KR20000042048A - Coolant for electric furnace - Google Patents

Coolant for electric furnace Download PDF

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Publication number
KR20000042048A
KR20000042048A KR1019980058116A KR19980058116A KR20000042048A KR 20000042048 A KR20000042048 A KR 20000042048A KR 1019980058116 A KR1019980058116 A KR 1019980058116A KR 19980058116 A KR19980058116 A KR 19980058116A KR 20000042048 A KR20000042048 A KR 20000042048A
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KR
South Korea
Prior art keywords
coolant
steel plate
dust
thin steel
sludge
Prior art date
Application number
KR1019980058116A
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Korean (ko)
Inventor
최춘행
김준식
Original Assignee
이구택
포항종합제철 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 이구택, 포항종합제철 주식회사 filed Critical 이구택
Priority to KR1019980058116A priority Critical patent/KR20000042048A/en
Publication of KR20000042048A publication Critical patent/KR20000042048A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • C21C5/4646Cooling arrangements
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C2200/00Recycling of waste material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • F27D2009/0002Cooling of furnaces

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

PURPOSE: A coolant is provided to wire a cooling material with a thin steel plate without a bonding material. CONSTITUTION: A coolant for an electric furnace uses dust and sludge as a cooling material. Herein, the dust is used in a collected state while the sludge is dried and crushed into a certain particle form. The dust and crushed sludge are mixed each or together and are covered on a thin steel plate. The thin steel plate is 0.3 to 1.2mm and is generated as a defective product in a thin steel plate production process so that it contributes to recycling. In addition, a waste thin steel plate is available even if it is oxidized. This is because the thin steel plate reacts like iron ore used as the existing coolant.

Description

전로 냉각재Converter coolant

본 발명은 전로(轉爐)정련과정에서 용강의 온도제어를 투입되는 냉각재에 관한 것으로, 상세하게는 냉각원료를 점결재로 경화한 기존의 단광형상의 냉각재와는 달리, 점결재없이 냉각원료를 박강판으로 와이어링한 냉각재에 관한 것이다.The present invention relates to a coolant to which the temperature control of molten steel is input during the converter refining process, and in detail, unlike the conventional briquette coolant cured from the raw material to the caking additive, the cooling material without the caking additive It is related with the coolant wired by the steel plate.

전로정련은 용선(鎔銑) 및 고철중의 불순물인 P, S, C, Si 등을 산화정련시키기 위하여 순산소(純酸素)를 전로 상부에서 랜스(Lance)를 통해 취입하고 이와 동시에 각종 부원료, 예를 들어 생석회, 돌로마이트(Dolomite), 형석, 철광석, 소결광석, 더스트단광 등을 첨가하여 용선을 정련한다. 이때 투입되는 철광석, 소결광석, 더스트단광 등은 금속 철(Metal Fe), 자철광(磁鐵鑛: Fe203), 적철광(赤鐵鑛: Fe304)등으로 구성되어 있으며, 전로내에 35Kg/Ton-Steel 정도까지 첨가되어 용선중에 함유되어 있는 탄소에 의해 환원되어 용강(鎔鋼)이 되거나 용강중에 산소로 존재하게 된다. 이러한 전로 정련중 순산소의 고압취련과 철광석, 소결광석, 더스트 단광 등의 투입으로 전로 정련과정에서 더스트와 슬러지가 약 12kg/Ton-Steel 발생이 되고 있다.In the converter refining, pure oxygen is blown through the lance at the top of the converter to oxidize P, S, C, and Si, which are impurities in molten iron and scrap metal, and at the same time, various auxiliary materials, For example, quicklime, dolomite, fluorite, iron ore, sintered ore and dust briquettes are added to refine the molten iron. Iron ore, sintered ore, dust briquette, etc. are composed of metal iron (Metal Fe), magnetite (磁鐵鑛: Fe203), hematite (赤 鐵鑛: Fe304), etc. in the converter up to about 35Kg / Ton-Steel It is added and reduced by the carbon contained in the molten iron to become molten steel or exist as oxygen in the molten steel. During the converter refining, dust and sludge are generated about 12kg / Ton-Steel during the converter refining process by the high pressure refining of pure oxygen and the input of iron ore, sinter ore and dust briquettes.

이러한 발생 부산물들은 초창기에는 폐기처리 되었으나 점결제(Bonding Material)를 이용하여 일정형태로 고형화 한후 전로에 냉각재로 재활용하는 기술이 개발되어 사용중에 있다. 냉각재는 전로 용선의 온도를 일정온도로 낮추는 것이 필요한 경우에 용선에 투입되는 것으로, 부산물을 점결재로 만든 냉각재로는 콜드 본디드 펠리트(Cold-bonded pellet), 더스트 단광등 많은 종류가 사용중이다.These by-products were discarded in the early stages, but the technology of solidifying them into a certain form by using a binder material and recycling them as a coolant in the converter is being used. The coolant is put into the molten iron when it is necessary to lower the temperature of the converter molten iron to a certain temperature. Many kinds of coolant made of by-products as a caking additive are used, such as cold-bonded pellets and dust briquettes. .

그러나, 지금까지의 개발되어 사용중인 냉각재는 점결제로 부산물을 경화시켜 일정형상으로 만들기 때문에 대기중에서 오랜시간 건조 및 경화를 시켜야 하는 제약이 있다. 특히, 이러한 냉각재는 점결제 첨가로 인해 Fe 함량이 낮아져 냉각능이 떨어지고 취급과정이나 투입과정에서 파쇄에 의한 분진으로의 손실이 문제가 되고 있다.However, the coolant developed and in use until now is hardened by curing the by-products to a certain shape by the binder, there is a restriction that the drying and curing in the air for a long time. In particular, such a coolant has a low Fe content due to the addition of the binder, the cooling capacity is reduced and the loss to dust by the crushing during handling or input process is a problem.

따라서, 본 발명은 지금까지 폐기물 재활용방법의 문제점을 해결하여 안정된 전로 냉각재를 공급하는데 그 목적이 있다.Therefore, an object of the present invention is to solve the problems of the waste recycling method so far to supply a stable converter coolant.

도1은 본 발명의 전로냉각재의 제조공정의 일례도1 is an example of the manufacturing process of the converter coolant of the present invention

도2는 본 발명의 냉각재의 일례도로서,2 is an example of the coolant of the present invention;

도 2(a)는 와이어링단계의 전로냉각재Figure 2 (a) is the converter coolant of the wiring step

도 2(b)는 양단을 밀봉한 전로냉각재의 평면도와 정면도2 (b) is a plan view and a front view of the converter coolant sealed at both ends;

상기 목적을 달성하기 위한 본 발명의 전로냉각재는, 제강더스트와 건조하여 파쇄한 제강슬러지의 1종 또는 2종의 혼합분말이 박강판으로 된 원통의 내부에 충진되고 원통의 양단이 봉합되는 것을 포함하여 구성된다.The converter coolant of the present invention for achieving the above object is that one or two mixed powders of steelmaking dust and steelmaking sludge dried and crushed are filled in a cylinder made of a steel sheet, and both ends of the cylinder are sealed. It is configured by.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명의 냉각재 원료는, 기존의 냉각재에서 마찬가지로 제강공정에서 발생하는 더스트와 슬러지를 이용한다. 아래 표 1에는 제강공정에서 사용하는 소결광석과 발생부산물인 더스트, 슬러지의 대표적인 화학조성을 나타낸 것이다.The coolant raw material of this invention uses the dust and sludge which generate | occur | produce in the steelmaking process similarly to the existing coolant. Table 1 below shows representative chemical compositions of sintered ores and by-products dust and sludge used in the steelmaking process.

구분division 화학성분(중량%)Chemical composition (% by weight) T.FeT.Fe FeOFeO CaOCaO SiO2 SiO 2 Al2O3 Al 2 O 3 PP SS ZnZn 1차 집진더스트Primary dust collection 61.061.0 33.333.3 20.020.0 3.203.20 0.500.50 0.090.09 0.020.02 0.160.16 2차 집진 더스트Secondary Dust Collection 58.958.9 39.539.5 11.611.6 1.901.90 0.300.30 0.080.08 0.110.11 0.500.50 집진 슬러지Dust collection sludge 64.564.5 18.118.1 7.17.1 1.901.90 0.400.40 0.130.13 0.020.02 0.110.11 소결광석Sintered Ore 65.065.0 -- 9.89.8 5.55.5 1.71.7 0.040.04 0.010.01 00

본 발명에서는 표 1과 같은 더스트와 슬러지를 냉각재의 원료로 이용하는데, 이를 위해서는 더스트는 집진된 것을 그대로 이용하나 슬러지는 건조하고 일정입도로 파쇄한다. 파쇄는 3mm이하 보다 바람직하게는 1mm이하로 파쇄한다.In the present invention, dust and sludge as shown in Table 1 is used as a raw material of the coolant. For this purpose, dust is used as it is, but the sludge is dried and crushed to a certain granularity. Crushing is crushed to 3mm or less, more preferably 1mm or less.

일정입도로 파쇄된 슬러지와 더스트는 도 1에 나타난 바와 같이, 각각 또는 서로 혼합한 다음, 이를 박강판으로 싸서 밀봉한다. 이때 박강판은 0.3-1.2mm로 제철소의 박강판제조공정에서 불량품으로 발생한 것을 이용하면 재활용측면에서 유리하다. 또한, 이러한 폐기 박강판은 장기간 옥외에 방치하여 산화되어도 그 이용이 가능한데, 이는 기존에 냉각재로 이용하던 철광석과 같은 작용을 할 수 있기 때문이다.Sludge and dust crushed to a certain particle size, as shown in FIG. 1, are mixed with each other or with each other, and then wrapped in a steel sheet to seal. At this time, the thin steel sheet is 0.3-1.2mm, which is advantageous in terms of recycling if it is used as a defective product in the steel sheet manufacturing process of the steel mill. In addition, such a waste steel sheet can be used even if it is oxidized after being left outdoors for a long time, because it can act the same as iron ore conventionally used as a coolant.

본 발명의 냉각재를 와이어링 한 경우를 예를 들어 도 1과 도 2를 통해 설명한다. 먼저 도 1과 같이 제강더스트와 건조 파쇄된 제강슬러지를 박강판으로 와이어 형태싸서 박강판의 길이방향의 양단(장변)을 절곡하여 결합하고, 이어 절단예상부위를 상하압착하고, 상하압착된 부분을 절단하고, 이 절단된 단변을 절곡하여 결합함으로써, 충진된 냉각원료의 유출을 막는다.The case of wiring the coolant of the present invention will be described with reference to FIGS. 1 and 2, for example. First, as shown in FIG. 1, the steelmaking dust and the dry crushed steelmaking sludge are wrapped in a thin steel sheet to be bent to combine both ends (long sides) in the longitudinal direction of the steel sheet, and then the cutting expected portion is compressed up and down, and the up and down compression portion is By cutting and bending and cutting the cut short sides, the outflow of the filled cooling raw material is prevented.

이와 같이 제조된 냉각재는 장변의 길이가 70-120mm, 단변의 길이가 40-70mm가 되도록 절단할 수 있다. 이는 냉각재를 전로에 자동투입할 때 투입성과 함께 상기 와이어링 공정의 가공성을 고려하여 설정한 것이다.The coolant prepared in this way can be cut so that the length of the long side is 70-120mm, the length of the short side is 40-70mm. This is set in consideration of the processability of the wiring process together with the inputability when the coolant is automatically injected into the converter.

상술한 바와 같이, 본 발명은 냉각재원료에 점결재없이 박강판으로 와이어링하여 밀봉함으로써, 가공에 소요되는 시간이 대폭 줄어들고 냉각재 자체의 Fe성분이 높아져 냉각효과가 크며, 투입과정에서 파쇄에 의한 분진발생의 염려가 없는 냉각재를 제공하는 효과가 있다.As described above, in the present invention, the sealing material is wired and sealed with a thin steel plate without a caking additive, so that the time required for processing is greatly reduced and the Fe component of the coolant itself is high, so that the cooling effect is large, and dust by crushing during the feeding process There is an effect of providing a coolant that is not concerned about generation.

Claims (2)

제강더스트와 건조하여 파쇄한 제강슬러지의 1종 또는 2종의 혼합분말이 박강판으로 된 원통의 내부에 충진되고 원통의 양단이 봉합되어 이루어지는 전로냉각재.A converter coolant in which one or two mixed powders of steelmaking dust and steelmaking sludge dried and crushed are filled in a cylinder made of a steel sheet and both ends of the cylinder are sealed. 제 1항에 있어서, 상기 원통의 장경은 70-120mm이고 단경은 40-70mm임을 특징으로 하는 전로냉각재.The converter coolant according to claim 1, wherein the cylinder has a long diameter of 70-120 mm and a short diameter of 40-70 mm.
KR1019980058116A 1998-12-24 1998-12-24 Coolant for electric furnace KR20000042048A (en)

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KR1019980058116A KR20000042048A (en) 1998-12-24 1998-12-24 Coolant for electric furnace

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101698177B1 (en) 2015-11-09 2017-01-19 리모트솔루션주식회사 Remocon for observing of rf enviroment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101698177B1 (en) 2015-11-09 2017-01-19 리모트솔루션주식회사 Remocon for observing of rf enviroment

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