KR102638591B1 - Manufacturing method of eco-friendly kitchen detergent containing natural substances - Google Patents
Manufacturing method of eco-friendly kitchen detergent containing natural substances Download PDFInfo
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- KR102638591B1 KR102638591B1 KR1020230058329A KR20230058329A KR102638591B1 KR 102638591 B1 KR102638591 B1 KR 102638591B1 KR 1020230058329 A KR1020230058329 A KR 1020230058329A KR 20230058329 A KR20230058329 A KR 20230058329A KR 102638591 B1 KR102638591 B1 KR 102638591B1
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- eco
- green papaya
- water
- friendly
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
Abstract
본 발명은 천연물질을 포함하는 친환경 주방세제의 제조방법에 관한 것으로 원적외선 나노필터를 거친 정제수에 껍질 손질된 그린파파야 열매를 혼합한 후 중탕하여 된 그린파파야 중탕수를 주방세제 제조에 사용함으로써 친환경적이면서도 세척력이 증대되도록 하기 위해, 정제수, 그린파파야 중탕수, 패각소성칼슘, 천일염, 베이킹소다, 베이스오일 및 글리세린의 혼합물을 포함하여 제조되는 것을 특징으로 한다.The present invention relates to a method of manufacturing an eco-friendly dish detergent containing natural substances, and is environmentally friendly by mixing purified green papaya fruit with peeled green papaya fruit and boiling it in a bath, and using it to manufacture a dish detergent. In order to increase the cleaning power, it is characterized in that it is manufactured including a mixture of purified water, green papaya water, calcined shell calcium, sea salt, baking soda, base oil, and glycerin.
Description
본 발명은 천연물질을 포함하는 친환경 주방세제의 제조방법에 관한 것으로서, 보다 상세하게는 원적외선 나노필터를 거친 정제수에 껍질 손질된 그린파파야 열매를 혼합한 후 중탕하여 된 그린파파야 중탕수를 주방세제 제조에 사용함으로써 친환경적이면서도 세척력이 증대되도록 하는 천연물질을 포함하는 친환경 주방세제의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing an eco-friendly dish detergent containing natural substances. More specifically, the present invention relates to a method of manufacturing an eco-friendly dish detergent containing natural substances. More specifically, the green papaya fruit is mixed with purified water that has passed through a far-infrared nanofilter and then boiled in a double boiler to produce a dish detergent using the green papaya double boiler water. It relates to a method of manufacturing an eco-friendly dish detergent containing natural substances that are environmentally friendly and increase cleaning power by using them.
일반적으로 세제란 오염에 대한 효율적인 세정을 도와주는 혼합물질로서, 계면활성제와 각종 보조성분으로 이루어지는데, 대부분이 합성 계면활성제를 사용하는 합성세제이다. 그런데 합성세제는 합성세제에 의해 환경오염이 유발되며, 또한, 체내에 흡수되어 질병의 원인이 되기도 하며, 주부습진을 비롯하여 각종 피부트러블을 유발시키기도 한다.In general, detergents are a mixture that helps in efficient cleaning of contaminants and are made up of surfactants and various auxiliary ingredients. Most of them are synthetic detergents that use synthetic surfactants. However, synthetic detergents cause environmental pollution, and can also cause diseases when absorbed into the body, and can also cause various skin problems, including eczema for housewives.
특히, 주방에서 사용되는 식기나, 행주, 수세미, 도마 등에는 음식물 찌꺼기와 수분으로 인하여 많은 종류의 세균이 번식하고, 세정 후에 잔류하는 음식물 찌꺼기가 부패하면서 불쾌한 냄새를 발생한다. 또한, 세제와 음식물찌꺼기 등에 접촉하는 사용자의 피부에 자극을 가하여 염증을 발생시키고, 음식물 중에서 생선, 육류, 물비린내(아민계 냄새), 김치(머캅탄계 냄새) 등의 냄새와, 싱크대의 배수구에 잔존하는 음식물 찌꺼기와 음식물 찌꺼기에서 번식하는 세균으로 인하여 발생하는 암모니아, 아민 등의 냄새는 쉽게 제거되지 않는다.In particular, many types of bacteria grow on dishes, dishcloths, scrubbers, cutting boards, etc. used in the kitchen due to food residue and moisture, and the food residue remaining after cleaning decays and generates an unpleasant odor. In addition, it irritates the user's skin when it comes in contact with detergents and food residue, causing inflammation, and causes odors such as fish, meat, fishy smell (amine-based smell), kimchi (mercaptan-based smell) in food, and the drain of the sink. Odors such as ammonia and amines generated by remaining food waste and bacteria growing in food waste are not easily removed.
또한, 음식의 조리과정에서 사용되는 각종 오일류 및 식재료가 포함하고 있는 기름 등은 물에 용해되지 않는 성질로 인하여 물로만 세정시에는 조리도구나 그릇에 부착되어 제거되지 않으므로 이후 사용 시 미끄러움과 끈적거림과 같은 감촉으로 거부감을 일으키고 세균이나 이물질이 부착하여 오염의 원인이 될 뿐 아니라 변색의 원인이 되고 있다. 또한, 상기한 오일류 외에도 각종 음식 찌꺼기가 그릇이나 도마에 형성된 미세 기공으로 침투한 후 제거되지 않아 세균번식의 원인이 된다.In addition, various oils used in the cooking process of food and the oil contained in food ingredients do not dissolve in water, so they stick to cooking utensils and dishes and cannot be removed when washed with water alone, making them slippery and sticky during subsequent use. It causes a feeling of rejection due to a scratchy texture, and bacteria or foreign substances attach to it, which not only causes contamination but also causes discoloration. In addition, in addition to the oils mentioned above, various food residues penetrate into the micropores formed in dishes or cutting boards and are not removed, causing bacterial growth.
기름기를 포함한 음식 찌꺼기의 제거를 위하여 종래에 사용되는 주방세제는 거품을 일으켜 세척력을 높이기 위한 석유화합물질인 LAS, AOS와 같은 계면활성제와 각종 보조성분으로 구성되는데, 이러한 석유계 계면활성제는 거품을 많이 발생시켜 이 거품을 헹구어내기 위해 많은 양의 물을 사용하게 만들고, 이 과정에서 나온 거품이 하수구를 통해 흘러나가 햇빛과 산소공급을 차단시켜 하천의 자정능력을 떨어뜨리는 원인이 된다. 또한, 합성세제의 보조성분인 인산염은 물속에 유기양분을 늘려 식물성 플랑크톤이 급증하게 한다. 이러한 부영화로 인해 발생하는 적조는 양식업에 많은 피해를 끼치며 그 일대의 수중생물들을 폐사할 뿐만 아니라, 조류나 미생물이 번식하게 되면 상수처리 과정에서 더 많은 화학약품을 투입하게 되므로 자원낭비 및 인체에 유해한 원인이 된다.Dishwashing detergents conventionally used to remove food residues, including grease, are composed of surfactants such as LAS and AOS, which are petroleum compounds to increase cleaning power by creating foam, and various auxiliary ingredients. These petroleum-based surfactants produce foam. By generating a large amount of water, a large amount of water is used to rinse away the foam, and the foam produced in this process flows out through the sewer, blocking sunlight and oxygen supply and reducing the river's self-purification ability. Additionally, phosphate, an auxiliary ingredient in synthetic detergents, increases organic nutrients in the water and causes phytoplankton to rapidly increase. The red tide that occurs due to this kind of subfertilization causes a lot of damage to the aquaculture industry and not only kills aquatic life in the area, but also causes more chemicals to be added during the water treatment process when algae or microorganisms multiply, which wastes resources and harms the human body. It can cause harm.
더욱이, 상기한 종래의 합성 주방세제는 인체에 해로운 독성을 갖는 물질이 포함되어 있는데 그 대표적인 것으로 불순물이 비소(60-70ppm)와 납성분, 오염재부착방지제로 사용되는 제올라이트, 중량제로 쓰이는 무수황산나트륨 등이다. 이들은 물고기의 경우 아가미 조직을 파괴하여 질식사시키고 전복,성게,어류,양서류 등의 생식능력을 떨어뜨리고, 기형률을 높이는 등 수중 생물에게 치명적인 유해성을 가진다. 또한 정수시설로 다 정화되지 않으므로 자연계를 돌고 돌아 다시 우리의 인체로 들어와 고스란히 쌓이게 되며, 이처럼 몸에 흡수된 합성세제 성분은 카드뮴이나 유기 수은 등 각종 중금속의 체내 흡수를 높일 뿐 아니라, 동물실험을 통해 정자의 파괴, 생식기능 저하, 기형아 출산 등을 불러일으킨다고 보고되고 있다. 뿐만 아니라 콜레스테롤의 흡수율을 높여 고혈압을 유발하고, 농약이나 식품 첨가물을 만나면 화학물질의 독성을 몇 배 강하게 만든다고 한다.Moreover, the conventional synthetic dish detergents described above contain substances that are harmful and toxic to the human body, representative examples of which include arsenic (60-70 ppm) and lead, zeolite used as an anti-adhesion agent for contaminants, and anhydrous sodium sulfate used as a weighting agent. etc. In the case of fish, they destroy the gill tissue and suffocate to death, reduce the reproductive ability of abalone, sea urchins, fish, and amphibians, and increase the deformity rate, making them fatally harmful to aquatic life. In addition, since not all of them are purified by water purification facilities, they circulate through the natural world and enter our human body again, accumulating intact. Synthetic detergent ingredients absorbed into the body not only increase the absorption of various heavy metals such as cadmium and organic mercury in the body, but have also been confirmed through animal testing. It is reported that it causes destruction of sperm, decreased reproductive function, and birth defects. In addition, it increases the absorption rate of cholesterol, causing high blood pressure, and when exposed to pesticides or food additives, it is said to make the toxicity of chemicals several times stronger.
한편, 최근 경제 성장과 더불어 국민 생활 수준의 향상으로 인해 건강한 삶을 추구하고자 하는 웰빙이라는 사회적 트랜드는 친환경 제품을 선호하는 소비 문화의 변화를 가져왔다. 환경과 인체에 유해한 환경 호르몬을 포함한 화학제품들은 체내에 축적되어 내분비 장애을 유발하고, 면역기능을 저하시켜 아토피와 같은 피부질환을 일으키는 요인으로 알려지면서 환경 친화적인 천연 제품의 소비 수요가 점점 증가되고 있는 것이다.Meanwhile, with the recent economic growth and the improvement in people's living standards, the social trend of well-being, which seeks to pursue a healthy life, has led to a change in consumer culture favoring eco-friendly products. As chemical products containing environmental hormones that are harmful to the environment and the human body are known to accumulate in the body, causing endocrine disorders and lowering immune function, causing skin diseases such as atopy, the demand for consumption of environmentally friendly natural products is increasing. will be.
이에 따라, 천연의 소재를 이용하여 환경 친화적이고, 세정력 및 항균성이 우수하며, 인간의 피부에도 이로운 주방용 세제에 대한 개발이 요구되고 있다.Accordingly, there is a demand for the development of kitchen detergents using natural materials that are environmentally friendly, have excellent cleaning and antibacterial properties, and are also beneficial to human skin.
이에 본 발명은 상기한 문제점을 일소하기 위해 창안한 것으로서, 원적외선 나노필터를 거친 정제수에 껍질 손질된 그린파파야 열매를 혼합한 후 중탕하여 된 그린파파야 중탕수를 주방세제 제조에 사용함으로써 친환경적이면서도 세척력이 증대되도록 하는 천연물질을 포함하는 친환경 주방세제의 제조방법에 주안점을 두고 그 기술적 과제로서 완성한 것이다.Accordingly, the present invention was created to eliminate the above-mentioned problems, and the green papaya double boiler water obtained by mixing peeled green papaya fruit with purified water that has passed through a far-infrared nanofilter and then boiling it in a double boiler is used to manufacture dish detergent, making it environmentally friendly and having great cleaning power. It was completed as a technical task with a focus on the manufacturing method of eco-friendly dishwashing detergent containing natural substances that increase the productivity of the product.
위 기술적 과제를 달성하기 위한 본 발명은, 천연물질을 포함하는 친환경 주방세제의 제조방법을 구성함에 있어서, 상기 정제수 72∼78중량％와, 그린파파야 중탕수 7∼12중량％와, 계면활성제 8∼10중량％와, 패각소성칼슘 0.1∼1.0중량％와, 천일염 1∼3중량％와, 베이킹소다 1∼3중량％와, 베이스오일 0.1∼1.0중량％와, 글리세린 0.5∼1.5중량％를 포함하는 혼합물을 포함하여 제조되고, 상기 그린파파야 중탕수는, 원적외선 나노필터를 거친 정제수 100중량부를 기준으로 껍질 손질된 그린파파야 열매 1∼3중량부를 혼합하여 중탕기 내에 충진한 후, 60∼65℃의 온도에서 24∼30시간 동안 중탕하여 제조되어지되, 상기 그린파파야 열매는 껍질을 탈피시켜 손질된 덜 익은 녹색 또는 녹황색을 띤 열매부분만을 2∼3등분 하여 사용토록 하고, 상기 그린파파야 중탕수는, 상기 중탕 후 23∼25℃의 온도에서 16∼20시간 동안 자연냉각시킨 후, 정제필터로 여과하여 사용토록 하며, 상기 계면활성제는 천연 계면 활성제인 알킬폴리글루코사이드(C08-14 alkyl polyglucoside)를 사용토록 하고, 상기 패각소성칼슘은 패각을 1,000∼1,500 ℃의 온도에서 소성된 분말로 사용토록 하며, 상기 패각소성칼슘 분말은 칼슘 함량 55∼65 %, 기공율 73∼77 %, 비표면적 2.5∼2.6 ㎡/g, 수분흡착율 390∼393 ㎤/g, 평균입경 0.1∼0.3 mm이며, 상기 혼합물에 솔잎허브 추출물 1∼1.5중량％와, 황기 추출물 1∼1.5중량％와, 어성초 추출물 1∼1.5중량％를 더 포함하여 제조됨을 특징으로 하는 천연물질을 포함하는 친환경 주방세제의 제조방법을 제공한다.In order to achieve the above technical problem, the present invention constitutes a method for manufacturing an eco-friendly dish detergent containing natural substances, comprising 72 to 78% by weight of purified water, 7 to 12% by weight of green papaya water boiling water, and surfactant 8. Contains ~10% by weight, 0.1~1.0% by weight of calcined shell calcium, 1~3% by weight of sea salt, 1~3% by weight of baking soda, 0.1~1.0% by weight of base oil, and 0.5~1.5% by weight of glycerin. The green papaya double boiler is prepared by mixing 1 to 3 parts by weight of peeled green papaya fruit with 100 parts by weight of purified water that has passed through a far-infrared nanofilter, filling the double boiler, and then boiling water at 60 to 65°C. It is manufactured by double boiling at a temperature for 24 to 30 hours, and the green papaya fruit is used by dividing only the unripe green or greenish yellow fruit parts that have been peeled and cleaned into 2 to 3 parts, and the green papaya double boiling water is, After the above bath, it is naturally cooled at a temperature of 23 to 25°C for 16 to 20 hours, and then filtered through a purification filter before use. The surfactant is a natural surfactant, alkyl polyglucoside (C08-14 alkyl polyglucoside). And, the shell calcined calcium is used as a powder obtained by calcining shells at a temperature of 1,000 to 1,500 ° C. The shell calcined calcium powder has a calcium content of 55 to 65%, a porosity of 73 to 77%, and a specific surface area of 2.5 to 2.6 ㎡/ g, moisture adsorption rate of 390-393 cm3/g, average particle diameter of 0.1-0.3 mm, and 1-1.5% by weight of pine needle herb extract, 1-1.5% by weight of Astragalus extract, and 1-1.5% by weight of Houttuynia cordata extract were added to the mixture. A method for manufacturing an eco-friendly dish detergent containing natural substances is provided.
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그리고, 상기 베이스오일은 올리브오일, 팜오일, 피마자오일 중 적어도 하나 이상 혼합되어 사용되는 것을 특징으로 한다.In addition, the base oil is characterized in that it is used in a mixture of at least one of olive oil, palm oil, and castor oil.
상기한 본 발명에 의하면 원적외선 나노필터를 거친 정제수에 껍질 손질된 그린파파야 열매를 혼합한 후 중탕하여 된 그린파파야 중탕수를 주방세제 제조에 사용함으로써 친환경적이면서도 세척력이 증대되는 등의 효과가 있다.According to the above-described present invention, green papaya fruit with peels is mixed with purified water that has passed through a far-infrared nanofilter and then boiled in a double boiler. The green papaya double boiler water is used to manufacture a dish detergent, which is environmentally friendly and has the effect of increasing cleaning power.
이하 본 발명의 실시를 위한 구체적인 내용을 첨부한 도면을 참조하여 더욱 상세하게 설명한다.Hereinafter, specific details for implementing the present invention will be described in more detail with reference to the attached drawings.
본 발명은 원적외선 나노필터를 거친 정제수에 껍질 손질된 그린파파야 열매를 혼합한 후 중탕하여 된 그린파파야 중탕수를 주방세제 제조에 사용함으로써 친환경적이면서도 세척력이 증대되도록 하는 천연물질을 포함하는 친환경 주방세제의 제조방법에 관한 것이다.The present invention is an eco-friendly dish detergent containing natural substances that are eco-friendly and increase cleaning power by mixing purified green papaya fruit with peeled green papaya fruit and boiling it in purified water that has passed through a far-infrared nanofilter and using the green papaya water in a double boiler to manufacture dish detergent. It is about manufacturing method.
본 발명의 천연물질을 포함하는 친환경 주방세제의 제조방법을 구현하기 위해 정제수, 그린파파야 중탕수, 계면활성제, 패각소성칼슘, 천일염, 베이킹소다, 베이스오일 및 글리세린의 혼합물을 준비한다.In order to implement the manufacturing method of an eco-friendly dish detergent containing natural substances of the present invention, a mixture of purified water, green papaya water boiling water, surfactant, calcined shell calcium, sea salt, baking soda, base oil, and glycerin is prepared.
본 발명에서는 친환경적이면서도 세척력이 증대되도록 하기 위해 정제수에 그린파파야 중탕수를 혼합하여 사용한다.In the present invention, green papaya water is mixed with purified water to increase cleaning power while being environmentally friendly.
상기 그린파파야 중탕수를 마련하기 위해 먼저 껍질 손질된 그린파파야 열매를 준비한 후, 원적외선 나노필터를 거친 정제수 100중량부를 기준으로 껍질 손질된 그린파파야 열매 1∼3중량부를 혼합토록 한다. 그런 다음, 중탕기 내에 정제수와 껍질 손질된 그린파파야 열매를 충진한 후, 60∼65℃의 온도에서 24∼30시간 동안 중탕하여 그린파파야 중탕수를 수득토록 한다.To prepare the green papaya double boiler, first prepare green papaya fruit with the peel removed, and then mix 1 to 3 parts by weight of the peeled green papaya fruit with 100 parts by weight of purified water that has passed through a far-infrared nanofilter. Then, purified water and peeled green papaya fruit are filled in a double boiler, and then double boiled at a temperature of 60 to 65°C for 24 to 30 hours to obtain green papaya double boiler.
그리고, 상기 그린파파야 중탕수는, 상기 중탕 후 23∼25℃의 온도에서 16∼20시간 동안 자연냉각시킨 후, 정제필터로 여과하여 사용토록 함이 바람직하다.In addition, the green papaya water boiler is preferably used after being naturally cooled at a temperature of 23 to 25° C. for 16 to 20 hours and then filtered through a purification filter.
이때, 상기 그린파파야 열매의 준비 시 껍질을 탈피시켜 손질된 덜 익은 녹색 또는 녹황색을 띤 그린파파야 열매부분만을 크게 2∼3등분 하여 사용토록 하는 것이 바람직하다.At this time, when preparing the green papaya fruit, it is desirable to use only the unripe green or greenish-yellow green papaya fruit portion that has been peeled and cleaned, and divided into 2 to 3 large parts.
상기 그린파파야 열매는 비타민C와 카로티오니드가 풍부한 열매로서 녹색 또는 녹황색에서 적황색으로 변하고 과육은 짙은 녹색계열이다. 과육은 두껍고 콩알만한 많은 종자가 젤리 같은 것에 싸여 있다.The green papaya fruit is a fruit rich in vitamin C and carothione, which changes from green or greenish yellow to reddish yellow, and the flesh is dark green. The flesh is thick and has many pea-sized seeds wrapped in a jelly-like substance.
그린파파야는 상처 치유를 돕는 효소가 함유되어 있어 동남아시아와 아프리카 등지에서 상처와 염증치료에 사용되고 있고, 그린파파야에는 파파인이란 효소가 들어 있는데 이것은 단백질을 분해하는 효소이다. 또한 그린파파야 열매는 비타민, 무기질, 유기산 등을 함유하고 있어 피부에 있는 세포 재생을 촉진시키고 각질의 유착을 줄여주며, 피부를 보다 부드럽고 유연하게 만들어 주는 것으로 알려져 있다. 이 QNs 아니라 그린파파야는 지방 및 탄수화물을 포함하고 있어 친환경적이면서도 높은 세척력을 기대할 수 있게 된다.Green papaya contains an enzyme that helps wound healing, so it is used to treat wounds and inflammation in Southeast Asia and Africa. Green papaya contains an enzyme called papain, which is an enzyme that breaks down proteins. In addition, green papaya fruit contains vitamins, minerals, and organic acids, and is known to promote cell regeneration in the skin, reduce dead skin adhesion, and make the skin softer and more flexible. Green papaya, as well as QNs, contains fat and carbohydrates, so it is environmentally friendly and can be expected to have high cleaning power.
위와 같이 그린파파야 중탕수를 준비한 후, 상기 정제수 72∼78중량％와, 그린파파야 중탕수 7∼12중량％와, 계면활성제 8∼10중량％와, 패각소성칼슘 0.1∼1.0중량％와, 천일염 1∼3중량％와, 베이킹소다 1∼3중량％와, 베이스오일 0.1∼1.0중량％와, 글리세린 0.5∼1.5중량％를 포함하여 본 발명의 친환경 주방세제를 제조토록 한다.After preparing green papaya double boiler water as above, 72 to 78% by weight of the purified water, 7 to 12% by weight of green papaya double boiler water, 8 to 10% by weight of surfactant, 0.1 to 1.0% by weight of calcined shell calcium, and sea salt. The eco-friendly dish detergent of the present invention is prepared by containing 1 to 3% by weight of baking soda, 0.1 to 1.0% by weight of base oil, and 0.5 to 1.5% by weight of glycerin.
상기 계면활성제는 하나의 분자 내에서 물에 녹기 쉬운 친수성 성분과, 기름에 녹기 쉬운 친유성 성분이 동시에 존재하는 물질로, 물과 기름의 경계면에 흡착해서 그 면의 성질을 현저하게 바꿔주는 역할을 하는 것으로, 본 발명에서는 천연 계면 활성제인 알킬폴리글루코사이드(C08-14 alkyl polyglucoside)를 사용토록 한다.The surfactant is a substance that contains both a hydrophilic component that is easily soluble in water and a lipophilic component that is easily soluble in oil within one molecule. It adsorbs to the interface between water and oil and plays a role in significantly changing the properties of that surface. In this way, in the present invention, alkyl polyglucoside (C08-14 alkyl polyglucoside), a natural surfactant, is used.
상기 알킬폴리글루코사이드는 코나코파 라고도 하며 비이온 계면활성제이며, 사탕, 옥수수, 무, 팜, 코코넛 오일에서 추출한 비이온 천연계면활성제생분해성이 뛰어나서 친환경적인 계면활성제로 많이 사용되는 것으로, 주로 샴푸, 주방세제, 세탁세제, 바디워시, 천연비누제조원료로 사용된다. 또한, 알킬폴리글루소사이드는 친수성과 친유성기를 지닌 다양한 당 복합물로서, 자극이 없고 독성이 없으며 자연재생 가능한 친환경 계면활성제로 성능도 뛰어나고, 또한 인체, 환경에 대한 안전성이 뛰어난 소재이며, 비이온계면활성제와 음이온계면활성제의 장점을 구현할 수 있는 분자 구조를 가지고 있다.The alkyl polyglucoside is also called conacopa and is a non-ionic surfactant. It is a non-ionic natural surfactant extracted from candy, corn, radish, palm, and coconut oil. It has excellent biodegradability and is widely used as an eco-friendly surfactant. It is mainly used in shampoos and kitchens. It is used as a raw material for making detergents, laundry detergents, body wash, and natural soap. In addition, alkylpolyglusoside is a variety of sugar complexes with hydrophilic and lipophilic groups. It is non-irritating, non-toxic, and has excellent performance as an eco-friendly surfactant that can be recycled naturally. It is also a material with excellent safety for the human body and the environment, and is non-ionic. It has a molecular structure that can realize the advantages of surfactants and anionic surfactants.
상기 패각소성칼슘은 패각(조개껍질) 성분을 갖는 천연 방부제로서 패각을 1,000∼1,500 ℃의 온도에서 소성된 분말로 사용토록 함이 바람직한데, 이렇게 소성한 경우 이온화도가 높아지면서 세척력이 보다 우수하게 된다. 이는 이온화 칼슘이 높아 흡수가 빠르고 다양한 미네랄이 함유되어 세척 과정에서 세척 대상 물질의 분해를 빠르게 달성할 수 있으며, 또한 본 발명에 따른 패각소성칼슘 분말은 강한 살균 효과를 가짐과 아울러 친환경 주방세제의 보존 기능을 수행하게 된다.The shell calcined calcium is a natural preservative containing shell components. It is preferable to use the shell as a powder calcined at a temperature of 1,000 to 1,500 ° C. When calcined in this way, the degree of ionization increases and the cleaning power is improved. . This has high ionized calcium, so it is fast absorbed and contains various minerals, so it can quickly achieve decomposition of materials to be cleaned during the washing process. In addition, the calcined shell calcium powder according to the present invention has a strong sterilizing effect and preserves eco-friendly dish detergent. performs its function.
상기 패각소성칼슘 분말의 칼슘 함량은 55∼65 %에 해당할 수 있다. 또한 상기 패각소성칼슘의 기타 물리적인 특성으로서 기공율은 73∼77 %, 비표면적 2.5∼2.6 ㎡/g, 수분흡착율 390∼393 ㎤/g을 보일 수 있다.The calcium content of the shell calcined calcium powder may be 55 to 65%. In addition, other physical properties of the shell calcined calcium include a porosity of 73 to 77%, a specific surface area of 2.5 to 2.6 m2/g, and a moisture adsorption rate of 390 to 393 cm3/g.
또한 상기 패각소성칼슘 분말은 특별한 제한이 있는 것은 아니지만 바람직하게는 평균입경이 0.1∼0.3 mm인 것이 바람직하다. 상기 패각소성칼슘 분말의 평균입경이 0.1 mm 미만인 경우에는 세척력이 충분히 발휘되기 어려워 바람직하지 않으며, 상기 패각소성칼슘 분말의 평균입경이 0.5 mm를 초과하는 경우에는 분말이 거칠어 세정 과정에서 불편함을 유발할 수 있으면서 식기 등에 손상을 줄 수 있으므로 바람직하지 않다.In addition, the shell calcined calcium powder is not particularly limited, but preferably has an average particle diameter of 0.1 to 0.3 mm. If the average particle diameter of the calcined calcium powder is less than 0.1 mm, it is difficult to sufficiently exert cleaning power, which is not desirable. If the average particle diameter of the calcined calcium powder is more than 0.5 mm, the powder is rough, causing discomfort during the cleaning process. However, it is not advisable because it can cause damage to dishes, etc.
또한 상기 패각은 조개류의 껍데기에 해당하는 것인데, 본 발명에서는 굴, 조개, 꼬막, 가리비, 전복, 고둥, 키조개 및 배말로 이루어지는 군으로부터 선택된 어느 하나 이상의 패각이 이에 해당할 수 있다.In addition, the shell corresponds to the shell of a shellfish, and in the present invention, any one or more shells selected from the group consisting of oysters, clams, cockles, scallops, abalone, whelks, clams, and sea bass may correspond to this.
상기 천일염은 국산 천일염으로, 마그네슘, 칼슘 등의 함유량이 높다. 외부 환경으로 인해 가득 쌓인 먼지와 노폐물을 제거하는데 용이하게 사용된다.The sea salt is a domestic sea salt and has a high content of magnesium and calcium. It is easily used to remove dust and waste accumulated due to the external environment.
상기 베이킹소다는 빵, 과자의 제조 시 제품을 팽창하게 하여 맛을 좋게 하고 연하게 하여 소화가 잘 되도록 하기 위한 식품 첨가물이다. 식품에 알칼리제, 팽창제, 완충제 등으로 사용되는 것으로 알려져 있지만, 사실 베이킹소다는 우리 실생활에 수도 없이 큰 효과를 안겨다 준다. 특히 불규칙한 입자 모양을 가지고 있어 냄새 흡수나 깔끔한 세척에 뛰어난 효과를 보인다. 우리 몸에서 자연적으로 생성되는 물질이기도 한 베이킹 소다는 인체에 독성이 없는 것으로 알려져 최근 화학 생활용품으로 대체 되어 많이 사용되고 있다. 가정집에 베이킹 소다 하나만 있어도 여러 쓰임새로 사용될 수 있다. 과일이나 채소를 잔류농약 없이 완벽하게 씻어낼 때 쓰이기도 하고, 여러 가지 악취를 없애는데 효과적이어서 베이킹 소다 한숟가락을 풀어서 바르거나 뿌리면 냄새가 없어진다. 그을린 냄비나 물건에 베이킹소다를 뿌려뒀다가 수세미로 닦아내면 그을음을 단번에 해결할 수 있다. 특히, 기름 때를 완벽히 제거하는데에 효과적이다. 지방산을 분해해 각종 찌든 때를 빼는데도 유용하므로, 용기 세척할 때에 유용하다. 또한 베이킹 소다의 원료가 탄산수소나트륨인데, 탄산수소나트륨은 몸을 알칼리와 해주어 항암제가 잘 듣게 해주어 항암 치료에 대한 연구가 많이 이루어지고 있다.The baking soda is a food additive used in the manufacture of bread and cookies to expand the product, improve the taste, soften it, and improve digestion. Although it is known to be used as an alkaline agent, leavening agent, and buffering agent in food, baking soda actually has countless great effects in our daily lives. In particular, it has an irregular particle shape and is excellent at absorbing odors and cleaning thoroughly. Baking soda, a substance naturally produced in our bodies, is known to be non-toxic to the human body and has recently been widely used as a chemical household product. Even just baking soda at home can be used for many purposes. It is used to completely wash fruits and vegetables without residual pesticides, and is effective in eliminating various odors, so dissolving a spoonful of baking soda and applying or spraying it will eliminate the smell. You can solve the soot at once by sprinkling baking soda on a burnt pot or object and wiping it off with a scrubber. In particular, it is effective in completely removing oil stains. It is also useful in breaking down fatty acids and removing various stains, so it is useful when cleaning containers. In addition, the raw material of baking soda is sodium bicarbonate. Sodium bicarbonate alkalizes the body and helps anticancer drugs work better, so many studies are being conducted on anticancer treatment.
상기 베이스오일은 올리브오일, 팜오일, 피마자오일 중 적어도 하나 이상 혼합된 것을 사용토록 한다. 이때, 상기 올리브 오일은 올리브 열매에서 추출한 오일로 보습 효과가 뛰어난 것으로 알려져 있고, 비타민 E를 다량 함유하고 있어 아기의 피부를 부드럽고 탄력있게 해주며 민감성 피부를 가진 사람이 사용하는 데에도 무리가 없다. 또한, 상기 팜오일은 매우 높은 포화지방을 함유한 몇 안 되는 식물유 중 하나로 아프리카 야자수의 과육에서 얻고, 오일의 제조를 위해 다른 오일에 혼합되어 사용된다. 그리고, 상기 피마자오일은 피마자 씨에서 추출한 지방유로 독특한 점착성이 있으며 모발에 친화성이 있으나 끈적거리는 느낌이 있다. 피마자의 종자를 압착하여 얻는 지방유로서, 아주까리기름이라고도 한다. 종자 속에 약 45% 함유된다. 종자에는 독성이 있는데, 압착하여 얻은 기름에는 없으며, 독성은 짜고 남은 찌꺼기에 남는다. 담황색으로 약간 점성이 있고, 간유(肝油)처럼 특이한 냄새가 강하다. 대부분 다른 지방유와 달리 알코올에 녹는 것이 특징이다. 의약품 외에도 윤활유, 로드유 제조용 등 다방면에 쓰인다.The base oil should be a mixture of at least one of olive oil, palm oil, and castor oil. At this time, the olive oil is extracted from olive fruits and is known to have an excellent moisturizing effect. It contains a large amount of vitamin E, so it makes the baby's skin soft and elastic, and can be used by people with sensitive skin. In addition, the palm oil is one of the few vegetable oils containing very high saturated fat. It is obtained from the pulp of African palm trees and used by mixing with other oils to produce oil. In addition, the castor oil is a fatty oil extracted from castor seeds and has a unique stickiness and affinity for hair, but has a sticky feeling. It is a fatty oil obtained by pressing castor seeds, and is also called castor oil. Contains about 45% in seeds. The seeds are toxic, but the oil obtained by pressing them is not, and the toxicity remains in the residue left after squeezing. It is light yellow in color, slightly viscous, and has a strong, unique odor like liver oil. Unlike most other fatty oils, it is characterized by being soluble in alcohol. In addition to pharmaceuticals, it is used in a variety of fields, including for the production of lubricants and rod oils.
상기 글리세린은 글리세롤이라고 불리는 무색, 무취의 액체로 점섬이 매우 강하고 뛰어난 수분 함유와 보습 함유를 지니고 있어 주로 화장품에 많이 사용되며, 화장품에 사용되는 만큼 피부에 안전한 성분과 피부의 유연성을 증가시켜 주는 기능을 갖고 있어 사용자에게 안전함을 부여할 수 있게 된다. 이러한 글리세린은 세제의 점성을 상승시켜 효과적인 세척이 가능하게 하며, 특히 지방족 3가 알코올인 글리세린은 하이드록실기가 세제의 점성을 상승시켜 세정 효과를 높일 수 있게 된다.The glycerin is a colorless and odorless liquid called glycerol. It has a very strong viscosity and has excellent moisture and moisturizing properties, so it is mainly used in cosmetics. As it is used in cosmetics, it is a safe ingredient for the skin and has the function of increasing the flexibility of the skin. It is possible to provide safety to the user. Such glycerin increases the viscosity of the detergent, enabling effective cleaning. In particular, the hydroxyl group of glycerin, an aliphatic trihydric alcohol, increases the viscosity of the detergent, thereby improving the cleaning effect.
상기와 같이 정제수, 그린파파야 중탕수, 계면활성제, 패각소성칼슘, 천일염, 베이킹소다, 베이스오일 및 글리세린의 혼합물을 사용하여 제조되는 천연물질을 포함하는 친환경 주방세제에 솔잎허브 추출물 1∼1.5중량％와, 황기 추출물 1∼1.5중량％와, 어성초 추출물 1∼1.5중량％를 더 포함하여 제조 사용토록 할 수 있다.As described above, an eco-friendly dish detergent containing natural substances prepared using a mixture of purified water, green papaya water, surfactant, calcined shell calcium, sea salt, baking soda, base oil and glycerin, and 1 to 1.5% by weight of pine needle herb extract. It can be manufactured and used by further containing 1 to 1.5% by weight of Astragalus extract and 1 to 1.5% by weight of Houttuynia cordata extract.
상기 솔잎허브 추출물은 비타민A, 비타민B, 비타민C, 비타민K, 베타카로틴 등이 풍부하게 들어 있어 피부건강에 매우 좋다. 이러한 성분들은 노화를 예방하는 항산화 효능이 뛰어나고, 콜라겐 분해를 막는 각종 성분이 피부를 더욱 탄력 있게 만들어준다. 솔잎의 히드록시메틸프라논(HMF) 성분은 멜라닌 생성을 억제해 피부를 맑고 투명하게 가꿔준다. 솔잎은 각종 세균과 곰팡이가 자라지 못 하게 하는 항균성 물질이 많고 항염증 효과가 있어, 아토피 피부 완화를 위한 기능성 화장품 원료로도 쓰이게 된다.The pine needle herb extract is rich in vitamin A, vitamin B, vitamin C, vitamin K, and beta-carotene, and is very good for skin health. These ingredients have excellent antioxidant effects that prevent aging, and various ingredients that prevent collagen decomposition make the skin more elastic. The hydroxymethylfranone (HMF) ingredient in pine needles suppresses melanin production and makes the skin clear and transparent. Pine needles are rich in antibacterial substances that prevent the growth of various bacteria and fungi and have an anti-inflammatory effect, so they are also used as a functional cosmetic raw material to relieve atopic skin.
상기 황기 추출물은 대표적인 강장제의 효능을 가지고 있다. 만성 피로 증후군에 효과를 보인다고도 한다. 황기의 다당류는 비특이 변역을 활성시켰으며, 몽골황기 물추출물의 주사는 선천성 심질환 소아의 면역기능을 개선했다고 한다. 이외에도 황기는 Th1/Th2 면역계 불균형을 개선하며, 세포자멸사 과정에도 영샹을 미친다. 황기는 당뇨에도 응용되는데 중국은 황기를 주사 및 경구제로 활용하고 있다. 몇몇 연구를 보면, 황기는 췌장의 베타세포가 파괴하는 것을 억제하며, 인슐린 저항성을 개선한다. 최근에는 당뇨병성 족부에 황기, 지황을 배합하여 사용하는 것에 대한 연구가 진행되고 있다. 이들 본초의 병행은 당뇨병성 족부에서 육아조직의 형성을 촉진하고, 섬유아세포의 생존율을 높였다고 보고된다. 특히 황기와 지황의 비율이 3:1일 때 가장 효과적이었다. 또한 특정한 독성 및 부작용이 크게 없다.The Astragalus extract has a representative tonic effect. It is also said to be effective for chronic fatigue syndrome. The polysaccharide of Astragalus astragalus activated non-specific immune function, and injection of water extract of Mongolian Astragalus was said to improve immune function in children with congenital heart disease. In addition, Astragalus improves the Th1/Th2 immune system imbalance and also affects the apoptosis process. Astragalus is also applied to diabetes, and in China, Astragalus is used as an injection and oral medication. Some studies show that astragalus inhibits the destruction of pancreatic beta cells and improves insulin resistance. Recently, research is being conducted on the use of a combination of Astragalus and Rehmannia glutinosa for diabetic feet. It is reported that the combination of these herbs promotes the formation of granulation tissue in diabetic feet and increases the survival rate of fibroblasts. In particular, it was most effective when the ratio of Astragalus and Rehmannia glutinosa was 3:1. Additionally, there are no significant specific toxicities or side effects.
상기 어성초 추출물은 어성초의 잎과 뿌리를 건조시킨 후 용매를 통해 추출한 것으로 플라보노이드, 쿠에르시트린, 마이르센, 라우리알데히드 등의 성분이 풍부하게 들어있어 뛰어난 항균작용을 할 수 있는데 특히 대장균, 장티푸스균, 황색포도상구균, 폐렴구균 등을 확실히 억제한다. 또한 피부 진균에도 효과가 뛰어나 염증작용을 억제하고 조직을 재생시켜 줄 수 있는 천연 항생제이다.The Houttuynia cordata extract is obtained by drying the leaves and roots of Houttuynia cordata and then extracting them with a solvent. It is rich in components such as flavonoids, quercitrin, myrcene, and laurealdehyde, and can have excellent antibacterial effects, especially against Escherichia coli and Typhoid fever bacteria. , Staphylococcus aureus, and pneumococcus. It is also a natural antibiotic that is highly effective against skin fungi, suppressing inflammation and regenerating tissues.
상술된 바와 같은 본 발명의 천연물질을 포함하는 친환경 주방세제의 제조방법에 의하면, 원적외선 나노필터를 거친 정제수에 껍질 손질된 그린파파야 열매를 혼합한 후 중탕하여 된 그린파파야 중탕수를 주방세제 제조에 사용함으로써 친환경적이면서도 세척력을 증대시킬 수 있게 된다.According to the method for producing an eco-friendly dish detergent containing natural substances of the present invention as described above, the green papaya double boiler water obtained by mixing peeled green papaya fruit with purified water that has passed through a far-infrared nanofilter and then boiling it in a double boiler is used to manufacture dish detergent. By using it, it is eco-friendly and can increase cleaning power.
이상에서 설명한 본 발명은, 도면에 도시된 일실시 예를 참고로 설명되었으나 이는 예시적인 것에 불과하며, 본 기술 분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시 예가 가능하다는 점을 명확히 하여야 할 것이다. 따라서, 본 발명의 진정한 기술적 보호 범위는 첨부된 청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술적 사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 할 것이다.The present invention described above has been described with reference to an embodiment shown in the drawings, but this is merely illustrative, and various modifications and other equivalent embodiments can be made by those skilled in the art. should be clarified. Therefore, the true technical protection scope of the present invention should be interpreted in accordance with the attached claims, and all technical ideas within the equivalent scope should be interpreted as being included in the scope of the present invention.
Claims (7)
정제수 72∼78중량％와, 그린파파야 중탕수 7∼12중량％와, 계면활성제 8∼10중량％와, 패각소성칼슘 0.1∼1.0중량％와, 천일염 1∼3중량％와, 베이킹소다 1∼3중량％와, 베이스오일 0.1∼1.0중량％와, 글리세린 0.5∼1.5중량％를 포함하는 혼합물을 포함하여 제조되고,
상기 그린파파야 중탕수는, 원적외선 나노필터를 거친 정제수 100중량부를 기준으로 껍질 손질된 그린파파야 열매 1∼3중량부를 혼합하여 중탕기 내에 충진한 후, 60∼65℃의 온도에서 24∼30시간 동안 중탕하여 제조되어지되, 상기 그린파파야 열매는 껍질을 탈피시켜 손질된 덜 익은 녹색 또는 녹황색을 띤 열매부분만을 2∼3등분 하여 사용토록 하고, 상기 그린파파야 중탕수는, 상기 중탕 후 23∼25℃의 온도에서 16∼20시간 동안 자연냉각시킨 후, 정제필터로 여과하여 사용토록 하며,
상기 계면활성제는 천연 계면 활성제인 알킬폴리글루코사이드(C08-14 alkyl polyglucoside)를 사용토록 하고,
상기 패각소성칼슘은 패각을 1,000∼1,500 ℃의 온도에서 소성된 분말로 사용토록 하며, 상기 패각소성칼슘 분말은 칼슘 함량 55∼65 %, 기공율 73∼77 %, 비표면적 2.5∼2.6 ㎡/g, 수분흡착율 390∼393 ㎤/g, 평균입경 0.1∼0.3 mm이며,
상기 혼합물에 솔잎허브 추출물 1∼1.5중량％와, 황기 추출물 1∼1.5중량％와, 어성초 추출물 1∼1.5중량％를 더 포함하여 제조됨을 특징으로 하는 천연물질을 포함하는 친환경 주방세제의 제조방법.
In constructing a method for manufacturing an eco-friendly dish detergent containing natural substances,
72 to 78% by weight of purified water, 7 to 12% by weight of green papaya water boil, 8 to 10% by weight of surfactant, 0.1 to 1.0% by weight of calcined shell calcium, 1 to 3% by weight of sea salt, and 1 to 1% of baking soda. It is prepared including a mixture containing 3% by weight, 0.1 to 1.0% by weight of base oil, and 0.5 to 1.5% by weight of glycerin,
The green papaya double boiler is prepared by mixing 1 to 3 parts by weight of peeled green papaya fruit with 100 parts by weight of purified water that has passed through a far-infrared nanofilter, filling the double boiler, and then boiling the water at a temperature of 60 to 65°C for 24 to 30 hours. The green papaya fruit is prepared by peeling the skin and dividing only the unripe green or greenish-yellow fruit parts into 2 to 3 parts. After being naturally cooled at the temperature for 16 to 20 hours, it is filtered through a purification filter before use.
The surfactant is a natural surfactant, alkyl polyglucoside (C08-14 alkyl polyglucoside),
The shell calcined calcium is used as a powder obtained by calcining shells at a temperature of 1,000 to 1,500 ° C. The shell calcined calcium powder has a calcium content of 55 to 65%, a porosity of 73 to 77%, a specific surface area of 2.5 to 2.6 ㎡/g, Moisture adsorption rate is 390-393 ㎤/g, average particle diameter is 0.1-0.3 mm,
A method for producing an eco-friendly dish detergent containing natural substances, characterized in that the mixture further contains 1 to 1.5% by weight of pine needle herb extract, 1 to 1.5% by weight of Astragalus extract, and 1 to 1.5% by weight of Houttuynia cordata extract.
상기 베이스오일은 올리브오일, 팜오일, 피마자오일 중 적어도 하나 이상 혼합되어 사용되는 것을 특징으로 하는 천연물질을 포함하는 친환경 주방세제의 제조방법.According to paragraph 1,
A method for producing an eco-friendly dish detergent containing natural substances, wherein the base oil is used in a mixture of at least one of olive oil, palm oil, and castor oil.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4143223B2 (en) * | 1999-07-30 | 2008-09-03 | 一丸ファルコス株式会社 | Cosmetic composition containing moisturizing plant extract |
| KR101539744B1 (en) * | 2015-02-11 | 2015-07-28 | 김미순 | A kitchen antimicrobial detergent containing an eco-friendly antimicrobial agent for preventing atopic dermatitis |
| KR20150111229A (en) * | 2014-03-25 | 2015-10-05 | 노병철 | Manufacturing method of black curcuma and extract and powder thereof |
| KR102226774B1 (en) * | 2019-10-29 | 2021-03-11 | 정해영 | Detergent comprising the extract of astragalus membranaceus, polydonati rhizoma and pine leaf, and the method of manufacturing thereof |
| KR102265107B1 (en) * | 2020-12-31 | 2021-06-15 | 주식회사 태승뷰티산업 | Composition for ecofriendly dishwashing capable of room temperature mix |
| KR102390505B1 (en) | 2021-08-08 | 2022-04-25 | 김수현 | Dishwashing detergent composition comprising natural material and the manufacturing method of eco-friendly dishwashing detergent |
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- 2023-05-04 KR KR1020230058329A patent/KR102638591B1/en active IP Right Grant
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4143223B2 (en) * | 1999-07-30 | 2008-09-03 | 一丸ファルコス株式会社 | Cosmetic composition containing moisturizing plant extract |
| KR20150111229A (en) * | 2014-03-25 | 2015-10-05 | 노병철 | Manufacturing method of black curcuma and extract and powder thereof |
| KR101539744B1 (en) * | 2015-02-11 | 2015-07-28 | 김미순 | A kitchen antimicrobial detergent containing an eco-friendly antimicrobial agent for preventing atopic dermatitis |
| KR102226774B1 (en) * | 2019-10-29 | 2021-03-11 | 정해영 | Detergent comprising the extract of astragalus membranaceus, polydonati rhizoma and pine leaf, and the method of manufacturing thereof |
| KR102265107B1 (en) * | 2020-12-31 | 2021-06-15 | 주식회사 태승뷰티산업 | Composition for ecofriendly dishwashing capable of room temperature mix |
| KR102390505B1 (en) | 2021-08-08 | 2022-04-25 | 김수현 | Dishwashing detergent composition comprising natural material and the manufacturing method of eco-friendly dishwashing detergent |
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