KR102603965B1 - Aqueous and oil-based adhesive - Google Patents
Aqueous and oil-based adhesive Download PDFInfo
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- KR102603965B1 KR102603965B1 KR1020210176569A KR20210176569A KR102603965B1 KR 102603965 B1 KR102603965 B1 KR 102603965B1 KR 1020210176569 A KR1020210176569 A KR 1020210176569A KR 20210176569 A KR20210176569 A KR 20210176569A KR 102603965 B1 KR102603965 B1 KR 102603965B1
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- cement
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- 239000000853 adhesive Substances 0.000 title claims abstract description 47
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 38
- 238000004078 waterproofing Methods 0.000 claims abstract description 29
- 239000004568 cement Substances 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 238000010276 construction Methods 0.000 claims abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010883 coal ash Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 9
- 239000011707 mineral Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 235000010755 mineral Nutrition 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 229910052602 gypsum Inorganic materials 0.000 claims description 7
- 239000010440 gypsum Substances 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 239000002893 slag Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 241000218691 Cupressaceae Species 0.000 claims description 6
- 229920002050 silicone resin Polymers 0.000 claims description 6
- 239000011398 Portland cement Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 4
- 239000000920 calcium hydroxide Substances 0.000 claims description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 4
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 4
- 239000010881 fly ash Substances 0.000 claims description 4
- 239000004566 building material Substances 0.000 abstract description 12
- 239000013464 silicone adhesive Substances 0.000 abstract description 8
- 239000002956 ash Substances 0.000 description 18
- 229920001296 polysiloxane Polymers 0.000 description 17
- 238000002156 mixing Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 8
- -1 alkylene compound Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004484 Briquette Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000003522 acrylic cement Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 2
- 240000004045 Cassia javanica Species 0.000 description 2
- 241000911175 Citharexylum caudatum Species 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000015001 Cucumis melo var inodorus Nutrition 0.000 description 2
- 240000002495 Cucumis melo var. inodorus Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 240000001972 Gardenia jasminoides Species 0.000 description 2
- 241000208152 Geranium Species 0.000 description 2
- 235000010254 Jasminum officinale Nutrition 0.000 description 2
- 240000005385 Jasminum sambac Species 0.000 description 2
- 244000178870 Lavandula angustifolia Species 0.000 description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 2
- 241000234435 Lilium Species 0.000 description 2
- 235000006679 Mentha X verticillata Nutrition 0.000 description 2
- 235000002899 Mentha suaveolens Nutrition 0.000 description 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 2
- 240000002505 Pogostemon cablin Species 0.000 description 2
- 235000011751 Pogostemon cablin Nutrition 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- 240000000513 Santalum album Species 0.000 description 2
- 235000008632 Santalum album Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 244000172533 Viola sororia Species 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000177 juniperus communis l. berry Substances 0.000 description 2
- 239000001102 lavandula vera Substances 0.000 description 2
- 235000018219 lavender Nutrition 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- CCDWGDHTPAJHOA-UHFFFAOYSA-N benzylsilicon Chemical compound [Si]CC1=CC=CC=C1 CCDWGDHTPAJHOA-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000012767 functional filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/02—Homopolymers or copolymers of monomers containing phosphorus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
본 발명은 향기나는 방수 접착제 및 이의 제조방법에 관한 것으로서, 보다 상세하게는 특수 시멘트, 아크릴계 방수제, 석탄회 또는 플래니탑(Planitop) 중 어느 하나, 특수 무기질 파우더 및 청향제를 포함하는 건축용 방수 접착제 및 이의 제조방법에 관한 것이다. 본 발명에 따른 접착제는 모든 건축 자재에 다용도로 사용 가능하고, 100% 불연제이며, 기존 실리콘 접착제 제품 보다 2 ~ 3배 이상 수명이 길고, 접착력이 매우 우수한 반영구적인 제품으로 건축 자재 접착에 유용하게 사용될 수 있다. The present invention relates to a scented waterproof adhesive and a method for manufacturing the same, and more specifically to a waterproof adhesive for construction containing special cement, an acrylic waterproofing agent, either coal ash or Planitop, a special mineral powder, and a freshener, and the manufacturing thereof. It's about method. The adhesive according to the present invention can be used for various purposes on all building materials, is 100% non-flammable, has a lifespan of 2 to 3 times longer than existing silicone adhesive products, and is a semi-permanent product with excellent adhesive strength, making it useful for adhering building materials. can be used
Description
본 발명은 건축용 방수 접착제 및 이의 제조방법에 관한 것으로서, 보다 상세하게는 특수 시멘트, 아크릴계 방수제, 연소된 재(ash) 및 특수 무기질 파우더를 포함하는 건축용 방수 접착제 및 이의 제조방법에 관한 것이다. The present invention relates to a waterproofing adhesive for construction and a method for manufacturing the same. More specifically, it relates to a waterproofing adhesive for construction containing special cement, acrylic waterproofing agent, burned ash, and special mineral powder, and a method for manufacturing the same.
일반적으로 주택이나 사무실 공장 등에서는 신축이나 보수 시 내 외부 장식 및 마감 처리재로서 타일 또는 전돌타일을 주로 사용하고 있다. 최근에는 작업의 편이성 및 시공 시간의 절약을 위하여 타일의 크기도 점차 대형화되는 추세이다. 또한, 장소에 상관없이 습기가 많은 화장실이나 세면장, 욕실 등에도 타일 시공을 원하고 있다. 그러한 이유로 타일 접착제는 갈수록 고부착성, 고내수성을 요구하고 있다.In general, tiles or brick tiles are mainly used as interior and exterior decoration and finishing materials during new construction or repairs in houses, offices, and factories. Recently, the size of tiles is gradually becoming larger for convenience of work and saving of construction time. In addition, regardless of the location, people want to install tiles in bathrooms, washrooms, and bathrooms where there is a lot of moisture. For that reason, tile adhesives are increasingly required to have high adhesion and high water resistance.
기존 타일 접착제는 타일 또는 전돌타일로 내·외벽 압착본드로 판넬에 시공해도 5 ~ 6년이 지나면 타일이 하나씩 떨어져 보기가 좋지 않다.Even if the existing tile adhesive is applied to the panel by pressing bond on the interior and exterior walls of tiles or brick tiles, the tiles fall off one by one after 5 to 6 years, which does not look good.
이에, 본 발명자는 상술한 문제점을 해결하기 위해, 기존 제품에 비해 접착력 및 지속력이 향상된 새로운 건축용 방수 접착제를 개발하기 위해 노력한 결과, 특수 시멘트, 아크릴계 방수제, 연소된 재(ash) 및 특수 무기질 파우더를 혼합하여 제조한 접착제가 다양한 건축자재에 모두 접착력이 우수하고, 기존제품인 내·외장 실리콘 접착제 보다 접착력이 높고 2 ~ 3배 이상 접착 지속력이 높은 것을 확인함으로써, 본 발명을 완성하였다. Accordingly, in order to solve the above-mentioned problems, the present inventor made efforts to develop a new construction waterproofing adhesive with improved adhesion and durability compared to existing products. As a result, special cement, acrylic waterproofing agent, burned ash, and special mineral powder were used. The present invention was completed by confirming that the adhesive produced by mixing has excellent adhesion to various building materials, has higher adhesion than existing interior and exterior silicone adhesives, and has 2 to 3 times higher adhesion durability.
본 발명의 목적은 기존 실리콘 접착제의 접착력 및 지속력이 떨어지는 문제점을 해결하기 위해, 특수 시멘트, 아크릴계 방수제, 석탄회 또는 플래니탑(Planitop) 중 어느 하나, 및 특수 무기질 파우더를 혼합하여 다양한 건축자재에 모두 접착력이 우수하고, 기존제품인 내·외장 실리콘 접착제 보다 접착력이 높고 2 ~ 3배 이상 접착 지속력이 높은 새로운 접착제를 제공하는 것이다.The purpose of the present invention is to solve the problem of poor adhesion and durability of existing silicone adhesives, and to provide adhesion to various building materials by mixing special cement, acrylic waterproofing agent, coal ash or Planitop, and special mineral powder. The goal is to provide a new adhesive that is excellent and has higher adhesion than the existing interior/exterior silicone adhesive and has 2 to 3 times more adhesive durability.
상기 목적을 달성하기 위하여, 본 발명은 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 포함하는 건축용 방수 접착제를 제공한다.In order to achieve the above object, the present invention contains 15 to 30% by weight of special cement, 10 to 20% by weight of an acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, and 15% by weight of inorganic powder. Provided is a waterproof adhesive for construction containing ~25% by weight and water.
또한, 본 발명은 실리콘 3 ~ 40 중량%, 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 포함하는 건축용 방수 접착제를 제공한다. In addition, the present invention contains 3 to 40% by weight of silicon, 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, and inorganic substances. A waterproof adhesive for construction containing 15 to 25% by weight of powder and water is provided.
또한, 본 발명은 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 혼합한 후 교반하는 공정을 포함하는 건축용 방수 접착제의 제조방법을 제공한다.In addition, the present invention includes 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, 15 to 25% by weight of inorganic powder, and A method of manufacturing a waterproof adhesive for construction is provided, including a process of mixing water and then stirring.
또한, 본 발명은 실리콘 3 ~ 40 중량%, 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 혼합한 후 교반하는 공정을 포함하는 건축용 방수 접착제의 제조방법을 제공한다.In addition, the present invention contains 3 to 40% by weight of silicon, 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, and inorganic substances. A method for manufacturing a waterproof adhesive for construction is provided, including a process of mixing 15 to 25% by weight of powder and water and then stirring.
아울러, 본 발명은 상기 본 발명에 따른 방수 접착제를 타일 등 건축자재에 타설하여 부착하는 시공방법을 제공한다.In addition, the present invention provides a construction method for attaching the waterproof adhesive according to the present invention by pouring it to building materials such as tiles.
본 발명에 따른 접착제는 철판, 판넬, 유리, 목재, 콘크리트, 플라스틱 및 기타 등 모든 건축 자재에 다용도로 사용 가능하고, 100% 불연제이며, 기존 실리콘 접착제 제품 보다 2 ~ 3배 이상 수명이 길고, 접착력이 매우 우수한 반영구적인 제품으로 건축 자재 접착에 유용하게 사용될 수 있다.The adhesive according to the present invention can be used for various purposes on all building materials such as steel plates, panels, glass, wood, concrete, plastic and others, is 100% non-flammable, and has a lifespan of 2 to 3 times longer than existing silicone adhesive products. It is a semi-permanent product with excellent adhesion and can be useful for adhering building materials.
특히, 기존 실리콘 접착제 제품의 경우, 타일 또는 전돌타일로 내·외벽 압착본드로 판넬에 시공하면 5 ~ 6년이 지나면 타일이 하나씩 떨어지는 반면, 본 발명에 따른 접착제 제품을 사용하는 경우 20년 이상 떨어지지 않고 유지될 수 있다.In particular, in the case of existing silicone adhesive products, when the tiles or brick tiles are installed on the panel with pressure bonding on the inner and outer walls, the tiles fall off one by one after 5 to 6 years, whereas when the adhesive product according to the present invention is used, the tiles do not fall off for more than 20 years. can be maintained without
도 1은 본 발명의 접착제를 사용한 한가지 실시예를 보여주는 사진이다.
도 2는 본 발명의 접착제를 사용한 또다른 한가지 실시예를 보여주는 사진이다.
도 3은 본 발명의 접착제를 사용한 또다른 한가지 실시예(수성·유성 겸용 실리콘 사용, 석탄회 사용, 향기나는 방수 실리콘 사용)를 보여주는 사진이다.
도 4는 본 발명의 접착제를 사용한 또다른 한가지 실시예(수성·유성 겸용 실리콘 사용)를 보여주는 사진이다.
도 5는 본 발명의 접착제를 사용한 또다른 한가지 실시예(석탄회 실리콘 사용)를 보여주는 사진이다.1 is a photograph showing one example using the adhesive of the present invention.
Figure 2 is a photograph showing another example using the adhesive of the present invention.
Figure 3 is a photograph showing another example using the adhesive of the present invention (use of water-based and oil-based silicone, use of coal ash, use of scented waterproof silicone).
Figure 4 is a photograph showing another example using the adhesive of the present invention (using water-based and oil-based silicone).
Figure 5 is a photograph showing another example (using coal ash silicon) using the adhesive of the present invention.
이하, 본 발명을 상세하게 설명한다. Hereinafter, the present invention will be described in detail.
본 발명을 설명함에 있어서 관련된 공지 구성 또는 기능에 대한 상세한 설명은 생략할 수 있다.In describing the present invention, detailed descriptions of related known structures or functions may be omitted.
본 명세서 및 특허청구범위에 사용된 용어나 단어는 통상적이거나 사전적 의미로 한정되어 해석되지 아니하며, 본 발명의 기술적 사항에 부합하는 의미와 개념으로 해석되어야 한다.Terms or words used in this specification and patent claims should not be construed as limited to their usual or dictionary meanings, but should be construed with meanings and concepts consistent with the technical details of the present invention.
본 명세서에 기재된 실시예와 도면에 도시된 구성은 본 발명의 바람직한 실시예이며, 본 발명의 기술적 사상을 모두 대변하는 것이 아니므로, 본 출원 시점에서 이들을 대체할 수 있는 다양한 균등물과 변형예들이 있을 수 있다.The embodiments described in this specification and the configurations shown in the drawings are preferred embodiments of the present invention, and do not represent the entire technical idea of the present invention, so various equivalents and modifications that can replace them at the time of filing the present application are available. There may be.
본 발명은 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 포함하는 건축용 방수 접착제를 제공한다.The present invention includes 15 to 30% by weight of special cement, 10 to 20% by weight of an acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, 15 to 25% by weight of mineral powder, and water. Provides a waterproof adhesive for construction containing:
상기 특수 시멘트는 보통포틀랜드시멘트 20 ~ 80 중량%, 클링커 파우더 3 ~ 30중량%, 슬래그 미분말 2 ~ 40 중량%, 석고 미분말 0 ~ 20 중량% 및 소석회 0 ~ 5 중량%를 포함하는 것이 바람직하다.The special cement preferably contains 20 to 80% by weight of ordinary Portland cement, 3 to 30% by weight of clinker powder, 2 to 40% by weight of fine slag powder, 0 to 20% by weight of fine gypsum powder, and 0 to 5% by weight of slaked lime.
이때, 상기 클링커 파우더의 첨가량은 3 ~ 30 중량%가 바람직한데, 그 이유는, 클링커 파우더를 3% 이하 첨가하면 고형화 촉진 효과가 떨어지고, 30% 이상 첨가하면 급결이 발생하여 작업성이 떨어지고 그로 인해 고형체 제작의 결함으로 장기강도도 떨어지기 때문이다.At this time, the amount of clinker powder added is preferably 3 to 30% by weight. The reason is that if less than 3% of clinker powder is added, the effect of promoting solidification decreases, and if more than 30% is added, rapid setting occurs and workability decreases. This is because long-term strength is reduced due to defects in solid body manufacturing.
상기 슬래그 미분말이나 석고의 혼합비율은 고형화시키는 대상물에 따라 배합비율을 정할 수 있다. 내화학성이나 내해수성 등이 필요한 곳일 수록 배합비를 높이는 것이 좋다. 슬래그 미분말의 경우, 40% 이상 혼합하면 슬래그 특성으로 강도발현이 늦어져 고형화 작업이 어려워지며, 석고의 경우 20% 이상 사용하면 석고의 응결지연 특성으로 고형화가 늦어지고, 고형화물이 팽창하며 강도가 낮아진다.The mixing ratio of the slag fine powder or gypsum can be determined depending on the object to be solidified. Where chemical resistance or seawater resistance is required, it is better to increase the mixing ratio. In the case of slag fine powder, if more than 40% is mixed, the development of strength is delayed due to the characteristics of slag, making solidification work difficult. In the case of gypsum, if more than 20% is used, solidification is delayed due to the setting delay characteristics of gypsum, the solidified product expands, and the strength decreases. It gets lower.
상기 아크릴계 방수제는 수용성 아크릴 수지 60 ~ 70 중량%, 수용성 아크릴-실리콘 수지 20 ~ 30 중량%, 유화제 1 ~ 3 중량%, 증점제 1 ~ 3 중량%, 실리카 0 ~ 3 중량%를 포함하는 것이 바람직하다.The acrylic waterproofing agent preferably contains 60 to 70% by weight of water-soluble acrylic resin, 20 to 30% by weight of water-soluble acrylic-silicone resin, 1 to 3% by weight of emulsifier, 1 to 3% by weight of thickener, and 0 to 3% by weight of silica. .
이때, 상기 수용성 아크릴 수지는 알킬 아크릴레이트 모노머, 알킬렌 화합물, 스티렌, 라디칼 중합개시제 및 유기용제를 포함하는 혼합물을 중합시킨 공중합체로서, 아크릴레이트 모노머 40 ~ 50 중량%, 알킬렌 화합물 10 ~ 15 중량%, 스티렌 5 ~ 10 중량%, 라디칼 중합개시제 0.01 ~ 0.2 중량% 및 유기용제 잔량을 포함할 수 있다.At this time, the water-soluble acrylic resin is a copolymer obtained by polymerizing a mixture containing an alkyl acrylate monomer, an alkylene compound, styrene, a radical polymerization initiator, and an organic solvent, and is comprised of 40 to 50% by weight of acrylate monomer and 10 to 15% by weight of alkylene compound. % by weight, it may include 5 to 10 wt% of styrene, 0.01 to 0.2 wt% of radical polymerization initiator, and the remaining amount of organic solvent.
상기 수용성 아크릴-실리콘 수지는 주된 방수 효과를 부여하는 수용성 아크릴 수지와 함께 사용되어 방수 효과를 증진시키며, 시멘트 등 다른 성분들과 수용성 아크릴-실리콘 수지 등 방수제 성분과의 결합력을 증대시키는 역할을 하는 것이며, 사용량이 20 중량부 미만이면 이의 사용으로 인한 방수제의 방수 증대 효과가 미비할 수 있고, 50 중량부를 초과하여 사용하는 것은 기계적 물성을 감소시킬 수 있다.The water-soluble acrylic-silicone resin is used together with the water-soluble acrylic resin, which provides the main waterproofing effect, to enhance the waterproofing effect, and serves to increase the bonding strength between other components such as cement and waterproofing agent components such as the water-soluble acrylic-silicone resin. , if the amount used is less than 20 parts by weight, the effect of increasing the waterproofing of the waterproofing agent due to its use may be insufficient, and if it is used in excess of 50 parts by weight, the mechanical properties may be reduced.
상기 유화제는 조성간 혼화성을 증대시키고, 타성분들과의 상용성을 증대시키는 역할을 하는 것으로서, 사용량은 수용성 아크릴 수지 100 중량부에 대하여, 1 ~ 3 중량부, 바람직하게는 1.2 ~ 2.8 중량부 사용하는 것이 바람직하며, 이때, 유화제 사용량이 1 중량부 미만이면 그 사용량이 너무 적어서 이의 사용으로 인한 조성물간 혼화성 증대가 미비할 수 있고, 3 중량부를 초과하여 사용하는 과량 사용이며, 추가 사용으로 인한 효과 증대가 없고 오히려 상대적으로 다른 조성물 사용량이 줄게 되므로 상기 범위 내로 사용하는 것이 좋다. 상기 유화제는 음이온성 유화제 및 비이온성 유화제 중에서 선택된 1종 이상을 포함할 수 있고, 상기 음이온성 유화제는 장쇄 알킬 카르복실산염, 술포숙신산알킬에스테르염, 알킬벤젠술폰산염 및 라우릴황산 나트륨 중에서 선택된 1종 이상을 포함할 수 있고, 상기 비이온성 유화제는 폴리옥시에틸렌(C2~C5의 직쇄형 알킬)에테르, 폴리옥시에틸렌노닐페닐에테르, 폴리에틸렌옥사이드폴리프로필렌옥사이드 공중합체 중에서 선택된 1종 이상을 포함할 수 있다.The emulsifier serves to increase miscibility between compositions and compatibility with other ingredients, and the amount used is 1 to 3 parts by weight, preferably 1.2 to 2.8 parts by weight, based on 100 parts by weight of the water-soluble acrylic resin. It is preferable to use it, and at this time, if the amount of emulsifier used is less than 1 part by weight, the amount used is too small and the increase in compatibility between compositions due to its use may be insufficient. If it is used in excess of 3 parts by weight, it is an excessive use, and additional use may result in insufficient emulsifier use. Since the effect does not increase and the amount of other compositions used is relatively reduced, it is better to use it within the above range. The emulsifier may include one or more selected from anionic emulsifiers and nonionic emulsifiers, and the anionic emulsifier is one selected from long-chain alkyl carboxylate, sulfosuccinic acid alkyl ester salt, alkylbenzene sulfonate, and sodium lauryl sulfate. It may include more than one type, and the nonionic emulsifier may include one or more types selected from polyoxyethylene (C2-C5 linear alkyl) ether, polyoxyethylene nonylphenyl ether, and polyethylene oxide-polypropylene oxide copolymer. there is.
상기 증점제는 적정 점도를 가지도록 하는 역할을 하는 것으로서, 당업계에서 사용하는 일반적인 증점제를 사용할 수 있고, 바람직하게는 하이드록시에틸셀룰로오즈(HydroxyEthyl Cellulose), 소수성 우레탄변성계 증점제 중에서 선택된 1종 이상을 포함할 수 있다. 증점제 사용량은 수용성 아크릴 수지 100 중량부에 대하여, 1 ~ 3 중량부, 바람직하게는 1.5 ~ 3 중량부를 사용하는 것이 적정 점도 확보면에서 유리하다.The thickener plays a role in ensuring an appropriate viscosity, and any general thickener used in the art can be used, and preferably includes at least one selected from among hydroxyethyl cellulose and hydrophobic urethane-modified thickeners. can do. It is advantageous to use 1 to 3 parts by weight of the thickener, preferably 1.5 to 3 parts by weight, based on 100 parts by weight of the water-soluble acrylic resin in terms of securing an appropriate viscosity.
상기 연소된 재(ash)는 연탄재, 석탄회, 석탄재, 조개탄재 및 화산재로 구성된 군으로부터 선택된 어느 하나 또는 둘 이상일 수 있다.The burned ash may be any one or two or more selected from the group consisting of briquette ash, coal ash, coal ash, briquette ash, and volcanic ash.
상기 플래니탑은 플래니탑(Planitop) 30K 또는 CD1 중 어느 하나를 더 포함할 수 있다. The Planitop may further include either Planitop 30K or CD1.
상기 특수 무기질 파우더는 주요 성분이 시멘트와 규사를 혼합하여 기능성 충진제와 제품 성능 향상을 위한 첨가제를 혼입한 방수재로 구성되며, 물의 첨가에 따라 화학적으로 반응하고 콘크리트 등의 시멘트계 바탕재 조직 속에서 불용성의 수화물을 생성하는 미세 분말 형태의 재료이다. 상기 특수 무기질 파우더는 규사 30 ~ 40 중량%, 알루미나 시멘트 20 ~ 40 중량% 및 플라이애쉬 10 ~ 40 중량%를 포함하는 것이 바람직하다. The special inorganic powder is composed of a waterproofing material in which the main ingredients are a mixture of cement and silica sand mixed with functional fillers and additives to improve product performance. It reacts chemically with the addition of water and forms an insoluble form in the structure of cement-based base materials such as concrete. It is a material in the form of a fine powder that creates hydrates. The special inorganic powder preferably contains 30 to 40% by weight of silica sand, 20 to 40% by weight of alumina cement, and 10 to 40% by weight of fly ash.
상기 물은 5 ~ 20 중량% 포함하는 것이 바람직하나 이에 한정되지 않는다.The water is preferably contained in an amount of 5 to 20% by weight, but is not limited thereto.
상기 접착제는 청향제를 더 포함할 수 있다. 이때, 청향제는 물을 대신하여 일부 포함할 수 있다. The adhesive may further include a freshener. At this time, some fresheners may be included in place of water.
상기 청향제로는 편백, 아로마, 로즈, 알데하이딕, 허브, 커피향, 쟈스민, 치자향, 바이올렛잎, 플로럴, 애플블라썸, 오리엔탈, 페브리즈, 라벤다, 그린, 민트, 라임, 신저, 워터, 머그렛, 백합, 허니듀, 제라듐, 주니퍼베리, 샌달우드, 쿠마린 및 파출리로 구성된 군으로부터 선택된 어느 하나 또는 둘 이상의 향을 나타내는 식물 추출물 또는 분획물일 수 있다.The freshening agents include cypress, aroma, rose, aldehydic, herb, coffee scent, jasmine, gardenia, violet leaf, floral, apple blossom, oriental, Febreze, lavender, green, mint, lime, sour, water, muglet. , lily, honeydew, geranium, juniper berry, sandalwood, coumarin, and patchouli may be a plant extract or fraction exhibiting one or more scents selected from the group consisting of.
또한, 본 발명은 실리콘 3 ~ 40 중량%, 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 포함하는 건축용 방수 접착제를 제공한다. In addition, the present invention contains 3 to 40% by weight of silicon, 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, and inorganic substances. A waterproof adhesive for construction containing 15 to 25% by weight of powder and water is provided.
상기 실리콘은 수성 실리콘, 수성 및 유성 겸용 실리콘, 바이오(크랙) 실리콘, 향기나는 방수 실리콘, 석탄회 방수 실리콘 및 방화용 내열 실리콘으로 구성된 군으로 부터 선택된 어느 하나일 수 있다. The silicone may be any one selected from the group consisting of water-based silicone, water-based and oil-based silicone, bio (crack) silicone, scented waterproof silicone, coal ash waterproof silicone, and heat-resistant silicone for fire prevention.
또한, 본 발명은 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 혼합한 후 교반하는 공정을 포함하는 건축용 방수 접착제의 제조방법을 제공한다.In addition, the present invention includes 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, 15 to 25% by weight of inorganic powder, and A method of manufacturing a waterproof adhesive for construction is provided, including a process of mixing water and then stirring.
상기 특수 시멘트는 보통포틀랜드시멘트 20 ~ 80 중량%, 클링커 파우더 3 ~ 30중량%, 슬래그 미분말 2 ~ 40 중량%, 석고 미분말 0 ~ 20 중량% 및 소석회 0 ~ 5 중량%를 포함하는 것이 바람직하다.The special cement preferably contains 20 to 80% by weight of ordinary Portland cement, 3 to 30% by weight of clinker powder, 2 to 40% by weight of fine slag powder, 0 to 20% by weight of fine gypsum powder, and 0 to 5% by weight of slaked lime.
상기 아크릴계 방수제는 수용성 아크릴 수지 60 ~ 70 중량%, 수용성 아크릴-실리콘 수지 20 ~ 30 중량%, 유화제 1 ~ 3 중량%, 증점제 1 ~ 3 중량%, 실리카 0 ~ 3 중량%를 포함하는 것이 바람직하다.The acrylic waterproofing agent preferably contains 60 to 70% by weight of water-soluble acrylic resin, 20 to 30% by weight of water-soluble acrylic-silicone resin, 1 to 3% by weight of emulsifier, 1 to 3% by weight of thickener, and 0 to 3% by weight of silica. .
상기 연소된 재(ash)는 연탄재, 석탄회, 석탄재, 조개탄재 및 화산재로 구성된 군으로부터 선택된 어느 하나 또는 둘 이상일 수 있다.The burned ash may be any one or two or more selected from the group consisting of briquette ash, coal ash, coal ash, briquette ash, and volcanic ash.
상기 플래니탑은 플래니탑(Planitop) 30K 또는 CD1 중 어느 하나를 더 포함할 수 있다. The Planitop may further include either Planitop 30K or CD1.
상기 특수 무기질 파우더는 규사 30 ~ 40 중량%, 알루미나 시멘트 20 ~ 40 중량% 및 플라이애쉬 10 ~ 40 중량%를 포함하는 것이 바람직하다. The special inorganic powder preferably contains 30 to 40% by weight of silica sand, 20 to 40% by weight of alumina cement, and 10 to 40% by weight of fly ash.
상기 물은 5 ~ 20 중량% 포함하는 것이 바람직하나 이에 한정되지 않는다.The water is preferably contained in an amount of 5 to 20% by weight, but is not limited thereto.
상기 접착제는 청향제를 더 포함할 수 있다. 이때, 청향제는 물을 대신하여 일부 포함할 수 있다. The adhesive may further include a freshener. At this time, some fresheners may be included in place of water.
상기 청향제로는 편백, 아로마, 로즈, 알데하이딕, 허브, 커피향, 쟈스민, 치자향, 바이올렛잎, 플로럴, 애플블라썸, 오리엔탈, 페브리즈, 라벤다, 그린, 민트, 라임, 신저, 워터, 머그렛, 백합, 허니듀, 제라듐, 주니퍼베리, 샌달우드, 쿠마린 및 파출리로 구성된 군으로부터 선택된 어느 하나 또는 둘 이상의 향을 나타내는 식물 추출물 또는 분획물일 수 있다.The freshening agents include cypress, aroma, rose, aldehydic, herb, coffee scent, jasmine, gardenia, violet leaf, floral, apple blossom, oriental, Febreze, lavender, green, mint, lime, sour, water, muglet. , lily, honeydew, geranium, juniper berry, sandalwood, coumarin, and patchouli may be a plant extract or fraction exhibiting one or more scents selected from the group consisting of.
또한, 본 발명은 실리콘 3 ~ 40 중량%, 특수 시멘트 15 ~ 30 중량%, 아크릴계 방수제 10 ~ 20 중량%, 연소된 재(ash) 또는 플래니탑(Planitop) 중 어느 하나 25 ~ 40 중량%, 무기질 파우더 15 ~ 25 중량% 및 물을 혼합한 후 교반하는 공정을 포함하는 건축용 방수 접착제의 제조방법을 제공한다.In addition, the present invention contains 3 to 40% by weight of silicon, 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either burned ash or Planitop, and inorganic substances. A method for manufacturing a waterproof adhesive for construction is provided, including a process of mixing 15 to 25% by weight of powder and water and then stirring.
상기 실리콘은 수성 실리콘, 수성 및 유성 겸용 실리콘, 바이오(크랙) 실리콘, 향기나는 방수 실리콘, 석탄회 방수 실리콘 및 방화용 내열 실리콘으로 구성된 군으로 부터 선택된 어느 하나일 수 있다. The silicone may be any one selected from the group consisting of water-based silicone, water-based and oil-based silicone, bio (crack) silicone, scented waterproof silicone, coal ash waterproof silicone, and heat-resistant silicone for fire prevention.
아울러, 본 발명은 상기 본 발명에 따른 방수 접착제를 타일 등 건축자재에 타설하여 부착하는 시공방법을 제공한다.In addition, the present invention provides a construction method for attaching the waterproof adhesive according to the present invention by pouring it to building materials such as tiles.
상기 시공방법은The above construction method is
콘크리트 등 건축 자재에 대해 불순물을 제거하고 청소하는 단계;Removing and cleaning impurities from building materials such as concrete;
청소된 부위에 건축 자재와 접착제 조성물의 일체화를 위해 프라이머 처리하는 단계;Primer treatment to integrate the building material and adhesive composition on the cleaned area;
프라이머 처리된 결과물에 본 발명에 따른 방수 접착제를 타설하는 단계;Pouring a waterproof adhesive according to the present invention on the primer-treated result;
타설된 건축 자재를 부착하는 단계; 및Attaching poured building materials; and
부착된 건축 자재 표면 등을 깨끗하게 세척하여 마무리 처리하는 단계;를 포함할 수 있으며, 상기 단계 중 청소, 프라이머 및 세척 단계는 일부 생략할 수 있다.It may include a step of cleansing and finishing the surface of the attached building material, etc., and some of the cleaning, primer, and washing steps may be omitted among the above steps.
이하, 본 발명을 구체적으로 설명하기 위해 실시예 및 실험예를 들어 상세히 설명하기로 한다.Hereinafter, the present invention will be described in detail using examples and experimental examples to specifically explain the present invention.
본 발명은 하기의 실시예 및 실험예에 의하여 보다 더 잘 이해 될 수 있으며, 하기의 실시예 및 실험예는 본 발명의 예시 목적을 위한 것이며, 첨부된 특허청구범위에 의하여 한정되는 보호범위를 제한하고자 하는 것은 아니다.The present invention can be better understood by the following examples and experimental examples, which are for illustrative purposes of the present invention and do not limit the scope of protection defined by the appended claims. That's not what I want to do.
<< 실시예Example 1> 방수 접착제 1의 제조 1> Preparation of waterproof adhesive 1
특수 시멘트 30g, 아크릴계 방수제 25cc, 플래니탑 30K 50g, 특수 무기질 파우더 40g, 물 25cc 및 편백추출물 10cc를 혼합한 후 교반하여 방수 접착제를 제조하였다.A waterproof adhesive was prepared by mixing 30g of special cement, 25cc of acrylic waterproofing agent, 50g of Planytop 30K, 40g of special mineral powder, 25cc of water, and 10cc of Cypress extract and stirring.
<< 실시예Example 2> 방수 접착제 2의 제조 2> Preparation of waterproof adhesive 2
특수 시멘트 30g, 아크릴계 방수제 25cc, 석탄재 50g, 특수 무기질 파우더 40g, 물 25cc 및 편백추출물 10cc를 혼합한 후 교반하여 방수 접착제를 제조하였다.A waterproof adhesive was prepared by mixing 30g of special cement, 25cc of acrylic waterproofing agent, 50g of coal ash, 40g of special mineral powder, 25cc of water, and 10cc of cypress extract and stirring.
<< 비교예Comparative example 1> 실리콘 접착제의 제조 1> Preparation of silicone adhesive
페닐메틸 실리콘 수지 10 중량%, 알콕시실릴-종결 폴리머(Geniosil® STP-E35, Wacker Chemie AG) 10 중량%, 충전제로서 모래 79.9 중량%, 수분제거제 2 중량%, 축합가교촉매 0.1 중량%를 혼합하여 실리콘 접착제를 제조하였다.Mix 10% by weight of phenylmethyl silicone resin, 10% by weight of alkoxysilyl-terminated polymer (Geniosil® STP-E35, Wacker Chemie AG), 79.9% by weight of sand as filler, 2% by weight of moisture remover, and 0.1% by weight of condensation crosslinking catalyst. A silicone adhesive was prepared.
<< 비교예Comparative example 2> 시멘트 접착제의 제조 2>Manufacture of cement adhesive
시멘트 40 중량%, 수분산 에폭시 수지 30 중량%, 규사 20 중량%, 혼화제 1 중량% 및 물 9 중량%를 혼합하여 시멘트 접착제를 제조하였다. A cement adhesive was prepared by mixing 40% by weight of cement, 30% by weight of water-dispersible epoxy resin, 20% by weight of silica sand, 1% by weight of admixture, and 9% by weight of water.
<< 실험예Experiment example 1> 물성 비교 1> Comparison of physical properties
본 발명의 실시예에 따른 접착제와 비교예들의 접착제의 물성을 비교하였다.The physical properties of the adhesive according to the examples of the present invention and the adhesives of comparative examples were compared.
1bs/in2 (MPa)compressive strength
1bs/ in2 (MPa)
1bs/in2 (MPa)ultimate tensile strength
1bs/ in2 (MPa)
1bs/in2 (MPa)flexural strength
1bs/ in2 (MPa)
<< 실험예Experiment example 2> 접착 강도 비교 2> Adhesion strength comparison
본 발명의 실시예에 따른 접착제와 비교예들의 접착제의 접착 강도를 비교하였다.The adhesive strength of the adhesive according to the example of the present invention and the adhesive of the comparative examples were compared.
(N/mm2)Tensile Adhesion Range
(N/ mm2 )
Claims (7)
여기서,
상기 특수 시멘트는 보통포틀랜드시멘트 20 ~ 80 중량%, 클링커 파우더 3 ~ 30중량%, 슬래그 미분말 2 ~ 40 중량%, 석고 미분말 0 ~ 20 중량% 및 소석회 0 ~ 5 중량%를 포함하고,
상기 아크릴계 방수제는 수용성 아크릴 수지 60 ~ 70 중량%, 수용성 아크릴-실리콘 수지 20 ~ 30 중량%, 유화제 1 ~ 3 중량%, 증점제 1 ~ 3 중량%, 실리카 0 ~ 3 중량%를 포함하며,
상기 무기질 파우더는 규사 30 ~ 40 중량%, 알루미나 시멘트 20 ~ 40 중량% 및 플라이애쉬 10 ~ 40 중량%를 포함하는 것을 특징으로 하는
건축용 방수 접착제.
Contains 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either coal ash or Planitop 30K, 15 to 25% by weight of mineral powder, cypress extract and water,
here,
The special cement includes 20 to 80% by weight of ordinary Portland cement, 3 to 30% by weight of clinker powder, 2 to 40% by weight of fine slag powder, 0 to 20% by weight of fine gypsum powder, and 0 to 5% by weight of slaked lime,
The acrylic waterproofing agent contains 60 to 70% by weight of water-soluble acrylic resin, 20 to 30% by weight of water-soluble acrylic-silicone resin, 1 to 3% by weight of emulsifier, 1 to 3% by weight of thickener, and 0 to 3% by weight of silica,
The inorganic powder is characterized in that it contains 30 to 40% by weight of silica sand, 20 to 40% by weight of alumina cement, and 10 to 40% by weight of fly ash.
Waterproof adhesive for construction.
여기서,
상기 특수 시멘트는 보통포틀랜드시멘트 20 ~ 80 중량%, 클링커 파우더 3 ~ 30중량%, 슬래그 미분말 2 ~ 40 중량%, 석고 미분말 0 ~ 20 중량% 및 소석회 0 ~ 5 중량%를 포함하고,
상기 아크릴계 방수제는 수용성 아크릴 수지 60 ~ 70 중량%, 수용성 아크릴-실리콘 수지 20 ~ 30 중량%, 유화제 1 ~ 3 중량%, 증점제 1 ~ 3 중량%, 실리카 0 ~ 3 중량%를 포함하며,
상기 무기질 파우더는 규사 30 ~ 40 중량%, 알루미나 시멘트 20 ~ 40 중량% 및 플라이애쉬 10 ~ 40 중량%를 포함하는 것을 특징으로 하는
건축용 방수 접착제의 제조방법.Mix 15 to 30% by weight of special cement, 10 to 20% by weight of acrylic waterproofing agent, 25 to 40% by weight of either coal ash or Planitop 30K, 15 to 25% by weight of mineral powder, cypress extract and water, then stir. Including the process of
here,
The special cement includes 20 to 80% by weight of ordinary Portland cement, 3 to 30% by weight of clinker powder, 2 to 40% by weight of fine slag powder, 0 to 20% by weight of fine gypsum powder, and 0 to 5% by weight of slaked lime,
The acrylic waterproofing agent contains 60 to 70% by weight of water-soluble acrylic resin, 20 to 30% by weight of water-soluble acrylic-silicone resin, 1 to 3% by weight of emulsifier, 1 to 3% by weight of thickener, and 0 to 3% by weight of silica,
The inorganic powder is characterized in that it contains 30 to 40% by weight of silica sand, 20 to 40% by weight of alumina cement, and 10 to 40% by weight of fly ash.
Manufacturing method of waterproof adhesive for construction.
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| KR101964008B1 (en) | 2018-08-21 | 2019-04-01 | 주식회사 쌍곰켐 | Superior acrylic emulsion adhesive composition is freeze and thawing for tile adhesive |
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| KR100602775B1 (en) * | 2005-10-24 | 2006-07-20 | 범미건설화학 주식회사 | Method of indoor wet-waterproofing construction |
| JP2009079184A (en) * | 2007-09-27 | 2009-04-16 | Toagosei Co Ltd | Waterproofing material composition |
| KR101099074B1 (en) * | 2011-07-04 | 2011-12-27 | 주식회사 제트콘코리아 | Concrete constitution |
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