KR20010025618A - Method for powdering aqueous solutions of CMS to flowable state by mixing with coco-peat - Google Patents

Abstract

PURPOSE: Provided is a method for pulverizing liquid CMS by adding coco-peat to a sub-product liquid with high viscosity generated from cane molasses fermentation. Thereby, problems from using liquid CMS(Condensed Molasses Solubles), such as salt aggregation, difficulties in delivery, storage, application, and handling, ase solved and CMS is disposed in economical way. CONSTITUTION: A liquid CMS pulverizing method is characterized by comprising the steps of: adding coco-peat, which is sub-product of a coconut processing, to CMS which is a sub-product of a cane-molasses fermentation product, having abundant nutritive such as protein, amino acid, organic acid and the like and mixing them well, wherein 5-90wt%, preferably 10-50wt%, more preferably 15-40wt% of coco-peat based on the total weight of the composition is used in pulverizing the CMS liquid.

Description

Method for powdering aqueous solutions of CMS to flowable state by mixing with coco-peat}

The present invention is a by-product produced in the fermentation process that proceeds using molasses, mainly a powdered method of CMS obtained as a by-product such as amino acid fermentation or vitamin fermentation, fertilizer, soil improver and animal using the powdered CMS as an active ingredient More specifically, it relates to feed, and more particularly, liquid molasses fermentation by-products in powder form by adding cocoite crushed by-products of the coconut industry to a CMS containing a large amount of beneficial substances for soil and crops such as various organic substances, proteins and amino acids. It is about how to switch.

The fermentation industry using microorganisms includes alcoholic fermentation, glutamate (glutamate), amino acid fermentation such as lysine fermentation, organic acid fermentation such as citric acid fermentation, production of various antibiotics, fermentation of biologically active substances such as vitamins, polymer peptides It is used for the production of various products such as fermentation of high molecular materials. For fermentation of microorganisms, carbon source, nitrogen source and various trace elements should be added.In addition to sugars of molasses (cane molasses), it contains various organic substances and trace elements necessary for the growth of microorganisms and is used as a representative carbon source in the fermentation industry using microorganisms. It is becoming. CMS (condensed molasses solubles), a by-product after separating the desired product from the fermentation broth obtained through the fermentation process based on molasses, contains various organic substances and trace amounts necessary for the growth of organisms such as sugars, organics, minerals, cells, proteins, and amino acids. Due to the high content of elements, attention has been focused on the value of use as a fertilizer or feed. In other words, if fermented by-products have sufficient value as fertilizers or animal feeds useful for crops, if processed and processed properly, current fertilizer process standards are registered to supply these CMSs as organic fertilizers and by-product fertilizers. .

Accordingly, many companies performing a fermentation process using molasses add the fermentation by-product CMS as an organic source or assembly promoter for the production of organic fertilizer, use as a fermentation promoter in the manufacture of compost, or use the concentrated CMS as an animal feed. It has been used by adding to. However, fermentation by-products generated from fermentation using molasses are very sticky due to their high density and viscosity, which makes it difficult to treat them in liquid form. Many shortcomings have been exposed, including salt accumulation.

In order to solve this problem, studies have been made to powder the highly viscous liquid CMS. For example, amino acid fermentation by using molasses is mixed with chaejongbak, bone meal, milk or gypsum and supplied as an organic fertilizer (e.g., Organic Resources Co., Ltd., Gangnam Emulsion Co., Ltd.). Rather than mixing the above additives and CMS, the CMS is coated on the surface several times in a state where dry additives are assembled, so that the CMS content is low, the production cost is high, and the concentration is high. There is a disadvantage. In addition, attempts were made to develop fertilizers, including CMS, using zeolites, which are known to have high adsorptive power (e.g., Hyosung Agricultural Co., Ltd.). However, if the CMS content is high, the CMS is stuck inside the dryer used to manufacture the fertilizer. The direct drying method did not show satisfactory results in terms of economic efficiency and CMS input ratio. In addition, there have been attempts to powder CMS by mixing various dry additives such as sawdust, bentonite, clay, diatomaceous earth, rice hull, and chaejongbak, which have excellent water absorption ability, but all of them have a sticky gel state due to the action of sugar with high viscosity in CMS. Only the physical properties have been modified, and no successful powdering has been achieved even for a high CMS content.

Despite the usefulness of the liquid CMS as described above, due to its high viscosity, CMS attaches to the inner wall of the dryer during fertilizer production, and it is difficult to transport, store and handle the liquid with high viscosity, In addition, the difficulty is accompanied, even when added to the feed compound as a concentrate is limited because of the disadvantages such as the CMS compounding ratio does not exceed a certain ratio.

On the other hand, CMS is used as a by-product fertilizer to dilute and neutralize with water to be used for the foliar cost of plants, but the quantity is very small. In addition, recently, it is known that CMS can be used as a fermentation accelerator in the manufacture of compost, the amount of use is increasing, but the situation is that the CMS content does not exceed more than 20%.

As described above, the conventional fertilizer manufacturing process attempted to add a large amount of CMS as an organic source in the manufacture of organic fertilizers, but was unsuccessful due to viscosity problems. However, it is used and used within 20% as an assembly promoter. In addition, concentrated CMS is being added to animal feed such as cows, but since the quantity is not large, most CMS is currently being treated as dumping at sea.

However, ocean dumping, a method of treating liquid CMS as described above, not only pollutes the sea, but also causes huge losses in the business and national economy due to the huge cost of processing itself. Due to the crisis, there is an urgent need to establish an efficient treatment plan for CMS.

Therefore, it is expected that the disposal of wastes will be a sharp problem to estimate the existence of the fermentation industry in the future, and the issue of fermentation by-products, especially molasses fermentation by-products, which have high viscosity, will be an important issue. In order to increase the amount of CMS that can be applied as a fertilizer or feed as one of its efficient treatment methods, it is required to develop an effective powdering method of CMS.

Therefore, the present inventors pay attention to the fact that coco copits produced in the Indian Ocean, the Philippine Islands, etc. have excellent water-retaining power, and applied to CMS powdering, and as a result, coco copit has excellent water absorption ability and transforms a large amount of CMS into a completely new powder form material. The present invention was completed by confirming that the test was performed.

It is an object of the present invention to provide a method for powdering a CMS which is a by-product produced in a fermentation process that proceeds using molasses.

Specifically, the object of the present invention is a fertilizer having a high value, but difficult to powder to a high concentration is limited to the use and when used as a liquid fertilizer CMS that is mostly due to problems of excessive fertilization and side effects on soil and crops It is to provide an effective powdering method of.

In addition, it is an object of the present invention to solve the problems in the treatment of by-products by pulverizing the liquid CMS, as well as to provide a use of it as a fertilizer, soil improver and feed that is rich in organic matter, protein, amino acids, etc., easy to handle. .

Figure 1a is a photograph of the reagent bottle and the cocoite powder containing the liquid CMS before mixing the cocoite in the liquid molasses fermentation byproduct CMS,

FIG. 1B is a photograph showing a CMS in which the surface is tangled in a shiny and sticky state immediately after mixing 5 wt% of cocoite with 95 wt% of CMS.

Figure 2a is a photo showing the CMS disappeared after 1 hour after mixing 5% by weight of cocoite to 95% by weight CMS,

FIG. 2B is a photograph showing that the CMS of FIG. 2A disappears, but is not completely powdered, so that the CMS does not become freely scattered and still adheres.

3a is a photograph showing a fully powdered CMS after 3 hours after mixing 5% by weight of cocoite to 95% by weight of CMS,

FIG. 3b is a photograph showing that the CMS of FIG. 3a can be completely powdered and scattered freely;

4 is a photograph of a CMS granulated by hand,

FIG. 5 is a photograph showing that after 12 hours of mixing 50% by weight of the foliar soil and 50% by weight of the liquid CMS, the CMS was not absorbed into the foliar soil to maintain a sticky gel state.

In order to achieve the above object, the present invention is a powder obtained by grinding cocopeat which is a by-product of coconut industry in liquid CMS (consensed molasses solubles) rich in nutrients such as proteins, amino acids and organic acids as a by-product of fermentation process using molasses. It provides a method of powdering a high viscosity molasses fermentation by-product by adding and stirring.

The present invention also provides fertilizers, soil improvers and animal feed comprising powdered molasses fermentation by-products produced by the process.

In the present invention, "molasses fermentation by-product", "liquid molasses by-product" or "liquid CMS" refers to the production of amino acids, such as glutamic acid, lysine, alcohol, organic acid, etc. through microbial fermentation using molasses as the main carbon source After the desired product is separated and recovered means the remaining liquid components.

In addition, in the present invention, "powdered CMS" or "powder CMS" means the degree of adhesion of particles or other objects with no surface lubrication produced by the method of the present invention by mixing the liquid CMS with cocoite. Is very low and refers to CMS in powdered or granular form with no gel.

Hereinafter, the present invention will be described in detail.

Liquid CMS, a molasses fermentation by-product powdered in the present invention, preferably produces bioactive substances, antibiotics, enzymes or polymers containing amino acids, organic acids including citric acid, and vitamins from molasses as a carbon source using microorganisms. It may be obtained after performing a fermentation process to remove the desired product from the fermentation broth, more preferably amino acid fermentation by-product can be used.

In particular, the effect can be enhanced by being applied to molasses fermentation by-product obtained in glutamic acid fermentation or lysine fermentation process, which takes up a large part of its production as a seasoning component in the fermentation industry.

As an example of amino acid fermentation, the molasses fermentation by-product is described. First, before the molasses is introduced into the fermenter, sulfuric acid is removed to remove calcium from the molasses and the separated gypsum is removed. After the fermentation by the microorganism is carried out, the sulfuric acid is added again to stop the fermentation reaction, and then the microbial cells (biomass) is removed by a method such as centrifugation. After separating microbial cells, the remaining liquid by-products such as glutamic acid or lysine are separated from the remaining fermentation broth using ion exchange resins, and the remaining liquid by-products contain various organic and trace elements such as sugars, amino acids, proteins, etc. This is called CMS. The CMS may have a high salt content, such as ammonium sulfate and potassium sulfate, depending on the type of the final product desired during fermentation, and the powdering method of the present invention removes the salt prior to mixing the liquid CMS and cocoite. The process may further include. In addition, the CMS has a serious difference from a thin to very thick concentration according to the manufacturer, the powdering method of the present invention is characterized in that it can be applied to a high concentration of CMS having a solid component of 65% or more.

Cocopit used to powder the molasses fermentation by-product CMS in the present invention can be used so that the mixing amount is 5 to 90% by weight of the total composition, preferably 10 to 50% by weight, more preferably 15 Use at -40 wt% is preferred in view of the content of various useful organic components, the degree of powdering and the economics of the powdered CMS as a final product.

Coco-peat is commonly referred to as copit, coir or coirdust and is a by-product of the well-developed coconut industry throughout the Pacific, Indian and archipelagos, especially the Philippine archipelago. to be. Coconut is used for coconut milk, copra which is a raw material of palm oil, shell which has a very stable carbon structure for carbonization, garden basket, bed mattress, filler of car chair, rope, roof buffer etc. It consists of a fiber layer (Husk) and the like. Cocopit is a by-product obtained after making this primary product of coconut, and is a dark brown powder with a particle size of 0.2 to 2 mm. It has excellent moisture and dehumidification ability and low salt content. As a component, cellulose and lignin account for more than 90%, and the particles have a porous network structure, which is advantageous for securing breathability, and has a pH level suitable for fermentation at a pH of about 5.4 to 6.8. In addition, it has a high cation substitution capacity capable of retaining a large number of cations such as NH ₄ ⁺ , K ⁺ , Ca ²⁺ , and Mg ²⁺ , which are easily used by crops, so that fermentation regulators, substrates for horticulture, soil improvement materials, It is mainly used as an agricultural base material such as casing used for mushroom cultivation, the maturing base of organic fertilizer, and wood sawdust substitute for livestock. In addition, considering the physical properties of coco peat is being developed rapidly for a variety of uses, such as soundproof building materials. Cocopit is an inert material that contains a large amount of lignin chemically and is relatively stable to decomposition, and various physical properties appear depending on the production method and processing technology in the process. The chemical and physical compositions of common cocoites are shown in Table 1 below.

Chemical Composition of Cocopit Organic matter pH C.E.C. (cation substitution capacity) N C C: N moisture Conservative 95-99% 5.8 to 6.4 60 ~ 120me / 100g 0.6% 48% 80 10-20% 8-9 times its own weight

Recently, the coco peat has been produced by compressing it into a brick shape for convenience of transportation. For the CMS powderization of the present invention, it is preferable to use the block-shaped coco peat by grinding. At this time, the particle size of the ground cocoite is preferably in the range of 0.2-2 mm.

According to the invention, examples of preferred CMS powdering methods are as follows. First, the compressed block-shaped cocoite is pulverized into particles having a diameter of about 0.2 to 2 mm, and then the CMS is slowly sprinkled on the cocoite in an amount of 10 to 95% by weight of the final composition, and at the same time, by using a stirrer, the cocoite and the CMS are used. Mix well. In this case, a known drying aid may be added if necessary, and additives such as an assembly promoter or a pH adjusting agent may be added. According to one embodiment of the present invention, when less than 5% by weight of cocoite is added, although the absorption of the CMS occurs but the surface is not pulverized and completely powdered, the part is attached to the container. When the same known drying aid was mixed, it was confirmed that the powdering occurred effectively in a shorter time. Therefore, in the method of the present invention, a mixture of liquid CMS and cocoite is added to a known mixture of known drying aids such as zeolite, bone meal, oil foil, rapeseed meal, rice bran, bran, sawdust, peat moss and peatto to make it into a complete powder state. Can shorten.

The powdered CMS may be molded into pellets or granules by additional compression molding according to the use, in which case the powdered CMS is mixed with coco peat as described above. Methods can be applied.

CMS powdered or additionally pelletized or granulated by the method of the present invention is easier to dry through evaporation of moisture than liquid CMS, and does not exhibit a phenomenon of sticking in the process of drying by increasing the temperature. Have

In the embodiment of the present invention, when the cocoite is mixed at less than 5% by weight, although the CMS is absorbed by the cocoite, the surface is bundled and not completely powdered, such as sticking to paper, Mixing of known drying aids which can be adsorbed resulted in complete powdering.

In another embodiment, when the cocopit was mixed in an amount of 5 wt% or more, the powder was always completely powdered. When the cocopit addition rate was 40% or more, the original form of the liquid CMS was not found at all. Therefore, when the addition amount of cocoite is low, the same effect can be acquired by adding a well-known drying adjuvant. In consideration of economical properties such as physical properties of CMS and production cost in mass production, the addition rate of cocoate is preferably 10 to 50% by weight, more preferably 15 to 40% by weight.

When Cocopit is mixed with CMS, it is initially sticky like other materials are mixed. However, if it is continuously stirred, water and sugars start to be absorbed by Cocopit, and after about 1 hour of mixing, the surface becomes greasy. The properties remain somewhat but the gel disappears, and after about 3 hours the powder becomes completely powdery and almost sticky enough to adhere to other objects (see FIGS. 2 and 3).

In another embodiment of the present invention, the component content was investigated to confirm the applicability as a fertilizer for the powdered compost prepared by varying the mixing ratio of CMS and cocoite. As a result, the organic matter content was 40 to 70%, which satisfies the organic fertilizer standard of 25% or more, and the ratio of organic matter to nitrogen having a standard of 50 or less is also 15 or less. It could be confirmed that it can be used as.

The powdered CMS produced by the present invention can be used as a component of various fertilizers such as by-product fertilizers, organic fertilizers, horticultural complex fertilizers, general compound fertilizers, soil improvers, animal feeds, preferably the powdered CMS feed 2 to 10% by weight of, can be used as 5 to 80% by weight of the fertilizer or soil improver.

The advantage of using granular or powdered CMS as a fertilizer is that it can complement the disadvantages of cocoite and liquid CMS. Specifically, coco peat containing 95% or more of organic matter is excellent organic material or low nitrogen content, so when used in soil alone, the decomposition rate is slow and there is concern of nitrogen starvation. Liquid CMS is very good material containing organic matter and nitrogen. When used directly in the soil, the problem of salt accumulation due to deterioration of breathability and excessive fertilization occurs, but compost prepared by using the powdered CMS of the present invention can be used as an excellent fertilizer to complement the above disadvantages.

Organic fertilizer as described above refers to a high-grade organic fertilizer produced from plants and animals as a fertilizer management method (fertilizer process standard) is a concept that generally includes by-product fertilizer as a relative concept of inorganic fertilizer or chemical fertilizer. Powdered CMS by adding coco pit is easy to control nitrogen, phosphoric acid, potassium content and moisture can be an excellent organic fertilizer.

The third type of compound fertilizer is currently being supplied only in small amounts due to the best fertilizer of chemical fertilizers and organic substances, due to the limitations and economics of organic sources, and difficulty in blending technology. However, when the third type of compound fertilizer is produced using the powdered CMS of the present invention, it is easier to mix with nitrogen, phosphoric acid and potassium than other organic fertilizers, and the organic matter content can be increased by 30% or more. Is very large.

In addition, when the powdered CMS prepared by mixing cocopite is used as a soil improver, the organic content is very high in the cocoite, and a relatively high content of lignin is directly or indirectly converted into soil humus. It contains a large amount of amino acids, proteins, and sugars, which are suitable for soil microorganisms, so it can be used as an excellent soil improver.

In addition, the feed containing the powdered CMS provided by the present invention is easier to transport and store than when used as a liquid feed and easy to mix with other nutrients, etc. can be used as an active ingredient in the production of animal feed.

On the other hand, when using the powdered CMS of the present invention prepared by mixing and stirring the coco peat and the liquid CMS as an active ingredient of fertilizers, soil improvers or animal feed, the powdered CMS prepared according to the method of the present invention It can also be used as a sieve with a certain pore size to even out the particle size.

Hereinafter, the present invention will be described in detail by way of examples.

However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited to the following examples.

<Example 1> Preparation of the powder CMS which varied the cocoite mixture ratio

The degree of powdering when added to the liquefied CMS at different cocoite blending ratios was investigated.

1-1) Less than 5% by weight of cocopite: Formulated in a proportion of more than 95% by weight of CMS

Although the liquefied CMS is absorbed by cocopit, the gel state disappears, but it is not completely powdered and the surface is greasy, and when the degree of powdering is investigated, it remains sticky and sticks together to form agglomerates. I stuck to it.

1-2) Copipit 5% by weight or more: blended in a proportion of less than 95% by weight of CMS

When the cocoite is added in more than 5% by weight, the powder of the CMS is always possible, the stickiness also disappeared, it was confirmed that the particles are dispersed. When the Cocopit addition rate is more than 40% by weight, it is almost impossible to find the original form of the liquid CMS. However, considering the economical properties such as the sticky physical properties of the CMS and the production cost required for the powdering process, the Cocopit addition rate is 15 to 40 The weight percentage seems to be the ideal.

<Comparative Example 1> Powdering CMS Using Subleaf Soil as Additive

In order to confirm the effect of powdering by coco peat, the degree of powdering was observed while mixing with a liquid CMS, which was mixed with a liquid CMS, which was known to have a high absorption power instead of coco peat. As a result of mixing 50% by weight of the foliar soil and 50% by weight of the liquid CMS, as shown in FIG. 5, it was confirmed that the liquid CMS was not absorbed into the foliar soil to maintain a sticky gel state even after 12 hours.

<Example 2> Preparation of the powder CMS by changing the cocoite mixing time

The degree of powdering of the liquid CMS according to the cocoite formulation time was investigated. Immediately after mixing 5% by weight of cocopite and 95% by weight of CMS, a sticky state appeared as in the case of mixing other materials (see FIG. 1B). Continued mixing gradually absorbs moisture as well as sugar, and after 1 hour of mixing, the material that is almost on the surface disappears (see FIG. 2A). However, even after 1 hour of mixing time when the surface shine disappeared, the adhesion between the particles was strong and the scattering was insignificant, indicating that the powder was not completely formed (see FIG. 2B). On the other hand, after mixing and stirring for about 3 hours it was completely powdered to give the form of fine particles, not agglomerates (see Fig. 3a), it was confirmed that the scattering between the particles freely (see Fig. 3b).

<Example 3> Component investigation of granular or powdery CMS fertilizer

In order to confirm the possibility of use as an organic fertilizer for the powder CMS prepared by mixing the cocoite and the liquid CMS, the ratio of the nutritional component was investigated. As the CMS used for the test, BASF's lysine fermentation by-product (CMS 1) having a high dry matter content and lysine fermentation by-product (CMS 2) of Cheil Jedang Co., Ltd. having a relatively low dry content were used. The components of the CMS are shown in Table 2 below.

CMS 1 CMS 2 building (%) 65 40.01 moisture (%) 35 59.99 Organic matter (%) 60 31.08 nitrogen (%) 6.8 5.18 Potassium (%) 0.25 1.32 calcium (%) 0.15 0.05 Magnesium (%) 0.15 0.05 salt (%) 0.05 0.75 importance 1.3 1.21 pH 4.5 5.62 Viscosity cps (25 ℃) 400 250

In addition, the mixing ratio of CMS, cocoite and zeolite used in the experiment is shown in Table 3 below.

CMS Coco Feet (%) Zeolite (%) CMS 1 (%) CMS 2 (%) Compost 1 69 - 8 23 Compost 2 70 - 30 - Compost 3 - 60 10 30 Compost 4 80 - 20 -

Nutritional ingredients, trace elements, moisture, salt content and pH in the compost according to the composition ratio was commissioned by A. End F. Co., Ltd. The analysis method was based on the fertilizer analysis method announced by RDA. The analysis results are shown in Table 4 below.

Item Standard result Compost 1 Compost 2 Compost 3 Compost 4 nitrogen(%) - 4.87 4.83 4.18 5.71 Phosphoric Acid (%) - 0.19 0.19 0.17 0.30 calcium(%) - 0.47 0.72 0.58 0.46 Organic matter (%) 25 or more 51.76 66.41 42.17 67.91 Nitrogen ratio in organic matter 50 or less 10.63 13.75 10.09 11.89 Arsenic (mg / kg) 50 or less - - - trace Cadmium (mg / kg) 5 or less - - - 0.03 Mercury (mg / kg) 2 or less - - - trace Lead (mg / kg) 150 or less - - - 10.03 Chromium (mg / kg) 300 or less - - - 3.81 Copper (mg / kg) 500 or less - - - 5.67 pH - 4.50 4.49 5.57 5.04 Electrical conductivity - 23.10 22.40 19.74 27.4 moisture - 25.10 25.90 26.10 27.75 salt 1 or less 0.19 0.64 0.42 0.40 C.E.C - - - - 13.21

From the above results, it can be seen that the fertilizer containing the powdered CMS of the present invention as an active ingredient includes various nutrients and can be used as an organic fertilizer suitable for the fertilizer process standard. Therefore, it contains 95% or more of organic materials and excellent organic materials or low nitrogen content, so when used in soil alone, the decomposition rate is slow and it is very excellent material or soil containing cocoite and organic matter and nitrogen which have the disadvantage of concern of starvation. When used directly on the compost of liquid CMS form the liquid CMS mixed with liquid CMS which has a problem of salt accumulation phenomenon due to deterioration of breathability and excessive fertilization, composting of the above mentioned disadvantages that can occur when using a liquid and liquid CMS alone It is expected to be used as an excellent organic fertilizer.

According to the method of powdering the liquid molasses fermentation by-product by adding the coco pit provided by the present invention, by mixing the pulverized coco pit in a liquid CMS in a proportion of 5 to 90% by weight, the organic acid, amino acid, protein, etc. It is rich in nutritional ingredients, but it is difficult to handle due to its high density and viscosity, it is difficult to powder due to its high viscosity. Despite its usefulness, it is possible to increase the utilization of CMS, which has been restricted in use. In addition, the method of the present invention is simpler than the conventional CMS powdering method and can be applied without a separate facility, and it is possible to improve the salt accumulation phenomenon due to the deterioration of breathability and excessive fertilization caused by using a liquid CMS, and A product that is easy to handle in storage and fertilization can be obtained. CMS powdered by the above method can be used as an effective raw material for fertilizers, soil improvers, animal feeds due to its high nutrient content and ease of handling, and it can be used for CMS treatments that had no suitable treatment method except ocean dumping. Also great effect.

Claims (17)

A method of powdering by mixing liquid fermentation by-products with cocoite in fermentation using molasses. The powdering method according to claim 1, wherein the mixing amount of cocoite is 5 to 90% based on the total weight. The powdering method according to claim 1, wherein the mixing amount of cocoite is 5 to 50% based on the total weight. The method of claim 1, wherein the liquid fermentation by-products are powdered by mixing and stirring with coco peat, or the powdered fermentation by-products are further compacted to form pellets or granules. Way. The method of claim 1, wherein the mixing and stirring of the liquid fermentation by-products and cocoite are additionally mixed with at least one additive selected from the group consisting of drying aids, coarse promoters and pH adjusting agents. 6. The method of claim 5, wherein the drying aid is at least one selected from the group consisting of zeolite, bone meal, rapeseed, oil foil, rice bran, bran, sawdust, clay, diatomaceous earth, rice bran, peat moss, peat soil. A process according to claim 5, characterized in that it is mixed in a proportion of 50 to 85% by weight of the liquid fermentation by-products, 5 to 30% by weight of cocoite and 10 to 50% by weight of the drying aid. The method of claim 1, wherein the molasses fermentation by-products are subjected to a fermentation process for producing bioactive substances, antibiotics, enzymes or polymers, including amino acids, organic acids including citric acid, vitamins from molasses as a carbon source using microorganisms, Obtained by removing the desired product from the fermentation broth. 9. The method of claim 8, wherein the molasses fermentation by-product is obtained by additionally removing microbial cells in addition to the removal of the desired product. The method of claim 8, wherein the amino acid to be produced by the fermentation process using a microorganism is characterized in that glutamate (glutamate) or lysine (lysine). The method of claim 1, wherein the cocoite has a particle size of 0.2-2 mm. The method of claim 1, wherein the desalting process is performed to remove salts from the fermentation by-product prior to mixing the liquid fermentation by-product and cocoate. A fertilizer comprising as an active ingredient molasses fermentation by-products produced by the method of any one of claims 1 to 12. 15. The fertilizer of claim 13, wherein the fertilizer is a by-product fertilizer, an organic fertilizer, or a third type of compound fertilizer. 14. The fertilizer of claim 13, further comprising a chemical fertilizer component comprising nitrogen, phosphoric acid and potassium. A soil improving agent comprising the dried molasses fermentation by-product produced by the method of any one of claims 1 to 12 as an active ingredient. An animal feed comprising dried molasses fermentation by-products produced by the method of claim 1 as an active ingredient.