KR102639702B1 - Wood furniture panel with excellent flame retardancy and manufacturing method thereof - Google Patents
Wood furniture panel with excellent flame retardancy and manufacturing method thereof Download PDFInfo
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- KR102639702B1 KR102639702B1 KR1020220136370A KR20220136370A KR102639702B1 KR 102639702 B1 KR102639702 B1 KR 102639702B1 KR 1020220136370 A KR1020220136370 A KR 1020220136370A KR 20220136370 A KR20220136370 A KR 20220136370A KR 102639702 B1 KR102639702 B1 KR 102639702B1
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- South Korea
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- flame retardant
- excellent flame
- wooden furniture
- retardant performance
- fire extinguishing
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000002023 wood Substances 0.000 title abstract description 7
- 239000003063 flame retardant Substances 0.000 claims abstract description 56
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000000853 adhesive Substances 0.000 claims abstract description 34
- 230000001070 adhesive effect Effects 0.000 claims abstract description 34
- 239000003094 microcapsule Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 12
- 239000011737 fluorine Substances 0.000 claims abstract description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 150000005206 1,2-dihydroxybenzenes Chemical class 0.000 claims description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 10
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 10
- 239000000123 paper Substances 0.000 claims description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 10
- 229920000877 Melamine resin Polymers 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 8
- 239000008199 coating composition Substances 0.000 claims description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 7
- 239000011094 fiberboard Substances 0.000 claims description 5
- GRVMOMUDALILLH-UHFFFAOYSA-N 1,1,1,2,4,5,5,5-octafluoro-2,4-bis(trifluoromethyl)pentan-3-one Chemical compound FC(F)(F)C(F)(C(F)(F)F)C(=O)C(F)(C(F)(F)F)C(F)(F)F GRVMOMUDALILLH-UHFFFAOYSA-N 0.000 claims description 4
- ABQIAHFCJGVSDJ-UHFFFAOYSA-N 1,1,1,3,4,4,4-heptafluoro-3-(trifluoromethyl)butan-2-one Chemical compound FC(F)(F)C(=O)C(F)(C(F)(F)F)C(F)(F)F ABQIAHFCJGVSDJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920002396 Polyurea Polymers 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 238000003860 storage Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 7
- 239000004114 Ammonium polyphosphate Substances 0.000 description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 description 6
- 239000003522 acrylic cement Substances 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- DXRKLUVKXMAMOV-UHFFFAOYSA-N 3-heptadecylcatechol Chemical compound CCCCCCCCCCCCCCCCCC1=CC=CC(O)=C1O DXRKLUVKXMAMOV-UHFFFAOYSA-N 0.000 description 2
- HUVBUJGLRMRTSF-UHFFFAOYSA-N 4-heptadecylbenzene-1,2-diol Chemical compound CCCCCCCCCCCCCCCCCC1=CC=C(O)C(O)=C1 HUVBUJGLRMRTSF-UHFFFAOYSA-N 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- RMTXUPIIESNLPW-UHFFFAOYSA-N 1,2-dihydroxy-3-(pentadeca-8,11-dienyl)benzene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1O RMTXUPIIESNLPW-UHFFFAOYSA-N 0.000 description 1
- QARRXYBJLBIVAK-UEMSJJPVSA-N 3-[(8e,11e)-pentadeca-8,11-dienyl]benzene-1,2-diol;3-[(8e,11e)-pentadeca-8,11,14-trienyl]benzene-1,2-diol;3-[(8e,11e,13e)-pentadeca-8,11,13-trienyl]benzene-1,2-diol;3-[(e)-pentadec-8-enyl]benzene-1,2-diol;3-pentadecylbenzene-1,2-diol Chemical compound CCCCCCCCCCCCCCCC1=CC=CC(O)=C1O.CCCCCC\C=C\CCCCCCCC1=CC=CC(O)=C1O.CCC\C=C\C\C=C\CCCCCCCC1=CC=CC(O)=C1O.C\C=C\C=C\C\C=C\CCCCCCCC1=CC=CC(O)=C1O.OC1=CC=CC(CCCCCCC\C=C\C\C=C\CC=C)=C1O QARRXYBJLBIVAK-UEMSJJPVSA-N 0.000 description 1
- IYROWZYPEIMDDN-UHFFFAOYSA-N 3-n-pentadec-8,11,13-trienyl catechol Natural products CC=CC=CCC=CCCCCCCCC1=CC=CC(O)=C1O IYROWZYPEIMDDN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000227 bioadhesive Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000003256 environmental substance Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- DQTMTQZSOJMZSF-UHFFFAOYSA-N urushiol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1O DQTMTQZSOJMZSF-UHFFFAOYSA-N 0.000 description 1
- 239000011276 wood tar Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/02—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
- A62D1/0021—Microcapsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/06—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
- B32B7/027—Thermal properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/028—Paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Business, Economics & Management (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Management (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Laminated Bodies (AREA)
- Fireproofing Substances (AREA)
Abstract
본 발명은 판재; 상기 판재의 일면 또는 양면에 접착 구비된 표면재; 및 상기 판재와 표면재를 접착시키기 위한 접착제;를 포함하는 목재가구로, 상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인 방염성능이 우수한 목재가구용 패널과 이의 제조 방법에 관한 것이다.The present invention relates to a plate; A surface material attached to one or both sides of the plate; and an adhesive for bonding the board and the surface material, wherein the adhesive contains fire extinguishing microcapsules with a fluorine-based fire extinguishing agent embedded therein. A panel for wood furniture with excellent flame retardant performance and a method for manufacturing the same. It's about.
Description
본 발명은 방염 성능이 우수한 목재가구용 패널 및 이의 제조 방법에 관한 것이다.The present invention relates to a wooden furniture panel with excellent flame retardant performance and a method of manufacturing the same.
근래에 들어서는 석유화학 문명의 발전으로 인한 유기화학소재의 인테리어 마감재 및 가구·집기류들의 사용이 증가하고 있는 추세에 있으며, 목재, 합판, 중밀도섬유판, 종이 등은 가구 및 건축 내장재로 많이 이용되고 있다.In recent years, due to the development of petrochemical civilization, the use of organic chemical materials as interior finishing materials and furniture and furniture has been increasing, and wood, plywood, medium-density fiberboard, paper, etc. are widely used as furniture and building interior materials. .
목재는 가열하면 목타르, 목가스로 분해되고 가연성 목가스가 산화되면서 순식간에 건축물을 연소시켜 재산과 인명 피해를 야기 시키는 주요 원인이 되고 있음따라 효과적인 방염 처리가 필요하다.When wood is heated, it decomposes into wood tar and wood gas, and the flammable wood gas oxidizes, quickly burning buildings and causing damage to property and people, so effective flame retardant treatment is necessary.
방염이란 화재의 위험이 높은 물질에 불연 처리를 하여 불에 잘 타지 않게 하는 것으로 화재 초기점화시간을 지연시키고 화재전파속도를 억제하기 위한 것이다.Flame retardation is a process of treating materials with a high risk of fire to make them less flammable, and is intended to delay the initial ignition time of a fire and suppress the speed of fire spread.
기존에는 암모늄 폴리포스페이트와 같은 성분을 포함하는 방염액을 목재 보드의 표면에 도포하여 방염 코팅층을 형성함으로써 방염성을 확보해 왔다. 그러나, 암모늄 폴리포스페이트와 같은 물질은 방염 성능이 우수하고 다른 수지와의 혼용성 또한 좋은 장점이 있으나, 고가로 적용 시 제조원가 상승의 원인이 되며, 목재 보드에 사용 시 휨강도, 접착강도 등의 보드 물성 값에 나쁜 영향을 주는 문제점이 있었다.Previously, flame retardancy was secured by applying a flame retardant solution containing ingredients such as ammonium polyphosphate to the surface of a wooden board to form a flame retardant coating layer. However, materials such as ammonium polyphosphate have excellent flame retardant performance and good compatibility with other resins, but they are expensive and cause an increase in manufacturing costs when applied, and when used on wooden boards, board physical properties such as bending strength and adhesive strength are affected. There was a problem that had a negative effect on the value.
한편, 이에 대한 유사 선행문헌으로는 대한민국 등록특허공보 제110-1235125호가 제시되어 있다.Meanwhile, Republic of Korea Patent Publication No. 110-1235125 is presented as a similar prior document.
상기와 같은 문제점을 해결하기 위하여 본 발명은 방염 성능이 우수하면서도 판재의 물성이 크게 저하되지 않는 방염 목재가구용 패널 및 이의 제조 방법을 제공하는 것을 목적으로 한다.In order to solve the above problems, the purpose of the present invention is to provide a flame-retardant wooden furniture panel and a method of manufacturing the same, which have excellent flame-retardant performance and do not significantly deteriorate the physical properties of the board.
다만 상기 목적은 예시적인 것으로, 본 발명의 기술적 사상은 이에 한정되는 것은 아니다.However, the above object is illustrative, and the technical idea of the present invention is not limited thereto.
상기 목적을 달성하기 위한 본 발명의 일 양태는 판재; 상기 판재의 일면 또는 양면에 접착 구비된 표면재; 및 상기 판재와 표면재를 접착시키기 위한 접착제;를 포함하는 목재가구로, 상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인, 방염성능이 우수한 목재가구용 패널에 관한 것이다.One aspect of the present invention for achieving the above object is a plate; A surface material attached to one or both sides of the plate; and an adhesive for adhering the plate and the surface material, wherein the adhesive contains fire extinguishing microcapsules with a fluorine-based fire extinguishing agent embedded therein. The present invention relates to a wooden furniture panel with excellent flame retardant performance.
상기 일 양태에 있어, 상기 불소계 소화약제는 CF3CF2C(O)CF(CF3)2, (CF3)2CFC(O)CF(CF3)2, CF3(CF2)2C(O)CF(CF3)2, CF3(CF2)3C(O)CF(CF3)2, CF3(CF2)5C(O)CF3, CF3CF2C(O)CF2CF2CF3, CF3C(O)CF(CF3)2, C2F5C(O)CF(CF3)2, (CF3)2CFC(O)CF2Cl 및 CF3OCF2CF2C(O)CF(CF3)2로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있다.In one aspect, the fluorine-based fire extinguishing agent is CF 3 CF 2 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 2 C (O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 3 C(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 5 C(O)CF 3 , CF 3 CF 2 C(O) CF 2 CF 2 CF 3 , CF 3 C(O)CF(CF 3 ) 2 , C 2 F 5 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF 2 Cl and CF 3 It may include one or more species selected from the group consisting of OCF 2 CF 2 C(O)CF(CF 3 ) 2 .
상기 일 양태에 있어, 상기 소화용 마이크로캡슐의 쉘은 폴리우레탄, 폴리우레아, 폴리올레핀, 폴리아미드 및 폴리에스테르로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있다.In the above aspect, the shell of the extinguishing microcapsule may include one or more selected from the group consisting of polyurethane, polyurea, polyolefin, polyamide, and polyester.
상기 일 양태에 있어, 상기 판재는 파티클보드 또는 중밀도 섬유판일 수 있다.In the above aspect, the board may be particleboard or medium-density fiberboard.
상기 일 양태에 있어, 상기 표면재는 저압 멜라민 함침지(LPM) 또는 고압 멜라민 함침지(HPM)일 수 있다.In the above aspect, the surface material may be low pressure melamine impregnated paper (LPM) or high pressure melamine impregnated paper (HPM).
상기 일 양태에 있어, 상기 판재는 송진, 인계 난연제 및 카테콜 유도체를 포함하는 코팅조성물로 코팅된 것일 수 있다.In the above aspect, the plate may be coated with a coating composition containing rosin, a phosphorus-based flame retardant, and a catechol derivative.
또한, 본 발명의 다른 일 양태는 전술한 목재가구용 패널로 제조된 방염성능이 우수한 목재가구에 관한 것으로, 상기 목재가구는 주방가구 또는 수납가구일 수 있다.In addition, another aspect of the present invention relates to wooden furniture having excellent flame retardant performance manufactured from the above-described wooden furniture panel, and the wooden furniture may be kitchen furniture or storage furniture.
또한, 본 발명의 또 다른 일 양태는 전술한 목재가구용 패널의 제조 방법에 관한 것으로, 상세하게 판재 상에 접착제를 도포하여 표면재를 접착시키는 단계;를 포함하며, 상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인, 방염성능이 우수한 목재가구용 패널의 제조 방법에 관한 것이다.In addition, another aspect of the present invention relates to a method for manufacturing the above-described wooden furniture panel, including the step of applying an adhesive on a board to adhere the surface material, wherein the adhesive has a fluorine-based fire extinguishing agent inside. It relates to a method of manufacturing a wooden furniture panel with excellent flame retardant performance, which contains built-in fire extinguishing microcapsules.
본 발명에 따른 목재가구용 패널은 접착제에 소화용 마이크로캡슐이 함유되어 있어 열원과 접촉 시 우수한 방염 성능을 제공할 수 있으며, 다른 방염처리 방식과 달리 접착제에 소화용 마이크로캡슐이 첨가되는 방식임에 따라 판재의 휨강도, 접착강도 등 물성이 크게 저하되지 않을 수 있다.The wooden furniture panel according to the present invention contains fire extinguishing microcapsules in the adhesive, so it can provide excellent flame retardant performance when in contact with a heat source. Unlike other flame retardant treatment methods, fire extinguishing microcapsules are added to the adhesive. The physical properties such as bending strength and adhesive strength of the plate may not be significantly reduced.
이하 본 발명에 따른 방염성능이 우수한 목재가구용 패널 및 이의 제조 방법에 대하여 상세히 설명한다. 다음에 소개되는 도면들은 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 예로서 제공되는 것이다. 따라서, 본 발명은 이하 제시되는 도면들에 한정되지 않고 다른 형태로 구체화될 수도 있으며, 이하 제시되는 도면들은 본 발명의 사상을 명확히 하기 위해 과장되어 도시될 수 있다. 이때, 사용되는 기술 용어 및 과학 용어에 있어서 다른 정의가 없다면, 이 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 통상적으로 이해하고 있는 의미를 가지며, 하기의 설명 및 첨부 도면에서 본 발명의 요지를 불필요하게 흐릴 수 있는 공지 기능 및 구성에 대한 설명은 생략한다.Hereinafter, the wooden furniture panel with excellent flame retardant performance and its manufacturing method according to the present invention will be described in detail. The drawings introduced below are provided as examples so that the idea of the present invention can be sufficiently conveyed to those skilled in the art. Accordingly, the present invention is not limited to the drawings presented below and may be embodied in other forms, and the drawings presented below may be exaggerated to clarify the spirit of the present invention. At this time, if there is no other definition in the technical and scientific terms used, they have the meaning commonly understood by those skilled in the art to which this invention pertains, and the gist of the present invention is summarized in the following description and attached drawings. Descriptions of known functions and configurations that may be unnecessarily obscure are omitted.
본 발명의 일 양태는 판재; 상기 판재의 일면 또는 양면에 접착 구비된 표면재; 및 상기 판재와 표면재를 접착시키기 위한 접착제;를 포함하는 목재가구로, 상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인, 방염성능이 우수한 목재가구용 패널에 관한 것이다.One aspect of the present invention is a plate; A surface material attached to one or both sides of the plate; and an adhesive for adhering the plate and the surface material, wherein the adhesive contains fire extinguishing microcapsules with a fluorine-based fire extinguishing agent embedded therein. The present invention relates to a wooden furniture panel with excellent flame retardant performance.
이처럼, 본 발명에 따른 목재가구용 패널은 접착제에 소화용 마이크로캡슐이 함유되어 있어 열원과 접촉 시 우수한 방염 성능을 제공할 수 있으며, 다른 방염처리 방식과 달리 접착제에 소화용 마이크로캡슐이 첨가되는 방식임에 따라 판재의 휨강도, 접착강도 등 물성이 크게 저하되지 않을 수 있다.As such, the wooden furniture panel according to the present invention contains fire extinguishing microcapsules in the adhesive, so it can provide excellent flame retardant performance when in contact with a heat source. Unlike other flame retardant treatment methods, fire extinguishing microcapsules are added to the adhesive. Accordingly, the physical properties such as bending strength and adhesive strength of the plate may not be significantly reduced.
이하, 본 발명의 일 예에 따른 방염성능이 우수한 목재가구용 패널에 대하여 보다 상세히 설명한다.Hereinafter, a panel for wooden furniture with excellent flame retardant performance according to an example of the present invention will be described in more detail.
먼저, 본 발명의 일 예에 있어, 상기 판재는 당업계에서 통상적으로 사용되는 것이라면 특별히 한정하지 않고 사용할 수 있으며, 구체적으로 예를 들면 상기 판재는 파티클보드(PB) 또는 중밀도 섬유판(MDF) 등일 수 있다.First, in one example of the present invention, the plate can be used without particular limitation as long as it is commonly used in the industry. Specifically, for example, the plate may be particleboard (PB) or medium density fiberboard (MDF). You can.
바람직하게, 상기 판재는 송진, 인계 난연제 및 카테콜 유도체를 포함하는 코팅조성물로 코팅된 것일 수 있다. 상기 송진은 천연접착제 역할을 하며, 인계 난연제 및 카테콜 유도체는 방염 역할을 하여, 패널의 방염 및 내화성을 더욱 향상시킬 수 있다.Preferably, the plate may be coated with a coating composition containing rosin, a phosphorus-based flame retardant, and a catechol derivative. The rosin acts as a natural adhesive, and the phosphorus-based flame retardant and catechol derivative act as flame retardants, which can further improve the flame resistance and fire resistance of the panel.
상세하게, 상기 카테콜 유도체는 우루시올(urushiol), 라콜(laccol) 및 티치올(thitsiol)로 이루어진 군에서 선택되는 1종 이상일 수 있으며, 방염, 내화성 및 항균 성능을 제공할 수 있다.In detail, the catechol derivative may be one or more selected from the group consisting of urushiol, laccol, and thitsiol, and may provide flame retardancy, fire resistance, and antibacterial performance.
상기 인계 난연제는 인을 포함하는 통상의 난연제를 이용할 수 있으며, 좋게는 암모늄 폴리포스페이트, 제1인산암모늄 및 제2인산암모늄으로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있고, 좋게는 암모늄 폴리포스페이트를 포함할 수 있다. 상기 암모늄 폴리포스페이트를 이용함으로써 송진 및 카테콜 유도체와 높은 상용성을 나타내며 높은 방염효과를 나타내는 특징이 있다. The phosphorus-based flame retardant may be a conventional flame retardant containing phosphorus, preferably containing at least one selected from the group consisting of ammonium polyphosphate, ammonium monophosphate, and ammonium diphosphate, preferably ammonium polyphosphate. May contain phosphate. By using the ammonium polyphosphate, it has the characteristic of showing high compatibility with rosin and catechol derivatives and showing a high flame retardant effect.
상기 코팅조성물은 송진 100 중량부 대비 6 내지 12 중량부의 인계 난연제 및 10 내지 50 중량부의 카테콜 유도체를 포함할 수 있으며, 보다 좋게는 7 내지 10 중량부의 인계 난연제 및 20 내지 35 중량부의 카테콜 유도체를 포함할 수 있다. 인계 난연제 및 카테콜 유도체를 소량 포함할 경우 방염 효과가 저하될 수 있고, 인계 난연제를 다량 포함할 경우 상대적으로 송진 및 카테콜 유도체의 비율이 낮아져 결착력 저하를 유발할 수 있다. The coating composition may include 6 to 12 parts by weight of a phosphorus-based flame retardant and 10 to 50 parts by weight of a catechol derivative, based on 100 parts by weight of rosin, and more preferably 7 to 10 parts by weight of a phosphorus-based flame retardant and 20 to 35 parts by weight of a catechol derivative. may include. If a small amount of phosphorus-based flame retardant and catechol derivatives are included, the flame retardant effect may be reduced, and if a large amount of phosphorus-based flame retardant is included, the ratio of rosin and catechol derivatives may be relatively low, which may cause a decrease in binding ability.
본 발명의 일 예에 있어, 상기 표면재는 당업계에서 통상적으로 사용되는 것이라면 특별히 한정하지 않고 사용할 수 있으며, 구체적으로 예를 들면 상기 표면재는 저압 멜라민 함침지(LPM) 또는 고압 멜라민 함침지(HPM)일 수 있다. 이와 같은 LPM 또는 HPM은 멜라민 수지를 함침시켜 제조된 것으로 약간의 방염 성능을 가지고 있으며, 함침 시 멜라민 수지에 인계 난연제 등을 추가하여 함침할 시 방염 성능을 더욱 향상시킬 수 있다.In one example of the present invention, the surface material can be used without particular limitation as long as it is commonly used in the industry. Specifically, for example, the surface material is low pressure melamine impregnated paper (LPM) or high pressure melamine impregnated paper (HPM). It can be. Such LPM or HPM is manufactured by impregnating melamine resin and has some flame retardant performance, and the flame retardant performance can be further improved by adding a phosphorus-based flame retardant to the melamine resin during impregnation.
본 발명의 일 예에 있어, 상기 접착제는 판재와 표면재를 접착시키는 역할과 동시에 패널에 강한 방염 및 소화 성능을 제공하기 위한 것으로, 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것일 수 있다. In one example of the present invention, the adhesive serves to bond the plate and the surface material and at the same time provides strong flame retardant and fire extinguishing performance to the panel, and may contain a fire extinguishing microcapsule with a fluorine-based fire extinguishing agent embedded therein. there is.
구체적인 일 예시로, 상기 불소계 소화약제는 CF3CF2C(O)CF(CF3)2, (CF3)2CFC(O)CF(CF3)2, CF3(CF2)2C(O)CF(CF3)2, CF3(CF2)3C(O)CF(CF3)2, CF3(CF2)5C(O)CF3, CF3CF2C(O)CF2CF2CF3, CF3C(O)CF(CF3)2, C2F5C(O)CF(CF3)2, (CF3)2CFC(O)CF2Cl 및 CF3OCF2CF2C(O)CF(CF3)2로 이루어진 군에서 선택되는 1종 이상일 수 있으며, 바람직하게는 CF3CF2C(O)CF(CF3)2일 수 있다. CF3CF2C(O)CF(CF3)2는 다른 할로겐 화합물의 소화약제들과 달리 오존층 파괴 환경 물질로 분류되지 않은 친환경 소화약제로, 열원과 접촉 시 열분해로 인해 부피가 팽창하면 열원 주변의 산소와의 반응을 지속적으로 차단하고, 끓는점이 낮아 열에너지를 흡수함에 따라 발열점에 도달하는 것을 억제하는 효과를 가진다.As a specific example, the fluorine-based fire extinguishing agent is CF 3 CF 2 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 2 C ( O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 3 C(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 5 C(O)CF 3 , CF 3 CF 2 C(O)CF 2 CF 2 CF 3 , CF 3 C(O)CF(CF 3 ) 2 , C 2 F 5 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF 2 Cl and CF 3 OCF 2 CF 2 C(O)CF(CF 3 ) 2 It may be one or more selected from the group consisting of CF 3 CF 2 C(O)CF(CF 3 ) 2 . CF 3 CF 2 C(O)CF(CF 3 ) 2 is an eco-friendly fire extinguishing agent that, unlike other halogen compound fire extinguishing agents, is not classified as an ozone-depleting environmental substance. When it comes in contact with a heat source, it expands in volume due to thermal decomposition, causing it to evaporate around the heat source. It continuously blocks the reaction with oxygen and has a low boiling point, which has the effect of preventing it from reaching the heating point as it absorbs heat energy.
또한, 상기 소화용 마이크로캡슐의 쉘은 폴리우레탄, 폴리우레아, 폴리올레핀, 폴리아미드 및 폴리에스테르로 이루어진 군에서 선택되는 1종 이상을 포함할 수 있다. 상기 쉘은 화재로 인지되는 100℃ 이상에서 연화됨과 동시에 소화약제의 팽창에 의해 파열됨으로써 그 소화약제를 외부로 분사시키며, 100℃ 이상에서의 파열을 위해 바람직하게는 50~2000 ㎚의 두께를 가질 수 있다. 또한, 상기 소화용 마이크로캡슐의 크기는 10 내지 500 ㎛일 수 있으며, 보다 상세하게 50 내지 200 ㎛일 수 있다.Additionally, the shell of the extinguishing microcapsule may include one or more selected from the group consisting of polyurethane, polyurea, polyolefin, polyamide, and polyester. The shell softens above 100°C, which is recognized as a fire, and at the same time ruptures due to expansion of the fire extinguishing agent, thereby spraying the fire extinguishing agent to the outside. For rupture above 100°C, it preferably has a thickness of 50 to 2000 nm. You can. Additionally, the size of the extinguishing microcapsule may be 10 to 500 ㎛, more specifically 50 to 200 ㎛.
한편, 상기 접착제는 목재용 접착제라면 특별히 한정하지 않고 사용할 수 있으며, 바람직한 일 예로 아크릴계 접착제를 사용할 수 있다. 아크릴계 접착제를 사용하여 판재와 표면재를 접착할 경우 두 기재가 서로 단단히 접착되어 쉽게 떨어지지 않을 수 있다.Meanwhile, the adhesive can be used without particular limitation as long as it is an adhesive for wood, and a preferred example is an acrylic adhesive. When using an acrylic adhesive to bond a board and a surface material, the two substrates are firmly adhered to each other and may not easily separate.
바람직하게, 뛰어난 접착력 및 우수한 방염 성능을 확보하기 위한 측면에서, 상기 접착제는 아크릴계 접착제 100 중량부에 대하여 소화용 마이크로캡슐 3 내지 20 중량부를 포함할 수 있으며, 보다 좋게는 소화용 마이크로캡슐 10 내지 15 중량부를 포함할 수 있다. 소화용 마이크로캡슐이 너무 소량 첨가될 시 충분한 방염 및 소화 능력을 발휘할 수 없으며, 소화용 마이크로캡슐 너무 과량 첨가될 시 판재와 표면재 간 접착력이 저하될 수 있다.Preferably, in terms of ensuring excellent adhesion and excellent flame retardant performance, the adhesive may include 3 to 20 parts by weight of fire extinguishing microcapsules per 100 parts by weight of the acrylic adhesive, and more preferably 10 to 15 parts by weight of fire extinguishing microcapsules. It may include weight parts. If too little fire extinguishing microcapsules are added, sufficient flame retardant and fire extinguishing abilities cannot be achieved, and if too much fire extinguishing microcapsules are added, the adhesion between the plate and the surface material may decrease.
이와 같은 목재가구용 패널을 가공하여 목재가구를 제조할 수 있으며, 구체적으로 예를 들면 상기 목재가구는 주방가구 또는 수납가구 등일 수 있으나, 반드시 이에 한정되는 것은 아니다.Wooden furniture can be manufactured by processing such wooden furniture panels. Specifically, for example, the wooden furniture may be kitchen furniture or storage furniture, but is not necessarily limited thereto.
또한, 본 발명의 또 다른 일 양태는 전술한 목재가구용 패널의 제조 방법에 관한 것으로, 상세하게 판재 상에 접착제를 도포하여 표면재를 접착시키는 단계;를 포함하며, 상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인, 방염성능이 우수한 목재가구용 패널의 제조 방법에 관한 것이다.In addition, another aspect of the present invention relates to a method for manufacturing the above-described wooden furniture panel, including the step of applying an adhesive on a board to adhere the surface material, wherein the adhesive has a fluorine-based fire extinguishing agent inside. It relates to a method of manufacturing a wooden furniture panel with excellent flame retardant performance, which contains built-in fire extinguishing microcapsules.
이때, 목재가구용 패널의 구체적인 구성 성분 및 함량은 전술한 바와 동일함에 따라 생략하도록 한다.At this time, the specific components and contents of the wooden furniture panel are omitted as they are the same as described above.
이하, 실시예를 통해 본 발명에 따른 방염성능이 우수한 목재가구용 패널 및 이의 제조 방법에 대하여 더욱 상세히 설명한다. 다만 하기 실시예는 본 발명을 상세히 설명하기 위한 하나의 참조일 뿐 본 발명이 이에 한정되는 것은 아니며, 여러 형태로 구현될 수 있다. Hereinafter, the wooden furniture panel with excellent flame retardant performance and its manufacturing method according to the present invention will be described in more detail through examples. However, the following examples are only a reference for explaining the present invention in detail, and the present invention is not limited thereto, and may be implemented in various forms.
또한 달리 정의되지 않은 한, 모든 기술적 용어 및 과학적 용어는 본 발명이 속하는 당업자 중 하나에 의해 일반적으로 이해되는 의미와 동일한 의미를 갖는다. 본원에서 설명에 사용되는 용어는 단지 특정 실시예를 효과적으로 기술하기 위함이고 본 발명을 제한하는 것으로 의도되지 않는다. 또한 명세서에서 특별히 기재하지 않은 첨가물의 단위는 중량%일 수 있다.Additionally, unless otherwise defined, all technical and scientific terms have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention pertains. The terminology used in the description herein is merely to effectively describe particular embodiments and is not intended to limit the invention. Additionally, the unit of additives not specifically described in the specification may be weight percent.
[실시예 1][Example 1]
내부에 CF3CF2C(O)CF(CF3)2이 내장된 소화용 마이크로캡슐(쉘 두께 1 ㎛, 크기 150 ㎛) 1 중량부를 아크릴계 접착제 100 중량부에 혼합하여 접착제 조성물을 준비하였다.An adhesive composition was prepared by mixing 1 part by weight of a fire extinguishing microcapsule (shell thickness 1 ㎛, size 150 ㎛) containing CF 3 CF 2 C(O)CF(CF 3 ) 2 with 100 parts by weight of an acrylic adhesive.
별도로, 송진 100 중량부에 암모늄 폴리포스페이트 8 중량부 및 티치올(thitsiol) 27 중량부를 혼합하여 코팅조성물을 준비한 후, 이를 판재에 도포하여 충분히 건조시켜 0.5 ㎜ 두께의 코팅층이 형성된 판재를 준비하였다.Separately, a coating composition was prepared by mixing 100 parts by weight of rosin with 8 parts by weight of ammonium polyphosphate and 27 parts by weight of thitsiol, and then applied to a plate and dried sufficiently to prepare a plate with a coating layer of 0.5 mm thick.
코티층이 형성된 판재 상에 준비된 접착제 조성물을 도포한 후 고압 멜라민 함침지(HPM)를 접착하여 패널 샘플을 제조하였다.A panel sample was prepared by applying the prepared adhesive composition on a plate with a coated layer and then attaching high-pressure melamine impregnated paper (HPM).
[실시예 1 내지 10 및 비교예 1][Examples 1 to 10 and Comparative Example 1]
하기 표 1에 나타낸 바와 같이, 구성 성분의 함량을 달리한 것 외 모든 과정을 실시예 1과 동일하게 수행하였다.As shown in Table 1 below, all processes were performed in the same manner as in Example 1 except that the contents of the components were changed.
[특성 평가][Characteristics Evaluation]
1) 접착강도(N/㎟): KS M 3705에 의거하여 패널 샘플의 압축 전단 접착강도를 각 3 측정하였으며, 그 평균값을 하기 표 2에 나타내었다.1) Adhesive strength (N/㎟): Based on KS M 3705, the compression shear adhesive strength of each of the three panel samples was measured, and the average values are shown in Table 2 below.
2) 방염성능: KS F 2819(건축용 얇은 재료의 방염성 시험방법)에 따라 패널 샘플의 탄화 길이, 탄화 면적, 잔염시간 및 잔신시간을 각 3 측정하였으며, 그 평균값을 하기 표 2에 나타내었다.2) Flame retardant performance: The carbonization length, carbonization area, afterflame time, and aftershock time of each panel sample were measured in accordance with KS F 2819 (Flame retardancy test method for thin materials for construction), and the average values are shown in Table 2 below.
(N/㎟)Adhesive strength
(N/㎟)
(㎝)Carbonization length
(cm)
(㎠)Carbonization area
(㎠)
(초)Afterflame time
(candle)
(초)remaining time
(candle)
상기 표 2를 참고하면, 본 발명에 따라 접착제에 소화용 마이크로캡슐을 적정 함량으로 첨가한 패널의 경우 접착강도와 방염 성능이 모두 우수하였다. 반면, 소화용 마이크로캡슐이 너무 소량 첨가된 실시예 1의 경우 방염 성능이 좋지 않았으며, 소화용 마이크로캡슐이 너무 과량 첨가된 실시예 6의 경우 접착강도가 떨어지는 문제가 있었다.Referring to Table 2 above, in the case of the panel in which fire extinguishing microcapsules were added to the adhesive in an appropriate amount according to the present invention, both adhesive strength and flame retardant performance were excellent. On the other hand, in Example 1, in which too little extinguishing microcapsules were added, the flame retardant performance was not good, and in Example 6, in which too much extinguishing microcapsules were added, there was a problem of poor adhesive strength.
이상과 같이 특정된 사항들과 한정된 실시예를 통해 본 발명이 설명되었으나, 이는 본 발명의 보다 전반적인 이해를 돕기 위해서 제공된 것일 뿐, 본 발명은 상기의 실시예에 한정되는 것은 아니며, 본 발명이 속하는 분야에서 통상의 지식을 가진 자라면 이러한 기재로부터 다양한 수정 및 변형이 가능하다. Although the present invention has been described through the above-described specific details and limited examples, this is only provided to facilitate a more general understanding of the present invention, and the present invention is not limited to the above-mentioned examples, and the present invention belongs to Those skilled in the art can make various modifications and variations from this description.
따라서, 본 발명의 사상은 설명된 실시예에 국한되어 정해져서는 아니되며, 후술하는 특허청구범위뿐 아니라 이 특허청구범위와 균등하거나 등가적 변형이 있는 모든 것들은 본 발명 사상의 범주에 속한다고 할 것이다.Accordingly, the spirit of the present invention should not be limited to the described embodiments, and the scope of the patent claims described below as well as all modifications that are equivalent or equivalent to the scope of this patent claim shall fall within the scope of the spirit of the present invention. .
Claims (14)
상기 판재의 일면 또는 양면에 접착 구비된 표면재; 및
상기 판재와 표면재를 접착시키기 위한 접착제;를 포함하는 목재가구로,
상기 판재는 송진 100 중량부에 대하여 인계 난연제 6 내지 12 중량부 및 카테콜 유도체 10 내지 50 중량부를 포함하는 코팅조성물로 코팅된 것이고,
상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인, 방염성능이 우수한 목재가구용 패널.plate;
A surface material attached to one or both sides of the plate; and
Wooden furniture including an adhesive for bonding the board and the surface material,
The plate is coated with a coating composition containing 6 to 12 parts by weight of a phosphorus-based flame retardant and 10 to 50 parts by weight of a catechol derivative based on 100 parts by weight of rosin,
The adhesive is a wooden furniture panel with excellent flame retardant performance, which contains fire extinguishing microcapsules with a fluorine-based fire extinguishing agent built into them.
상기 불소계 소화약제는 CF3CF2C(O)CF(CF3)2, (CF3)2CFC(O)CF(CF3)2, CF3(CF2)2C(O)CF(CF3)2, CF3(CF2)3C(O)CF(CF3)2, CF3(CF2)5C(O)CF3, CF3CF2C(O)CF2CF2CF3, CF3C(O)CF(CF3)2, C2F5C(O)CF(CF3)2, (CF3)2CFC(O)CF2Cl 및 CF3OCF2CF2C(O)CF(CF3)2로 이루어진 군에서 선택되는 1종 이상을 포함하는, 방염성능이 우수한 목재가구용 패널.According to clause 1,
The fluorine-based fire extinguishing agent is CF 3 CF 2 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 2 C(O)CF(CF) 3 ) 2 , CF 3 (CF 2 ) 3 C(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 5 C(O)CF 3 , CF 3 CF 2 C(O)CF 2 CF 2 CF 3 , CF 3 C(O)CF(CF 3 ) 2 , C 2 F 5 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF 2 Cl and CF 3 OCF 2 CF 2 C( O) CF (CF 3 ) A panel for wooden furniture with excellent flame retardant performance, containing at least one selected from the group consisting of 2 .
상기 소화용 마이크로캡슐의 쉘은 폴리우레탄, 폴리우레아, 폴리올레핀, 폴리아미드 및 폴리에스테르로 이루어진 군에서 선택되는 1종 이상을 포함하는, 방염성능이 우수한 목재가구용 패널.According to clause 1,
The shell of the fire extinguishing microcapsule is a wooden furniture panel with excellent flame retardant performance, comprising at least one selected from the group consisting of polyurethane, polyurea, polyolefin, polyamide, and polyester.
상기 판재는 파티클보드 또는 중밀도 섬유판인, 방염성능이 우수한 목재가구용 패널.According to clause 1,
The board is a particleboard or medium-density fiberboard, a panel for wooden furniture with excellent flame retardant performance.
상기 표면재는 저압 멜라민 함침지(LPM) 또는 고압 멜라민 함침지(HPM)인, 방염성능이 우수한 목재가구용 패널.According to clause 1,
A panel for wooden furniture with excellent flame retardant performance, wherein the surface material is low-pressure melamine impregnated paper (LPM) or high-pressure melamine impregnated paper (HPM).
상기 목재가구는 주방가구 또는 수납가구인, 방염성능이 우수한 목재가구.According to clause 7,
The wooden furniture is kitchen furniture or storage furniture and has excellent flame retardant performance.
상기 판재는 송진 100 중량부에 대하여 인계 난연제 6 내지 12 중량부 및 카테콜 유도체 10 내지 50 중량부를 포함하는 코팅조성물로 코팅된 것이고,
상기 접착제는 내부에 불소계 소화약제가 내장된 소화용 마이크로캡슐을 함유하는 것인, 방염성능이 우수한 목재가구용 패널의 제조 방법.It includes the step of applying an adhesive on the plate to adhere the surface material,
The plate is coated with a coating composition containing 6 to 12 parts by weight of a phosphorus-based flame retardant and 10 to 50 parts by weight of a catechol derivative based on 100 parts by weight of rosin,
A method of manufacturing a wooden furniture panel with excellent flame retardant performance, wherein the adhesive contains a fire extinguishing microcapsule with a fluorine-based fire extinguishing agent built into it.
상기 불소계 소화약제는 CF3CF2C(O)CF(CF3)2, (CF3)2CFC(O)CF(CF3)2, CF3(CF2)2C(O)CF(CF3)2, CF3(CF2)3C(O)CF(CF3)2, CF3(CF2)5C(O)CF3, CF3CF2C(O)CF2CF2CF3, CF3C(O)CF(CF3)2, C2F5C(O)CF(CF3)2, (CF3)2CFC(O)CF2Cl 및 CF3OCF2CF2C(O)CF(CF3)2로 이루어진 군에서 선택되는 1종 이상을 포함하는, 방염성능이 우수한 목재가구용 패널의 제조 방법.According to clause 9,
The fluorine-based fire extinguishing agent is CF 3 CF 2 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 2 C(O)CF(CF) 3 ) 2 , CF 3 (CF 2 ) 3 C(O)CF(CF 3 ) 2 , CF 3 (CF 2 ) 5 C(O)CF 3 , CF 3 CF 2 C(O)CF 2 CF 2 CF 3 , CF 3 C(O)CF(CF 3 ) 2 , C 2 F 5 C(O)CF(CF 3 ) 2 , (CF 3 ) 2 CFC(O)CF 2 Cl and CF 3 OCF 2 CF 2 C( O) A method of manufacturing a wooden furniture panel with excellent flame retardant performance, comprising at least one selected from the group consisting of CF(CF 3 ) 2 .
상기 소화용 마이크로캡슐의 쉘은 폴리우레탄, 폴리우레아, 폴리올레핀, 폴리아미드 및 폴리에스테르로 이루어진 군에서 선택되는 1종 이상을 포함하는, 방염성능이 우수한 목재가구용 패널의 제조 방법.According to clause 9,
The shell of the extinguishing microcapsule includes at least one selected from the group consisting of polyurethane, polyurea, polyolefin, polyamide, and polyester. A method of manufacturing a wooden furniture panel with excellent flame retardant performance.
상기 판재는 파티클보드 또는 중밀도 섬유판인, 방염성능이 우수한 목재가구용 패널의 제조 방법.According to clause 9,
A method of manufacturing a wooden furniture panel with excellent flame retardant performance, wherein the board is particleboard or medium-density fiberboard.
상기 표면재는 저압 멜라민 함침지(LPM) 또는 고압 멜라민 함침지(HPM)인, 방염성능이 우수한 목재가구용 패널의 제조 방법.According to clause 9,
A method of manufacturing a wooden furniture panel with excellent flame retardant performance, wherein the surface material is low-pressure melamine-impregnated paper (LPM) or high-pressure melamine-impregnated paper (HPM).
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007038522A (en) * | 2005-08-03 | 2007-02-15 | Yamaha Corp | Wood covering composite and its manufacturing method |
| KR101235125B1 (en) | 2012-08-13 | 2013-02-20 | 주식회사 하이파오피스 | Flame retardant panel for furniture, manufacture method of the panel and furnitire made from the same |
| KR101395788B1 (en) * | 2013-07-29 | 2014-05-16 | (주) 엘엠시 | Method for manufacturing partion panel for building and partion panel therefrom |
| KR102123659B1 (en) * | 2019-05-08 | 2020-06-16 | 한국소방산업기술원 | Fire extinguishing sheet comprising a microcapsule for fire extinguishing |
| KR102323267B1 (en) * | 2021-04-07 | 2021-11-08 | (주)로자 | Semi-incombustible plywood |
-
2022
- 2022-10-21 KR KR1020220136370A patent/KR102639702B1/en active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007038522A (en) * | 2005-08-03 | 2007-02-15 | Yamaha Corp | Wood covering composite and its manufacturing method |
| KR101235125B1 (en) | 2012-08-13 | 2013-02-20 | 주식회사 하이파오피스 | Flame retardant panel for furniture, manufacture method of the panel and furnitire made from the same |
| KR101395788B1 (en) * | 2013-07-29 | 2014-05-16 | (주) 엘엠시 | Method for manufacturing partion panel for building and partion panel therefrom |
| KR102123659B1 (en) * | 2019-05-08 | 2020-06-16 | 한국소방산업기술원 | Fire extinguishing sheet comprising a microcapsule for fire extinguishing |
| KR102323267B1 (en) * | 2021-04-07 | 2021-11-08 | (주)로자 | Semi-incombustible plywood |
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