KR101807104B1 - Versatile eco-friendly finishing composition for coating surface and coating method for coating surface of concrete structure therewith - Google Patents
Versatile eco-friendly finishing composition for coating surface and coating method for coating surface of concrete structure therewith Download PDFInfo
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- KR101807104B1 KR101807104B1 KR1020170084906A KR20170084906A KR101807104B1 KR 101807104 B1 KR101807104 B1 KR 101807104B1 KR 1020170084906 A KR1020170084906 A KR 1020170084906A KR 20170084906 A KR20170084906 A KR 20170084906A KR 101807104 B1 KR101807104 B1 KR 101807104B1
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
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Abstract
Description
본 발명은 다기능 친환경 표면 마감 코팅제 조성물 및 이를 이용한 콘크리트 구조물 표면 마감 코팅 방법에 관한 것으로, 더욱 상세하게는 시공이 용이하고, 자기 보수성, 내식성, 난연성, UV 저항성, 내염해성, 중성화 저항성, 부착성, 동결융해저항성, 방수성 등이 우수하여 콘크리트 구조물의 공용기간 증가, 유지보수비용 절감 및 시공성 향상을 구현할 수 있는 다기능 친환경 표면 마감 코팅제 조성물 및 이를 이용한 콘크리트 구조물 표면 마감 코팅 방법에 관한 것이다.The present invention relates to a multifunctional environmentally friendly surface finishing coating composition and a method for coating a surface of a concrete structure using the same. More specifically, the present invention relates to a multifunctional environmentally friendly surface finishing coating composition, Freeze-thaw resistance, and waterproofness, thereby realizing an increase in the period of use of the concrete structure, maintenance cost reduction, and improvement of the workability, and a surface finishing coating method of a concrete structure using the same.
일반적으로 콘크리트 구조물에 균열이 발생하면 방수 성능 저하, 철근부식, 내구성 저하, 강도 저하 등으로 치명적인 결함을 초래할 수 있다. 콘크리트의 균열은 염해, 열화와 같은 외적 환경 원인, 설계하중, 소성수축 또는 건조수축과 같은 재료 특성, 배합조건, 시공적인 요인 등의 여러 가지 요인에 의하여 발생한다. 이와 같은 여러 가지 요인에 의해 콘크리트 구조물에 균열이 발생하면 콘크리트 구조물은 하중을 견디지 못하고 붕괴할 수 있다. 균열이 발생한 콘크리트 구조물에 대하여는 구조물의 안정성, 미관 등을 고려하여 방수성, 내구성 등을 회복하기 위한 보수작업이 필요하다.Generally, cracks in concrete structures can lead to fatal defects such as deterioration of waterproof performance, corrosion of reinforcing steel, deterioration of durability, and decrease of strength. Cracks in concrete are caused by various factors such as external environmental causes such as deterioration, deterioration, material properties such as design load, plastic shrinkage or drying shrinkage, mixing conditions, and construction factors. When cracks occur in the concrete structure due to various factors such as these, the concrete structure can collapse without being able to withstand the load. Concrete structures with cracks are required to be repaired in order to restore the waterproofness and durability in consideration of the stability and the beauty of the structure.
화학적 부식은 콘크리트가 외부에서 화학적 작용을 받아, 시멘트 경화체를 구성하는 수화 생성물을 변형 혹은 분해하여 결합 능력을 잃어버리는 열화 현상을 총칭한다. 이는 기존의 중성화, 동해, 염해에 의한 열화 현상과 혼동하기 쉬우며, 콘크리트 구조물에 내황산성 보수 모르타르가 아닌 기존의 보수용 모르타르로 타설됨으로써 결국 구조물에 균열 또는 박리 현상 등 성능 저하가 발생되어 내구성이 급격히 저하되는 경우가 빈번히 발생하고 있다.Chemical corrosion is a general term of deterioration phenomenon where concrete receives chemical action from the outside and deforms or decomposes the hydration products constituting the cement hardened body and loses its bonding ability. It is easy to be confused with the deterioration phenomenon by existing neutralization, East Sea and salting, and the concrete structure is not replaced with the sulfuric acid repair mortar, but the existing repair mortar is poured into the concrete structure, resulting in deterioration such as cracking or peeling in the structure, There are frequent occurrences of rapid decrease.
따라서, 산성, 중성화, 동해, 염해 등과 별도로 화학적 부식이 일어날 가능성이 맨홀 등에 사용되는 라이닝 및 코팅재 조성물에 대한 개발이 요구되고 있다.Accordingly, there is a demand for development of a lining and coating material composition which is likely to cause chemical corrosion separately from acidity, neutralization, corrosion, corrosion, and the like, and which is used for a manhole or the like.
일반적인 환경에서 화학적 부식 문제가 생기는 것은 확률적으로 매우 적으며, 생활 하수 등에 포함된 유기물이 세균에 의해 반응을 일으켜 황산 이온을 생성함으로써 콘크리트를 침식하는 경우가 대부분이다. 화학적 부식을 받는 구조물로는 수로, 수로터널, 하수 관련 구조물, 복개 구조물, 화학공장, 식품공장 등의 관련 구조물, 토양 오염 및 온천 지대의 지하 구조물 등을 들 수 있다.In general, it is probable that chemical corrosion problems occur very little, and most of the organic matter contained in domestic wastewater is reacted by bacteria to generate sulfate ion and erode the concrete. Structures subject to chemical corrosion include waterways, waterway tunnels, sewer related structures, closure structures, chemical structures, related structures such as food factories, soil contamination and underground structures in the hot springs.
본 발명이 해결하고자 하는 과제는 자기 보수성, 내식성, 난연성, UV 저항성, 내염해성, 중성화 저항성, 부착성, 동결융해저항성, 방수성 등이 우수하여 콘크리트 구조물의 공용기간 증가, 유지보수비용 절감 및 시공성 향상을 구현할 수 있는 다기능 친환경 표면 마감 코팅제 조성물 및 이를 이용한 콘크리트 구조물 표면 마감 코팅 방법을 제공함에 있다. The problem to be solved by the present invention is to improve the cohesion period of concrete structures, maintenance cost reduction, and workability by providing excellent self-retention, corrosion resistance, flame retardancy, UV resistance, flame retardancy, neutralization resistance, adhesion, freezing and thawing resistance and waterproofness Functional surface-finishing coating composition and a method of coating a surface of a concrete structure using the same.
본 발명은, 무기 충전재 5∼98중량%, 기능성 혼화제 1∼70중량% 및 물 1~30중량%를 포함하며, 상기 기능성 혼화제는 아크릴-우레탄 공중합체 30∼99중량%, 에폭시 에스테르 수지 0.1∼25중량%, 폴리메타크릴산메틸 0.01∼25중량%, 폴리이소부틸렌 0.01~20중량% 및 알콕시실릴이소시아누레이트 0.01∼20중량%를 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물을 제공한다. The functional admixture comprises 30 to 99% by weight of an acrylic-urethane copolymer, 0.1 to 30% by weight of an epoxy ester resin, Characterized in that the polyisobutylene is present in an amount of from 0.1 to 25% by weight, from 0 to 25% by weight of polymethylmethacrylate, from 0.01 to 20% by weight of polyisobutylene and from 0.01 to 20% by weight of alkoxysilylisocyanurate. to provide.
상기 기능성 혼화제는 점도 및 유동성을 개선하기 위한 에틸셀롤로오스를 0.01∼10중량% 더 포함할 수 있다.The functional admixture may further contain 0.01 to 10% by weight of ethylcellulose to improve viscosity and fluidity.
또한, 상기 기능성 혼화제는 내유성, 내용제성, 내한성, 작업성을 개선하기 위하여 테트라플루오로에틸렌 0.01∼10중량% 더 포함할 수 있다.In addition, the functional admixture may further contain 0.01 to 10% by weight of tetrafluoroethylene to improve oil resistance, solvent resistance, cold resistance, and workability.
또한, 상기 기능성 혼화제는 붓자국, 로울러자국, 오렌지필(orange peal), 분화구현상(cratering), 핀홀(pin hole), 색얼룩 등의 표면에 생기는 결함을 방지하기 위하여 부틴디올(butindiol을 0.001∼10중량% 더 포함할 수 있다. The functional admixture may also contain butindiol in an amount of 0.001 to 10 wt% to prevent defects on the surface such as brush marks, roller marks, orange peal, cratering, pinhole, 10% by weight.
또한, 상기 기능성 혼화제는 접착력, 내마모성, 내한성 등을 개선하기 위하여 염화비닐-초산비닐 공중합체를 0.001~10중량% 더 포함할 수 있다.The functional admixture may further contain 0.001 to 10% by weight of a vinyl chloride-vinyl acetate copolymer in order to improve adhesion, abrasion resistance, cold resistance and the like.
또한, 상기 기능성 혼화제는 연행공기의 발생으로 인한 공기량의 증가를 감소시키기 위한 소포제 0.01∼10중량%를 더 포함할 수 있다.In addition, the functional admixture may further include 0.01 to 10% by weight of an antifoaming agent to reduce an increase in the amount of air due to generation of entrained air.
상기 무기 충전재는 알루미나 시멘트 5∼90중량%, 분말도가 4,000 cm2/g이상인 고로슬래그 미분말 5∼40중량%, 글라스 버블 0.1~30중량%, 질석 0.1~30중량%, 견운모 분말 0.1~30중량%, 마그네슘알루미늄실리케이트 0.1∼20중량%, 실리카질 규사 0.1~20중량%, 벤토나이트 0.01~10중량% 및 산화 마그네슘 0.01∼10중량%를 포함할 수 있다.The inorganic filler is 5 to 90% by weight of alumina cement, fineness is 4,000 cm 2 / g or more blast furnace slag 5 to 40% by weight of glass bubbles from 0.1 to 30% by weight, 0.1 to 30% by weight of vermiculite, sericite powder, 0.1 to 30 0.1 to 20% by weight of magnesium aluminum silicate, 0.1 to 20% by weight of silica silica, 0.01 to 10% by weight of bentonite, and 0.01 to 10% by weight of magnesium oxide.
상기 무기 충전재는 시멘트에 의해 수축되는 것을 억제하기 위한 폴리에틸렌글리콜 0.01∼10중량%를 더 포함할 수 있다.The inorganic filler may further include 0.01 to 10% by weight of polyethylene glycol for inhibiting shrinkage by cement.
또한, 상기 무기 충전재는 시멘트 경화체의 내부 조직을 치밀하게 하여 수밀성 및 동결융해 저항성을 개선시키고 내구성을 증진시키기 위한 폴리카본산, 나프탈렌, 멜라민 및 리그닌 감수제 중에서 선택된 1종 이상의 물질 0.01∼10중량%를 더 포함할 수 있다.Also, the inorganic filler is preferably used in an amount of 0.01 to 10% by weight of at least one material selected from the group consisting of polycarboxylic acid, naphthalene, melamine and lignin reducing agents to improve the watertightness and freeze-thaw resistance and to improve durability by densifying the internal structure of the cement- .
또한, 상기 무기 충전재는 급격하게 경화되는 것을 지연하기 위한 지연제 0.01∼10중량%를 더 포함할 수 있다.The inorganic filler may further include 0.01 to 10% by weight of a retarder for delaying rapid curing.
또한, 상기 무기 충전재는 색상을 구현하고 미관을 개선하기 위한 안료 0.01~10 중량%를 더 포함하는 것이 바람직하다. In addition, the inorganic filler preferably further comprises 0.01 to 10% by weight of pigment for realizing hue and improving the appearance.
또한, 본 발명은, 콘크리트 구조물의 레이턴스, 불순물 또는 열화부위를 그라인더, 평삭기, 연마기, 숏블라스터 등으로 치핑하여 제거하는 단계와, 치핑된 부위를 핸드 워터젯, 진공 흡입기 등으로 청소하는 단계와, 바탕 콘크리트 구조물과 상기 고성능 친환경 표면 마감 코팅제 조성물의 부착력을 개선하고, 물의 침투와 염소이온 침투를 억제하며, 내수성 및 방수성을 개선하기 위한 표면 침투제를 도포하는 단계와, 상기 다기능 친환경 표면 마감 코팅제 조성물을 붓, 롤러, 에어리스 등을 이용하여 살포하는 단계; 살포된 상기 다기능 친환경 표면 마감 코팅제 조성물 상부에 염해 저항성, 중성화 저항성, 표면 경도 개선, 방수성, 내수성을 개선하기 위하여 표면 강화제를 도포하는 단계; 및 양생하는 단계를 포함하는 콘크리트 구조물 표면 마감 코팅 방법을 제공한다.The present invention also relates to a method of manufacturing a concrete structure, comprising: a step of chipping and removing a latent, an impurity or a deteriorated part of a concrete structure by a grinder, a planer, a grinder, a short blaster, Applying a surface penetrant to improve adhesion of the backing concrete structure and the high performance environmentally friendly surface finish coating composition, to inhibit water penetration and chlorine ion penetration, and to improve water resistance and water resistance; and applying the surface functional agent to the multi- Spraying using a brush, roller, airless or the like; Applying a surface strengthening agent on top of the sprayed multifunctional eco-friendly surface finish coating composition to improve resistance to salt, neutralization resistance, surface hardness, water resistance and water resistance; And curing the surface of the concrete structure.
여기서, 상기 표면 침투제는 상기 기능성 혼화제의 고형분을 10%이하로 조정하여 사용하는 것이 바람직하다.Here, it is preferable that the surface wetting agent is used by adjusting the solid content of the functional admixture to 10% or less.
여기서, 상기 표면 강화제는 아크릴-우레탄, 실리카 무기질 표면 강화제, 실란계 침투강화제, 상기 기능성 혼화제 중 어느 하나 이상을 포함한 것을 사용하는 것이 바람직하다. Here, the surface strengthening agent is preferably one containing at least one of acryl-urethane, silica inorganic surface hardener, silane penetration enhancer, and functional admixture.
본 발명의 콘크리트 구조물 다기능 친환경 표면 마감 코팅제 조성물은 지수성능, 자기 치유성, 작업성, 내염해성, 내화학성, 중성화 저항성, 내구성, 부착성, 방수성 등이 우수하여 콘크리트 구조물의 공용기간 증가, 유지보수비용 절감 및 시공성 향상을 구현할 수 있다. The multi-functional eco-friendly surface finish coating composition of the present invention is excellent in index performance, self-healing property, workability, salt resistance, chemical resistance, neutralization resistance, durability, adhesion property and waterproof property, It is possible to realize cost reduction and improved workability.
또한, 본 발명의 다기능 친환경 표면 마감 코팅제 조성물은, 피착물이 습윤 상태에서도 시공이 가능하고 우수한 접착력을 나타내 기존 유기계 수지에서처럼 건조할 필요가 없어 시공기간을 단축할 수 있어 비용 절감효과를 얻을 수 있다. In addition, the multifunctional eco-friendly surface coating composition of the present invention can be applied even when the adherend is in a wet state, exhibits excellent adhesive force, and is not required to be dried as in conventional organic resins, .
본 발명의 다기능 친환경 표면 마감 코팅제 조성물을 이용한 콘크리트 구조물 표면 마감 코팅 방법에 의하면, 고성능 친환경 표면 마감 코팅제 조성물이 속경성이고 높은 강도 및 내구성을 나타냄으로써, 시공기간을 단축하고, 구조물의 사용기간을 증가시킬 수 있을 뿐만 아니라 유지보수에 소요되는 비용을 절감할 수 있으며, 우수한 강도특성과 내구성을 보유하여 공용기간 증가와 유지보수에 소요되는 비용을 절감할 수 있다. According to the surface finish coating method of a concrete structure using the multifunctional eco-friendly surface finishing coating composition of the present invention, a high performance eco-friendly surface finish coating composition shows quick hardness and high strength and durability, thereby shortening the construction period, It is possible to reduce the maintenance cost as well as to have excellent strength and durability, which can increase the maintenance period and reduce maintenance cost.
이하, 본 발명에 따른 바람직한 실시예를 상세하게 설명한다. 그러나, 이하의 실시예는 이 기술 분야에서 통상적인 지식을 가진 자에게 본 발명이 충분히 이해되도록 제공되는 것으로서 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 다음에 기술되는 실시예에 한정되는 것은 아니다. Hereinafter, preferred embodiments according to the present invention will be described in detail. However, it should be understood that the following embodiments are provided so that those skilled in the art will be able to fully understand the present invention, and that various modifications may be made without departing from the scope of the present invention. It is not.
이하에서, 콘크리트 구조물이라 함은 일반적인 수로, 수로 터널, 정수장, 배수지, 하수구조물, 지하구조물, 지수구조물, 도로 및 고속도로뿐만 아니라 차량이 통행하는 시설 구조물(중앙 분리벽, 날개벽, 측구 콘크리트), 옹벽 구조물, 콘크리트 슬래브, 해양 구조물 등을 포함하는 콘크리트로 이루어진 모든 구조물의 의미로 사용한다. Hereinafter, the concrete structure refers to a concrete structure, such as a general waterway, a waterway tunnel, a water purification plant, a reservoir, a sewage structure, an underground structure, an exponent structure, roads and highways, It is used to mean all structures made of concrete including structures, concrete slabs, and offshore structures.
본 발명의 바람직한 실시예에 따른 다기능 친환경 표면 마감 코팅제 조성물은 무기 충전재, 기능성 혼화제 및 물을 포함한다. A multifunctional environmentally friendly surface finish coating composition according to a preferred embodiment of the present invention comprises an inorganic filler, a functional admixture and water.
상기 무기 충전재는 상기 친환경 표면 마감 코팅제 조성물에 대하여 5∼98중량% 함유되는 것이 바람직하다. The inorganic filler is preferably contained in an amount of 5 to 98% by weight based on the eco-friendly surface finish coating composition.
상기 기능성 혼화제는 시멘트 경화체의 내부에 필름을 형성하여 휨, 인장 및 부착강도를 향상시키고 작업성 및 내구성을 개선하며 고유동성(셀프 레벨링)을 갖게 하는 역할을 하며, 상기 다기능 친환경 표면 마감 코팅제 조성물에 대하여 1∼70중량% 함유되는 것이 바람직하다. The functional admixture serves to improve the warp, tensile, and adhesion strength, improve workability and durability, and has high self-leveling property by forming a film in the cement hardened body. By weight to 1% by weight to 70% by weight.
상기 무기 충전재는, 알루미나 시멘트 5∼90중량%, 분말도가 4,000 cm2/g이상인 고로슬래그 미분말 5∼40중량%, 글라스 버블 0.1~30중량%, 질석 0.1~30중량%, 견운모 분말 0.1~30중량%, 마그네슘알루미늄실리케이트 0.1∼20중량%, 실리카질 규사 0.1~20중량%, 벤토나이트 0.01~10중량% 및 산화 마그네슘 0.01∼10중량%를 포함할 수 있다.The inorganic fillers, alumina cement, 5 to 90% by weight, the powder is also 4,000 cm 2 / g or more blast furnace slag 5 to 40% by weight, the glass bubbles of 0.1 to 30% by weight, 0.1 to 30% by weight of vermiculite, sericite powder 0.1 , Magnesium aluminosilicate 0.1 to 20 wt%, silica silica silica 0.1 to 20 wt%, bentonite 0.01 to 10 wt%, and magnesium oxide 0.01 to 10 wt%.
상기 무기 충전재는 시멘트에 의해 수축되는 것을 억제하기 위한 폴리에틸렌글리콜 0.01∼10중량%를 더 포함할 수 있다.The inorganic filler may further include 0.01 to 10% by weight of polyethylene glycol for inhibiting shrinkage by cement.
또한, 상기 무기 충전재는 시멘트 경화체의 내부 조직을 치밀하게 하여 수밀성 및 동결융해 저항성을 개선시키고 내구성을 증진시키기 위한 폴리카본산, 나프탈렌, 멜라민 및 리그닌계 감수제 중에서 선택된 1종 이상의 물질 0.01∼10중량%를 더 포함할 수 있다.The inorganic filler may be used in an amount of 0.01 to 10% by weight, more preferably 0.01 to 10% by weight, of at least one material selected from the group consisting of polycarboxylic acid, naphthalene, melamine and lignin-based water reducing agents for improving the watertightness and freeze / thaw resistance and improving durability, As shown in FIG.
또한, 상기 무기 충전재는 급격하게 경화되는 것을 지연하기 위한 지연제 0.01∼10중량%를 더 포함할 수 있다.The inorganic filler may further include 0.01 to 10% by weight of a retarder for delaying rapid curing.
또한, 상기 무기 충전재는 색상을 구현하고 미관을 개선하기 위한 안료 0.01~10 중량%를 더 포함하는 것이 바람직하다. In addition, the inorganic filler preferably further comprises 0.01 to 10% by weight of pigment for realizing hue and improving the appearance.
상기 알루미나 시멘트는 초속경 재료로서 시멘트와 혼합할 때 수 일 혹은 수 십일에 얻어지는 일반 포틀랜드 시멘트의 압축강도를 수 시간 내에 얻을 수 있게 한다. 상기 알루미나 시멘트는 상기 무기 충전재에 대하여 5∼90중량%를 함유되는 것이 바람직하다. 상기 알루미나 시멘트의 함량이 5중량% 미만이면 초기 강도 발현 및 내구성능 발현이 미약할 수 있고, 그 함량이 90중량%를 초과하면 작업성 및 가격경쟁력이 저하될 수 있다. The alumina cement, when mixed with cement as a first-speed material, enables to obtain the compressive strength of ordinary Portland cement obtained within several days or several days within a few hours. The alumina cement is preferably contained in an amount of 5 to 90% by weight based on the inorganic filler. If the content of the alumina cement is less than 5% by weight, initial strength development and durability performance may be insufficient. If the content is more than 90% by weight, workability and price competitiveness may be deteriorated.
상기 분말도가 4,000 cm2/g 이상인 고로슬래그 미분말은 잠재수경성 물질로 시멘트 경화체의 장기강도를 증진시키며 시멘트 경화체의 수화조직을 치밀하게 하여 화학저항성과 내구성을 증대시키는 역할을 한다. 상기 고로슬래그 미분말은 상기 무기 충전재에 대하여 5∼40중량% 함유되는 것이 바람직하다. 상기 고로슬래그 미분말의 함량이 5중량% 미만이면 장기강도 발현, 내구성 개선효과가 저하되고, 그 함량이 40중량%를 초과하면 초기강도 발현이 지연될 수 있다.The blast furnace slag powder having a powderity of 4,000 cm 2 / g or more is a latent hydraulic material, which improves the long-term strength of the hardened cement body and tightens the hydrated structure of the cement hardened body to increase the chemical resistance and durability. The blast furnace slag fine powder is preferably contained in an amount of 5 to 40% by weight based on the inorganic filler. When the content of the blast furnace slag powder is less than 5% by weight, the long-term strength development and durability improving effect are deteriorated. When the content is more than 40% by weight, the initial strength development may be delayed.
상기 글라스 버블은 공동의 박판형 단세포성구 형상을 갖으며 난연성 및 표면경도 개선을 위하여 사용된다. 상기 글라스 버블은 상기 무기 충전재에 대하여 0.1∼30중량% 함유되는 것이 바람직하며, 상기 글라스 버블의 함량이 30중량%를 초과하면 난연성 및 표면경도는 개선되나 작업성이 저하될 수 있고, 상기 글라스 버블의 함량이 0.1중량% 미만이면 작업성은 개선되나 난연성 및 표면경도 개선 효과가 미약할 수 있다.The glass bubble has a thin lamellar unicellular bulb shape and is used for improving flame retardancy and surface hardness. The glass bubbles are preferably contained in an amount of 0.1 to 30% by weight based on the inorganic filler. When the content of the glass bubbles exceeds 30% by weight, flame retardancy and surface hardness are improved but workability may be deteriorated. Is less than 0.1% by weight, the workability is improved but the flame retardancy and surface hardness improvement effect may be weak.
상기 질석은 무독성 무취를 구비하고 다공성으로 경량이며 열전도율이 낮아 불연 및 단열 효과를 개선하기 위하여 사용한다. 상기 질석은 상기 무기 충전재에 대하여 0.1∼30중량% 함유되는 것이 바람직하다. 상기 질석의 함량이 30중량%를 초과하면 성능은 개선되나 작업성이 저하되고 경제성이 떨어지고, 상기 질석의 함량이 0.1중량% 미만이면 작업성은 개선되나 불연 및 단열효과가 미약할 수 있다.The vermiculite has a non-toxic odorless, porous, lightweight, low thermal conductivity and is used to improve fire retardant and adiabatic effects. The vermiculite is preferably contained in an amount of 0.1 to 30% by weight based on the inorganic filler. If the content of the vermiculite exceeds 30% by weight, the performance is improved but the workability is decreased and the economical efficiency is deteriorated. If the content of the vermiculite is less than 0.1% by weight, the workability is improved but the fireproofing and heat insulating effect may be weak.
상기 견운모 분말은 천연 포졸란 물질로 장기강도 증진 및 내구성 개선 뿐만 아니라 방수성능 및 자기치유성능을 증대시키는 역할을 한다. 상기 견운모 분말은 상기 무기 충전재에 대하여 0.1∼30중량% 함유되는 것이 바람직하다. 상기 견운모 분말의 함량이 0.1중량% 미만이면 장기강도 발현, 내구성, 방수성능 및 자기치유성능이 저하되고, 그 함량이 30중량%를 초과하면 작업성이 저하되고 초기강도 발현이 지연될 수 있다.The above-mentioned sericite powder is a natural pozzolanic substance and plays a role of enhancing long-term strength and durability as well as improving waterproof performance and self-healing performance. The content of the sericite powder is preferably 0.1 to 30% by weight based on the inorganic filler. When the content of the sericite powder is less than 0.1% by weight, the long-term strength development, durability, waterproofing performance and self-healing performance are deteriorated, and if the content is more than 30% by weight, workability may be deteriorated and initial strength development may be delayed.
상기 마그네슘알루미늄실리케이트는 증점제로서 조성물의 재료분리 방지, 분산성 및 셀프 레벨링성을 개선하기 위하여 사용된다. 상기 마그네슘 알루미늄 실리케이트는 상기 무기 충전재에 대하여 0.1∼20중량% 함유되는 것이 바람직하며, 상기 마그네슘 알루미늄 실리케이트의 함량이 20중량%를 초과하면 작업성이 저하될 수 있고, 상기 마그네슘 알루미늄 실리케이트의 함량이 0.1중량% 미만이면 분산성 및 셀프레벨링성 개선 효과가 미약할 수 있다.The magnesium aluminum silicate is used as a thickener in order to improve the material separation prevention, dispersibility and self-leveling property of the composition. The magnesium aluminum silicate is preferably contained in an amount of 0.1 to 20 wt% with respect to the inorganic filler. When the content of the magnesium aluminum silicate exceeds 20 wt%, workability may be deteriorated, and when the content of the magnesium aluminum silicate is 0.1 When the amount is less than 10% by weight, the effect of improving the dispersibility and the self-leveling property may be insignificant.
상기 실리카질 규사는 상기 분말 결합재에 대하여 0.1~20중량% 함유되는 것이 바람직하다. 상기 잔골재는 6호규사 : 7호규사를 중량비로 0.1~0.4 : 1로 혼합한 것을 사용하는 것이 바람직하다. The silica silica is preferably contained in an amount of 0.1 to 20% by weight based on the powdery binder. The fine aggregate is preferably a mixture of silica sand (No. 6) and silica sand (No. 7) in a weight ratio of 0.1 to 0.4: 1.
상기 벤토나이트는 조성물의 재료분리 방지를 위하여 사용한다. 상기 벤토나이트는 상기 무기 충전재에 대하여 0.01∼10중량% 함유되는 것이 바람직하다. 상기 벤토나이트의 함량이 0.01중량% 미만이면 재료분리현상이 발생하기 쉽고, 그 함량이 10중량%를 초과하면 점도가 높아져 작업성이 저하된다.The bentonite is used for preventing the separation of the composition of the composition. The bentonite is preferably contained in an amount of 0.01 to 10% by weight based on the inorganic filler. When the content of bentonite is less than 0.01% by weight, separation of the material tends to occur. When the content of bentonite is more than 10% by weight, viscosity increases and workability is lowered.
상기 산화 마그네슘은 산화 방지 및 난연성을 개선하기 위해 사용한다. 상기 산화마그네슘은 상기 무기 충전재에 대하여 0.01∼10중량% 함유되는 것이 바람직하다. 상기 산화마그네슘의 함량이 0.01중량% 미만이면 산화 및 난연성 개선 효과가 미약할 수 있고, 상기 산화마그네슘의 함량이 10중량%를 초과하면 산화 및 난연성은 개선되나 경제성이 저하된다. The magnesium oxide is used for improving the oxidation resistance and the flame retardancy. The magnesium oxide is preferably contained in an amount of 0.01 to 10 wt% with respect to the inorganic filler. If the content of magnesium oxide is less than 0.01% by weight, the effect of improving oxidation and flame retardancy may be insignificant. If the content of magnesium oxide exceeds 10% by weight, oxidation and flame retardancy are improved but economical efficiency is lowered.
상기 폴리에틸렌글리콜은 시멘트에 의해 수축되는 것을 억제하는 역할을 한다. 상기 폴리에틸렌글리콜은 상기 무기 충전재에 대하여 0.01∼10중량% 함유되는 것이 바람직하다. 상기 폴리에틸렌글리콜의 함량이 0.01중량% 미만이면 시멘트에 의한 수축을 억제하는 효과가 미약할 수 있고, 그 함량이 10중량%를 초과하면 작업성이 저하될 수 있다.The polyethylene glycol serves to inhibit shrinkage by cement. The polyethylene glycol is preferably contained in an amount of 0.01 to 10% by weight based on the inorganic filler. If the content of the polyethylene glycol is less than 0.01% by weight, the effect of suppressing shrinkage by cement may be insignificant. If the content exceeds 10% by weight, the workability may be deteriorated.
상기 폴리카본산, 나프탈렌, 멜라민 및 리그닌계 고성능 감수제 중에서 선택된 1종 이상의 물질은 시멘트 경화체의 내부 조직을 치밀하게 하여 수밀성 및 동결융해 저항성을 개선시키고 내구성을 증진시킨다. 상기 폴리카본산, 나프탈렌, 멜라민 및 리그닌계 감수제 중에서 선택된 1종 이상의 물질은 상기 무기 충전재에 대하여 0.01∼10중량% 함유되는 것이 바람직하다.The at least one material selected from the group consisting of polycarboxylic acid, naphthalene, melamine and lignin-based high-performance water reducing agents is dense in the internal structure of the cement hardened body to improve watertightness and freeze- It is preferable that at least one material selected from the above polycarboxylic acids, naphthalene, melamine and lignin-based water reducing agents is contained in an amount of 0.01 to 10% by weight based on the inorganic filler.
상기 지연제는 일정 시간 동안 작업성을 확보하기 위해 급격하게 경화되는 것을 지연하기 위하여 사용되는 것으로서, 상기 무기 충전재에 대하여 0.01∼10중량%를 함유되는 것이 바람직하다. 지연제로는 일반적으로 잘 알려진 물질을 사용할 수 있는데, 예컨대 포도당, 글루코오스, 텍스트린, 덱스트란과 같은 당류, 글루콘산, 사과산, 시트릭산(citric acid)과 같은 산류 또는 그의 염, 아미노카복실산 또는 그의 염, 포스폰산 또는 그의 유도체, 글리세린과 같은 다가알코올 등을 사용할 수 있다. 상기 지연제는 시트릭산 : 글루콘산을 0.5~0.95 : 0.05~0.5의 비율로 혼합된 것을 사용하는 것이 바람직하다. The retarder is used for delaying rapid curing in order to ensure workability for a certain period of time, and it is preferable that the retarder is contained in an amount of 0.01 to 10 wt% with respect to the inorganic filler. As the delaying agent, generally well known substances can be used. Examples thereof include saccharides such as glucose, glucose, texturin and dextran, acids or salts thereof such as gluconic acid, malic acid and citric acid, aminocarboxylic acids or salts thereof , Phosphonic acid or derivatives thereof, and polyhydric alcohols such as glycerin. The retarder is preferably a mixture of citric acid and gluconic acid in a ratio of 0.5 to 0.95: 0.05 to 0.5.
상기 안료는 색상을 구현하고 미관을 개선하기 위하여 사용하는 것으로서, 상기 무기 충전재에 대하여 0.01~10 중량% 함유되는 것이 바람직하다. 상기 안료는 식별이 용이하도록 첨가되며, 보다 선명한 색상으로 식별이 용이하고 색상의 지속성이 향상될 수 있다. 상기 안료는 적색 산화철, 황색 산화철, 산화크롬 (CrO3), 자색 산화철 및 흑색 산화철(카본 블랙) 중에서 선택된 1종 또는 2종 이상의 물질을 사용할 수 있으며, 이에 의해 적색, 녹색, 황색, 흑색, 청색, 흰색 등 다양한 색상을 구현할 수 있다. The pigment is used to improve hue and to realize hue, and is preferably contained in an amount of 0.01 to 10% by weight with respect to the inorganic filler. The pigment is added for easy identification, is easier to identify with a sharper color, and color persistence can be improved. The pigment may be at least one material selected from red iron oxide, yellow iron oxide, chromium oxide (CrO 3 ), purple iron oxide and black iron oxide (carbon black), whereby red, green, yellow, , And white.
상기 기능성 혼화제는 시멘트 경화체에 분산되면서 시멘트 경화체의 내부에 필름을 형성하여 휨, 인장 및 부착강도를 향상시키고 보수성을 개선하여 중성화 저항성, 내염해성, 내화학성, 동결융해 저항성 등의 내구성을 향상시킬 수 있으며, 고유동성(셀프 레벨링)을 갖게 하는 역할을 한다.The functional admixture is dispersed in a cement hardened product to form a film in the cured hardened product to improve warpage, tensile and adhesion strength and improve water retention, thereby improving durability such as neutralization resistance, salt resistance, chemical resistance and freezing and thaw resistance And plays a role of providing high fluidity (self-leveling).
상기 기능성 혼화제는 아크릴-우레탄 공중합체 30∼99중량%, 에폭시 에스테르 수지 0.1∼30중량%, 폴리메타크릴산메틸 0.01∼30중량%, 폴리이소부틸렌 0.01~20중량% 및 알콕시실릴이소시아누레이트 0.01∼20중량%를 포함한다.Wherein the functional admixture comprises 30 to 99% by weight of an acrylic-urethane copolymer, 0.1 to 30% by weight of an epoxy ester resin, 0.01 to 30% by weight of polymethyl methacrylate, 0.01 to 20% by weight of polyisobutylene, 0.01 to 20% by weight.
상기 아크릴-우레탄 공중합체는 상기 친환경 표면 마감 코팅제 조성물 내부에 폴리머 필름을 형성하여 휨, 인장 및 부착강도를 증진시킬 뿐만 아니라 폴리머 필름막으로 인하여 내구성을 개선시킨다. 상기 아크릴-우레탄 공중합체는 상기 기능성 혼화제에 대하여 30∼99중량% 함유되는 것이 바람직하다. 상기 아크릴-우레탄 공중합체의 함량이 30중량% 미만이면 강도 및 내구성 개선효과가 저하되고, 그 함량이 99중량%를 초과하면 개선효과는 뚜렷하나 경제성이 떨어진다.The acrylic-urethane copolymer not only enhances warpage, tensile and adhesion strength by forming a polymer film inside the environmentally-friendly surface coating composition, but also improves durability due to the polymer film. The acrylic-urethane copolymer is preferably contained in an amount of 30 to 99% by weight based on the functional admixture. If the content of the acryl-urethane copolymer is less than 30% by weight, the effect of improving the strength and durability is deteriorated. If the content of the acrylic-urethane copolymer is more than 99% by weight, the improvement effect is obvious but economical.
상기 에폭시 에스테르 수지는 건조성, 도막경도, 내황변성, 열연화성을 향상시키기 위하여 첨가한다. 상기 에폭시 에스테르 수지은 상기 고성능 혼화제에 대하여 0.1∼30중량% 함유되는 것이 바람직하다. 상기 에폭시 에스테르 수지의 함량이 0.1중량% 미만이면 성능이 저하되고, 그 함량이 30중량%를 초과하면 성능은 개선되나 작업성이 저하된다. The epoxy ester resin is added in order to improve dryness, film hardness, vulcanization resistance, and heat-hardenability. The epoxy ester resin is preferably contained in an amount of 0.1 to 30% by weight based on the high performance admixture. When the content of the epoxy ester resin is less than 0.1% by weight, the performance is deteriorated. When the content is more than 30% by weight, the performance is improved but the workability is decreased.
상기 폴리메타크릴산메틸은 부착력 및 인성을 개선하기 위해서 사용된다. 상기 폴리메타크릴산메틸은 상기 기능성 혼화제에 대하여 0.01~30중량%함유되는 것이 바람직하며, 상기 폴리메타크릴산메틸의 함량이 30중량%를 초과하면 내충격성, 강성, 내약품성, 작업성, 인성 및 신장률이 증가하지만 경제적이지 못하며, 상기 폴리메타크릴산메틸의 함량이 0.01중량% 미만이면 인성, 신장률, 내충격성, 강성, 내약품성 및 작업성 개선 효과가 미약할 수 있다. The polymethyl methacrylate is used to improve adhesion and toughness. The methyl polymethacrylate is preferably contained in an amount of 0.01 to 30% by weight based on the functional admixture, and when the content of the polymethyl methacrylate exceeds 30% by weight, impact resistance, rigidity, chemical resistance, And the elongation is increased but it is not economical. If the content of the polymethyl methacrylate is less than 0.01% by weight, the effect of improving toughness, elongation, impact resistance, rigidity, chemical resistance and workability may be weak.
상기 폴리이소부틸렌은 인성, 신장률, 내충격성, 강성, 내약품성 및 작업성을 개선하기 위하여 사용된다. 상기 폴리이소부틸렌은 내충격성, 강성, 유동성 등이 뛰어나며, 치수안정성, 성형가공성, 내약품성 등의 제반특성도 매우 뛰어나고, 작업성이 편리하며, 가격 경쟁력이 좋은 장점을 가지고 있다. 상기 폴리이소부틸렌은 상기 기능성 혼화제에 대하여 0.01∼20중량% 함유되는 것이 바람직하며, 상기 폴리이소부틸렌의 함량이 20중량%를 초과하면 내충격성, 강성, 내약품성, 작업성, 인성 및 신장률이 증가하지만 경제적이지 못하며, 상기 폴리이소부틸렌의 함량이 0.01중량% 미만이면 인성, 신장률, 내충격성, 강성, 내약품성 및 작업성 개선 효과가 미약할 수 있다. The polyisobutylene is used to improve toughness, elongation, impact resistance, rigidity, chemical resistance and workability. The polyisobutylene is excellent in impact resistance, rigidity and fluidity, and has various advantages such as dimensional stability, molding processability, chemical resistance and the like, and is easy to work and has good price competitiveness. The polyisobutylene is preferably contained in an amount of 0.01 to 20 wt% with respect to the functional admixture. When the content of the polyisobutylene exceeds 20 wt%, impact resistance, rigidity, chemical resistance, workability, toughness and elongation But it is not economical. If the content of polyisobutylene is less than 0.01% by weight, the effect of improving toughness, elongation, impact resistance, rigidity, chemical resistance and workability may be weak.
상기 알콕시실릴이소시아누레이트는 유연성과 내한성을 개선하고 수지의 점도를 낮게 하여 작업성을 용이하게 하기 위하여 사용된다. 상기 알콕시실릴 이소시아누레이트는 상기 기능성 혼화제에 대하여 0.01∼20중량% 함유되는 것이 바람직하며, 상기 알콕시실릴 이소시아누레이트의 함량이 20중량%를 초과하면 유연하고 내한성 및 작업성은 좋아지나 재료분리 현상이 발생되기 쉽고, 상기 알콕시실릴 이소시아누레이트의 함량이 0.01중량% 미만이면 유연성, 내한성 및 작업성 개선 효과가 미약할 수 있다.The alkoxysilylisocyanurate is used to improve flexibility and cold resistance and lower the viscosity of the resin to facilitate workability. The alkoxysilyl isocyanurate is preferably contained in an amount of 0.01 to 20% by weight based on the functional admixture, and when the content of the alkoxysilyl isocyanurate exceeds 20% by weight, the alkoxysilyl isocyanurate is flexible and has good cold resistance and workability, If the content of the alkoxysilyl isocyanurate is less than 0.01% by weight, the effect of improving flexibility, cold resistance and workability may be weak.
상기 기능성 혼화제는 점도 및 유동성을 개선하기 위한 에틸셀롤로오스를 0.01∼10중량% 더 포함할 수 있다.The functional admixture may further contain 0.01 to 10% by weight of ethylcellulose to improve viscosity and fluidity.
또한, 상기 기능성 혼화제는 내유성, 내용제성, 내한성, 작업성을 개선하기 위하여 테트라플루오로에틸렌 0.01∼10중량% 더 포함할 수 있다.In addition, the functional admixture may further contain 0.01 to 10% by weight of tetrafluoroethylene to improve oil resistance, solvent resistance, cold resistance, and workability.
또한, 상기 기능성 혼화제는 붓자국, 로울러자국, 오렌지필(orange peal), 분화구현상(cratering), 핀홀(pin hole), 색얼룩 등의 표면에 생기는 결함을 방지하기 위하여 부틴디올(butindiol을 0.001∼10중량% 더 포함할 수 있다. The functional admixture may also contain butindiol in an amount of 0.001 to 10 wt% to prevent defects on the surface such as brush marks, roller marks, orange peal, cratering, pinhole, 10% by weight.
또한, 상기 기능성 혼화제는 접착력, 내마모성, 내한성 등을 개선하기 위하여 염화비닐-초산비닐 공중합체를 0.001~10중량% 더 포함할 수 있다.The functional admixture may further contain 0.001 to 10% by weight of a vinyl chloride-vinyl acetate copolymer in order to improve adhesion, abrasion resistance, cold resistance and the like.
또한, 상기 기능성 혼화제는 연행공기의 발생으로 인한 공기량의 증가를 감소시키기 위한 소포제 0.01∼10중량%를 더 포함할 수 있다.In addition, the functional admixture may further include 0.01 to 10% by weight of an antifoaming agent to reduce an increase in the amount of air due to generation of entrained air.
본 발명의 바람직한 실시예에 따른 다기능 친환경 표면 마감 코팅제 조성물은 상기 무기 충전재 5∼98중량%, 기능성 혼화제 1∼70중량% 및 물 1~30중량%을 혼합하여 소정시간 (예를 들어 1~5분간) 동안 교반하여 제조할 수 있다. The multifunctional environmentally friendly surface coating composition according to the present invention may be prepared by mixing 5 to 98% by weight of the inorganic filler, 1 to 70% by weight of the functional admixture and 1 to 30% by weight of water, Lt; / RTI > for a few minutes).
본 발명에 따른 다기능 친환경 표면 마감 코팅제 조성물을 이용한 콘크리트 구조물 표면 마감 코팅 방법은, 콘크리트 구조물의 레이턴스, 불순물 또는 열화부위를 그라인더, 평삭기, 연마기, 숏블라스터 등으로 치핑하여 제거하는 단계와, 치핑된 부위를 핸드 워터젯, 진공 흡입기 등으로 청소하는 단계와, 바탕 콘크리트 구조물과 상기 다기능 친환경 표면 마감 코팅제 조성물의 부착력을 개선하고, 물의 침투와 염소이온 침투를 억제하며, 내수성 및 방수성을 개선하기 위한 표면 침투제를 도포하는 단계와, 상기 다기능 친환경 표면 마감 코팅제 조성물을 붓, 롤러, 에어리스 등을 이용하여 살포하는 단계; 살포된 상기 다기능 친환경 표면 마감 코팅제 조성물 상부에 염해 저항성, 중성화 저항성, 표면 경도 개선, 방수성, 내수성을 개선하기 위하여 표면 강화제를 도포하는 단계; 및 양생하는 단계를 포함한다.The method of coating a surface of a concrete structure using a multifunctional environmentally friendly surface finish coating composition according to the present invention comprises the steps of chipping and removing a latent, an impurity or a deteriorated part of a concrete structure by a grinder, a planer, a grinder, a shot blaster, And a surface for improving the adhesion of the multi-functional eco-friendly surface-finishing coating composition to the base concrete structure, suppressing penetration of water and penetration of chlorine ions, and improving water resistance and waterproofness Applying a penetrating agent, and spraying the multifunctional environmentally friendly surface finish coating composition using a brush, roller, airless or the like; Applying a surface strengthening agent on top of the sprayed multifunctional eco-friendly surface finish coating composition to improve resistance to salt, neutralization resistance, surface hardness, water resistance and water resistance; And curing.
여기서, 상기 표면 침투제는 상기 기능성 혼화제를 고형분 10%이하로 조정하여 사용하는 것이 바람직하다.Herein, it is preferable that the surface-penetrating agent is used by adjusting the functional admixture to a solid content of 10% or less.
여기서, 상기 표면 강화제는 아크릴-우레탄, 실리카 무기질 표면 강화제, 실란계 침투강화제, 상기 기능성 혼화제 중 어느 하나 이상을 포함한 것을 사용하는 것이 바람직하다. Here, the surface strengthening agent is preferably one containing at least one of acryl-urethane, silica inorganic surface hardener, silane penetration enhancer, and functional admixture.
이하에서, 본 발명에 따른 다기능 친환경 표면 마감 코팅제 조성물의 실시예들을 더욱 구체적으로 제시하며, 다음에 제시하는 실시예들에 의하여 본 발명이 한정되는 것은 아니다. Hereinafter, embodiments of the multifunctional eco-friendly surface finish coating composition according to the present invention will be more specifically shown and the present invention is not limited by the following embodiments.
<실시예 1>≪ Example 1 >
무기 충전재 50중량%, 기능성 혼화제 40중량% 및 물 10중량%를 강제식 믹서로 2분간 교반하여 다기능 친환경 표면 마감 코팅제 조성물을 제조하였다. 50% by weight of inorganic filler, 40% by weight of functional admixture and 10% by weight of water were stirred with a forced mixer for 2 minutes to prepare a multifunctional environmentally friendly surface finish coating composition.
이때, 상기 무기 충전재는, 알루미나 시멘트 50중량%, 고로슬래그 미분말 10중량%, 글라스 버블 10중량%, 질석 5중량%, 견운모 분말 5중량%, 마그네슘알루미늄실리케이트 5중량%, 실리카질 규사 5중량%, 벤토나이트 5중량%, 산화 마그네슘 3중량%, 폴리에틸렌글리콜 0.5중량%, 지연제 0.5중량%, 폴리카본산계 감수제 0.5중량% 및 안료 0.5 중량%를 혼합하여 사용하였다. 이 때, 상기 지연제는 시트릭산을 사용하였다. At this time, the inorganic filler is composed of 50% by weight of alumina cement, 10% by weight of blast furnace slag, 10% by weight of glass bubble, 5% by weight of vermiculite, 5% by weight of sericite powder, 5% by weight of magnesium aluminum silicate, 5% by weight of bentonite, 3% by weight of magnesium oxide, 0.5% by weight of polyethylene glycol, 0.5% by weight of retarder, 0.5% by weight of a polycarboxylic acid-based water reducing agent and 0.5% by weight of pigment. At this time, citric acid was used as the retarder.
상기 기능성 혼화제는 아크릴-우레탄 공중합체 91중량%, 에폭시 에스테르 수지 2중량%, 폴리메타크릴산메틸 1중량%, 폴리이소부틸렌 1중량%, 알콕시실릴이소시아누레이트 1중량%, 테트라플루오로에틸렌 1중량%, 부틴디올(butindiol) 1중량%, 염화비닐-초산비닐 공중합체 1중량% 및 실리콘계 소포제 1중량%를 혼합하여 사용하였다. The functional admixture is composed of 91% by weight of an acryl-urethane copolymer, 2% by weight of an epoxy ester resin, 1% by weight of polymethyl methacrylate, 1% by weight of polyisobutylene, 1% by weight of alkoxysilylisocyanurate, 1% by weight of ethylene, 1% by weight of butindiol, 1% by weight of a vinyl chloride-vinyl acetate copolymer and 1% by weight of a silicone antifoaming agent were mixed and used.
<실시예 2>≪ Example 2 >
무기 충전재 50중량%, 기능성 혼화제 40중량% 및 물 10중량%를 강제식 믹서로 2분간 교반하여 다기능 친환경 표면 마감 코팅제 조성물을 제조하였다. 50% by weight of inorganic filler, 40% by weight of functional admixture and 10% by weight of water were stirred with a forced mixer for 2 minutes to prepare a multifunctional environmentally friendly surface finish coating composition.
이때, 상기 무기 충전재는, 알루미나 시멘트 50중량%, 고로슬래그 미분말 10중량%, 글라스 버블 10중량%, 질석 5중량%, 견운모 분말 5중량%, 마그네슘알루미늄실리케이트 5중량%, 실리카질 규사 5중량%, 벤토나이트 5중량%, 산화 마그네슘 3중량%, 폴리에틸렌글리콜 0.5중량%, 지연제 0.5중량%, 폴리카본산계 감수제 0.5중량% 및 안료 0.5 중량%를 혼합하여 사용하였다. 이 때, 상기 지연제는 시트릭산을 사용하였다. At this time, the inorganic filler is composed of 50% by weight of alumina cement, 10% by weight of blast furnace slag, 10% by weight of glass bubble, 5% by weight of vermiculite, 5% by weight of sericite powder, 5% by weight of magnesium aluminum silicate, 5% by weight of bentonite, 3% by weight of magnesium oxide, 0.5% by weight of polyethylene glycol, 0.5% by weight of retarder, 0.5% by weight of a polycarboxylic acid-based water reducing agent and 0.5% by weight of pigment. At this time, citric acid was used as the retarder.
상기 기능성 혼화제는 아크릴-우레탄 공중합체 85중량%, 에폭시 에스테르 수지 4중량%, 폴리메타크릴산메틸 2중량%, 폴리이소부틸렌 2중량%, 알콕시실릴이소시아누레이트 2중량%, 테트라플루오로에틸렌 2중량%, 부틴디올(butindiol) 1중량%, 염화비닐-초산비닐 공중합체 1중량% 및 실리콘계 소포제 1중량%를 혼합하여 사용하였다. The functional admixture was composed of 85% by weight of an acryl-urethane copolymer, 4% by weight of an epoxy ester resin, 2% by weight of polymethyl methacrylate, 2% by weight of polyisobutylene, 2% by weight of alkoxysilylisocyanurate, 2% by weight of ethylene, 1% by weight of butindiol, 1% by weight of a vinyl chloride-vinyl acetate copolymer and 1% by weight of a silicone antifoaming agent were mixed and used.
<실시예 3>≪ Example 3 >
무기 충전재 50중량%, 기능성 혼화제 40중량% 및 물 10중량%를 강제식 믹서로 2분간 교반하여 다기능 친환경 표면 마감 코팅제 조성물을 제조하였다. 50% by weight of inorganic filler, 40% by weight of functional admixture and 10% by weight of water were stirred with a forced mixer for 2 minutes to prepare a multifunctional environmentally friendly surface finish coating composition.
이때, 상기 무기 충전재는, 알루미나 시멘트 50중량%, 고로슬래그 미분말 10중량%, 글라스 버블 10중량%, 질석 5중량%, 견운모 분말 5중량%, 마그네슘알루미늄실리케이트 5중량%, 실리카질 규사 5중량%, 벤토나이트 5중량%, 산화 마그네슘 3중량%, 폴리에틸렌글리콜 0.5중량%, 지연제 0.5중량%, 폴리카본산계 감수제 0.5중량% 및 안료 0.5 중량%를 혼합하여 사용하였다. 이 때, 상기 지연제는 시트릭산을 사용하였다. At this time, the inorganic filler is composed of 50% by weight of alumina cement, 10% by weight of blast furnace slag, 10% by weight of glass bubble, 5% by weight of vermiculite, 5% by weight of sericite powder, 5% by weight of magnesium aluminum silicate, 5% by weight of bentonite, 3% by weight of magnesium oxide, 0.5% by weight of polyethylene glycol, 0.5% by weight of retarder, 0.5% by weight of a polycarboxylic acid-based water reducing agent and 0.5% by weight of pigment. At this time, citric acid was used as the retarder.
상기 기능성 혼화제는 아크릴-우레탄 공중합체 78중량%, 에폭시 에스테르 수지 5중량%, 폴리메타크릴산메틸 3중량%, 폴리이소부틸렌 3중량%, 알콕시실릴이소시아누레이트 3중량%, 테트라플루오로에틸렌 3중량%, 부틴디올(butindiol) 2중량%, 염화비닐-초산비닐 공중합체 2중량% 및 실리콘계 소포제 1중량%를 혼합하여 사용하였다. The functional admixture is composed of 78% by weight of an acrylic-urethane copolymer, 5% by weight of an epoxy ester resin, 3% by weight of polymethyl methacrylate, 3% by weight of polyisobutylene, 3% by weight of alkoxysilylisocyanurate, 3% by weight of ethylene, 2% by weight of butindiol, 2% by weight of a vinyl chloride-vinyl acetate copolymer and 1% by weight of a silicone antifoaming agent were mixed and used.
상술한 실시예 1 내지 실시예 3에 따라 제조된 다기능 친환경 표면 마감 코팅제 조성물의 물성과 비교하기 위하여, 현재 일반적으로 널리 사용되고 있는 마감재 조성물을 비교예 1로서 제시한다. In order to compare the physical properties of the multifunctional eco-friendly surface-finishing coating composition prepared according to the above-described Examples 1 to 3, the presently widely used finishing materials composition is shown as Comparative Example 1.
<비교예 1>≪ Comparative Example 1 &
보통 포틀랜드 시멘트 50중량%, 아크릴-우레탄 공중합체 40중량% 및 물 10중량%를 강제식 믹서로 2분간 교반하여 폴리머 마감재 조성물을 제조하였다. Usually, 50 wt% of Portland cement, 40 wt% of acryl-urethane copolymer and 10 wt% of water were stirred with a forced mixer for 2 minutes to prepare a polymer finishing composition.
<시험예 1> 시험용 공시체의 제작≪ Test Example 1 > Preparation of test specimens
상기 실시예 1 내지 3 및 비교예 1에서 제시한 배합에 따라 KS F 4936(콘크리트 보호용 도막재)에 의하여 제조하고, 치수 100×100mm(도막형성 후 겉모양), 100×100×100mm모르타르판(중성화깊이), 100×50mm모르타르판(염화물이온침투저항성), 150mm시험편(투습도), 150×40mm모르타르판(내투수성), 70×70×20mm모르타르판(부착강도)을 사용하여 시험체를 제작하였으며, 온도(20±2)℃, 습도(65±10)%로 양생하여 시험을 실시하였다. 또한, KS F 4919 (시멘트계 폴리머 혼입 방수재)에 의하여 인장성능, 내투수성 및 내알칼리성 시험을 실시하였다. Was prepared by KS F 4936 (coating material for concrete protection) according to the formulations shown in the above Examples 1 to 3 and Comparative Example 1, and a 100 × 100 mm (appearance after forming a film) and a 100 × 100 × 100 mm mortar plate (Depth of neutralization), 100 × 50 mm mortar plate (chloride ion penetration resistance), 150 mm test piece (moisture permeability), 150 × 40 mm mortar plate (water permeability) and 70 × 70 × 20 mm mortar plate (20 ± 2) ° C and humidity (65 ± 10)%, respectively. In addition, tensile performance, water permeability and alkali resistance test were conducted by KS F 4919 (cement-based polymer mixed waterproofing material).
<시험예 2> 도막형성후의 겉모양<Test Example 2> Appearance after Coating Film Formation
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1에 따라 제조된 조성물의 도막형성 후의 겉모양을 아래의 표 1에 나타내었다.The appearance of the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 after formation of the coating film is shown in Table 1 below.
상기 표 1에 나타난 바와 같이, 실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1에 따라 제조된 조성물 모두 도막형성 후의 겉모양은 이상 없이 나타났다. As shown in Table 1, the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 exhibited no abnormal appearance after coating film formation.
<시험예 3> 중성화 깊이≪ Test Example 3 >
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1에 따라 제조된 조성물의 중성화 깊이 시험을 수행하였고, 그 결과를 하기 표 2에 나타내었다.Neutralization depth tests of the compositions prepared according to Examples 1 to 3 and the compositions prepared according to Comparative Example 1 were carried out, and the results are shown in Table 2 below.
상기 표 2에 나타난 바와 같이, 실시예 1 내지 실시예 3에 따라 제조된 조성물은 비교예 1에 따라 제조된 조성물과 비교하여 중성화 저항성이 매우 우수함을 알 수 있었다.As shown in Table 2, the compositions prepared according to Examples 1 to 3 have excellent neutralization resistance as compared with the composition prepared according to Comparative Example 1.
<시험예 4> 염화물 이온 침투 저항성≪ Test Example 4 > Chloride ion penetration resistance
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1에 따라 제조된 조성물의 염화물 이온 침투 저항성 시험을 수행하였고, 그 결과를 하기 표 3에 나타내었다.The chloride ion penetration resistance test of the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 was carried out, and the results are shown in Table 3 below.
침투저항성
(Coulombs)Chloride ion
Penetration resistance
(Coulombs)
상기 표 3에 나타난 바와 같이, 실시예 1 내지 실시예 3에 따라 제조된 조성물은 비교예 1에 따라 제조된 조성물과 비교하여 매우 우수한 염화물 이온 침투 저항성을 나타내었다. As shown in Table 3, the compositions prepared according to Examples 1 to 3 exhibited excellent chloride ion penetration resistance as compared with the composition prepared according to Comparative Example 1. [
<시험예 5> 투습도≪ Test Example 5 >
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1 에 따라 제조된 조성물의 투습도를 측정하였고, 그 결과를 하기 표 4에 나타내었다.The moisture permeability of the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 were measured, and the results are shown in Table 4 below.
(g/m2ㅇ℃)Moisture permeability
(g / m 2 캜)
상기 표 4에 나타난 바와 같이, 본 발명의 실시예 1 내지 실시예 3에 따라 제조된 조성물은 비교예 1 에 따라 제조된 조성물과 비교하여 투습도가 낮게 나타났다. As shown in Table 4, the compositions prepared according to Examples 1 to 3 of the present invention showed lower moisture permeability than the compositions prepared according to Comparative Example 1. [
<시험예 6> 부착강도≪ Test Example 6 >
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1 에 의하여 제조된 조성물의 부착강도 시험을 수행하였고, 그 결과를 표 5에 나타내었다.Bond strength test of the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 was carried out, and the results are shown in Table 5.
(N/mm2)Bond strength
(N / mm 2 )
위의 표 5에서와 같이, 실시예 1 내지 실시예 3이 비교예 1에 비하여 높은 부착강도를 나타내는 것을 알 수 있었다. As shown in Table 5 above, it can be seen that Examples 1 to 3 exhibit a higher adhesive strength than Comparative Example 1.
<시험예 7> 인장성능Test Example 7 Tensile performance
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1에 따라 제조된 조성물의 인장성능 시험을 수행하였고, 그 결과를 하기 표 6에 나타내었다.The tensile performance tests of the compositions prepared according to Examples 1 to 3 and the compositions prepared according to Comparative Example 1 were carried out, and the results are shown in Table 6 below.
상기 표 6에 나타난 바와 같이, 실시예 1 내지 실시예 3에 따라 제조된 조성물이 비교예 1에 따라 제조된 조성물보다 인장성능이 우수함을 알 수 있었다.As shown in Table 6, it was found that the compositions prepared according to Examples 1 to 3 were superior in tensile performance to the compositions prepared according to Comparative Example 1.
<시험예 7> 내투수성Test Example 7: Permeability
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1 에 따라 제조된 조성물의 내투수성을 측정하였고, 그 결과를 하기 표 7에 나타내었다.The permeability of the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 was measured, and the results are shown in Table 7 below.
상기 표 7에 나타난 바와 같이, 본 발명의 실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1 에 따라 제조된 조성물 모두 내투수성이 우수함을 알 수 있었다. As shown in Table 7, it can be seen that the compositions prepared according to Examples 1 to 3 of the present invention and the compositions prepared according to Comparative Example 1 are excellent in permeability.
<시험예 8> 내알칼리성≪ Test Example 8 >
실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1 에 따라 제조된 조성물의 내알칼리성을 측정하였고, 그 결과를 하기 표 8에 나타내었다.The alkali resistance of the composition prepared according to Examples 1 to 3 and the composition prepared according to Comparative Example 1 was measured, and the results are shown in Table 8 below.
상기 표 8에 나타난 바와 같이, 본 발명의 실시예 1 내지 실시예 3에 따라 제조된 조성물과 비교예 1 에 따라 제조된 조성물 모두 내알칼리성이 우수함을 알 수 있었다. As shown in Table 8, it was found that the compositions prepared according to Examples 1 to 3 of the present invention and the compositions prepared according to Comparative Example 1 were excellent in alkali resistance.
이상, 본 발명의 바람직한 실시예를 들어 상세하게 설명하였으나, 본 발명은 상기 실시예에 한정되는 것은 아니며, 본 발명의 기술적 사상의 범위 내에서 당 분야에서 통상의 지식을 가진 자에 의하여 여러 가지 변형이 가능하다.While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, This is possible.
Claims (14)
무기 충전재 5∼98중량%, 기능성 혼화제 1∼70중량% 및 물 1~30중량%를 포함하며,
상기 기능성 혼화제는 아크릴-우레탄 공중합체 30∼99중량%, 에폭시 에스테르 수지 0.1∼25중량%, 폴리메타크릴산메틸 0.01∼25중량%, 폴리이소부틸렌 0.01~20중량% 및 알콕시실릴이소시아누레이트 0.01∼20중량%를 포함하는
것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
A multifunctional environmentally friendly surface finish coating composition for concrete structures,
5 to 98% by weight of an inorganic filler, 1 to 70% by weight of a functional admixture and 1 to 30% by weight of water,
Wherein the functional admixture comprises 30 to 99% by weight of an acrylic-urethane copolymer, 0.1 to 25% by weight of an epoxy ester resin, 0.01 to 25% by weight of polymethyl methacrylate, 0.01 to 20% by weight of polyisobutylene, 0.0 >%< / RTI >
≪ RTI ID = 0.0 > 1, < / RTI >
상기 기능성 혼화제는 점도 및 유동성을 개선하기 위한 에틸셀롤로오스를 0.01∼10중량% 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
The method according to claim 1,
Wherein the functional admixture further comprises 0.01 to 10% by weight of ethylcellulose for improving viscosity and fluidity.
상기 기능성 혼화제는 내유성, 내용제성, 내한성, 및 작업성을 개선하기 위하여 테트라플루오로에틸렌 0.01∼10중량% 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
The method according to claim 1,
Wherein the functional admixture further comprises 0.01 to 10% by weight of tetrafluoroethylene in order to improve oil resistance, solvent resistance, cold resistance, and workability.
상기 기능성 혼화제는 표면에 생기는 결함을 방지하기 위하여 부틴디올(butindiol을 0.001∼10중량% 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
The method according to claim 1,
Wherein the functional admixture further comprises 0.001 to 10 wt% of butindiol to prevent surface defects. ≪ RTI ID = 0.0 > 8. < / RTI >
상기 기능성 혼화제는 접착력, 내마모성, 및 내한성을 개선하기 위하여 염화비닐-초산비닐 공중합체를 0.001~10중량% 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
The method according to claim 1,
Wherein the functional admixture further comprises 0.001 to 10 wt% of a vinyl chloride-vinyl acetate copolymer to improve adhesion, abrasion resistance, and cold resistance.
상기 기능성 혼화제는 연행공기의 발생으로 인한 공기량의 증가를 감소시키기 위한 소포제 0.01∼10중량%를 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
The method according to claim 1,
Wherein the functional admixture further comprises from 0.01 to 10% by weight of an antifoaming agent to reduce an increase in the amount of air due to generation of entrained air.
상기 무기 충전재는 알루미나 시멘트 5∼90중량%, 분말도가 4,000 cm2/g이상인 고로슬래그 미분말 5∼40중량%, 글라스 버블 0.1~30중량%, 질석 0.1~30중량%, 견운모 분말 0.1~30중량%, 마그네슘알루미늄실리케이트 0.1∼20중량%, 실리카질 규사 0.1~20중량%, 벤토나이트 0.01~10중량% 및 산화 마그네슘 0.01∼10중량%를 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
The method according to claim 1,
The inorganic filler is 5 to 90% by weight of alumina cement, fineness is 4,000 cm 2 / g or more blast furnace slag 5 to 40% by weight of glass bubbles from 0.1 to 30% by weight, 0.1 to 30% by weight of vermiculite, sericite powder, 0.1 to 30 0.1 to 20% by weight of magnesium aluminosilicate, 0.1 to 20% by weight of silica silica, 0.01 to 10% by weight of bentonite and 0.01 to 10% by weight of magnesium oxide, based on the total weight of the composition.
상기 무기 충전재는 시멘트에 의해 수축되는 것을 억제하기 위한 폴리에틸렌글리콜 0.01∼10중량%를 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
8. The method of claim 7,
Wherein the inorganic filler further comprises 0.01 to 10% by weight of polyethylene glycol for inhibiting shrinkage by cement.
상기 무기 충전재는 시멘트 경화체의 내부 조직을 치밀하게 하여 수밀성 및 동결융해 저항성을 개선시키고 내구성을 증진시키기 위한 폴리카본산, 나프탈렌, 멜라민 및 리그닌 감수제 중에서 선택된 1종 이상의 물질 0.01∼10중량%를 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
8. The method of claim 7,
The inorganic filler further contains 0.01 to 10% by weight of at least one substance selected from the group consisting of polycarboxylic acid, naphthalene, melamine and lignin water reducing agents for improving the watertightness and freeze-thaw resistance and improving durability by tightening the internal structure of the cement hardened body Functional surface-finishing coating composition.
상기 무기 충전재는 급격하게 경화되는 것을 지연하기 위한 지연제 0.01∼10중량%를 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
8. The method of claim 7,
Wherein the inorganic filler further comprises 0.01 to 10% by weight of a retarding agent for delaying rapid curing.
상기 무기 충전재는 색상을 구현하고 미관을 개선하기 위한 안료 0.01~10 중량%를 더 포함하는 것을 특징으로 하는 다기능 친환경 표면 마감 코팅제 조성물.
8. The method of claim 7,
Wherein the inorganic filler further comprises 0.01 to 10% by weight of pigment for realizing hue and improving the appearance.
콘크리트 구조물 바탕면의 레이턴스, 불순물 또는 열화부위를 그라인더, 평삭기, 연마기, 또는 숏블라스터로 치핑하여 제거하고, 치핑된 부위를 청소하는 단계;
콘크리트 구조물 바탕면과 상기 다기능 친환경 표면 마감 코팅제 조성물의 부착력을 개선하고, 물의 침투와 염소이온 침투를 억제하며, 내수성 및 방수성을 개선하기 위한 표면 침투제를 도포하는 단계;
도포된 상기 표면 침투제 상부에 상기 다기능 친환경 표면 마감 코팅제 조성물을 살포하는 단계;
살포된 상기 다기능 친환경 표면 마감 코팅제 조성물 상부에 염해 저항성, 중성화 저항성, 표면 경도 개선, 방수성, 및 내수성을 개선하기 위하여 표면 강화제를 도포하는 단계; 및
양생하는 단계를
포함하는 것을 특징으로 하는 콘크리트 구조물 표면 마감 코팅 방법.
12. A method for surface finishing a concrete structure using the multifunctional eco-friendly surface-finishing coating composition according to any one of claims 1 to 11,
Removing a portion of the laitance, impurity, or deteriorated portion of the concrete structure by a grinder, a planer, a grinder, or a shot blaster, and cleaning the chipped portion;
Applying a surface penetrant to improve adhesion of the multi-functional eco-friendly surface finish coating composition to the concrete structure substrate, to inhibit water penetration and chlorine ion penetration, and to improve water resistance and water resistance;
Applying the multifunctional eco-friendly surface finish coating composition on top of the applied surface impermeant;
Applying a surface strengthening agent on the sprayed multi-functional environmentally-friendly surface coating composition to improve resistance to salt, neutralization resistance, surface hardness, water resistance, and water resistance; And
Curing step
The method of claim 1,
상기 표면 침투제는 상기 다기능 친환경 표면 마감 코팅제의 기능성 혼화제를 고형분을 10%이하로 조정한 것임을 특징으로 하는 콘크리트 구조물 표면 마감 코팅 방법.
13. The method of claim 12,
Wherein the surface wetting agent is a functional admixture of the multifunctional eco-friendly surface finish coating agent, the solid content of which is adjusted to 10% or less.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109231874A (en) * | 2018-09-21 | 2019-01-18 | 佛山齐安建筑科技有限公司 | A kind of concrete air-entrainer and preparation method thereof |
| KR102340245B1 (en) * | 2021-07-29 | 2021-12-17 | (주)성원이피에스 | 1 liquid type ceramic coating composition for construction |
| KR102352951B1 (en) * | 2021-08-20 | 2022-01-20 | (주)삼흥건설 | Finishing composition for protecting surface of concrete structure and steel structure having excellent visibility and finishing method for protecting surface of concrete structure and steel structure using the same |
| KR20220027369A (en) * | 2020-08-26 | 2022-03-08 | (주)인덱스글로벌 | Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same |
| CN114961145A (en) * | 2021-01-11 | 2022-08-30 | 上海伟星新材料科技有限公司 | Wall surface self-repairing method based on self-repairing polymer cement waterproof coating |
| KR102512161B1 (en) | 2022-05-02 | 2023-03-22 | (주)미지건설 | Construction method for repairing concrete structure using quick-hardening cement mortar composition and surface protection coating agent for self-healing and crack-reducing type repairs |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004293161A (en) | 2003-03-27 | 2004-10-21 | Showa Highpolymer Co Ltd | Floor covering construction method |
| JP2004352728A (en) | 1993-02-03 | 2004-12-16 | Ciba Specialty Chem Holding Inc | Electrodeposition coat/base coat/clear coat polishing material stabilized by s-triazine ultraviolet absorber |
-
2017
- 2017-07-04 KR KR1020170084906A patent/KR101807104B1/en active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004352728A (en) | 1993-02-03 | 2004-12-16 | Ciba Specialty Chem Holding Inc | Electrodeposition coat/base coat/clear coat polishing material stabilized by s-triazine ultraviolet absorber |
| JP2004293161A (en) | 2003-03-27 | 2004-10-21 | Showa Highpolymer Co Ltd | Floor covering construction method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109231874A (en) * | 2018-09-21 | 2019-01-18 | 佛山齐安建筑科技有限公司 | A kind of concrete air-entrainer and preparation method thereof |
| KR20220027369A (en) * | 2020-08-26 | 2022-03-08 | (주)인덱스글로벌 | Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same |
| KR102450685B1 (en) | 2020-08-26 | 2022-10-05 | (주)인덱스글로벌 | Composition of cement surface preparation compound for heat insulating material and Cement surface preparation compound for heat insulating material comprising the same |
| CN114961145A (en) * | 2021-01-11 | 2022-08-30 | 上海伟星新材料科技有限公司 | Wall surface self-repairing method based on self-repairing polymer cement waterproof coating |
| KR102340245B1 (en) * | 2021-07-29 | 2021-12-17 | (주)성원이피에스 | 1 liquid type ceramic coating composition for construction |
| KR102352951B1 (en) * | 2021-08-20 | 2022-01-20 | (주)삼흥건설 | Finishing composition for protecting surface of concrete structure and steel structure having excellent visibility and finishing method for protecting surface of concrete structure and steel structure using the same |
| KR102512161B1 (en) | 2022-05-02 | 2023-03-22 | (주)미지건설 | Construction method for repairing concrete structure using quick-hardening cement mortar composition and surface protection coating agent for self-healing and crack-reducing type repairs |
| CN115873428A (en) * | 2022-10-27 | 2023-03-31 | 陕西宝光陶瓷科技有限公司 | Coating solution for ceramic sintering cushion block and preparation method and application thereof |
| CN115873428B (en) * | 2022-10-27 | 2023-08-22 | 陕西宝光陶瓷科技有限公司 | Coating solution for ceramic sintering cushion block and preparation method and application thereof |
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