KR100369493B1 - Waterproof agent for bridges - Google Patents

Waterproof agent for bridges Download PDF

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KR100369493B1
KR100369493B1 KR10-2000-0019438A KR20000019438A KR100369493B1 KR 100369493 B1 KR100369493 B1 KR 100369493B1 KR 20000019438 A KR20000019438 A KR 20000019438A KR 100369493 B1 KR100369493 B1 KR 100369493B1
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mixture
bridge
coating
waterproofing
high boiling
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KR10-2000-0019438A
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KR20000049586A (en
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서청
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(주)창신종합엔지니어링
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01DCONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
    • E01D19/00Structural or constructional details of bridges
    • E01D19/08Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
    • E01D19/083Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Paints Or Removers (AREA)
  • Bridges Or Land Bridges (AREA)

Abstract

고비점 방향족 용제에 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민을 용해한 것을 주재로하고 상기와 동일한 고비점 방향족 용제에 관용되는 경화제인 메탄 4,4'디 이소시아네이트(MDI)을 용해한 경화제 혼합물을 상기 주재와 1:1로 배합한 것을 초벌칠로하고, 폴리프로필렌 글리콜, 트리이소프로파놀아민, 1.4-부틸디올, 아로마틱 오일(신전유)을 주재로 하고 상기와 동일한 아로마틱 오일에 상기와 동일한 경화제인 MDI을 혼합한 경화제 혼합물을 상기 주제와 1:1의 비율로 배합한 것을 재벌칠로 하므로서 방수성이 양호하고 아스팔트와의 접착제력 및 시공력이 우수한 교량상판 방수용칠이 되는것이다.Methane 4,4 'diisocyanate, which is a curing agent commonly used in the high boiling aromatic solvents as described above, is mainly based on dissolving N, N, N, N-tetrakis (2-hydroxypropyl) ethylenediamine in a high boiling aromatic solvent. The mixture of the curing agent mixture dissolved in MDI 1: 1 with the main material was first applied, and the polypropylene glycol, triisopropanolamine, 1.4-butyldiol, and aromatic oil (new oil) were used as the main material. As a chaebol coating of a mixture of aromatics with MDI, the same curing agent as above, in a ratio of 1: 1 with the above-mentioned main body, it has good waterproofness and waterproofing of bridge deck with excellent adhesive strength and construction ability. That's it.

Description

교량상판 방수용칠{Waterproof agent for bridges}Waterproofing agent for bridges

본 발명은 교량상판의 방수용칠에 관한 것으로서, 특히 교면 누수부위나 크랙등을 보수한 후나 새로 시공한 교량상판에 방수처리를 하기 위한 초벌 및 재벌칠용 교량상판 방수용칠에 관한 것이다.The present invention relates to waterproof coating of bridge decks, and more particularly, to repair waterproofing of bridge decks, cracks, etc., or to repair waterproofing of bridge decks for priming and chaebol for newly constructed bridge decks.

일반적으로 교량의 누수부위나 크랙이 진 부위를 유지 보수하기 위하여 각종 보수공사를 한 교량상판에나 새롭게 시공된 교량상판(이하 교면이라고 함)에 포장하는 것으로는 대개 일부 접착성과 방수성이 있는 아스팔트만으로된 아스팔트유제(접착용 액체아스팔트)를 매개로 하여 교면을 포장하게되므로 방수가 완벽치 못하여 아스팔트사이로 수분이 스며들어 교량을 이루고 있는 시멘 콘크리트층에까지 도달하게되면 시멘 콘크리트층을 쉽게 균열, 파쇄 및 와해시키게되므로 단시간내에 교면을 취약하게 하는 결점이 있었다.In general, in order to maintain the leaked part or cracked part of the bridge, it is usually packaged on bridge deck with various repair work or newly constructed bridge deck (hereinafter referred to as bridge). As the pavement is paved with asphalt emulsion (adhesive liquid asphalt), the waterproofing is not perfect, and when water reaches into the cement concrete layer that forms the bridge, it is easily cracked, crushed and broken. As a result, there was a defect that weakens the bridge in a short time.

본 발명은 상기한 바와같은 종래의 교량의 유지보수를 위한 보수 및 방수제의 취약점을 개량하여 보수된 교면이나 새로이 시공된 교면이나를 막론하고 그 상판에 완벽한 보수를 할 수 있는 교면 방수용칠을 제공코저하는 것으로서 이를 실예를 들어 상세히 설명하면 다음과 같다.The present invention improves the weakness of the repair and the waterproofing agent for the maintenance of the conventional bridge as described above to provide a waterproof waterproof coating that can be completely repaired on the top plate, whether repaired bridge or newly constructed bridge. If it is described in detail by taking an example as a decrease as follows.

고비점 방향족 용제 50~60wt%에 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민 40~50wt%를 적량의 통상적인 경화촉진제 및 안료와 혼합하여 용해한 것을 주재로하고 상기와 동일한 고비점 방향족 용제 30~50wt%에 관용되는 경화제인 메탄 4,4'디 이소시아네이트(MDI) 50~70wt%를 용해하여된 경화제 혼합물을 상기 주재와 1:1로 배합한 것을 초벌칠로하고, 에틸렌옥사이드 함유 폴리프로필렌 글리콜60~80wt%, 트리이소프로파놀아민5~15wt%, 1.4-부틸디올2~8wt%, 아로마틱 오일(신전유)12~20wt%의 혼합물에 관용되는 경화촉진제 및 안료적량을 첨가한 혼합물을 주재로 하고 상기와 동일한 아로마틱 오일30~50wt%에 상기 초벌칠에 사용한 것과 동일한 경화제인 MDI40~80wt%를 혼합한 경화제 혼합물을 상기 주제와 1:1의 비율로 혼합한 것을 재벌칠로 한 것이다.50 to 60 wt% of high boiling aromatic solvent, 40 to 50 wt% of N, N, N, N-tetrakis (2-hydroxypropyl) ethylenediamine, mixed with an appropriate amount of conventional curing accelerators and pigments, are mainly used. The mixture of 50 to 70 wt% of methane 4,4 'diisocyanate (MDI), which is a curing agent commonly used in 30 to 50 wt% of the same high boiling point aromatic solvent, is prepared by mixing a 1: 1 mixture with the main material, Hardening accelerators and pigments commonly used in mixtures of ethylene oxide-containing polypropylene glycol 60 to 80 wt%, triisopropanolamine 5 to 15 wt%, 1.4-butyldiol 2 to 8 wt%, and aromatic oils (new oil) 12 to 20 wt% It is a conglomerate which mixes the hardener mixture which mixes the appropriate amount in the ratio of 1: 1 with the said main body and 30-50 wt% of the same aromatic oils and MDI40-80 wt% which is the same hardening | curing agent as used for the above first painting. It is painted.

상기에서, 고비점 방향족 용제는 비점이 110~220℃, 증발율이 0.06~1.8, 비중이 0.85~0.90인 톨루엔, 에틸벤젠,클실렌 또는 그것들의 혼합물, 에틸렌글리콜,퍼클로로 에틸렌중에서 선택된것 중 어느하나로 한다.In the above, the high boiling point aromatic solvent is any one selected from toluene, ethylbenzene, xylene or a mixture thereof, ethylene glycol, perchloroethylene having a boiling point of 110 to 220 ℃, evaporation rate of 0.06 to 1.8, specific gravity of 0.85 to 0.90 One.

상기에서, 아로마틱 오일(신전유)은 비중이 15.6℃에서 0.98~1.02이고, 평균 분자량이 230~350이며, 점도가 100℃에서 5~36인 것으로 한다.In the above description, the aromatic oil (extension oil) has a specific gravity of 0.98 to 1.02 at 15.6 ° C, an average molecular weight of 230 to 350, and a viscosity of 5 to 36 at 100 ° C.

이상과 같이 구성되는 본 발명의 교면 방수용칠은 보수되었거나 새로 시공된 교면에 먼저 초벌칠로 칠을 하므로서 일차적으로 방수가 되는데 상기 초벌칠을 한 위에 재벌칠을 스프레이방법에 의해 코팅하여 건조한 다음 다시 그 위에 상기 재벌칠을 반복 스프레이 코팅하면서 규사를 살포하여 삼벌칠층을 형성하게 되면 완벽한 방수가 되는 것으로서 초벌칠과 재벌칠을 사용하는 구체적인 방법은 본 발명 출원과 동일자 출원된 교면방수방법에서 상세히 설명되어 있다.The cross-coating waterproof coating of the present invention constituted as described above is primarily waterproofed by first painting the bridges that have been repaired or newly constructed, and the first coating is dried by coating the chaebol coating by the spray method and then dried again. When spraying the chaebol coating repeatedly spray coating the silica sand to form a three-layer coating layer as a perfect waterproof, the specific method of using the primary coating and chaebol painting is described in detail in the cross-section waterproofing method filed with the present invention.

본원 발명의 교면 방수용칠중 초벌칠에서 고비점 용제를 사용하는 것은 여기에 사용되는 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민의 용제겸 점도조절을 위한 것과 시멘트내에 강력한 침투력을 이용하여 초벌칠이 세멘트로된 교면에 깊이 침투되어 완벽한 방수효과를 얻기위한 것이고, 상기 N,N,N,N-테트라 키스(2-하이드록시 프로필)에틸렌디아민을 사용하는것은 시멘트로된 교면과의 강력한 접착력 및 침투력으로 강력한 방수효과를 얻기위한 것이며, 경화촉진제는 경화제인 MDI에 의한 초벌칠의 경화를 촉진하기 위한 것이다.상기에서 용제와 접착제 또는 경화제등의 배합비율은 점도조절 및 접착력과 침투력을 향상시키기 위한 것으로서 상기 배합범위가 가장 바람직하다.The use of a high boiling point solvent in the primary coating of the cross-coating waterproofing coating of the present invention is for the solvent and viscosity control of N, N, N, N-tetrakiss (2-hydroxypropyl) ethylenediamine used herein, and strong penetration in cement. In order to achieve perfect waterproofing effect, the primary coating penetrates deeply into the cement bridge, and the use of N, N, N, N-tetrakiss (2-hydroxypropyl) ethylenediamine is used for cement bridges. To achieve a strong waterproof effect by the strong adhesion and penetration of the, the curing accelerator is to promote the curing of the primary coating by the curing agent MDI. In the above, the mixing ratio of the solvent and the adhesive or curing agent, such as viscosity control and adhesion and penetration. As for improving, the said compounding range is the most preferable.

본 발명의 교량상판용칠중에 재벌칠에서 에틸렌옥사이드 함유 폴리프로필렌 글리콜을 사용하는 것은 방수층이 부드러우면서도 탄력이 있고 질겨서 크랙현상이 나지 않고 방수막을 강하게 유지하기위한 것이 목적이고 접착력이 강한 도장제인 트리이소 프로파놀아민 방수칠층을 견고하게 하면서 막이 질기게 하여 쉽게 경화가 되어 방수칠층 형성을 단시간에 이루기 위한 것이며, 1.4-부틸디올은 방수칠층을 더욱 견고하게 하기위한 것이고, 아로마틱 오일은 아스팔트와 규사 및 방수칠층과의 접착력을 증진하기 위한 것으로서 상기 재벌칠을 형성하는 각 물질들의 배합비율은 재벌칠의 분사 도포에 알맞은 점도와 접착력등을 고려하여 가장 바람직한 비율로 배합한 것이다.The use of ethylene oxide-containing polypropylene glycol in chaebol lacquer in the bridge top coating of the present invention is a tree which is a coating agent having a strong and adhesive force for the purpose of keeping the waterproof membrane strong without being cracked due to the soft, elastic and tough waterproof layer. Isopropanolamine waterproofing layer makes the film tough and easy to harden to form waterproofing layer in a short time, 1.4-butyldiol is to make the waterproofing layer more solid, and aromatic oil is asphalt and silica sand And to improve the adhesion to the waterproof coating layer, the compounding ratio of each of the materials forming the chaebol is formulated in the most desirable ratio in consideration of the viscosity and adhesion for the spray coating of the chaebol.

Claims (5)

(삭제)(delete) 기존 교면의 누수나 클랙발생부위 및 새로 시공한 교량상판용의 초벌칠과 재벌칠로된 교량상판 방수용칠에 있어서, 상기 초벌칠을 고비점 방향족 용제 50~60wt%에 N,N,N,N-테트라키스(2-하이드록시 프로필)에틸렌디아민 40~50wt%을 적량의 관용되는 경화촉진제 및 안료 적량을 첨가한 혼합물을 주재로하고, 상기와 동일한 고비점 방향족 용제 30~50wt%에 관용되는 경화제인 메탄 4,4' 디이소시아네이트(MDI)50~70wt%를 용해하여된 경화제 혼합물을 상기 주제와 1:1의 비율로 혼합한 것으로 구성함을 특징으로하는 교량 상판 방수용칠.In the waterproofing coating of bridge decks with leaks or cracks on existing bridges, and bridge coatings and re-coatings for newly constructed bridge decks, the primary coating is 50 to 60wt% of N, N, N, N-tetra in a high boiling point aromatic solvent. Methane, which is a curing agent commonly used in the above-mentioned high boiling point aromatic solvent 30-50 wt%, mainly containing a mixture of kiss (2-hydroxy propyl) ethylenediamine 40-50 wt% and a suitable curing accelerator and a suitable amount of pigment. 50. 70 wt% of 4,4 'diisocyanate (MDI) is a waterproof coating for the bridge top plate, characterized in that consisting of a mixture of the primary and the curing agent mixture in a ratio of 1: 1. 제2항에 있어서, 상기 고비점 방향족 용제는 비점이 110~220℃, 증발율이 0.06~1.8, 비중이 0.85~0.90인 톨루엔, 에틸벤젠, 클실렌 또는 그것들의 혼합물, 에틸렌글리콜, 퍼클로로 에틸렌중에서 선택된 어느하나로 함을 특징으로하는 교량상판 방수용 칠.The toluene, ethylbenzene, xylene or a mixture thereof, ethylene glycol, perchloro ethylene according to claim 2, wherein the high boiling aromatic solvent has a boiling point of 110 to 220 ° C, an evaporation rate of 0.06 to 1.8, and a specific gravity of 0.85 to 0.90. Bridge deck waterproofing paint, characterized in that any one selected. 기존 교면의 누수나 클랙발생부위 및 새로 시공한 교량상판용의 초벌칠과 재벌칠로된 교량상판 방수용칠에 있어서, 상기 재벌칠을 에틸렌 옥사이드 함유 폴리프로필렌 글리콜 60~80wt%, 트리이소 프로파놀아민 5wt%~15wt%, 1.4-부틸디올 2wt%~8wt%, 아로마틱 오일 12~20wt%의 혼합물에 관용되는 경화촉진제 및 안료 적량을 첨가한 혼합물을 주재로하고, 상기와 동일한 아로마틱 오일 30~50wt%에 관용되는 메탄 4,4'의 이소시아네이트(MDI) 40~80wt%을 혼합한 경화제 혼합물을 상기 주재와 1:1의 비율로 혼합한 것으로 구성함을 특징으로하는 교량 상판 방수용 칠.In the waterproofing coating of bridge tops with leaks or cracks on existing bridges and the first and the second tops for bridge decks, the chaebol is 60-80 wt% of ethylene oxide-containing polypropylene glycol, triisopropanolamine Mainly a mixture of 5 wt% to 15 wt%, 1.4-butyl diol 2 wt% to 8 wt%, and a curing accelerator and a pigment suitable to a mixture of 12 to 20 wt% of aromatic oils, and 30 to 50 wt% of the same aromatic oil as above. A coating for waterproofing a bridge deck, comprising a mixture of a hardener mixture of 40 to 80 wt% of methane 4,4 'isocyanate (MDI) commonly used in a ratio of 1: 1 with the main material. 제4항에 있어서, 상기 아로마틱 오일은 비중이 15.6℃에서 0.98~1.02이고, 평균 분자량이 230~350이며, 점도가 100℃에서 5~36인 것으로함을 특징으로하는 교량 상판 방수용 칠.The method of claim 4, wherein the aromatic oil has a specific gravity of 0.98 ~ 1.02 at 15.6 ℃, the average molecular weight is 230 ~ 350, the viscosity of the bridge top plate, characterized in that 5 to 36 at 100 ℃.
KR10-2000-0019438A 2000-04-14 2000-04-14 Waterproof agent for bridges KR100369493B1 (en)

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KR20020076214A (en) * 2002-09-05 2002-10-09 주식회사 대아화학 A process for waterproofing surface of concrete bridges

Citations (1)

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Publication number Priority date Publication date Assignee Title
JPS594473A (en) * 1982-06-28 1984-01-11 Asahi Glass Co Ltd Painting and finishing method of cement base material

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
JPS594473A (en) * 1982-06-28 1984-01-11 Asahi Glass Co Ltd Painting and finishing method of cement base material

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