KR20000049586A - Waterproof agent for bridges - Google Patents

Waterproof agent for bridges Download PDF

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Publication number
KR20000049586A
KR20000049586A KR1020000019438A KR20000019438A KR20000049586A KR 20000049586 A KR20000049586 A KR 20000049586A KR 1020000019438 A KR1020000019438 A KR 1020000019438A KR 20000019438 A KR20000019438 A KR 20000019438A KR 20000049586 A KR20000049586 A KR 20000049586A
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South Korea
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mixture
high boiling
bridge
coating
aromatic
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KR1020000019438A
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Korean (ko)
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KR100369493B1 (en
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서청
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서청
주식회사 대아화학
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Publication of KR20000049586A publication Critical patent/KR20000049586A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01DCONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
    • E01D19/00Structural or constructional details of bridges
    • E01D19/08Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
    • E01D19/083Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Paints Or Removers (AREA)
  • Bridges Or Land Bridges (AREA)

Abstract

PURPOSE: A coat for waterproofing a bridge floor is provided which exhibits good waterproofness and has excellent in constructive property and adhesive property with asphalt. CONSTITUTION: A coat for waterproofing a bridge floor comprises: (a) a first coating on a bridge floor a blend prepared by dissolving N,N,N,N-tetrakis(2-hydroxypropyl)ethylene diamine in an aromatic solvent having high boiling point as a main material; dissolving methane 4,4'-diisocyanate(MDI) that is a hardening agent commonly used in the aromatic solvent having high boiling point, in the same solvent; and blending the two mixtures in the ratio of 1:1, and (b) a second coating on the bridge floor a blend prepared by mixing a polypropylene glycol, triisopropanol amine, 1,4-butadiol and an aromatic oil as a main material; dissolving the same hardening agent(MDI) in the same aromatic oil; and blending the two mixtures in the ratio of 1:1.

Description

교량상판 방수용칠{Waterproof agent for bridges}Waterproofing agent for bridges

본 발명은 교량상판(교면)의 방수용칠에 관한 것으로서, 특히 교면 누수부위나 크랙등을 보수한 후나 새로 시공한 교면에 방수처리를 하기 위한 초벌 및 재벌칠용 교량상판 방수용칠에 관한 것이다.The present invention relates to a waterproof coating of bridge decks (bridges), and more particularly, to repair bridges and chaebol bridge decks for repairing new bridges after repairing bridge leaks or cracks.

일반적으로 교량의 누수부위나 크랙이 진 부위를 유지 보수하기 위하여 각종 보수공사를 한후에나 새롭게 시공된 교량상판인 경우 대개 일부 접착성과 방수성이 있는 아스팔트만을 아스팔트유제(접착용 액체아스팔트)를 매개로 하여 교량상판을 포장하게되므로 방수가 완벽치 못하여 아스팔트사이로 수분이 스며들어 교량을 이루고 있는 시멘 콘크리트층에 도달하게되면 콘크리트층을 쉽게 균열, 파쇄 및 와해시키게되어 단시간내에 교량상판이 취약하게 되는 결점이 있었다.In general, in the case of newly constructed bridge tops after various repair works to maintain the leaked or cracked areas of the bridge, only some adhesive and waterproof asphalt is used as an asphalt emulsion (adhesive liquid asphalt). As the bridge deck is paved, the waterproofness is not perfect, and when water reaches into the cement concrete layer that forms the bridge due to moisture seeping through the asphalt, the concrete layer easily cracks, crushes, and breaks down. .

본 발명은 상기한 바와같은 종래의 교량의 유지보수를 위한 보수 및 방수제의 취약점을 개량하여 보수된 교량이나 새로이 시공된 교량이나를 막론하고 그 상판에 완벽한 보수를 할 수 있는 교량상판 방수용칠을 제공코저하는 것으로서 이를 실예를 들어 상세히 설명하면 다음과 같다.The present invention improves the weakness of the repair and the waterproofing agent for the maintenance of the conventional bridges as described above to provide a waterproof coating for bridge top plate that can be completely repaired regardless of the repaired bridge or newly constructed bridge. If this is described in detail with an example as a coser as follows.

고비점 방향족 용제 50~60wt%에 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민 40~50wt%를 적량의 통상적인 경화촉진제 및 안료와 혼합하여 용해한 것을 주재로하고 상기와 동일한 고비점 방향족 용제 30~50wt%에 관용되는 경화제인 메탄 4,4'디 이소시아네이트(MDI) 50~70wt%를 용해하여된 경화제 혼합물을 상기 주재와 1:1로 배합한 것을 초벌칠로하고, 에틸렌옥사이드 함유 폴리프로필렌 글리콜60~80wt%, 트리이소프로파놀아민5~15wt%, 1.4-부틸디올2~8wt%, 아로마틱 오일(신전유)12~20wt%의 혼합물에 관용되는 경화촉진제 및 안료적량을 첨가한 혼합물을 주재로 하고 상기와 동일한 아로마틱 오일30~50wt%에 상기 초벌칠에 사용한 것과 동일한 경화제인 MDI40~80wt%를 혼합한 경화제 혼합물을 상기 주제와 1:1의 비율로 혼합한 것을 재벌칠로 한 것이다.50 to 60 wt% of high boiling aromatic solvent, 40 to 50 wt% of N, N, N, N-tetrakis (2-hydroxypropyl) ethylenediamine, mixed with an appropriate amount of conventional curing accelerators and pigments, are mainly used. The mixture of 50 to 70 wt% of methane 4,4 'diisocyanate (MDI), which is a curing agent commonly used in 30 to 50 wt% of the same high boiling point aromatic solvent, is prepared by mixing a 1: 1 mixture with the main material, Hardening accelerators and pigments commonly used in mixtures of ethylene oxide-containing polypropylene glycol 60 to 80 wt%, triisopropanolamine 5 to 15 wt%, 1.4-butyldiol 2 to 8 wt%, and aromatic oils (new oil) 12 to 20 wt% It is a conglomerate which mixes the hardener mixture which mixes the appropriate amount in the ratio of 1: 1 with the said main body and 30-50 wt% of the same aromatic oils and MDI40-80 wt% which is the same hardening | curing agent as used for the above first painting. It is painted.

상기에서, 고비점 방향족 용제는 비점이 110~220℃, 증발율 0.06~1.8, 비중 0.85~0.90인 툴루엔, 에틸벤젠,클실렌 또는 그것들의 혼합물, 에틸렌글리콜,퍼클로로 에틸렌중에서 선택된것 중 어느하나로 한다.In the above, the high boiling point aromatic solvent is any one selected from toluene, ethylbenzene, cylene or a mixture thereof, ethylene glycol, perchloroethylene having a boiling point of 110 to 220 ℃, evaporation rate of 0.06 to 1.8, specific gravity 0.85 to 0.90. do.

상기에서, 아로마틱 오일(신전유)은 비중이 15.6℃에서 0.98~1.02이고, 평균 분자량이 230~350이며, 점도가 100℃에서 5~36인 것으로 한다.In the above description, the aromatic oil (extension oil) has a specific gravity of 0.98 to 1.02 at 15.6 ° C, an average molecular weight of 230 to 350, and a viscosity of 5 to 36 at 100 ° C.

이상과 같이 구성되는 본 발명의 교량상판 방수용칠은 보수되었거나 새로 시공된 교량상판에 초벌칠을 하므로서 일차적으로 방수가 되는데 상기 초벌칠로서 코팅한 후 재벌칠을 스프레이 코팅하여 건조한 다음 다시 상기 재벌칠을 스프레이 코팅하면서 규사를 살포하여 삼벌칠층을 형성하게 되면 완벽한 방수가 되는 것으로서 초벌칠과 재벌칠을 사용하는 구체적인 방법은 본 발명 출원과 동일자 출원되는 교면방수방법에서 상세히 설명되어 있다.The bridge top waterproofing coating of the present invention constituted as described above is primarily waterproofed by first applying to a repaired or newly constructed bridge top. After coating as the first coating, the chaebol coating is spray-coated and dried, and then the chaebol coating is spray coated again. While spraying the silica sand to form a three-layer coating layer, as a perfect waterproof, the specific method of using the first coating and the chaebol is described in detail in the cross-section waterproofing method filed with the present invention.

본원 발명의 교량상판 방수용칠중 초벌칠에서 고비점 용제를 사용하는 것은 여기에 사용되는 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민의 용제겸 점도조절을 위한 것과 시멘트내에 강력한 침투력을 이용하여 초벌칠이 세멘트로된 교량상판에 깊이 침투되어 완벽한 방수효과를 얻기위한 것이고, 상기 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민을 사용하는것은 시멘트로된 교량상판과의 강력한 접착력 및 침투력으로 방수효과를 얻기위한 것이며, 경화촉진제는 경화제인 MDI에 의한 초벌칠의 경화를 촉진하기 위한 것이다.The use of a high boiling point solvent in the primary coating of the bridge deck waterproofing coating of the present invention is a solvent and viscosity control agent of N, N, N, N-tetrakiss (2-hydroxypropyl) ethylenediamine used herein, and strong in cement. It is to penetrate deeply into the cemented bridge deck using the penetrating power to obtain the perfect waterproof effect. The use of N, N, N, N-tetrakiss (2-hydroxypropyl) ethylenediamine is made of cement. It is to obtain a waterproof effect by the strong adhesion and penetration force with the bridge deck, the curing accelerator is to promote the curing of the primary coating by the curing agent MDI.

본 발명의 교량상판용칠중에서 재벌칠에서 에틸렌옥사이드 함유 폴리프로필렌 글리콜을 사용하는 것은 방수층이 부드러우면서도 탄력이 있고 질겨서 크랙현상이 나지 않고 방수막을 강하게 유지하기위한 것이 목적이고 트리이소 프로파놀아민 방수칠층을 견고하게 하면서 막이 질기게 하여 쉽게 경화가 되어 방수칠층 형성을 단시간에 이루기 위한 것이며, 1.4-부틸디올은 방수칠층을 더욱 견고하게 하기위한 것이고, 아로마틱 오일은 아스팔트와 규사 및 방수칠층과의 접착력을 증진하기 위한 것이다.The use of ethylene oxide-containing polypropylene glycol in chaebol lacquer coating of the present invention is to keep the waterproof membrane strong without cracking due to the soft, elastic and tough waterproof layer and triisopropanolamine waterproof. To harden the seven layers and harden the film easily to harden to form the waterproofing layer in a short time, 1.4-butyldiol is to strengthen the waterproofing layer more, aromatic oil is the adhesion between asphalt and silica sand and waterproofing layer Is to promote.

Claims (5)

누수, 크랙 발생부위를 보수하였거나 새로이 시공한 교량상판에 일차로 직접 도포하는 초벌칠과 그 초벌칠 위에 다시 적층되게 칠하는 재벌칠로 구성되는 교량 상판 방수용칠.Waterproofing coating for bridge deck consisting of priming paint that is applied directly to the bridge deck that has repaired leaks or cracks or newly installed, and re-lamination on the same. 제1항에 있어서, 초벌칠은 고비점 방향족 용제 50~60wt% 에 N,N,N,N-테트라키스(2-하이드록시 프로필)에틸렌디아민 40~50wt% 을 적량의 관용되는 경화촉진제 및 안료 적량을 첨가한 혼합물을 주재로하고, 상기와 동일한 고비점 방향족 용제 30~50wt% 에 관용되는 경화제인 메탄 4,4' 디이소시아네이트(MDI)50~70wt% 를 용해햐여된 경화제 혼합물을 상기 주제와 1:1의 비율로 혼합한 것으로 구성됨을 특징으로하는 교량 상판 방수용칠.The method of claim 1, wherein the primary coating is a suitable amount of the curing accelerator and pigment suitable for a large amount of 40 ~ 50wt% of N, N, N, N-tetrakis (2-hydroxypropyl) ethylenediamine in 50-60wt% of high boiling aromatic solvent The curing agent mixture was prepared by dissolving 50 to 70 wt% of methane 4,4 'diisocyanate (MDI), which is a curing agent commonly used in the same high boiling aromatic solvent as the above. Water-resistant coating for bridge decks, characterized by mixing at a ratio of 1: 1. 제2항에 있어서, 고비점 방향족 용제는 비점이 110~220℃, 증발율 0.06~1.8, 비중 0.85~0.90인 툴루엔, 에틸벤젠,클실렌 또는 그것들의 혼합물, 에틸렌글리콜,퍼클로로 에틸렌중에서 선택된 어느하나로 함을 특징으로하는 교량상판 방수용 초벌칠.The high boiling point aromatic solvent according to claim 2, wherein the high boiling point aromatic solvent has a boiling point of 110 to 220 ° C, an evaporation rate of 0.06 to 1.8, a specific gravity of 0.85 to 0.90, and any one selected from toluene, ethylbenzene, xylene or a mixture thereof, ethylene glycol, and perchloroethylene. Bridge top waterproofing, characterized in that one. 제1항에 있어서,재벌칠은 에틸렌 옥사이드 함유 폴리프로필렌 글리콜 60~80wt%, 트리이소 프로파놀아민 5wt%~15wt%, 1.4-부틸디올 2wt%~8wt%, 아로마틱 오일(신전유)12~20wt%의 혼합물에 관용되는 경화촉진제 및 안료 적량을 첨가한 혼합물을 주재로하고, 상기와 동일한 아로마틱 오일(신전유) 30~50wt%에 관용되는 메탄 4,4'의 이소시아네이트(MDI) 40~80wt%을 혼합한 경화제 혼합물을 상기 주재와 1:1의 비율로 혼합한 것으로 구성됨을 특징으로하는 교량 상판 방수용 재벌칠.According to claim 1, The chaebol lacquer is 60 ~ 80wt% ethylene oxide containing polypropylene glycol, 5wt% ~ 15wt% triiso propanolamine, 2wt% ~ 8wt% 1.4-butyldiol, 12 ~ aromatic oil 40 to 80 wt% of methane 4,4 'isocyanate (MDI) tolerant to 30 to 50 wt% of the same aromatic oil (new oil) as the predominant mixture of a curing accelerator and a pigment suitable for a 20 wt% mixture The bridge top waterproofing conglomerate, characterized in that consisting of a mixture of the curing agent mixture in a ratio of 1: 1 with the main material. 제4항에 있어서 아로마틱 오일(신전유)은 비중이 15.6℃에서 0.98~1.02이고, 평균 분자량이 230~350이며, 점도가 100℃에서 5~36인 것으로함을 특징으로하는 교량 상판 방수용 재벌칠.The method of claim 4 wherein the aromatic oil (extension oil) has a specific gravity of 0.98 ~ 1.02 at 15.6 ℃, the average molecular weight is 230 ~ 350, the viscosity is 100 ~ 5 ℃ at the temperature of the bridge deck characterized in that 5 ~ 36 .
KR10-2000-0019438A 2000-04-14 2000-04-14 Waterproof agent for bridges KR100369493B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020076214A (en) * 2002-09-05 2002-10-09 주식회사 대아화학 A process for waterproofing surface of concrete bridges

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS594473A (en) * 1982-06-28 1984-01-11 Asahi Glass Co Ltd Painting and finishing method of cement base material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020076214A (en) * 2002-09-05 2002-10-09 주식회사 대아화학 A process for waterproofing surface of concrete bridges

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