KR20000015039A - Organic acid mixture for laver cultivation - Google Patents

Organic acid mixture for laver cultivation Download PDF

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KR20000015039A
KR20000015039A KR1019980034726A KR19980034726A KR20000015039A KR 20000015039 A KR20000015039 A KR 20000015039A KR 1019980034726 A KR1019980034726 A KR 1019980034726A KR 19980034726 A KR19980034726 A KR 19980034726A KR 20000015039 A KR20000015039 A KR 20000015039A
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acid
organic acid
organic
citric acid
growth
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KR1019980034726A
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KR100290681B1 (en
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이광일
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G33/00—Cultivation of seaweed or algae
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Cultivation Of Seaweed (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: An organic acid mixture is provided, which is not harmful both to a fishing place and to marine ecosystem, but improves the marine production by the increase of an amino acid which promotes laver growth without causing entrophication. CONSTITUTION: The organic mixture comprises:the citric acid 30-55 %; the nitrogen 0.1-2.5 %; the potassium 0.1-3.0 %; the amino acid 0.2-7.5%; and the rest water. The citric acid is one of the hydroxy tricarboxylic acid, being isolated among the citron, the stirrups, and the tangerine, and has the property of an organic acid. The citric acid has the weak acidity, removes impurities such as sea weeds, and various germs on the surface of laver, and prevents marine pollution by being dissolved into seawater promptly.

Description

김양식용 유기산 혼합물Seaweed Organic Acid Mixture

본 발명은 바다에서 김(해태) 양식시 사용되는 유기산 혼합물에 관한 것으로, 특히 PH를 하강시켜 김엽체 표면의 잡조, 잡균 등의 이물질 및 매생이 등을 구제하고 영양분 공급으로 김성장을 촉진시켜 양식어업인의 소득증대는 물론, 유기산 혼합물이 해수에서 오염되지 않는데 적합한 김 양식용 유기산 혼합물에 관한 것이다.The present invention relates to an organic acid mixture used in seaweed (Haitai) farming in the sea, and in particular, by lowering the pH to remove foreign substances such as algae and various bacteria on the surface of the lamellar body, and to promote the growth of seaweed by supplying nutrients, Increasing income, of course, relates to organic farming mixtures for seaweed farming, which are suitable for the organic acid mixtures not to be contaminated in seawater.

바다에서 김을 양식함에 있어 김은 뿌리가 아닌 엽체로 영양염류를 흡수하여 김엽체가 성장하기 시작하면 김엽체 표면에 각종 세균 등의 이물질이 부착하여 김의 성장을 저하시키고 영양염류의 흡수를 차단시켜 부실한 엽체로 만들어 병해에 약해지는 등의 문제가 있다.In cultivating seaweed in the sea, the seaweed absorbs nutrients with the leaf rather than the roots, and when the seaweed starts to grow, foreign substances such as various bacteria adhere to the surface of the seaweed to reduce the growth of seaweed and block the absorption of nutrients. There are problems such as poor leaf formation and weakening of the disease.

김양식 어장에서 사용되는 김발에는 바다에서 자생하는 파래, 매생이, 뻘곱등이 부착하여 김의 성장에 막대한 지장을 주고 고품질로 인정을 받지 못하여 그간 이러한 물질을 제거하기 위하여 어민들은 극독물질의 일종인 각종 무기산(HC1, HNO3, H2SO4등)을 혼합하여 pH0.7% 미만으로 희석한 다음 양식어장에서 사용하는 배에 실어 바다에 설치된 김망을 상기 무기산이 담겨진 용기에 약 20초 정도 침적시킨후 김망을 바다에 원래의 상태로 넣어 처리하여 왔다.The gimbal used in seaweed farming is attached to seaweed, seaweed, and ginseng, which grows wild in the sea, which greatly affects the growth of seaweed and is not recognized as high quality. HC1, HNO 3 , H 2 SO 4, etc.) and dilute to less than 0.7% of pH, and then put the seaweeds installed in the sea for 20 seconds in the vessel containing the inorganic acid after placing them on the vessel used in the farm. Has been treated in its original state in the sea.

이렇게 함에 따라 김엽체 표면에 부착된 각종 세균 및 이물질, 파래, 잡초, 매생이, 뻘꼽등이 강산성의 화학물질에 의거 제거되었다.As a result, various bacteria and foreign substances attached to the surface of the lamellar body, green grass, weeds, falcons, and muds were removed based on strong acidic chemicals.

그러나 상기와 같은 무기산의 사용은 이물질이 제거된 후에는 해수와의 접촉에서 빨리 분해되어야 하나, 그 분해력이 약하고 중금속등이 남아 결국 해저에 침적하거나 부유된 상태로 잔류함으로써 각종 어폐류(바지락, 피조개, 새고막등)의 폐사, 어군의 미형성등 생태계의 파괴로 어장의 황폐화를 초래하고 있으며, 전통적인 우리 국민의 기호 식품인 김이 근래에와서 김의 소비 기피현상마저 나타나고 있는등 김의 수출 부진마저 발생하여 어업인의 소득저하로 이어지고 있는 실정에 있다.However, the use of such inorganic acid should be decomposed quickly in contact with seawater after the removal of foreign substances, but its degradability is weak and heavy metals remain and eventually remain in the seafloor or floated. Kim's exports have been sluggish due to the destruction of ecosystems, such as the loss of fish, birds, etc. There is even a situation that leads to a decrease in income of fishers.

이를 시정하기 위해 정부에서는 무기산 사용 단속을 강화하고 유기산 사용을 권장하고 있으나, 그간 오래 전부터 무기산 사용 등으로 이미 바다 연근해는 황폐화되어 고기가 잡히지 않기 때문에 김양식을 지주식에서 현재는 거의 먼 바다로 나가 완전 해수에 묻혀지는 부류식으로 양식 방법을 달리하고 있다.To correct this, the government has tightened the use of inorganic acids and encourages the use of organic acids.However, since the sea has been devastated since the use of inorganic acids has been desolated for a long time, the seaweeds are now almost distant from the holding ceremony. They are buried in seawater and are farmed differently.

본 출원인은 상기한 문제점을 해결하기 위한 일환으로써 특허공보 제93-1375호로 특허를 받은 바 있다.Applicant has been patented in Patent Publication No. 93-1375 as part of solving the above problems.

상기한 유기산 혼합물은 구연산 5-30%, 링고산 또는 주석산 5-30%, 아미노산 0.5-20%, 질소, 인산, 칼리가 배합된 복합비료 1.0-8.0%, 활성수 30-88%로 구성되고 있으나, 링고산 또는 주석산의 많은 사용으로 경제적이지 못하여 본 출원인은 구연산 10-30%의 영양소를 첨가하여서된 특허 제129827호(이하 "선기술"이라함)를 받은 바 있다.The above organic acid mixture is composed of 5-30% citric acid, 5-30% lingoic or tartaric acid, 0.5-20% amino acid, 1.0-8.0% composite fertilizer with nitrogen, phosphoric acid and kali, 30-88% active water However, because of the large use of ringo acid or tartaric acid, it is not economical, so the applicant has received patent No. 129827 (hereinafter referred to as "prior art") by adding 10-30% citric acid.

상기 선기술은 구연산 10-30%, 질소 0.3-2.5%, 인 0.1-2.0%, 규소 0.3-2.3%, 아미노산 0.2% 이하이고, 나머지는 활성수로 조성되어 있다.The prior art is 10-30% citric acid, 0.3-2.5% nitrogen, 0.1-2.0% phosphorus, 0.3-2.3% silicon, 0.2% amino acid or less, the rest is composed of active water.

인은 바다의 부영양화를 일으키는 것으로, 상기 선기술에서는 그 함량이 적으므로 큰 영향이 없을 것으로 판단되나, 인은 물에서 분해가 잘 되지 않으므로 적은 량이라 할지라도 그 범위가 넓거나 사용기간이 길어지면 영향이 전혀 없다 할 것이며, 또한 선기술의 유기산 혼합물은 사용할 때 침적시간이 대략 5분 이상임으로 추운 겨울바다에서 작업하기에 비능률적이며, 또한 김엽체 표면의 잡조, 잡균 등의 이물질제거가 충분하지 못하는등 생산성이 저하되고 있다.Phosphorus is the cause of eutrophication of the sea, and it is judged that there is no significant effect because of its low content in the above-mentioned technology. However, since phosphorus does not decompose well in water, even if the amount is long, the range is long In addition, the organic acid mixture of the prior art is inefficient to work in cold winter seas because the deposition time is about 5 minutes or more when used, and also it is not sufficient to remove foreign substances such as miscellaneous microorganisms on the surface of the lamellar body. Back productivity is falling.

본 발명은 상기한 종래의 문제점을 해결하기 위한 것으로, 구연산의 함량을 증대시켜 산도를 강화시키면서도 생태계 파괴에 따른 어장의 황폐화를 주지 않음과 함께 인을 전혀 사용하지 않아 부영양화를 방지하고 김성장을 촉진시키는 아미노산 증대로 생산성을 향상시킬 수 있는 유기산 혼합물을 제공하고자 하는데 그 목적이 있다.The present invention is to solve the above-mentioned problems, by increasing the content of citric acid to strengthen the acidity while not depleting the fishery caused by the destruction of the ecosystem and do not use any phosphorus to prevent eutrophication and to promote the growth of gold. An object of the present invention is to provide an organic acid mixture capable of increasing productivity by increasing amino acids.

상기한 목적을 달성하기 위한 본 발명은 100중량%로서, 구연산 30-55%, 질소 0.1-2.5%, 칼리 0.1-3.0%, 아미노산 0.2-7.5% 이고, 나머지는 물로 이루어진 유기산 혼합물로 조성된다.The present invention for achieving the above object is 100% by weight, citric acid 30-55%, nitrogen 0.1-2.5%, Kali 0.1-3.0%, amino acids 0.2-7.5%, the remainder is composed of an organic acid mixture consisting of water.

구연산(citric acid)은 히드록시트리카르복실산의 하나이며, 시트론, 등자, 밀감 등의 과실중에 유리되어 존재하며 여기에서 짜내어 제조되거나, 당류를 미생물로 발효시켜 제조되는 것으로 유기산(카르복실산)의 성질을 가진다.Citric acid (citric acid) is one of the hydroxytricarboxylic acid, and is present in the fruit of citron, stirrup, mandarin, etc. and is produced by squeezing or fermenting sugars into microorganisms. ) Has the property of.

이와 같은 구연산은 약산성을 띠는 것으로 김엽체 표면의 잡조, 잡균 등의 이물질을 제거시킴과 함께 조해성(潮解性)이 강하여 해수와의 접촉에서 빨리 분해됨으로써 해저에 침적되거나 부유된 상태로 존재하지 않아 바다의 오염을 방지한다.Such citric acid is weakly acidic and removes foreign substances such as miscellaneous microorganisms and microorganisms on the surface of the lamellar body, and has a strong deliquescent property. Prevent the pollution of the sea.

이와 같은 구연산을 사용함에 있어 그 사용량이 30% 이하 일 경우도 가능하다.In using such citric acid, it is possible to use less than 30%.

적으면 김엽체 표면의 잡조, 잡균 등과 같은 이물질의 달라붙음 방지가 충분하지 못하고 55% 이상일 경우는 사용량 증대에 따른 제조원가의 상승요인이 된다.If it is small, it is not enough to prevent foreign matters such as miscellaneous microorganisms on the surface of gimme leaf, and if it is 55% or more, it will increase the manufacturing cost due to the increase of usage.

따라서, 사용범위를 30-55%로 한 것이다.Therefore, the usage range is 30-55%.

아미노산은 여러 가지 사용될 수 있으나, 아스파르트산(Aspartic acid), 글수탐산(Glutamic acid), 알라닌(Alanine), 아르기닌(Arginine), 시스테인(Cysteine), 발린(Valine), 메티오닌(Methionine), 페닐알라닌(Phenylalanine), 이솔루신(Isoleucine), 프롤린(Proline), 히스티딘(Histidine)중 1종 이상을 들 수 있다.Amino acids may be used in various ways, but aspartic acid, glutamic acid, alanine, arginine, cysteine, valine, methionine, phenylalanine ), Isoleucine (Isoleucine), proline (Proline), histidine (Histidine) at least one kind.

이와 같은 조성을 갖는 본 발명을 동일한 바다에서 파래등이 있는 양식발을 5책을 사용 본 발명의 유기산 화합물을 적용하였다.The organic acid compound of the present invention was applied to the present invention having such a composition using five cultured hairs with blue light in the same sea.

이때 시험발 종류는 부류식으로 5책중 본 발명 3책, 대조구 2책으로 하여 시험방법은 파래구제, 성장도, 색택, 맛과 특히 어민이 요구한 파래구제 및 작업시간을 비교시험 하였다.At this time, the types of test feet were classified into three types of the present invention, three of the present invention, and two of the control, and the test methods were compared with the green remedies, growth degree, color selection, taste, and especially the green remedies required by fishermen and the working time.

또한 아미노산을 충분히 함유함으로서 성장 효과가 대단히 빨랐다.In addition, by containing enough amino acids, the growth effect was very fast.

선기술은 침지 시간이 너무 오래걸린 단점이 있었으나, 본 발명은 작업시간의 단축으로도 탁월효과를 가져왔다.The prior art had a disadvantage that the immersion time was too long, but the present invention has an excellent effect even shortening the working time.

본 발명은 30초 - 1분간 침지하여 파래, 잡조, 매생이 및 이물질 제거에 어업인들의 작업시간 단축 요구에 부응하였음을 획실히 확인하였다.The present invention clearly verified that the immersion of 30 seconds-1 minute to meet the demands of the fisherman to reduce the working time in the removal of greenery, miscellaneous, perennial and debris.

침지시간에 따른 구제효과Remedy Effect by Soaking Time 비고Remarks 30초30 seconds 60초60 seconds 100중량%중 30%30% in 100% by weight 40%40% 55%55% 100중량%중 35%35% in 100% by weight 55%55% 60%60% 100중량%중 40%40% in 100% by weight 60%60% 75%75% 100중량% 45%100% by weight 45% 75%75% 80%80% 100중량% 50%100% by weight 50% 87%87% 93%93% 100중량% 55%100% by weight 55% 93%93% 98%98%

아미노산 함유량Amino acid content 침지시간은 상과동Immersion time is same as above 재취일자Retake date 성장과정Growth process 성장률과 성장기간Growth Rate and Growth Period 0.2-3.0%0.2-3.0% 1㎝-20㎝1cm-20cm 96.10.19.96.10.19. 96.11.03.96.11.03. 성장왕성Growth 3.0-5.0%3.0-5.0% 6㎝-30㎝6 cm-30 cm 96.11.03.96.11.03. 96.11.11.96.11.11. 성장왕성Growth 5.0-7.0%5.0-7.0% 6㎝ 남기고 25㎝채취Take 6cm and leave 25cm 96.11.11.96.11.11. 96.11.19.96.11.19. 성장왕성Growth 5.0-7.0%5.0-7.0% 5㎝ 남기고 25㎝채취Collect 25cm leaving 5cm 96.11.19.96.11.19. 96.11.26.96.11.26. 성장왕성Growth

현 어장에서 어업인이 김을 1회채취 후 약제 처리를 전후하여 2회 시료를 하고 있으며, 채취기간은 약 15-20일만에 25㎝정도 성장후 채취하고 있으나, 본 발명은 분망후 왕성한 성장률에 의해 채취기일을 앞당겼으며, 2번째 시료부터는 채취후 3일에 시료 정상의 대단한 효과에 의해 생산성 향상은 물론 작업을 매 채취후 1회로 만족한 효과를 거두었다.In the current fishery, the fisherman takes two samples before and after the drug treatment after collecting seaweed once, and the harvesting period is collected after growth of about 25cm in about 15-20 days, but the present invention is characterized by a strong growth rate after delivery. The collection date was advanced, and from the second sample on the third day after collection, the productivity was improved by the great effect of the normal sample, and the work was satisfied once after every collection.

약제실험 장소 및 효과Drug experiment place and effect 구분division 본 발 명Invention 대조구(무처리)Control (no treatment) 시험장소Test place 해남군 송지면 내장리김규환어장(만호해)Haenam-gun Songji Naejang-ri Kim Gyu-hwan fishery (Manho Sea) 좌동Left 시험기간Test period 93.10.19. - 96.11.26.93.10.19. -96.11.26. 좌동Left 시험발 종류Trial type 부류식(뒤집기발)Type (Flip) 좌동Left 희석비율Dilution Ratio 10:110: 1 약제시비횟수Drug fertilization frequency 4회4 times 성장상태Growth 엽체성장 왕성Leaf growth vigor 부진Sluggish 병해발생상태Disease outbreak 파래,규조,잡조제거,갯병피해없음No blue, diatom, miscellaneous removal, no bottle damage 파래,규조,잡조등이 물질부착Blue, diatom, miscellaneous materials adhere 가공후수확량Post-processing yield 60속60 speed 15속15 speed 김의색깔Color of gold 적갈색 및 흑갈색Maroon and dark brown 흑갈색Dark brown 김의윤기Euiyun Kim 상급(1등급)Advanced (Level 1) 하급low class 김의맛Taste of seaweed 양호Good 하급low class 기 타Other 무처리제에 비해 성장이 왕성하여 수확량에 차이가 컷으며, 파래규조류, 잡조 등 이물질이 거의 발견되지 않았으며 김의 품질이 좋았음.Compared to the non-treatment agent, the growth rate is strong, and the yield is reduced. Almost no foreign substances such as green diatoms and miscellaneous algae are found, and the quality of seaweed was good. 파래,잡조,이물질 등에 의해 2회 채취후 전혀 수확할 수 없는 상태임Harvesting is not possible at all after harvesting twice due to greening, miscellaneous goods, foreign matters, etc.

이와 같은 본 발명은 유기산 혼합물 김엽체에 부착된 파래, 잡조, 규조등 이물질을 완전구제하고 중성포자 부착을 촉진하며, 또한 건강한 김엽체 성장을 촉진 시킴과 동시에 여러 종류의 갯병을 방제 하였으며, pH 하강으로 인한 생산어업인의 작업시간 단축과 인을 사용하지 않아 부영양화를 예방하고 충분한 아미노산을 제공하여 주므로써 우수한 품질을 비롯한 생산량이 크게 증대된 김을 얻을 수 있었다.The present invention completely eliminates foreign substances such as greens, algae, and diatoms attached to the organic acid mixture laver, promotes the attachment of neutral spores, and promotes the growth of healthy laver, while controlling various types of mussels, and lowering the pH. This resulted in a shorter production time for the fishermen and prevented eutrophication by providing phosphorus without providing phosphorus and providing sufficient amino acids.

이상에서와 같이 본 발명은 구연산 및 아미노산 함량을 증대시키고, 인이 함유되지 않은 유기산 화합물로 조성시킴으로써 파래, 잡조, 규조 등의 이물질 제거가 용이하고, 김엽체 성장촉진으로 우수한 품질 및 생산성이 증대된 김을 얻을 수 있다.As described above, the present invention increases citric acid and amino acid content, and is composed of an organic acid compound that does not contain phosphorus, thereby making it easy to remove foreign substances such as greens, miscellaneous products, diatoms, etc. You can get steam.

Claims (2)

100중량%로서, 구연산 30-55%, 질소 0.1-2.5%, 칼리 0.1-3.0%, 아미노산 0.2-7.5% 이고, 나머지는 물로 이루어짐을 특징으로 하는 김양식용 유기산 혼합물.100% by weight, citric acid 30-55%, nitrogen 0.1-2.5%, Kali 0.1-3.0%, amino acids 0.2-7.5%, the rest of the organic farming organic acid mixture characterized in that consisting of water. 제 1 항에 있어서,The method of claim 1, 아미노산이 아스파르트산(Aspartic acid), 글루탐산(Glutamic acid), 알라닌(Alanine), 아르기닌(Arginine), 시스테인(Cysteine), 발린(Valine), 메티오닌(Methionine), 페닐알라닌(Phenylalanine), 이솔루신(Isoleucine), 포로린(Proline), 히스티딘(Histidine) 중 1종 이상인 김양식용 유기산 혼합물.Aspartic acid, Glutamic acid, Alanine, Arginine, Arginine, Cysteine, Valine, Methionine, Phenylalanine, Isoleucine ), A mixture of organic acid for seaweed farming, at least one of proline and histidine.
KR1019980034726A 1998-08-26 1998-08-26 Seaweed Organic Organic Mixture KR100290681B1 (en)

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