KR102613274B1 - Four-ply sheets comprising leaf mustard extracts, and its manufacturing method - Google Patents
Four-ply sheets comprising leaf mustard extracts, and its manufacturing method Download PDFInfo
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- KR102613274B1 KR102613274B1 KR1020230113112A KR20230113112A KR102613274B1 KR 102613274 B1 KR102613274 B1 KR 102613274B1 KR 1020230113112 A KR1020230113112 A KR 1020230113112A KR 20230113112 A KR20230113112 A KR 20230113112A KR 102613274 B1 KR102613274 B1 KR 102613274B1
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- extract
- sheet
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/22—Fungicidal, bactericidal, insecticidal, disinfecting, antiseptic, or corrosion-inhibiting paper antistatic, antioxygenic paper
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
- A47K10/18—Holders; Receptacles
- A47K10/22—Holders; Receptacles for rolled-up webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F—MECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F5/00—Attaching together sheets, strips or webs; Reinforcing edges
- B31F5/04—Attaching together sheets, strips or webs; Reinforcing edges by exclusive use of adhesives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J199/00—Adhesives based on natural macromolecular compounds or on derivatives thereof, not provided for in groups C09J101/00 -C09J107/00 or C09J189/00 - C09J197/00
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
- D21H23/56—Rolls
- D21H23/58—Details thereof, e.g. surface characteristics, peripheral speed
- D21H23/60—Details thereof, e.g. surface characteristics, peripheral speed the material on the applicator roll being subjected to a particular treatment before applying to the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/70—Multistep processes; Apparatus for adding one or several substances in portions or in various ways to the paper, not covered by another single group of this main group
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
- D21H27/32—Multi-ply with materials applied between the sheets
- D21H27/34—Continuous materials, e.g. filaments, sheets, nets
Abstract
본 발명은 일측면에 데코무늬가 형성되고 타측면에 갓 추출물이 포함된 항균접착성조성물이 코팅된 두 겹 시트(P1+P2)와, 일측면에 데코무늬가 형성된 또 다른 두 겹 시트(P3+P4)가 합지되어 이루어지는 4겹시트(P1+P2+P3+P4)로 구성되되, 상기 4겹시트는, 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 시트면과 상기 두 겹 시트(P3+P4)의 일측면이 마주보게 합지되는 것을 특징으로 하는 갓 추출물이 포함된 4겹 시트에 관한 것이다. The present invention is a two-ply sheet (P1 + P2) with a decorative pattern on one side and coated with an antibacterial adhesive composition containing mustard extract on the other side, and another two-ply sheet (P3) with a decorative pattern on one side. +P4) is composed of a 4-ply sheet (P1+P2+P3+P4) laminated together, wherein the 4-ply sheet includes the sheet surface coated with the antibacterial adhesive composition of the two-ply sheet (P1+P2) and the It relates to a four-ply sheet containing mustard extract, characterized in that one side of the two-ply sheet (P3 + P4) is laminated facing each other.
Description
본 발명은, 갓 추출물이 포함된 4겹 시트에 관한 것이다.The present invention relates to a 4-ply sheet containing leaf extract.
본 발명은, 한 쌍의 더블 시트가 접합되어 이루어지는 4겹시트로 이루어지되, 갓 추출물이 포함되는 것을 특징으로 하는 4겹 시트에 관한 것이다.The present invention relates to a 4-ply sheet consisting of a pair of double sheets joined together, and characterized in that it contains leaf extract.
본 발명은, 갓 추출물이 포함된 항균접착성조성물이 더블 시트 내측에 코팅됨으로서 변기 내 청결 유지와 화장실 내 악취를 저감에 도움이 되는 추출물을 포함하는 4겹 시트에 관한 것이다.The present invention relates to a four-ply sheet containing an extract that helps maintain cleanliness in the toilet and reduce bad odors in the toilet by coating the inside of the double sheet with an antibacterial adhesive composition containing leaf extract.
본 발명은, 갓 추출물이 포함된 항균접착성조성물이 더블 시트 내측에 코팅되어 제조되는 갓 추출물이 포함된 4겹 시트 제조방법에 관한 것이다. The present invention relates to a method of manufacturing a four-ply sheet containing mustard extract, which is manufactured by coating the inside of a double sheet with an antibacterial adhesive composition containing mustard extract.
본 발명은, 2010.04.08. 한국 특허등록 제0953123호 "은나노-쑥이 함유된 복층 페이퍼 시트의 제조방법" 및 2021.11.05. 한국 특허등록 제2324915호 "애완동물용 천연성분 페이퍼 시트 및 그 제조방법"에서 제조설비를 크게 변경하지 않으면서, 새로운 효과를 가진 갓 추출물이 포함된 4겹 시트 및 그 제조방법에 관한 것이다. This invention, 2010.04.08. Korean Patent Registration No. 0953123 “Manufacturing method of multi-layer paper sheet containing silver nano-mugwort” and 2021.11.05. Korean Patent Registration No. 2324915, “Natural Ingredient Paper Sheet for Pets and its Manufacturing Method,” relates to a 4-ply sheet containing leaf extract with new effects and its manufacturing method without significantly changing the manufacturing equipment.
화장실을 청결하게 관리하기 위한 인류의 노력은 과거부터 현재까지 이어져 왔다. 이는 화장실이 용변을 처리하는 곳인 만큼 세균과 악취에서 자유롭지 못하기 때문이다. 화장실 내 세균에는 대장균, 노로바이러스, 포도상구균, 장알균, 연쇄상구균, 녹농균 등 31종 이상이 존재하며 이는 인체에 해로운 영향을 미친다. 연구에 따르면, 용변의 세균이 화장실 내 높은 습도가 조합되면 평균 10제곱Cm당 3천800백 마리의 세균이 번식되는 것으로 알려져 있다. 특히 변기 두껑을 닫지 않고 물을 내리는 경우, 변기 표면에 붙어있던 병균이 외부로 로켓처럼 분사되어 화장실 사방으로 비산되는데, 이는 문고리나 변기 외부 표면에까지 세균과 바이러스가 번식하는 원인이 된다. 많은 사람들이 공동으로 사용하는 공중화장실은 세심한 관리가 어렵기 때문에 이러한 세균, 바이러스 및 악취에 취약하며, 이는 몸이 약한 노인이나 영유아의 건강에 치명적일 수 있다. Humanity's efforts to keep toilets clean have continued from the past to the present. This is because the bathroom is not free from germs and bad smells as it is a place to dispose of urine. There are more than 31 types of bacteria in the bathroom, including E. coli, norovirus, staphylococcus, enterococcus, streptococcus, and Pseudomonas aeruginosa, which have a harmful effect on the human body. According to research, it is known that an average of 3,800 hundred bacteria per 10 square centimeters are propagated when feces bacteria are combined with high humidity in the bathroom. In particular, if you flush the toilet without closing the lid, the germs attached to the toilet surface are sprayed outward like a rocket and scattered in all directions of the toilet. This causes bacteria and viruses to multiply on the door handle and the outer surface of the toilet. Public restrooms shared by many people are difficult to maintain carefully, so they are vulnerable to bacteria, viruses, and odors, which can be fatal to the health of the elderly or infants and young children.
이에, 한국특허공개 제10-2009-0049927호 (2009.05.19) "하이드로겔 제형의 변기 세정제 조성물" 및 한국특허공개 제10-2019-0001774호(2019.01.07) "실리콘 오일을 포함하는 변기 세정제 조성물" 등 변기 내 세균 및 악취를 제거하기 위한 세정제에 관한 기술이 출원된 바 있으나, 매번 구입하여 사용해야 하므로 사용이 번거롭고, 이를 사용하고 일정 기간까지만 효과가 있어 주기적으로 상기 세정제를 이용해 청소를 하지 않는 한 지속적 효능을 누리기 어렵다는 문제가 있다. 또한, 변기의 저수조 내에 고형, 액상 조성물을 투입하여 담가두는 방식의 경우 일정 시간이 지나면 점점 옅어져 기능이 저하되는 문제가 있다. Accordingly, Korean Patent Publication No. 10-2009-0049927 (2009.05.19) “Hydrogel-type toilet cleaner composition” and Korean Patent Publication No. 10-2019-0001774 (2019.01.07) “Toilet bowl cleaner containing silicone oil” There has been an application for a technology for a cleaner to remove bacteria and bad odors in the toilet, such as "composition", but it is cumbersome to use because it has to be purchased and used every time, and it is only effective for a certain period of time after use, so it is difficult to regularly clean with the cleaner. There is a problem that it is difficult to enjoy continuous efficacy. In addition, in the case of the method of pouring solid or liquid composition into the water tank of the toilet and soaking it, there is a problem that the composition gradually becomes lighter over a certain period of time and its function deteriorates.
또한, 한국등록특허 제10-0954721호 (2010.04.19) "천연 추출물을 함유하는 항균활성이 뛰어난 화장실 및 욕실 세정용 조성물"과 같이 세정 또는 악취를 제거하는 용도의 물티슈 또는 오일티슈 등 발명도 있으나, 이는 화장실 또는 욕조를 직접적으로 청소하기 위한 목적의 발명으로, 일반 화장실 이용객이 용변을 처리할 용도의 두루마리 화장지를 목적으로 하는 본 발명과 비교하기에 적절치 않다. 물에 쉽게 녹는 두루마리 휴지와 달리, 물티슈나 오일티슈는 물에서 분해되지 않아 배관을 막는 문제가 있기 때문이다. In addition, there are inventions such as wet tissues or oil tissues for cleaning or removing bad odors, such as Korean Patent No. 10-0954721 (2010.04.19) “Composition for cleaning toilets and bathrooms with excellent antibacterial activity containing natural extracts.” , This is an invention for the purpose of directly cleaning a toilet or bathtub, and is not appropriate for comparison with the present invention, which is intended for toilet rolls used by general bathroom users to dispose of their bowels. Unlike toilet paper rolls, which easily dissolve in water, wet tissues or oil tissues do not decompose in water, which poses the problem of clogging pipes.
본 발명은 상기 문제를 해결하기 위하여, 두 겹의 시트가 결합된 두 겹 시트 한 쌍을 접합하여 4겹시트(P1+P2+P3+P4)를 제조하되, 상기 4겹시트 내측에 갓 추출물이 포함된 항균접착성조성물이 코팅되는 갓 추출물이 포함된 4겹 시트를 제공하는 것을 발명의 목적으로 한다. In order to solve the above problem, the present invention manufactures a four-ply sheet (P1+P2+P3+P4) by joining a pair of two-ply sheets in which two ply sheets are combined, and the fresh extract is inside the four-ply sheet. The purpose of the invention is to provide a four-ply sheet containing mustard extract coated with the included antibacterial adhesive composition.
또한, 상기 4겹시트(P1+P2+P3+P4)를 소정의 물에 적셔 물티슈처럼 활용가능한 갓 추출물이 포함된 4겹 시트를 제공하는 것을 발명의 목적으로 한다. In addition, the purpose of the invention is to provide a 4-ply sheet containing fresh green leaf extract that can be used as a wet tissue by soaking the 4-ply sheet (P1+P2+P3+P4) in a predetermined amount of water.
본 발명은 항균접착성조성물을 코팅된 갓 추출물이 포함된 4겹 시트가 대·소변 등 극소부위 세정에 사용된 후 변기 내 투하되면, 변기 내 잔존된 항균접착성조성물로 인하여 변기 내 청결이 유지되고 악취가 저감되는 갓 추출물이 포함된 4겹 시트를 제공하는 것을 발명의 목적으로 한다. In the present invention, when a 4-ply sheet containing mustard extract coated with an antibacterial adhesive composition is used for cleaning very small areas such as stool and urine and then dropped into the toilet, the cleanliness of the toilet is maintained due to the antibacterial adhesive composition remaining in the toilet. The purpose of the invention is to provide a four-ply sheet containing leaf extract that reduces bad odor.
본 발명은, 2010.04.08. 한국 특허등록 제0953123호 "은나노-쑥이 함유된 복층 페이퍼 시트의 제조방법" 및 2021.11.05. 한국 특허등록 제2324915호 "애완동물용 천연성분 페이퍼 시트 및 그 제조방법"에서 제조설비를 크게 변경하지 않으면서, 새로운 효과를 가진 갓 추출물이 포함된 4겹 시트 및 그 제조방법에 관한 것이다. This invention, 2010.04.08. Korean Patent Registration No. 0953123 “Manufacturing method of multi-layer paper sheet containing silver nano-mugwort” and 2021.11.05. Korean Patent Registration No. 2324915, “Natural Ingredient Paper Sheet for Pets and its Manufacturing Method,” relates to a 4-ply sheet containing leaf extract with new effects and its manufacturing method without significantly changing the manufacturing equipment.
상기 문제를 해결하기 위해, To solve the above problem,
본 발명은 하기, 복층 페이퍼 시트 제조장치를 통해 4겹 시트를 제조하는 것으로서, 한 쌍의 두 겹 시트를 구비하는 단계(S1)와, The present invention is to manufacture a 4-ply sheet through a multi-layer paper sheet manufacturing apparatus, including the step (S1) of providing a pair of two-ply sheets,
상기 한 쌍의 두 겹 시트 중 하나(P1+P2)가 각추 형태의 돌기(14a)가 형성되는 제1데코무늬실린더(14) 및 제1압력 로울러(12) 사이로 통과되어 가압되면서 상기 두 겹 시트 일측면에 데코무늬가 형성되는 단계(S2)와, One of the pair of two-ply sheets (P1 + P2) is passed between the first deco pattern cylinder 14 and the first pressure roller 12 in which the pyramid-shaped protrusion 14a is formed and is pressed, thereby forming the two-ply sheet. A step (S2) in which a decoration pattern is formed on one side,
상기 한 쌍의 두 겹 시트 중 다른 하나(P3+P4)가 각추 형태의 돌기(24a)가 형성되는 제2데코무늬실린더(24) 및 제2압력 로울러(22) 사이로 통과되어 가압되면서 상기 두 겹 시트 일측면에 데코무늬가 형성되는 단계(S3)와, The other one of the pair of two-ply sheets (P3 + P4) is passed between the second deco pattern cylinder 24 and the second pressure roller 22 in which pyramid-shaped protrusions 24a are formed and pressed, thereby forming the two layers. A step (S3) in which a decoration pattern is formed on one side of the sheet,
갓 추출물이 포함된 항균접착성조성물이 잉크공급챔버(C)에 충진되고, 상기 잉크공급챔버(C)가 잉크공급 로울러(34)와 접촉되어 상기 잉크공급 로울러(34)에 상기 항균접착성조성물이 1차 전이되는 단계(S4)와, The antibacterial adhesive composition containing fresh extract is filled in the ink supply chamber (C), and the ink supply chamber (C) is in contact with the ink supply roller (34) to apply the antibacterial adhesive composition to the ink supply roller (34). This first transition step (S4),
상기 항균접착성조성물이 1차 전이된 잉크공급 로울러(34)가 전이 실린더(32)와 접촉되면서, 전이돌기(32a)가 표면에 형성된 전이돌기(32a)에 상기 항균접착성조성물이 2차 전이되는 단계(S5)와, As the ink supply roller 34 on which the antibacterial adhesive composition is first transferred comes into contact with the transfer cylinder 32, the antibacterial adhesive composition is secondaryly transferred to the transfer protrusions 32a formed on the surface. Step (S5) and,
상기 항균접착성조성물이 2차 전이된 전이돌기(32a)가 상기 데코무늬가 형성된 두 겹 시트(P1+P2)의 데코무늬가 형성되지 않은 시트면과 접촉되면서 상기 의 데코무늬가 형성되지 않은 두 겹 시트(P1+P2)의 일측면에 항균접착성조성물이 3차 전이되어 코팅되는 단계(S6)와, The transfer protrusion 32a, to which the antibacterial adhesive composition is secondaryly transferred, is brought into contact with the sheet surface on which the decoration pattern is not formed of the two-ply sheet (P1 + P2) on which the decoration pattern is formed, and the two sheets on which the decoration pattern is not formed are A step (S6) in which the antibacterial adhesive composition is thirdly transferred and coated on one side of the double sheet (P1 + P2),
상기 일측면에 데코무늬가 형성되고 타측면에 항균접착성조성물이 코팅된 두 겹 시트(P1+P2)와 상기 일측면에 데코무늬가 형성된 두 겹 시트(P3+P4)가 제1압력 로울러(12) 및 제2압력 로울러(22) 사이에 동시 통과되어 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 면에 상기 두 겹 시트(P3+P4)가 접합됨으로써 4겹시트(P1+P2+P3+P4)가 형성되는 단계(S7)와, A two-ply sheet (P1 + P2) with a deco pattern formed on one side and coated with an antibacterial adhesive composition on the other side and a two-ply sheet (P3 + P4) with a deco pattern formed on one side are formed on a first pressure roller ( 12) and the second pressure roller 22 are simultaneously passed between the two-ply sheets (P1 + P2) and the two-ply sheets (P3 + P4) are bonded to the surface coated with the antibacterial adhesive composition, thereby forming a four-ply sheet ( A step (S7) in which P1+P2+P3+P4) is formed,
상기 4겹시트(P1+P2+P3+P4)가 합지롤(40)을 통과하여 합지되고, 상기 합지된 최종 4겹시트가 가이드 로울러(G)를 통하여 권취용 보빈(51)으로 이송되는 단계(S8)가 포함되는 갓 추출물이 포함된 4겹 시트 제조방법을 제공한다. The 4-ply sheets (P1+P2+P3+P4) are laminated through the lamination roll 40, and the laminated final 4-ply sheets are transferred to the winding bobbin 51 through the guide roller (G). (S8) provides a method for manufacturing a 4-ply sheet containing leaf extract.
또한, 각추 형태의 돌기(14a)가 형성되는 제1데코무늬실린더(14)와, 제1압력 로울러(12)를 구비하여, 상기 데코무늬실린더(14A) 및 제1압력 로울러(12) 사이를 두 겹 시트(P1+P2)를 통과시켜 가압하면서 상기 두 겹 시트(P1+P2) 일측면에 데코무늬를 형성하는 제1패턴성형부(10); In addition, it is provided with a first deco pattern cylinder (14) in which pyramid-shaped protrusions (14a) are formed and a first pressure roller (12), between the deco pattern cylinder (14A) and the first pressure roller (12). A first pattern forming unit (10) that passes through the two-ply sheets (P1+P2) and presses them to form a deco pattern on one side of the two-ply sheets (P1+P2);
각추 형태의 돌기(24a)가 형성되는 제2데코무늬실린더(24)와, 제2압력 로울러(22)를 구비하여, 상기 데코무늬실린더(24) 및 제2압력 로울러(22) 사이를 두 겹 시트(P3+P4)를 통과시켜 가압하면서 상기 를 두 겹 시트(P3+P4) 일측면에 데코무늬를 형성하는 제2패턴성형부(20);It is provided with a second deco pattern cylinder (24) in which pyramid-shaped protrusions (24a) are formed and a second pressure roller (22), and a double layer is formed between the deco pattern cylinder (24) and the second pressure roller (22). a second pattern forming unit (20) that passes the sheet (P3+P4) and presses it to form a deco pattern on one side of the two-ply sheet (P3+P4);
갓 추출물이 포함된 항균접착성조성물이 충전되는 잉크공급챔버(C)와, An ink supply chamber (C) filled with an antibacterial adhesive composition containing fresh extract,
상기 항균접착성조성물이 충전되는 잉크공급챔버(C)로부터 상기 항균접착성조성물이 공급되는 잉크공급 로울러(34)와,an ink supply roller (34) through which the antibacterial adhesive composition is supplied from an ink supply chamber (C) in which the antibacterial adhesive composition is filled;
상기 잉크공급 로울러(34)와 접촉되는 전이돌기(32a)가 표면에 형성되는 전이실린더(32)를 포함하고, 상기 전이돌기(32a)에 의해 상기 시트(P1+P2)의 일측면이 항균접착성조성물로 코팅되되, 상기 전이실린더(32)는 상기 제1압력 로울러(12)와 접촉되는 조성물전이부(30); A transition protrusion (32a) in contact with the ink supply roller 34 includes a transition cylinder (32) formed on the surface, and one side of the sheet (P1 + P2) is antibacterially bonded by the transition projection (32a). It is coated with a sex composition, and the transfer cylinder 32 includes a composition transfer portion 30 in contact with the first pressure roller 12;
제1패턴성형부(10)와, 제2패턴성형부(20)와, 조성물전이부(30)를 통해 상기 각각의 시트(P1+P2), 시트(P3+P4)가 접합되어 형성된 4겹시트(P1+P2+P3+P4)를 포함하고, 4-ply formed by bonding each of the sheets (P1 + P2) and sheets (P3 + P4) through the first pattern forming part 10, the second pattern forming part 20, and the composition transfer part 30 Includes sheets (P1+P2+P3+P4),
상기 4겹시트(P1+P2+P3+P4)를 최종 합지하는 합지롤(40);, 상기 합지롤(40)를 통해 최종 합지된 4겹시트(P1+P2+P3+P4)를 가이드 로울러(G)를 통해 권취용 보빈(51)으로 이송하는 최종형성부(50);를 포함하는 복층 페이퍼 시트 제조장치를 제공한다. A lamination roll 40 for final lamination of the 4-ply sheets (P1+P2+P3+P4); a guide roller for the 4-ply sheets (P1+P2+P3+P4) finally laminated through the lamination roll 40 It provides a multi-layer paper sheet manufacturing apparatus including a final forming unit 50 that is transferred to the winding bobbin 51 through (G).
첫째, 용변 처리 후 변기 내 화장지를 버리면, 화장지의 항균 성분이 변기내부에 잔존되어 세균이 억제되는 효과가 있다. First, if you throw away the toilet paper in the toilet after handling the toilet, the antibacterial ingredients of the toilet paper remain inside the toilet, which has the effect of suppressing bacteria.
둘째, 용변 처리 후 변기 내 화장지를 버리면, 화장지의 항균 성분이 변기내부에 잔존되어 변기 뚜껑을 열고 물을 내렸을 때 변기의 외부 및 화장실 내의 세균을 억제하는 효과가 있다. Second, when toilet paper is thrown away in the toilet after toilet treatment, the antibacterial ingredients of the toilet paper remain inside the toilet, which has the effect of suppressing bacteria on the outside of the toilet and inside the toilet when the toilet lid is opened and water is flushed.
셋째, 용변 처리 후 변기 내 화장지를 버리면, 합침된 항균, 살균 및 탈취 성분이 변기에 잔존되어 악취 성분의 제거 또는 중화를 보조하는 효과가 있다.Third, when toilet paper is thrown away in the toilet after toilet treatment, the mixed antibacterial, sterilizing and deodorizing ingredients remain in the toilet, which has the effect of assisting in the removal or neutralization of odorous ingredients.
넷째, 용변 처리 후 변기 내 화장지를 버리면, 합침된 향기 성분이 변기에 잔존되어 방향 효과가 있다.Fourth, if you throw away the toilet paper in the toilet after defecating, the scented ingredients remain in the toilet and have a fragrance effect.
다섯째, 저수조 내에 고형 및 액상 조성물을 주기적으로 투입해야하는 종래 발명과 다르게 용변 처리 후 변기 내 화장지를 버리기만 하면 되므로, 편의성이 우수하다.Fifth, unlike conventional inventions that require periodic injection of solid and liquid compositions into a water storage tank, convenience is excellent because all you have to do is dispose of the toilet paper in the toilet after handling the toilet.
여섯째, 변기의 수도관을 따라 내려간 항균, 살균 및 탈취 성분이 자외선 및 오존의 접촉반응 통한 미세입자 및 대장균을 제거하는 3차 수처리 과정에서 무기 항균제를 통한 수질 처리를 보조하므로 환경 친화적인 효과가 있다.Sixth, the antibacterial, sterilizing, and deodorizing ingredients that flow down the toilet's water pipe assist in water quality treatment through inorganic antibacterial agents in the tertiary water treatment process, which removes fine particles and E. coli through the contact reaction of ultraviolet rays and ozone, making it environmentally friendly.
일곱째, 변기의 배관을 막는 주요 원인인 물티슈 사용을 대체하는 효과가 있다.Seventh, it has the effect of replacing the use of wet tissues, which is the main cause of clogged toilet pipes.
여덟째, 항균접착성조성물로 내측을 코팅하면서 두 겹 시트(P1+P2)와 두 겹 시트(P3+P4) 사이에 격분리가 저지되는 효과가 있다. Eighth, coating the inside with an antibacterial adhesive composition has the effect of preventing separation between the two-ply sheets (P1 + P2) and the two-ply sheets (P3 + P4).
아홉째, 2010.04.08. 한국 특허등록 제0953123호 "은나노-쑥이 함유된 복층 페이퍼 시트의 제조방법" 및 2021.11.05. 한국 특허등록 제2324915호 "애완동물용 천연성분 페이퍼 시트 및 그 제조방법"에서 제조설비의 큰 변경없이 새로운 제품을 생산하는 효과가 있다. 한편, 본 출원인은 상기 한국 등록 제0953123호 권리자로써 상기 제조방법을 이용한 천연성분 페이퍼 시트지의 생선설비를 갖추고 있는바, 펄프 가공 사업에서 제조설비는 한번 시공하면 시설을 변경하거나 새로운 시설을 추가하기 어려운 문제가 있으므로, 기존 설비를 크게 바꾸지 않으면서 기존과 다른 새로운 제품을 개발하는 것은 원가 절감에 매우 중요하다.Ninth, 2010.04.08. Korean Patent Registration No. 0953123 “Manufacturing method of multi-layer paper sheet containing silver nano-mugwort” and 2021.11.05. Korean Patent Registration No. 2324915, “Natural ingredient paper sheet for pets and manufacturing method thereof,” has the effect of producing a new product without major changes in manufacturing equipment. Meanwhile, the present applicant, as the holder of the above Korean Registration No. 0953123, is equipped with equipment for producing natural ingredient paper sheets using the above manufacturing method. In the pulp processing business, once the manufacturing equipment is constructed, it is difficult to change the facility or add new facilities. Because of this problem, developing new products that are different from existing ones without significantly changing existing facilities is very important for cost reduction.
도 1은 본 발명의 갓 추출물이 포함된 4겹 시트의 제조 공정도.
도 2는 본 발명의 갓 추출물이 포함된 4겹 시트의 작용을 도시한 흐름도.
도 3은 본 발명의 갓 추출물이 포함된 4겹 시트의 작용을 도시한 흐름도.
도 4는 본 발명의 갓 추출물이 포함된 4겹 시트의 항균접창성조성물이 화장실 내 세균과 함께 방출되어 공간 내 탈취 및 항균 효과가 일어나는 것이 표현된 도면. Figure 1 is a manufacturing process diagram of a 4-ply sheet containing mustard extract of the present invention.
Figure 2 is a flow chart showing the operation of a 4-ply sheet containing mustard extract of the present invention.
Figure 3 is a flow chart showing the operation of a 4-ply sheet containing mustard extract of the present invention.
Figure 4 is a view showing that the antibacterial adhesive composition of the 4-ply sheet containing the mustard extract of the present invention is released together with bacteria in the bathroom to produce deodorizing and antibacterial effects in the space.
이하, 갓 추출물이 포함된 4겹 시트 및 이의 제조방법에 따른 구체적 내용을 살펴본다.Hereinafter, we will look at the details of the 4-ply sheet containing mustard extract and its manufacturing method.
먼저, 본 발명의 갓 추출물이 포함된 4겹 시트 제조방법을 살펴본다.First, we will look at the method of manufacturing a 4-ply sheet containing the leaf extract of the present invention.
본 발명의 갓 추출물이 포함된 4겹 시트는, 복층 페이퍼 시트 제조장치를 통해 제조된다.The 4-ply sheet containing the mustard extract of the present invention is manufactured using a multi-layer paper sheet manufacturing device.
본 발명의 갓 추출물이 포함된 4겹 시트 제조방법은, 두 겹 시트 한 쌍이 구비되는 단계(S1)와, The method for manufacturing a four-ply sheet containing mustard extract of the present invention includes the steps of providing a pair of two-ply sheets (S1),
상기 두 겹 시트 중 하나의 시트(P1+P2)가 각추 형태의 돌기(14a)가 형성되는 제1데코무늬실린더(14) 및 제1압력 로울러(12) 사이로 통과되어 가압되면서 상기 두 겹 시트(P1+P2) 일측면에 데코무늬가 형성되는 단계(S2)와, One of the two-ply sheets (P1 + P2) is passed between the first deco pattern cylinder 14 and the first pressure roller 12 in which pyramid-shaped protrusions 14a are formed and is pressed, forming the two-ply sheet ( P1 + P2) a step (S2) in which a decoration pattern is formed on one side,
상기 두 겹 시트 중 다른 하나의 시트(P3+P4)가 각추 형태의 돌기(24a)가 형성되는 제2데코무늬실린더(24) 및 제2압력 로울러(22) 사이로 통과되어 가압되면서 상기 두 겹 시트(P3+P4) 일측면에 데코무늬가 형성되는 단계(S3)와,The other sheet (P3 + P4) of the two-ply sheets is passed between the second deco pattern cylinder 24 and the second pressure roller 22 in which pyramid-shaped protrusions 24a are formed and is pressed, thereby forming the two-ply sheet. (P3+P4) A step (S3) in which a decoration pattern is formed on one side,
갓 추출물이 포함된 항균접착성조성물이 잉크공급챔버(C)에 충진되고, 상기 잉크공급챔버(C)가 잉크공급 로울러(34)와 접촉되어 상기 잉크공급 로울러(34)에 상기 항균접착성조성물이 1차 전이되는 단계(S4)와, The antibacterial adhesive composition containing fresh extract is filled in the ink supply chamber (C), and the ink supply chamber (C) is in contact with the ink supply roller (34) to apply the antibacterial adhesive composition to the ink supply roller (34). This first transition step (S4),
상기 항균접착성조성물이 1차 전이된 잉크공급 로울러(34)가 전이 실린더(32)와 접촉되면서, 전이돌기(32a)가 표면에 형성된 전이돌기(32a)에 상기 항균접착성조성물이 2차 전이되는 단계(S5)와, As the ink supply roller 34 on which the antibacterial adhesive composition is first transferred comes into contact with the transfer cylinder 32, the antibacterial adhesive composition is secondaryly transferred to the transfer protrusions 32a formed on the surface. Step (S5) and,
상기 항균접착성조성물이 2차 전이된 전이돌기(32a)가 상기 데코무늬가 형성된 두 겹 시트(P1+P2)의 데코무늬가 형성되지 않은 시트면과 접촉되면서 상기 의 데코무늬가 형성되지 않은 두 겹 시트(P1+P2)의 일측면에 항균접착성조성물이 3차 전이되어 코팅되는 단계(S6)와, The transfer protrusion 32a, to which the antibacterial adhesive composition is secondaryly transferred, is brought into contact with the sheet surface on which the decoration pattern is not formed of the two-ply sheet (P1 + P2) on which the decoration pattern is formed, and the two sheets on which the decoration pattern is not formed are A step (S6) in which the antibacterial adhesive composition is thirdly transferred and coated on one side of the double sheet (P1 + P2),
상기 일측면에 데코무늬가 형성되고 타측면에 항균접착성조성물이 코팅된 두 겹 시트(P1+P2)와, 상기 일측면에 데코무늬가 형성된 두 겹 시트(P3+P4)가 제1압력 로울러(12) 및 제2압력 로울러(22) 사이에 동시 통과되어 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 면에 상기 두 겹 시트(P3+P4)가 접합됨으로써 4겹시트(P1+P2+P3+P4)가 형성되는 단계(S7)와, A two-ply sheet (P1+P2) with a deco pattern formed on one side and coated with an antibacterial adhesive composition on the other side, and a two-ply sheet (P3+P4) with a deco pattern formed on one side are the first pressure roller. (12) and the second pressure roller (22) are simultaneously passed between the two-ply sheets (P1+P2) and the two-ply sheets (P3+P4) are bonded to the surface coated with the antibacterial adhesive composition, forming a four-ply sheet. A step (S7) in which (P1+P2+P3+P4) is formed,
상기 4겹시트(P1+P2+P3+P4)가 합지롤(40)을 통과하여 합지되고, 상기 합지된 최종 4겹시트가 가이드 로울러(G)를 통하여 권취용 보빈(51)으로 이송되는 단계(S8)를 포함한다. The 4-ply sheets (P1+P2+P3+P4) are laminated through the lamination roll 40, and the laminated final 4-ply sheets are transferred to the winding bobbin 51 through the guide roller (G). Includes (S8).
이때 상기 복층 페이퍼 시트 제조장치는, At this time, the multi-layer paper sheet manufacturing device,
각추 형태의 돌기(14a)가 형성되는 제1데코무늬실린더(14)와 제1압력 로울러(12)가 구비되어, 상기 데코무늬실린더(14A) 및 제1압력 로울러(12) 사이에 두 겹 시트(P1+P2)가 통과되어 가압되면서 상기 두 겹 시트(P1+P2) 일측면에 데코무늬가 형성되는 제1패턴성형부(10);A first deco pattern cylinder 14 in which pyramid-shaped protrusions 14a are formed and a first pressure roller 12 are provided, and a two-ply sheet is formed between the deco pattern cylinder 14A and the first pressure roller 12. A first pattern forming unit 10 where (P1+P2) is passed through and pressurized to form a deco pattern on one side of the two-ply sheet (P1+P2);
각추 형태의 돌기(24a)가 형성되는 제2데코무늬실린더(24)와 제2압력 로울러(22)가 구비되어, A second deco pattern cylinder 24 and a second pressure roller 22 are provided, in which pyramid-shaped protrusions 24a are formed,
데코무늬실린더(24) 및 제2압력 로울러(22) 사이에 두 겹 시트(P3+P4)가 통과되어 가압되면서 상기 두 겹 시트(P3+P4) 일측면에 데코무늬가 형성되는 제2패턴성형부(20);Second pattern forming in which a decoration pattern is formed on one side of the two-layer sheet (P3 + P4) as the two-layer sheet (P3 + P4) is passed between the decoration pattern cylinder (24) and the second pressure roller (22) and pressed. Wealth (20);
갓 추출물이 포함된 항균접착성조성물이 충전된 잉크공급챔버(C)로부터 상기 항균접착성조성물을 공급받는 잉크공급 로울러(34)와 상기 잉크공급 로울러(34)와 접촉되는 전이돌기(32a)가 표면에 형성된 전이실린더(32)로 구성되고, 상기 전이돌기(32a)에 의하여 상기 시트(P1+P2)의 일측면이 항균접착성조성물로 코팅되되, 상기 전이실린더(32)가 상기 제1압력 로울러(12)와 접촉되는 조성물전이부(30); An ink supply roller 34 that receives the antibacterial adhesive composition from an ink supply chamber (C) filled with an antibacterial adhesive composition containing fresh extract and a transition protrusion 32a in contact with the ink supply roller 34. It consists of a transition cylinder 32 formed on the surface, and one side of the sheet (P1 + P2) is coated with an antibacterial adhesive composition by the transition protrusion 32a, and the transition cylinder 32 applies the first pressure. A composition transfer portion 30 in contact with the roller 12;
상기 제1패턴성형부(10), 제2패턴성형부(20) 및 조성물전이부(30)를 통하여 상기 두 겹 시트(P3+P4) 및 두 겹 시트(P3+P4)가 접합되어 형성된 4겹시트(P1+P2+P3+P4)가 형성되고, 상기 4겹시트(P1+P2+P3+P4)가 최종 합지되는 합지롤(40);4 formed by joining the two-ply sheets (P3 + P4) and the two-ply sheets (P3 + P4) through the first pattern forming part 10, the second pattern forming part 20, and the composition transfer part 30. A lamination roll 40 in which a double sheet (P1+P2+P3+P4) is formed and the 4-ply sheets (P1+P2+P3+P4) are finally laminated;
상기 합지롤(40)를 통하여 최종 합지된 4겹시트를 가이드 로울러(G)를 통하여 권취용 보빈(51)으로 이송하는 최종형성부(50);가 더 포함된다.A final forming unit 50 that transfers the final laminated 4-ply sheet through the lamination roll 40 to the winding bobbin 51 through a guide roller (G) is further included.
이하, 각 단계별로 갓 추출물이 포함된 4겹 시트의 제조방법의 구체적 내용을 살펴본다.Below, we will look at the specific details of the manufacturing method of the 4-ply sheet containing leaf extract in each step.
[갓 추출물이 포함된 4겹 시트 제조방법][Method of manufacturing 4-ply sheet containing fresh extract]
[시트 구비단계(S1)][Sheet preparation stage (S1)]
상기 시트 구비단계(S1)는 한 쌍의 독립된 두 겹 시트를 구비하는 단계이다. The sheet provision step (S1) is a step of providing a pair of independent two-ply sheets.
본 발명에서는 이해를 돕기 위하여, 상기 두 겹 시트 중 하나를 두 겹 시트(P1+P2)로 표현하고, 다른 하나를 두 겹 시트(P3+P4)로 표시한다. In the present invention, to facilitate understanding, one of the two-ply sheets is expressed as a two-ply sheet (P1 + P2), and the other is expressed as a two-ply sheet (P3 + P4).
상기 두 겹 시트(P1+P2)는 한 겹 시트(P1)와 한 겹 시트(P2)가 접합되어 구성된다. The two-ply sheet (P1+P2) is composed of a single-ply sheet (P1) and a single-ply sheet (P2) joined together.
상기 두 겹 시트(P3+P4)는 한 겹 시트(P3)와 한 겹 시트(P4)가 접합되어 구성된다. The two-ply sheet (P3+P4) is composed of a single-ply sheet (P3) and a single-ply sheet (P4) joined together.
상기 두 겹 시트는, 펄프 1 ~ 29.5wt%와, 정제수 70.0 ~ 98.5 wt%와, 잎혼합농축액 0.01 ~ 1.0 wt%가 혼합된 혼합펄프가 가열 건조되어 이루어지는 한 겹 시트 한 쌍이 가압·접합되어 제조된다. The two-ply sheet is manufactured by pressing and joining a pair of one-ply sheets made by heating and drying a mixed pulp of 1 to 29.5 wt% of pulp, 70.0 to 98.5 wt% of purified water, and 0.01 to 1.0 wt% of leaf mixed concentrate. do.
[시트 구비단계(S1) : 잎 혼합농축액][Sheet preparation step (S1): leaf mixed concentrate]
이때, 상기 잎 혼합농축액은, 초피 잎 1 ~ 40 wt%, 측백나무 잎 1 ~ 40 wt%, 갈참나무 잎 1 ~ 40 wt% 및 산벚나무 잎 1 ~ 40 wt%이 혼합되어 제조된 잎 혼합물이 80 ~ 150 ℃에서 볶음 건조되어 잎 건조물이 제조되고, 상기 잎 건조물이 80 ~ 150 ℃에서 1 ~ 2 시간 동안 열수추출된 후 여과되어 제조된 잎 혼합추출액이 원심분리기에서 7,500 ~ 8,500 rpm으로 15 ~ 25 분 동안 원심분리되어 수득된 상층액이 여과되고, 상기 여과된 상층액이 감압농축기로 0.1 ~ 0.5 mPA의 조건에서 30 ~ 120분 동안 감압농축됨으로써 제조된다. At this time, the leaf mixed concentrate is a leaf mixture prepared by mixing 1 to 40 wt% of scoria leaves, 1 to 40 wt% of arborvitae leaves, 1 to 40 wt% of brown oak leaves, and 1 to 40 wt% of wild cherry leaves. Dried leaves are prepared by roasting and drying at 80 to 150 ℃, and the dried leaves are subjected to hot water extraction at 80 to 150 ℃ for 1 to 2 hours, and then filtered to produce a mixed leaf extract, which is centrifuged at 7,500 to 8,500 rpm for 15 to 15 minutes. The supernatant obtained by centrifuging for 25 minutes is filtered, and the filtered supernatant is concentrated under reduced pressure for 30 to 120 minutes using a vacuum concentrator under conditions of 0.1 to 0.5 mPA.
이하, 상기 입 혼합농축액을 포함하는 구성 성분에 대해 간략 설명한다.Hereinafter, the components including the oral mixed concentrate will be briefly described.
상기 초피 잎은 초피나무의 잎으로서 운향과에 속하는 식물이다. 조피나무·천초라고도 하며 지역에 따라 제피·젠피 등으로도 부른다. 한방에서는 구충 억제제로 활용되고 있고 티몰(Thymol), 피노스트로빈(Pinostrobin), 카테킨(Catechin), 리모넨(Limonene)을 통하여 항균활성을 나타낸다. The perianth leaves are leaves of the perianth tree and are a plant belonging to the Rutaceae family. It is also called Jeppi tree and Cheoncho, and depending on the region, it is also called Jeppi or Zenpi. In oriental medicine, it is used as an anthelmintic inhibitor and exhibits antibacterial activity through thymol, pinostrobin, catechin, and limonene.
측백나무 잎은 측백나무의 잎으로서 구과식물의 하나로 측백나무속의 유일한 종이다. 중국 북부가 원산지로, 한국, 일본, 인도, 이란 등 다양한 아시아 지역에서 자생하고 플라바놀(flavanol) 화합물인 피노반크신(pinobanksin), 택시폴린(taxifolin) 및 암펠롭신(ampelopsin)을 포함하여 역시 높은 항균 활성을 나타낸다. Arborvitae leaves are the leaves of the Arborvitae tree, one of the coniferous plants and the only species of the Arborvitae genus. It is native to northern China, grows wild in various Asian regions such as Korea, Japan, India, and Iran, and is also high in flavanol compounds, including pinobanksin, taxifolin, and ampelopsin. Shows antibacterial activity.
갈참나무 잎은 갈참나무의 잎으로서 참나무과에 속하며 겨울에 잎이 지는 큰키나무로서 페놀류, 플라보노이드류, 테르펜류, 알칼로이드 등의 화합물를 통한 높은 항균 활성을 나타낸다. Quercus leaves are the leaves of Quercus Quercus, a member of the Quercus family, and are a large tree that loses its leaves in winter. It exhibits high antibacterial activity through compounds such as phenols, flavonoids, terpenes, and alkaloids.
산벚나무 잎은 삼출엽이며 잎의 배열은 호생이다. 가지의 색은 고동색이며 잎의 모양은 난형이다. 잎맥은 우상맥이고 엽정은 점첨두이며 우수한 항균 작용이 있다. The leaves of wild cherry trees are trifoliate and the leaves are arranged alternately. The color of the branches is maroon and the shape of the leaves is oval. The leaf veins are right-veined and the leaf blades are acuminate and have excellent antibacterial activity.
변기 내 배설물을 통한 오염 물질 중화, 미생물의 억제 및 악취 저감에 보조적인 역할을 하는 상기 잎 혼합농축액이 1차적으로 함침되면서, 변기 내 오염도가 낮아지도록 보조하는 효과가 있다.The leaf mixed concentrate, which plays an auxiliary role in neutralizing contaminants through excrement in the toilet, inhibiting microorganisms, and reducing odor, is primarily impregnated, which has the effect of helping to lower the level of contamination in the toilet.
[두 겹 시트(P1+P2) 데코무늬 형성 단계(S2)][Double-layer sheet (P1+P2) decoration pattern formation step (S2)]
도 1에 도시된 바와 같이, 각추 형태의 돌기(14a)가 형성되는 제1데코무늬실린더(14) 및 제1압력 로울러(12) 사이로 상기 두 겹 시트(P1+P2)가 통과되어 가압되면서 일측면에 데코무늬가 형성된다.As shown in FIG. 1, the two-ply sheet (P1 + P2) is passed between the first deco pattern cylinder 14 and the first pressure roller 12 in which the pyramid-shaped protrusion 14a is formed and pressurized to work. A deco pattern is formed on the side.
즉, 상기 두 겹 시트(P1+P2)가 데코무늬실린더(14) 및 제1압력 로울러(12) 사이를 통과할 때, 제1데코무늬실린더(14)의 각추 형태의 돌기(14a)와 접촉되면서 상기 각추 형태의 돌기(14a)에 의하여 두 겹 시트(P1+P2)의 일측면에 데코무늬가 형성된다.That is, when the two-layer sheet (P1 + P2) passes between the deco pattern cylinder 14 and the first pressure roller 12, it contacts the pyramid-shaped protrusion 14a of the first deco pattern cylinder 14. As a result, a deco pattern is formed on one side of the two-ply sheet (P1 + P2) by the pyramid-shaped protrusion (14a).
[두 겹 시트(P3+P4) 데코무늬 형성 단계(S3)][Double-layer sheet (P3+P4) decoration pattern formation step (S3)]
각추 형태의 돌기(24a)가 형성되는 제2데코무늬실린더(24) 및 제2압력 로울러(22) 사이로 두 겹 시트(P3+P4)가 통과되어 가압되면서 상기 두 겹 시트(P3+P4) 일측면에 데코무늬가 형성된다.The two-ply sheet (P3 + P4) is passed through and pressed between the second deco pattern cylinder (24) and the second pressure roller (22) in which the pyramid-shaped protrusion (24a) is formed, and the two-ply sheet (P3 + P4) is pressed. A deco pattern is formed on the side.
즉, 상기 두 겹 시트(P3+P4)가 제2데코무늬실린더(24) 및 제2압력 로울러(22) 사이를 통과할 때, 제2데코무늬실린더(24)의 각추 형태의 돌기(24a)와 접촉되면서 상기 각추 형태의 돌기(24a)에 의하여 두 겹 시트(P3+P4)의 일측면에 데코무늬가 형성된다. That is, when the two-layer sheet (P3 + P4) passes between the second deco pattern cylinder 24 and the second pressure roller 22, the pyramid-shaped protrusion 24a of the second deco pattern cylinder 24 A deco pattern is formed on one side of the two-ply sheet (P3+P4) by the pyramid-shaped protrusion (24a) while being in contact with.
[항균접착성조성물 1차 전이 단계(S4)][Antibacterial adhesive composition first transition step (S4)]
먼저, 갓 추출물이 포함된 항균접착성조성물이 잉크공급챔버(C)에 충진된다. First, an antibacterial adhesive composition containing fresh extract is filled into the ink supply chamber (C).
이후 상기 항균접착성조성물이 충진된 잉크공급챔버(C)가 잉크공급 로울러(34)와 접촉되고, 상기 잉크공급 로울러(34)에 항균접착성조성물이 1차 전이된다.Thereafter, the ink supply chamber (C) filled with the antibacterial adhesive composition is brought into contact with the ink supply roller (34), and the antibacterial adhesive composition is first transferred to the ink supply roller (34).
[항균접착성조성물 1차 전이 단계(S4):항균접착성조성물][Antibacterial adhesive composition first transition step (S4): Antibacterial adhesive composition]
이하, 항균접착성조성물을 먼저 살펴본다.Hereinafter, we will first look at the antibacterial adhesive composition.
[제1혼합물][First mixture]
먼저, 갓 잎 40 ~ 60 wt% 및 갓 종자 40 ~ 60wt%를 혼합한 후, 60 ~ 70 ℃에서 열풍건조하고, 상기 건조물 10 ~ 30 wt%을 80% 에탄올 70 ~ 90 wt%에 투입한 후, 2 ~ 4 시간 동안 2 ~ 4회 반복하여 환류 추출한 갓 추출물 10 ~ 20wt% 및 정제수 80 ~ 90 wt%을 혼합하여 제1혼합물을 제조한다. 상기 갓 추출물은 대부분 균주에서 항균 효과가 있으며, 주된 성분은 시니그린(Sinigrin)이다. First, 40 to 60 wt% of mustard leaves and 40 to 60 wt% of mustard seeds were mixed, then hot air dried at 60 to 70°C, and 10 to 30 wt% of the dried material was added to 70 to 90 wt% of 80% ethanol. , Prepare the first mixture by mixing 10 to 20 wt% of reflux-extracted green leaf extract and 80 to 90 wt% of purified water, repeated 2 to 4 times for 2 to 4 hours. The mustard extract has an antibacterial effect on most strains, and its main ingredient is sinigrin.
[제2혼합물][Second mixture]
생강 추출물 1 ~ 30 wt%, 오레가노 추출물 1 ~ 30 wt%, 매실 추출물 1 ~ 30 wt%, 차나무 잎 추출물 1 ~ 30 wt%, 자몽 종자 추출물 1 ~ 30 wt%, 레몬 껍질 추출물 1 ~ 30 wt%, 허브 추출물 1 ~ 30 wt%, 적포도과피 추출물 1 ~ 30 wt%, 서양금혼초 줄기 추출물 1 ~ 30 wt%, 오미자 추출물 1 ~ 30 wt%, 보골지열매추출물 1 ~ 30 wt%를 10 ~ 30 ℃에서 500 ~ 800 rpm로 혼합 교반하여 제2혼합물을 제조한다. Ginger extract 1 to 30 wt%, Oregano extract 1 to 30 wt%, Plum extract 1 to 30 wt%, Camellia leaf extract 1 to 30 wt%, Grapefruit seed extract 1 to 30 wt%, Lemon peel extract 1 to 30 wt% , herbal extract 1 to 30 wt%, red grape skin extract 1 to 30 wt%, Western Georgina rhododendron stem extract 1 to 30 wt%, Schisandra chinensis extract 1 to 30 wt%, and Bogolji fruit extract 1 to 30 wt%. A second mixture is prepared by mixing and stirring at 500 to 800 rpm at 30°C.
상기 생강 추출물은, 생강을 70 ~ 80℃에서 열풍 건조한 후, 그 건조물을 30 ~ 40 wt%을 정제수 60 ~ 70wt%에 투입한 후, 80 ~ 150 ℃, 1 ~ 2 시간 동안 열수추출하고 여과하여 제조한다. 상기 생강 추출물의 진저롤과 쇼가올은 매운맛을 내는 페놀화합물 성분으로 강한 항균 활성이 있다.The ginger extract is obtained by drying ginger with hot air at 70 to 80°C, adding 30 to 40 wt% of the dried product into 60 to 70 wt% of purified water, followed by hot water extraction at 80 to 150°C for 1 to 2 hours and filtering. manufacture. Gingerol and shogaol in the ginger extract are phenolic compounds that produce a spicy taste and have strong antibacterial activity.
상기 오레가노 추출물은, 오레가노 5 ~ 20 wt%를 70 % 에탄올 80 ~ 95 wt%에 투입하고, 70 ~ 80 ℃에서 3시간씩 3회 추출 후 여과하여 제조한다. 오레가노는 오레가노는 꿀풀과 오레가노속에 속하는 여러해살이풀로, 오레가노 추출물은 이성질체 페놀 성분(isomeric phenolic constituents, carvacrol) 및 티몰(thymol) 등의 강한 항균 활성 성분을 포함한다.The oregano extract is prepared by adding 5 to 20 wt% of oregano to 80 to 95 wt% of 70% ethanol, extracting three times for 3 hours at 70 to 80 ° C, and then filtering. Oregano is a perennial plant belonging to the genus Lamiaceae oregano. Oregano extract contains strong antibacterial active ingredients such as isomeric phenolic constituents (carvacrol) and thymol.
상기 매실 추출물은, 매실을 60 ~ 90 ℃에서 열풍건조한 후, 그 건조물 30 ~ 40 wt%을 정제수 60 ~ 70wt%에 투입한 후, 80 ~ 150 ℃, 1 ~ 2 시간 동안 열수추출한 후, 여과하여 제조한다. 이때 상기 매실은 매실 껍질을 제거한 과즙만을 포함할 수도 있다. 이는 매실 껍질을 제대로 건조하지 않으면 알레르기 반응을 일으킬 수 있기 때문이다. 한편, 매실의 항균물질은 항균활성이 높고 항균 스펙트럼이 광범위할뿐만 아니라 넓은 범위의 온도 및 pH에 안정적이어서 이상적인 천연 항균제로 알려져 있다. The plum extract is obtained by drying plums with hot air at 60 to 90°C, adding 30 to 40 wt% of the dried product into 60 to 70 wt% of purified water, performing hot water extraction at 80 to 150°C for 1 to 2 hours, and then filtering. manufacture. At this time, the plum may contain only juice from which the plum skin has been removed. This is because plum peels can cause allergic reactions if they are not dried properly. Meanwhile, the antibacterial substances in plum have high antibacterial activity, a wide antibacterial spectrum, and are stable over a wide range of temperature and pH, making it an ideal natural antibacterial agent.
상기 차나무 잎 추출물은 차나무 잎을 60 ~ 90 ℃에서 열풍건조한 후, 그 건조물 30 ~ 40 wt%을 정제수 60 ~ 70 wt%에 투입한 후, 80 ~ 150 ℃, 1 ~ 2 시간 동안 열수추출한 후 여과하여 제조한다. 상기 차나무 잎은 일명 녹차로 알려져 있으며, 차나무 잎 추출물의 주성분인 카테킨(Catechin)은 식중독균이나 포도상구균 등 을 포함한 모든 세균의 세포막을 상해(傷害)함으로써 강력한 살균 작용이 있다.The tea tree leaf extract is obtained by drying tea tree leaves with hot air at 60 to 90°C, adding 30 to 40 wt% of the dried material into 60 to 70 wt% of purified water, hot water extraction at 80 to 150°C for 1 to 2 hours, and then filtering. It is manufactured. The tea tree leaves are also known as green tea, and catechin, the main component of the tea tree leaf extract, has a strong sterilizing effect by damaging the cell membrane of all bacteria, including food poisoning bacteria and staphylococci.
상기 자몽 종자 추출물은 자몽 종자를 60 ~ 80 ℃에서 열풍건조한 후, 그 건조물을 80% 에탄올에 10 배의 중량비로 혼합한 후 2 ~ 4시간 동안 2회 ~ 4회 반복하여 환류 추출하여 제조한다. 자몽은 비타민 P라고 알려진 후라보노이드 성분과 구연산 등 항균 성분이 풍부하다.The grapefruit seed extract is prepared by drying grapefruit seeds with hot air at 60 to 80°C, mixing the dried product with 80% ethanol at a weight ratio of 10, and performing reflux extraction two to four times for 2 to 4 hours. Grapefruit is rich in antibacterial ingredients such as flavonoid known as vitamin P and citric acid.
상기 레몬 껍질 추출물은 레몬 껍질을 60 ~ 80 ℃에서 열풍건조한 후, 그 건조물을 80% 에탄올에 10 배의 중량비로 혼합한 후 2 ~ 4시간 동안 2회 ~ 4회 반복하여 환류 추출하여 제조한다. 레몬에 포함된 항산화 물질인 비타민C와 D-리모넨은 대표적인 살균 및 탈취 성분이다.The lemon peel extract is prepared by drying the lemon peel with hot air at 60 to 80°C, mixing the dried product with 80% ethanol at a weight ratio of 10, and performing reflux extraction two to four times for 2 to 4 hours. Vitamin C and D-limonene, antioxidants contained in lemons, are representative sterilizing and deodorizing ingredients.
상기 허브 추출물은 타임의 잎을 60 ~ 80 ℃에서 열풍건조한 후, 상기 건조된 타임의 잎을 80% 에탄올에 10 배의 중량비로 혼합하여 2 ~ 4시간 동안 환류 추출하고, 상기 과정을 2회 ~ 4회 반복한다. 상기 타임의 잎은 살균 성분인 티몰이 함유되어 있으며, 방부제와 보존제로 사용된다. The herbal extract was prepared by drying thyme leaves with hot air at 60 to 80°C, mixing the dried thyme leaves with 80% ethanol at a weight ratio of 10, extracting the extract under reflux for 2 to 4 hours, and repeating the process twice. Repeat 4 times. The leaves of thyme contain thymol, a bactericidal ingredient, and are used as a preservative and preservative.
상기 적포도과피 추출물은 적포도과피를 60 ~ 80 ℃에서 열풍건조한 후, 그 건조물을 80% 에탄올에 10 배의 중량비로 혼합한 후 2 ~ 4시간 동안 2회 ~ 4회 반복하여 환류 추출하여 제조한다. 상기 적포도과피 추출물은 강력한 항산화제로서, 미생물의 생육을 저하하고, 후술할 제3혼합물의 보존성을 강화한다.The red grape skin extract is prepared by drying the red grape skin with hot air at 60 to 80°C, mixing the dried product with 80% ethanol in a 10-fold weight ratio, and performing reflux extraction 2 to 4 times for 2 to 4 hours. do. The red grape skin extract is a powerful antioxidant, reduces the growth of microorganisms, and enhances the preservation of the third mixture, which will be described later.
상기 서양금혼초 줄기 추출물은 서양금혼초 줄기를 60 ~ 80 ℃에서 열풍건조한 후, 그 건조물을 80% 에탄올에 10 배의 중량비로 혼합한 후 2 ~ 4시간 동안 2회 ~ 4회 반복하여 환류 추출하여 제조한다. 상기 서양금혼초는 유럽 원산의 귀화식물로 목장과 공터에서 자라는 여러해살이풀로써, 미생물의 생육을 저하하고 후술할 제3혼합물의 보존성을 강화하는 효과가 있다. The Western Geumhoncho stem extract is obtained by drying the Western Geumhoncho stems with hot air at 60 to 80°C, mixing the dried product with 80% ethanol at a weight ratio of 10, and then extracting by refluxing 2 to 4 times for 2 to 4 hours. It is manufactured. The Western Geumhoncho is a naturalized plant native to Europe and a perennial herb that grows in pastures and vacant lots. It has the effect of reducing the growth of microorganisms and enhancing the preservation of the third mixture, which will be described later.
상기 오미자 추출물은 오미자를 60 ~ 80 ℃에서 열풍건조한 후, 그 건조물을 80% 에탄올에 10 배의 중량비로 혼합한 후 2 ~ 4시간 동안 2회 ~ 4회 반복하여 환류 추출하여 제조한다. 상기 오미자 추출물은 리그난, 알토산, 유기산 등 항균 성분을 포함한다.The Schisandra chinensis extract is prepared by drying Schisandra chinensis with hot air at 60 to 80°C, mixing the dried product with 80% ethanol at a weight ratio of 10, and performing reflux extraction two to four times for 2 to 4 hours. The Schisandra chinensis extract contains antibacterial ingredients such as lignans, altoic acids, and organic acids.
상기 보골지 열매 추출물은 보골지 열매를 60 ~ 80 ℃에서 열풍건조한 후, 그 건조물을 80 % 에탄올에 10 배의 중량비로 혼합한 후 2 ~ 4시간 동안 2회 ~ 4회 반복하여 환류 추출하여 제조한다. 상기 보골지풀은 콩과 높이 40~90cm 되는 한해살이풀로, 바쿠치올이라는 성분을 다량 함유하고 있으며, 이는 병원성 세균 증식을 억제하는 효과가 있다. The Bogolji fruit extract is prepared by hot-air drying the Bogolji fruit at 60 to 80°C, mixing the dried product with 80% ethanol in a 10-fold weight ratio, and performing reflux extraction 2 to 4 times for 2 to 4 hours. do. The Bogoljipul is a legume and an annual herb with a height of 40 to 90 cm, and contains a large amount of a component called bakuchiol, which has the effect of suppressing the growth of pathogenic bacteria.
[제3혼합물][Third mixture]
개망초꽃 오일 1 ~ 30 wt%, 코코넛 오일 1 ~ 30 wt%, 님 오일 1 ~ 30 wt%, 팜 오일 1 ~ 30 wt%, 유칼립투스 오일 1 ~ 30 wt%, 티트리 오일 1 ~ 30 wt%을 40 ~ 50 ℃에서 500 ~ 800 rpm로 혼합 교반하여 제3혼합물을 제조한다. Contains 1 to 30 wt% of eucalyptus oil, 1 to 30 wt% of coconut oil, 1 to 30 wt% of neem oil, 1 to 30 wt% of palm oil, 1 to 30 wt% of eucalyptus oil, 1 to 30 wt% of tea tree oil. A third mixture is prepared by mixing and stirring at 500 to 800 rpm at 40 to 50 °C.
상기 개망초꽃 오일은 개망초 꽃을 디에틸에테르(diethyl ether)에 침지한 후, 추출 농축하여 콘크리트를 얻은 후, 에탄올를 가하여 30 ~ 40 ℃에서 교반하여 용해하고, 그 용해물을 -20 ℃에서 냉각시켜 왁스 제거 및 여과 농축하여 앱솔루트 상태의 오일을 얻는다. 상기 개망초꽃 오일은 항균 효과가 우수하다. The above-mentioned perilla flower oil is prepared by immersing the perennial perennial flower in diethyl ether, extracting and concentrating it to obtain concrete, adding ethanol and stirring at 30 to 40 ° C to dissolve it, and cooling the dissolved product at -20 ° C. Wax is removed, filtered and concentrated to obtain absolute oil. The foreboding flower oil has excellent antibacterial effect.
상기 상기 코코넛 오일은 코코넛을 패쇄하여 코코넛과 속살을 분리한 후, 상기 속살을 건조하고, 상기 속살 건조물을 30 ~ 60 ℃의 온도의 열을 가한 후, 압착, 여과하여 제조한다. 코코넛 오일에 함유된 라우르산(lauric acid)은 살균 소독 은 물론 항바이러스 기능이 있다.The coconut oil is manufactured by crushing a coconut to separate the coconut and flesh, drying the flesh, applying heat to the dried flesh at a temperature of 30 to 60° C., then pressing and filtering. Lauric acid contained in coconut oil has sterilizing and antiviral properties.
상기 님 오일은 님 나무(Need tree)의 씨앗, 열매, 잎사귀, 뿌리 또는 둥지로부터 추출한 오일로서, 본 발명에서는 님나무 씨앗에서 냉각압착 방법으로 추출한 님 오일을 사용한다. 상기 님 오일의 유효성분인 아자디라크틴(azadirachtin)은 많은 리미노이드(liminoid) 화합물을 포함하며 이는 강력한 살균 탈취 효과가 있다.The neem oil is oil extracted from the seeds, fruits, leaves, roots, or nests of the neem tree. In the present invention, neem oil extracted from neem tree seeds by cold pressing is used. Azadirachtin, the active ingredient of neem oil, contains many liminoid compounds and has a strong sterilizing and deodorizing effect.
상기 팜 오일은 기름야자 열매의 과육을 쪄서 압축 채유되는 식물성 유지로서, 천연 항균 물질로 알려져 있다.The palm oil is a vegetable oil obtained by compressing the pulp of oil palm fruit by steaming it, and is known as a natural antibacterial substance.
상기 유칼립투스 오일은 유칼립투스 오일은 수증기 증류법으로 잎에서 추출한 것으로서, 항바이러스 작용이 우수하다. 유칼립투스에 포함된 시네올(Cineole) 성분은 살균 및 박테리아 번식 방지 특성과 탈취 효과가 있다. The eucalyptus oil is extracted from leaves by steam distillation and has excellent antiviral activity. Cineole contained in eucalyptus has sterilizing and bacterial growth-preventing properties and a deodorizing effect.
상기 티트리 오일은 티트리 잎을 통해 수증기 증류법으로 추출한 것으로서 살균소독 효과가 뛰어나며 박테리아, 바이러스 및 곰팡이의 세 가지 전염성 유기체에 대해 강력한 항균 작용을 가지고 있다.The tea tree oil is extracted from tea tree leaves by steam distillation, has an excellent sterilizing and disinfecting effect, and has a strong antibacterial effect against three types of infectious organisms: bacteria, viruses, and mold.
[제4혼합물][Fourth mixture]
정제수 1 ~ 50 wt%, 구리 나노 분말 1 ~ 40 wt%, 산화 아연 나노 분말 1 ~ 40 wt%를 80 ~ 90 ℃에서 300 ~ 400 rpm로 혼합 교반하여 제4혼합물을 제조한다. A fourth mixture is prepared by mixing and stirring 1 to 50 wt% of purified water, 1 to 40 wt% of copper nanopowder, and 1 to 40 wt% of zinc oxide nanopowder at 300 to 400 rpm at 80 to 90°C.
상기 구리 나노 분말은 극성용매를 구리 화합물과 혼합하고, 80℃ 내지 150℃에서 가열하여 구리 화합물을 용해하고, 환원제를 부가하여 구리 나노입자를 제조한다. 다만, 본 발명의 구리 나노 분말의 제조방법은 이에 한정되지 않는다. The copper nanopowder is prepared by mixing a polar solvent with a copper compound, heating at 80°C to 150°C to dissolve the copper compound, and adding a reducing agent. However, the method for producing copper nanopowder of the present invention is not limited to this.
상기 나노 구리 분말은 표면의 구리 원자가 매우 활성화되어 많은 양의 구리 이온을 방출한다. 양전하구리 이온과 음전하세포막은 흡착을 일으킨 후 세포벽을 통과하여 세포로 들어가 세포 합성 효소의 활성을 파괴하여 세포의 분열, 증식 및 소멸 능력을 잃게하여 박테리아 성장을 억제하는 효과가 있다.The copper atoms on the surface of the nano-copper powder are highly activated and emit a large amount of copper ions. After causing adsorption, positively charged copper ions and negatively charged cell membranes pass through the cell wall and enter cells, destroying the activity of cell synthesis enzymes and causing cells to lose their ability to divide, proliferate, and die, which has the effect of inhibiting bacterial growth.
상기 구리 나노 입자는 세균 내부에서 반응산소종(Reactive Oxygen Species, ROS)를 생성하고, ROS는 세균의 DNA, 단백질, 리파이드 등을 손상시키는데, 이로 인하여 세균의 생존과 성장이 억제된다. The copper nanoparticles generate reactive oxygen species (ROS) inside the bacteria, and ROS damages the DNA, proteins, and lipids of bacteria, which inhibits the survival and growth of bacteria.
또한, 박테리아가 죽으면 구리 이온이 박테리아에서 용해되어 반복 살균의 역할이 수행된다. 특히, 대장균, 황색포도상구균, 대한 항균성은 99.9% 이상이다. In addition, when the bacteria die, copper ions are dissolved from the bacteria and play the role of repeated sterilization. In particular, the antibacterial activity against Escherichia coli and Staphylococcus aureus is over 99.9%.
즉, 구리 나노 분말 역시 배수관 따라 하수도 처리 공정에서 대장균등의 병원균을 억제함으로써 원천적 악취를 제거하는 화학적 프로세스를 촉진한다. In other words, copper nanopowder also promotes a chemical process that removes the original odor by inhibiting pathogens such as E. coli during the sewage treatment process along the drain pipe.
상기 산화아연(ZnO) 나노 분말은 백색 분말로 산 및 알칼리에 용해되며 항균성을 갖는다.The zinc oxide (ZnO) nanopowder is a white powder that is soluble in acids and alkalis and has antibacterial properties.
상기 산화아연(ZnO) 나노 분말은 ZnCl2와 NaCO3 의 분말을 지르코니아 볼로 혼합반응한 후, 세척 및 원심분리하고, 열처리하는 것에 의하여 ZnO 나노입자를 제조한다. The zinc oxide (ZnO) nanopowder is manufactured by mixing powders of ZnCl 2 and NaCO 3 with zirconia balls, followed by washing, centrifugation, and heat treatment.
산화 아연 나노 분말은 항균 메커니즘은 금속 이온 용해 메커니즘에 기초로 한다. 유리 아연 이온은 산화 환원 작용을 수행하며, 유기 물질인 티오, 카복실, 수산화물등과 반응한다. 이러한 반응 후 박테리아 세포막과 막 단백질과 결합하여 구조를 파괴하고 박테리아의 활동을 상실시켜 항균 효과를 달성할 수 있다. The antibacterial mechanism of zinc oxide nanopowder is based on the metal ion dissolution mechanism. Free zinc ions perform oxidation-reduction functions and react with organic substances such as thio, carboxyl, and hydroxide. After this reaction, it can bind to the bacterial cell membrane and membrane proteins, destroying the structure and causing loss of bacterial activity, thereby achieving an antibacterial effect.
또한, 산화 아연 분말의 항균력은 표면의 구멍 수(孔石)와 관련이 있는데, 표면에 구멍이 많으면 많은 전자가 생성된다. 이러한 공석(孔石)으로 동시 반응이 일어나 살균 성능이 향상된다. Additionally, the antibacterial activity of zinc oxide powder is related to the number of holes on the surface. If there are many holes on the surface, many electrons are generated. Simultaneous reactions occur due to these vacancies, improving sterilization performance.
즉, 아연 이온(Zn2+)으로부터 살균 효과를 발휘하는 것으로서 아연 이온은 박테리아 세포막과 상호 작용하여 세포막을 파괴하거나 생리적 기능을 방해하여 박테리아의 증식을 억제한다.In other words, it exerts a sterilizing effect from zinc ions (Zn2+), and zinc ions interact with bacterial cell membranes to destroy the cell membrane or interfere with physiological functions, thereby suppressing the proliferation of bacteria.
[A혼합물][Mixture A]
상기 제1혼합물 40 ~ 60 wt%, 제2혼합물 1 ~ 30 wt%, 제3혼합물 1 ~ 30 wt%, 제4혼합물 1 ~ 30 wt%, 워터 솔루빌라이져 1 ~ 30 wt%를 100 ~ 500 rpm, 80 ~ 90 ℃에서 혼합하여 A혼합물을 제조한다. 40 to 60 wt% of the first mixture, 1 to 30 wt% of the second mixture, 1 to 30 wt% of the third mixture, 1 to 30 wt% of the fourth mixture, and 1 to 30 wt% of the water solubilizer, 100 to 500 wt%. Prepare mixture A by mixing at rpm and 80 to 90 °C.
상기 워터 솔루빌라이져는 폴리소르베이트 80(Polysorbate 80)이라고 불리우며, 폴리올과 솔비톨을 에틸렌 옥사이드와 반응시켜 생성되는 계면활성제이다. 워터 솔루빌라이져를 통해 항균접착성조성물을 구성하는 물(수성성분)에 오일(유성성분)을 분산, 안정화한다. The water solubilizer is called Polysorbate 80, and is a surfactant produced by reacting polyol and sorbitol with ethylene oxide. Through a water solubilizer, oil (oily component) is dispersed and stabilized in the water (aqueous component) that constitutes the antibacterial adhesive composition.
이때, 워터 솔루빌라이져를 대체하여 A혼합물 전체중량대비 동일한 배합비로 레시틴 또는 소르비탄지방산에스테르가 함유될 수 있다. At this time, in place of the water solubilizer, lecithin or sorbitan fatty acid ester may be contained in the same mixing ratio based on the total weight of mixture A.
[A혼합물과 접착제 혼합물][Mixture A and adhesive mixture]
상기 A혼합물 60 ~ 70 wt%에 접착제 30 ~ 40 wt%를 투입한 후, 100 ~ 120 ℃ 에서 30초 동안 혼합하여 제조한다.It is prepared by adding 30 to 40 wt% of the adhesive to 60 to 70 wt% of the A mixture and mixing for 30 seconds at 100 to 120°C.
상기 접착제는, 단백질계 아교, 젤라틴(Gelatin), 알부민(Albumin), 카제인(Casein), 대두단백 등과, 탄수화물계 전분, 셀룰로오스 유도체, 다당류 등과, 천연고무계 고무나무에서 유출하는 라텍스를 응고한 것을 포함한 자연 산출된 물질이 접착제로 사용된다. The adhesive includes protein glue, gelatin, albumin, casein, soy protein, carbohydrate starch, cellulose derivatives, polysaccharides, etc., and natural rubber latex leaking from rubber trees. Naturally occurring substances are used as adhesives.
본 발명의 접착제는, 갈조류인 대황, 다시마, 미역, 감태, 홍조류인 도박, 풀가사리, 우뭇가사리, 후노리 중 하나가 선택되어 제조되는 것으로서, The adhesive of the present invention is manufactured by selecting one of the brown algae such as rhubarb, kelp, seaweed, gamtae, and the red algae such as agar, agar, agar, and funori,
상기 해조류 중 하나를 증류수에서 1시간 동안 탈염하여 염도가 0% 될 때까지 반복하여 탈염처리하고, 음지에서 자연 건조하고, 상기 건조된 해조류 건조물을 50℃에서 0.07% NaOH 처리하여 2시간 동안 1차 처리 후, 상온에서 0.7% HCl 처리하여 1 시간 동안 2차 처리하고, 2차 처리된 해조류를 탄산나트륨(Na2CO3), 탄산칼슘(K2CO3), 정제수를 혼합한 용액에 100℃에서 5시간 동안 각각 가열하면서 고점도의 다당류 용액을 제조하고 상기 다당류 용액을 25℃ 이하로 냉각한 후, 메탄올과 에탄올을 첨가하여 침전하고, 상기 침전된 각 알진 용액들을 1차 여과처리하고, 여과된 추출물은 다시 알코올을 이용하분쇄하였으며 알코올 상에서 48시간 동안 안정화 및 침전을 거친 후 여과지를 이용하여 감압 여과하여 제조한 후, 정제수로 희석하여 점도를 조정한다. One of the seaweeds was desalted in distilled water for 1 hour and repeatedly desalted until the salinity reached 0%, dried naturally in the shade, and the dried seaweed was treated with 0.07% NaOH at 50°C for 2 hours. After treatment, secondary treatment was performed with 0.7% HCl at room temperature for 1 hour, and the secondary treated seaweed was placed in a solution of sodium carbonate (Na 2 CO 3), calcium carbonate (K 2 CO 3), and purified water at 100°C. A high-viscosity polysaccharide solution was prepared by heating for 5 hours, the polysaccharide solution was cooled to 25° C. or lower, and methanol and ethanol were added to precipitate it. Each of the precipitated algin solutions was subjected to primary filtration, and the filtered extract was obtained. It was again ground using alcohol, stabilized and precipitated on alcohol for 48 hours, and then filtered under reduced pressure using filter paper to adjust the viscosity by diluting with purified water.
상기와 같은 항균접착성조성물은, 접착제에 의하여 항균 성분들이 응집된체 4겹시트의 내측에 코팅처리되어 변기 내 배설물을 통한 오염물질을 중화하고 미생물을 억제하여 악취 발생과 변기 내 오염도를 낮추게 된다. The antibacterial adhesive composition as described above is coated on the inside of a four-ply sheet in which antibacterial ingredients are aggregated by an adhesive, neutralizing contaminants through excrement in the toilet and suppressing microorganisms, thereby reducing the generation of bad odor and the degree of contamination in the toilet. .
나아가, 나노 ZnO는 배수관 따라서 하수처리 과정을 거칠 때 자외선 및 오존 접촉반응을 통해 미세먼지 및 대장균 등의 병원균을 제거하는 공정에서 광촉매 반응을 일으켜 수질정화를 보조하게 된다. 즉, 나노 ZnO의 경우, 자외선 하에서 활성화되어 광촉매 작용을 수행하는데, 하수도 마지막 단계인 공정에서 자외선 조사에 의해 나노 ZnO의 전자가 활성화되어 유기 오염물질 분해, 산소 활성화, 박테리아의 살균 등 화학적 프로세스를 촉진한다. Furthermore, nano ZnO assists in water purification by causing a photocatalytic reaction in the process of removing pathogens such as fine dust and E. coli through contact reaction with ultraviolet rays and ozone when going through the sewage treatment process along the drain pipe. In other words, in the case of nano ZnO, it is activated under ultraviolet rays and performs a photocatalytic function. In the final step of the sewage process, the electrons of nano ZnO are activated by ultraviolet irradiation to promote chemical processes such as decomposition of organic pollutants, oxygen activation, and sterilization of bacteria. do.
[항균접착성조성물 2차 전이 단계(S5)][Antibacterial adhesive composition second transition step (S5)]
상기 항균접착성조성물이 1차 전이된 잉크공급 로울러(34)가 전이 실린더(32)와 접촉되면서, 전이돌기(32a)가 표면에 형성된 전이돌기(32a)에 상기 항균접착성조성물이 2차 전이된다. As the ink supply roller 34 on which the antibacterial adhesive composition is first transferred comes into contact with the transfer cylinder 32, the antibacterial adhesive composition is secondaryly transferred to the transfer protrusions 32a formed on the surface. do.
[항균접착성조성물 3차 전이 코팅 단계(S6)][Antibacterial adhesive composition 3rd transfer coating step (S6)]
상기 항균접착성조성물이 2차 전이된 전이돌기(32a)가 상기 데코무늬가 형성된 두 겹 시트(P1+P2)의 데코무늬가 형성되지 않은 시트면과 접촉되면서 상기 의 데코무늬가 형성되지 않은 두 겹 시트(P1+P2)의 일측면에 항균접착성조성물이 3차 전이되어 코팅된다. The transfer protrusion 32a, to which the antibacterial adhesive composition is secondaryly transferred, is brought into contact with the sheet surface on which the decoration pattern is not formed of the two-ply sheet (P1 + P2) on which the decoration pattern is formed, and the two sheets on which the decoration pattern is not formed are The antibacterial adhesive composition is thirdly transferred and coated on one side of the double sheet (P1+P2).
[4겹시트 형성 단계(S7)][4-layer sheet formation step (S7)]
상기 일측면에 데코무늬가 형성되고 타측면에 항균접착성조성물이 코팅된 두 겹 시트(P1+P2)와 상기 일측면에 데코무늬가 형성된 두 겹 시트(P3+P4)가 제1압력 로울러(12) 및 제2압력 로울러(22) 사이에 동시 통과되어 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 면에 상기 두 겹 시트(P3+P4)가 접합됨으로써 4겹시트지(P1+P2+P3+P4)가 형성된다. A two-ply sheet (P1+P2) with a deco pattern formed on one side and coated with an antibacterial adhesive composition on the other side and a two-ply sheet (P3+P4) with a deco pattern formed on one side are formed on a first pressure roller ( 12) and the second pressure roller 22 are simultaneously passed between the two-ply sheets (P1 + P2) and the two-ply sheets (P3 + P4) are bonded to the surface coated with the antibacterial adhesive composition, thereby forming a four-ply sheet ( P1+P2+P3+P4) is formed.
즉, 상기 4겹시트(P1+P2+P3+P4)는 바깥쪽 양면에 데코무늬가 형성되되, 내측에는 항균접착성조성물이 코팅된다. That is, the 4-ply sheet (P1+P2+P3+P4) has a decorative pattern formed on both outer sides, and the inner side is coated with an antibacterial adhesive composition.
[권취용 보빈(51)으로 이송하는 단계(S8)][Step of transferring to the winding bobbin (51) (S8)]
상기 4겹시트지(P1+P2+P3+P4)가 합지롤(40)을 통과하여 합지되고, 상기 합지된 최종 4겹시트지가 가이드 로울러(G)를 통하여 권취용 보빈(51)으로 이송된다.The 4-ply sheets (P1+P2+P3+P4) pass through the lamination roll 40 and are laminated, and the laminated final 4-ply sheets are transferred to the winding bobbin 51 through the guide roller (G).
[항균 살균 탈취 과정][Antibacterial sterilization and deodorization process]
도 2 및 도 3에 도시된 바와 같이, 4겹 시트의 사용법과 구체적 항균 살균 탈취 과정을 설명하도록 한다. As shown in Figures 2 and 3, how to use the 4-ply sheet and the specific antibacterial, sterilizing and deodorizing process will be explained.
본 발명의 갓 추출물이 포함된 4겹 시트는 인분이 변기에 투입되기 전에 투입하여 변기 내부에 항균, 살균, 탈취 물질을 퍼트리는 과정과, The 4-ply sheet containing the leaf extract of the present invention is put in before human waste is put into the toilet, and the process of spreading antibacterial, sterilizing, and deodorizing substances inside the toilet;
상기 인분이 체내에서 방출되는 과정에서도 상기 4겹시트로 인해 지속적으로 항균, 살균, 탈취를 이루면서 상기 인분이 변기 내부에 모두 자리하는 과정으로 이루어진다.Even in the process of the human waste being released from the body, the four-ply sheet continuously achieves antibacterial, sterilization, and deodorization, and all of the human waste is placed inside the toilet.
또한, 본 발명의 갓 추출물이 포함된 4겹 시트는, 상기 4겹 시트를 통해 극소부위를 세정한 후 변기 내 투입하고 변기를 내리되, 도 4에 도시된 바와 같이, 변기를 내릴때 발생되는 변기 수면 근처에 형성되어 있는 세균이 사방으로 퍼져나갈때, 항균, 살균, 탈취 성분이 동시에 같이 확산되어 사방으로 퍼지면서 확산된 세균을 억제하고, 상기 확산된 항균, 살균, 탈취 성분으로 탈취 및 방향 효과를 보조한다. In addition, the 4-ply sheet containing the mustard extract of the present invention is placed in the toilet after cleaning a very small area through the 4-ply sheet, and the toilet is flushed. As shown in FIG. 4, the waste generated when the toilet is flushed is removed. When bacteria formed near the surface of the toilet spread in all directions, the antibacterial, sterilizing, and deodorizing ingredients spread simultaneously and spread in all directions to suppress the spread bacteria, and the diffused antibacterial, sterilizing, and deodorizing ingredients provide a deodorizing and aroma effect. assists.
또한, 본 발명의 갓 추출물이 포함된 4겹 시트는, 항균, 탈취, 살균 성분을 방출하며 하수도의 관을 따라 내려가면서 관을 세척하는 것을 보조하면서 포도상구균, 대장균, 엔테로박터 클로아카, 녹농균, 살모넬라, 쉬게라, 글로스타리디움균 등의 세균 처리하는 과정을 보조한다.In addition, the 4-ply sheet containing the mustard extract of the present invention releases antibacterial, deodorizing, and sterilizing ingredients and assists in cleaning the pipe as it moves down the sewer pipe, eliminating Staphylococcus aureus, Escherichia coli, Enterobacter cloaca, Pseudomonas aeruginosa, It assists in the process of treating bacteria such as Salmonella, Shigerra, and Glostaridium bacteria.
또한, 본 발명의 갓 추출물이 포함된 4겹 시트는, 4겹시트 및 인분이 하수관을 따라 내려가고, 상기 항균, 탈취, 살균 기능이 있는 일부 성분이 특히 변기 표면에 잔존하여, 상기 잔존된 성분으로 인하여 항균, 살균, 탈취 기능이 촉진된다.In addition, in the 4-ply sheet containing the leaf extract of the present invention, the 4-ply sheet and human waste go down the sewer pipe, and some of the ingredients with the antibacterial, deodorizing, and sterilizing functions remain, especially on the surface of the toilet, and the remaining ingredients This promotes antibacterial, sterilizing, and deodorizing functions.
또한, 하수처리는 1차 처리 과정인 물리화학적 처리 과정과, 2차 처리 과정인 생물학적 처리 과정과, 3차 처리 과정인 자외선 및 오존의 접촉반응 통해 미세입자 및 대장균을 제거하는 과정을 통과하는데, 이때 본 발명의 갓 추출물이 포함된 4겹 시트는, 상기 항균접착성조성물의 무기항균제가 광촉매 반응, 흡착 반응을 통해 살균 효과를 발생시켜 수질 처리를 보조한다.In addition, sewage treatment goes through a physical and chemical treatment process, which is the primary treatment process, a biological treatment process, which is a secondary treatment process, and a process of removing fine particles and E. coli through contact reaction with ultraviolet rays and ozone, which is a tertiary treatment process. At this time, the 4-ply sheet containing the mustard extract of the present invention assists water quality treatment by generating a sterilizing effect through the photocatalytic reaction and adsorption reaction of the inorganic antibacterial agent of the antibacterial adhesive composition.
또한, 본 발명의 갓 추출물이 포함된 4겹 시트는, 상기 4겹시트(P1+P2+P3+P4) 5장을 수직으로 결합하여, 물티슈 대용으로 사용하도록 제공될 수 있다. 이는 화장지 사용자가 상기 5장이 수직으로 결합된 갓 추출물이 포함된 4겹 시트에 소량의 물을 적셔 사용하도록 하기 위한 것으로, 이 경우 내측에 코팅되는 항균접착성조성물이 물과 함께 용해되면서 항균성 물티슈로 대체 활용될 수 있다. 이는 변기의 배관을 막는 주 원인인 물티슈의 사용을 대체시켜 사용 편의성을 높이고 공익에 이바지하는 효과가 있다.In addition, the 4-ply sheet containing the mustard extract of the present invention can be provided to be used as a substitute for wet tissues by vertically combining five 4-ply sheets (P1 + P2 + P3 + P4). This is to enable toilet paper users to wet the 4-ply sheet containing the leaf extract, in which the 5 sheets are vertically joined, with a small amount of water. In this case, the antibacterial adhesive composition coated on the inside dissolves with water and becomes an antibacterial wet tissue. It can be used as an alternative. This has the effect of increasing convenience of use and contributing to the public interest by replacing the use of wet tissues, which is the main cause of clogged toilet pipes.
실시예 1 Example 1
상기 4겹시트는 상기 제시된 복층 페이퍼 시트 제조장치를 통해 S1 ~ S8의 단계별 제조방법으로 제조되되, 상기 두 겹 시트(P1+P2) 또는 두 겹 시트(P3+P4)는, 펄프 29.5wt%와, 정제수 69.5 wt%와, 잎혼합농축액 1.0 wt%를 혼합한 혼합펄프를 가열 건조하여 이루어지는 한 겹 시트 두 쌍을 가압·접합하여 제조한다.The four-ply sheet is manufactured by the step-by-step manufacturing method S1 to S8 through the multi-layer paper sheet manufacturing apparatus presented above, and the two-ply sheet (P1 + P2) or the two-ply sheet (P3 + P4) is composed of 29.5 wt% of pulp and , It is manufactured by pressing and joining two pairs of one-ply sheets made by heating and drying mixed pulp mixed with 69.5 wt% of purified water and 1.0 wt% of leaf mixed concentrate.
또한, 상기 잎혼합농축액은, 초피 잎 20 wt%, 측백나무잎 40 wt%, 갈참나무 잎 20 wt% 및 산벚나무 잎 20 wt%을 혼합하여 제조된 잎 혼합물을 120 ℃ 에서 볶음 건조하여 잎건조물을 제조하고, 상기 잎건조물을 80 ℃, 2 시간 동안 열수추출한 후, 여과하여 제조된 잎혼합추출액을 원심분리기에서 8,500 rpm으로 25 분 동안 원심분리하여 수득한 상층액을 여과하고, 여과한 추출물을 감압농축기로 0.5 mPA의 조건에서 120분 동안 감압농축하여 제조한다. In addition, the leaf mixture concentrate is a leaf mixture prepared by mixing 20 wt% of Chinese bark leaves, 40 wt% of arborvitae leaves, 20 wt% of Japanese oak leaves, and 20 wt% of wild cherry leaves, stir-fried and dried at 120°C to produce dried leaves. was prepared, the dried leaf material was subjected to hot water extraction at 80° C. for 2 hours, and then filtered. The resulting mixed leaf extract was centrifuged in a centrifuge at 8,500 rpm for 25 minutes. The supernatant obtained was filtered, and the filtered extract was filtered. It is prepared by concentrating under reduced pressure for 120 minutes under conditions of 0.5 mPA.
또한, 잉크공급챔버(C)에 충진된 항균접착성조성물은, 갓 잎과 갓 종자를 70 ℃에서 열풍건조한 후, 그 건조물 30 wt%을 80% 에탄올 70 wt%에 투입한 후, 4 시간 동안 4회 반복하여 환류 추출한 갓 추출물 20wt% 및 정제수 80 wt%을 혼합하여 제1혼합물을 제조하고, In addition, the antibacterial adhesive composition filled in the ink supply chamber (C) is made by drying mustard leaves and mustard seeds with hot air at 70°C, adding 30 wt% of the dried material into 70 wt% of 80% ethanol, and then drying for 4 hours. A first mixture was prepared by mixing 20 wt% of fresh green extract extracted under reflux and 80 wt% of purified water, repeated four times,
그 후, 생강 추출물 10 wt%, 오레가노 추출물 10 wt%, 매실 추출물 10 wt%, 차나무 잎 추출물 10 wt%, 자몽 종자 추출물 10 wt%, 레몬 껍질 추출물 10 wt%, 타임 잎 추출물 10 wt%, 적포도과피 추출물 10 wt%, 서양금혼초 줄기 추출물 10 wt%, 오미자 추출물 5 wt%, 보골지열매추출물 5 wt%를 25 ℃에서 500 rpm로 혼합 교반하여 제2혼합물을 제조하고, Afterwards, ginger extract 10 wt%, oregano extract 10 wt%, plum extract 10 wt%, tea tree leaf extract 10 wt%, grapefruit seed extract 10 wt%, lemon peel extract 10 wt%, thyme leaf extract 10 wt%, red A second mixture was prepared by mixing and stirring 10 wt% of grape skin extract, 10 wt% of Western Geumhoncho stem extract, 5 wt% of Schisandra chinensis extract, and 5 wt% of Bogolji fruit extract at 500 rpm at 25°C,
그 후, 개망초꽃 오일 30 wt%, 코코넛 오일 15 wt%, 님 오일 15 wt%, 팜 오일 30 wt%, 유칼립투스 오일 5 wt%, 티트리 오일 5 wt%을 50 ℃에서 800 rpm로 혼합 교반하여 제3혼합물을 제조하고, Afterwards, 30 wt% of fennel flower oil, 15 wt% of coconut oil, 15 wt% of neem oil, 30 wt% of palm oil, 5 wt% of eucalyptus oil, and 5 wt% of tea tree oil were mixed and stirred at 800 rpm at 50°C. Preparing a third mixture,
그 후, 정제수 50 wt%, 구리 나노 분말 25 wt%, 산화 아연 나노 분말 25 wt%를 80 ℃에서 400 rpm로 혼합 교반하여 제4혼합물을 제조하고, Afterwards, 50 wt% of purified water, 25 wt% of copper nanopowder, and 25 wt% of zinc oxide nanopowder were mixed and stirred at 80°C at 400 rpm to prepare a fourth mixture,
그 후, 상기 제1혼합물 60 wt%, 제2혼합물 15wt%, 제3혼합물 15 wt%, 제4혼합물 5 wt%, 워터 솔루빌라이져 5 wt%를 500 rpm, 90 ℃에서 혼합하여 A혼합물을 제조하고, Afterwards, 60 wt% of the first mixture, 15 wt% of the second mixture, 15 wt% of the third mixture, 5 wt% of the fourth mixture, and 5 wt% of the water solubilizer were mixed at 500 rpm and 90 ° C to obtain mixture A. manufacturing,
상기 A혼합물 70 wt%에 접착제 30 wt%를 투입한 후, 120 ℃ 에서 30초 동안 혼합하여 제조한다. It is prepared by adding 30 wt% of adhesive to 70 wt% of mixture A and mixing at 120°C for 30 seconds.
이하, 본 발명의 실시예 1로 부터 제조된 4겹시트의 시험예를 살펴본다.Hereinafter, we will look at a test example of the 4-ply sheet manufactured in Example 1 of the present invention.
하기, 시험의 결과는 표 1에 나타냈다. Below, the results of the test are shown in Table 1.
[탈취력 시험]: 악취원으로는 암모니아(암모니아 검지관 사용, 003% 수용액 05 mL 사용), 아민(아민류 검지관 사용, 03 % 수용액 05 mL사용), 머캅탄(머캅탄류 검지관 사용, (0.1벤젠용액, 0.1 mL)를 사용하였다. 밀폐된 용기에 4겹시트(정제수 500ml, 20℃에 침지함,)를 넣고 동량의 악취원을 각각 넣은 후, 일정시간 뒤 소취되지 않은 악취의 잔류량을 검지관에 흡입시켜 잔류 가스 농도를 측정했다. 또한, (80 ppm 초과는 불량),(40 ~ 60 ppm은 보통),(10 ~ 30 ppm은 양호)로 판단함. [Deodorization power test]: Odor sources include ammonia (using an ammonia detection tube, using 05 mL of 003% aqueous solution), amines (using an amine detection tube, using 05 mL of a 03% aqueous solution), mercaptan (using a mercaptan detection tube, (0.1 Benzene solution (0.1 mL) was used. Put a 4-ply sheet (500 ml of purified water, immersed at 20°C) in a sealed container, add the same amount of odor source to each, and detect the remaining amount of odor that was not deodorized after a certain period of time. The residual gas concentration was measured by sucking it into a pipe. Additionally, it was judged as (over 80 ppm is bad), (40 ~ 60 ppm is normal), (10 ~ 30 ppm is good).
[확산 시험]: 확산 시험기를 이용하여 수온 20℃를 유지하도록 하고 4겹휴지에서 포함된 항균접착성조성물이 완전 확산된 시간을 육안으로 측정하고 양호, 보통, 불량으로 평가하였다.[Diffusion test]: Using a diffusion tester, the water temperature was maintained at 20°C, and the time for the antibacterial adhesive composition contained in the 4-ply tissue to completely diffuse was visually measured and evaluated as good, average, or poor.
[살균력]: 물 1L에 4겹휴지를 투입한 후, 타임-킬 테스트 방법에 따라 대장균, 황색포도상구균에 30초 간 접촉 후 살균 정도를 측정하였다.[Sterilization power]: After adding 4-ply toilet paper to 1L of water, the degree of sterilization was measured after contact with E. coli and Staphylococcus aureus for 30 seconds according to the time-kill test method.
[피부자극평가]: 생쥐(3kg) 3마리를 사용하고 4겹시트를 털 깎은 부위의 피부에 테잎으로 고정한 후, 1시간동안 접촉시켜 피부 자극 정도를 양호, 보통, 불량으로 평가하였다. [Skin irritation evaluation]: Three mice (3 kg) were used, a 4-ply sheet was fixed to the skin of the shaved area with tape, and the skin irritation was evaluated as good, average, and poor by contacting the skin for 1 hour.
구분
division
탈취력
Deodorizing power
확산 시험
diffusion test
살균력(%)
Sterilization power (%)
피부자극평가
Skin irritation evaluation
4겹휴지
4-ply toilet paper
양호
Good
양호
Good
94%
94%
양호
Good
일측면에 데코무늬가 형성되고 타측면에 갓 추출물이 포함된 항균접착성조성물이 코팅된 두 겹 시트(P1+P2)와, 일측면에 데코무늬가 형성된 또 다른 두 겹 시트(P3+P4)가 합지되어 이루어지는 4겹시트(P1+P2+P3+P4)로 구성되되, 상기 4겹시트(P1+P2+P3+P4)는, 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 시트면과 상기 두 겹 시트(P3+P4)의 일측면이 마주보게 합지되는 것을 특징으로 하는 갓 추출물이 포함된 4겹 시트에 관한 것으로 산업상 이용가능성이 있다. A two-ply sheet (P1+P2) with a decorative pattern on one side and coated with an antibacterial adhesive composition containing mustard extract on the other side, and another two-ply sheet (P3+P4) with a decorative pattern on one side. It is composed of 4-ply sheets (P1+P2+P3+P4) made by lamination, wherein the 4-ply sheets (P1+P2+P3+P4) contain the antibacterial adhesive composition of the two-ply sheets (P1+P2). It relates to a four-ply sheet containing mustard extract, characterized in that the coated sheet surface and one side of the two-ply sheet (P3 + P4) are laminated to face each other, and has industrial applicability.
제1패턴성형부(10)
제2패턴성형부(20)
조성물전이부(30)
합지롤(40)
최종형성부(50)
각추 형태의 돌기(14a)
제1데코무늬실린더(14)
제1압력 로울러(12)
각추 형태의 돌기(24a)
제2데코무늬실린더(24)
제2압력 로울러(22)
데코무늬실린더(24)
잉크공급챔버(C)
잉크공급 로울러(34)
전이돌기(32a)
전이실린더(32)
가이드 로울러(G)
권취용 보빈(51)First pattern forming unit (10)
Second pattern forming unit (20)
Composition transfer unit (30)
Laminated roll (40)
Final forming part (50)
Pyramid-shaped protrusion (14a)
1st deco pattern cylinder (14)
First pressure roller (12)
Pyramid-shaped protrusion (24a)
2nd deco pattern cylinder (24)
Second pressure roller (22)
Deco pattern cylinder (24)
Ink supply chamber (C)
Ink supply roller (34)
Transitional process (32a)
Transition cylinder (32)
Guide roller (G)
Bobbin for winding (51)
Claims (6)
상기 4겹시트(P1+P2+P3+P4)는, 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 시트면과 상기 두 겹 시트(P3+P4)의 일측면이 마주보게 합지되는 갓 추출물이 포함된 4겹 시트에 있어서,
상기 두 겹 시트(P1+P2, P3+P4)는,
펄프 1 ~ 29.5wt%와, 정제수 70.0 ~ 98.5 wt%와, 잎혼합농축액 0.01 ~ 1.0 wt%를 혼합한 혼합펄프를 가열 건조하여 이루어지는 한 겹 시트 두 쌍을 가압·접합하여 이루어지고,
상기 잎혼합농축액은, 초피 잎 1 ~ 40 wt%, 측백나무 잎 1 ~ 40 wt%, 갈참나무 잎 1 ~ 40 wt% 및 산벚나무 잎 1 ~ 40 wt%을 혼합하여 제조된 잎 혼합물을 80 ~ 150 ℃ 에서 볶음 건조하여 잎건조물을 제조하고, 상기 잎 건조물을 80 ~ 150 ℃, 1 ~ 2 시간 동안 열수추출한 후, 여과하여 제조된 잎 혼합추출액을 원심분리기에서 7,500 ~ 8,500 rpm으로 15 ~ 25 분 동안 원심분리하여 수득한 상층액을 여과하고, 여과한 추출물을 감압농축기로 0.1 ~ 0.5 mPA의 조건에서 30 ~ 120분 동안 감압농축하여 제조되는 것을 특징으로 하는 갓 추출물이 포함된 4겹 시트
There is a two-ply sheet (P1+P2) with a decorative pattern on one side and an antibacterial adhesive composition containing mustard extract on the other side, and another two-ply sheet (P3+P4) with a decorative pattern on one side. It is composed of 4-ply sheets (P1+P2+P3+P4) that are laminated,
In the four-ply sheet (P1+P2+P3+P4), the sheet surface coated with the antibacterial adhesive composition of the two-ply sheet (P1+P2) faces one side of the two-ply sheet (P3+P4). In the 4-ply sheet containing mustard extract to be laminated,
The two-ply sheets (P1+P2, P3+P4) are,
It is made by pressing and joining two pairs of one-ply sheets made by heating and drying a mixed pulp of 1 to 29.5 wt% of pulp, 70.0 to 98.5 wt% of purified water, and 0.01 to 1.0 wt% of leaf mixed concentrate,
The leaf mixture concentrate is a leaf mixture prepared by mixing 1 to 40 wt% of Chinese bark leaves, 1 to 40 wt% of arborvitae leaves, 1 to 40 wt% of brown oak leaves, and 1 to 40 wt% of wild cherry leaves. Dried leaves were prepared by roasting and drying at 150°C, the dried leaves were subjected to hot water extraction at 80 to 150°C for 1 to 2 hours, and the mixed leaf extract was filtered and centrifuged at 7,500 to 8,500 rpm for 15 to 25 minutes. A 4-layer sheet containing mustard extract, which is prepared by filtering the supernatant obtained by centrifugation and concentrating the filtered extract under reduced pressure for 30 to 120 minutes under conditions of 0.1 to 0.5 mPA using a vacuum concentrator.
항균접착성조성물은,
갓 잎과 갓 종자를 60 ~ 70 ℃에서 열풍건조한 후, 상기 건조물 10 ~ 30 wt%을 80% 에탄올 70 ~ 90 wt%에 투입한 후, 2 ~ 4 시간 동안 2 ~ 4회 반복하여 환류 추출한 갓 추출물 10 ~ 20wt% 및 정제수 80 ~ 90 wt%을 혼합하여 제조되는 제1혼합물과,
생강 추출물 1 ~ 30 wt%, 오레가노 추출물 1 ~ 30 wt%, 매실 추출물 1 ~ 30 wt%, 차나무 잎 추출물 1 ~ 30 wt%, 자몽 종자 추출물 1 ~ 30 wt%, 레몬 껍질 추출물 1 ~ 30 wt%, 타임 잎 추출물 1 ~ 30 wt%, 적포도과피 추출물 1 ~ 30 wt%, 서양금혼초 줄기 추출물 1 ~ 30 wt%, 오미자 추출물 1 ~ 30 wt% 및 보골지열매추출물 1 ~ 30 wt%를 10 ~ 30 ℃에서 500 ~ 800 rpm로 혼합 교반하여 제조되는 제2혼합물과,
개망초꽃 오일 1 ~ 30 wt%, 코코넛 오일 1 ~ 30 wt%, 님 오일 1 ~ 30 wt%, 팜 오일 1 ~ 30 wt%, 유칼립투스 오일 1 ~ 30 wt% 및 티트리 오일 1 ~ 30 wt%을 40 ~ 50 ℃에서 500 ~ 800 rpm로 혼합 교반하여 제조되는 제3혼합물과,
정제수 1 ~ 50 wt%, 구리 나노 분말 1 ~ 40 wt% 및 산화 아연 나노 분말 1 ~ 40 wt%를 80 ~ 90 ℃에서 300 ~ 400 rpm로 혼합 교반하여 제조되는 제4혼합물과,
상기 제1혼합물 40 ~ 60 wt%, 제2혼합물 1 ~ 30 wt%, 제3혼합물 1 ~ 30 wt%, 제4혼합물 1 ~ 30 wt% 및 워터 솔루빌라이져 1 ~ 30 wt%를 100 ~ 500 rpm, 80 ~ 90 ℃에서 혼합하여 제조되는 A혼합물를 포함하고,
상기 A혼합물 60 ~ 70 wt%에 접착제 30 ~ 40 wt%를 투입한 후, 100 ~ 120 ℃ 에서 30초 동안 혼합하여 제조하는 것을 특징으로 하는 갓 추출물이 포함된 4겹 시트
In claim 1,
The antibacterial adhesive composition is,
After drying mustard leaves and mustard seeds with hot air at 60 to 70°C, 10 to 30 wt% of the dried material was added to 70 to 90 wt% of 80% ethanol, and then refluxed 2 to 4 times for 2 to 4 hours. A first mixture prepared by mixing 10 to 20 wt% of extract and 80 to 90 wt% of purified water,
Ginger extract 1 to 30 wt%, Oregano extract 1 to 30 wt%, Plum extract 1 to 30 wt%, Camellia leaf extract 1 to 30 wt%, Grapefruit seed extract 1 to 30 wt%, Lemon peel extract 1 to 30 wt% , 1 to 30 wt% of thyme leaf extract, 1 to 30 wt% of red grape skin extract, 1 to 30 wt% of Western Georgina rhododendron stem extract, 1 to 30 wt% of Schisandra chinensis extract, and 1 to 30 wt% of Bogolji fruit extract. A second mixture prepared by mixing and stirring at 500 to 800 rpm at ~30°C,
Contains 1 to 30 wt% of eucalyptus oil, 1 to 30 wt% of coconut oil, 1 to 30 wt% of neem oil, 1 to 30 wt% of palm oil, 1 to 30 wt% of eucalyptus oil, and 1 to 30 wt% of tea tree oil. A third mixture prepared by mixing and stirring at 40 to 50 ℃ and 500 to 800 rpm,
A fourth mixture prepared by mixing and stirring 1 to 50 wt% of purified water, 1 to 40 wt% of copper nanopowder, and 1 to 40 wt% of zinc oxide nanopowder at 80 to 90°C at 300 to 400 rpm,
40 to 60 wt% of the first mixture, 1 to 30 wt% of the second mixture, 1 to 30 wt% of the third mixture, 1 to 30 wt% of the fourth mixture, and 1 to 30 wt% of the water solubilizer at 100 to 500 It includes mixture A prepared by mixing at 80 to 90 ℃ at rpm,
A 4-ply sheet containing fresh extract, characterized in that it is prepared by adding 30 to 40 wt% of adhesive to 60 to 70 wt% of mixture A and mixing for 30 seconds at 100 to 120 ° C.
두 겹 시트 한 쌍이 구비되는 단계와,
상기 두 겹 시트 중 하나의 시트(P1+P2)가, 각추 형태의 돌기가 형성된 제1데코무늬실린더 및 제1압력 로울러 사이로 통과되어 가압되면서 상기 두 겹 시트(P1+P2) 일측면에 데코무늬가 형성되는 단계와,
상기 두 겹 시트 중 다른 하나의 시트(P3+P4)가 각추 형태의 돌기가 형성되는 제2데코무늬실린더 및 제2압력 로울러 사이로 통과되어 가압되면서 상기 두 겹 시트(P3+P4) 일측면에 데코무늬가 형성되는 단계와,
갓 추출물이 포함된 항균접착성조성물이 잉크공급챔버에 충진되고, 상기 잉크공급챔버가 잉크공급 로울러와 접촉되어 상기 잉크공급 로울러에 상기 항균접착성조성물이 1차 전이되는 단계와,
상기 항균접착성조성물이 1차 전이된 잉크공급 로울러가 전이 실린더와 접촉되면서, 전이돌기가 표면에 형성된 전이돌기에 상기 항균접착성조성물이 2차 전이되는 단계와,
상기 항균접착성조성물이 2차 전이된 전이돌기가 상기 데코무늬가 형성된 두 겹 시트(P1+P2)의 데코무늬가 형성되지 않은 시트면과 접촉되면서 상기 의 데코무늬가 형성되지 않은 두 겹 시트(P1+P2)의 일측면에 항균접착성조성물이 3차 전이되어 코팅되는 단계와,
상기 일측면에 데코무늬가 형성되고 타측면에 항균접착성조성물이 코팅된 두 겹 시트(P1+P2)와 상기 일측면에 데코무늬가 형성된 두 겹 시트(P3+P4)가 제1압력 로울러 및 제2압력 로울러 사이에 동시 통과되어 상기 두 겹 시트(P1+P2)의 항균접착성조성물이 코팅된 면에 상기 두 겹 시트(P3+P4)가 접합됨으로써 4겹시트(P1+P2+P3+P4)가 형성되는 단계와,
상기 4겹시트가 합지롤을 통과하여 합지되고, 상기 합지된 최종 4겹시트가 가이드 로울러를 통하여 권취용 보빈으로 이송되는 단계가 포함되는 갓 추출물이 포함된 4겹 시트 제조방법
In manufacturing a 4-ply sheet through a double-layer paper sheet manufacturing device,
providing a pair of two-ply sheets;
One of the two-ply sheets (P1 + P2) is passed between the first deco pattern cylinder and the first pressure roller in which pyramid-shaped protrusions are formed and is pressed, forming a deco pattern on one side of the two-ply sheet (P1 + P2). The stage in which it is formed,
The other one of the two-ply sheets (P3 + P4) is passed between the second deco pattern cylinder and the second pressure roller in which pyramid-shaped protrusions are formed and is pressed, thereby forming a deco on one side of the two-ply sheets (P3 + P4). The stages in which patterns are formed,
An antibacterial adhesive composition containing a leaf extract is filled in an ink supply chamber, the ink supply chamber is brought into contact with an ink supply roller, and the antibacterial adhesive composition is first transferred to the ink supply roller;
A step of secondary transfer of the antibacterial adhesive composition to the transfer protrusions formed on the surface as the ink supply roller to which the antibacterial adhesive composition is first transferred is brought into contact with a transfer cylinder;
The transfer protrusion to which the antibacterial adhesive composition is secondaryly transferred contacts the sheet surface on which the decoration pattern is not formed of the two-ply sheet (P1 + P2) on which the decoration pattern is formed, and the two-ply sheet on which the decoration pattern is not formed ( A third transfer step of coating an antibacterial adhesive composition on one side of P1+P2);
A two-ply sheet (P1+P2) with a deco pattern formed on one side and coated with an antibacterial adhesive composition on the other side and a two-ply sheet (P3+P4) with a deco pattern formed on one side are formed on a first pressure roller and The two-ply sheets (P3+P4) are simultaneously passed between the second pressure rollers and bonded to the antibacterial adhesive composition-coated side of the two-ply sheets (P1+P2), forming a four-ply sheet (P1+P2+P3+ The stage in which P4) is formed,
A method of producing a 4-ply sheet containing fresh extract, which includes the step of lamination of the 4-ply sheet through a lamination roll, and transferring the laminated final 4-ply sheet to a winding bobbin through a guide roller.
상기 복층 페이퍼 시트 제조장치는,
각추 형태의 돌기가 형성되는 제1데코무늬실린더와 제1압력 로울러가 구비되어, 상기 데코무늬실린더 및 제1압력 로울러 사이에 두 겹 시트(P1+P2)가 통과되어 가압되면서 상기 두 겹 시트(P1+P2) 일측면에 데코무늬가 형성되는 제1패턴성형부;
각추 형태의 돌기가 형성되는 제2데코무늬실린더와 제2압력 로울러가 구비되어, 데코무늬실린더(24) 및 제2압력 로울러 사이에 두 겹 시트(P3+P4)가 통과되어 가압되면서 상기 두 겹 시트(P3+P4) 일측면에 데코무늬가 형성되는 제2패턴성형부;
갓 추출물이 포함된 항균접착성조성물이 충전된 잉크공급챔버로부터 상기 항균접착성조성물을 공급받는 잉크공급 로울와 상기 잉크공급 로울러와 접촉되는 전이돌기가 표면에 형성된 전이실린더로 구성되고, 상기 전이돌기에 의하여 상기 시트(P1+P2)의 일측면이 항균접착성조성물로 코팅되되, 상기 전이실린더가 상기 제1압력 로울러와 접촉되는 조성물전이부;
상기 제1패턴성형부, 제2패턴성형부 및 조성물전이부를 통과한 상기 두 겹 시트(P1+P2) 및 두 겹 시트(P3+P4)가 접합되어 형성된 4겹시트(P1+P2+P3+P4)가 형성되고, 상기 4겹시트가 최종 합지되는 합지롤;
상기 합지롤를 통하여 최종 합지된 4겹시트를 가이드 로울러를 통하여 권취용 보빈으로 이송하는 최종형성부;가 더 포함되는 것을 특징으로 하는 갓 추출물이 포함된 4겹 시트 제조방법.
In claim 5,
The multi-layer paper sheet manufacturing device,
A first deco pattern cylinder in which pyramid-shaped protrusions are formed and a first pressure roller are provided, and a two-ply sheet (P1 + P2) is passed between the deco pattern cylinder and the first pressure roller and pressurized, thereby forming the two-ply sheet ( P1+P2) A first pattern forming portion where a deco pattern is formed on one side;
A second deco pattern cylinder in which pyramid-shaped protrusions are formed and a second pressure roller are provided, and a two-ply sheet (P3 + P4) is passed between the deco pattern cylinder 24 and the second pressure roller and pressurized, thereby forming the two layers. a second pattern forming portion in which a deco pattern is formed on one side of the sheet (P3+P4);
It consists of an ink supply roll that receives the antibacterial adhesive composition from an ink supply chamber filled with an antibacterial adhesive composition containing a leaf extract, and a transfer cylinder on the surface of which a transfer protrusion in contact with the ink supply roller is formed, and the transfer protrusion has One side of the sheet (P1+P2) is coated with an antibacterial adhesive composition, and the composition transfer portion where the transfer cylinder is in contact with the first pressure roller;
A four-ply sheet (P1 + P2 + P3 + P4) is formed, and the lamination roll in which the 4-ply sheets are finally laminated;
A method of manufacturing a 4-ply sheet containing fresh mustard extract, further comprising a final forming part that transfers the 4-ply sheet finally laminated through the lamination roll to a winding bobbin through a guide roller.
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