KR102448643B1 - 1,2,5,6-헥산테트롤(hto)의 테트라하이드로푸란 디카르복실산(thfdca)으로의 전환 - Google Patents

1,2,5,6-헥산테트롤(hto)의 테트라하이드로푸란 디카르복실산(thfdca)으로의 전환 Download PDF

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KR102448643B1
KR102448643B1 KR1020207032605A KR20207032605A KR102448643B1 KR 102448643 B1 KR102448643 B1 KR 102448643B1 KR 1020207032605 A KR1020207032605 A KR 1020207032605A KR 20207032605 A KR20207032605 A KR 20207032605A KR 102448643 B1 KR102448643 B1 KR 102448643B1
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acid
thfdca
catalyst
hto
anhydro
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KR20200135540A (ko
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치 쳉 마
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아처 다니엘 미드랜드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
KR1020207032605A 2018-04-13 2019-03-28 1,2,5,6-헥산테트롤(hto)의 테트라하이드로푸란 디카르복실산(thfdca)으로의 전환 Active KR102448643B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862657277P 2018-04-13 2018-04-13
US62/657,277 2018-04-13
PCT/US2019/024493 WO2019199468A1 (en) 2018-04-13 2019-03-28 Conversion of 1,2,5,6-hexanetetrol (hto) to tetrahydrofuran dicarboxylic acid (thfdca)

Publications (2)

Publication Number Publication Date
KR20200135540A KR20200135540A (ko) 2020-12-02
KR102448643B1 true KR102448643B1 (ko) 2022-09-28

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KR1020207032605A Active KR102448643B1 (ko) 2018-04-13 2019-03-28 1,2,5,6-헥산테트롤(hto)의 테트라하이드로푸란 디카르복실산(thfdca)으로의 전환

Country Status (8)

Country Link
US (1) US12024496B2 (https=)
EP (1) EP3774753B1 (https=)
JP (1) JP7071534B2 (https=)
KR (1) KR102448643B1 (https=)
CN (1) CN111971274B (https=)
BR (1) BR112020020667B1 (https=)
ES (1) ES2924952T3 (https=)
WO (1) WO2019199468A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113121477A (zh) * 2021-06-02 2021-07-16 宁波国生科技有限公司 一种2,5-四氢呋喃二甲酸的制备方法
CN116063258B (zh) * 2021-10-29 2025-03-11 中国石油化工股份有限公司 一种连续生产5-羟甲基糠醛和2,5-呋喃二甲酸的方法
EP4680600A1 (en) * 2023-03-16 2026-01-21 Specialty Operations France Method for producing tetrahydrofuran-2-carboxylic acid

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015156803A1 (en) 2014-04-10 2015-10-15 Archer Daniels Midland Company Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3001970B1 (fr) 2013-02-11 2015-02-27 Centre Nat Rech Scient Procede de preparation d'acide 2,5-furane dicarboxylique
MX2016000106A (es) 2013-06-28 2016-03-01 Archer Daniels Midland Co Tetrahidrofuran-2,5-dicarbaldehidos (diformiltetrahidrofurano, dfthf) y procesos para su sintesis.
US9593064B2 (en) * 2014-05-01 2017-03-14 Wisconsin Alumni Research Foundation Conversion of alcohols to alkyl esters and carboxylic acids using heterogeneous palladium-based catalysts
ES2830174T3 (es) * 2015-03-05 2021-06-03 Bp Corp North America Inc Síntesis de furanos a partir de azúcares a través de intermediarios ceto
WO2017061858A1 (en) 2015-10-05 2017-04-13 Avantium Knowledge Centre B.V. Process for the manufacture of an adipic acid product
FR3053336B1 (fr) * 2016-07-01 2018-09-21 Centre National De La Recherche Scientifique Procede de preparation de l'acide 2,5-furane dicarboxylique (fdca) a partir de derives de pentoses

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015156803A1 (en) 2014-04-10 2015-10-15 Archer Daniels Midland Company Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols

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Publication number Publication date
KR20200135540A (ko) 2020-12-02
ES2924952T3 (es) 2022-10-11
US20210032215A1 (en) 2021-02-04
US12024496B2 (en) 2024-07-02
EP3774753B1 (en) 2022-07-27
EP3774753A1 (en) 2021-02-17
BR112020020667A2 (pt) 2021-01-12
WO2019199468A1 (en) 2019-10-17
CN111971274B (zh) 2023-04-11
JP2021521117A (ja) 2021-08-26
JP7071534B2 (ja) 2022-05-19
BR112020020667B1 (pt) 2022-05-17
EP3774753A4 (en) 2021-05-19
CN111971274A (zh) 2020-11-20

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