KR19990010915A - Water soluble coating composition - Google Patents
Water soluble coating composition Download PDFInfo
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- KR19990010915A KR19990010915A KR1019970033794A KR19970033794A KR19990010915A KR 19990010915 A KR19990010915 A KR 19990010915A KR 1019970033794 A KR1019970033794 A KR 1019970033794A KR 19970033794 A KR19970033794 A KR 19970033794A KR 19990010915 A KR19990010915 A KR 19990010915A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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Abstract
본 발명은 건축물 내, 외부용이나 산업용으로 사용되는 수용성 도료 조성물에 관한 것으로서, 특히 항균, 방취, 제습기능과 같은 기능성을 향상시키는 것을 목적으로 안출된 것이다.The present invention relates to a water-soluble coating composition for use in buildings, exterior and industrial use, and is particularly intended to improve functionality such as antibacterial, deodorant, dehumidification function.
본 발명은 구체적으로 통상적으로 사용되고 있는 수용성 아크릴계 수지를 바인더 수지로 하는 수용성 도료 조성물에 고온에서 소성하여 분쇄된 소성황토 5-30중량% 및 분쇄된 맥반석 0.5-5중량%를 첨가 혼합하여 얻어지는 것을 특징으로 하는 수용성 도료 조성물에 관한 것으로서, 이와 같은 도료 조성물은 황토나 맥반석의 원적외선 방사효과나 흡착작용에 의해 항균, 방취, 제습기능과 같은 기능성이 뛰어나고 인체에도 유익한 효능을 나타내는 등의 유용성을 지닌다.The present invention is specifically obtained by adding and mixing 5-30% by weight of calcined ocher and 0.5-5% by weight of pulverized aggelite to a water-soluble coating composition comprising a water-soluble acrylic resin that is commonly used as a binder resin at high temperature. The present invention relates to a water-soluble coating composition, which has excellent utility such as antimicrobial, deodorant, dehumidifying function, and beneficial effects to the human body by the far-infrared radiation effect or adsorption action of loess or elvan.
Description
본 발명은 특히 건축물의 내, 외부용이나 산업용으로 사용되는 수용성 도료 조성물에 관한 것으로서, 좀 더 상세히는, 원적외선 방사효과 등의 유용한 효과를 지닌 황토와 맥반석을 수용성페인트, 퍼티(putty), 본타일과 같은 수용성 도료에 일정량 함유시킨 수용성 도료 조성물에 관한 것이다.The present invention relates to a water-soluble coating composition for use in the interior, exterior or industrial use of buildings, and more particularly, water-soluble paints, putty, bone tiles, such as ocher and elvan have useful effects such as far-infrared radiation effect. It relates to a water-soluble coating composition contained in a certain amount in such a water-soluble coating.
황토는 지표의 약 10%를 차지하고 있는 붉은 색을 띄는 흙으로서 다량의 탄산칼슘(CaCO3)을 함유하고 있어 쉽게 부서지지 않는 점력을 지니고 있으며 물을 가하면 찰흙으로 변하는 성질이 있다. 황토는 탄산칼슘외에 실리카(SiO2), 알루미나(Al2O3), 철분, 마그네슘, 나트륨, 칼륨 등의 성분으로 구성되어 있으며, 이러한 성분들은 동, 식물의 성장에 필요하고 항균, 탈취기능과 같은 유익한 작용을 일으키는 원적외선을 다량 방사하는 것으로 알려져 있다.Ocher is a red soil that occupies about 10% of the earth's surface and contains a large amount of calcium carbonate (CaCO 3 ), which has a viscous power that does not break easily. In addition to calcium carbonate, ocher consists of components such as silica (SiO 2 ), alumina (Al 2 O 3 ), iron, magnesium, sodium and potassium. These components are necessary for the growth of copper and plants. It is known to emit a large amount of far infrared rays that cause the same beneficial action.
그리고, 맥반석은 화성암류 중 석영반암에 속하는 것으로 중생대 말부터 신생대 초에 걸쳐 분출되어 긴 세월동안 풍화작용 등으로 점토화한 장석의 반점과 석영의 결정이 고루 섞여 있는 맥반 모양의 원석으로, 무수규산, 산화알루미늄 등을 주성분으로 하고 산화제2철, 칼슘, 망간, 마그네슘 등의 성분들이 소량 함유되어 있으며, 특히 그 표면에 대략 25,000개/㎠ 정도의 다공질로 되어 있다. 이러한 맥반석은 황토와 같이 원적외선을 방사하는 작용이 있으며, 또한 다공성인 특성으로 인하여 대기오염이나 수질오염의 주원인인 공해물질의 흡착작용에 탁월한 효과가 있는 물질이다.Elvanite is a quartz-like gemstone in the igneous rocks that is spun from the late Mesozoic to early Cenozoic. The main component is aluminum oxide and the like, and contains a small amount of components such as ferric oxide, calcium, manganese, and magnesium, and is particularly porous on the surface of about 25,000 pieces / cm 2. Such elvan has the effect of emitting far-infrared rays like ocher, and because of its porosity, it is an excellent effect on the adsorption of pollutants, which is the main cause of air pollution and water pollution.
한편, 일반적으로 사용되는 수용성 도료의 경우, 건축물의 내, 외부를 도포하는 수성페인트나 구조물의 틈새를 채우기 위한 퍼티 또는 요철무늬를 형성시키는 본타일 도료 조성물에는 바인더를 주로 아크릴에멀젼이 사용되고 여기에 첨가제를 물에 분산혼합하여 사용되기 때문에, 이때 사용되는 화학물질의 휘발이나 먼지화로 인한 인체에의 유해성 문제가 있고, 또한 습기를 흡착하는 기능이 없기 때문에 습기가 많을 경우 호흡기 질환을 유발하는 원인으로 작용하기도 한다.On the other hand, in the case of commonly used water-soluble paints, the binder is mainly used as an acrylic emulsion, and the binder is mainly used in the water-based paint to apply the interior and exterior of the building or the putty or the uneven pattern to fill the gap of the structure. Because it is used by mixing and dispersing in water, there is a problem of harm to the human body due to volatilization or dust of chemicals used at this time, and because it does not have the function of absorbing moisture, it acts as a cause of respiratory disease when there is too much moisture. Sometimes.
위와 같은 문제점을 해결하기 위한 종래의 기술로 대한민국 특허공고 제94-3069호에서는 맥반석을 다량사용하는 방법이 제시되어 있으나, 이 경우는 항균, 탈취 또는 제습기능이 어느 정도 개선되는 효과가 있으나 만족스러운 수준이 아니고, 특히 도막에 크랙이 발생하는 등의 문제점을 지니고 있다.As a conventional technique for solving the above problems, Korean Patent Publication No. 94-3069 proposes a method of using a large amount of elvan, but in this case, the antibacterial, deodorizing or dehumidifying function is somewhat improved but satisfactory. It is not a level, and especially has a problem that a crack occurs in a coating film.
본 발명은 상기와 같은 문제점을 해결하기 위해 안출된 것으로서, 전술한 바와 같은 효능를 지닌 황토와 맥반석을 도료조성물에 첨가하여 원적외선 방사효과 및 흡착효과에 의해 항균, 탈취, 제습기능 등을 부여하고 인체에 유익한 작용을 유발하는 등의 기능적 효과를 지닌 수용성 도료조성물을 제공하는데 그 목적이 있는 것이다.The present invention has been made to solve the above problems, by adding ocher and elvan rock having the above-described efficacy to the coating composition to give antimicrobial, deodorant, dehumidifying function and the like by far infrared radiation effect and adsorption effect to the human body The purpose is to provide a water-soluble paint composition having a functional effect, such as causing a beneficial action.
본 발명은 구체적으로 통상의 수용성 아크릴계 수지를 바인더로 하는 도료 조성물에 고온에서 소성하여 폐기공 상태의 안정한 구조를 지닌 황토 5-30중량% 및 다공성 맥반석 분말 0.5-5중량%를 함유시켜 제조되는 것을 특징으로 한 수용성 도료 조성물에 관한 것이다.Specifically, the present invention is prepared by baking at a high temperature in a coating composition using a conventional water-soluble acrylic resin as a binder and containing 5-30% by weight of ocher having a stable structure in a closed state and 0.5-5% by weight of porous machelite powder. It is related with the water-soluble coating composition characterized by the above-mentioned.
이하에서 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail.
본 발명에서 사용되는 황토는 전술한 바와 같이 원적외선 방사효과에 의해 항균, 탈취 작용은 물론 인체에 대해 제독 또는 해독 등의 유익한 작용을 일으키는데, 본 발명에서는 특히 황토의 기능성을 더욱 향상시키기 위하여 개기공의 형태로 불안정한 구조를 지닌 일반 황토를 대략 1200℃이상의 고온에서 소성하여 폐기공 상태의 안정한 구조로 가공하여 사용하는데, 이와 같이 함으로써 압축강도가 향상되고 원적외선 방사효과가 더욱 증진될 수 있다. 이러한 소성황토는 대략 300메쉬 이상으로 분쇄하여 사용하며 그 사용량은 조성물 총량의 5-30중량% 범위에서 사용하는 것이 바람직하다. 이때 30중량% 초과하여 사용하면 분산성과 같은 도료 물성이 저하되고 5중량% 미만으로 사용시는 첨가효과가 미미한 문제가 있다.The ocher used in the present invention has a beneficial effect such as detoxification or detoxification to the human body as well as antibacterial, deodorizing effect by the far-infrared radiation effect as described above, in the present invention in particular to further improve the functionality of the ocher The general loess having an unstable structure in the form is fired at a high temperature of about 1200 ° C. or more and processed into a stable structure in a closed hole state, thereby improving compressive strength and further improving the far-infrared radiation effect. Such calcined ocher is pulverized to about 300 mesh or more, and the amount of use is preferably in the range of 5-30% by weight of the total amount of the composition. At this time, when used in excess of 30% by weight, paint properties such as dispersibility is lowered, and when used in less than 5% by weight there is a problem that the addition effect is insignificant.
그리고, 다공성의 맥반석은 역시 300메쉬 이상으로 분쇄하여 사용하는데, 맥반석의 경도가 높으므로 습식 분쇄법을 이용하여 분쇄한 후 건조시켜 사용하는 것이 좋으며, 그 바람직한 사용량은 0.5-5중량% 범위로서, 5중량% 초과 사용시는 도막에 크랙이 발생하는 등의 문제가 있으며 0.5중량% 미만으로 사용시는 그 첨가효과가 나타나지 않는다.In addition, porous ganban stone is also used to be pulverized to more than 300 mesh, because the hardness of the ganban stone is high, it is preferable to use it after pulverizing by using a dry grinding method, the preferred amount of use is in the range of 0.5-5% by weight, When using more than 5% by weight, there is a problem such as cracks in the coating film and when used less than 0.5% by weight does not appear the addition effect.
한편, 본 발명에서 수용성 도료는 일반 수성 페인트는 물론 퍼티나 본타일 도료를 모두 포함하는 것으로서, 이때 사용되는 도료용 첨가제는 통상적으로 도료에 사용되는 증점제, 분산제, 소포제, 레벨링제 등으로써 그 사용에 의해 본 발명이 제한되지는 않는다.On the other hand, in the present invention, the water-soluble paints, as well as general water paints, including both putty and bone tile paints, the paint additives used in this case is commonly used for the thickener, dispersant, antifoaming agent, leveling agent, etc. The present invention is not limited thereto.
이하에서 실시예 및 비교예를 들어, 본 발명을 좀 더 구체적으로 설명한다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.
(실시예 1)(Example 1)
물 40중량부, 325메쉬로 분쇄한 소성황토 25중량부, 325메쉬로 분쇄한 맥반석 5중량부를 혼합하고 3단로울러를 이용해 연화도를 Hegman No.7이상으로 연화한 것을 아크릴에멀젼 18중량부, 아크릴증점제 0.5중량부 및 소포제, 분산제 등의 통상적인 기타 첨가제 2.0중량부와 충분히 혼합한 후 암모니아수(28%) 0.1중량부를 가하여 pH를 8.5로 조정하여 수용성 아크릴계 페인트를 제조하였다.40 parts by weight of water, 25 parts by weight of calcined ocher crushed with 325 mesh, 5 parts by weight of gannet rock crushed with 325 mesh, and a softening degree of Hegman No. 7 or more by using a three-stage roller, 18 parts by weight of acrylic emulsion, A water-soluble acrylic paint was prepared by thoroughly mixing 0.5 parts by weight of an acrylic thickener and 2.0 parts by weight of other conventional additives such as an antifoaming agent and a dispersant, and then adjusting the pH to 8.5 by adding 0.1 part by weight of ammonia water (28%).
(실시예 2)(Example 2)
물 30중량부에 325메쉬로 분쇄한 소성황토 25중량부 및 325메쉬로 분쇄한 맥반석 5중량부를 차례로 첨가하여 2000rpm으로 30분간 교반기로 혼합한 후 아크릴에멀젼 7중량부 및 증점제, 소포제, 안정제와 같은 통상적인 기타 첨가제 2.0중량부를 투입하여 충분히 혼합함에 의해 수용성 아크릴계 본타일 도료를 제조하였다.To 30 parts by weight of water, 25 parts by weight of calcined ocher crushed with 325 mesh and 5 parts by weight of gannet rock crushed with 325 mesh were added sequentially and mixed with a stirrer at 2000 rpm for 30 minutes, and then 7 parts by weight of an acrylic emulsion, a thickener, an antifoaming agent, and a stabilizer were added. A water-soluble acrylic bone tile coating was prepared by sufficiently mixing 2.0 parts by weight of conventional additives.
(실시예 3)(Example 3)
물 25중량부에 325메쉬로 분쇄한 소성황토 25중량부 및 325메쉬로 분쇄한 맥반석 5중량부를 차례로 첨가하여 2000rpm으로 30분간 교반기로 혼합한 후 아크릴에멀젼 7중량부, 아라비아검(Arabia Gum) 0.2중량부 및 벤토나이트클레이 0.2중량부를 넣고 충분히 교반하여 증점을 시킨 후 계속하여 소포제, 안정제 등의 첨가제를 2.0중량부 첨가 혼합하여 퍼티를 제조하였다.25 parts by weight of water was added 25 parts by weight of calcined ocher crushed with 325 mesh and 5 parts by weight of gannet rock crushed with 325 mesh, and then mixed with a stirrer at 2000 rpm for 30 minutes, 7 parts by weight of acrylic emulsion, Arabian Gum 0.2 A weight part and 0.2 part by weight of bentonite clay were added and sufficiently stirred to thicken. Then, 2.0 parts by weight of additives such as an antifoaming agent and a stabilizer were added and mixed to prepare a putty.
상기 실시예와 같이 본 발명에 따라 제조된 수용성 도료 조성물은 소성황토와 맥반석을 다량 함유하기 때문에 항균, 탈취 또는 제습과 같은 기능성이 뛰어나고 도장 작업시 또는 작업 후 인체에 유익한 작용을 일으키는 등의 유용한 효과를 지닌다.Since the water-soluble coating composition prepared according to the present invention as in the above embodiment contains a large amount of calcined ocher and elvan, it has excellent functions such as antibacterial, deodorant or dehumidification, and useful effects such as causing beneficial effects on the human body during or after painting work. Has
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| Country | Link |
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| KR (1) | KR19990010915A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010100122A (en) * | 2001-10-08 | 2001-11-14 | (주)파워바이오 | The method of making the paint that it happens oxygen anion. |
| KR20030018284A (en) * | 2001-08-27 | 2003-03-06 | 김선일 | Admixture prescription of ocher paint and preparation method |
| KR100524625B1 (en) * | 2002-09-17 | 2005-10-28 | 이진헌 | Yellow Soil Paint Containing Microcapsules Emitting Long-Lasting Fragrance |
| KR100989284B1 (en) * | 2009-08-27 | 2010-10-22 | 창 한 김 | A method manufacturing composition water-soluble chinhwangyeong |
| KR101519404B1 (en) * | 2014-11-03 | 2015-05-13 | 유지씨 주식회사 | Building coating method using the composition and the composition born tile paint to prevent flow down |
| KR20180005966A (en) | 2016-07-07 | 2018-01-17 | 명진에코 주식회사 | Environment-friendly paint compositions using yellow soil stone |
-
1997
- 1997-07-19 KR KR1019970033794A patent/KR19990010915A/en not_active Application Discontinuation
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030018284A (en) * | 2001-08-27 | 2003-03-06 | 김선일 | Admixture prescription of ocher paint and preparation method |
| KR20010100122A (en) * | 2001-10-08 | 2001-11-14 | (주)파워바이오 | The method of making the paint that it happens oxygen anion. |
| KR100524625B1 (en) * | 2002-09-17 | 2005-10-28 | 이진헌 | Yellow Soil Paint Containing Microcapsules Emitting Long-Lasting Fragrance |
| KR100989284B1 (en) * | 2009-08-27 | 2010-10-22 | 창 한 김 | A method manufacturing composition water-soluble chinhwangyeong |
| KR101519404B1 (en) * | 2014-11-03 | 2015-05-13 | 유지씨 주식회사 | Building coating method using the composition and the composition born tile paint to prevent flow down |
| KR20180005966A (en) | 2016-07-07 | 2018-01-17 | 명진에코 주식회사 | Environment-friendly paint compositions using yellow soil stone |
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