KR19980073351A - Softener in Washing Machine - Google Patents
Softener in Washing Machine Download PDFInfo
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- KR19980073351A KR19980073351A KR1019970008583A KR19970008583A KR19980073351A KR 19980073351 A KR19980073351 A KR 19980073351A KR 1019970008583 A KR1019970008583 A KR 1019970008583A KR 19970008583 A KR19970008583 A KR 19970008583A KR 19980073351 A KR19980073351 A KR 19980073351A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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Abstract
본 발명은 일련의 세탁행정중 헹굼행정시 세탁물에 유연성 및 대전방지를 위하여 투입하게 되는 유연사상제의 유연처리 및 대전방지 효과를 향상할 수 있도록 한 세탁기의 유연사상제에 관한 것으로,The present invention relates to a flexible sanding agent of a washing machine to improve the flexible treatment and the antistatic effect of the flexible sanding agent to be put into the laundry for flexibility and antistatic during the rinsing stroke of a series of washing operations,
본 발명은 비이온계 계면활성제 25 - 37%로 조성하되 상기 계면활성제는 대전방지제로 도데실 폴리옥시 에틸렌 에테르 10 - 15%, 섬유유연제인 디에탄올 아미드 15 - 22% 로 각각 조성하고, 증량제 22 - 33% 로 조성하되 상기 증량제는 계면활성제의 성능 촉진제로 솔비탄 모노 올레이트 7 - 10%, 세척제로 노말파라핀 10 - 15%, 저온조건에서 활성제로 프로필렌 글리콜 5 - 8%로 각각 조성하며, 기타 방향제로 오렌지오일 0.5 - 1%, 물 29- 52.5% 로 혼합 조성하여,상기 비이온계 계면활성제와 음이온계 계면활성제와의 반응을 근원적으로 차단및 화학반응이 일어나지 않도록 함으로써, 세탁물에 유연 및 대전방지 효과 향상은 물론, 얼룩이 세탁조에 고착되지 않도록 하여 위생적인 세탁효과를 얻을수 있도록 한 것을 특징으로 한다.The present invention is composed of 25 to 37% of nonionic surfactants, wherein the surfactant is composed of 10 to 15% of dodecyl polyoxy ethylene ether as an antistatic agent and 15 to 22% of diethanol amide, a fabric softener, and an extender 22. -33%, the extender is composed of sorbitan monooleate 7-10% as a surfactant performance promoter, normal paraffin 10-15% as a detergent, propylene glycol 5-8% as an active agent at low temperature conditions, respectively, It is mixed with 0.5-1% of orange oil and 29-52.5% of water as other fragrances, so that the reaction between the nonionic surfactant and the anionic surfactant is prevented from occurring and the chemical reaction does not occur. As well as improving the antistatic effect, it is characterized in that the stain is not fixed to the washing tank to obtain a sanitary washing effect.
Description
본 발명은 세탁기의 유연사상제에 관한 것으로, 특히 일련의 세탁행정중 헹굼행정시 세탁물에 유연성 및 대전방지를 위하여 투입하게 되는 유연사상제의 유연처리 및 대전방지 효과를 향상할 수 있도록 한 세탁기의 유연사상제에 관한 것이다.The present invention relates to a flexible washing agent of a washing machine, and more particularly, to a flexible washing agent and an antistatic effect of a flexible washing agent, which is added to the laundry for flexibility and antistatic rinsing during a series of washing strokes. It is related to a soft thought agent.
일반적으로 세탁기의 유연사상제는 유연 및 대전방지의 목적으로 여러 가지 물질이 사용되고 있지만, 널리 사용되고 있는 것은 계면활성제로서 양이온계(4차 암모늄염)등이 주로 사용되게 된다.In general, a flexible washing agent of a washing machine is used for various materials for the purpose of softening and antistatic, but is widely used cationic (quaternary ammonium salt) and the like as a surfactant.
왜냐하면 세탁시 섬유는 물속에서 음이온(-)을 나타내게 되므로 상기 양이온계 계면활성제를 투입하게 되면 상기 양이온계 계면활성제는 음이온(-)을 띠는 섬유에 흡착되어 섬유의 표면에 배열되고, 여기에 다시 수분이 흡착되어 대전을 방지하게 되기 때문이다.Because, when washing, the fiber shows an anion (-) in water, so when the cationic surfactant is added, the cationic surfactant is adsorbed on the anionic (-) fiber and is arranged on the surface of the fiber. This is because moisture is adsorbed to prevent charging.
또한 상기 섬유는 세탁에 의하여 굳어지는 성질이 있는데, 이것은 세탁에 의해 섬유와 직물조직이 고정되어 섬유가 자유롭게 움직이지 못하기 때문이다.In addition, the fiber has a property of being hardened by washing, because the fiber and the fabric structure is fixed by washing, the fiber does not move freely.
따라서 상기 굳어진 섬유를 유연제사상제로 처리하게 되면 계면활성제의 양전하를 가진 친수기가 섬유쪽으로 향하고, 친유기는 밖으로 향하게 되어 상기 섬유의 표면에는 친유기로 덮여 마치 기름의 얇은 막을 입힌 것과 같이 되므로 윤활작용을 하게 되어 결국 섬유와 실의 움직임이 자유롭고 부드러워지며, 부피 또한 증가하게 된다.Therefore, when the hardened fiber is treated with a softener, the hydrophilic group having a positive charge of the surfactant is directed toward the fiber, and the lipophilic group is directed outwards, so that the surface of the fiber is covered with a lipophilic layer as if it is coated with a thin film of oil, thereby lubricating. Eventually, the fiber and yarn move freely and smoothly, increasing in volume.
이와같이 세탁물에 대전방지 및 유연성을 주기 위하여 사용되는 종래의 유연사상제는 계면활성제중 음이온계(-)성분이 대부분 양이온계 계면활성제인 유연및 대전방지제와 결합하여 중화작용을 하게 되므로, 섬유에 유연및 대전방지 기능이 모두 상실되게 되며, 또한 음이온계(-)성분은 세탁조 내벽에 고착되어 얼룩이 지고, 이 얼룩은 세탁완료후에도 쉽게 제거되지 않는 문제점을 가지게 되었다.Thus, the conventional softening agent used to give antistatic property and flexibility to the laundry, since the anionic (-) component of the surfactant is combined with the softening and antistatic agent, which is mostly cationic surfactants, it is neutralized to the fiber. And all the antistatic function is lost, and also the anionic (-) component is fixed to the inner wall of the washing tank staining, this stain has a problem that is not easily removed even after washing.
본 발명의 목적은 유연 및 대전방지제의 계면활성제 성분을 비이온계로 적용하고, 저온에서 효과가 좋은 프로필렌글리콜을 활성제를 첨가하여 상기 비이온계 계면활성제와 음이온계 계면활성제(LAS,AOS,AS)와의 반응을 근원적으로 차단및 화학반응이 일어나지 않도록 함으로써, 세탁물에 유연 및 대전방지 효과 향상은 물론, 얼룩이 세탁조에 고착되지 않도록 하여 위생적인 세탁효과를 얻고자 하는데 있다.An object of the present invention is to apply the surfactant component of the softening and antistatic agent to the nonionic, and the nonionic surfactant and anionic surfactant (LAS, AOS, AS) by adding an active agent to propylene glycol which is effective at low temperatures By fundamentally blocking the reaction with and do not cause a chemical reaction, to improve the soft and antistatic effect of the laundry, as well as to prevent the stains adhere to the washing tank to obtain a hygienic washing effect.
상기의 목적을 실현하기 위하여 본 발명은 비이온계 계면활성제인 대전방지제로 도데실 폴리옥시 에틸렌 에테르, 섬유유연제인 디에탄올 아미드, 계면활성제의 성능 촉진제로 솔비탄 모노 올레이트, 세척제로 노말파라핀, 저온조건에서 활성제로 프로필렌 글리콜, 방향제로 오렌지오일, 물로 조성하여서 된 것을 특징으로 한다.In order to realize the above object, the present invention is a nonionic surfactant antistatic agent, dodecyl polyoxy ethylene ether, a fiber softener diethanol amide, surfactant surfactant sorbitan monooleate, cleaning agent normal paraffin, It is characterized by consisting of propylene glycol as an active agent under low temperature conditions, orange oil as a perfume, water.
이하 실시예에 의거 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the following Examples.
실시예Example
본 발명은 비이온계 계면활성제 25 - 37%로 조성하되 상기 계면활성제는 대전방지제로 도데실 폴리옥시 에틸렌 에테르 10 - 15%, 섬유유연제인 디에탄올 아미드 15 - 22% 로 각각 조성하고, 증량제 22 - 33% 로 조성하되 상기 증량제는 계면활성제의 성능 촉진제로 솔비탄 모노 올레이트 7 - 10%, 세척제로 노말파라핀 10 - 15%, 저온조건에서 활성제로 프로필렌 글리콜 5 - 8%로 각각 조성하며, 기타 방향제로 오렌지오일 0.5 - 1%, 물 29- 52.5% 로 혼합 조성하게 된다.The present invention is composed of 25 to 37% of nonionic surfactants, wherein the surfactant is composed of 10 to 15% of dodecyl polyoxy ethylene ether as an antistatic agent and 15 to 22% of diethanol amide, a fabric softener, and an extender 22. -33%, the extender is composed of sorbitan monooleate 7-10% as a surfactant performance promoter, normal paraffin 10-15% as a detergent, propylene glycol 5-8% as an active agent at low temperature conditions, respectively, Other fragrances are 0.5-1% orange oil and 29-52.5% water.
이때 상기 본 발명의 바람직한 조성은 상기 비이온계 계면활성제인 도데실 폴리옥시 에틸렌 에테르는 12%, 디에탄올 아미드는 20%, 계면활성제의 성능 촉진제인 솔비탄 모노 올레이트는 10%, 세척제인 노말파라핀 12%, 저온조건에서 활성제인 프로필렌 글리콜은 5%, 기타 방향제로 오렌지오일은 1%, 물은 40% 로 조성함으로써, 계면활성제 중 음이온계(-)성분(LAS,AOS,AS)과 결합 및 화학반응이 발생되지 않아 섬유에 대전방지 뿐만 아니라, 화학반응에 의한 얼룩이 존재하지 않게 되고,보다 효과적으로 섬유에 대전방지 및 유연성을 갖게 할수 있게 된다.At this time, the preferred composition of the present invention is 12% dodecyl polyoxy ethylene ether of the nonionic surfactant, 20% diethanol amide, 10% sorbitan monooleate, a performance promoter of the surfactant, normal detergent 12% paraffin, 5% propylene glycol as active agent at low temperature, 1% orange oil and 40% water as other fragrances to bind anionic (-) components (LAS, AOS, AS) among surfactants And since the chemical reaction does not occur, as well as the antistatic, the stain of the chemical reaction is not present in the fiber, it is possible to more effectively have the antistatic and flexible to the fiber.
상기와 같이 조성되는 본 발명 유연사상제를 세탁개시전에 세탁기의 정전기방지제 투입구에 0.5g/L 로 하여 세탁수위에 맞게 투입하여 헹굼행정의 최종단계에서 자동적으로 세탁조의 내부로 유입되면서 헹굼이 이루어지게 되는데, 이때 상기 본 발명 유연사상제의 성분은 비이온계 계면활성제 로서 대전방지제인 도데실 폴리옥시 에틸렌 에테르와 섬유유연제인 디에탄올아미드에 의하여 계면활성제 중 음이온계(-)성분(LAS,AOS,AS)과 결합 및 화학반응이 발생되지 않아 섬유에 대전방지 뿐만 아니라 화학반응에 의한 얼룩이 존재하지 않게 되고, 계면활성제의 양전하를 가진 친수기가 섬유쪽으로 향하고, 친유기는 밖으로 향하게 되어 상기 섬유의 표면에는 친유기로 덮여 마치 기름의 얇은 막을 형성하여 윤활작용을 하게 되므로 섬유에 내구성 및 유연성을 갖게 되고, 상기 저온활성제인 프로필렌 글리콜과 솔비탄 모노 올레이트에 의하여 헹굼시 저온조건에서도 상기 계면활성제의 활성을 촉진시켜 주게 되어 섬유에 쉽게 유연처리 및 대전방지를 할수 있게 된다.0.5 g / L into the antistatic agent inlet of the washing machine before the start of washing the flexible softener of the present invention as described above is put into the washing water level so that the rinsing is performed automatically into the washing tank at the final stage of the rinsing cycle. In this case, the components of the present invention, the softening agent is an anionic (-) component of the surfactant (LAS, AOS, by a non-ionic surfactant dodecyl polyoxy ethylene ether and anti-ethanolamide as a fiber softener AS) does not occur and the chemical reaction does not occur, as well as the antistatic as well as the staining by the chemical reaction does not exist in the fiber, the positively charged hydrophilic group of the surfactant is directed toward the fiber, the lipophilic group is directed outward to the lipophilic group on the surface of the fiber It is covered with a film, which forms a thin film of oil for lubrication, which makes the fiber durable and flexible. Have been, in the rinsing water during the low-temperature condition by the low temperature surfactant is propylene glycol and sorbitan monooleate is dropped by stimulating the activity of the surfactant it is possible to be easy to handle, flexible and antistatic fibers.
이상에서 설명한 바와같이, 본 발명은 유연 및 대전방지제의 계면활성제 성분을 비이온계인 도데실 폴리옥시 에틸렌 에테르, 섬유유연제인 디에탄올 아미드로 조성하고, 저온에서 효과가 좋은 프로필렌글리콜을 활성제를 첨가하여 상기 비이온계 계면활성제와 음이온계 계면활성제(LAS,AOS,AS)와의 반응을 근원적으로 차단및 화학반응이 일어나지 않도록 함으로써, 세탁물에 유연 및 대전방지 효과 향상은 물론, 얼룩이 세탁조에 고착되지 않도록 하여 위생적인 세탁효과를 제공할 수 있게 되는 것이다.As described above, in the present invention, the surfactant component of the softening and antistatic agent is composed of a nonionic dodecyl polyoxy ethylene ether and a fiber softener diethanol amide. By blocking the reaction between the non-ionic surfactant and the anionic surfactant (LAS, AOS, AS) to prevent the reaction and chemical reactions to occur fundamentally, as well as improving the soft and antistatic effect on the laundry, as well as preventing stains from sticking to the washing tank It will be able to provide a sanitary washing effect.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019970008583A KR100207228B1 (en) | 1997-03-14 | 1997-03-14 | Soft detergent for a washing machine |
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| KR1019970008583A KR100207228B1 (en) | 1997-03-14 | 1997-03-14 | Soft detergent for a washing machine |
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| KR19980073351A true KR19980073351A (en) | 1998-11-05 |
| KR100207228B1 KR100207228B1 (en) | 1999-07-15 |
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