KR102639436B1 - Thermoplastic double-composite waterproofing method and waterproofing structure for bridges with smooth blisterling discharge - Google Patents
Thermoplastic double-composite waterproofing method and waterproofing structure for bridges with smooth blisterling discharge Download PDFInfo
- Publication number
- KR102639436B1 KR102639436B1 KR1020230112153A KR20230112153A KR102639436B1 KR 102639436 B1 KR102639436 B1 KR 102639436B1 KR 1020230112153 A KR1020230112153 A KR 1020230112153A KR 20230112153 A KR20230112153 A KR 20230112153A KR 102639436 B1 KR102639436 B1 KR 102639436B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- layer
- blistering
- coating material
- waterproofing
- Prior art date
Links
- 238000004078 waterproofing Methods 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 20
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 20
- 239000010426 asphalt Substances 0.000 claims abstract description 41
- 239000010410 layer Substances 0.000 claims abstract description 36
- 239000004567 concrete Substances 0.000 claims abstract description 24
- 239000011247 coating layer Substances 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims description 34
- 238000000576 coating method Methods 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 31
- 239000000853 adhesive Substances 0.000 claims description 19
- 239000011230 binding agent Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- 230000001070 adhesive effect Effects 0.000 claims description 17
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 16
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 9
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 239000002174 Styrene-butadiene Substances 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 claims description 5
- 229910052582 BN Inorganic materials 0.000 claims description 5
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 5
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 230000006866 deterioration Effects 0.000 abstract description 15
- 230000001976 improved effect Effects 0.000 abstract description 6
- 238000000926 separation method Methods 0.000 abstract description 5
- 238000009423 ventilation Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229960000878 docusate sodium Drugs 0.000 description 5
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 5
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000004629 polybutylene adipate terephthalate Substances 0.000 description 4
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- MDYPDLBFDATSCF-UHFFFAOYSA-N nonyl prop-2-enoate Chemical compound CCCCCCCCCOC(=O)C=C MDYPDLBFDATSCF-UHFFFAOYSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 239000001508 potassium citrate Substances 0.000 description 2
- 229960002635 potassium citrate Drugs 0.000 description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 2
- 235000011082 potassium citrates Nutrition 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- IFKPLJWIEQBPGG-QGZVFWFLSA-N (5s)-6-(dimethylamino)-5-methyl-4,4-diphenylhexan-3-one Chemical compound C=1C=CC=CC=1C([C@H](C)CN(C)C)(C(=O)CC)C1=CC=CC=C1 IFKPLJWIEQBPGG-QGZVFWFLSA-N 0.000 description 1
- 125000006185 3,4-dimethyl benzyl group Chemical group [H]C1=C(C([H])=C(C(=C1[H])C([H])([H])[H])C([H])([H])[H])C([H])([H])* 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000011384 asphalt concrete Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007500 overflow downdraw method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Polymers [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D19/00—Structural or constructional details of bridges
- E01D19/08—Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
- E01D19/083—Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/47—Oils, fats or waxes natural resins
- C04B41/478—Bitumen, asphalt, e.g. paraffin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4857—Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/70—Coating or impregnation for obtaining at least two superposed coatings having different compositions
- C04B41/71—Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being an organic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D21/00—Methods or apparatus specially adapted for erecting or assembling bridges
Abstract
본 발명은 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법 및 방수구조에 관한 것으로, 보다 상세하게는 교량의 교면 포장시 바닥 슬래브층인 콘크리트 구조물의 표면에 존재하는 미세크랙, 크랙에 의한 파손, 내구성 저하를 억제하여 콘크리트 구조물의 강도, 방수성을 증대시키면서 무엇보다도 도막층과 시트층으로 이루어진 2중 복합 방수식 아스팔트 포장시 슬래브에 함유된 수분에 의해 유발되는 블리스터링을 해소하여 계면분리, 포트홀 발생, 아스팔트 내구성 저하 등의 교면 포장면의 열화현상을 해소하도록 개선된 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법 및 방수구조에 관한 것이다.The present invention relates to a thermoplastic double composite waterproofing method and waterproofing structure for bridge surfaces that facilitate the discharge of blistering. More specifically, it relates to fine cracks and damage caused by cracks present on the surface of the concrete structure, which is the floor slab layer, when paving the bridge surface of a bridge. , suppresses durability deterioration, increases the strength and waterproofing of concrete structures, and above all, eliminates blistering caused by moisture contained in the slab during double composite waterproof asphalt pavement consisting of a coating layer and a sheet layer, preventing interfacial separation and potholes. This relates to a thermoplastic double composite waterproofing method and waterproofing structure for bridge surfaces that allow smooth discharge of blistering, which has been improved to resolve the deterioration of the bridge surface surface, such as the occurrence of cracks and deterioration of asphalt durability.
Description
본 발명은 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법 및 방수구조에 관한 것으로, 보다 상세하게는 교량의 교면 포장시 바닥 슬래브층인 콘크리트 구조물의 표면에 존재하는 미세크랙, 크랙에 의한 파손, 내구성 저하를 억제하여 콘크리트 구조물의 강도, 방수성을 증대시키면서 무엇보다도 도막층과 시트층으로 이루어진 2중 복합 방수식 아스팔트 포장시 슬래브에 함유된 수분에 의해 유발되는 블리스터링을 해소하여 계면분리, 포트홀 발생, 아스팔트 내구성 저하 등의 교면 포장면의 열화현상을 해소하도록 개선된 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법 및 방수구조에 관한 것이다.The present invention relates to a thermoplastic double composite waterproofing method and waterproofing structure for bridge surfaces that facilitate the discharge of blistering. More specifically, it relates to fine cracks and damage caused by cracks present on the surface of the concrete structure, which is the floor slab layer, when paving the bridge surface of a bridge. , suppresses durability deterioration, increases the strength and waterproofing of concrete structures, and above all, eliminates blistering caused by moisture contained in the slab during double composite waterproof asphalt pavement consisting of a coating layer and a sheet layer, preventing interfacial separation and potholes. This relates to a thermoplastic double composite waterproofing method and waterproofing structure for bridge surfaces that allow smooth discharge of blistering, which has been improved to resolve the deterioration of the bridge surface surface, such as the occurrence of cracks and deterioration of asphalt durability.
일반적으로 교량바닥판은 차량의 하중이나 비, 눈, 직사관선에의한 자외선 노출 등 가혹한 자연환경에 노출되어 있다.In general, bridge decks are exposed to harsh natural environments such as vehicle loads, rain, snow, and exposure to ultraviolet rays from direct sunlight.
또한 차량에 의한 반복하중 발생으로 처짐, 진동과 온도변화에 의한 수축, 팽창은 교량 바닥판에 균열을 발생시키는데, 이때 균열 부위에 수분이 침투하여 콘크리트의 동해가 발생하여 내부 철근을 부식시키고 이는 콘크리트의 균열을 가속화 시킨다.In addition, deflection due to repetitive loads caused by vehicles, and contraction and expansion due to vibration and temperature changes cause cracks in the bridge deck. At this time, moisture penetrates into the crack area, causing freezing of the concrete, corroding the internal reinforcing bars, and causing concrete damage. accelerates the cracking of
뿐만 아니라, 동절기 제설제 사용에 의한 염화물이 침투하여 철근부식을 촉진시키는데, 교량의 안전성 및 내구성능을 확보하기 위하여 교면에 방수공법을 적용하게 된다.In addition, chloride from the use of snow removers in the winter penetrates and accelerates corrosion of reinforcing bars. In order to ensure the safety and durability of bridges, waterproofing methods are applied to the bridge surfaces.
기존의 교면 방수공법은 시트식 방수공법, 도막식 방수공법, 복합식방수공법으로 분류할 수 있다.Existing bridge waterproofing methods can be classified into sheet-type waterproofing methods, film-type waterproofing methods, and composite waterproofing methods.
먼저, 시트식 방수공법은 시트 하부면에 토치를 이용하여 시트를 녹여 바탕면에 접착하는 토치 융착식, 방수시트 자체 접착성능을 이용하여 바탕면에 접착하는 자착식으로 구분 할 수 있다.First, the sheet-type waterproofing method can be divided into the torch fusion method, which uses a torch on the lower surface of the sheet to melt the sheet and adheres it to the substrate, and the self-adhesive method, which uses the self-adhesive performance of the waterproof sheet to adhere to the substrate.
도막식 방수공법은 톨루엔이나 자일렌 등 유기용제에 합성고무를 용해시켜 피막을 형성하는 상온 도막방수, 고온의 아스팔트에 합성고무 등을 용해시켜 시공시 재가열하여 사용하는 가열용융형 도막방수공법으로 구분한다.The paint-film waterproofing method is divided into room-temperature film waterproofing, which forms a film by dissolving synthetic rubber in an organic solvent such as toluene or xylene, and a heat-melt film waterproofing method, which uses synthetic rubber, etc. dissolved in high-temperature asphalt and reheated during construction. do.
복합식 방수공법은 도막방수재와 시트방수재를 동시에 시공하는 공법으로 도막방수재의 장점인 이음없는 방수층 형성과 시트의 장점인 일정한 방수층의 두께 형성 등의 특성을 결합한 방수공법이다.The composite waterproofing method is a method of simultaneously constructing a coating waterproofing material and a sheet waterproofing material. It is a waterproofing method that combines the characteristics of a seamless waterproofing layer, which is an advantage of a coating waterproofing material, and the formation of a constant waterproof layer thickness, which is an advantage of a sheet.
상기와 같이 교면용 방수공법은 시트식 방수공법의 경우 직접가열에 의한 열화로 개질아스팔트의 물성변화에 의한 물성저하를 초래할 수 있고, 하부 필름의 불완전 용융에 의한 하부 바탕면과의 접착이 되지 않는 문제점이 있으며 토치 가스 및 용융에 의한 가스가 발생하여 에어포켓이 발생하여 아스콘 포설 후 포트홀의 원인이 되며 겹침 이음의 과다 발생으로 누수를 유발시킬 수 있는 문제점이 있다.As mentioned above, in the case of the sheet-type waterproofing method for bridge surfaces, it may result in a decrease in physical properties due to changes in the physical properties of the modified asphalt due to deterioration due to direct heating, and may not adhere to the lower surface due to incomplete melting of the lower film. There is a problem: torch gas and melting gas are generated, creating air pockets, which can cause potholes after laying asphalt concrete, and excessive occurrence of overlapping joints can cause water leaks.
즉, 시트에 의해 형성된 시트층이 형성된 후에 아스팔트를 포장하게 되면 포장시 발생되는 약 140-160℃의 열에 의해 콘크리트 바닥판 슬래브에 잔류하고 있던 수분이 브리스터링(blisterling)으로 변하면서 에어포켓을 형성하게 된다.In other words, when asphalt is paved after the sheet layer is formed, the moisture remaining in the concrete floor slab changes to blistering due to the heat of about 140-160℃ generated during paving, forming air pockets. I do it.
그러면, 이 에어포켓은 방수층과 콘크리트 바닥층 사이의 접착성능을 약화시키므로 아스팔트의 내구성을 급격히 떨어뜨리게 된다.Then, these air pockets weaken the adhesive performance between the waterproof layer and the concrete floor layer, drastically reducing the durability of the asphalt.
이를 개선하기 위해, [선행기술문헌]을 포함한 다수의 복합방수공법이 개시되어 있으나, 방수시트를 완전히 만든 상태에서 에어벤트를 형성하기 때문에 방수시트를 포장 관리하기 위해 권취하게 되는데 그때 찢어지기 쉽다. 때문에, [선행기술문헌]상의 에어벤트는 많이 형성할 수 없고 국부적일 수 밖에 없어 에어벤트 효과가 떨어진다.To improve this, a number of composite waterproofing methods, including [prior art literature], have been disclosed. However, since air vents are formed when the waterproof sheet is completely made, the waterproof sheet is wound for packaging and management, and it is easy to tear at that time. Therefore, the air vents in the [prior art literature] cannot be formed in large numbers and can only be localized, which reduces the air vent effect.
특히, [선행기술문헌]의 경우 에어벤트를 제일 마지막에 형성할 수 밖에 없는 이유는 에어벤트를 먼저 형성할 경우 부직포를 함침하는 함침액에 의해 에어벤트가 막혔을 때 이 함침액이 쉽게 터지지 않기 때문인데, 이는 함침액의 조성상 결합력과 부착력이 높은 특징 때문이다.In particular, in the case of [prior art literature], the reason why the air vent has to be formed last is because if the air vent is formed first, the impregnating liquid that impregnates the nonwoven fabric does not easily burst when the air vent is blocked. This is because the composition of the impregnating liquid has high bonding and adhesion properties.
본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 교량의 교면 포장시 바닥 슬래브층인 콘크리트 구조물의 표면에 존재하는 미세크랙, 크랙에 의한 파손, 내구성 저하를 억제하여 콘크리트 구조물의 강도, 방수성을 증대시키면서 무엇보다도 도막층과 시트층으로 이루어진 2중 복합 방수식 아스팔트 포장시 슬래브에 함유된 수분에 의해 유발되는 블리스터링을 해소하여 계면분리, 포트홀 발생, 아스팔트 내구성 저하 등의 교면 포장면의 열화현상을 해소하도록 개선된 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법 및 방수구조을 제공함에 그 주된 목적이 있다.The present invention was created in consideration of various problems in the prior art as described above to solve them, and suppresses micro cracks, damage caused by cracks, and decreased durability on the surface of the concrete structure, which is the floor slab layer, when paving the bridge surface. This increases the strength and waterproofing of the concrete structure, and above all, it eliminates blistering caused by moisture contained in the slab when paving with double composite waterproof asphalt consisting of a coating layer and a sheet layer, which leads to interfacial separation, occurrence of potholes, and deterioration of asphalt durability. The main purpose is to provide a thermoplastic double composite waterproofing method and waterproofing structure for bridge surfaces with improved blistering discharge, which has been improved to resolve the deterioration phenomenon of bridge surface pavements such as bridges.
본 발명은 상기한 목적을 달성하기 위한 수단으로, 콘크리트 바닥인 슬래브 위에 접착제를 도포하는 제1단계; 상기 접착제 위에 도막재를 도포하여 도막층을 형성하는 제2단계; 상기 도막층 위에 방수시트를 깔아 방수층을 형성하는 제3단계; 상기 방수층 위에 아스팔트를 포장하는 제4단계;를 포함하는 교면용 열가소성 2중 복합 방수공법에 있어서; 상기 제2단계에서 사용되는 도막재는 탄화수소수지(Hydrocarbon Resin) 15-20중량%, SBR(Styrene-Butadiene Rubber) 5-15중량%, 아스팔트유화제(Asphalt Emulsifier) 5-10중량% 및 나머지 열가소성 엘라스토머(Thermoplastic Elastomer)로 조성된 것을 특징으로 하는 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법 및 방수구조을 제공한다.The present invention is a means for achieving the above object, comprising: a first step of applying an adhesive on a slab, which is a concrete floor; A second step of forming a coating layer by applying a coating material on the adhesive; A third step of forming a waterproof layer by laying a waterproof sheet on the coating layer; In the thermoplastic double composite waterproofing method for bridge surfaces, including the fourth step of paving asphalt on the waterproofing layer; The coating material used in the second step is 15-20% by weight of hydrocarbon resin, 5-15% by weight of SBR (Styrene-Butadiene Rubber), 5-10% by weight of asphalt emulsifier, and the remaining thermoplastic elastomer ( It provides a thermoplastic double composite waterproofing method and waterproofing structure for bridge surfaces with smooth blistering discharge, which is characterized by being composed of Thermoplastic Elastomer.
이때, 상기 도막재를 구성할 때 도막재 조성물 100중량부에 대해, 비닐피롤리돈(Vinyl pyrrolidone) 10중량부, 1,3:2,4-비스(3,4-디메틸벤질리덴)솔비톨 10중량부, 질화붕소(Boron Nitride) 분말 5중량부를 더 첨가하여 조성할 수 있다.At this time, when composing the coating material, 10 parts by weight of vinyl pyrrolidone, 10 parts by weight of 1,3:2,4-bis(3,4-dimethylbenzylidene)sorbitol, based on 100 parts by weight of the coating material composition. It can be composed by adding 5 parts by weight of boron nitride powder.
또한, 상기 방수시트는 중심 기재를 바인더조성물에 함침시켜, 모래-바인더-중심 기재-바인더-모래의 층구조로 두께 1.5-2.5mm를 갖도록 만들되, 상기 중심 기재는 폴리에스터, 폴리프로필렌, 폴리에틸렌 중 어느 하나의 섬유 원단일 수 있다.In addition, the waterproof sheet is made by impregnating the central substrate with a binder composition to have a layer structure of sand-binder-central substrate-binder-sand with a thickness of 1.5-2.5mm, and the central substrate is made of polyester, polypropylene, or polyethylene. It may be any one fiber fabric.
또한, 상기 바인더조성물은 탄화수소수지(Hydrocarbon Resin) 15-20중량%, 알콕시레이티드 알코올(alkoxylated alcohol) 2.5-5.0중량%, SBR(Styrene-Butadiene Rubber) 5-15중량%, 퍼플루오르(2,2-디메틸-1,3-디옥솔(Perfluoro(2,2-dimethyl-1,3-dioxole)) 2.5-4.5중량%, 아스팔트유화제(Asphalt Emulsifier) 5-10중량% 및 나머지 열가소성 엘라스토머(Thermoplastic Elastomer)로 조성될 수 있다.In addition, the binder composition contains 15-20% by weight of hydrocarbon resin, 2.5-5.0% by weight of alkoxylated alcohol, 5-15% by weight of SBR (Styrene-Butadiene Rubber), and perfluorine (2, 2.5-4.5% by weight of 2-dimethyl-1,3-dioxole (Perfluoro(2,2-dimethyl-1,3-dioxole)), 5-10% by weight of Asphalt Emulsifier, and the remaining Thermoplastic Elastomer ) can be composed.
또한, 본 발명은 콘크리트 바닥인 슬래브 위에 도포된 접착제; 상기 접착제 위에 도포되어 도막층을 형성하는 도막재; 상기 도막재 위에 설치되어 방수층을 형성하는 방수시트; 상기 방수시트 위에 포장된 아스팔트를 포함하는 것을 특징으로 하는 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수구조도 제공한다.In addition, the present invention relates to an adhesive applied on a slab, which is a concrete floor; A coating material applied on the adhesive to form a coating layer; A waterproof sheet installed on the coating material to form a waterproof layer; Also provided is a thermoplastic double composite waterproof structure for a bridge surface with smooth blistering discharge, which includes asphalt packed on the waterproof sheet.
본 발명에 따르면, 교량의 교면 포장시 바닥 슬래브층인 콘크리트 구조물의 표면에 존재하는 미세크랙, 크랙에 의한 파손, 내구성 저하를 억제하여 콘크리트 구조물의 강도, 방수성을 증대시키면서 무엇보다도 도막층과 시트층으로 이루어진 2중 복합 방수식 아스팔트 포장시 슬래브에 함유된 수분에 의해 유발되는 블리스터링을 해소하여 계면분리, 포트홀 발생, 아스팔트 내구성 저하 등의 교면 포장면의 열화현상을 해소하도록 개선된 효과를 얻을 수 있다.According to the present invention, the strength and waterproofness of the concrete structure are increased by suppressing fine cracks, damage caused by cracks, and durability deterioration existing on the surface of the concrete structure, which is the floor slab layer, when paving the bridge surface, and, above all, the coating layer and the sheet layer. By resolving blistering caused by moisture contained in the slab during double-layer composite waterproof asphalt paving, improved effects can be obtained to eliminate deterioration of the bridge surface surface such as interfacial separation, occurrence of potholes, and deterioration of asphalt durability. there is.
도 1은 본 발명에 따른 방수공법을 보인 예시적인 플로우챠트이다.
도 2는 본 발명에 따른 방수시트를 구성하는 중심 기재의 예시적인 사진이다.
도 3은 본 발명에 따른 방수공법에 의해 형성된 방수구조를 보인 예시적인 단면도이다.1 is an exemplary flow chart showing a waterproofing method according to the present invention.
Figure 2 is an exemplary photograph of the central substrate constituting the waterproof sheet according to the present invention.
Figure 3 is an exemplary cross-sectional view showing a waterproof structure formed by the waterproofing method according to the present invention.
이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in more detail.
본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Prior to describing the present invention, the following specific structural and functional descriptions are merely illustrative for the purpose of explaining embodiments according to the concept of the present invention, and embodiments according to the concept of the present invention may be implemented in various forms. It should not be construed as limited to the embodiments described herein.
본 발명이 속한 교량의 교면인 콘크리트 상판은 차량 통과로 인해 지속적으로 수직하중을 받을 뿐만 아니라, 상시 노출되어 있기 때문에 교량의 다른 부분에 비해 더 빨리 열화되는 결과를 초래하므로 빈번한 보수 또는 교체가 요구된다.The concrete deck, which is the bridge surface of the bridge to which the present invention belongs, not only receives continuous vertical load due to passing vehicles, but also deteriorates faster than other parts of the bridge because it is always exposed, so frequent repair or replacement is required. .
이러한 보수 또는 교체작업중 교면 방수를 위한 방수재 시공이 매우 중요한데 이는 콘크리트 상판에서 상판으로 물이 침투되는 것을 차단하여야 상판의 내구성을 향상시킬 수 있기 때문이다.During such repair or replacement work, the construction of waterproofing material for bridge surface waterproofing is very important because the durability of the deck can be improved only by blocking water from penetrating from the concrete top plate to the top plate.
즉, 교면방수는 교통하중에 의한 충격작용 및 우수의 침입이나 온도변화 등 기상작용에 대항하여 교면을 보호할 뿐만 아니라, 통행 차량의 쾌적한 주행을 확보하는 중요한 역할을 담당한다.In other words, bridge waterproofing not only protects the bridge surface against the impact of traffic loads and weather effects such as rainwater intrusion or temperature changes, but also plays an important role in ensuring comfortable driving for passing vehicles.
이를 위한 본 발명에 따른 교면용 열가소성 2중 복합 방수공법은 시트식과 도막식이 복합적으로 사용된 2층 방수개념으로써 방수효과를 증대시키도록 구성된다.For this purpose, the thermoplastic double composite waterproofing method for bridge surfaces according to the present invention is configured to increase the waterproofing effect through a two-layer waterproofing concept using a combination of sheet type and coating type.
다시 말해, 도막층이 형성된 위에 방수시트층이 더 형성된 2중 복합 방수공법에 관한 것이다.In other words, it relates to a double composite waterproofing method in which a waterproof sheet layer is further formed on top of the coating layer.
보다 구체적으로, 도 1의 예시와 같이, 본 발명은 콘크리트 바닥인 슬래브 위에 접착제를 도포하는 제1단계; 상기 접착제 위에 도막재를 도포하여 도막층을 형성하는 제2단계; 상기 도막층 위에 방수시트를 깔아 방수층을 형성하는 제3단계; 상기 방수층 위에 아스팔트를 포장하는 제4단계;를 포함한다.More specifically, as shown in the example of Figure 1, the present invention includes a first step of applying an adhesive on a slab, which is a concrete floor; A second step of forming a coating layer by applying a coating material on the adhesive; A third step of forming a waterproof layer by laying a waterproof sheet on the coating layer; It includes a fourth step of paving asphalt on the waterproof layer.
이때, 상기 제1단계에서 사용되는 접착제는 폴리우레탄수지 100중량부에 대해, 트리메틸-2.4-팬탄디올-1.3-이소부틸레이트 10중량부, PBAT(Poly-Butylene Adipate Terephthalate) 15중량부, 규산나트륨(Na2SiO3) 분말 8.5중량부, 벤조산비닐에스테르(Benzoic acid vinyl ester) 10중량부를 혼합하여 만들어진다.At this time, the adhesive used in the first step is 10 parts by weight of trimethyl-2.4-pentanediol-1.3-isobutyrate, 15 parts by weight of PBAT (Poly-Butylene Adipate Terephthalate), and sodium silicate based on 100 parts by weight of polyurethane resin. It is made by mixing 8.5 parts by weight of (Na 2 SiO 3 ) powder and 10 parts by weight of benzoic acid vinyl ester.
여기에서, 상기 트리메틸-2.4-팬탄디올-1.3-이소부틸레이트(2.4-trimetyl-1.3-pentandiol isobutyrate)은 가수분해 및 산화에 대한 안정성이 높고, 점도가 높은데 비하여 신축성과 유동성을 모두 증진시키면서 접착력을 강화시키는데 기여한다.Here, the trimethyl-2.4-pentanediol-1.3-isobutyrate (2.4-trimetyl-1.3-pentandiol isobutyrate) has high stability against hydrolysis and oxidation, and has a high viscosity, while improving both elasticity and fluidity and improving adhesion. Contributes to strengthening
또한, 상기 PBAT(Poly-Butylene Adipate Terephthalate)는 연신율을 증대시켜 유연성과 가공성, 내구성을 피착재에 부여하기 위해 첨가된다.In addition, PBAT (Poly-Butylene Adipate Terephthalate) is added to increase elongation and provide flexibility, processability, and durability to the adherend.
뿐만 아니라, 규산나트륨(Na2SiO3) 분말은 콘크리트의 공극, 크랙, 크랙 부위로 침투, 충진되면서 겔화되어 치밀화시키며, 높은 방수성과 인장강도 및 압축강도를 유지하여 내구성을 높이게 되고, 중성화억제에 기여한다.In addition, sodium silicate (Na 2 SiO 3 ) powder penetrates and fills the pores, cracks, and cracks of concrete, gelling and densifying them, maintaining high water resistance, tensile strength, and compressive strength to increase durability, and to inhibit neutralization. Contribute.
아울러, 벤조산비닐에스테르(Benzoic acid vinyl ester)는 CAS 번호 769-78-8에 해당하는 물질로서 자외선에 대한 광열화 작용으로 자외선을 흡수하여 피착재의 표면을 보호하고 갈라짐을 억제하며, 접착력을 강화시키기 위해 첨가된다.In addition, benzoic acid vinyl ester is a material corresponding to CAS number 769-78-8 and absorbs ultraviolet rays through photodeterioration of ultraviolet rays to protect the surface of the adherend, suppress cracking, and strengthen adhesion. It is added for
한편, 상기 제2단계에서 사용되는 도막재는 탄화수소수지(Hydrocarbon Resin) 15-20중량%, SBR(Styrene-Butadiene Rubber) 5-15중량%, 아스팔트유화제(Asphalt Emulsifier) 5-10중량% 및 나머지 열가소성 엘라스토머(Thermoplastic Elastomer)로 조성된다.Meanwhile, the coating material used in the second step is 15-20% by weight of hydrocarbon resin, 5-15% by weight of SBR (Styrene-Butadiene Rubber), 5-10% by weight of asphalt emulsifier, and the remaining thermoplastic. It is composed of elastomer (Thermoplastic Elastomer).
이때, 상기 탄화수소수지는 염화알루미늄이나 황산의 존재에서 탄화수소(올레핀과 달리)의 자동 반응으로 만들어진 합성 수지이다. 특히, 염화알루미늄의 존재에서 가솔린 열분해로부터의 이소프렌 없는 C5 부분이나 가솔린 열분해(열분해 오일)의 끓는점이 높은 부분을 가열함으로써 만들어진 것을 사용한다.At this time, the hydrocarbon resin is a synthetic resin made by the automatic reaction of hydrocarbons (unlike olefins) in the presence of aluminum chloride or sulfuric acid. In particular, those made by heating the isoprene-free C5 fraction from gasoline pyrolysis or the high boiling point fraction of gasoline pyrolysis (pyrolysis oil) in the presence of aluminum chloride are used.
다시 말해, 상기 탄화수소수지는 콜타르ㆍ로진(rosin)ㆍ석유의 불포화 성분을 종합하여 만드는 무른 고체상 또는 고무상의 물질이라고 보면 이해하기 쉽고, 접착성을 강화시키는 기능을 수행한다.In other words, it is easy to understand that the hydrocarbon resin is a soft solid or rubber-like material made by combining unsaturated components of coal tar, rosin, and petroleum, and performs the function of strengthening adhesion.
또한, 상기 SBR(Styrene-Butadiene Rubber)은 침입도를 작게 하고 연화점을 높이며 신도는 크게 하고 고온에서 점도를 증가 시키며 감온성을 크게 개선하는 특징을 가지고 있다.In addition, the SBR (Styrene-Butadiene Rubber) has the characteristics of reducing penetration, increasing softening point, increasing elongation, increasing viscosity at high temperatures, and greatly improving temperature sensitivity.
아울러, 상기 아스팔트유화제(Asphalt Emulsifier)는 아스팔트에 유화제와 안정제 등을 첨가한 용액으로써 아스팔트 포장을 할 때 아스콘이 지면에 잘 붙을 수 있도록 방습과 방수의 기능을 가진 접착제이며, 비교적 안정하고 양생이 빠른 장점을 가진다. 보통, 물 25-60중량%, 유화제 0.1-2.5중량% 및 나머지 아스팔트로 조성되는 것이 일반적이다.In addition, the asphalt emulsifier is a solution in which emulsifiers and stabilizers are added to asphalt. It is an adhesive that has moisture-proof and waterproof functions so that asphalt can adhere well to the ground when paving with asphalt. It is relatively stable and cures quickly. It has advantages. Typically, it is composed of 25-60% by weight of water, 0.1-2.5% by weight of emulsifier, and the remainder asphalt.
그리고, 상기 열가소성 엘라스토머(Thermoplastic Elastomer)는 고무와 플라스틱 두 성질을 가지고 있는 고분자 아스팔트 바인더로서 폴리우레탄계를 사용함이 바람직하다.In addition, the thermoplastic elastomer is a polymer asphalt binder that has both rubber and plastic properties, and it is preferable to use a polyurethane type.
특히 바람직하기로는, AP-5(일반 아스팔트 바인더)를 사용할 수 있다.Particularly preferably, AP-5 (general asphalt binder) can be used.
상기 AP-5는 침입도 60-80, 25℃, 100g, 0.1mm, PG 64-22에 해당하는 바인더를 말하며, 이때 'PG 64-22'의 표현에서 PG는 Performance Grade로서 아스팔트 바인더의 등급을 말하며, 숫자 64는 7일 평균 최고 포장온도를 말하며, 22는 최저 포장온도를 나타낸다.The AP-5 refers to a binder corresponding to penetration degree 60-80, 25℃, 100g, 0.1mm, PG 64-22. In this case, in the expression 'PG 64-22', PG is Performance Grade and refers to the grade of asphalt binder. The number 64 refers to the 7-day average highest packaging temperature, and 22 refers to the lowest packaging temperature.
이에 더하여, 본 발명에서는 상기 도막재를 구성할 때 도막재 조성물 100중량부에 대해, 비닐피롤리돈(Vinyl pyrrolidone) 10중량부, 1,3:2,4-비스(3,4-디메틸벤질리덴)솔비톨 10중량부, 질화붕소(Boron Nitride) 분말 5중량부를 더 첨가하여 조성할 수 있다.In addition, in the present invention, when constructing the coating material, 10 parts by weight of vinyl pyrrolidone, 1,3:2,4-bis (3,4-dimethylbenzyl) are added to 100 parts by weight of the coating material composition. Liden) can be prepared by adding 10 parts by weight of sorbitol and 5 parts by weight of boron nitride powder.
이 경우, 상기 비닐피롤리돈(Vinyl pyrrolidone)은 CAS 넘버 25086-89-9에 해당하는 물질로서, 조성물에 함유된 결정들의 조대 성장을 억제하여 아스팔트 표면층의 크랙, 탈락, 포트홀 발생을 억제하는데 기여하게 된다.In this case, the vinyl pyrrolidone is a substance corresponding to CAS number 25086-89-9, and contributes to suppressing the occurrence of cracks, peeling, and potholes in the asphalt surface layer by suppressing the coarse growth of crystals contained in the composition. I do it.
그리고, 상기 1,3:2,4-비스(3,4-디메틸벤질리덴)솔비톨(1,3:2,4-Bis(3,4-Dimethylobenzylideno) Sorbitol)은 CAS 넘버 135861-56-2에 해당하는 물질로서, 구형화된 피착재의 내열성과 내균열성, 크랙 방지성을 강화시키기 위해 첨가된다.And, the 1,3:2,4-bis(3,4-dimethylbenzylideno) Sorbitol (1,3:2,4-Bis(3,4-Dimethylobenzylideno) Sorbitol) is listed in CAS No. 135861-56-2. As a corresponding material, it is added to strengthen the heat resistance, crack resistance, and crack prevention of spherical adherends.
아울러, 상기 질화붕소(Boron Nitride)는 열전도율이 높고 열을 효과적으로 반사시켜 방열성을 유지하여 아스팔트 표면층을 안정화시키는데 기여한다.In addition, boron nitride has high thermal conductivity and effectively reflects heat to maintain heat dissipation, thereby contributing to stabilizing the asphalt surface layer.
다른 한편, 상기 제3단계는 방수시트를 깔아 도막층에 부착시키는 단계로서, 그 전에 방수시트를 만드는 전처리단계가 수행되어야 한다.On the other hand, the third step is a step of laying a waterproof sheet and attaching it to the coating layer, and before that, a pretreatment step of making the waterproof sheet must be performed.
상기 전처리단계는 기재를 중심으로 양측면에 바인더가 부착되고 그 양면에 각각 모래가 부착된 구조를 갖도록 방수시트를 제조하는 단계이다.The pretreatment step is a step of manufacturing a waterproof sheet to have a structure in which a binder is attached to both sides of the substrate and sand is attached to both sides.
즉, 상기 전처리단계를 거쳐 완성된 방수시트는 모래-바인더-중심 기재-바인더-모래의 층구조로 두께 1.5-2.5mm를 갖도록 만들어진다.That is, the waterproof sheet completed through the above pretreatment step is made to have a thickness of 1.5-2.5 mm with a layer structure of sand-binder-center base-binder-sand.
이것은 중심 기재는 폴리에스터, 폴리프로필렌, 폴리에틸렌 중 어느 하나의 섬유 원단, 바람직하게는 부직포일 수 있다.The central substrate may be a fibrous fabric made of polyester, polypropylene, or polyethylene, preferably a non-woven fabric.
그리고, 이 섬유 원단은 도 2의 예시와 같이, 펀칭에 의한 다수의 통기홀이 형성된 상태에서 바인더조성물에 함침되어 그 양측면에 바인더층이 형성되도록 구성된다.And, as shown in the example of FIG. 2, this fiber fabric is impregnated with a binder composition in a state in which a plurality of ventilation holes are formed by punching, and a binder layer is formed on both sides of the fabric.
그런 후에, 말아서 보관할 때 서로 달라붙지 말라고 모래를 뿌려 모래층이 형성된다.Afterwards, sand is sprinkled on them to prevent them from sticking together when rolled up and stored, forming a sand layer.
이와 같이, 본 발명에 따른 방수시트는 기존과 달리 펀칭이 먼저된 상태에서 바인더조성물에 함침되기 때문에 방수시트가 만들어졌을 때는 통기홀이 바인더조성물에 의해 막혀 있는 상태가 된다.In this way, unlike the existing waterproof sheet according to the present invention, the waterproof sheet is first punched and then impregnated with the binder composition, so when the waterproof sheet is made, the ventilation holes are blocked by the binder composition.
종래에는 이렇게 막히면 통기성이 없어져 에어포켓을 해소할 수 없기 때문에 부득이하게 방수시트를 만든 후에 제일 마지막으로 펀칭하여 통기홀을 형성하였으므로 찢어지는 것을 방지하기 위해 통기홀을 많이 형성할 수 없었지만, 본 발명에서는 미리 다수의 통기홀을 형성한 상태에서 함침하기 때문에 권취할 때는 통기홀이 막힌 상태이므로 찢어질 염려가 없어 종래 보다 상대적으로 훨씬 많은 통기홀을 형성할 수 있다.In the past, if it was clogged in this way, ventilation was lost and air pockets could not be eliminated, so the ventilation holes were inevitably formed by punching at the end after making the waterproof sheet, so it was not possible to form many ventilation holes to prevent tearing. However, in the present invention, Since it is impregnated with a large number of ventilation holes formed in advance, the ventilation holes are blocked when winding, so there is no fear of tearing, and relatively more ventilation holes can be formed than before.
다만, 본 발명에서는 바인더조성물을 특수하게 구성하여 방수시트를 깐 후 에어포켓에서 브리스터링이 올라올 때 통기홀이 뚫리면서 자연스럽게 배출될 수 있도록 한 특징을 갖는다.However, in the present invention, the binder composition is specially designed so that when the blistering rises from the air pocket after laying the waterproof sheet, the ventilation hole is opened and it can be naturally discharged.
이를 위해, 상기 바인더조성물은 탄화수소수지(Hydrocarbon Resin) 15-20중량%, 알콕시레이티드 알코올(alkoxylated alcohol) 2.5-5.0중량%, SBR(Styrene-Butadiene Rubber) 5-15중량%, 퍼플루오르(2,2-디메틸-1,3-디옥솔(Perfluoro(2,2-dimethyl-1,3-dioxole)) 2.5-4.5중량%, 아스팔트유화제(Asphalt Emulsifier) 5-10중량% 및 나머지 열가소성 엘라스토머(Thermoplastic Elastomer)로 조성된다.For this purpose, the binder composition contains 15-20% by weight of hydrocarbon resin, 2.5-5.0% by weight of alkoxylated alcohol, 5-15% by weight of SBR (Styrene-Butadiene Rubber), and perfluorine (2 ,2-dimethyl-1,3-dioxole (Perfluoro(2,2-dimethyl-1,3-dioxole)) 2.5-4.5% by weight, Asphalt Emulsifier 5-10% by weight and the remaining thermoplastic elastomer (Thermoplastic) Elastomer).
이때, 알콕시레이티드 알코올(alkoxylated alcohol)은 비이온성 계면활성제로서 통기홀에 피착되는 바인더막을 약화시켜 브리스터링에 의한 기포 발생시 터짐을 쉽게 함으로써 기포 배출을 용이하게 하도록 유도한다.At this time, alkoxylated alcohol is a nonionic surfactant that weakens the binder film deposited on the ventilation hole, making it easier to burst when bubbles are generated by blistering, thereby facilitating the discharge of bubbles.
또한, 퍼플루오르(2,2-디메틸-1,3-디옥솔(Perfluoro(2,2-dimethyl-1,3-dioxole))은 CAS 넘버 37697-64-6에 해당하는 물질로서, 통기홀에 부착되는 수지액이 응집되지 않고 균일하게 분산되도록 유도하여 두께를 작게 하면서 표면장력을 약화시켜 브리스터링압에 의해 쉽게 터질 수 있도록 유도한다.In addition, Perfluoro(2,2-dimethyl-1,3-dioxole) is a substance corresponding to CAS number 37697-64-6 and is installed in the ventilation hole. It induces the attached resin liquid to be uniformly dispersed rather than agglomerated, reducing the thickness and weakening the surface tension so that it can easily burst due to blistering pressure.
이 경우, 상기 바인더조성물에는 상기 바인더조성물 100중량부에 대해, 인산에스테르(Phosphoric Acid) 2.5중량부, 이소헥사데칸(Isohexadecane) 2.5중량부, 시트르산칼륨(Potassium Citrate) 2.5중량부, 폴리인산염(polyphosphate salts) 2.5중량부를 더 첨가할 수 있다.In this case, the binder composition includes 2.5 parts by weight of phosphoric acid, 2.5 parts by weight of isohexadecane, 2.5 parts by weight of potassium citrate, and polyphosphate, based on 100 parts by weight of the binder composition. salts) can be added in an additional 2.5 parts by weight.
이때, 인산에스테르(Phosphoric Acid)는 특히, 염소성분에 의한 침식방지력을 높이는데 기여하여 내크랙성을 방지하기 위해 첨가된다.At this time, phosphoric acid is added to prevent cracking resistance by contributing to increasing the anti-erosion ability especially due to chlorine components.
또한, 이소헥사데칸(Isohexadecane)은 고형분의 용해성 증대 및 분산성 강화를 위해 첨가된다.Additionally, isohexadecane is added to increase the solubility and dispersibility of solids.
그리고, 시트르산칼륨(Potassium Citrate)은 방수성과 강도 증대를 위해 기여한다.Additionally, Potassium Citrate contributes to increasing waterproofness and strength.
아울러, 폴리인산염(polyphosphate salts)은 표면의 인열강도과 인장강도를 증대시켜 내구성을 강화시키며, 내침식성과 내수압특성을 강화시킨다.In addition, polyphosphate salts enhance durability by increasing the tear strength and tensile strength of the surface, and enhance corrosion resistance and water pressure resistance.
이렇게 구성된 교면 샘플에 대한 테스트 결과는 아래 표 1과 같이 나타났다.The test results for the bridge surface sample constructed in this way are shown in Table 1 below.
상기 표 1에 따르면, 교면 포장시 요구되는 품질기준을 모두 만족하였음을 확인할 수 있었다.According to Table 1 above, it was confirmed that all quality standards required for bridge surface paving were satisfied.
한편, 본 발명에 따른 방수공법에 따라 시공하게 되면 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수구조는 도 3과 같은 층 구조를 갖게 된다.On the other hand, when constructed according to the waterproofing method according to the present invention, the thermoplastic double composite waterproofing structure for bridge surfaces that facilitates blistering discharge has a layer structure as shown in FIG. 3.
도 3에 따르면, 본 발명에 따른 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수구조는 콘크리트 바닥인 슬래브(1) 위에 도포된 접착제(2); 상기 접착제(2) 위에 도포되어 도막층을 형성하는 도막재(3); 상기 도막재(3) 위에 설치되어 방수층을 형성하는 방수시트(4); 상기 방수시트(4) 위에 포장된 아스팔트(5)를 포함한다.According to Figure 3, the thermoplastic double composite waterproof structure for a bridge surface with smooth blistering discharge according to the present invention includes an adhesive (2) applied on a slab (1), which is a concrete floor; A coating material (3) applied on the adhesive (2) to form a coating layer; A waterproof sheet (4) installed on the coating material (3) to form a waterproof layer; It includes asphalt (5) packed on the waterproof sheet (4).
이와 같은 방수구조를 갖게 되면, 교량의 교면 포장시 바닥 슬래브층인 콘크리트 구조물의 표면에 존재하는 미세크랙, 크랙에 의한 파손, 내구성 저하를 억제하여 콘크리트 구조물의 강도, 방수성을 증대시키면서 무엇보다도 도막층과 시트층으로 이루어진 2중 복합 방수식 아스팔트 포장시 슬래브에 함유된 수분에 의해 유발되는 블리스터링을 해소하여 계면분리, 포트홀 발생, 아스팔트 내구성 저하 등의 교면 포장면의 열화현상을 해소할 수 있게 된다.Having such a waterproof structure increases the strength and waterproofness of the concrete structure by suppressing fine cracks, damage caused by cracks, and durability degradation on the surface of the concrete structure, which is the floor slab layer, when paving the bridge surface, and above all, the coating layer. By resolving blistering caused by moisture contained in the slab when paving with a double composite waterproof asphalt consisting of a layer and a sheet layer, it is possible to resolve deterioration of the bridge pavement surface such as interfacial separation, occurrence of potholes, and deterioration of asphalt durability. .
한편, 방수시트(4)와 아스팔트(5) 사이에는 접착향상제가 도포될 수 있다. Meanwhile, an adhesion improver may be applied between the waterproof sheet (4) and the asphalt (5).
상기 접착향상제는 물 65중량부, 노닐아크릴레이트 12중량부, 비닐트리에톡시실란 16중량부, 과황산암모늄 4중량부, 중탄산나트륨 3중량부를 포함하여 이루어질 수 있다. The adhesion improver may include 65 parts by weight of water, 12 parts by weight of nonyl acrylate, 16 parts by weight of vinyltriethoxysilane, 4 parts by weight of ammonium persulfate, and 3 parts by weight of sodium bicarbonate.
노닐아크릴레이트 및 비닐트리에톡시실란은 밀착, 접착성 부여 등의 역할을 하고, 과황산암모늄은 촉매제 역할을 하며, 중탄산나트륨은 완충제 역할을 한다.Nonyl acrylate and vinyltriethoxysilane serve as adhesion and adhesion, ammonium persulfate acts as a catalyst, and sodium bicarbonate acts as a buffer.
상기와 같이 구성 물질 및 구성 성분을 한정하고 혼합 비율의 수치를 한정한 이유는, 본 발명자가 수차례 실패를 거듭하면서 시험 결과를 통해 분석한 결과, 상기 구성 성분 및 수치 한정 비율에서 최적의 효과를 나타내었다.The reason for limiting the constituent materials and components and limiting the mixing ratio as described above is that the present inventor analyzed the test results after repeated failures and found that the optimal effect was achieved with the above-mentioned constituents and numerical ratio. indicated.
또한, 방수시트(4)에는 내오염성을 향상시키기 위해 오염 방지 도포용 조성물로 이루어진 내오염성도포층이 도포될 수 있다.In addition, a stain-resistant coating layer made of an anti-fouling coating composition may be applied to the waterproof sheet 4 to improve stain resistance.
상기 내오염성도포층은 디옥틸설포숙시네이트 및 아미도콰트가 1:0.01 ~ 1:2 몰비로 포함되어 있고, 디옥틸설포숙시네이트 및 아미도콰트의 총 함량은 전체 수용액에 대해 1 ~12 중량%이다.The fouling-resistant coating layer contains dioctylsulfosuccinate and amidoquat in a molar ratio of 1:0.01 to 1:2, and the total content of dioctylsulfosuccinate and amidoquat is 1 to 12 weight based on the total aqueous solution. %am.
상기 디옥틸설포숙시네이트 및 아미도콰트는 몰비로서 1:0.01 ~ 1:2가 바람직한 바, 몰비가 상기 범위를 벗어나는 경우에는 방수시트(4)의 도포성이 저하되거나 도포 후에 표면의 수분흡착이 증가하여 도포막이 제거되는 문제점이 있다.The molar ratio of dioctylsulfosuccinate and amidoquat is preferably 1:0.01 to 1:2. If the molar ratio is outside the above range, the applicability of the waterproof sheet 4 may decrease or moisture adsorption on the surface may occur after application. There is a problem that the coating film is removed due to the increase.
상기 디옥틸설포숙시네이트 및 아미도콰트는 전체 조성물 수용액 중 1 ~ 12 중량%가 바람직한 바, 1 중량% 미만이면 방수시트(4)의 도포성이 저하되는 문제점이 있고, 12 중량%를 초과하면 도포막 두께의 증가로 인한 결정석출이 발생하기 쉽다.The dioctylsulfosuccinate and amidoquat are preferably used in an amount of 1 to 12% by weight in the total composition aqueous solution. If it is less than 1% by weight, there is a problem that the applicability of the waterproof sheet 4 is reduced, and if it exceeds 12% by weight, the applicability of the waterproof sheet 4 is reduced. Crystal precipitation is likely to occur due to an increase in coating film thickness.
한편, 본 내오염성 도포용 조성물을 방수시트(4)에 도포하는 방법으로는 스프레이법에 의해 도포하는 것이 바람직하다. 또한, 방수시트(4)의 최종 도포막 두께는 900 ~ 2300Å이 바람직하다. 상기 도포막의 두께가 900 Å미만이면 고온 열처리의 경우에 열화되는 문제점이 있고, 2300 Å을 초과하면 도포 표면의 결정석출이 발생하기 쉬운 단점이 있다.Meanwhile, it is preferable to apply the stain-resistant coating composition to the waterproof sheet 4 by spraying. In addition, the final coating film thickness of the waterproof sheet 4 is preferably 900 to 2300 Å. If the thickness of the coating film is less than 900 Å, there is a problem of deterioration in the case of high temperature heat treatment, and if it exceeds 2300 Å, there is a disadvantage that crystal precipitation on the coating surface is likely to occur.
또한, 본 내오염성 도포용 조성물은 디옥틸설포숙시네이트 0.1 몰 및 아미도콰트 0.05몰을 증류수 1000 ㎖에 첨가한 다음 교반하여 제조될 수 있다.Additionally, this stain-resistant coating composition can be prepared by adding 0.1 mole of dioctylsulfosuccinate and 0.05 mole of amidoquat to 1000 ml of distilled water and then stirring.
상기 구성 성분의 비율 및 도포막 두께를 상기와 같이 수치 한정한 이유는, 본 발명자가 수차례 실패를 거듭하면서 시험결과를 통해 분석한 결과, 상기 비율에서 최적의 오염방지 도포 효과를 나타내었다.The reason for limiting the ratio of the components and the thickness of the coating film to the above values is that the present inventor analyzed the test results after repeated failures and found that the ratio showed the optimal anti-contamination application effect.
그리고, 아스팔트(5)의 표면에는 차열코팅제가 도포될 수 있으며, 이에 따라 태양열이 아스팔트(5)에 전달되는 것일 일부 차단시킬 수 있다.In addition, a heat-insulating coating agent may be applied to the surface of the
이 차열코팅제는 자일렌 19중량%, 디메틸포름아미드 42중량%, 산화크롬 8중량%, 그라파이트 12중량%, 질화규소 7중량%, 수산화나트륨(NaOH) 5중량%, 산화티탄 3중량%, 발연 실리카 4중량% 로 구성된다.This heat-insulating coating agent contains 19% by weight of xylene, 42% by weight of dimethylformamide, 8% by weight of chromium oxide, 12% by weight of graphite, 7% by weight of silicon nitride, 5% by weight of sodium hydroxide (NaOH), 3% by weight of titanium oxide, and fumed silica. It consists of 4% by weight.
자일렌은 방열 코팅층 보호 등의 역할을 하며, 디메틸포름아미드는 바인더 수지 역할을 하고, 산화크롬은 내마모 역할을 하며, 그라파이트는 열전도성과 전기적 특성이 우수하고, 질화규소는 강도 향상 및 균열을 방지하며, 수산화나트륨은 분산제 역할을 하고, 산화티탄은 내후성을 위해서, 발연 실리카는 침강방지 역할을 한다.Xylene plays a role in protecting the heat dissipation coating layer, dimethylformamide acts as a binder resin, chromium oxide acts as wear resistance, graphite has excellent thermal conductivity and electrical properties, and silicon nitride improves strength and prevents cracking. , sodium hydroxide acts as a dispersant, titanium oxide serves for weather resistance, and fumed silica acts as an anti-settling agent.
차열코팅제의 두께는 8~1200㎛을 형성하는 것이 바람직하다.The thickness of the heat-insulating coating is preferably 8 to 1200㎛.
상기와 같이 구성 물질 및 구성 성분을 한정하고 혼합 비율의 수치를 한정한 이유는, 본 발명자가 수차례 실패를 거듭하면서 시험 결과를 통해 분석한 결과, 상기 구성 성분 및 수치 한정 비율에서 최적의 효과를 나타내었다.The reason for limiting the constituent materials and components and limiting the mixing ratio as described above is that the present inventor analyzed the test results after repeated failures and found that the optimal effect was achieved with the above-mentioned constituents and numerical ratio. indicated.
Claims (5)
상기 제2단계에서 사용되는 도막재는 탄화수소수지(Hydrocarbon Resin) 15-20중량%, SBR(Styrene-Butadiene Rubber) 5-15중량%, 아스팔트유화제(Asphalt Emulsifier) 5-10중량% 및 나머지 열가소성 엘라스토머(Thermoplastic Elastomer)로 조성되며;
상기 도막재를 구성할 때 도막재 조성물 100중량부에 대해, 비닐피롤리돈(Vinyl pyrrolidone) 10중량부, 1,3:2,4-비스(3,4-디메틸벤질리덴)솔비톨 10중량부, 질화붕소(Boron Nitride) 분말 5중량부를 더 첨가하여 조성한 것을 특징으로 하는 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법.The first step is to apply adhesive on the slab, which is a concrete floor; A second step of forming a coating layer by applying a coating material on the adhesive; A third step of forming a waterproof layer by laying a waterproof sheet on the coating layer; In the thermoplastic double composite waterproofing method for bridge surfaces, which includes a fourth step of paving asphalt on the waterproofing layer;
The coating material used in the second step is 15-20% by weight of hydrocarbon resin, 5-15% by weight of SBR (Styrene-Butadiene Rubber), 5-10% by weight of asphalt emulsifier, and the remaining thermoplastic elastomer ( Thermoplastic Elastomer);
When composing the coating material, 10 parts by weight of vinyl pyrrolidone, 10 parts by weight of 1,3:2,4-bis(3,4-dimethylbenzylidene)sorbitol, based on 100 parts by weight of the coating material composition. , A thermoplastic double composite waterproofing method for bridge surfaces with smooth blistering discharge, characterized by adding 5 parts by weight of Boron Nitride powder.
상기 방수시트는 중심 기재를 바인더조성물에 함침시켜, 모래-바인더-중심 기재-바인더-모래의 층구조로 두께 1.5-2.5mm를 갖도록 만들되, 상기 중심 기재는 폴리에스터, 폴리프로필렌, 폴리에틸렌 중 어느 하나의 섬유 원단인 것을 특징으로 하는 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법.According to paragraph 1,
The waterproof sheet is made by impregnating the central substrate with a binder composition to have a layer structure of sand-binder-central substrate-binder-sand with a thickness of 1.5-2.5mm, and the central substrate is any one of polyester, polypropylene, and polyethylene. A thermoplastic double composite waterproofing method for bridge surfaces with smooth blistering discharge, characterized in that it is made of a fiber fabric.
상기 바인더조성물은 탄화수소수지(Hydrocarbon Resin) 15-20중량%, 알콕시레이티드 알코올(alkoxylated alcohol) 2.5-5.0중량%, SBR(Styrene-Butadiene Rubber) 5-15중량%, 퍼플루오르(2,2-디메틸-1,3-디옥솔(Perfluoro(2,2-dimethyl-1,3-dioxole)) 2.5-4.5중량%, 아스팔트유화제(Asphalt Emulsifier) 5-10중량% 및 나머지 열가소성 엘라스토머(Thermoplastic Elastomer)로 조성된 것을 특징으로 하는 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수공법.According to paragraph 3,
The binder composition includes 15-20% by weight of hydrocarbon resin, 2.5-5.0% by weight of alkoxylated alcohol, 5-15% by weight of SBR (Styrene-Butadiene Rubber), and perfluorine (2,2- 2.5-4.5% by weight of dimethyl-1,3-dioxole (Perfluoro(2,2-dimethyl-1,3-dioxole)), 5-10% by weight of asphalt emulsifier, and the remaining thermoplastic elastomer. A thermoplastic double composite waterproofing method for bridge surfaces with smooth blistering discharge, characterized by the composition.
콘크리트 바닥인 슬래브(1) 위에 도포된 접착제(2); 상기 접착제(2) 위에 도포되어 도막층을 형성하는 도막재(3); 상기 도막재(3) 위에 설치되어 방수층을 형성하는 방수시트(4); 상기 방수시트(4) 위에 포장된 아스팔트(5)를 포함하는 것을 특징으로 하는 브리스터링 배출이 원활한 교면용 열가소성 2중 복합 방수구조.The first step is to apply adhesive on the slab, which is a concrete floor; A second step of forming a coating layer by applying a coating material on the adhesive; A third step of forming a waterproof layer by laying a waterproof sheet on the coating layer; It includes a fourth step of paving asphalt on the waterproofing layer; The coating material used in the second step is 15-20% by weight of hydrocarbon resin, 5-15% by weight of SBR (Styrene-Butadiene Rubber), 5-10% by weight of asphalt emulsifier, and the remaining thermoplastic elastomer ( Thermoplastic Elastomer); When composing the coating material, 10 parts by weight of vinyl pyrrolidone, 10 parts by weight of 1,3:2,4-bis(3,4-dimethylbenzylidene)sorbitol, based on 100 parts by weight of the coating material composition. , It relates to a thermoplastic double composite waterproofing structure for bridge surfaces with smooth blistering discharge using a thermoplastic double composite waterproofing method for smooth blistering discharge, which was created by adding 5 parts by weight of Boron Nitride powder,
Adhesive (2) applied on the slab (1), which is a concrete floor; A coating material (3) applied on the adhesive (2) to form a coating layer; A waterproof sheet (4) installed on the coating material (3) to form a waterproof layer; A thermoplastic double composite waterproof structure for a bridge surface with smooth blistering discharge, comprising asphalt (5) packed on the waterproof sheet (4).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020230112153A KR102639436B1 (en) | 2023-08-25 | 2023-08-25 | Thermoplastic double-composite waterproofing method and waterproofing structure for bridges with smooth blisterling discharge |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020230112153A KR102639436B1 (en) | 2023-08-25 | 2023-08-25 | Thermoplastic double-composite waterproofing method and waterproofing structure for bridges with smooth blisterling discharge |
Publications (1)
Publication Number | Publication Date |
---|---|
KR102639436B1 true KR102639436B1 (en) | 2024-02-23 |
Family
ID=90041789
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020230112153A KR102639436B1 (en) | 2023-08-25 | 2023-08-25 | Thermoplastic double-composite waterproofing method and waterproofing structure for bridges with smooth blisterling discharge |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR102639436B1 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101722126B1 (en) * | 2016-07-25 | 2017-04-03 | 현대브릿지(주) | Waterproof Layer for bridge and method for construction the same |
KR101988801B1 (en) | 2018-05-11 | 2019-06-12 | 이태범 | Heating complex water proof method for the bridge surface |
KR102384567B1 (en) * | 2021-08-05 | 2022-04-11 | 주식회사 씨엠에스 | Coating film waterproofing composition using emulsified asphalt |
KR102512432B1 (en) * | 2022-03-28 | 2023-03-21 | 케이비건설 주식회사 | Waterproof construction method |
-
2023
- 2023-08-25 KR KR1020230112153A patent/KR102639436B1/en active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101722126B1 (en) * | 2016-07-25 | 2017-04-03 | 현대브릿지(주) | Waterproof Layer for bridge and method for construction the same |
KR101988801B1 (en) | 2018-05-11 | 2019-06-12 | 이태범 | Heating complex water proof method for the bridge surface |
KR102384567B1 (en) * | 2021-08-05 | 2022-04-11 | 주식회사 씨엠에스 | Coating film waterproofing composition using emulsified asphalt |
KR102512432B1 (en) * | 2022-03-28 | 2023-03-21 | 케이비건설 주식회사 | Waterproof construction method |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107033611B (en) | High-grade asphalt composition with waterproof function and construction method using same | |
CA2607812C (en) | Method of applying asphalt waterproofing membrane material for buildings and bridge decks | |
KR101545011B1 (en) | Paving Method of Providing Inpermeable Intermediate Layer with Only One Paving Process with Paving Material Composition Comprising of Rubberized Asphalt | |
KR101712845B1 (en) | Bridge deck waterproofing structure using a grid with waterproof coating | |
US4175978A (en) | Road pavement and repair | |
JP5086917B2 (en) | Repair method for asphalt pavement | |
JP3640968B2 (en) | Stress-absorbing composite material for road repair | |
KR102036879B1 (en) | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
KR101810550B1 (en) | Bridge deck Waterproof composition and complex waterproof method using fiber reinforcing agent | |
KR100533231B1 (en) | Stretchy rubberized asphalt felt for waterproofing and waterproofing material of duplex rubberized asphalt membrane plus felt | |
KR101044499B1 (en) | Adhesive composition for use on roads and a method of adhesive construction using the same | |
KR102178147B1 (en) | A Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
KR101806135B1 (en) | Waterproof composition of Self-healing type composition and waterproof method using fiber reinforcing agent | |
KR100886158B1 (en) | Waterproofing method using waterproofing sheet with gas hole | |
KR101681531B1 (en) | Eco-friendly construction method use waterproof sheet and Eco-friendly waterproof sheet | |
KR102639436B1 (en) | Thermoplastic double-composite waterproofing method and waterproofing structure for bridges with smooth blisterling discharge | |
KR100607154B1 (en) | Waterproofing Material of Duplex Rubberized Asphalt Membrane plus Felt And Its Method For Application | |
KR100814087B1 (en) | The asphalt waterproofing sheet using butyl rubber or poly vinyl butyral and waterproofing method using the same | |
KR102199977B1 (en) | Bridge waterproofing structure and waterproofing method with improved adhesion between pavement layer and waterproofing layer | |
KR102262506B1 (en) | Waterproof structure for bridge | |
US4251586A (en) | Road pavement and repair | |
KR102058021B1 (en) | A Waterproofing Treatment Composition for Road and Complex Waterproofing Methods using Waterproofing Sheet | |
KR101386116B1 (en) | Method for constructing expansion joint opening using asphalt-based silant | |
KR100672004B1 (en) | Waterproof method for bridges | |
KR102641293B1 (en) | Thermoplastic double composite waterproofing method for bridge surfaces with rainwater penetration prevention structure on the edge of bridges and rainwater penetration prevention structure on the edge |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant |