13 | Heat pumps using organometallic liquid absorbents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20010041159A true KR20010041159A (ko) | 2001-05-15 |
Family
ID=22125571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020007009209A Withdrawn KR20010041159A (ko) | 1998-02-20 | 1998-11-13 | 유기 금속액 흡수제를 사용하는 열펌프 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6389841B1 (enExample) |
| EP (1) | EP1060222A4 (enExample) |
| JP (1) | JP2003517490A (enExample) |
| KR (1) | KR20010041159A (enExample) |
| CN (1) | CN1291221A (enExample) |
| AU (1) | AU1460399A (enExample) |
| WO (1) | WO1999042538A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004324977A (ja) * | 2003-04-24 | 2004-11-18 | Sanyo Electric Co Ltd | 吸収式冷凍機 |
| TWI296323B (en) * | 2003-12-25 | 2008-05-01 | Ind Tech Res Inst | Constant temperature refrigeration system for extensive temperature range application and control method thereof |
| US7240492B2 (en) * | 2004-07-22 | 2007-07-10 | Sprint Communications Company L.P. | Fuel system used for cooling purposes |
| US7081687B2 (en) * | 2004-07-22 | 2006-07-25 | Sprint Communications Company L.P. | Power system for a telecommunications facility |
| US7629707B2 (en) * | 2005-06-15 | 2009-12-08 | Sprint Communications Company L.P. | Power system with hydrogen on demand |
| US7728458B2 (en) | 2006-01-05 | 2010-06-01 | Sprint Communications Company L.P. | Telecommunications megasite with backup power system |
| AT507617A1 (de) * | 2008-09-22 | 2010-06-15 | Otto Dr Preglau | Wärmepumpe |
| US10222078B2 (en) | 2009-11-23 | 2019-03-05 | Carrier Corporation | Method and device for air conditioning with humidity control |
| EP2348088A1 (en) | 2010-01-22 | 2011-07-27 | Continental Automotive GmbH | Cooling circuit and method for cooling a heat generating device |
| US8544284B2 (en) * | 2010-06-25 | 2013-10-01 | Petrochina North China Petrochemical Company | Method and apparatus for waste heat recovery and absorption gases used as working fluid therein |
| TWI405939B (zh) * | 2010-06-30 | 2013-08-21 | Chunghwa Telecom Co Ltd | 定頻冷凍空調冰水系統之冷凍能力調控方法 |
| WO2012006757A1 (zh) * | 2010-07-12 | 2012-01-19 | Liu Wenxiang | 低碳光化学系统 |
| KR101364691B1 (ko) * | 2012-12-28 | 2014-02-27 | 한국화학연구원 | 고압 반응장치 |
| US9951976B2 (en) * | 2014-06-05 | 2018-04-24 | University Of Florida Research Foundation, Inc. | Architecture for Absorption Based Heaters |
| US10961874B2 (en) | 2016-03-06 | 2021-03-30 | Husham Al-Ghizzy | Enhanced thermoutilizer |
| US20190249909A1 (en) * | 2016-04-01 | 2019-08-15 | Vasileios STYLIARAS | Heat pump and power production utilizing hydrated salts |
| GB201617508D0 (en) * | 2016-10-14 | 2016-11-30 | Cambridge Enterprise Limited And Universitat Polit�Cnica De Catalunya And Universitat De Barc | Use of Barocaloric materials and Barocaloric devices |
| JP2018077001A (ja) * | 2016-11-09 | 2018-05-17 | 東洋エンジニアリング株式会社 | ケミカルヒートポンプシステム |
| CN112254372B (zh) * | 2020-09-28 | 2022-04-26 | 东南大学 | 基于化学反应选择性吸收-压缩复合热泵循环装置及方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1960368A (en) * | 1931-05-25 | 1934-05-29 | Booth Harold Simmons | Artificial refrigeration |
| US2987529A (en) * | 1958-04-25 | 1961-06-06 | Ethyl Corp | Use of transition metal carbonyls in the manufacture of cyclopentadienyl manganese tricarbonyl |
| US3458445A (en) * | 1967-05-05 | 1969-07-29 | American Gas Ass | Absorption refrigeration system containing solutions of monoethylamine with thiocyanates |
| US4724101A (en) * | 1981-11-09 | 1988-02-09 | The Dow Chemical Company | Metal chelates of polymeric ferrocenes |
| US4646541A (en) * | 1984-11-13 | 1987-03-03 | Columbia Gas System Service Corporation | Absorption refrigeration and heat pump system |
| DE3723938A1 (de) * | 1987-07-20 | 1989-02-02 | Thermo Consulting Heidelberg | Resorptions-waermewandleranlage |
| USRE34259E (en) * | 1987-11-02 | 1993-05-25 | Rocky Research | System for low temperature refrigeration and chill storage using ammoniated complex compounds |
| US4952713A (en) * | 1988-06-02 | 1990-08-28 | Battelle Memorial Institute | Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation |
| US5057300A (en) * | 1988-06-02 | 1991-10-15 | Battelle Memorial Institute | Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation |
| US5241831A (en) * | 1989-11-14 | 1993-09-07 | Rocky Research | Continuous constant pressure system for staging solid-vapor compounds |
| US5026885A (en) * | 1990-03-06 | 1991-06-25 | Ethyl Corporation | Process for preparing transition metal cyclopentadienyl carbonyl compounds |
| US5225174A (en) * | 1991-12-11 | 1993-07-06 | Bend Research, Inc. | Nitrogen sorption |
| US5434116A (en) * | 1992-06-05 | 1995-07-18 | Tosoh Corporation | Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same |
| US5582020A (en) * | 1994-11-23 | 1996-12-10 | Mainstream Engineering Corporation | Chemical/mechanical system and method using two-phase/two-component compression heat pump |
| US5617739A (en) * | 1995-03-29 | 1997-04-08 | Mmr Technologies, Inc. | Self-cleaning low-temperature refrigeration system |
| US5723058A (en) * | 1996-04-01 | 1998-03-03 | Schuurman; Eiko A. | Absorbent compositions for refrigerating and heating systems |
-
1998
- 1998-11-13 US US09/622,625 patent/US6389841B1/en not_active Expired - Fee Related
- 1998-11-13 EP EP98958590A patent/EP1060222A4/en not_active Withdrawn
- 1998-11-13 KR KR1020007009209A patent/KR20010041159A/ko not_active Withdrawn
- 1998-11-13 AU AU14603/99A patent/AU1460399A/en not_active Abandoned
- 1998-11-13 WO PCT/US1998/024364 patent/WO1999042538A1/en not_active Ceased
- 1998-11-13 CN CN98813978A patent/CN1291221A/zh active Pending
- 1998-11-13 JP JP2000532485A patent/JP2003517490A/ja not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999042538A1 (en) | 1999-08-26 |
| EP1060222A1 (en) | 2000-12-20 |
| EP1060222A4 (en) | 2002-11-06 |
| CN1291221A (zh) | 2001-04-11 |
| AU1460399A (en) | 1999-09-06 |
| US6389841B1 (en) | 2002-05-21 |
| JP2003517490A (ja) | 2003-05-27 |
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