KR102684633B1 - Anti-slip powder composition and constructing method of floor surface finishing material using the composition - Google Patents
Anti-slip powder composition and constructing method of floor surface finishing material using the composition Download PDFInfo
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- KR102684633B1 KR102684633B1 KR1020240050061A KR20240050061A KR102684633B1 KR 102684633 B1 KR102684633 B1 KR 102684633B1 KR 1020240050061 A KR1020240050061 A KR 1020240050061A KR 20240050061 A KR20240050061 A KR 20240050061A KR 102684633 B1 KR102684633 B1 KR 102684633B1
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- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 239000000843 powder Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 12
- 238000009408 flooring Methods 0.000 claims abstract description 37
- 229920000642 polymer Polymers 0.000 claims abstract description 26
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- 238000010276 construction Methods 0.000 claims abstract description 22
- 239000004848 polyfunctional curative Substances 0.000 claims abstract description 13
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 11
- 239000004743 Polypropylene Substances 0.000 claims abstract description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000004202 carbamide Substances 0.000 claims abstract description 11
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 11
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 polypropylene Polymers 0.000 claims abstract description 11
- 229920001155 polypropylene Polymers 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000004593 Epoxy Substances 0.000 claims description 12
- 239000003973 paint Substances 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004952 Polyamide Substances 0.000 description 6
- 229920002647 polyamide Polymers 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 239000010426 asphalt Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 206010039203 Road traffic accident Diseases 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/21—Urea; Derivatives thereof, e.g. biuret
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/149—Antislip compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Floor Finish (AREA)
Abstract
본 발명은 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥용 표면 마감재의 시공 방법에 관한 것으로, 상기 미끄럼 방지용 분말 조성물은 탄산칼슘, 멜라민, 우레아, 무수말레인산 및 폴리프로필렌으로 이루어지며, 상기 미끄럼 방지용 분말 조성물을 이용한 바닥 시공 방법은 시공면에 하도 도막을 형성하는 하도도막형성단계, 상기 하도도막형성단계를 통해 형성된 하도 도막의 상부면에 바닥재용 고분자, 경화제 및 미끄럼 방지용 분말 조성물로 이루어진 미끄럼방지용 바닥재를 도포하는 미끄럼방지층형성단계 및 상기 미끄럼방지층형성단계를 통해 형성된 미끄럼 방지층의 상부면에 상도 도막을 형성하는 상도도막형성단계로 이루어진다.
상기의 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥 시공 방법은 미끄럼 방지 저항성과 내충격강도가 우수하며 미끄럼 방지 성능이 장기간 지속됨에 따라 수명주기에 따른 경제적 비용을 절감할 뿐만 아니라, 하도나 중도와의 부착성이 강력한 미끄럼 방지용 분말이 사용되어 우수한 내구성을 나타내는 바닥면을 제공한다.The present invention relates to an anti-slip powder composition and a method of constructing a floor surface finishing material using the composition. The anti-slip powder composition is composed of calcium carbonate, melamine, urea, maleic anhydride and polypropylene, and the anti-slip powder composition includes: The floor construction method includes the steps of forming an undercoat film on the construction surface, and applying an anti-slip flooring material consisting of a flooring polymer, a hardener, and an anti-slip powder composition to the upper surface of the undercoat film formed through the undercoat film forming step. It consists of a non-slip layer forming step and a top coat film forming step of forming a top coat on the upper surface of the anti-slip layer formed through the anti-slip layer forming step.
The anti-slip powder composition and the floor construction method using the composition have excellent anti-slip resistance and impact resistance, and the anti-slip performance lasts for a long period of time, which not only reduces economic costs over the life cycle, but also adheres to the base or middle layer. A highly durable anti-slip powder is used to provide a floor surface with excellent durability.
Description
본 발명은 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥용 표면 마감재의 시공 방법에 관한 것으로, 더욱 상세하게는 미끄럼 방지 저항성과 내충격강도가 우수하며 미끄럼 방지 성능이 장기간 지속됨에 따라 수명주기에 따른 경제적 비용을 절감할 뿐만 아니라, 하도나 중도와의 부착성이 강력한 미끄럼 방지용 분말이 사용되어 우수한 내구성을 나타내는 바닥면을 제공하는 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥용 표면 마감재의 시공 방법에 관한 것이다.The present invention relates to an anti-slip powder composition and a method of constructing a floor surface finishing material using the composition. More specifically, it has excellent anti-slip resistance and impact strength, and the economic cost according to the life cycle as the anti-slip performance lasts for a long period of time. The present invention relates to an anti-slip powder composition that not only saves money, but also provides a floor surface with excellent durability by using an anti-slip powder that has strong adhesion to the base or middle layer, and a method of constructing a floor surface finishing material using the composition.
통상적으로 미끄럼방지 포장은 포장의 미끄럼 저항을 높여 차량의 안전한 주행을 도모하기 위한 시설로, 노면의 미끄럼 저항이 낮아진 곳, 도로의 평면 및 종단 선형이 불량한 곳 등의 포장 면에 미끄럼 저항을 향상시켜 차량의 제동거리를 짧게 하거나 식별력을 향상시켜 교통사고를 예방하기 위한 목적으로 진행된다.Typically, anti-slip pavement is a facility to promote safe driving of vehicles by increasing the slip resistance of the pavement. It improves the slip resistance on the pavement surface, such as in places where the slip resistance of the road surface is low or where the planar and longitudinal alignment of the road is poor. The purpose is to prevent traffic accidents by shortening the vehicle's braking distance or improving its identification.
이러한, 미끄럼방지 포장은 도로의 기하구조 및 교통 특성에 따라 요구되는 수준의 미끄럼 저항이 확보되지 못하는 구간에 설치하여 마찰력을 증진시키는데 목적이 있다. 즉, 도로의 사용 기간이 증가함에 따라 포장의 미끄럼 저항이 전 구간에 걸쳐서 일정 수준 이하로 떨어지는 경우에는 포장의 유지관리 측면에서 근본적으로 미끄럼 저항을 높이기 위해 미끄럼 방지용 도료 조성물을 이용하여 도로를 보수하며, 최근 이러한 미끄럼방지용 도료 조성물은 도로 이외에도 보행시 미끄러지기 쉬운 장소인 건축물의 옥상, 야외주차장, 공원 등에도 도포함에 따라 그 수요가 급증하고 있다.The purpose of this anti-slip pavement is to increase friction by installing it in sections where the required level of slip resistance cannot be secured depending on the geometry of the road and traffic characteristics. In other words, if the slip resistance of the pavement falls below a certain level throughout the entire section as the period of use of the road increases, the road must be repaired using an anti-slip paint composition to fundamentally increase the slip resistance in terms of pavement maintenance. , Recently, the demand for these anti-slip paint compositions is rapidly increasing as they are applied not only to roads but also to places where it is easy to slip while walking, such as rooftops of buildings, outdoor parking lots, and parks.
특히, 아스팔트나 콘크리트로 포장된 도로는 노면이 견고하고 평탄하기 때문에 차량 주행시 쾌적하고 양호한 승차감을 주는 반면에, 고속으로 주행하거나 혹은 눈, 비가 온 경우 노면이 상당히 미끄러워 커브길, 비탈길 등과 같은 위험지역에서 교통사고가 자주 발생하게 된다는 문제점을 내포하고 있다.In particular, roads paved with asphalt or concrete have a solid and flat road surface, providing a pleasant and good ride. However, when driving at high speeds or when it snows or rains, the road surface is quite slippery and poses risks such as curves and slopes. The problem is that traffic accidents frequently occur in the area.
종래에는 미끄럼방지 효과를 부여하기 위해 폴리올레핀 분쇄물의 표면에 실란코팅을 실시한 미끄럼 방지용 분말을 사용하고자하는 시도가 이루어지고 있으나, 실란으로 표면개질된 폴리올레핀 분쇄물의 경우 제조비용이 지나치게 고가이며, 응집에너지는 강하지만 부착성이 낮아 도막에서 쉽게 이탈되는 문제점이 있었다.Conventionally, attempts have been made to use anti-slip powder coated with silane on the surface of polyolefin pulverized product to provide an anti-slip effect. However, in the case of polyolefin pulverized product surface-modified with silane, the manufacturing cost is too high, and the cohesive energy is low. Although it was strong, it had low adhesion and had the problem of being easily separated from the paint film.
본 발명의 목적은 미끄럼 방지 저항성과 내충격강도가 우수하며 시공비가 저렴할 뿐만 아니라, 도막과의 부착성이 강력한 미끄럼 방지용 분말이 사용되어 우수한 내구성을 나타내는 바닥면을 제공하는 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥용 표면 마감재의 시공 방법에 관한 것이다.The object of the present invention is to provide an anti-slip powder composition that not only has excellent anti-slip resistance and impact strength, has low construction costs, and provides a floor surface with excellent durability by using an anti-slip powder with strong adhesion to the coating film, and the composition thereof. This relates to the construction method of the floor surface finishing material used.
본 발명의 목적은 탄산칼슘, 멜라민, 우레아, 무수말레인산 및 폴리프로필렌을 포함하는 것을 특징으로 하는 미끄럼 방지용 분말 조성물을 제공함에 의해 달성된다.The object of the present invention is achieved by providing an anti-slip powder composition comprising calcium carbonate, melamine, urea, maleic anhydride and polypropylene.
본 발명의 바람직한 특징에 따르면, 상기 미끄럼 방지용 분말 조성물은 탄산칼슘 100 중량부, 멜라민 100 내지 200 중량부, 우레아 100 내지 200 중량부, 무수말레인산 10 내지 50 중량부 및 폴리프로필렌 10 내지 50 중량부를 포함하는 것으로 한다.According to a preferred feature of the present invention, the anti-slip powder composition includes 100 parts by weight of calcium carbonate, 100 to 200 parts by weight of melamine, 100 to 200 parts by weight of urea, 10 to 50 parts by weight of maleic anhydride, and 10 to 50 parts by weight of polypropylene. Do it by doing it.
본 발명의 더 바람직한 특징에 따르면, 상기 미끄럼 방지용 분말 조성물은 탄산칼슘 100 중량부, 멜라민 100 내지 200 중량부, 우레아 100 내지 200 중량부, 무수말레인산 10 내지 50 중량부 및 폴리프로필렌 10 내지 50 중량부를 혼합하고 210 내지 270℃의 온도로 1차 압출한 후에, 1차 압출물 100 중량부 대비 안료 1 내지 5 중량부를 혼합하고 180 내지 190℃의 온도로 2차 압출, 냉각 및 분쇄하는 과정으로 제조되는 것으로 한다.According to a more preferred feature of the present invention, the anti-slip powder composition contains 100 parts by weight of calcium carbonate, 100 to 200 parts by weight of melamine, 100 to 200 parts by weight of urea, 10 to 50 parts by weight of maleic anhydride, and 10 to 50 parts by weight of polypropylene. After mixing and primary extrusion at a temperature of 210 to 270°C, 1 to 5 parts by weight of pigment is mixed with 100 parts by weight of the primary extrudate, secondary extrusion at a temperature of 180 to 190°C, cooling and grinding. Let's do it.
본 발명의 더욱 바람직한 특징에 따르면, 상기 미끄럼 방지용 분말 조성물은 200 내지 1000 마이크로미터의 입자크기를 나타내는 것으로 한다.According to a more preferred feature of the present invention, the anti-slip powder composition has a particle size of 200 to 1000 micrometers.
또한, 본 발명의 목적은 시공면에 하도 도막을 형성하는 하도도막형성단계, 상기 하도도막형성단계를 통해 형성된 하도 도막의 상부면에 바닥재용 고분자, 경화제 및 상기 미끄럼 방지용 분말 조성물로 이루어진 미끄럼방지용 바닥재 조성물을 도포하는 미끄럼방지층형성단계 및 상기 미끄럼방지층형성단계를 통해 형성된 미끄럼 방지층의 상부면에 상도 도막을 형성하는 상도도막형성단계로 이루어지는 것을 특징으로 하는 미끄럼 방지용 분말 조성물을 이용한 바닥용 표면 마감재의 시공 방법을 제공함에 의해 달성된다.In addition, the object of the present invention is to provide an undercoat film forming step of forming a undercoat film on the construction surface, an anti-slip flooring material composed of a flooring polymer, a curing agent, and the anti-slip powder composition on the upper surface of the undercoat film formed through the undercoat film forming step. Construction of a floor surface finish using an anti-slip powder composition, characterized in that it consists of a non-slip layer forming step of applying the composition and a top coat forming step of forming a top coat on the upper surface of the anti-slip layer formed through the anti-slip layer forming step. This is achieved by providing a method.
본 발명의 바람직한 특징에 따르면, 상기 미끄럼 방지층은 300 내지 1000 마이크로미터의 두께로 형성되는 것으로 한다.According to a preferred feature of the present invention, the anti-slip layer is formed to have a thickness of 300 to 1000 micrometers.
본 발명의 더 바람직한 특징에 따르면, 상기 바닥재용 고분자는 에폭시, 우레탄, 메틸아크릴레이트 및 메틸메타아크릴레이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the polymer for flooring is made of one or more selected from the group consisting of epoxy, urethane, methyl acrylate, and methyl methacrylate.
본 발명의 더욱 바람직한 특징에 따르면, 상기 바닥재용 고분자에는 모르타르가 더 함유되는 것으로 한다.According to a more preferred feature of the present invention, the polymer for flooring further contains mortar.
본 발명에 따른 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥용 표면 마감재의 시공 방법은 미끄럼 방지 저항성과 내충격강도가 우수하며 시공비가 저렴할 뿐만 아니라, 도막과의 부착성이 강력한 미끄럼 방지용 분말이 사용되어 우수한 내구성을 나타내는 바닥면을 제공하는 탁월한 효과를 나타낸다.The anti-slip powder composition according to the present invention and the method of constructing a floor surface finishing material using the composition have excellent anti-slip resistance and impact strength, and not only are the construction costs low, but the anti-slip powder with strong adhesion to the coating film is used, resulting in excellent anti-slip powder. It has an excellent effect in providing a durable floor surface.
도 1은 본 발명에 따른 미끄럼 방지용 분말 조성물을 이용한 바닥용 표면 마감재의 시공 방법을 나타낸 순서도이다.Figure 1 is a flowchart showing a method of constructing a floor surface finishing material using an anti-slip powder composition according to the present invention.
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.Below, preferred embodiments of the present invention and the physical properties of each component are described in detail, but the purpose is to provide a detailed description so that a person skilled in the art can easily carry out the invention. This does not mean that the technical idea and scope of the present invention are limited.
본 발명에 따른 미끄럼 방지용 분말 조성물은 탄산칼슘, 멜라민, 우레아, 무수말레인산 및 폴리프로필렌을 포함하여 이루어지며, 탄산칼슘 100 중량부, 멜라민 100 내지 200 중량부, 우레아 100 내지 200 중량부, 무수말레인산 10 내지 50 중량부 및 폴리프로필렌 10 내지 50 중량부를 포함하여 이루어지는 것이 바람직한데, 탄산칼슘 100 중량부, 멜라민 100 내지 200 중량부, 우레아 100 내지 200 중량부, 무수말레인산 10 내지 50 중량부 및 폴리프로필렌 10 내지 50 중량부를 혼합하고 210 내지 270℃의 온도로 1차 압출한 후에, 1차 압출물 100 중량부 대비 안료 1 내지 5 중량부를 혼합하고 180 내지 190℃의 온도로 2차 압출, 냉각 및 분쇄하는 과정으로 제조되는 것이 더욱 바람직하다.The anti-slip powder composition according to the present invention includes calcium carbonate, melamine, urea, maleic anhydride, and polypropylene, including 100 parts by weight of calcium carbonate, 100 to 200 parts by weight of melamine, 100 to 200 parts by weight of urea, and 10 parts by weight of maleic anhydride. to 50 parts by weight and 10 to 50 parts by weight of polypropylene, including 100 parts by weight of calcium carbonate, 100 to 200 parts by weight of melamine, 100 to 200 parts by weight of urea, 10 to 50 parts by weight of maleic anhydride, and 10 to 10 parts by weight of polypropylene. After mixing 50 parts by weight and first extruding at a temperature of 210 to 270 ℃, mixing 1 to 5 parts by weight of pigment based on 100 parts by weight of the primary extrudate, secondary extrusion at a temperature of 180 to 190 ℃, cooling and pulverizing. It is more preferable to manufacture it through a process.
상기의 과정을 통해 제조되는 미끄럼 방지용 분말 조성물은 아래 화학식 1에 나타낸 것처럼 에폭시, 우레탄, 메틸아크릴레이트 및 메틸메타아크릴레이트 등과 같은 도막형성용 수지와의 화학적 결합이 가능하도록 하는 관능기가 다수 존재하여 도막형성용 수지에 견고하게 결합될 수 있다.The anti-slip powder composition manufactured through the above process contains a large number of functional groups that enable chemical bonding with resins for forming a coating film such as epoxy, urethane, methyl acrylate, and methyl methacrylate, as shown in Chemical Formula 1 below, thereby forming a coating film. It can be firmly bonded to the forming resin.
<화학식 1><Formula 1>
이때, 상기 2차 압출시 압출기의 스크류는 3 내지 30rpm의 속도로 회전 하는 것이 바람직하며, 상기의 분쇄를 통해 제조되는 미끄럼 방지용 분말 조성물은 200 내지 1000 마이크로미터의 입자크기를 나타내는 것이 더욱 바람직하다.At this time, during the secondary extrusion, the screw of the extruder is preferably rotated at a speed of 3 to 30 rpm, and the anti-slip powder composition produced through the above grinding preferably has a particle size of 200 to 1000 micrometers.
상기 미끄럼 방지용 분말 조성물의 입자크기가 200 마이크로미터 미만이면 미끄럼 방지 효과가 미미하며, 상기 미끄럼 방지용 분말 조성물의 입자크기가 1000 마이크로미터를 초과하게 되면 도막형성용 수지와의 결합력이 지나치게 저하될 수 있기 때문에 바람직하지 못하다.If the particle size of the anti-slip powder composition is less than 200 micrometers, the anti-slip effect is minimal, and if the particle size of the anti-slip powder composition exceeds 1000 micrometers, the bonding strength with the resin for forming a coating film may be excessively reduced. Therefore, it is not desirable.
또한, 본 발명에 따른 미끄럼 방지용 분말 조성물을 이용한 바닥 시공 방법은 시공면에 하도 도막을 형성하는 하도도막형성단계(S101), 상기 하도도막형성단계(S101)를 통해 형성된 하도 도막의 상부면에 바닥재용 고분자, 경화제 및 상기 미끄럼 방지용 분말 조성물로 이루어진 미끄럼방지용 바닥재 조성물을 도포하는 미끄럼방지층형성단계(S103) 및 상기 미끄럼방지층형성단계(S103)를 통해 형성된 미끄럼 방지층의 상부면에 상도 도막을 형성하는 상도도막형성단계(S105)로 이루어진다.In addition, the floor construction method using the anti-slip powder composition according to the present invention includes an undercoat film forming step (S101) of forming an undercoat film on the construction surface, and a flooring material on the upper surface of the undercoat film formed through the undercoat film forming step (S101). A non-slip layer forming step (S103) of applying an anti-slip flooring composition consisting of a polymer, a curing agent, and the anti-slip powder composition, and a top coat of forming a top coat on the upper surface of the anti-slip layer formed through the anti-slip layer forming step (S103). It consists of a film formation step (S105).
상기 하도도막형성단계(S101)는 시공면에 하도 도막을 형성하는 단계로, 시공면에 이물질을 제거한 후에 바닥재용 고분자 100 중량부 및 경화제 30 내지 50 중량부로 이루어진 하도용 도료를 100 내지 1000 마이크로미터의 두께로 도포하는 과정으로 이루어지는 것이 바람직하다.The undercoat film forming step (S101) is a step of forming a undercoat film on the construction surface. After removing foreign substances from the construction surface, an undercoat paint consisting of 100 parts by weight of a polymer for flooring and 30 to 50 parts by weight of a hardener is applied to a thickness of 100 to 1000 micrometers. It is desirable to carry out the process of applying with a thickness of.
이때, 상기 바닥재용 고분자는 에폭시, 우레탄, 메틸아크릴레이트 및 메틸메타아크릴레이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하며, 상기의 성분으로 이루어지는 바닥재용 고분자에는 모르타르가 더 함유되는 것이 더욱 바람직하다.At this time, the polymer for flooring is preferably made of at least one selected from the group consisting of epoxy, urethane, methyl acrylate, and methyl methacrylate, and it is more preferable that the polymer for flooring made of the above components further contains mortar. .
상기 경화제는 바닥재용 고분자 성분에 대응되는 에폭시 경화제, 우레탄 경화제 및 아크릴 경화제로 이루어지는 것이 바람직하다.The curing agent is preferably composed of an epoxy curing agent, a urethane curing agent, and an acrylic curing agent corresponding to the polymer component for flooring.
상기의 과정으로 이루어지는 하도도막형성단계(S101)를 통해 형성된 하도 도막은 상온에서 경화시키는 것이 바람직하다.It is preferable that the base coat film formed through the base coat film forming step (S101) consisting of the above process is cured at room temperature.
상기 미끄럼방지층형성단계(S103)는 상기 하도도막형성단계(S101)를 통해 형성된 하도 도막의 상부면에 바닥재용 고분자, 경화제 및 상기 미끄럼 방지용 분말 조성물로 이루어진 미끄럼방지용 바닥재 조성물을 도포하는 단계로, 상기 하도도막형성단계(S101)를 통해 형성된 하도 도막의 상부면에 바닥재용 고분자 100 중량부, 경화제 30 내지 50 중량부 및 상기 미끄럼 방지용 분말 조성물 10 내지 20 중량부로 이루어진 미끄럼방지용 바닥재 조성물을 300 내지 1000 마이크로미터의 두께로 도포하는 과정으로 이루어지는 것이 바람직하다.The anti-slip layer forming step (S103) is a step of applying an anti-slip flooring composition consisting of a flooring polymer, a curing agent, and the anti-slip powder composition to the upper surface of the undercoat film formed through the undercoat film forming step (S101). An anti-slip flooring composition consisting of 100 parts by weight of a flooring polymer, 30 to 50 parts by weight of a hardener, and 10 to 20 parts by weight of the anti-slip powder composition was applied to the upper surface of the undercoat film formed through the undercoat film forming step (S101) at 300 to 1000 micrometers. It is desirable to carry out the process of applying with a thickness of one meter.
상기 미끄럼 방지용 분말 조성물의 함량이 10 중량부 미만이면 미끄럼 방지층의 미끄럼 방지효과가 미미하며, 상기 미끄럼 방지용 분말 조성물의 함량이 20 중량부를 초과하게 되면 미끄럼 방지층의 미끄럼 방지 효과는 크게 향상되지 않으면서 미끄럼 방지용 분말 조성물이 쉽게 이탈될 수 있기 때문에 바람직하지 못하다.If the content of the anti-slip powder composition is less than 10 parts by weight, the anti-slip effect of the anti-slip layer is minimal, and if the content of the anti-slip powder composition exceeds 20 parts by weight, the anti-slip effect of the anti-slip layer is not significantly improved and the anti-slip effect is minimal. This is undesirable because the preventive powder composition can easily come off.
또한, 상기의 성분으로 이루어지는 미끄럼 방지층은 300 내지 1000 마이크로미터의 두께로 형성되는데, 상기 미끄럼 방지층의 두께가 300 마이크로미터 미만이면 미끄럼 방지 효과가 미미하며, 상기 미끄럼 방지층의 두께가 1000 마이크로미터를 초과하게 되면 미끄럼 방지효과는 크게 향상되지 않으면서 제조비용을 지나치게 증가시킬 수 있기 때문에 바람직하지 못하다.In addition, the anti-slip layer made of the above components is formed to a thickness of 300 to 1000 micrometers. If the thickness of the anti-slip layer is less than 300 micrometers, the anti-slip effect is minimal, and if the thickness of the anti-slip layer exceeds 1000 micrometers. This is undesirable because it may excessively increase manufacturing costs without significantly improving the anti-slip effect.
이때, 상기 바닥재용 고분자와 경화제의 성분 및 함량은 상기 하도도막형성단계(S101)에 기재된 내용과 동일하므로, 이에 대한 설명은 생략하기로 한다.At this time, since the components and contents of the polymer for flooring and the curing agent are the same as those described in the base coating film forming step (S101), their description will be omitted.
또한, 하도 도막의 상부면에 미끄럼 방지 바닥재를 도포하는 과정은 롤러, 에어 스프레이 및 에어리스 스프레이 등의 장비를 이용하여 이루어질 수 있으며, 상기 에어리스 스프레이의 노즐은 10 내지 30mm의 팁(tip) 구경을 가질 수 있고, 상기 에어리스 스프레이에 의한 상기 미끄럼 방지 바닥재의 토출 압력은 500 내지 3l00psi일 수 있으며, 상기 에어리스 스프레이의 모터 파워는 4 내지 10HP일 수 있다.In addition, the process of applying anti-slip flooring to the upper surface of the undercoat film can be done using equipment such as rollers, air sprays, and airless sprays, and the nozzle of the airless spray has a tip diameter of 10 to 30 mm. The discharge pressure of the anti-slip flooring by the airless spray may be 500 to 3l00 psi, and the motor power of the airless spray may be 4 to 10 HP.
또한, 상기의 과정으로 이루어지는 미끄럼방지층형성단계(S103)를 통해 형성된 미끄럼방지층은 상온에서 경화시키는 것이 바람직하다.In addition, it is preferable that the anti-slip layer formed through the anti-slip layer forming step (S103) consisting of the above process is cured at room temperature.
상기 상도도막형성단계(S105)는 상기 미끄럼방지층형성단계(S103)를 통해 형성된 미끄럼 방지층의 상부면에 상도 도막을 형성하는 단계로, 상기 미끄럼방지층형성단계(S103)를 통해 형성된 미끄럼 방지층의 상부면에 바닥재용 고분자 100 중량부 및 경화제 30 내지 50 중량부로 이루어진 상도용 도료를 50 내지 100 마이크로미터의 두께로 도포하는 과정으로 이루어지는 것이 바람직하다.The top coat forming step (S105) is a step of forming a top coat on the upper surface of the anti-slip layer formed through the anti-slip layer forming step (S103). The upper surface of the anti-slip layer formed through the anti-slip layer forming step (S103) It is preferable to apply a top paint consisting of 100 parts by weight of a flooring polymer and 30 to 50 parts by weight of a hardener to a thickness of 50 to 100 micrometers.
상기의 과정으로 이루어지는 상도도막형성단계(S105)를 통해 형성되는 상도 도막은 상기 미끄럼방지층형성단계(S103)를 통해 형성된 미끄럼 방지층의 표면을 보호하며, 미끄럼 방지층에 함유된 미끄럼 방지용 분말 조성물이 이탈되는 것을 억제하는 역할을 한다.The top coat formed through the top coat film forming step (S105) consisting of the above process protects the surface of the anti-slip layer formed through the anti-slip layer forming step (S103), and prevents the anti-slip powder composition contained in the anti-slip layer from coming off. It plays a role in suppressing
상기 상도용 도료의 도포 두께가 50 마이크로미터 미만이면 상기의 효과가 미미하며, 상기 상도용 도료의 도포 두께가 100 마이크로미터를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 미끄럼 방지층의 미끄럼 방지효과가 저하될 수 있기 때문에 바람직하지 못하다.If the application thickness of the top coat is less than 50 micrometers, the above effect is minimal, and if the application thickness of the top coat is more than 100 micrometers, the above effect is not significantly improved and the anti-slip effect of the anti-slip layer is reduced. This is undesirable because it may decrease.
이때, 상기 바닥재용 고분자 및 경화제의 성분 및 함량은 상기 하도도막형성단계에 기재된 내용과 동일하므로, 이에 대한 설명은 생략하기로 한다. At this time, since the components and contents of the flooring polymer and hardener are the same as those described in the base coating film forming step, their description will be omitted.
또한, 상기의 과정으로 이루어지는 상도도막형성단계(S105)를 통해 형성된 상도 도막은 상온에서 경화시키는 것이 바람직하다.In addition, it is preferable that the top coat film formed through the top coat film forming step (S105) consisting of the above process is cured at room temperature.
이하에서는, 본 발명에 따른 미끄럼 방지용 분말 조성물을 이용한 바닥 시공 방법 및 그 시공 방법으로 시공된 바닥의 물성을 실시예를 들어 설명하기로 한다.Hereinafter, the floor construction method using the anti-slip powder composition according to the present invention and the physical properties of the floor constructed by the construction method will be described by way of examples.
<제조예 1> 미끄럼 방지용 분말 조성물의 제조<Preparation Example 1> Preparation of anti-slip powder composition
탄산칼슘 100 중량부, 멜라민 150 중량부, 우레아 150 중량부, 무수말레인산 30 중량부 및 폴리프로필렌 30 중량부를 혼합하고 240℃의 온도로 1차 압출한 후에, 1차 압출물 100 중량부에 안료 3 중량부를 혼합하고 185℃의 온도로 2차 압출하고 22℃의 온도로 냉각한 후에 분쇄기에 투입하여 200 내지 400 마이크로미터의 입자크로 분쇄하는 과정을 통해 미끄럼 방지용 분말 조성물을 제조하였다.After mixing 100 parts by weight of calcium carbonate, 150 parts by weight of melamine, 150 parts by weight of urea, 30 parts by weight of maleic anhydride, and 30 parts by weight of polypropylene and performing primary extrusion at a temperature of 240°C, pigment 3 is added to 100 parts by weight of the primary extrudate. An anti-slip powder composition was prepared by mixing parts by weight, secondary extrusion at a temperature of 185°C, cooling to a temperature of 22°C, and then putting it into a grinder and pulverizing it into particles of 200 to 400 micrometers.
<제조예 2> 미끄럼 방지용 분말 조성물의 제조<Preparation Example 2> Preparation of anti-slip powder composition
상기 제조예 1과 동일하게 진행하되, 탄산칼슘 100 중량부, 멜라민 100 중량부, 우레아 100 중량부, 무수말레인산 10 중량부 및 폴리프로필렌 10 중량부를 혼합하여 미끄럼 방지용 분말 조성물을 제조하였다.Proceeding in the same manner as Preparation Example 1, an anti-slip powder composition was prepared by mixing 100 parts by weight of calcium carbonate, 100 parts by weight of melamine, 100 parts by weight of urea, 10 parts by weight of maleic anhydride, and 10 parts by weight of polypropylene.
<제조예 3> 미끄럼 방지용 분말 조성물의 제조<Preparation Example 3> Preparation of anti-slip powder composition
상기 제조예 1과 동일하게 진행하되, 탄산칼슘 100 중량부, 멜라민 200 중량부, 우레아 200 중량부, 무수말레인산 50 중량부 및 폴리프로필렌 50 중량부를 혼합하여 미끄럼 방지용 분말 조성물을 제조하였다.Proceeding in the same manner as Preparation Example 1, an anti-slip powder composition was prepared by mixing 100 parts by weight of calcium carbonate, 200 parts by weight of melamine, 200 parts by weight of urea, 50 parts by weight of maleic anhydride, and 50 parts by weight of polypropylene.
<비교 제조예 1> 미끄럼 방지용 분말 조성물의 제조<Comparative Production Example 1> Preparation of anti-slip powder composition
초고분자량 폴리에틸렌 펠렛을 냉동분쇄한 후 300㎛의 평균 입도 크기를 갖는 초고분자량 폴리에틸렌 분말을 선별하였다. 상기 초고분자량 폴리에틸렌 분말 100 중량부와 메틸트리메톡시실란 5 중량부를 혼합한 후 고속 분산하여 실란으로 코팅된 초고분자량 폴리에틸렌으로 이루어진 미끄럼 방지용 분말 조성물을 제조하였다.After freeze-grinding ultra-high molecular weight polyethylene pellets, ultra-high molecular weight polyethylene powder with an average particle size of 300㎛ was selected. 100 parts by weight of the ultra-high molecular weight polyethylene powder and 5 parts by weight of methyltrimethoxysilane were mixed and dispersed at high speed to prepare an anti-slip powder composition made of ultra-high molecular weight polyethylene coated with silane.
<실시예 1><Example 1>
바닥 시공면(아스팔트)에 이물질을 제거한 후에 바닥재용 고분자(에폭시) 100 중량부 및 경화제(폴리아미드) 40 중량부로 이루어진 하도용 도료를 500 마이크로미터의 두께로 도포한 후에 22℃의 온도로 2시간 동안 경화하여 하도층을 형성하고, 형성된 하도층의 상부면에 바닥재용 고분자(에폭시) 100 중량부, 경화제(폴리아미드) 40 중량부 및 상기 제조예 1을 통해 제조된 미끄럼 방지용 분말 조성물 15 중량부를 혼합하여 이루어진 미끄럼방지용 바닥재 조성물을 400 마이크로미터의 두께로 도포하고 22℃의 온도로 2시간 동안 경화하여 미끄럼 방지층을 형성하고, 형성된 미끄럼 방지층의 상부면에 바닥재용 고분자(에폭시) 100 중량부 및 경화제(폴리아미드) 40 중량부로 이루어진 상도용 도료를 75 마이크로미터의 두께로 도포한 후에 22℃의 온도로 2시간 동안 경화하여 상도층을 형성하는 과정을 통해 바닥을 시공하였다.After removing foreign substances from the floor construction surface (asphalt), a base paint consisting of 100 parts by weight of flooring polymer (epoxy) and 40 parts by weight of hardener (polyamide) was applied to a thickness of 500 micrometers and left at 22°C for 2 hours. After curing to form an undercoat layer, 100 parts by weight of polymer for flooring (epoxy), 40 parts by weight of hardener (polyamide), and 15 parts by weight of the anti-slip powder composition prepared through Preparation Example 1 were added to the upper surface of the formed undercoat layer. The mixed anti-slip flooring composition was applied to a thickness of 400 micrometers and cured at a temperature of 22°C for 2 hours to form an anti-slip layer, and 100 parts by weight of flooring polymer (epoxy) and a hardener were added to the upper surface of the formed anti-slip layer. (Polyamide) 40 parts by weight of top coat paint was applied to a thickness of 75 micrometers and then cured at a temperature of 22°C for 2 hours to form a top coat layer, thereby constructing the floor.
<실시예 2><Example 2>
상기 실시예 1과 동일하게 진행하되, 제조예 2를 통해 제조된 미끄럼 방지용 분말 조성물을 사용하여 바닥을 시공하였다.The same procedure as in Example 1 was carried out, but the floor was constructed using the anti-slip powder composition prepared in Preparation Example 2.
<실시예 3><Example 3>
상기 실시예 1과 동일하게 진행하되, 제조예 3을 통해 제조된 미끄럼 방지용 분말 조성물을 사용하여 바닥을 시공하였다.The same procedure as in Example 1 was carried out, but the floor was constructed using the anti-slip powder composition prepared in Preparation Example 3.
<비교예 1><Comparative Example 1>
바닥 시공면(아스팔트)에 이물질을 제거한 후에 바닥재용 고분자(에폭시) 100 중량부 및 경화제(폴리아미드) 40 중량부로 이루어진 하도용 도료를 500 마이크로미터의 두께로 도포한 후에 22℃의 온도로 2시간 동안 경화하여 하도층을 형성하고, 형성된 하도층의 상부면에 바닥재용 고분자(에폭시) 100 중량부 및 경화제(폴리아미드) 40 중량부를 혼합하여 이루어진 중도용 도료를 400 마이크로미터의 두께로 도포하고 22℃의 온도로 2시간 동안 경화하여 중도층을 형성하고, 형성된 중도층의 상부면에 바닥재용 고분자(에폭시) 100 중량부 및 경화제(폴리아미드) 40 중량부로 이루어진 상도용 도료를 75 마이크로미터의 두께로 도포한 후에 22℃의 온도로 2시간 동안 경화하여 상도층을 형성하는 과정을 통해 바닥을 시공하였다.After removing foreign substances from the floor construction surface (asphalt), a base paint consisting of 100 parts by weight of flooring polymer (epoxy) and 40 parts by weight of hardener (polyamide) was applied to a thickness of 500 micrometers and left at 22°C for 2 hours. After curing for a while to form an undercoat layer, a mid-coat paint made by mixing 100 parts by weight of a flooring polymer (epoxy) and 40 parts by weight of a hardener (polyamide) was applied to the upper surface of the formed undercoat layer to a thickness of 400 micrometers and 22. It was cured for 2 hours at a temperature of ℃ to form a middle layer, and a top coat consisting of 100 parts by weight of flooring polymer (epoxy) and 40 parts by weight of hardener (polyamide) was applied to the upper surface of the formed middle layer to a thickness of 75 micrometers. After applying it, it was cured at a temperature of 22°C for 2 hours to form a top coat layer, thereby constructing the floor.
<비교예 2><Comparative Example 2>
상기 실시예 1과 동일하게 진행하되, 비교 제조예 1을 통해 제조된 미끄럼 방지용 분말 조성물을 사용하여 바닥을 시공하였다.The same procedure as in Example 1 was carried out, but the floor was constructed using the anti-slip powder composition prepared in Comparative Preparation Example 1.
상기 실시예 1 내지 3 및 비교예 1 내지 2를 통해 시공된 바닥면의 미끄럼 방지 저항성과 IZOD 충격강도를 측정하여 아래 표 1에 나타내었다.The anti-slip resistance and IZOD impact strength of the floor surfaces constructed through Examples 1 to 3 and Comparative Examples 1 to 2 were measured and shown in Table 1 below.
{단, 미끄럼 방지 저항성은 KS F 2375의 시험방법을 이용하여 측정하였으며, 상기 IZOD 충격강도는 ASTM D 256의 시험방법을 이용하여 측정하였다.}{However, anti-slip resistance was measured using the test method of KS F 2375, and the IZOD impact strength was measured using the test method of ASTM D 256.}
<표 1><Table 1>
상기 표 1에 나타낸 것처럼, 본 발명의 실시예 1 내지 3을 통해 미끄럼 방지 시공이 이루어진 바닥면은 비교예 1 내지 2를 통해 미끄럼 방지 시공이 이루어진 바닥면에 비해 미끄럼 방지 저항성이 월등하게 향상되는 것을 알 수 있다.As shown in Table 1, the anti-slip resistance of the floor surface on which anti-slip construction was performed through Examples 1 to 3 of the present invention was significantly improved compared to the floor surface on which anti-slip construction was performed through Comparative Examples 1 and 2. Able to know.
또한, 본 발명의 실시예 1 내지 3을 통해 미끄럼 방지 시공이 이루어진 바닥면은 비교예 2를 통해 미끄럼 방지 시공이 이루어진 바닥면에 비해 미끄럼 방지 효과 뿐만 아니라, IZOD 충격강도가 월등하게 향상되는 것을 알 수 있다.In addition, it was found that the floor surface on which anti-slip construction was performed through Examples 1 to 3 of the present invention not only had an anti-slip effect, but also significantly improved the IZOD impact strength compared to the floor surface on which anti-slip construction was performed through Comparative Example 2. You can.
따라서, 본 발명에 따른 미끄럼 방지용 분말 조성물 및 그 조성물을 이용한 바닥용 표면 마감재의 시공 방법은 미끄럼 방지 저항성과 내충격강도가 우수하며 시공비가 저렴할 뿐만 아니라, 도막과의 부착성이 강력한 미끄럼 방지용 분말이 사용되어 우수한 내구성을 나타내는 바닥면을 제공한다.Therefore, the anti-slip powder composition according to the present invention and the method of constructing a floor surface finishing material using the composition use an anti-slip powder that not only has excellent anti-slip resistance and impact resistance, has low construction costs, and has strong adhesion to the coating film. This provides a floor surface with excellent durability.
S101 ; 하도도막형성단계
S103 ; 미끄럼방지층형성단계
S105 ; 상도도막형성단계S101 ; Undercoat film formation stage
S103 ; Anti-slip layer formation stage
S105 ; Top coat film formation stage
Claims (8)
200 내지 1000 마이크로미터의 입자크기를 나타내는 것을 특징으로 하는 미끄럼 방지용 분말 조성물.
100 parts by weight of calcium carbonate, 100 to 200 parts by weight of melamine, 100 to 200 parts by weight of urea, 10 to 50 parts by weight of maleic anhydride, and 10 to 50 parts by weight of polypropylene are mixed and first extruded at a temperature of 210 to 270 ° C. It is manufactured by mixing 1 to 5 parts by weight of pigment with 100 parts by weight of the primary extrudate, followed by secondary extrusion, cooling and grinding at a temperature of 180 to 190 ° C.
An anti-slip powder composition characterized by a particle size of 200 to 1000 micrometers.
상기 하도도막형성단계를 통해 형성된 하도 도막의 상부면에 바닥재용 고분자, 경화제 및 청구항 1을 통해 제조된 미끄럼 방지용 분말 조성물로 이루어진 미끄럼방지용 바닥재 조성물을 도포하는 미끄럼방지층형성단계; 및
상기 미끄럼방지층형성단계를 통해 형성된 미끄럼 방지층의 상부면에 상도 도막을 형성하는 상도도막형성단계;로 이루어지며,
상기 하도도막형성단계는 바닥재용 고분자 100 중량부 및 경화제 30 내지 50 중량부로 이루어진 하도용 도료를 100 내지 1000 마이크로미터의 두께로 도포하여 이루어지고,
상기 미끄럼방지층형성단계는 바닥재용 고분자 100 중량부, 경화제 30 내지 50 중량부 및 상기 미끄럼 방지용 분말 조성물 10 내지 20 중량부로 이루어진 미끄럼방지용 바닥재 조성물을 300 내지 1000 마이크로미터의 두께로 도포하여 이루어지며,
상기 상도도막형성단계는 상기 미끄럼방지층형성단계를 통해 형성된 미끄럼 방지층의 상부면에 바닥재용 고분자 100 중량부 및 경화제 30 내지 50 중량부로 이루어진 상도용 도료를 50 내지 100 마이크로미터의 두께로 도포하여 이루어지고,
상기 바닥재용 고분자는 에폭시, 우레탄, 메틸아크릴레이트 및 메틸메타아크릴레이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지며,
상기 경화제는 에폭시 경화제, 우레탄 경화제 및 아크릴 경화제로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 지는 것을 특징으로 하는 미끄럼 방지용 분말 조성물을 이용한 바닥용 표면 마감재의 시공 방법.
An undercoat film forming step of forming an undercoat film on the construction surface;
An anti-slip layer forming step of applying an anti-slip flooring composition consisting of a flooring polymer, a curing agent, and an anti-slip powder composition prepared according to claim 1 on the upper surface of the undercoat film formed through the undercoat film forming step; and
It consists of a top coat film forming step of forming a top coat film on the upper surface of the anti-slip layer formed through the anti-slip layer forming step,
The base coating film forming step is performed by applying a base paint consisting of 100 parts by weight of a flooring polymer and 30 to 50 parts by weight of a hardener to a thickness of 100 to 1000 micrometers,
The anti-slip layer forming step is achieved by applying an anti-slip flooring composition consisting of 100 parts by weight of a flooring polymer, 30 to 50 parts by weight of a curing agent, and 10 to 20 parts by weight of the anti-slip powder composition to a thickness of 300 to 1000 micrometers,
The top coat film forming step is achieved by applying a top coat paint consisting of 100 parts by weight of a flooring polymer and 30 to 50 parts by weight of a hardener to a thickness of 50 to 100 micrometers on the upper surface of the anti-slip layer formed through the anti-slip layer forming step. ,
The polymer for flooring consists of one or more selected from the group consisting of epoxy, urethane, methyl acrylate, and methyl methacrylate,
A method of constructing a floor surface finish using an anti-slip powder composition, characterized in that the curing agent is made of one or more selected from the group consisting of an epoxy curing agent, a urethane curing agent, and an acrylic curing agent.
상기 바닥재용 고분자에는 모르타르가 더 함유되는 것을 특징으로 하는 미끄럼 방지용 분말 조성물을 이용한 바닥용 표면 마감재의 시공 방법.In claim 5,
A method of constructing a surface finishing material for flooring using an anti-slip powder composition, characterized in that the polymer for flooring further contains mortar.
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