KR102450685B1 - Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same - Google Patents

Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same Download PDF

Info

Publication number
KR102450685B1
KR102450685B1 KR1020200108066A KR20200108066A KR102450685B1 KR 102450685 B1 KR102450685 B1 KR 102450685B1 KR 1020200108066 A KR1020200108066 A KR 1020200108066A KR 20200108066 A KR20200108066 A KR 20200108066A KR 102450685 B1 KR102450685 B1 KR 102450685B1
Authority
KR
South Korea
Prior art keywords
cement
weight
parts
oxide
present
Prior art date
Application number
KR1020200108066A
Other languages
Korean (ko)
Other versions
KR20220027369A (en
Inventor
신홍철
Original Assignee
(주)인덱스글로벌
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by (주)인덱스글로벌 filed Critical (주)인덱스글로벌
Priority to KR1020200108066A priority Critical patent/KR102450685B1/en
Publication of KR20220027369A publication Critical patent/KR20220027369A/en
Application granted granted Critical
Publication of KR102450685B1 publication Critical patent/KR102450685B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • C04B14/18Perlite
    • C04B14/185Perlite expanded
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • C04B18/141Slags
    • C04B18/144Slags from the production of specific metals other than iron or of specific alloys, e.g. ferrochrome slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0076Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2611Polyalkenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4598Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with waste materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4857Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B41/4861Polyalkenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5029Magnesia
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5079Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5083Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5085Calcium sulfate cements
    • C04B41/5087Anhydrite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00551Refractory coatings, e.g. for tamping
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

본 발명은 단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재에 관한 것으로서, 기존 시멘트계 바탕조정재 보다 열전도성이 낮은 단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재에 관한 것이다.The present invention relates to a cement-based background conditioning material composition for an insulating material and a cement-based background conditioning material for an insulating material comprising the same, and to a cement-based background conditioning material composition for an insulating material having lower thermal conductivity than an existing cement-based background conditioning material, and a cement-based background conditioning material for an insulating material comprising the same.

Description

단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재{Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same}Cement-based base adjusting material composition for heat insulating material and cement-based base adjusting material for heat insulating material comprising the same

본 발명은 단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재에 관한 것으로서, 기존 시멘트계 바탕조정재 보다 열전도성이 낮은 단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재에 관한 것이다.The present invention relates to a cement-based background conditioning material composition for an insulating material and a cement-based background conditioning material for an insulating material comprising the same, and to a cement-based background conditioning material composition for an insulating material having lower thermal conductivity than an existing cement-based background conditioning material, and a cement-based background conditioning material for an insulating material comprising the same.

일반적으로 습식 외단열 공법에서는 건물 외피를 둘러싼 단열재의 상부에 시멘트계 바탕조정재를 시공한 뒤 얇은 마감재를 상부에 미장하는 방식으로 마감 시공한다. In general, in the wet exterior insulation method, a cement-based base adjustment material is installed on the top of the insulation surrounding the building envelope, and then a thin finishing material is plastered on the top.

기존 시멘트계 바탕조정재는 무기물인 시멘트 성분의 함량이 높아 외부 기온이 상승함에 따라 표면의 온도가 상승하고, 열에너지가 누적되면서 구조물의 온도 상승을 유발하게 된다. 따라서, 구조물의 열적 성능을 개선하기 위한 시멘트계 바탕조정재가 요구되고 있다. Existing cement-based base conditioning materials have a high content of inorganic cement components, so the surface temperature rises as the external temperature rises, and thermal energy accumulates, causing the temperature of the structure to rise. Therefore, there is a demand for a cement-based base control material for improving the thermal performance of the structure.

한편, 제철 산업 부산물 중 페로니켈 슬래그는 마그네슘 함량이 약 24 ~ 40% 가량을 함유하고 있는 물질로서 텅스텐 제조 공정에서 발생되고 있다. 매년 약 10만톤 가량의 산업부산물이 발생되면서, 누적 산업부산물은 해마다 증가하는 추세에 있어 이의 처리 방안에 대한 연구가 절실한 상황이다. 페로니켈슬래그는 높은 마그네슘 함량으로 인해 열확산성이 크고, 열전도율이 낮은 특성을 지니고 있음에 따라 구조물의 표면에 누적되는 열량을 제어할 수 있는 소재로 기대될 수 있는 장점이 있다. On the other hand, ferronickel slag among the by-products of the ironmaking industry is a material containing about 24 to 40% of magnesium and is generated in the tungsten manufacturing process. As about 100,000 tons of industrial by-products are generated every year, the accumulated industrial by-products are increasing year by year, so research on treatment methods is urgently needed. Since ferronickel slag has high thermal diffusivity and low thermal conductivity due to its high magnesium content, it has the advantage that it can be expected as a material that can control the amount of heat accumulated on the surface of the structure.

국내 천연규사는 해사와 규석 광산에서 채취하는 인공 규사로 구분되어 생산되고 있다. 현재 규사 자원 중 순도가 높은 규석의 경우, 폴리실리콘의 원료와 같이 전자산업 소재로 주로 사용되고 있으며, 이외의 인공 규사는 특수 모르타르의 골재로 사용되고 있다. 인공 규사는 임야를 채굴하여 규석을 추출하는 공정을 거치게 됨에 따라 환경 파괴와 부산물로 발생되는 여러 문제점을 수반하고 있어 천연 규사의 사용량을 증가시키는 것이 중요한 시점이다. In Korea, natural silica sand is produced separately from sea sand and artificial silica sand collected from silicate mines. Currently, among the silica sand resources, high-purity silica is mainly used as a material for the electronics industry, such as a raw material for polysilicon, and artificial silica sand is used as an aggregate for special mortars. As artificial silica sand goes through the process of extracting silica by mining forest fields, it is accompanied by environmental destruction and various problems that occur as by-products, so it is important to increase the amount of natural silica sand used.

대한민국 공개번호 10-2000-0017876호(2002.11.23)Republic of Korea Publication No. 10-2000-0017876 (December 23, 2002)

본 발명은 기존 시멘트계 바탕조정재 보다 산업부산물의 사용을 증진하여 천연규사의 사용량을 저감하고, 열환경성을 향상할 수 있는 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재를 제공하고자 한다.The present invention is to promote the use of industrial by-products compared to the existing cement-based background conditioning material, thereby reducing the amount of natural silica sand used, and to provide a cement-based background conditioning material composition capable of improving thermal environmental properties and a cement-based background conditioning material for insulation including the same.

상술한 과제를 해결하기 위하여, 본 발명은 단열재용 시멘트계 바탕조정재 조성물에 관한 것으로서, 시멘트, 페로니켈 슬래그(ferronikel slag), 산화마그네슘, 골재 및 팽창 펄라이트(expanded perlite)를 포함한다.In order to solve the above problems, the present invention relates to a cement-based background adjusting material composition for an insulating material, and includes cement, ferronikel slag, magnesium oxide, aggregate and expanded perlite.

본 발명의 바람직한 일실시예에 있어서, 본 발명의 바탕조정재 조성물은 폴리올레핀 분말수지를 더 포함할 수 있다.In a preferred embodiment of the present invention, the background adjusting material composition of the present invention may further include a polyolefin powder resin.

본 발명의 바람직한 일실시예에 있어서, 본 발명의 바탕조정재 조성물은 시멘트 100 중량부에 대하여, 페로니켈 슬래그 20 ~ 40 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the ground conditioning material composition of the present invention may contain 20 to 40 parts by weight of ferronickel slag based on 100 parts by weight of cement.

본 발명의 바람직한 일실시예에 있어서, 본 발명의 바탕조정재 조성물은 시멘트 100 중량부에 대하여, 산화마그네슘 2.0 ~ 4.0 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the background adjusting material composition of the present invention may contain 2.0 to 4.0 parts by weight of magnesium oxide based on 100 parts by weight of cement.

본 발명의 바람직한 일실시예에 있어서, 본 발명의 바탕조정재 조성물은 시멘트 100 중량부에 대하여, 팽창 펄라이트 2.0 ~ 4.0 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the background adjusting material composition of the present invention may contain 2.0 to 4.0 parts by weight of expanded perlite based on 100 parts by weight of cement.

본 발명의 바람직한 일실시예에 있어서, 본 발명의 바탕조정재 조성물은 시멘트 100 중량부에 대하여, 골재 253 ~ 472 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the background adjusting material composition of the present invention may contain 253 to 472 parts by weight of aggregate based on 100 parts by weight of cement.

본 발명의 바람직한 일실시예에 있어서, 본 발명의 바탕조정재 조성물은 시멘트 100 중량부에 대하여, 폴리올레핀 분말수지 2.0 ~ 4.0 중량부를 포함할 수 있다.In a preferred embodiment of the present invention, the ground conditioning material composition of the present invention may contain 2.0 to 4.0 parts by weight of the polyolefin powder resin based on 100 parts by weight of the cement.

본 발명의 바람직한 일실시예에 있어서, 페로니켈 슬래그는 이산화규소(SiO2), 산화마그네슘(MgO), 토탈-철(T-Fe), 산화알루미늄(Al2O3) 및 산화칼슘(CaO)을 포함할 수 있다.In a preferred embodiment of the present invention, the ferronickel slag is silicon dioxide (SiO 2 ), magnesium oxide (MgO), total-iron (T-Fe), aluminum oxide (Al 2 O 3 ) and calcium oxide (CaO) may include

본 발명의 바람직한 일실시예에 있어서, 페로니켈 슬래그는 입도가 0.15 ~ 0.6mm일 수 있다.In a preferred embodiment of the present invention, the ferronickel slag may have a particle size of 0.15 to 0.6 mm.

본 발명의 바람직한 일실시예에 있어서, 팽창 펄라이트는 이산화규소(SiO2), 산화알루미늄(Al2O3), 산화철(Fe2O3), 산화칼슘(CaO), 산화마그네슘(MgO), 산화칼륨(K2O) 및 산화나트륨(Na2O)을 포함할 수 있다.In a preferred embodiment of the present invention, expanded pearlite is silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), iron oxide (Fe 2 O 3 ), calcium oxide (CaO), magnesium oxide (MgO), oxide potassium (K 2 O) and sodium oxide (Na 2 O).

본 발명의 바람직한 일실시예에 있어서, 팽창 펄라이트는 입도가 0.15 ~ 0.6mm일 수 있다.In a preferred embodiment of the present invention, the expanded pearlite may have a particle size of 0.15 to 0.6 mm.

본 발명의 바람직한 일실시예에 있어서, 시멘트는 석고 시멘트, 고로 슬래그 시멘트 및 포틀랜드 시멘트 중에서 선택된 1종 이상을 포함할 수 있다.In a preferred embodiment of the present invention, the cement may include at least one selected from gypsum cement, blast furnace slag cement, and Portland cement.

본 발명의 바람직한 일실시예에 있어서, 골재는 평균입경이 0.15mm ~ 0.6mm인 규사를 포함할 수 있다.In a preferred embodiment of the present invention, the aggregate may include silica sand having an average particle diameter of 0.15 mm to 0.6 mm.

본 발명의 바람직한 일실시예에 있어서, 폴리올레핀 분말수지는 에틸렌초산비닐(ethylene vinyl acetate, EVA) 분말수지 및 저밀도폴리에틸렌(low density polyethylene, LDPE) 분말수지 중에서 선택된 1종 이상을 포함할 수 있다.In a preferred embodiment of the present invention, the polyolefin powder resin may include at least one selected from ethylene vinyl acetate (EVA) powder resin and low density polyethylene (LDPE) powder resin.

한편, 본 발명은 단열재용 시멘트계 바탕조정재에 관한 것으로서, 앞서 언급한 단열재용 시멘트계 바탕조정재 조성물을 포함한다.On the other hand, the present invention relates to a cement-based background adjusting material for a heat insulator, and includes the above-mentioned cement-based base adjusting material composition for an insulator.

본 발명의 단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재는 페로니켈 슬래그를 주요 골재로 사용함에 따라 원가를 절감할 수 있으며, 마그네슘 함량이 높은 페로니켈 슬래그의 효과로 인해 건축물의 표면부의 집중되는 열에너지를 제어하여 냉방부하를 억제할 수 있다.The cement-based background conditioning material composition for an insulating material of the present invention and the cement-based background conditioning material for an insulating material comprising the same can reduce costs by using ferronickel slag as a main aggregate, and the surface of buildings due to the effect of ferronickel slag with a high magnesium content It is possible to suppress the cooling load by controlling the concentrated thermal energy of negative.

또한, 본 발명의 단열재용 시멘트계 바탕조정재 조성물 및 이를 포함하는 단열재용 시멘트계 바탕조정재는 부착강도 및 온냉반복강도가 우수할 뿐만 아니라, 물흡수계수가 낮고, 열환경성 평가에 있어서도 우수한 결과를 보인다.In addition, the cement-based background conditioning material composition for an insulation material of the present invention and the cement-based background adjustment material for insulation material comprising the same are excellent in adhesion strength and heat and cold repetition strength, as well as a low water absorption coefficient, and excellent results in thermal environmental evaluation.

이하, 본 발명은 더욱 상세히 설명한다.Hereinafter, the present invention will be described in more detail.

본 발명의 단열재용 시멘트계 바탕조정재 조성물은 시멘트, 페로니켈 슬래그(ferronikel slag), 산화마그네슘, 골재 및 팽창 펄라이트(expanded perlite)를 포함한다.The cement-based background adjusting material composition for an insulating material of the present invention includes cement, ferronikel slag, magnesium oxide, aggregate and expanded perlite.

먼저, 본 발명의 시멘트는 특별히 한정하지는 않으나, 석회 시멘트, 고로질 석회 시멘트, 석고 시멘트, 마그네시아 시멘트, 포틀랜드(portland) 시멘트, 고로 슬래그 시멘트, 플라이 애시 시멘트 및 포틀랜드 포졸란 시멘트 중에서 선택된 1종 이상을 포함할 수 있고, 바람직하게는 석고 시멘트, 고로 슬래그 시멘트 및 포틀랜드(portland) 시멘트 중에서 선택된 1종 이상을 포함할 수 있다.First, the cement of the present invention is not particularly limited, but includes at least one selected from lime cement, blast furnace lime cement, gypsum cement, magnesia cement, Portland cement, blast furnace slag cement, fly ash cement, and Portland pozzolan cement. and preferably, may include at least one selected from gypsum cement, blast furnace slag cement, and portland cement.

포틀랜드 시멘트(KS L 5201)는 주성분으로서 실리카, 알루미늄, 산화철 및 석회를 포함한 원료를 적당한 비율로 혼합하고, 이 혼합물을 소성하여 얻은 클링커에 적량의 석고를 가하여 분말화 한 것이다. 포틀랜드 시멘트의 종류는 1종 보통 포틀랜드 시멘트, 2종 중용열 포틀랜드 시멘트, 3종 조강 포틀랜드 시멘트, 4종 저열 포틀랜드 시멘트, 5종 내황산염 포틀랜드 시멘트로 나누어지며, 본 발명에서는 용도에 따라 각 종류의 포틀랜드 시멘트를 모두 적용할 수 있다. Portland cement (KS L 5201) is powdered by mixing raw materials including silica, aluminum, iron oxide and lime in an appropriate ratio as main components, and adding an appropriate amount of gypsum to clinker obtained by calcining this mixture. Types of Portland cement are divided into type 1 normal Portland cement, type 2 medium heat portland cement, type 3 crude steel portland cement, type 4 low heat Portland cement, and type 5 sulfate-resistant Portland cement, and in the present invention, each type of Portland cement is All cement can be applied.

고로 슬래그 시멘트(KS L 5210)는 포틀랜드 시멘트에 혼합재로서 제철공장의 부산물인 고로 슬래그를 첨가한 시멘트로서 후기강도가 높고, 수화열이 적으며, 화학적 저항성, 내열성이 좋다.Blast furnace slag cement (KS L 5210) is a cement in which blast furnace slag, a by-product of a steel mill, is added as a mixture to Portland cement. It has high late strength, low heat of hydration, and good chemical resistance and heat resistance.

플라이 애시 시멘트(KS L 5211)는 포틀랜드 시멘트에 혼합재로 화력발전소의 석탄 연소재(灰)를 첨가한 시멘트로서, 선택 연소재는 구형으로 볼 베어링(ball bearing)효과에 의하여 워커 빌리티의 증대 및 단위 수량을 감소시킨다.Fly ash cement (KS L 5211) is a cement obtained by adding coal combustion ash from a thermal power plant as a mixture to Portland cement. reduce the quantity.

포틀랜드 포졸란 시멘트(실리카 시멘트)(KS L 5401)는 포틀랜드 시멘트에 혼합재로 포졸란(pozzolan)을 첨가한 시멘트로서, 황산염에 강하고 수밀성 및 내열성이 좋다. 상기 포졸란(pozzolan)은 화산회, 화산암의 풍화물로 규산, 백토, 의회암의 풍화물 등을 포함한다.Portland pozzolan cement (silica cement) (KS L 5401) is a cement in which pozzolan is added as an admixture to Portland cement. It is strong against sulfate and has good watertightness and heat resistance. The pozzolan is volcanic ash, a weathered product of volcanic rock, and includes silicic acid, white clay, and a weathered product of limestone.

또한, 본 발명의 시멘트로서 분말도가 3,000 ~ 4,600cm3/g, 바람직하게는 3,400 ~ 4,200cm3/g인 것을 사용할 수 있다.In addition, as the cement of the present invention, a fineness of 3,000 to 4,600 cm 3 /g, preferably 3,400 to 4,200 cm 3 /g, may be used.

다음으로, 본 발명의 페로니켈 슬래그(ferronikel slag)는 페로니켈 제조 공정 중에 발생되는 부산물이다. 페로니켈 제조 공정은 1890년대부터 프랑스의 SLN사에 의해 개발되어 일본, 콜롬비아 등에서 채택하여 가동중인 건식 제조 공법으로서 전기로에서 광석을 용융, 환원하여 페로니켈을 제조하는 방식이다. 주요 공정 과정에서 약 20%의 니켈과 80% 정도의 철이 함유된 페로니켈을 생산한다. 페로니켈 슬래그는 보통 페로니켈 1톤 생산시 약 6톤의 슬래그가 발생하는 것으로 알려져 있으며, 페로니켈 슬래그는 년간 100만톤 정도 발생되고 화학적으로 안정하기 때문에 채움재 및 콘크리트 골재로서의 활용가능성이 상당히 높다. 바탕조정재로서 본 발명의 페로니켈 슬래그를 포함하는 경우, 페로니켈 슬래그 내의 높은 마그네슘 함량으로 인해 건축물 외피에 존재하는 열량을 외부로 쉽게 확산시켜 줌으로 인해 열의 집중을 저감시킬 수 있는 장점이 있다. 또한, 본 발명의 페로니켈 슬래그(ferronikel slag)는 제철소에서 텅스텐 생산 과정 중에 부산물을 서냉하여 적정 입도로 분쇄 및 분리한 것일 수 있다.Next, the ferronickel slag of the present invention is a by-product generated during the ferronickel manufacturing process. The ferronickel manufacturing process is a dry manufacturing method developed by SLN of France from the 1890s and adopted and operated in Japan and Colombia. It is a method of manufacturing ferronickel by melting and reducing ore in an electric furnace. In the main process, ferronickel containing about 20% nickel and about 80% iron is produced. It is known that ferronickel slag generates about 6 tons of slag when producing 1 ton of ferronickel, and ferronickel slag is generated about 1 million tons per year and is chemically stable, so its potential to be used as a filler and concrete aggregate is quite high. When the ferronickel slag of the present invention is included as a ground control material, there is an advantage in that the concentration of heat can be reduced by easily diffusing the amount of heat present in the building envelope to the outside due to the high magnesium content in the ferronickel slag. In addition, the ferronikel slag of the present invention may be one obtained by slowly cooling a by-product during a tungsten production process in an ironworks and pulverizing and separating it to an appropriate particle size.

본 발명의 페로니켈 슬래그(ferronikel slag)는 이산화규소(SiO2), 산화마그네슘(MgO), 토탈-철(T-Fe), 산화알루미늄(Al2O3) 및 산화칼슘(CaO)을 포함할 수 있고, 기타 성분들을 더 포함할 수 있다. 구체적으로, 본 발명의 페로니켈 슬래그(ferronikel slag)는 전체 중량%에 대하여 이산화규소(SiO2) 40 ~ 50 중량%, 바람직하게는 43 ~ 47 중량%, 산화마그네슘(MgO) 30 ~ 40 중량%, 바람직하게는 36 ~ 40 중량%, 토탈-철(T-Fe) 2.5 ~ 6.5 중량%, 바람직하게는 3.5 ~ 5.5 중량%, 산화알루미늄(Al2O3) 0.45 ~ 2.45 중량%, 바람직하게는 0.95 ~ 1.95 중량%, 산화칼슘(CaO) 0.15 ~ 1.15 중량%, 바람직하게는 0.35 ~ 0.95 중량%를 포함할 수 있다.The ferronikel slag of the present invention may include silicon dioxide (SiO 2 ), magnesium oxide (MgO), total-iron (T-Fe), aluminum oxide (Al 2 O 3 ) and calcium oxide (CaO). and may further include other ingredients. Specifically, the ferronickel slag of the present invention is silicon dioxide (SiO 2 ) 40-50 wt%, preferably 43-47 wt%, magnesium oxide (MgO) 30-40 wt% with respect to the total weight% , preferably 36 to 40 wt%, total-iron (T-Fe) 2.5 to 6.5 wt%, preferably 3.5 to 5.5 wt%, aluminum oxide (Al 2 O 3 ) 0.45 to 2.45 wt%, preferably 0.95 to 1.95 wt%, calcium oxide (CaO) 0.15 to 1.15 wt%, preferably 0.35 to 0.95 wt%.

또한, 본 발명의 페로니켈 슬래그는 입도가 0.15 ~ 0.6mm, 바람직하게는 입도가 입도가 0.15 ~ 0.3mm일 수 있으며, 만일 입도가 0.15mm 미만이면 비표면적의 증가로 인해 유동성이 감소되어 작업성의 문제가 있을 수 있고, 0.6mm를 초과하면 미장 공정 중에 표면의 두께가 증가되는 문제가 있을 수 있다.In addition, the ferronickel slag of the present invention may have a particle size of 0.15 to 0.6 mm, preferably a particle size of 0.15 to 0.3 mm. There may be a problem, and if it exceeds 0.6 mm, there may be a problem in that the thickness of the surface increases during the plastering process.

또한, 본 발명의 페로니켈 슬래그는 시멘트 100 중량부에 대하여, 20 ~ 40 중량부, 바람직하게는 25 ~ 35 중량부를 포함할 수 있으며, 만일 페로니켈 슬래그를 20 중량부 미만으로 포함한다면 열환경성의 향상을 기대할 수 없는 문제가 있을 수 있고, 40 중량부를 초과하면 시공 후 모르타르의 하부 침하가 발생하여 표면에서 탈락할 수 있는 문제가 있을 수 있다.In addition, the ferronickel slag of the present invention may contain 20 to 40 parts by weight, preferably 25 to 35 parts by weight, based on 100 parts by weight of cement. There may be a problem that cannot be expected to improve, and if it exceeds 40 parts by weight, there may be a problem in that the lower settlement of the mortar occurs after construction and may be detached from the surface.

다음으로, 본 발명의 산화마그네슘은 수분 방출에 의한 표면부의 열방출을 억제할 수 있는 성분으로서, 순도가 90% 이상이 백색 분말을 사용할 수 있다. 또한, 본 발명의 산화마그네슘은 분말도가 4000g/cm3 이상, 바람직하게는 4000 ~ 10,000g/cm3 인 것일 수 있다.Next, the magnesium oxide of the present invention is a component capable of suppressing the heat release of the surface part due to the release of moisture, and a white powder having a purity of 90% or more may be used. In addition, the magnesium oxide of the present invention may have a fineness of 4000 g/cm 3 or more, preferably 4000 ~ 10,000 g/cm 3 .

또한, 본 발명의 산화마그네슘은 시멘트 100 중량부에 대하여, 2.0 ~ 4.0 중량부, 바람직하게는 2.5 ~ 3.5 중량부를 포함할 수 있으며, 만일 산화마그네슘을 2.0 중량부 미만으로 포함한다면 부착강도 및 온냉반복강도가 저하될 뿐만 아니라, 물흡수계수가 KS F 4716의 표준 규격을 초과하는 문제가 있을 수 있고, 4.0 중량부를 초과하면 부착강도 및 온냉반복강도가 저하되는 문제가 있을 수 있다.In addition, the magnesium oxide of the present invention may contain 2.0 to 4.0 parts by weight, preferably 2.5 to 3.5 parts by weight, based on 100 parts by weight of cement. In addition to the decrease in strength, there may be a problem that the water absorption coefficient exceeds the standard specification of KS F 4716, and if it exceeds 4.0 parts by weight, there may be a problem in that the adhesion strength and the strength in repeated heating and cooling are reduced.

다음으로, 본 발명의 골재는 하천, 산림, 공유수면, 기타 지상, 지하 등에 부존되어 있는 쇄석용 암석, 모래, 자갈, 슬래그를 포함하며, 골재의 평균입경에 따라 5mm 이상인 조골재(粗骨材), 5mm 이하의 세골재(洗骨材)로 나눌 수 있는데, 본 발명의 골재는 평균입경이 0.15mm ~ 0.6mm, 바람직하게는 0.15mm ~ 0.3mm인 골재를 포함하여 사용할 수 있으며, 바람직하게는 평균입경이 0.15mm ~ 0.6mm, 바람직하게는 0.15mm ~ 0.3mm인 규사가 사용될 수 있다. 만일, 골재의 평균입경이 0.15mm 미만이면 유동성 저하로 인한 작업성의 문제가 있을 수 있고, 0.6mm를 초과하면 표면부의 미장시 문제가 있을 수 있다.Next, the aggregate of the present invention includes crushed stone, sand, gravel, and slag, which are present in rivers, forests, public waters, other ground, underground, etc., and coarse aggregate of 5 mm or more according to the average particle diameter of the aggregate. , can be divided into fine aggregates of 5 mm or less, the aggregate of the present invention can be used including aggregates having an average particle diameter of 0.15 mm to 0.6 mm, preferably 0.15 mm to 0.3 mm, preferably average Silica sand having a particle diameter of 0.15 mm to 0.6 mm, preferably 0.15 mm to 0.3 mm may be used. If the average particle diameter of the aggregate is less than 0.15mm, there may be a problem in workability due to reduced fluidity, and if it exceeds 0.6mm, there may be a problem during plastering of the surface.

또한, 본 발명의 골재는 시멘트 100 중량부에 대하여, 253 ~ 472 중량부, 바람직하게는 290 ~ 435 중량부, 더욱 바람직하게는 326 ~ 400 중량부를 포함할 수 있으며, 만일 골재를 253 중량부 미만으로 포함한다면 경재성의 문제가 있을 수 있고, 472 중량부를 초과하면 부착강도와 내수성이 저하되는 문제가 있을 수 있다.In addition, the aggregate of the present invention may contain 253 to 472 parts by weight, preferably 290 to 435 parts by weight, more preferably 326 to 400 parts by weight, based on 100 parts by weight of cement, and if less than 253 parts by weight of the aggregate If it is included, there may be a problem of hardwood, and if it exceeds 472 parts by weight, there may be a problem of lowering the adhesion strength and water resistance.

다음으로, 본 발명의 팽창 펄라이트(expanded perlite)는 진주암을 약 1400도의 온도에서 소성하여 내부 발포를 통해 생산되는 인공 경량 골재의 일종으로 비중은 약 0.2인 경량 소재이다. Next, expanded perlite of the present invention is a kind of artificial lightweight aggregate produced through internal foaming by calcining perlite at a temperature of about 1400 degrees, and is a lightweight material having a specific gravity of about 0.2.

본 발명의 팽창 펄라이트는 이산화규소(SiO2), 산화알루미늄(Al2O3), 산화철(Fe2O3), 산화칼슘(CaO), 산화마그네슘(MgO), 산화칼륨(K2O) 및 산화나트륨(Na2O)을 포함할 수 있고, 기타 성분들을 더 포함할 수 있다. 구체적으로, 본 발명의 팽창 펄라이트는 전체 중량%에 대하여 이산화규소(SiO2) 65.5 ~ 85.5 중량%, 바람직하게는 70.5 ~ 80.5 중량%, 산화마그네슘(MgO) 5.3 ~ 25.3 중량%, 바람직하게는 10.3 ~ 20.3 중량%, 산화철(Fe2O3) 0.1 ~ 1.7 중량%, 바람직하게는 0.5 ~ 1.4 중량%, 산화칼슘(CaO) 0.07 ~ 0.17 중량%, 바람직하게는 0.1 ~ 0.14 중량%, 산화마그네슘(MgO) 0.01 ~ 0.15 중량%, 바람직하게는 0.05 ~ 0.13 중량%, 산화칼륨(K2O) 2.0 ~ 6.0 중량%, 바람직하게는 3.0 ~ 5.0 중량%, 산화나트륨(Na2O) 1.5 ~ 5.5 중량%, 바람직하게는 2.5 ~ 4.5 중량%를 포함할 수 있다.The expanded pearlite of the present invention is silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), iron oxide (Fe 2 O 3 ), calcium oxide (CaO), magnesium oxide (MgO), potassium oxide (K 2 O) and It may include sodium oxide (Na 2 O), and may further include other components. Specifically, the expanded pearlite of the present invention is silicon dioxide (SiO 2 ) 65.5 to 85.5 wt%, preferably 70.5 to 80.5 wt%, magnesium oxide (MgO) 5.3 to 25.3 wt%, preferably 10.3 based on the total weight% ~ 20.3% by weight, iron oxide (Fe 2 O 3 ) 0.1 to 1.7% by weight, preferably 0.5 to 1.4% by weight, calcium oxide (CaO) 0.07 to 0.17% by weight, preferably 0.1 to 0.14% by weight, magnesium oxide ( MgO) 0.01 to 0.15 wt%, preferably 0.05 to 0.13 wt%, potassium oxide (K 2 O) 2.0 to 6.0 wt%, preferably 3.0 to 5.0 wt%, sodium oxide (Na 2 O) 1.5 to 5.5 wt% %, preferably 2.5 to 4.5 wt%.

또한, 본 발명의 팽창 펄라이트는 입도가 0.15 ~ 0.6mm, 바람직하게는 입도가 입도가 0.15 ~ 0.3mm일 수 있으며, 만일 입도가 0.15mm 미만이면 작업성 저하의 문제가 있을 수 있고, 0.6mm를 초과하면 흡수율이 높은 펄라이트가 주변의 수분을 흡수함에 따라 얇게 도포된 시멘트계 바탕조정재의 불균질한 매트릭스를 구성하게 하는 문제가 있을 수 있다.In addition, the expanded pearlite of the present invention may have a particle size of 0.15 to 0.6 mm, preferably a particle size of 0.15 to 0.3 mm, and if the particle size is less than 0.15 mm, there may be a problem of deterioration of workability, and 0.6 mm If it is exceeded, there may be a problem of constituting an inhomogeneous matrix of thinly applied cement-based background control material as perlite, which has a high absorption rate, absorbs surrounding moisture.

또한, 본 발명의 팽창 펄라이트는 시멘트 100 중량부에 대하여 2.0 ~ 4.0 중량부, 바람직하게는 2.5 ~ 3.5 중량부를 포함할 수 있으며, 만일 팽창 펄라이트를 2.0 중량부 미만으로 포함한다면 페로니켈 슬래그로 증가된 모르타르의 중량을 인해 발생되는 침하를 억제할 수 없는 문제가 있을 수 있고, 4.0 중량부를 초과하면 팽창 펄라이트의 내부 다공질로 인한 낮은 인장강도 및 높은 흡수율로 인하여 부착강도가 저하될 뿐만 아니라, 물흡수계수가 KS F 4716의 표준 규격을 초과하는 문제가 있을 수 있다.In addition, the expanded perlite of the present invention may contain 2.0 to 4.0 parts by weight, preferably 2.5 to 3.5 parts by weight, based on 100 parts by weight of cement. There may be a problem that the settlement cannot be suppressed due to the weight of the mortar, and when it exceeds 4.0 parts by weight, the adhesion strength is lowered due to the low tensile strength and high water absorption due to the internal porosity of the expanded pearlite, and the water absorption coefficient There may be a problem that exceeds the standard specification of KS F 4716.

한편, 본 발명의 단열재용 시멘트계 바탕조정재 조성물은 폴리올레핀 분말수지를 더 포함할 수 있다.On the other hand, the cement-based background adjusting material composition for insulation of the present invention may further include a polyolefin powder resin.

본 발명의 폴리올레핀 분말수지는 에틸렌초산비닐(elthylene vinyl acetate, EVA) 분말수지, 저밀도 폴리에틸렌(low density polyethylene, LDPE) 분말수지, 초저밀도 폴리에틸렌(very low density polyethylene) 분말수지 및 고 초산비닐(high vinyl acetate resin) 분말수지 중에서 선택된 1종 이상을 포함할 수 있으며, 바람직하게는 에틸렌초산비닐(elthylene vinyl acetate, EVA) 분말수지를 포함할 수 있다.The polyolefin powder resin of the present invention is an ethylene vinyl acetate (EVA) powder resin, a low density polyethylene (LDPE) powder resin, a very low density polyethylene powder resin, and a high vinyl acetate (high vinyl) resin. Acetate resin) may include one or more selected from among powdered resins, preferably ethylene vinyl acetate (EVA) powdered resin.

또한, 본 발명의 폴리올레핀 분말수지는 시멘트 100 중량부에 대하여, 2.0 ~ 4.0 중량부, 바람직하게는 1.8 ~ 2.2 중량부, 더욱 바람직하게는 1.9 ~ 2.1 중량부를 포함할 수 있으며, 만일 폴리올레핀 분말수지를 2.0 중량부 미만으로 포함한다면 내수성 및 부착강도의 저하의 문제가 있을 수 있고, 4.0 중량부를 초과하면 경제성의 문제가 있을 수 있다.In addition, the polyolefin powder resin of the present invention may contain 2.0 to 4.0 parts by weight, preferably 1.8 to 2.2 parts by weight, more preferably 1.9 to 2.1 parts by weight, based on 100 parts by weight of cement, and if the polyolefin powder resin If it contains less than 2.0 parts by weight, there may be a problem of a decrease in water resistance and adhesion strength, and if it exceeds 4.0 parts by weight, there may be a problem of economic feasibility.

또한, 본 발명의 단열재용 시멘트계 바탕조정재 조성물은 증점제를 더 포함할 수 있다.In addition, the cement-based background adjusting material composition for insulation of the present invention may further include a thickener.

본 발명의 증점제는 점성을 시공상황에 맞게 조절해주고, 수분의 급격한 증발을 막고 일정하게 유지하는 보습작용을 할 수 있다.The thickener of the present invention can have a moisturizing effect by adjusting the viscosity according to the construction situation, preventing rapid evaporation of moisture and maintaining it constant.

본 발명의 증점제는 메틸셀룰로오즈(methyl cellulose), 에틸셀룰로오즈(ethyl cellulose) 및 폴리사카라이드(polysaccharide)계 증점제 중에서 선택된 1종 이상을 포함할 수 있고, 바람직하게는 메틸셀룰로오즈가 포함될 수 있다.The thickener of the present invention may include one or more selected from methyl cellulose, ethyl cellulose, and polysaccharide-based thickeners, preferably methyl cellulose.

또한, 본 발명의 단열재용 시멘트계 바탕조정재 조성물은 물을 더 포함할 수 있고, 바람직하게는 시멘트 100 중량부에 대하여, 50 ~ 250 중량부, 더욱 바람직하게는 100 ~ 200 중량부를 포함할 수 있지만 이에 한정되지는 않는다.In addition, the cement-based background adjusting material composition for an insulating material of the present invention may further include water, preferably, based on 100 parts by weight of cement, 50 to 250 parts by weight, more preferably 100 to 200 parts by weight, but not limited

나아가, 본 발명의 단열재용 시멘트계 바탕조정재는 앞서 설명한 단열재용 시멘트계 바탕조정재 조성물을 포함한다.Furthermore, the cement-based background adjusting material for heat insulators of the present invention includes the above-described cement-based base adjusting material composition for heat insulators.

본 발명의 단열재용 시멘트계 바탕조정재는 화재 대응형으로서, 외단열용으로 사용될 수 있다.The cement-based base control material for insulation of the present invention is a fire-response type, and can be used for external insulation.

본 발명의 단열재용 시멘트계 바탕조정재는 KS F 4716규정에 의해 측정시, 1.2 ~ 2.5 N/㎟, 바림직하게는 1.8 ~ 2.2 N/㎟의 부착강도를 가질 수 있다.The cement-based base adjuster for insulation of the present invention may have an adhesive strength of 1.2 to 2.5 N/mm2, preferably 1.8 to 2.2 N/mm2, as measured by KS F 4716 regulations.

또한, 본 발명의 단열재용 시멘트계 바탕조정재는 KS F 4716 규정에 의해 측정시, 0.2 kg/m2h0.5이하, 바람직하게는 0.08 ~ 0.15 kg/m2h0.5, 더욱 바람직하게는 0.1 ~ 0.13 kg/m2h0.5의 물흡수계수를 가질 수 있다.In addition, the cement-based base adjuster for insulation of the present invention is 0.2 kg/m 2 h 0.5 or less, preferably 0.08 to 0.15 kg/m 2 h 0.5 , more preferably 0.1 to 0.13 kg, when measured according to KS F 4716 regulations. It can have a water absorption coefficient of /m 2 h 0.5 .

또한, 본 발명의 단열재용 시멘트계 바탕조정재는 KS F 4716 규정에 의해 측정시, 1.0 ~ 2.0 N/㎟, 바람직하게는 1.5 ~ 1.9 N/㎟의 온냉반복강도를 가질 수 있다.In addition, the cement-based base control material for insulation of the present invention may have a heat/cool repetition strength of 1.0 to 2.0 N/mm 2 , preferably 1.5 to 1.9 N/mm 2 as measured by KS F 4716 regulations.

이하, 실시예를 통하여 본 발명을 더욱 구체적으로 설명하기로 하지만, 하기 실시예가 본 발명의 범위를 제한하는 것은 아니며, 이는 본 발명의 이해를 돕기 위한 것으로 해석되어야 할 것이다.Hereinafter, the present invention will be described in more detail through examples, but the following examples are not intended to limit the scope of the present invention, which should be construed to aid understanding of the present invention.

실시예 1 : 단열재용 시멘트계 바탕조정재의 제조 Example 1: Preparation of cement-based base adjustment material for insulation

시멘트(1종 포틀랜드 시멘트, 분말도 : 3,800cm3/g) 100 중량부에 대하여, 하기 표 1에 기재된 성분을 가지는 페로니켈 슬래그((주)포스코, 입도 : 0.15 ~ 0.3 mm) 30 중량부, 산화마그네슘(요령성 단동 흠양광업그룹, 순도 90%급 산화마그네슘) 3 중량부, 골재인 규사 7호사(입경 : 0.17 ~ 0.25mm) 362.5 중량부, 하기 표 2에 기재된 성분을 가지는 팽창 펄라이트(미성펄라이트 사, 입도 : 0.15 ~ 0.3 mm) 3 중량부 및 에틸렌초산비닐 분말수지(바커케미칼, Vinnapas 4044) 2.75 중량부를 혼합한 후 3분 동안 100rpm으로 믹싱(mixing)한다. 그 뒤, 시멘트 100 중량부에 대하여 물 162 중량부를 투입한 후 1분 동안 100rpm으로 저속 믹싱(mixing)한 후, 30초 동안 정지한다. 마지막으로, 다시 2분 동안 500rpm으로 고속 믹싱(mixing)하여 단열재용 시멘트계 바탕조정재를 제조하였다.Based on 100 parts by weight of cement (Type 1 Portland cement, fineness: 3,800 cm 3 /g), 30 parts by weight of ferronickel slag (POSCO Co., Ltd., particle size: 0.15 to 0.3 mm) having the components shown in Table 1 below; 3 parts by weight of magnesium oxide (Yoryongseong Dandong Heumyang Mining Group, purity 90% grade magnesium oxide), 362.5 parts by weight of silica sand No. 7 as aggregate (particle diameter: 0.17 to 0.25 mm) 362.5 parts by weight of expanded pearlite having the components shown in Table 2 below (unrefined Pearlite yarn, particle size: 0.15 to 0.3 mm) 3 parts by weight and 2.75 parts by weight of ethylene vinyl acetate powder resin (Wacker Chemical, Vinnapas 4044) are mixed, and then mixed at 100 rpm for 3 minutes. Then, after adding 162 parts by weight of water based on 100 parts by weight of cement, mixing was performed at a low speed at 100 rpm for 1 minute, followed by stopping for 30 seconds. Finally, by high-speed mixing (mixing) at 500 rpm for 2 minutes again to prepare a cement-based base control material for the insulation material.

Figure 112020090053935-pat00001
Figure 112020090053935-pat00001

Figure 112020090053935-pat00002
Figure 112020090053935-pat00002

실시예 2 ~ 7, 비교예 1 ~ 3Examples 2 to 7, Comparative Examples 1 to 3

실시예 1과 동일한 방법으로 단열재용 시멘트계 바탕조정재를 제조하였다. 다만, 표 3에 기재된 바와 같이 성분들의 함량을 달리하여 실시예 2 ~ 3 및 비교예 1 ~ 4의 단열재용 시멘트계 바탕조정재를 제조하였다.In the same manner as in Example 1 A cement-based base adjustment material for insulation was prepared. However, as shown in Table 3, by varying the content of the components, Examples 2 to 3 and Comparative Examples 1 to 4 were prepared as cement-based ground conditioning materials for insulating materials.

Figure 112020090053935-pat00003
Figure 112020090053935-pat00003

실험예 1 : 단열재용 시멘트계 바탕조정재 물성 측정Experimental Example 1: Measurement of physical properties of cement-based base adjustment material for insulation

실시예 1 ~ 7 및 비교예 1 ~ 3에서 제조한 단열재용 시멘트계 바탕조정재의 부착강도, 물흡수계수, 온냉반복강도 및 열환경성 평가를 하기 방법에 의거하여 측정하였고, 그 결과를 하기 표 4에 나타내었다.The adhesion strength, water absorption coefficient, hot and cold repetition strength, and thermal environment evaluation of the cement-based base control material for insulation prepared in Examples 1 to 7 and Comparative Examples 1 to 3 were measured according to the following methods, and the results are shown in Table 4 below. indicated.

1) 부착강도 측정(N/㎟)1) Measurement of adhesion strength (N/㎟)

제조된 단열재용 시멘트계 바탕조정재에 대해 KS F 4716규정에 의해 부착강도를 측정하였다.Adhesive strength was measured in accordance with KS F 4716 for the manufactured cement-based base adjustment material for insulation.

2) 물흡수계수 측정(kg/m2) Measurement of water absorption coefficient (kg/m 22 hh 0.50.5 ))

제조된 단열재용 시멘트계 바탕조정재에 대해 KS F 4716규정에 의해 물흡수계수를 측정하였다.The water absorption coefficient was measured in accordance with KS F 4716 for the manufactured cement-based background adjustment material for insulation.

3) 온냉반복강도 측정(N/㎟)3) Measurement of heat and cold repetition strength (N/㎟)

제조된 단열재용 시멘트계 바탕조정재에 대해 KS F 4716규정에 의해 온냉반복강도를 측정하였다.For the manufactured cement-based background adjustment material for insulation, the strength of hot and cold repeated strength was measured according to KS F 4716.

4) 열환경성 평가4) Thermal environment evaluation

제조된 단열재용 시멘트계 바탕조정재에 대해 열환경성 평가를 진행하기 위해 30cm(가로) X 30cm(세로) X 30cm(높이)의 스티로폼 박스의 외부에 열환경 제어를 위해 제조된 시멘트계 바탕조정재를 표면에 도포한 뒤 건조하였다. 이 후, 스티로폼 박스 상부에 열센서를 설치한 뒤, 외기 노출시의 외피면의 최저온도 및 최고온도를 측정하였다.In order to conduct thermal environmental evaluation of the manufactured cement-based base adjuster for insulation, the cement-based base adjuster prepared for thermal environment control is applied to the outside of a 30cm (width) X 30cm (length) X 30cm (height) styrofoam box. and then dried. After that, a thermal sensor was installed on the upper part of the Styrofoam box, and the minimum and maximum temperatures of the outer surface when exposed to outdoor air were measured.

Figure 112020090053935-pat00004
Figure 112020090053935-pat00004

상기 표 4에서 확인할 수 있듯이, 실시예 1에서 제조된 단열재용 시멘트계 바탕조정재는 부착강도 및 온냉반복강도가 우수할 뿐만 아니라, 물흡수계수가 낮고, 열환경성 평가 또한 우수한 것을 확인할 수 있었다.As can be seen in Table 4, it was confirmed that the cement-based base control material for insulation prepared in Example 1 was excellent in adhesion strength and hot/cold repetition strength, as well as a low water absorption coefficient and excellent thermal environment evaluation.

Claims (10)

시멘트 100 중량부에 대하여, 페로니켈 슬래그(ferronikel slag) 20 ~ 40 중량부, 산화마그네슘 2.0 ~ 4.0 중량부, 골재 253 ~ 472 중량부, 팽창 펄라이트(expanded perlite) 2.0 ~ 4.0 중량부 및 폴리올레핀 분말수지 2.0 ~ 4.0 중량부를 포함하고,
상기 페로니켈 슬래그는 이산화규소(SiO2), 산화마그네슘(MgO), 토탈-철(T-Fe), 산화알루미늄(Al2O3) 및 산화칼슘(CaO)을 포함하고, 입도가 0.15 ~ 0.6mm이며,
상기 팽창 펄라이트는 이산화규소(SiO2), 산화알루미늄(Al2O3), 산화철(Fe2O3), 산화칼슘(CaO), 산화마그네슘(MgO), 산화칼륨(K2O) 및 산화나트륨(Na2O)을 포함하고, 입도가 0.15 ~ 0.6mm인 것을 특징으로 하는 단열재용 시멘트계 바탕조정재 조성물.
Based on 100 parts by weight of cement, 20 to 40 parts by weight of ferronikel slag, 2.0 to 4.0 parts by weight of magnesium oxide, 253 to 472 parts by weight of aggregate, 2.0 to 4.0 parts by weight of expanded perlite, and polyolefin powder resin 2.0 to 4.0 parts by weight,
The ferronickel slag includes silicon dioxide (SiO 2 ), magnesium oxide (MgO), total-iron (T-Fe), aluminum oxide (Al 2 O 3 ) and calcium oxide (CaO), and has a particle size of 0.15 to 0.6 mm, and
The expanded pearlite is silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), iron oxide (Fe 2 O 3 ), calcium oxide (CaO), magnesium oxide (MgO), potassium oxide (K 2 O) and sodium oxide (Na 2 O) comprising, and a particle size of 0.15 ~ 0.6mm, characterized in that the cement-based background adjusting material composition for insulation.
삭제delete 삭제delete 삭제delete 삭제delete 삭제delete 제1항에 있어서,
상기 시멘트는 석고 시멘트, 고로 슬래그 시멘트 및 포틀랜드 시멘트 중에서 선택된 1종 이상을 포함하는 것을 특징으로 하는 단열재용 시멘트계 바탕조정재 조성물.
The method of claim 1,
Wherein the cement comprises at least one selected from gypsum cement, blast furnace slag cement and Portland cement.
제1항에 있어서,
상기 골재는 평균입경이 0.15mm ~ 0.6mm인 규사를 포함하는 것을 특징으로 하는 단열재용 시멘트계 바탕조정재 조성물.
The method of claim 1,
The aggregate is a cement-based background adjusting material composition for insulation, characterized in that it comprises silica sand having an average particle diameter of 0.15 mm to 0.6 mm.
제1항에 있어서,
상기 폴리올레핀 분말수지는 에틸렌초산비닐(ethylene vinyl acetate, EVA) 분말수지 및 저밀도폴리에틸렌(low density polyethylene, LDPE) 분말수지 중에서 선택된 1종 이상을 포함하는 것을 특징으로 하는 단열재용 시멘트계 바탕조정재 조성물.
The method of claim 1,
The polyolefin powder resin is ethylene vinyl acetate (ethylene vinyl acetate, EVA) powder resin and low-density polyethylene (low density polyethylene, LDPE) powder resin, characterized in that it comprises at least one selected from a cement-based base material composition for insulation.
제1항, 제7항 내지 제9항 중 어느 한 항에 따른 단열재용 시멘트계 바탕조정재 조성물을 포함하는 것을 특징으로 하는 단열재용 시멘트계 바탕조정재.
[Claim 10] A cement-based background conditioning material for insulation, comprising the cement-based background adjustment material composition for insulation according to any one of claims 1 to 9.
KR1020200108066A 2020-08-26 2020-08-26 Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same KR102450685B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020200108066A KR102450685B1 (en) 2020-08-26 2020-08-26 Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020200108066A KR102450685B1 (en) 2020-08-26 2020-08-26 Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same

Publications (2)

Publication Number Publication Date
KR20220027369A KR20220027369A (en) 2022-03-08
KR102450685B1 true KR102450685B1 (en) 2022-10-05

Family

ID=80813425

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020200108066A KR102450685B1 (en) 2020-08-26 2020-08-26 Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same

Country Status (1)

Country Link
KR (1) KR102450685B1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101311700B1 (en) * 2013-05-07 2013-09-26 강상수 Cement mortar composite having improved adiabatic capacity and durability, manufacturing method of panel and manufacturing method block using the composite
KR101807104B1 (en) 2017-07-04 2017-12-08 주식회사 세진에스엠씨 Versatile eco-friendly finishing composition for coating surface and coating method for coating surface of concrete structure therewith
KR101944249B1 (en) * 2017-12-29 2019-01-31 한국세라믹기술원 Cement-based binder mixed with ferronikel slag, cement mortar composition, cement concrete composition and lightweight concrete composition using the binder

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100363709B1 (en) 1999-12-24 2003-02-07 김재욱 concrete surface preparation compound and installation by using portland cement and epoxy resin
KR102017213B1 (en) * 2017-11-06 2019-09-02 (주)유송엔지니어링 Complex heat insulating material having multi-layer structure

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101311700B1 (en) * 2013-05-07 2013-09-26 강상수 Cement mortar composite having improved adiabatic capacity and durability, manufacturing method of panel and manufacturing method block using the composite
KR101807104B1 (en) 2017-07-04 2017-12-08 주식회사 세진에스엠씨 Versatile eco-friendly finishing composition for coating surface and coating method for coating surface of concrete structure therewith
KR101944249B1 (en) * 2017-12-29 2019-01-31 한국세라믹기술원 Cement-based binder mixed with ferronikel slag, cement mortar composition, cement concrete composition and lightweight concrete composition using the binder

Also Published As

Publication number Publication date
KR20220027369A (en) 2022-03-08

Similar Documents

Publication Publication Date Title
Klyuev et al. The micro silicon additive effects on the fine-grassed concrete properties for 3-D additive technologies
CN110272244B (en) Crack-resistant concrete and preparation process thereof
CN102515635B (en) Ceramsite heat insulation brick and preparation method thereof
KR20160144058A (en) Ultra-high performance concrete for mixing micro basalt fiber and macro steel fiber, and manufacturing method for the same
KR100985194B1 (en) Waterproofing Material In The Form of Powder
EP2831015B1 (en) Binder composition comprising lignite fly ash
Park et al. Effects of processing and materials variations on mechanical properties of lightweight cement composites
CN107721358A (en) Slag micropowder mixes perlite tailing baking-free ceramicite and preparation method thereof
CN110776334A (en) Cement-based wallboard with large hollow rate and ultrahigh toughness and preparation method thereof
EP2878585B1 (en) Method for the manufacturing of cementitious C-S-H seeds
Si-Ahmed et al. Influence of metakaolin on the performance of mortars and concretes
KR20190051191A (en) Complex heat insulating material having multi-layer structure
KR102450685B1 (en) Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same
CN108249849A (en) A kind of high agstone volume green concrete
KR101664273B1 (en) cement mortar compositon and cement mortar comprising the same, method thereof
JP3267895B2 (en) Cement clinker and cement composition
CZ25398U1 (en) Heat-insulating alkali activated filling material based on siopor
KR102450633B1 (en) Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same
Vyšvařil et al. Foam glass dust as a supplementary material in lime mortars
KR100516758B1 (en) High strength cement composition and method of high strength cement panel
JP2000233955A (en) Hardening accelerator for high flowage spraying concrete
KR20210147819A (en) Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same
KR101989927B1 (en) Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same
KR20210009946A (en) Non-cement Mortar with Reduction of Autogenous Shrinkage And Carbonation
CN104609818A (en) High-strength water-resistant aerated brick containing lithium silicate and preparation thereof

Legal Events

Date Code Title Description
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant