KR20060130959A - Ommited - Google Patents

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Publication number
KR20060130959A
KR20060130959A KR1020050050714A KR20050050714A KR20060130959A KR 20060130959 A KR20060130959 A KR 20060130959A KR 1020050050714 A KR1020050050714 A KR 1020050050714A KR 20050050714 A KR20050050714 A KR 20050050714A KR 20060130959 A KR20060130959 A KR 20060130959A
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South Korea
Prior art keywords
coating agent
surface coating
solvent
color asphalt
asphalt
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KR1020050050714A
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Korean (ko)
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오은영
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오은영
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Priority to KR1020050050714A priority Critical patent/KR20060130959A/en
Publication of KR20060130959A publication Critical patent/KR20060130959A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/41Organic pigments; Organic dyes

Abstract

Provided is a high-speed curable surface coating agent, which has highly increased drying and hardening rates and improved physical properties, increases a service life of color asphalt, and facilitates maintenance and repair of color asphalt. The surface coating agent for color asphalt is prepared by mixing one selected from various synthetic resin polymers or elastomers, or a combination thereof with one organic solvent selected from methylene chloride or 141b, or a combination thereof, homogeneously. The solvent further comprises at least one solvent with a high boiling point. The coating agent further comprises at least one admixture selected from various physical admixtures and chemical admixtures in order to reinforce physical and chemical properties of the surface coating agent.

Description

초고속 경화성 표면코팅제 및 칼라아스팔트{ommited}Ultra-fast curing surface coating agent and colored asphalt {ommited}

본 발명은 칼라아스팔트용 표면코팅제에 관한 것이다.The present invention relates to a surface coating agent for color asphalt.

공지의 칼라아스팔트의 표면코팅제로는 등록번호20-0364311-0000의As the surface coating agent of the known color asphalt, the registration number 20-0364311-0000

수성용제인 물(H2O)에 합성수지를 용해 및 필요에 따라 안료를 추가로 투입하므로 제조한 것을 특징으로 하는 칼라아스팔트 유지 및 보수용 표면코팅제에 관한 내용이 공지되어 있다.The content of the surface coating agent for color asphalt maintenance and repair, which is prepared by dissolving synthetic resin in water (H 2 O), which is an aqueous solvent, and additionally adding a pigment as necessary, is known.

그러나 상기에 있어서는,But in the above,

용질에 따른 용제로서 물(H20)을 사용하고 있으므로,As water (H20) is used as a solvent according to the solute,

내수성의 약화로 인해 접착성, 내마모성, 내오염성, 내후성 등의 강도가 저하되고, Due to the weakening of water resistance, the strength of adhesiveness, abrasion resistance, pollution resistance, weather resistance, etc. is lowered,

특히, 용제로 사용된 물(H2O)의 특성상 비점이 높아 속건성이 떨어지는 단점을 나타내고 있다.In particular, the water (H 2 O) used as a solvent has a high boiling point due to the disadvantages of fast drying properties.

그러므로 본 발명에서는 상술된 무기용제의 단점이 극복된 우수한 품질의 칼라아스팔트용 표면코팅제를 제공하기 위하여,Therefore, in the present invention, in order to provide a good quality surface coating agent for color asphalt overcoming the disadvantages of the above-described inorganic solvent,

단독 또는 혼용한 각종 합성수지 폴리머 또는 엘라스토머에 To various synthetic resins or elastomers, alone or in combination

유기용제인 MC(Methylene Chloride) 또는 141b를 단독으로 사용하거나,Organic solvent MC (Methylene Chloride) or 141b alone or

상기 단독 또는 혼용 용제에 비점 등의 화학적 물성이 MC 및 141b보다 높은 여타의 용제를 필요에 따라 추가로 혼합하여 작업성 및 시공성을 증대된 투명 또는 유색의 칼라아스팔트용 표면코팅제를 제조하고자 한다.To further prepare a surface coating agent for a transparent or colored asphalt with improved workability and workability by further mixing the solvent or other solvents having higher chemical properties such as boiling point than MC and 141b to the solvent alone or mixed.

또한, 필요에 따라 상기에 각종 물리적혼화재 및 화학적혼화제를 1 종 이상 추가로 투입하므로써 더욱 물성이 개선된 표면코팅제를 제조할 수 있다.In addition, by adding one or more kinds of various physical admixtures and chemical admixtures as necessary, it is possible to produce a surface coating agent with improved physical properties.

본 발명은The present invention

유기용제 및 수성용제에 따르는 다양한 단점을 강화하기 위한 목적으로 착안된 것으로서,It is conceived for the purpose of reinforcing various disadvantages according to the organic solvent and the aqueous solvent,

일반적으로 사용되어온 기존의 유성용제인 신나, 톨루엔, 알콜, MEK, 석유용제 등의 용제에 따른 단점인 악취, 인화성, 환경유해성, 인체유해성 등의 단점을 완화시키고, To alleviate the disadvantages of odor, flammability, environmental hazard, human harmfulness, etc., which are disadvantages of solvents such as thinner, toluene, alcohol, MEK, petroleum solvent, etc.

수성용제인 물(H2O)의 단점인 내수성, 속건성, 강도, 접착성 등이 낮은 단점을 해소하므로써By eliminating the disadvantages of water resistance, quick drying, strength, adhesiveness, which are disadvantages of water (H2O), which is an aqueous solvent,

우수한 기계적 물성인 내마모성, 내후성, 내오염성, 내수성, 접착성 및 속건성 등의 칼라아스팔트표면코팅제의 요구물성을 충족시키는 표면코팅제를 제공하기 위하여 In order to provide a surface coating agent that satisfies the properties of the color asphalt surface coating agent such as wear resistance, weather resistance, pollution resistance, water resistance, adhesiveness and quick-drying, which are excellent mechanical properties

각종 폴리머 또는 엘라스토머를 1종 이상 단독 또는 혼용한 원료에 One or more kinds of polymers or elastomers may be used alone or in combination.

유성용제인 MC 또는 141b에 용해시키므로써 제조한 칼라아스팔트용 표면코팅제를 제공한다.It provides a surface coating agent for color asphalt prepared by dissolving in MC or 141b which is an oil solvent.

본 발명을 보다 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

상기를 위하여 본 발명에서는,In the present invention for the above,

각종의 단독 또는 혼용된 합성수지 폴리머(polymer) 또는 엘라스토머(elastomer)에 To a variety of single or mixed synthetic polymers or elastomers

비점이 낮은 초고속 휘발성 유기용제인 MC(Methylene Chloride) 또는 141b를 단독 또는 혼용하거나 Methylene Chloride (MC) or 141b, a low-boiling ultra-high volatile organic solvent, can be used alone or in combination

또는 상기 각 용제에 비해 상대적으로 비점이 높은 기타 용제를 1 종 이상 혼합한 혼합용제를 사용한다.Or a mixed solvent in which one or more other solvents having a relatively high boiling point compared to the above solvents is used.

*각 용제의 비점 비교표*Boiling point comparison table for each solvent

용 제   Solvent 비 점  Rain point MC    MC 40℃    40 ℃ 141b   141b 40℃    40 ℃ 메탄올    Methanol 64.65℃    64.65 ℃ 에탄올    ethanol 78.32℃   78.32 ℃ 프로판올    Propanol 97.15℃   97.15 ℃ 물(H2O)    Water (H2O) 100℃   100 ℃ 에틸렌글리콜    Ethylene glycol 197.7℃   197.7 ℃ 기타    Etc -     -

그 외에도Besides

중비점 용제로서 비점이 100∼150℃톨루엔, 크실렌, 부틸 알코올 등 As a boiling point solvent, boiling point is 100-150 degreeC, toluene, xylene, butyl alcohol, etc.

고비점 용제 비점이 150℃이상 부틸셀로솔브, 부틸셀로솔브 아세테이트, pe글리콜 등을 포함하는 상대적 고비점 용제 중 1종 이상을 추가 투입할 수 있으며, High boiling point solvent It is possible to add at least one of the high boiling point solvents containing boiling point 150 ℃ or more butyl cellosolve, butyl cellosolve acetate, pe glycol, etc.,

상술된 예 이외에도 다양한 용제를 포함하며, 추가 투입 용제로 사용할 수 있다.In addition to the examples described above, various solvents may be included and used as additional input solvents.

이는 본 발명에 따른 MC 및 141b가 매우 낮은 비점을 갖는 관계로 This is because MC and 141b according to the present invention have a very low boiling point.

실제 시공된 칼라아스팔트의 표면에 표면코팅제 살포시에 초급속의 휘발로 인하여 원료인 합성수지폴리머 및 엘라스토머의 급속한 경화가 초래되므로써 비록 매우 짧은 시간차(약 10초)를 간격으로 하여 살포된 경우라할지라도 코팅제 간의 원활한 접착이 발현되지 못 하는 단점을 초래하게 되므로, As a result of the rapid volatilization of the surface coating agent on the surface of the colored asphalt, the rapid curing of the synthetic resin polymer and the elastomer resulted in the application of the coating agent even though the coating was applied at very short time intervals (about 10 seconds). Since this leads to the disadvantage of not exhibiting smooth adhesion,

상기 표에서 예시된 바와 같이 상대적으로 비점이 높은 휘발성 용제를 적정량 추가 혼합하여 표면코팅제를 제조하므로써 결과적으로 용제의 비점이 상승되므로써 휘발속도가 저하되어 일정 시간차를 두고 살포되어지는 코팅제 간의 원활한 접착을 가능하도록 해 주어 시공성 및 작업성이 크게 향상되게 된다.As exemplified in the above table, the surface coating agent is prepared by additionally mixing a relatively high boiling point volatile solvent, and as a result, the boiling point of the solvent is increased, thereby lowering the volatilization rate, thereby enabling smooth adhesion between the coatings sprayed with a certain time difference. The workability and workability are greatly improved.

또, 상기 MC 및 141b는 여타의 유기용제에 비해 심한 악취를 발산하지 않으며,In addition, the MC and 141b does not emit a bad odor compared to other organic solvents,

특히, 유기용제의 단점인 인화성에 대해 불연성의 특성을 지니고 있으며, In particular, it has a nonflammable property with respect to flammability which is a disadvantage of the organic solvent,

환경위해성평가에 의한 환경위해성 유기용제로 분류되지 않은 제품이므로 환경 및 인체에 비교적 안전한 유기용제라고 할 수 있다.It is a product that is not classified as an environmental risk organic solvent by environmental risk assessment, so it is a relatively safe organic solvent to the environment and human body.

한편, 상기 표면코팅제의 제조시에 이하 기술된 각종 물리적혼화재 및 화학적혼화제를 추가로 투입하므로써 물성이 더욱 바람직하게 개선된 칼라아스팔트용 표면코팅제를 제조할 수 있다.On the other hand, by the addition of various physical admixtures and chemical admixtures described below at the time of the preparation of the surface coating agent it is possible to manufacture a surface coating agent for color asphalt more preferably improved.

그 예로서,As an example

1) 가소제(可塑劑) : 도막의 유연성, 노후방지, 내구성 등을 부여한다.   1) Plasticizer (可塑 劑): Provides flexibility, anti-aging and durability of coating.

주성분에 유연성을 부여한다(푸탈산디부틸 등).                        Flexibility is given to the main component (dibutyl phthalate, etc.).

2) 분산제(分散劑) : 안료의 분산을 쉽게하고, 분산된 안료의 재응집을 막아   2) Dispersant: It is easy to disperse the pigment and prevents reaggregation of the dispersed pigment.

준다.                       give.

3) 침강 방지제 : 안료와 수지가 분리되어 침전하는 것을 방지하고 점도를   3) Sedimentation inhibitor: prevent pigment and resin from sedimentation and increase viscosity

높여 사용을 쉽게 한다.                   To make it easier to use.

4) 색분리방지제 : 여러가지 원색(조색제)을 혼합 하였을 때 분리되는 현상을   4) Color Separation Inhibitor: The phenomenon of separation when mixing several primary colors (coloring agents).

방지한다.                    prevent.

5) 자외선흡수제 : 색의 변색을 막아주는 물질(도막의 약화 방지)  5) UV absorbers: substances that prevent color discoloration (prevention of weakening of the coating)

6) 증점제 : 수성용제를 추가투입하여 제조한(에멀젼, 라텍스 등)의   6) Thickener: of prepared by adding additional aqueous solvent (emulsion, latex, etc.)

겉보기 점도를 높이기 위해 첨가한다(메틸셀룰로스, 카본불랙,             Add to increase the apparent viscosity (methylcellulose, carbon black,

탄산칼슘 등).               Calcium carbonate and the like).

7) 계면활성제 :각 원료간의 혼합 및 반응환경을 원활하게 조성한다.  7) Surfactant: Smoothly mixes and reacts with each raw material.

8)경화제 : 특히,우레탄계 원료를 사용하여 표면코팅제를 제조할 경우에   8) Hardening agent: Especially when manufacturing surface coating agent using urethane raw materials

있어서는              In that case

경화제로 HMDI (헥사메틸렌 디 이소시아 네이트),             HMDI (hexamethylene di isocyanate) as a hardener,

IPDI (이소프론 디 이소시아네이트) 등을 첨가하므로써 내황변성,              Yellowing resistance by adding IPDI (isoprone diisocyanate)

내후성 등의 장점을 부여한다.             It gives advantages such as weather resistance.

9)산화방지제: 고무를 주성분으로 하는 접착제에 투입하며,  9) Antioxidant: It is put in the adhesive which contains rubber as the main ingredient

이는 고무계 성분이 투입된 접착제가 시일이 경과함에 따라 일광               This is due to the fact that the rubber-based adhesive seals with sunlight.

또는 산소 등에 의해 변질되는 것을 방지하기 위해 첨가한다.               Or in order to prevent deterioration by oxygen or the like.

10)소포제:거품이 생기기 쉬운 접착제에 사용되는 것으로 거품을 없애기도  10) Defoamer: It is used for the adhesive which a bubble is easy to remove, and

하고 생기는 것을 방지하기도 한다(실리콘오일 등).            It also prevents them from forming (silicone oil, etc.).

11)착색제:필요에 따라 접착제에 희망하는 색을 부여하기 위해 사용한다.  11) Colorant: Used to give the adhesive the desired color as needed.

(염료/안료).          (Dyes / pigments).

12)방부제: 본 발명에 따라 친환경성을 향상시키기 위하여 수성용제를 12) Preservative: In order to improve the environmental friendliness according to the present invention,

추가 투입하여 제조한 수성접착제의 보존 중에 부패하거나 곰팡이가           Decayed or mildew during the preservation of aqueous adhesives

생기는 것을 방지하기 위한 목적으로 사용한다(펜타클로로페놀 등).          Used for the purpose of preventing the formation (pentachlorophenol, etc.).

 

등이 사용될 수 있으며,     Etc. may be used,

상술된 이외에도 다양한 원료를 추가 투입 제조할 수 있다.    In addition to the above, various raw materials may be additionally prepared.

한편, Meanwhile,

본 발명에 따른 According to the invention

폴리머(polymer)는 분자가 중합하여 생성되는 화합물로서, A polymer is a compound formed by polymerization of molecules.

2종류의 단위체로 된 혼성중합체(공중합체)인 코폴리머(copolymer),Copolymer, a copolymer of two kinds of units,

3종류의 단위체로 된 하나의 고분자를 터폴리머(terpolymer)와One polymer consisting of three types of monomers is used for terpolymer and

합성고분자인 합성중합체 및 고무·녹말·단백질 등 천연중합체 등을 모두 포함한다.Synthetic polymers include synthetic polymers and natural polymers such as rubber, starch and protein.

엘라스토머(elastomer)는 상온 부근에서 고무처럼 고탄성을 나타내는 고분자물질의 총칭으로서, 탄성률 ㎝²당 1∼100㎏ 정도, 신장률 100% 이상인 고탄성체로서 탄성중합체라고도 하며,Elastomer is a general term for a high elastic material like rubber at room temperature. The elastomer is a high elastic material having an elastic modulus of about 1 to 100 kg and an elongation of 100% or more.

외력으로 인해 생긴 변형이 외력을 제거하면 즉시 원상태로 되돌아가는 성질이 있다.Deformation caused by external force removes the external force and immediately returns to its original state.

안료Pigment

유기 또는 무기안료, 특히 상기를 용제에 희석된 토너를 사용하는 것이 균일한 혼합을 위해 바람직한 방법이다.The use of organic or inorganic pigments, especially toners diluted in solvents, is the preferred method for uniform mixing.

이하, 실시예를 통해 본 발명의 표면코팅제를 제조하였다.Hereinafter, the surface coating agent of the present invention was prepared through the examples.

실시예1)Example 1

MC(용제) 100KGMC (solvent) 100KG

아크릴수지분말 30KGAcrylic resin powder 30KG

CMC(증점제) 1KGCMC (Thickener) 1KG

NP8(계면활성제) 0.5KGNP8 (Surfactant) 0.5KG

에틸렌글리콜 20KGEthylene Glycol 20KG

산화철(안료) 10KGIron Oxide (Pigment) 10KG

을 상온에서 균일하게 혼합하여 액상의 표면코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid surface coating agent,

상기를 칼라아스팔트의 표면에 살포하였으며,The above was sprayed onto the surface of the colored asphalt,

살포 2분 경과 후에 상기 용제가 완전히 휘발되므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of sparging, the solvent was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

실시예2)Example 2

MC(용제) 100KGMC (solvent) 100KG

PS(폴리스틸렌) 20KGPS (polystyrene) 20KG

아크릴수지분말 10KGAcrylic resin powder 10KG

CMC(증점제) 1KGCMC (Thickener) 1KG

NP8(계면활성제) 0.5KGNP8 (Surfactant) 0.5KG

산화철(안료) 10KGIron Oxide (Pigment) 10KG

을 상온에서 균일하게 혼합하여 액상의 코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid coating agent,

상기를 칼라아스팔트의 표면에 도포하였으며,The above was applied to the surface of the colored asphalt,

도포 2분 경과 후에 상기 용제가 완전히 휘발되므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of application, the solvent was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

실시예3)Example 3

MC(용제) 100KGMC (solvent) 100KG

PS(폴리스틸렌) 20KGPS (polystyrene) 20KG

석유수지 10KGPetroleum Resin 10KG

CMC(증점제) 1KGCMC (Thickener) 1KG

NP8(계면활성제) 0.5KGNP8 (Surfactant) 0.5KG

산화철(토너) 20KGIron Oxide (Toner) 20KG

을 상온에서 균일하게 혼합하여 액상의 코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid coating agent,

상기를 칼라아스팔트의 표면에 도포하였으며,The above was applied to the surface of the colored asphalt,

도포 2분 경과 후에 상기 용제가 완전히 휘발되므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of application, the solvent was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

실시예4)Example 4

MC(용제) 100KGMC (solvent) 100KG

PS(폴리스틸렌) 20KGPS (polystyrene) 20KG

멜라민수지분말 10KGMelamine Resin Powder 10KG

CMC(증점제) 1KGCMC (Thickener) 1KG

NP8(계면활성제) 0.5KGNP8 (Surfactant) 0.5KG

산화철(안료) 10KGIron Oxide (Pigment) 10KG

을 상온에서 균일하게 혼합하여 액상의 코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid coating agent,

상기를 칼라아스팔트의 표면에 도포하였으며,The above was applied to the surface of the colored asphalt,

도포 2분 경과 후에 상기 용제가가 완전히 휘발되므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of application, the solvent value was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

실시예5)Example 5

MC(용제) 100KGMC (solvent) 100KG

멜라민수지분말 10KGMelamine Resin Powder 10KG

CMC(증점제) 1KGCMC (Thickener) 1KG

NP8(계면활성제) 0.5KGNP8 (Surfactant) 0.5KG

산화철(토너) 10KGIron Oxide (Toner) 10KG

을 상온에서 균일하게 혼합하여 액상의 코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid coating agent,

상기를 칼라아스팔트의 표면에 도포하였으며,The above was applied to the surface of the colored asphalt,

도포 2분 경과 후에 상기 용제가가 완전히 휘발시키므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of application, the solvent was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

실시예6)Example 6

MC(용제) 100KGMC (solvent) 100KG

우레탄수지(액상;고형분50%) 20KGUrethane Resin (Liquid; Solid 50%) 20KG

아크릴수지분말 10KGAcrylic resin powder 10KG

CMC(증점제) 1KGCMC (Thickener) 1KG

NP8(계면활성제) 0.5KGNP8 (Surfactant) 0.5KG

산화철(안료) 10KGIron Oxide (Pigment) 10KG

경화제(HMDI) 0.1KGCuring Agent (HMDI) 0.1KG

을 상온에서 균일하게 혼합하여 액상의 코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid coating agent,

상기를 칼라아스팔트의 표면에 도포하였으며,The above was applied to the surface of the colored asphalt,

도포 2분 경과 후에 상기 용제가가 완전히 휘발되므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of application, the solvent value was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

실시예7)Example 7

MC(용제) 100KGMC (solvent) 100KG

PS(폴리스틸렌) 20KGPS (polystyrene) 20KG

멜라민수지분말 10KGMelamine Resin Powder 10KG

CMC(증점제) 1KGCMC (Thickener) 1KG

MP8(계면활성제) 0.5KGMP8 (Surfactant) 0.5KG

산화철(안료) 10KGIron Oxide (Pigment) 10KG

을 상온에서 균일하게 혼합하여 액상의 코팅제를 제조하고,Uniformly mixed at room temperature to prepare a liquid coating agent,

상기를 칼라아스팔트의 표면에 도포하였으며,The above was applied to the surface of the colored asphalt,

도포 2분 경과 후에 상기 용제가가 완전히 휘발되므로써 표면이 완전히 건조 및 경화된 칼라아스팔트를 제공하였다.After 2 minutes of application, the solvent value was completely volatilized to give a colored asphalt whose surface was completely dried and cured.

상기 1~7에 따르는 모든 실시예에 있어서,In all embodiments according to 1-7 above,

상기 용제는 141b로 대체할 수 있으며,The solvent can be replaced with 141b,

상술된 실시예에 경우에 따라 물(H2O) 또는 알콜 등의 여타 용제를 적정량 추가로 혼합하여 사용하므로써 유해성 유기용제의 사용량을 감소시키므로써 부분적인 친환경성의 개선을 도모할 수 있음은 물론이거니와, In the above-described embodiment, by using an additional amount of other solvents such as water (H 2 O) or alcohol in an appropriate amount, it is possible to improve partial eco-friendliness by reducing the amount of the harmful organic solvent.

이 또한 본 발명에 따르는 또 하나의 바람직한 실시예가 되며, 상기 물을 추가 투입한 경우에는 정적량의 방부제를 투여하여 제조하므로써 보관을 용이하게 하다.This is also another preferred embodiment according to the present invention, when the additional water is added to facilitate the storage by administering a static amount of preservatives.

또 상기 각 실시예에 제오라이트를 포함하는 탈취제를 미량 첨가하여 제조하므로써 용제에서 발산되는 냄새를 감소시킬 수 있다.In addition, it is possible to reduce the odor emitted from the solvent by preparing a small amount of the deodorant containing zeolite in each of the above examples.

또 필요에 따라 상기 모든 실시예에 메틸셀룰로스, 탄산칼슘, 카본블랙 등의 물리적혼화재를 추가 투입하여 제조하므로써 접착제의 겉보기점도를 향상시키므로써 초기 접착성을 강화시킬 수 있다.Further, if necessary, by adding a physical admixture such as methyl cellulose, calcium carbonate, carbon black, etc. to all of the above examples, the initial viscosity can be enhanced by improving the apparent viscosity of the adhesive.

상기 각 투입원료간의 혼합비는 표면코팅제의 원활한 접착성과 내구성 및 시공성 등을 비롯한 칼라코팅제에 따른 다양한 요구물성에 적합한 성능을 발현시킬 수 있는 범위 내에서 각 원료간의 혼합비율을 가감하여 조정할 수 있으며, The mixing ratio between the input raw materials can be adjusted by adding or subtracting the mixing ratio between the raw materials within the range that can express the performance suitable for various requirements according to the color coating agent, including the smooth adhesion of the surface coating agent and durability and construction properties,

이 또한 본 발명의 청구범위에 포함되는 것으로 간주되어야할 것이다. It should also be considered to be included in the claims of the present invention.

또한 상기에 안료를 첨가하지 않은 투명코팅제로 제조하므로써 사용도 가능함은 물론이다.In addition, by using a transparent coating agent is not added to the pigment can be used as a matter of course.

상술된 바와 같은 방법으로 제조된 칼라아스팔트용 표면코팅제는Surface coating agent for the color asphalt prepared by the method as described above

불연성이며, 환경유해성이 비교적 낮은 용제를 사용하므로써 유성용제의 환경 및 인체에 대한 유해성을 감소시키고,By using non-flammable and relatively low environmentally harmful solvents, oil solvents reduce the environmental and human hazards,

수성용제를 사용하여 제조된 표면코팅제에서 나타나는 저내수성으로 인한 낮은 강도와 낮은 마찰강도 및 접착력 등에 따르는 오염 및 균열, 코팅층의 박리 등의 단점들을 해소 또는 강화시키므로써 칼라아스팔트의 사용기한을 증대시키며,The service life of the color asphalt is increased by eliminating or strengthening the disadvantages such as contamination, cracks and peeling of the coating layer due to low strength, low frictional strength and adhesion due to the low water resistance of the surface coating agent manufactured using the aqueous solvent.

특히, 초고속휘발성 용제를 사용하므로써 건조 및 경화속도를 획기적으로 상승시키므로써 칼라아스팔트의 시공에 따르는 단점인 통행제한, 오염의 단점을 해소하였으며, In particular, by using a very high-speed volatile solvent to drastically increase the drying and curing speed to solve the disadvantages of traffic restrictions, pollution, which is a disadvantage of the construction of color asphalt,

상기에 따른 유색의 코팅제를 칼라아스팔트의 표면 코팅제의 마모 및 균열에 따른 보수시에 보수제로 활용하므로써 칼라아스팔트의 시공비를 낮춤과 동시에 보수비용을 획기적으로 절감할 수 있는 효과가 있다.By using the colored coating according to the above as a repair agent when repairing due to wear and cracking of the surface coating agent of the color asphalt, it is possible to reduce the construction cost of the color asphalt and at the same time significantly reduce the repair cost.

Claims (6)

칼라아스팔트용 표면코팅제에 있어서,In the surface coating agent for color asphalt, 단독 또는 혼용한 각종 합성수지 폴리머(polymer) 또는 엘라스토머(elastomer)를 Various synthetic resin polymers or elastomers alone or in combination 유기용제인 MC(Methylene Chloride) 또는 141b를 단독 또는 혼용하고, Organic solvent MC (Methylene Chloride) or 141b alone or in combination, 상기를 균일하게 혼합하므로써 제조한 것을 특징으로 하는 칼라아스팔트용 표면코팅제.A surface coating agent for color asphalt, which is prepared by uniformly mixing the above. 상기 1항의 용제에 고비점의 용제를 1종 이상 추가투입하여 제조한 것을 특징으로 하는 칼라아스팔트용표면코팅제. A surface coating agent for color asphalt, which is prepared by adding at least one solvent having a high boiling point to the solvent of claim 1. 상기1항 또는 2항의 표면코팅제의 물리적 및 화학적 특성을 강화하기 위한 목적으로 For the purpose of enhancing the physical and chemical properties of the surface coating agent of claim 1 or 2. 각종 물리적혼화재 및 화학적혼화제를 1종 이상 추가로 투입하므로써 제조한 것을 특징으로 하는 칼라아스팔트용 표면코팅제.A surface coating agent for color asphalt, which is prepared by adding one or more kinds of various physical admixtures and chemical admixtures. 상기 3항의 물리적혼화재 및 화학적혼화제는 The physical admixture and chemical admixture of claim 3 제오라이트, 메틸셀룰로스, 탄산칼슘, 카본블랙, 에틸렌글리콜, PE글리콜, 제오라이트 중 1종인 것을 특징으로 하여 제조된 칼라아스팔트용 표면코팅제.Zeolite, methyl cellulose, calcium carbonate, carbon black, ethylene glycol, PE glycol, zeolite surface coating agent prepared by characterized in that one of the zeolite. 상기 1또는 2 및 3항의 표면코팅제에 In the surface coating agent of 1 or 2 and 3 칼라아스팔트의 유지 및 보수를 위하여 유색의 유기 또는 무기 안료를 추가로 투입하여 제조한 것을 특징으로 하는 칼라아스팔트용 표면코팅제.Surface coating agent for color asphalt, characterized in that the addition of colored organic or inorganic pigments for the maintenance and repair of the color asphalt. 상기 1항, 2항, 3항, 4항, 5항의 표면코팅제 중 선택된 1종의 코표면코팅제를 1, 2, 3, 4, 5 of the surface coating agent selected from the surface coating agent 칼라아스팔트의 표면에 코팅하여 시공한 것을 특징으로 하는 칼라아스팔트. Color asphalt, characterized in that the coating is coated on the surface of the color asphalt.
KR1020050050714A 2005-06-14 2005-06-14 Ommited KR20060130959A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11709156B2 (en) 2017-09-18 2023-07-25 Waters Technologies Corporation Use of vapor deposition coated flow paths for improved analytical analysis
US11709155B2 (en) 2017-09-18 2023-07-25 Waters Technologies Corporation Use of vapor deposition coated flow paths for improved chromatography of metal interacting analytes
US11918936B2 (en) 2020-01-17 2024-03-05 Waters Technologies Corporation Performance and dynamic range for oligonucleotide bioanalysis through reduction of non specific binding

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11709156B2 (en) 2017-09-18 2023-07-25 Waters Technologies Corporation Use of vapor deposition coated flow paths for improved analytical analysis
US11709155B2 (en) 2017-09-18 2023-07-25 Waters Technologies Corporation Use of vapor deposition coated flow paths for improved chromatography of metal interacting analytes
US11918936B2 (en) 2020-01-17 2024-03-05 Waters Technologies Corporation Performance and dynamic range for oligonucleotide bioanalysis through reduction of non specific binding

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