KR20000058765A - A fertilizer containg organic compounds and minerals - Google Patents

A fertilizer containg organic compounds and minerals Download PDF

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KR20000058765A
KR20000058765A KR1020000035927A KR20000035927A KR20000058765A KR 20000058765 A KR20000058765 A KR 20000058765A KR 1020000035927 A KR1020000035927 A KR 1020000035927A KR 20000035927 A KR20000035927 A KR 20000035927A KR 20000058765 A KR20000058765 A KR 20000058765A
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fertilizer
organic
slag
present
mineral fertilizer
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KR100371058B1 (en
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박상득
김대광
김영
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오명환
주식회사 제철세라믹
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D5/00Fertilisers containing magnesium
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

PURPOSE: An organic mineral fertilizer is provided to reduce manufacturing costs and to contain essential substances for growth and ripening of the crops by reacting slag, which is generated from a converter for manufacturing steel with waste food. CONSTITUTION: The organic mineral fertilizer contains 10 wt.% or more of OM(Oligosaccharide Molecular), 40 wt.% or less of OM/N(Oligosaccharide Molecular/Nitrogen), 35-45 wt.% of CaO, 3.5-7.5 wt.% of SiO2, 12-18 wt.% of MgO, 3-7 wt.% of Fe2O3, 2-5 wt.% of MnO, 0.3-0.6 wt.% of P2O5, 0.3-1.8 wt.% of Al2O3, and 0.05 wt.% or less of S and other essential substances. Once food waste and slag, which are generated from a converter for manufacturing steel, are mixed, cationic elements contained in the slag, such as Ca, Mg, P, S, Mn, Si, bond to anions derived from organic compounds of OM/N so that they form aliphatic ester having long chain. The food waste and the slag are characterized by being mixed in a ratio of 40:60.

Description

유기 광물질 비료{A fertilizer containg organic compounds and minerals}A fertilizer containg organic compounds and minerals}

본 발명은 음식 찌꺼기와 제철소에서 발생되는 부산물로부터 제조한 유기 광물질 비료에 관한 것으로, 보다 상세하게는 일반 생활 음식 찌꺼기와 제철소에서 부산물로 발생되는 제강 전로 슬래그를 이용함으로써, 종래의 비료에 비해 제조원가가 저렴하고, 농작물의 발육, 성장 및 결실을 촉진시키면서, 아울러 산성 토양 및 노후 토양의 개질에도 기여할 수 있는 유기 광물질 비료를 제공한다.The present invention relates to an organic mineral fertilizer prepared from food waste and by-products generated in steel mills, and more specifically, by using steelmaking converter slag generated as a by-product from general household food waste and steel mills, manufacturing costs compared to conventional fertilizers. It provides an organic mineral fertilizer that is inexpensive and promotes the growth, growth and fruiting of crops, while also contributing to the reforming of acidic and aging soils.

일반적으로 토양에는 농작물의 발육, 성장, 결실 등에 필요한 제원소들이 많이 산재되어 있고, 또 화학비료 사용시 일시적으로는 농작물이 잘 자라고 수확량도 증가하나, 시간이 지날수록 비료의 과잉 사용으로 인한 농작물의 해거리가 심화되고 수확량도 떨어지는 등의 문제점들이 상존해 왔다. 이러한 문제점들을 해결하기 위하여 여러 가지 복합비료 및 질소질, 인산질, 카리질, 고토류, 유기질류와 같은 종류별 비료들이 농업용으로 개발 사용되어 왔지만, 이 또한 질소, 암모니아, 유황, 인산, 수용성 인산, 고토, 규산, 카리 및 유기질 등의 몇몇 주된 원소 위주로만 구성되어, 농작물에 필요한 다양한 성분들을 충분히 제공하지 못하는 단점을 가지고 있다.In general, the soil is scattered with many elements necessary for the development, growth, and fruiting of crops, and when chemical fertilizers are used, crops grow well temporarily and yields increase, but over time, the distance of crops due to overuse of fertilizers. Problems such as deepening and low yields have existed. In order to solve these problems, various fertilizers and fertilizers such as nitrogen, phosphate, caryzil, clay and organic matter have been developed and used for agriculture, but also nitrogen, ammonia, sulfur, phosphoric acid, water-soluble phosphoric acid, goto, Consists of only a few main elements, such as silicic acid, carry and organic matter, has the disadvantage that it does not provide enough of the various components required for crops.

이에 따라, 현재 농업 분야에서는 식물을 구성하는데 필요한 3원소인, 질소, 인산, 카리의 함유량에 따라 제조한 유기질 비료를 사용하고 있다.Accordingly, the agricultural field currently uses organic fertilizers produced in accordance with the content of nitrogen, phosphoric acid and carry, which are three elements necessary for forming plants.

유기질 화합물의 분자구조는 탄소, 산소, 수소 등으로 구성되어 있으며, 이것은 보통 단백질, 탄수화물, 지질, 핵산의 4가지 형태로 존재한다. 단백질은 효소 및 호르몬의 저장, 수송, 구성, 수축 및 방어 등의 역할을 수행하고, 탄수화물은 단당류 유도체로 구성된 다당류 유도체로 존재하며, 지질은 긴 사슬 지방산이나 에스테르 형태로서 단백질이나 탄수화물의 기능을 돕거나 저지하는 역할을 수행하고, 핵산은 이들 상호간의 결합 구조 구성을 위한 중매역할을 수행한다. 유기질 성분(OM/N; Oligosaccharide Molecular/Nitrogen)은 농작물에 필요한 여러 성분들을 제공하지만, 토양에는 식물 특성에 따라 그외에도 많은 원소들이 필요하게 된다.The molecular structure of the organic compound is composed of carbon, oxygen, hydrogen, etc., which are usually present in four forms: protein, carbohydrate, lipid, and nucleic acid. Proteins play a role in the storage, transport, composition, contraction and defense of enzymes and hormones, and carbohydrates exist as polysaccharide derivatives composed of monosaccharide derivatives. Lipids are long-chain fatty acids or esters that help proteins or carbohydrates function. Or nucleic acid plays a role in mediating for constructing the binding structure between them. The organic component (OM / N; Oligosaccharide Molecular / Nitrogen) provides many of the components necessary for crops, but the soil requires many other elements, depending on the plant's properties.

이에, 본 발명은 생활 음식 찌꺼기와 제철소에서 부산물로 발생되는 제강 전로 슬래그를 이용함으로써, 상기한 종래의 고토 비료 또는 유기질 비료 등에 비해 제조원가가 저렴하면서도 농작물의 발육, 성장 및 결실에 필요한 제성분들을 광범위하게 제공하는 유기 광물질 비료를 제공하고자 한다.Therefore, the present invention uses a steelmaking converter slag generated as a by-product from household food waste and steel mills, a wider range of ingredients necessary for the development, growth and deletion of crops, while manufacturing costs are lower than conventional fertilizers or organic fertilizers. To provide organic mineral fertilizer.

따라서 본 발명의 비료는 농작물의 결실 및 성장을 촉진시키며, 산성 토양 및 노후 토양의 개질에도 기여하는 탁월한 효과를 제공한다.Therefore, the fertilizer of the present invention promotes the deletion and growth of crops, and provides an excellent effect of contributing to the reforming of acidic soils and aged soils.

본 발명의 유기 광물질 비료는 OM(Oligosaccharide Molecular) 10중량% 이상 및 OM/N(Oligosaccharide Molecular/Nitrogen) 40중량% 이하, CaO 35-45중량%, SiO23.5-7.5중량%, MgO 12-18중량%, Fe2O33-7중량%, MnO 2-5중량%, P2O50.3-0.6중량%, Al2O30.3-1.8중량%, S 0.05중량% 이하 및 기타 불가피한 성분을 포함한다.The organic mineral fertilizer of the present invention is at least 10% by weight of Oligosaccharide Molecular (OM) and at most 40% by weight of Oligosaccharide Molecular / Nitrogen (OM / N), 35-45% by weight of CaO, 3.5-7.5% by weight of SiO 2 , MgO 12-18 Weight%, Fe 2 O 3 3-7%, MnO 2-5%, P 2 O 5 0.3-0.6%, Al 2 O 3 0.3-1.8%, S 0.05% by weight or less and other unavoidable components Include.

본 발명의 비료는 원료로서 광물질을 직접 사용하여서도 제조가능하지만, 일반 생활 음식 찌꺼기와 제철소에서 발생되는 부산물, 특히 제강 전로 슬래그를 사용하는 것이 바람직하다.The fertilizer of the present invention can be produced by using minerals directly as raw materials, but it is preferable to use general food debris and by-products generated in steel mills, in particular steel converter slag.

즉, 본 발명의 비료는 유기질 함유물로서 인류의 식생활후 폐기물인 음식 찌꺼기를 수거 발효시키면서 광물질원으로서 제철소에서 부산물로 발생된 슬래그를 분쇄후 혼합하여 제조된다. 구체적으로, 본 발명의 비료는 일반 생활 음식 찌꺼기인 폐기물을 발효시켜 발생된 OM/N에 Ca, Mg, P, S, Mn, Si 등의 제철산업 폐기물중의 원소들을 첨가시킴에 있어서, 양이온인 Ca, Mg, P, S, Mn, Si 등에 유기 화합물로부터 유래된 음이온이 결합된 형태를 취한다.In other words, the fertilizer of the present invention is prepared by crushing and mixing the slag generated as a by-product from steel mills as a mineral source while fermenting food waste, which is a waste after human diet, as an organic content. Specifically, the fertilizer of the present invention is a cation in the addition of elements in the steel industry wastes such as Ca, Mg, P, S, Mn, Si to the OM / N generated by fermenting the waste of the general food waste Ca, Mg, P, S, Mn, Si or the like is taken in the form of anion derived from an organic compound.

따라서 본 발명의 비료는 기존의 비료에서 볼 수 없었던 성분들을 다양하게 보유하므로 현재까지 사용되어 왔던 비료들과는 달리, 무기물질에서 보유한 알칼리성 물질과 산성물질들이 유기물질과 혼합된 형태의 비료로서 활용될 수 있다. 유기물과 무기물은 결합시 화학반응에서 중성이 된다. 그러나 본 발명에서는 화학약품이 아닌 유기물류를 처리하면서 무기물질류를 첨가 결합시키는 방법을 사용함으로써, 유기물질들이 대기중에서가 아닌 무기물질류들에 쌓여서 발효되므로 긴 사슬 지방산 에스테르 형태로 존재하게 된다. 이것을 분쇄하여 미립자로 제분시키면 본 발명의 유기 광물질 비료가 된다.Therefore, the fertilizer of the present invention has a variety of components that were not seen in the conventional fertilizer, unlike the fertilizers that have been used until now, alkaline and acidic substances possessed in the inorganic material can be utilized as a fertilizer in the form of mixed with the organic material have. Organics and inorganics become neutral in chemical reactions when combined. However, in the present invention, by using a method of adding and combining inorganic substances while treating organic substances other than chemicals, organic substances are present in the form of long-chain fatty acid esters because they are accumulated and fermented in inorganic substances rather than in the air. When this is ground and milled into fine particles, it becomes the organic mineral fertilizer of the present invention.

이하, 본 발명의 비료중에 포함되는 각 성분들에 대해 구체적으로 설명한다.Hereinafter, each component contained in the fertilizer of this invention is demonstrated concretely.

본 발명의 비료에서는 OM을 10중량% 이상 및 OM/N을 40중량% 이하로 함유하는 것이 식생활 음식 찌꺼기와 광물질의 혼합관계에서 최적 값으로 바람직하다.In the fertilizer of the present invention, containing at least 10% by weight of OM and at most 40% by weight of OM / N is preferable as the optimum value in the mixing relationship between dietary food waste and minerals.

또한, 상기 CaO 성분은 Ca에 의해 식물의 발육, 성장 및 결실을 촉진시키고, 토질의 산성화를 방지하는 역할을 한다. 농작물의 균형과 적정한 범위를 고려하여 비료중에 함유되는 CaO 함량은 35-45중량% 범위로 하는 것이 바람직하다.In addition, the CaO component promotes the growth, growth and deletion of plants by Ca, and serves to prevent acidification of the soil. In consideration of the balance and proper range of crops, the CaO content in the fertilizer is preferably in the range of 35-45% by weight.

본 발명의 비료중에 함유되어 있는 SiO2성분은 농작물의 외벽에 부착되어 병충해를 예방하는 역할을 하는데, 일반 토양과의 조합을 위해서는 3.5-7.5중량% 범위가 바람직하다.SiO 2 component contained in the fertilizer of the present invention is attached to the outer wall of the crop serves to prevent pests, for combination with the general soil is preferably in the range of 3.5-7.5% by weight.

비료의 성분중 MgO는 농작물의 엽록소 구성에 필요한 주요 촉진 원소로서 토질의 산성화를 억제하는 효과를 제공하며, 본 발명의 비료중에는 12-18중량% 범위로 포함시키는 것이 바람직하다. 12중량% 이하이거나 18중량% 이상이 되면 과실의 모양과 맛 등의 특성을 살릴 수 없어 바람직하지 않다. 또한 본 발명에서 MgO는 MnO, Fe2O3, P2O5, S 등과 함께 존재하여 식물의 엽록소 구성에 중요한 역할을 하므로, 이들 함량은 산성 토질 개선과 식물의 성장 촉진을 위해서 일반적인 요구 함량으로 함유되었다.MgO in the components of the fertilizer provides the effect of inhibiting the acidification of the soil as a major promoting element necessary for the chlorophyll composition of the crop, it is preferable to include in the range of 12-18% by weight in the fertilizer of the present invention. If it is 12% by weight or less or 18% by weight or more, the shape and taste of the fruit cannot be utilized, which is not preferable. In addition, in the present invention, MgO is present together with MnO, Fe 2 O 3 , P 2 O 5 , S and the like to play an important role in the chlorophyll composition of the plant, these contents are required as a general content for improving the acidic soil and promote plant growth Contained.

또한, 본 발명의 Al2O3성분은 식물 성장에 유해하므로 가능한한 적을수록 좋다.In addition, Al 2 O 3 component of the invention is good as far as possible, because the less detrimental to plant growth.

본 발명에 따른 비료는 상기 음식 찌꺼기와 전로 슬래그를 40:60의 중량비로 적재 발효시킨후, 그대로 분쇄하여 입도 선별하는 과정을 통해 제조한다.Fertilizer according to the present invention is prepared by loading and fermenting the food debris and converter slag in a weight ratio of 40:60, and then pulverized as is to produce a particle size selection process.

이하, 본 발명을 실시예를 통하여 더욱 상세히 설명한다. 그러나, 이들 실시예는 본 발명을 구체적으로 예시하고자 제시된 것으로, 본 발명의 범위가 이들 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples. However, these examples are presented to specifically illustrate the present invention, but the scope of the present invention is not limited by these examples.

〈실시예 1-5〉<Example 1-5>

유기 광물질 비료Organic mineral fertilizer

일반 음식 찌꺼기를 수거 저장시키면서 제강 전로로부터 배재(deslagging)된 슬래그를 40:60의 비율로 저장하여 30일 이상 발효시킨 다음, 이를 1mm 정도로 분쇄하여 하기 표 1의 조성을 갖는 본 발명의 유기 광물질 비료를 제조하였다.Collecting and storing the general food waste slag deslagging from the steelmaking converter in a ratio of 40:60 and fermented for 30 days or more, and then crushed by 1mm to the organic mineral fertilizer of the present invention having the composition of Table 1 Prepared.

성분ingredient OMOM OM/NOM / N CaOCaO SiO2 SiO 2 MgOMgO Fe2O3 Fe 2 O 3 MnOMnO P2O5 P 2 O 5 SS Al2O3 Al 2 O 3 기타Etc 조성(중량%)Composition (% by weight) 10이상over 10 40이하40 or less 35-4535-45 3.5-7.53.5-7.5 12-1812-18 3-73-7 2-52-5 0.3-0.60.3-0.6 0.05이하0.05 or less 0.3-1.80.3-1.8 --

상기 표 1에 제시된 바와 같이, 유기질 성분과 함께 여러 광물질 성분이 함유되어 있는 본 발명의 유기 광물질 비료(실시예 1-5)를 제조하고, 이를 종래의 유사 비료인 용성 인비, 어분질 비료, 규산질 비료, 고토 인산질 비료와 함께 사용하여 식물을 재배하였다. 그 결과, 이들 종래의 비료들에 비해 본 발명의 비료가 식물의 발육, 성장 및 결실 모든 면에서 탁월한 효과를 나타내는 것으로 나타났다. 종래 비료와 본 발명의 비료에 대한 각 성분과 이들을 사용하여 식물을 재배하였을 때의 결과에 대해 하기 표 2에 제시하였다.As shown in Table 1 above, an organic mineral fertilizer (Example 1-5) of the present invention containing various mineral components together with organic components was prepared, and the conventional similar fertilizers were soluble phosphorus, fish meal fertilizer, and siliceous Plants were grown in combination with fertilizers, high soil phosphate fertilizers. As a result, it has been shown that the fertilizer of the present invention has an excellent effect in all aspects of plant development, growth and deletion compared to these conventional fertilizers. Each component of the conventional fertilizer and the fertilizer of the present invention and the results of cultivating plants using them are shown in Table 2 below.

조성(중량%)시료명Composition (wt%) OMOM OM/NOM / N CaOCaO SiO2 SiO 2 MgOMgO Fe2O3 Fe 2 O 3 MnOMnO P2O5 P 2 O 5 SS Al2O3 Al 2 O 3 기타Etc 발육Development 성장growth 결실fruition 용성인비 1Yongin Ryu 1 3535 1515 1414 -- 55 1717 -- -- 1414 용성인비 2Yongseong B2 2 3636 1414 1313 -- 55 1818 -- -- 1414 용성인비 33 3535 1414 1515 -- 55 1616 -- -- 1515 어분질 1Fishmeal 1 5050 3636 -- -- -- -- -- -- -- -- 1414 어분질 2Fishmeal 2 5151 3434 -- -- -- -- -- -- -- -- 1515 어분질 3Fishmeal 3 5151 3535 -- -- -- -- -- -- -- -- 1414 규산질 1Silicate 1 -- -- 4040 2020 55 16.816.8 3.23.2 -- -- 0.70.7 14.314.3 규산질 2Siliceous 2 -- -- 4343 2222 66 17.217.2 4.34.3 -- -- 0.60.6 6.96.9 규산질 3Siliceous 3 -- -- 4343 2121 66 16.316.3 3.73.7 -- -- 0.70.7 9.39.3 고토인산 1Goto phosphoric acid 1 2020 -- 2020 -- 4040 -- -- -- -- -- 2020 고토인산 2Goto Phosphoric Acid 2 2222 -- 2222 -- 4141 -- -- -- -- -- 1515 고토인산 3Kotophosphate 3 2121 -- 2121 -- 4141 -- -- -- -- -- 1717 실시예 1Example 1 1010 3030 3636 4.24.2 1313 3.83.8 2.32.3 0.40.4 0.020.02 0.350.35 미량a very small amount 실시예 2Example 2 1111 2929 3636 4.24.2 1212 3.73.7 2.32.3 0.30.3 0.020.02 0.340.34 미량a very small amount 실시예 3Example 3 1010 3030 3737 4.24.2 1212 3.63.6 2.42.4 0.30.3 0.020.02 0.350.35 미량a very small amount 실시예 4Example 4 1111 3030 3535 4.14.1 1313 4.14.1 2.12.1 0.30.3 0.030.03 0.350.35 미량a very small amount 실시예 5Example 5 1111 2929 3636 4.34.3 1212 4.34.3 2.32.3 0.30.3 0.030.03 0.340.34 미량a very small amount

범례 : ◎ 양호, △ 대체로 적격, × 열위Legend: ◎ good, △ generally eligible, × inferior

본 발명의 유기 광물질 비료는 유기질과 광물질 성분들이 광범위하게 함유되어 있어, 종래의 비료들에 비해 식물의 발육, 성장, 결실면에서 뛰어난 효과를 나타낼 뿐만 아니라, 산성 토양 및 노후 토양의 개질에도 기여하고, 일반 생활 음식 찌꺼기와 제철소 부산물인 제강 전로 스래그를 이용하여 제조함으로써, 경제적인 측면과 더불어 환경 보전 측면에서도 획기적인 효과를 제공한다.The organic mineral fertilizer of the present invention contains a wide range of organic and mineral components, showing excellent effects in terms of plant development, growth, and fruit compared to conventional fertilizers, as well as contribute to the reforming of acidic soils and aged soils. In addition, it manufactures using ordinary food scraps and steel converter converter slag which is a by-product of steel mills, thereby providing significant economic and environmental benefits.

Claims (4)

OM 10중량% 이상 및 OM/N 40중량% 이하로서, CaO 35-45중량%, SiO23.5-7.5중량%, MgO 12-18중량%, Fe2O33-7중량%, MnO 2-5중량%, P2O50.3-0.6중량%, Al2O30.3-1.8중량%, S 0.05중량% 이하 및 기타 불가피한 성분을 포함하는 유기 광물질 비료.10 wt% or more of OM and 40 wt% or less of OM / N including 35-45 wt% of CaO, 3.5-7.5 wt% of SiO 2 , 12-18 wt% of MgO, 3-7 wt% of Fe 2 O 3 , and MnO 2- Organic mineral fertilizer comprising 5 % by weight, P 2 O 5 0.3-0.6%, Al 2 O 3 0.3-1.8%, S 0.05% or less and other unavoidable components. 제 1 항에 있어서,The method of claim 1, 일반 생활 음식 찌꺼기와 제철소에서 부산물로 발생되는 제강 전로 슬래그로부터 제조된 것을 특징으로 하는 유기 광물질 비료.Organic mineral fertilizer, characterized in that it is prepared from general food debris and steelmaking converter slag generated as a by-product from steel mills. 제 2 항에 있어서,The method of claim 2, 상기 생활 음식 찌꺼기와 제강 전로 슬래그를 적재 발효시킨 후, 분쇄하여 입도 선별하는 과정을 통해 제조된 것을 특징으로 하는 유기 광물질 비료.Organic fertilizer, characterized in that produced by the process of loading the fermentation slag of the household food waste and steelmaking converter slag, and then crushed by the particle size. 제 2 항 또는 제 3 항에 있어서,The method of claim 2 or 3, 상기 생활 음식 찌꺼기와 제강 전로 슬래그의 혼합비가 40:60인 것을 특징으로 하는 유기 광물질 비료.Organic mineral fertilizer, characterized in that the mixing ratio of the living food debris and steelmaking converter slag is 40:60.
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KR100720764B1 (en) * 2006-07-21 2007-05-23 김재근 Manufacturing method for lime fertilizer

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KR19980048913A (en) * 1996-12-18 1998-09-15 김종진 Fertilizer for Soil Improvement Using Steel By-Products
JPH11171677A (en) * 1997-12-11 1999-06-29 Nagano Prefecture Nokyo Hiryo Kk Compost and its production

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100720764B1 (en) * 2006-07-21 2007-05-23 김재근 Manufacturing method for lime fertilizer

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