KR102422635B1 - Thermoplastic ceramic ink composition containing nano-inorganic substances - Google Patents

Thermoplastic ceramic ink composition containing nano-inorganic substances Download PDF

Info

Publication number
KR102422635B1
KR102422635B1 KR1020210083054A KR20210083054A KR102422635B1 KR 102422635 B1 KR102422635 B1 KR 102422635B1 KR 1020210083054 A KR1020210083054 A KR 1020210083054A KR 20210083054 A KR20210083054 A KR 20210083054A KR 102422635 B1 KR102422635 B1 KR 102422635B1
Authority
KR
South Korea
Prior art keywords
weight
parts
ceramic ink
ink composition
ceramic
Prior art date
Application number
KR1020210083054A
Other languages
Korean (ko)
Inventor
박정선
Original Assignee
박정선
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박정선 filed Critical 박정선
Priority to KR1020210083054A priority Critical patent/KR102422635B1/en
Application granted granted Critical
Publication of KR102422635B1 publication Critical patent/KR102422635B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/322—Pigment inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes

Abstract

The present invention relates to a thermoplastic ceramic ink composition comprising nano-inorganic materials, and more particularly, to a thermoplastic ceramic ink composition comprising nano-inorganic materials which enables high-quality images to be printed on a surface of an interior and exterior finishing material by spraying ceramic ink on a surface of a natural stone or an artificial stone and a metal plate.

Description

나노무기물을 포함하는 열가소성 세라믹잉크 조성물{Thermoplastic ceramic ink composition containing nano-inorganic substances}Thermoplastic ceramic ink composition containing nano-inorganic substances

본 발명은 나노무기물을 포함하는 열가소성 세라믹잉크 조성물에 관한 것으로, 보다 상세하게는 세라믹잉크를 천연석이나 인조석 및 금속판 표면에 분사하여 고품질의 이미지를 내외부 마감재 표면에 인쇄할 수 있도록 한 나노무기물을 포함하는 열가소성 세라믹잉크 조성물에 관한 것이다.The present invention relates to a thermoplastic ceramic ink composition containing a nano-inorganic material, and more particularly, the ceramic ink is sprayed on the surface of natural or artificial stone and metal plate to print high-quality images on the surface of interior and exterior finishing materials. It relates to a thermoplastic ceramic ink composition.

세라믹잉크젯 프린터는 천연석이나 인조석 및 금속판과 같은 소재 표면에 세라믹잉크를 분사하여 고품질 이미지를 구현하는 인쇄장치이다.Ceramic inkjet printer is a printing device that realizes high-quality images by spraying ceramic ink on the surface of materials such as natural or artificial stones and metal plates.

그리고, 세라믹잉크젯 프린터에 사용되는 세라믹잉크는 변색이나 인체에 유해성이 거의 발생하지 않으며, 소재 표면에 세라믹잉크가 직접 분사되는 방식이어서 인쇄판의 제작이 불필요하고, 다색 인쇄도 단 한 번의 인쇄 작업으로 끝낼 수 있다는 이점이 있다.In addition, the ceramic ink used in ceramic inkjet printers rarely causes discoloration or harm to the human body, and since the ceramic ink is directly sprayed on the surface of the material, the production of a printing plate is unnecessary, and multi-color printing can be completed in just one printing operation. There are advantages to being able to

즉, 프린트 헤드로부터 분사되는 세라믹잉크의 액적 크기가 전압의 강약 조절을 통해 제어될 수 있기 때문에 세라믹잉크의 색이 몇 안 되어도 인쇄 소재 표면에 분사하는 세라믹잉크의 액적 크기나 개수를 조절하여 다양한 색상 표현이 가능하고, 비접촉 인쇄 방식이므로 요철이 있는 소재에 대해서도 인쇄 가능하다는 이점이 있다.In other words, since the size of the droplet of the ceramic ink sprayed from the print head can be controlled by adjusting the intensity of the voltage, even if the color of the ceramic ink is few, the size or number of the droplets of the ceramic ink sprayed on the surface of the printing material can be adjusted to provide various colors. It can be expressed and since it is a non-contact printing method, it has the advantage of being able to print even on uneven materials.

그런데, 종래 세라믹잉크는 분산성이 떨어져 엉겨 뭉치는 현상, 이로 인한 인쇄불량이 유발되고, 결국 인쇄 적정성을 떨어뜨리는 단점이 작용하고 있어 개선이 필요한 상황이다.However, conventional ceramic inks have poor dispersibility and agglomeration, resulting in printing defects, and eventually reducing print adequacy, which is a situation in need of improvement.

특히, 노즐 막힘현상에 따른 인쇄불량의 문제도 종종 발생하기도 한다.In particular, the problem of printing defects due to the clogging of the nozzles often occurs.

국내 특허 제10-2152600호(2020.09.01.) 소수성 세라믹잉크 조성물Domestic Patent No. 10-2152600 (2020.09.01.) Hydrophobic Ceramic Ink Composition 국내 특허 제10-2139518호(2020.07.24.) 글로시 세라믹잉크 조성물 및 그 제조방법Domestic Patent No. 10-2139518 (2020.07.24.) Glossy ceramic ink composition and its manufacturing method

본 발명은 상술한 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 세라믹잉크를 천연석이나 인조석 및 금속판 표면에 분사하여 고품질의 이미지를 내외부 마감재 표면에 인쇄할 수 있도록 한 나노무기물을 포함하는 열가소성 세라믹잉크 조성물을 제공함에 그 주된 목적이 있다.The present invention was created to solve the above-mentioned problems in the prior art, and by spraying ceramic ink on the surface of natural or artificial stones and metal plates to print high-quality images on the surface of interior and exterior finishing materials containing nano-inorganic materials Its main object is to provide a thermoplastic ceramic ink composition.

본 발명은 상기한 목적을 달성하기 위한 수단으로, 물 100중량부에 대해, 10-20nm의 입도를 갖는 세라믹 무기안료 30-40중량부, 콜로이드실리카 5-10중량부, 디페닐디에톡시실란(DPDES)과 이소시아누레이트(Isocyanurate)가 2:1의 중량비로 혼합된 혼합물 20-30중량부, 10-20nm의 입도를 갖는 실리카졸 5-10중량부 및, 10-20nm의 입도를 갖는 지르코니아 2-5중량부를 포함하는 것을 특징으로 하는 나노무기물을 포함하는 열가소성 세라믹잉크 조성물을 제공한다.The present invention is a means for achieving the above object, based on 100 parts by weight of water, 30-40 parts by weight of a ceramic inorganic pigment having a particle size of 10-20 nm, 5-10 parts by weight of colloidal silica, diphenyldiethoxysilane ( DPDES) and isocyanurate (Isocyanurate) are mixed in a weight ratio of 2:1 20-30 parts by weight of a mixture, 5-10 parts by weight of silica sol having a particle size of 10-20 nm, and zirconia having a particle size of 10-20 nm It provides a thermoplastic ceramic ink composition comprising a nano-inorganic material, characterized in that it contains 2-5 parts by weight.

삭제delete

삭제delete

본 발명에 따르면, 세라믹잉크를 천연석이나 인조석 및 금속판 표면에 분사하여 고품질의 이미지를 내외부 마감재 표면에 노즐 막힘없이 적정하게 인쇄할 수 있도록 하는 효과를 얻을 수 있다.According to the present invention, ceramic ink is sprayed on the surface of natural or artificial stone and metal plate to obtain an effect of properly printing high-quality images on the surface of the interior and exterior finishing materials without clogging the nozzles.

본 발명을 보다 구체적으로 설명하기 전에, 본 명세서 및 청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정되어서는 아니되며, 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다. Before describing the present invention in more detail, the terms or words used in the present specification and claims should not be limited to their ordinary or dictionary meanings, and the concept of terms should be properly explained in order to best describe the invention. Based on the principle that it can be defined, it should be interpreted as meaning and concept consistent with the technical idea of the present invention.

본 발명에 따른 나노무기물을 포함하는 열가소성 세라믹잉크 조성물은 물 100중량부에 대해, 10-20nm의 입도를 갖는 세라믹 무기안료 30-40중량부, 콜로이드실리카 5-10중량부, 디페닐디에톡시실란(DPDES)과 이소시아누레이트(Isocyanurate)가 2:1의 중량비로 혼합된 혼합물 20-30중량부, 10-20nm의 입도를 갖는 실리카졸 5-10중량부 및 10-20nm의 입도를 갖는 지르코니아 2-5중량부를 포함한다.The thermoplastic ceramic ink composition containing the nano-inorganic material according to the present invention is based on 100 parts by weight of water, 30-40 parts by weight of a ceramic inorganic pigment having a particle size of 10-20 nm, 5-10 parts by weight of colloidal silica, and diphenyldiethoxysilane 20-30 parts by weight of a mixture of (DPDES) and isocyanurate in a weight ratio of 2:1, 5-10 parts by weight of silica sol having a particle size of 10-20 nm, and zirconia having a particle size of 10-20 nm 2-5 parts by weight.

이때, 세라믹 무기안료는 레드, 블루, 엘로우, 블랙 등의 색상을 구현하기 위해 CoAl2O4계 분말, Mg1-xCoxAl2O4(0.1≤x≤1)계 분말, Mg1-xNixAl2O4(0.1≤x≤1)계 분말, Co(Fe1-xCrx)2O4(0.01≤x≤0.5)계 분말, Zr1-xCexSiO4(0.01≤x≤0.5)계 분말 중에서 선택되는 어느 하나 혹은 둘 이상의 조합일 수 있다.At this time, the ceramic inorganic pigment is a CoAl 2 O 4 based powder, Mg1-xCoxAl 2 O 4 (0.1≤x≤1) based powder, Mg1-xNixAl 2 O 4 ( Any one or a combination of two or more selected from 0.1≤x≤1)-based powder, Co(Fe1-xCrx) 2 O 4 (0.01≤x≤0.5)-based powder, and Zr1-xCexSiO 4 (0.01≤x≤0.5)-based powder can be

이 경우, 이러한 세라믹 무기안료는 이미 공지된 색상 구현용 성분들이다.In this case, these ceramic inorganic pigments are already known components for realizing color.

그리고, 콜로이드실리카는 무기물의 분산성 촉진 및 균일한 분산안정성을 유지하기 위해 첨가된다.In addition, colloidal silica is added to promote the dispersibility of inorganic substances and to maintain uniform dispersion stability.

또한, 디페닐디에톡시실란(DPDES)과 이소시아누레이트(Isocyanurate)가 2:1의 중량비로 혼합된 혼합물은 내열성과 내충격성 및 내후성을 증대시키기 위해 첨가되는 성분조합이다.In addition, a mixture of diphenyldiethoxysilane (DPDES) and isocyanurate in a weight ratio of 2:1 is a component combination added to increase heat resistance, impact resistance and weather resistance.

아울러, 실리카졸은 인쇄층의 완충 및 변형방지, 그리고 인쇄된 표면이 일광, 풍우, 무상, 한난, 건습 등의 자연의 작용에 저항하여 쉽게 변화하지 않는 성질인 내후성을 두텁게 보호하기 위해 첨가된다.In addition, the silica sol is added to protect the buffering and deformation prevention of the printed layer, and the weather resistance, which is a property that the printed surface does not easily change by resisting the action of nature such as sunlight, wind and rain, frost, cold and dryness, etc.

뿐만 아니라, 지르코니아는 인쇄 및 인쇄층의 내마모도를 증대시키기 위해 첨가된다.In addition, zirconia is added to increase the print and abrasion resistance of the printed layer.

덧붙여, 본 발명에서는 상기 물 100중량부에 대해, 오산화안티몬 10중량부, 비닐트리에톡시실란 10중량부 및 벤조구아나민 5중량부를 더 첨가할 수 있다.In addition, in the present invention, with respect to 100 parts by weight of the water, 10 parts by weight of antimony pentoxide, 10 parts by weight of vinyl triethoxysilane and 5 parts by weight of benzoguanamine may be further added.

이 경우, 오산화안티몬은 성분 교반시 급격한 겔화를 막으면서 교반물의 강도는 증대시키고 인쇄시 인쇄층의 내수성을 증대시킨다.In this case, antimony pentoxide increases the strength of the stirred material while preventing rapid gelation when the component is stirred, and increases the water resistance of the printed layer during printing.

그리고, 비닐트리에톡시실란(Vinyltriethoxysilane)은 잉크의 내열성, 내유성 및 인쇄 후 수축변형저항성을 증대시켜 인쇄 적정성을 높이게 된다.And, vinyltriethoxysilane (Vinyltriethoxysilane) increases the heat resistance, oil resistance, and shrinkage deformation resistance after printing of the ink, thereby increasing the printing adequacy.

또한, 벤조구아나민은 정전 특성을 유지하면서 부착력 안정화를 유지하기 위해 첨가된다.In addition, benzoguanamine is added to maintain adhesion stabilization while maintaining electrostatic properties.

이러한 조성물을 이용하여 세라믹잉크를 제조하는 방법은 다음과 같다.A method of manufacturing a ceramic ink using such a composition is as follows.

먼저, 잉크베이스 조성단계가 수행된다.First, the ink base composition step is performed.

상기 잉크베이스 조성단계는 상술한 물 100중량부를 기준으로 세라믹 무기안료 30-40중량부와, 콜로이드 실리카 5-10중량부를 교반기에 넣고 혼합 분산시켜 혼합물을 만드는 단계이다.The ink base composition step is a step of mixing and dispersing 30-40 parts by weight of the ceramic inorganic pigment and 5-10 parts by weight of colloidal silica in a stirrer based on 100 parts by weight of the above-described water to prepare a mixture.

이는 세라믹잉크의 기본성분들, 즉 잉크베이스를 먼저 균일하게 혼합 분산되게 하여 인쇄시 뭉침이나 노즐 토출 불량을 방지하기 위한 것이다.This is to prevent agglomeration or nozzle ejection failure during printing by uniformly mixing and dispersing the basic components of the ceramic ink, that is, the ink base first.

이어, 가수분해물 조성단계가 수행된다.Then, the hydrolyzate composition step is performed.

상기 가수분해물 조성단계는 세라믹잉크를 제조할 때 가수분해되게 하여 용질의 미립 안정화를 유지하고, 잉크의 특성을 강화시키는데 기능하도록 하기 위한 것이다.The hydrolyzate composition step is to make the ceramic ink hydrolyzed to maintain fine stabilization of the solute and to function to enhance the properties of the ink.

상기 가수분해물 조성단계는 디페닐디에톡시실란(DPDES)과 이소시아누레이트(Isocyanurate)를 2:1의 중량비로 혼합하여 혼합물 20-30중량부를 만드는 단계이다.The hydrolyzate composition step is a step of mixing diphenyldiethoxysilane (DPDES) and isocyanurate in a weight ratio of 2:1 to make 20-30 parts by weight of the mixture.

이때, 상기 혼합물에 물 100중량부를 기준으로 AP(Aliphatic polyester) 10중량부, 메타카올린 5중량부, 삼불화붕소아민착염 10중량부를 더 첨가할 수 있다.At this time, 10 parts by weight of aliphatic polyester (AP), 5 parts by weight of metakaolin, and 10 parts by weight of boron trifluoride amine complex salt may be further added to the mixture based on 100 parts by weight of water.

이 경우, AP(Aliphatic polyester)는 가수분해물의 저온 균일 분산성을 증대시키면서 고온 저항성을 유지시키고, 메타카올린(Metakaolin)은 가수분해 작용시 잉크의 수밀성 및 내구성을 증진시키며, 삼불화붕소아민착염은 가수분해 후 잉크 인쇄시 안정적인 점착강도와 내화학성을 유지시킨다.In this case, aliphatic polyester (AP) maintains high temperature resistance while increasing the low temperature uniform dispersibility of the hydrolyzate, metakaolin improves the watertightness and durability of the ink during hydrolysis, and boron trifluoride amine complex salt It maintains stable adhesive strength and chemical resistance when printing ink after hydrolysis.

이어, 세라믹잉크 제조단계가 수행된다.Then, the ceramic ink manufacturing step is performed.

상기 세라믹잉크 제조단계는 잉크베이스가 담겨 있는 교반기에 가수분해물을 넣고 50-60℃로 가열하면서 150-200rpm으로 5시간 동안 교반하면서 가수분해시켜 세라믹잉크로 안정화시키는 단계이다.The ceramic ink manufacturing step is a step of stabilizing the ceramic ink by putting the hydrolyzate into a stirrer containing the ink base and hydrolyzing it while stirring at 150-200 rpm for 5 hours while heating to 50-60°C.

삭제delete

이렇게 제조된 세라믹잉크를 세라믹 잉크젯 프린터로 인쇄해 본 결과, 기존 잉크 대비 노즐막힘 현상이 전혀 발생하지 않았다.As a result of printing the ceramic ink prepared in this way with a ceramic inkjet printer, there was no nozzle clogging compared to the conventional ink.

이는 인쇄시 퍼짐 정도, 인쇄 경화 후 탈락, 물 분사시 계면 탈락 등을 테스트함으로써 확인하였으며, 기존 대비 인쇄 퍼짐 현상이 발생하지 않았으며, 계면 탈락도 발생하지 않았다.This was confirmed by testing the degree of spread during printing, drop-off after printing hardening, and interface drop-off when spraying water.

Claims (2)

물 100중량부에 대해, 10-20nm의 입도를 갖는 세라믹 무기안료 30-40중량부, 콜로이드실리카 5-10중량부, 디페닐디에톡시실란(DPDES)과 이소시아누레이트(Isocyanurate)가 2:1의 중량비로 혼합된 혼합물 20-30중량부, 10-20nm의 입도를 갖는 실리카졸 5-10중량부 및, 10-20nm의 입도를 갖는 지르코니아 2-5중량부를 포함하는 나노무기물을 포함하는 열가소성 세라믹잉크 조성물에 있어서;
상기 열가소성 세라믹잉크 조성물에는 상기 물 100중량부를 기준으로 오산화안티몬 10중량부, 비닐트리에톡시실란 10중량부 및 벤조구아나민 5중량부가 더 첨가되어 조성된 것을 특징으로 하는 나노무기물을 포함하는 열가소성 세라믹잉크 조성물.Based on 100 parts by weight of water, 30-40 parts by weight of a ceramic inorganic pigment having a particle size of 10-20 nm, 5-10 parts by weight of colloidal silica, diphenyldiethoxysilane (DPDES) and isocyanurate (Isocyanurate) 2: 20-30 parts by weight of the mixture mixed in a weight ratio of 1, 5-10 parts by weight of silica sol having a particle size of 10-20 nm, and 2-5 parts by weight of zirconia having a particle size of 10-20 nm Thermoplastic containing nano-inorganic substances In the ceramic ink composition;
Thermoplastic ceramic containing nano-inorganic substances, characterized in that 10 parts by weight of antimony pentoxide, 10 parts by weight of vinyl triethoxysilane, and 5 parts by weight of benzoguanamine are further added to the thermoplastic ceramic ink composition based on 100 parts by weight of water ink composition. 삭제delete
KR1020210083054A 2021-06-25 2021-06-25 Thermoplastic ceramic ink composition containing nano-inorganic substances KR102422635B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020210083054A KR102422635B1 (en) 2021-06-25 2021-06-25 Thermoplastic ceramic ink composition containing nano-inorganic substances

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020210083054A KR102422635B1 (en) 2021-06-25 2021-06-25 Thermoplastic ceramic ink composition containing nano-inorganic substances

Publications (1)

Publication Number Publication Date
KR102422635B1 true KR102422635B1 (en) 2022-07-18

Family

ID=82700957

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020210083054A KR102422635B1 (en) 2021-06-25 2021-06-25 Thermoplastic ceramic ink composition containing nano-inorganic substances

Country Status (1)

Country Link
KR (1) KR102422635B1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63120772A (en) * 1986-11-10 1988-05-25 Takenaka Komuten Co Ltd Binder for ceramic paint
KR20140124783A (en) * 2012-01-19 2014-10-27 코닝 인코포레이티드 Method of decorating chemically strengthened glass
KR20200035513A (en) * 2018-09-27 2020-04-06 한국세라믹기술원 Ceramic ink composition having hydrophobicity
KR102139518B1 (en) 2018-08-14 2020-07-29 (주)한일 Glossy ceramic ink composition and manufacturing method of the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63120772A (en) * 1986-11-10 1988-05-25 Takenaka Komuten Co Ltd Binder for ceramic paint
KR20140124783A (en) * 2012-01-19 2014-10-27 코닝 인코포레이티드 Method of decorating chemically strengthened glass
KR102139518B1 (en) 2018-08-14 2020-07-29 (주)한일 Glossy ceramic ink composition and manufacturing method of the same
KR20200035513A (en) * 2018-09-27 2020-04-06 한국세라믹기술원 Ceramic ink composition having hydrophobicity
KR102152600B1 (en) 2018-09-27 2020-09-07 한국세라믹기술원 Ceramic ink composition having hydrophobicity

Similar Documents

Publication Publication Date Title
CN101120065B (en) Aqueous ink composition and urethane resin composition for aqueous ink composition
KR100518990B1 (en) Liquid Composition, Ink Set, Method of Forming Colored Portion in Recording Medium and Ink-Jet Rocording Apparatus
US6863391B2 (en) Liquid composition, ink set, method of forming a colored section on recording medium and ink-jet recording apparatus
EP3004264B1 (en) White inkjet ink
CN101108920A (en) High color density fine inorganic pigment, method for producing the same and inorganic pigment ink composition thereof
CN102959021A (en) Printing ink having enhanced gloss and lower viscosity
KR102422635B1 (en) Thermoplastic ceramic ink composition containing nano-inorganic substances
JP5038832B2 (en) Color material-containing composition, recording ink, ink cartridge, and image recording apparatus using the same
JP2008057131A (en) Decorative building board
JP5189610B2 (en) Designable building material and method for producing the same
JP4728802B2 (en) Building board manufacturing method
JP2002019268A (en) Ultrafine particle ceramic powder aggregate dispersed water for forming ink absorption layer of ink jet recording medium
KR101605365B1 (en) Printing device, printing method, and ink set
CN105131715A (en) Water ink for ceramic ink-jet printing and preparation method thereof
KR20190075226A (en) Glass-ceramic ink composition for inkjet printing and manufacturing method of the same
JP5054343B2 (en) Decorative building board
KR101365577B1 (en) Paint composite for glass printed silk screen and its manufacturing method
JP2018002786A (en) Ink, ink set, and image-forming set
CN115667386B (en) Aqueous polymer particle dispersions
KR102152600B1 (en) Ceramic ink composition having hydrophobicity
JP4100976B2 (en) Ink set for ink jet recording, ink jet recording method, ink cartridge, recording unit, and ink jet recording apparatus
JP5213306B2 (en) Image forming method
CN1974688A (en) Water-base pigment ink
JP4814735B2 (en) Decorative building board
JP5952610B2 (en) Manufacturing method of decorative building board

Legal Events

Date Code Title Description
E701 Decision to grant or registration of patent right
GRNT Written decision to grant