KR102314720B1 - Method for Manufacturing air filter for neutralization of antimicrobial and deodorant harmful components coated with metal silicon and air filter manufactured that method - Google Patents

Method for Manufacturing air filter for neutralization of antimicrobial and deodorant harmful components coated with metal silicon and air filter manufactured that method Download PDF

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KR102314720B1
KR102314720B1 KR1020190053205A KR20190053205A KR102314720B1 KR 102314720 B1 KR102314720 B1 KR 102314720B1 KR 1020190053205 A KR1020190053205 A KR 1020190053205A KR 20190053205 A KR20190053205 A KR 20190053205A KR 102314720 B1 KR102314720 B1 KR 102314720B1
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air filter
metal silicon
weight
manufacturing
parts
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KR20200128962A (en
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김수원
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0442—Antimicrobial, antibacterial, antifungal additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/045—Deodorising additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0471—Surface coating material
    • B01D2239/0492—Surface coating material on fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Filtering Materials (AREA)

Abstract

본 발명은 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법 및 그 제조방법에 의해 제조된 에어필터에 관한 것으로, 보다 상세하게는 메탈실리콘 럼프를 나노수준으로 분쇄하여 무기질의 바인더와 함께 성장이 완료된 섬유질 상에 확산 침입시켜 제조되며, 메탈실리콘의 99%를 차지하는 규소(Si)에서 생성되는 파동에너지에 의한 유해가스 중화작용을 이용하여 항균과 탈취 효과를 증대시킨 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법 및 그 제조방법에 의해 제조된 에어필터에 관한 것이다.The present invention relates to a method for manufacturing an air filter for neutralizing antibacterial and deodorizing harmful components to which metal silicon is adsorbed and applied, and an air filter manufactured by the manufacturing method, and more particularly, to an air filter manufactured by the manufacturing method, and more particularly, to an inorganic binder and Manufactured by diffusion invading onto the fibers that have grown together, silicon (Si), which accounts for 99% of metal silicon, uses the neutralizing action of harmful gas by wave energy generated by metal silicon, which has increased antibacterial and deodorizing effects, is applied by adsorption. It relates to an air filter manufacturing method for neutralizing antibacterial and deodorizing harmful components and an air filter manufactured by the manufacturing method.

Description

메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법 및 그 제조방법에 의해 제조된 에어필터{Method for Manufacturing air filter for neutralization of antimicrobial and deodorant harmful components coated with metal silicon and air filter manufactured that method}Method for Manufacturing air filter for neutralization of antimicrobial and deodorant harmful components coated with metal silicon and air filter manufactured that method }

본 발명은 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법 및 그 제조방법에 의해 제조된 에어필터에 관한 것으로, 보다 상세하게는 메탈실리콘 럼프를 나노수준으로 분쇄하여 무기질의 바인더와 함께 성장이 완료된 섬유질 상에 확산 침입시켜 제조되며, 메탈실리콘의 99%를 차지하는 규소(Si)에서 생성되는 파동에너지에 의한 유해가스 중화작용을 이용하여 항균과 탈취 효과를 증대시킨 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법 및 그 제조방법에 의해 제조된 에어필터에 관한 것이다.The present invention relates to a method for manufacturing an air filter for neutralizing antibacterial and deodorizing harmful components to which metal silicon is adsorbed and applied, and an air filter manufactured by the manufacturing method, and more particularly, to an air filter manufactured by the manufacturing method, and more particularly, to an inorganic binder and Manufactured by diffusion invading onto the fibers that have grown together, silicon (Si), which accounts for 99% of metal silicon, uses the neutralizing action of harmful gas by wave energy generated by metal silicon, which has increased antibacterial and deodorizing effects, is applied by adsorption. It relates to an air filter manufacturing method for neutralizing antibacterial and deodorizing harmful components and an air filter manufactured by the manufacturing method.

갈수록 늘어만 가고 있는 화석연료 사용의 자동차와 산업기계, 그리고 가정 및 산업용 보일러, 공장의 굴뚝 등에서 배출되는 매연으로 인해 공기중의 미세먼지와 악취는 그 농도를 더해하고 있어 실내외를 비롯한 그 어느 곳에서도 오염된 공기를 흡착 중화시켜 자연상태의 청정한 공기로 되돌려 줄 수 있는 에어필터가 내장된 공기청정기 혹은 마스크와 방독면 등이 절실하게 요구되는 시대이다.Due to the increasing number of fossil-fueled automobiles and industrial machinery, home and industrial boilers, and smoke emitted from factory chimneys, fine dust and odors in the air are increasing in concentration, polluting anywhere, including indoors and outdoors. In this era, an air purifier with a built-in air filter that can adsorb and neutralize the exhausted air and return it to the clean air in its natural state, or a mask and gas mask, is desperately needed.

통상, 공기의 오염물질을 여과하는 에어필터는 먼지와 티끌(PM)을 제거하는 단순 필터와, 냄새를 제거하는 탈취 필터, 그리고 세균, 담배연기, 곰팡이, 꽃가루 등을 제거하는 고밀도의 혜파 필터 등이 있다.In general, air filters that filter pollutants in the air include a simple filter that removes dust and dust (PM), a deodorization filter that removes odor, and a high-density filter that removes bacteria, cigarette smoke, mold, pollen, etc. There is this.

그러나, 도시의 대기오염 물질은 자동차의 배기가스와 각각의 주택과, 빌팅의 난방을 위한 보일러의 배출가스, 그리고 공장 굴뚝의 연기 등에서 미세먼지와 악취를 내뿜고 있고, 특히 이들이 배출하는 배출가스에는 인체 유해물질이면서 독성을 갖는 휘발성 유기화합물인 벤젠을 비롯한 포름알데히드, 일산화탄소와 탄화수소, 질소산화물, 이산화황, 황산화물 등이 포함되어 있어 단순 미세먼지만을 흡착하는 기능을 가진 에어필터로는 이들의 독성물질 등을 중화 내지 반감시킬 수 없는 한계에 있다.However, urban air pollutants emit fine dust and odors from automobile exhaust gas, exhaust gas from boilers for heating each house, building, and smoke from factory chimneys. As it contains formaldehyde, carbon monoxide and hydrocarbons, nitrogen oxides, sulfur dioxide and sulfur oxides, including benzene, which is a toxic and toxic volatile organic compound, an air filter with a function of adsorbing only simple fine dust is There is a limit that cannot neutralize or halve.

국내 공개특허 제10-2019-0002770호(2019-01-09), 활성탄소 이용 정전 에어 필터 및 그 제조 방법Domestic Patent Publication No. 10-2019-0002770 (2019-01-09), an electrostatic air filter using activated carbon and a manufacturing method thereof 국내 등록특허 제10-1867522호(2018-06-07), 탄소나노소재가 적용된 캐빈에어필터의 제조방법 및 이에 의해 제조된 탄소나노소재가 적용된 캐빈에어필터Domestic Registered Patent No. 10-1867522 (2018-06-07), manufacturing method of cabin air filter to which carbon nano material is applied, and cabin air filter to which carbon nano material is applied

본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 메탈실리콘 럼프를 나노수준으로 분쇄하여 무기질의 바인더와 함께 성장이 완료된 섬유질 상에 확산 침입시켜 제조되며, 메탈실리콘의 99%를 차지하는 규소(Si)에서 생성되는 파동에너지에 의한 유해가스 중화작용을 이용하여 항균과 탈취 효과를 증대시킨 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법 및 그 제조방법에 의해 제조된 에어필터를 제공함에 그 주된 목적이 있다.The present invention was created to solve the problems in the prior art as described above, and is manufactured by pulverizing metal silicon lumps to a nano level and spreading and invading onto the grown fibers together with an inorganic binder, metal silicon A method of manufacturing an air filter for neutralizing antibacterial and deodorizing harmful components adsorbed and coated with metal silicon that has increased antibacterial and deodorizing effects using the neutralization action of harmful gas by the wave energy generated from silicon (Si), which accounts for 99% of the Its main object is to provide an air filter manufactured by

또한, 본 발명은 이 에어필터를 자동차 엔진의 에어클리너 필터로도 전환시켜 사용케함으로써 엔진에 흡기되는 공기가 화석연료의 연소과정에서 연소효율을 높이는데 기여하고, 이를 통해 연비향상과 매연 저감에 일조하며, 특히 미세먼지 발생을 감소시키는데 기여할 수 있도록 함에 그 다른 목적이 있다.In addition, the present invention uses this air filter by converting it into an air cleaner filter of an automobile engine, so that the air sucked into the engine contributes to increasing the combustion efficiency in the combustion process of fossil fuels, thereby improving fuel efficiency and reducing smoke. It has another purpose, in particular, to contribute to reducing the generation of fine dust.

본 발명은 상기한 목적을 달성하기 위한 수단으로, 환원된 메탈실리콘 러프를 크러셔로 부순 후 다시 롤링분쇄기에서 분쇄하여 파우더로 만드는 파쇄 및 분말화단계; 상기 파우더를 수집한 후 나노분쇄기에 넣고 분쇄하여 메탈실리콘 나노분말을 만드는 나노분말화 단계; 상기 메탈실리콘 나노분말과 규산나트륨 및 물을 4:1:5의 중량비로 혼합하여 괴는 겔화단계; 메탈실리콘 나노분말 겔을 순면, 부직포, 화학섬유 중 어느 하나의 표면에 침적시켜 고정, 건조하는 단계;를 포함하는 것을 특징으로 하는 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법을 제공한다.The present invention is a means for achieving the above object, crushing and pulverizing the reduced metal silicon rough with a crusher and then pulverizing again in a rolling grinder to make a powder; a nano-powdering step of collecting the powder and then putting it in a nano-pulverizer and pulverizing it to make a metal silicon nano-powder; a gelation step of mixing the metal silicon nanopowder, sodium silicate, and water in a weight ratio of 4:1:5; Metal silicon nano-powder gel is deposited on the surface of any one of pure cotton, non-woven fabric, and chemical fiber, fixed and dried. to provide.

이때, 상기 겔화 단계에서, 메틸실리콘 나노분말 겔 100중량부에 대해 폴리옥시알킬렌 트리올 25중량부와, 레조시놀 5중량부와, 이소퀴놀린 알칼로이드 20중량부와, 에레몰 25중량부를 더 첨가한 후 30-40rpm으로 저속교반하는 단계를 더 수행하는 것에도 그 특징이 있다.At this time, in the gelation step, 25 parts by weight of polyoxyalkylene triol, 5 parts by weight of resorcinol, 20 parts by weight of an isoquinoline alkaloid, and 25 parts by weight of eremol based on 100 parts by weight of the methylsilicon nanopowder gel. It is also characterized by further performing the step of low-speed stirring at 30-40 rpm after addition.

또한, 상기에 기재된 제조방법으로 제조된 것을 특징으로 하는 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터도 제공한다.In addition, there is also provided an air filter for neutralizing antibacterial and deodorizing harmful components to which metal silicon is adsorbed and coated, characterized in that it is manufactured by the manufacturing method described above.

본 발명에 따르면, 메탈실리콘 럼프를 나노수준으로 분쇄하여 무기질의 바인더와 함께 성장이 완료된 섬유질 상에 확산 침입시켜 제조되며, 메탈실리콘의 99%를 차지하는 규소(Si)에서 생성되는 파동에너지에 의한 유해가스 중화작용을 이용하여 항균과 탈취 효과를 증대시킨 효과를 얻을 수 있다.According to the present invention, it is manufactured by pulverizing metal silicon lumps to a nano level and diffusing into the grown fibers together with an inorganic binder. By using gas neutralization, the effect of increasing antibacterial and deodorizing effects can be obtained.

이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in more detail.

본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Prior to the description of the present invention, the following specific structural or functional descriptions are only exemplified for the purpose of describing embodiments according to the concept of the present invention, and embodiments according to the concept of the present invention may be implemented in various forms, It should not be construed as limited to the embodiments described herein.

또한, 본 발명의 개념에 따른 실시예는 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있으므로, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경물, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.In addition, since the embodiment according to the concept of the present invention may have various changes and may have various forms, it should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention. .

먼저, 본 발명의 이해를 위해 메탈실리콘의 99%를 차지하는 순수 규소(Si)에 대해 알아본다.First, for understanding of the present invention, pure silicon (Si), which occupies 99% of silicon metal, will be described.

규소 또는 실리콘은 화학원소로 기호는 Si, 원자번호는 14이다.Silicon or silicon is a chemical element with the symbol Si and atomic number 14.

또한, 4가 준금속으로 탄소보다는 반응성이 떨어지고 저마늄 보다는 반응성이 크다. 지구의 지각에서 산소 다음으로 많은 원소로 질량의 27.7%를 차지하며, 점토나 모래, 석영, 장석, 화강암 등의 형태로 산출되며, 산소와 친화력이 강해서 주로 이산화규소나 규산염 상태를 하고 있어 자연에서 생성되는 순수 형태의 규소는 쉽게 발견되지 않는다.In addition, as a tetravalent metalloid, it is less reactive than carbon and more reactive than germanium. It is the second most abundant element in the earth's crust after oxygen, accounting for 27.7% of the mass, and is produced in the form of clay, sand, quartz, feldspar, granite, etc. Silicon in its pure form is not easily found.

순수한 규소는 다른 원자와 공유할 수 있는 원자가 전자가 4개인 준금속 원소로 다양한 화학결합을 할 수 있다. 규소는 탄소와 같은 4족에 포함되지만 규소가 탄소보다 약 1.5배 더 큰 공유결합을 갖는다. 그리고, 전기음성도도 규소가 탄소의 경우보다 이중결합 및 3중 결합을 만드는 경향이 적으며, 탄소에 없는 빈 궤도를 갖고 있기 때문에 다른 원자의 전자를 끌어 들이려는 경향이 크다.Pure silicon is a metalloid element with four valence electrons that can be shared with other atoms and can form various chemical bonds. Silicon is included in the same group 4 as carbon, but silicon has about 1.5 times greater covalent bonding than carbon. Also, in electronegativity, silicon has less tendency to form double and triple bonds than carbon, and since it has an empty orbital that does not exist in carbon, it tends to attract electrons from other atoms.

규소와 탄소 두 원자각을 같으나 규소의 공유결합 반경이 더 큰 것을 볼 수 있다. 규소에는 트리메틸실란이란 성분이 있는데 이를 추출하여 미래 연료로 사용하기 위한 연구가 진행되고 있으며, 이를 사용한 규소 연료는 공기중의 80%를 차지하는 질소와 화합해 에너지를 발생시킨 후 실리지움이라는 물질을 배출하게 된다.It can be seen that silicon and carbon have the same atomic angle, but the covalent radius of silicon is larger. There is a component called trimethylsilane in silicon, and research is being conducted to extract it and use it as a fuel in the future. The silicon fuel using this combines with nitrogen, which accounts for 80% of the air, to generate energy, and then emits a substance called silium. will do

그런데, 실리지움은 식물의 성장을 돕는 비료로 쓰이거나 암모니아를 회수하면 연료로 다시 사용할 수 있다고 노르웨이, 독일 등의 학회에서 이미 발표된 바 있다.However, it has already been announced at conferences in Norway and Germany that psyllium can be used as a fertilizer to help plants grow or can be reused as fuel by recovering ammonia.

또한, 희토류 없이도 고속 충방전과 높은 싸이클 특성을 보이는 이차전지도 개발중에 있으며, 규소는 컴퓨터나 태양전지에 사용되는 반도체의 대표적인 소재이다.In addition, secondary batteries that exhibit high-speed charge/discharge and high cycle characteristics without rare earths are also under development, and silicon is a representative material of semiconductors used in computers and solar cells.

최근에는 규소에서 1초간 1조회 진동하는 테라헤르츠, 즉 전파와 원적외선의 중간에 해당하는 진동에너지를 동시에 발산하는 것으로 확인되어 그 쓰임재가 갈수록 다양화되고 있다.Recently, it has been confirmed that silicon emits terahertz vibrating 1 trillion times per second, that is, vibration energy that is halfway between radio waves and far-infrared rays.

그러나, 규소는 산소와 친화력이 강해 모래, 석영, 차돌(규석) 등의 형태로 산출되어 이산화규소나 규산염 상태를 하고 있을 뿐 자연에서 순수 형태로 발견되기가 극히 어렵기 때문에 규소를 얻기 위해서는 이산화규소를 환원시켜야 한다.However, since silicon has a strong affinity for oxygen, it is produced in the form of sand, quartz, marble, etc., and is in the form of silicon dioxide or silicate, but it is extremely difficult to find in a pure form in nature. should be returned

이때, 규사는 모래나 차돌 등에서 추출하고, 탄소는 코크스나 검탄을 이용하여 환원시키면 된다. 즉, 아크로에 규사, 코크스나 검탄을 넣고 고전류를 흘려 고온으로 올리면 환원반응이 일어나면서 액체 규소가 형성되고, 이산화탄소와 실리카 증기 등이 부산물로 생성되며, 용융된 규소를 응고시키면 순도 96-99%의 금속 규소를 얻게 된다.At this time, silica sand may be extracted from sand or marble, and carbon may be reduced using coke or gum coal. That is, when silica sand, coke or gum coal is put into an arc furnace and a high current is applied to raise it to a high temperature, a reduction reaction occurs and liquid silicon is formed, carbon dioxide and silica vapor are produced as by-products, and when molten silicon is solidified, the purity is 96-99% of metallic silicon is obtained.

본 발명은 이렇게 환원되어 생성된 금속 규소, 즉 메탈실리콘을 사용하여 에어필터를 제조하는데 특징이 있다.The present invention is characterized in that the air filter is manufactured using the metal silicon produced by the reduction, that is, metal silicon.

즉, 본 발명에 따른 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터는 다음과 같이 제조된다.That is, the air filter for neutralizing antibacterial and deodorizing harmful components to which metal silicon is adsorbed and applied according to the present invention is manufactured as follows.

먼저, 파쇄 및 분말화단계가 수행된다.First, crushing and pulverizing steps are performed.

상기 파쇄 및 분말화단계는 환원된 메탈실리콘 러프를 크러셔로 잘게 부순 후 다시 롤링분쇄기에서 분쇄하여 파우더로 만드는 단계이다.The crushing and pulverizing step is a step of crushing the reduced metal silicon rough with a crusher and then pulverizing it again in a rolling crusher to make a powder.

이렇게 하여, 파우더, 즉 분말화되면 이어 나노분말화 단계가 수행된다.In this way, a powder, ie, powdered, is followed by a nanopulverization step.

상기 나노분말화 단계는 파우더를 수집한 후 나노분쇄기에 넣고 분쇄하여 메탈실리콘 나노분말을 만드는 단계이다.The nano-pulverization step is a step of collecting the powder and then putting it in a nano-pulverizer and pulverizing it to make a metal silicon nano-powder.

이후, 메탈실리콘 나노분말과 무기바인더 및 물을 4:1:5의 중량비로 혼합하여 괴는 겔화단계를 수행한다.Thereafter, the metal silicon nanopowder, the inorganic binder, and water are mixed in a weight ratio of 4:1:5 to perform a gelation step.

이때, 상기 무기바인더(Inorganic Binder)는 액상의 규산나트륨이 바람직하다. 이 규산나트륨은 물과 잘 섞이며, 메탈실리콘 나노분말을 끈적거리게 만들어 겔화시킨다.In this case, the inorganic binder is preferably liquid sodium silicate. This sodium silicate mixes well with water and makes the metal silicon nanopowder sticky and gels.

그런 다음, 성장이 완료된 섬유질 상에 침적시켜 고정, 건조하는 단계를 거친다.Then, it is immersed on the growth-completed fibers, fixed and dried.

상기 고정, 건조단계는 성장이 완료된 섬유질 상, 이를 테면 순면 혹은 부직포 혹은 각종 화학섬유에 겔화된 메탈실리콘 나노분말을 코팅하여 에어필터 원단을 만드는 단계이다.The fixing and drying step is a step of making an air filter fabric by coating the gelled metal silicon nanopowder on the grown fibrous phase, for example, pure cotton or non-woven fabric or various chemical fibers.

이후, 이 에어필터 원단을 이중원단으로 만들어 에어마스크로 사용하거나 혹은 또다른 가공을 통해 매트재로 사용하거나 혹은 다른 가공을 통해 냉장고용 탈취제로 사용하거나 혹은 또다른 가공을 통해 방진마스크나 방독면 혹은 자동차용 에어크리너로 사용할 수 있다.After that, this air filter fabric is made into a double fabric and used as an air mask, or as a mat material through another processing, or as a deodorant for a refrigerator through another processing, or as a dust mask, gas mask, or automobile through another processing. It can be used as an air cleaner for

이와 같이,본 발명은 기본 원단을 만들고, 그 원단 자체에 특징이 있는 것이며, 그것을 이용하여 다양한 용도로 활용되는 것까지 구체적으로 설명할 필요는 없다할 것이다.As such, the present invention makes a basic fabric, and the fabric itself has characteristics, and it will not be necessary to explain in detail how it is utilized for various purposes.

이때, 상기 무기질 바인더 대신 식물성 바인더를 사용할 수 있으며, 이 경우 식물성 고유의 향과 색감을 넣을 수 있다.In this case, a vegetable binder may be used instead of the inorganic binder, and in this case, a plant-specific fragrance and color may be added.

덧붙여, 본 발명에서는 항균성과 탈취효과를 더욱 극대화시키기 위해 상기 겔화 단계에서 메틸실리콘 나노분말 겔 100중량부에 대해 폴리옥시알킬렌 트리올 25중량부와, 레조시놀 5중량부와, 이소퀴놀린 알칼로이드 20중량부와, 에레몰 25중량부를 더 첨가한 후 30-40rpm으로 저속교반하는 단계를 추가로 수행할 수 있다.In addition, in the present invention, 25 parts by weight of polyoxyalkylene triol, 5 parts by weight of resorcinol, and isoquinoline alkaloid with respect to 100 parts by weight of methylsilicon nanopowder gel in the gelation step in order to further maximize the antibacterial and deodorizing effect After adding 20 parts by weight and 25 parts by weight of eremol, a step of low-speed stirring at 30-40 rpm may be additionally performed.

이때, 상기 폴리옥시알킬렌 트리올은 정포제로서의 기능을 통해 세균 활성을 억제함과 함께 가교성 증대를 통한 바인딩력을 높이고, 습열내구성 및 내충격성을 향상시키기 위해 첨가된다.In this case, the polyoxyalkylene triol is added to suppress bacterial activity through its function as a foam stabilizer, increase binding force through cross-linking, and improve wet heat durability and impact resistance.

또한, 상기 레조시놀(Resorcinol)은 습윤 및 건조강도를 높이고, 고온 저항성이 커 가교강도를 유지하면서 탈취력을 높이는데 기여하게 된다.In addition, the resorcinol (Resorcinol) contributes to increase the wet and dry strength, high temperature resistance, while maintaining the cross-linking strength to increase the deodorizing power.

아울러, 상기 이소퀴놀린 알칼로이드는 항균성과 면역성을 강화시키는 천연 항균제로서 암팔라야(Bitter Melon), 황련 뿌리, 매발톱나무 뿌리에서 추출되는 추출물로서 곰팡이는 물론 살모넬라균 등 널리 알려진 균류에 대한 천연항균성이 매우 뛰어난 항균제이다.In addition, the isoquinoline alkaloid is a natural antibacterial agent that strengthens antibacterial properties and immunity. It is an extract extracted from Bitter Melon, Yellow Lotus root, and Barberry root. It is an excellent antibacterial agent.

뿐만 아니라, 상기 에레몰(elemol)은 천연 항균기능은 물론 탈취효과와 함께 은은한 향이 방출되게 하여 공기정화 기능을 달성하기 위해 첨가된다.In addition, the elemol (elemol) is added to achieve an air purification function by releasing a mild fragrance with a deodorizing effect as well as a natural antibacterial function.

여기에서, 상기와 같이 성분 추가후에는 저속으로 교반해야 하는 이유는 이미 겔화가 진행되고 있기 때문에 이들을 풀어주면서 재 바인딩이 균질하게 이루어지도록 하기 위함이다.Here, the reason for stirring at a low speed after adding the components as described above is to make re-binding homogeneously while releasing them because gelation is already in progress.

또한, 본 발명에서는 미세 공극 유지를 통해 유해가스 중화 탈취력을 높이고, 아울러 상온 상태에서도 원적외선 방출 특성을 높이기 위해 상기 겔화 단계에서 메틸실리콘 나노분말 겔 100중량부에 대해 나노급으로 분쇄된 귀양석 분말 10중량부와, 하이드롤라이즈드케라틴 5중량부와, 나노급으로로 분쇄된 케나프 숯 분말 10중량부와, 나노급으로 분쇄된 백토분말 10중량부를 더 첨가 혼합할 수 있다.In addition, in the present invention, in order to increase the deodorization ability of neutralizing harmful gases by maintaining micropores, and also to increase the far-infrared emission characteristics even at room temperature, in the gelation step, 10 parts by weight of the methylsilicon nanopowder gel, pulverized to a nano level with respect to 100 parts by weight of the methylsilicon powder. Parts by weight, 5 parts by weight of hydrolyzed keratin, 10 parts by weight of kenaf charcoal powder pulverized to nano grades, and 10 parts by weight of white clay powder pulverized to nano grades may be further added and mixed.

이때, 귀양석은 상온에서도 원적외선을 96% 방출하는 천연석이며, 미세한 3차원 망목구조를 갖기 때문에 혼합시 미세 공극을 유지함으로써 유해가스 포집 능력을 높여 그 제거기능 및 탈취 기능을 더욱 강화시킬 수 있다.At this time, Guiyangseok is a natural stone that emits 96% of far-infrared rays even at room temperature, and since it has a fine three-dimensional network structure, it maintains micropores during mixing to increase the ability to capture harmful gases and further strengthen its removal and deodorization functions.

그리고, 하이드롤라이즈드케라틴는 혼합물 중 나노분말 입자를 감싸 피막을 형성함으로써 슬립성을 높이고, 유해물질 탈리 특성을 높이게 된다.In addition, the hydrolyzed keratin wraps the nanopowder particles in the mixture to form a film, thereby increasing the slip property and improving the desorption properties of harmful substances.

또한, 케나프 숯은 케나프를 탄화시켜 만든 것으로서, 케나프(Hibiscus cannabinus L.)는 보통 섬유를 얻을 목적으로 인도, 방글라데시, 태국 등에서 재배되고 있는 양마(洋麻)로서 활성산소의 작용을 억제하는 항산화물질이 다량 함유되어 있어 항염, 항바이러스 기능 및 탈취효과가 우수한 것으로 보고되어 있다. In addition, kenaf charcoal is made by carbonizing kenaf, and kenaf (Hibiscus cannabinus L.) is a sheep horse cultivated in India, Bangladesh, Thailand, etc. for the purpose of obtaining fibers, and suppresses the action of active oxygen. It is reported to have excellent anti-inflammatory, antiviral and deodorizing effects as it contains a large amount of antioxidants.

뿐만 아니라, 백토(Terra abla)는 카올린과 몬모릴론석을 주체로 하는 백색 점토를 가리키지만, 몬모릴론석질 점토인 산성 백토가 바람직하며, 강한 흡착성과 살충성이 있기 때문에 탈취, 정화 기능에 뛰어난 특성을 제공한다.In addition, Terra abla refers to white clay mainly composed of kaolin and montmorillon stone, but acid clay, which is montmorillon stone clay, is preferable. provides characteristics.

이하, 실시예에 대하여 설명한다.Hereinafter, an Example is demonstrated.

[실시예 1][Example 1]

상술한 제조방법으로 제조하여 에어필터 원단을 만들었다.The air filter fabric was manufactured by the manufacturing method described above.

[실시예 2][Example 2]

실시예 1의 제조과정중 겔화 단계에서, 메틸실리콘 나노분말 겔 100중량부에 대해 폴리옥시알킬렌 트리올 25중량부와, 레조시놀 5중량부와, 이소퀴놀린 알칼로이드 20중량부와, 에레몰 25중량부를 더 첨가한 후 30-40rpm으로 저속교반하는 단계를 더 수행하여 에어필터 원단을 만들었다.In the gelation step of the manufacturing process of Example 1, 25 parts by weight of polyoxyalkylene triol, 5 parts by weight of resorcinol, 20 parts by weight of an isoquinoline alkaloid, and eremol based on 100 parts by weight of methylsilicon nanopowder gel After adding 25 parts by weight, a low-speed stirring step of 30-40 rpm was further performed to make an air filter fabric.

[실시예 3][Example 3]

실시예 2와 동일하게 하되, 나노급으로 분쇄된 귀양석 분말 10중량부와, 하이드롤라이즈드케라틴 5중량부와, 나노급으로로 분쇄된 케나프 숯 분말 10중량부, 나노급으로 분쇄된 백토분말 10중량부를 더 첨가하였다.In the same manner as in Example 2, but 10 parts by weight of guiyangseok powder pulverized to a nano level, 5 parts by weight of hydrolyzed keratin, 10 parts by weight of kenaf charcoal powder pulverized to a nano level, and pulverized to a nano level An additional 10 parts by weight of white clay powder was added.

이렇게 제조된 실시예1,2,3의 에어필터 원단이 항균성이 있는지 확인하기 위해 각 에어필터 원단 표면에 곰팡이균과 포도상구균(Staphylococcus aureus)을 각각 나누어 분무한 후 20일간 방치하여 이들 균의 활성여부를 확인하였다.In order to check whether the air filter fabrics of Examples 1, 2, and 3 prepared in this way have antibacterial properties, mold and Staphylococcus aureus were sprayed separately on the surface of each air filter fabric, and then left for 20 days to activate the bacteria. It was checked whether

확인 결과, 20일 경과 후 곰팡이균 및 포도상구균의 활성도가 떨어졌다. 가장 높은 항균활성을 보인 것은 실시예 3의 에어필터 원단이었고, 그 뒤를 이어 실시예 2,1 순서였다. 이를 통해, 항균성이 있는 것으로 확인되었다.As a result of the confirmation, the activity of fungi and staphylococcus decreased after 20 days. It was the air filter fabric of Example 3 that showed the highest antibacterial activity, followed by Examples 2 and 1 in the order. Through this, it was confirmed that there is an antibacterial property.

또한, 탈취 효과를 확인하기 위해 20cm × 20cm × 15cm 크기의 투명한 박스를 3개 제작한 다음, 각 박스에 상기 실시예 1,2,3의 원단을 넣고, 박스 내부를 담배연기로 가득채우고 밀폐한 다음 담배연기가 사라지는데까지 걸리는 시간을 측정하였다.In addition, in order to check the deodorization effect, three transparent boxes of 20 cm × 20 cm × 15 cm were made, and then the fabrics of Examples 1, 2, and 3 were put in each box, and the inside of the box was filled with cigarette smoke and sealed. The time it takes for the next cigarette smoke to disappear was measured.

실험결과, 실시예 1은 1시간 40분, 실시예 2는 1시간 15분, 실시예 3은 58분 만에 담배연기가 완전히 제거되었다. 이 경우, 비교를 위해 활성탄이 들어 있는 시판중인 마스크를 비교예로 사용하였다. 비교예는 1시간 55분이 경과하자 담배연기의 2/3가 사라졌고, 희미하게 조금 남아 있었다.As a result of the experiment, the cigarette smoke was completely removed in Example 1 in 1 hour 40 minutes, Example 2 in 1 hour 15 minutes, and Example 3 in 58 minutes. In this case, a commercially available mask containing activated carbon was used as a comparative example for comparison. In the comparative example, 2/3 of the cigarette smoke disappeared after 1 hour and 55 minutes had elapsed, and a little faint remained.

이를 통해, 본 발명에 따른 에어필터 원단의 탈취효능이 있음을 분명히 확인하였다.Through this, it was clearly confirmed that there is a deodorizing effect of the air filter fabric according to the present invention.

뿐만 아니라, 원적외선 방출 기능을 확인하기 위해, FT-IR 스펙트로메터를 이용하여 KFIA-F1-1005에 의거 실시예 1,2,3시료에 대한 원적외선 방사시험을 실시하였다.In addition, in order to confirm the far-infrared emission function, a far-infrared radiation test was performed on the samples of Examples 1, 2, and 3 according to KFIA-F1-1005 using an FT-IR spectrometer.

실시결과, 30℃에서 원적외선 방사율은 각각 0.817, 0.829, 0.848로 확인되었고, 방사에너지(W/㎡)도 2.48×102, 2.51×102, 2.66×102으로 각각 나타나 원적외선 방사효과가 있는 것으로 확인되었다.As a result, the far-infrared emissivity at 30°C was confirmed to be 0.817, 0.829, and 0.848, respectively, and the radiant energy (W/m2) was also 2.48×10 2 , 2.51×10 2 , and 2.66×10 2 , respectively, indicating that there is a far-infrared radiation effect. Confirmed.

Claims (3)

환원된 메탈실리콘 러프를 크러셔로 부순 후 다시 롤링분쇄기에서 분쇄하여 파우더로 만드는 파쇄 및 분말화단계;
상기 파우더를 수집한 후 나노분쇄기에 넣고 분쇄하여 메탈실리콘 나노분말을 만드는 나노분말화 단계;
상기 메탈실리콘 나노분말과 규산나트륨 및 물을 4:1:5의 중량비로 혼합하여 괴는 겔화단계;
메탈실리콘 나노분말 겔을 순면, 부직포, 화학섬유 중 어느 하나의 표면에 침적시켜 고정, 건조하는 단계;를 포함하는 것을 특징으로 하는 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법.
Crushing and pulverizing the reduced metal silicon rough with a crusher and then pulverizing again in a rolling mill to make powder;
a nano-powdering step of collecting the powder and then putting it in a nano-pulverizer and pulverizing it to make a metal silicon nano-powder;
a gelation step of mixing the metal silicon nanopowder, sodium silicate, and water in a weight ratio of 4:1:5;
A method of manufacturing an air filter for neutralizing antibacterial and deodorizing harmful components adsorbed with metal silicon, comprising the step of immersing a metal silicon nano powder gel on the surface of any one of pure cotton, non-woven fabric, and chemical fiber, fixing and drying.
 청구항 1에 있어서,
상기 겔화 단계에서, 메틸실리콘 나노분말 겔 100중량부에 대해 폴리옥시알킬렌 트리올 25중량부와, 레조시놀 5중량부와, 이소퀴놀린 알칼로이드 20중량부와, 에레몰 25중량부를 더 첨가한 후 30-40rpm으로 저속교반하는 단계를 더 수행하는 것을 특징으로 하는 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터 제조방법.
The method according to claim 1,
In the gelation step, 25 parts by weight of polyoxyalkylene triol, 5 parts by weight of resorcinol, 20 parts by weight of an isoquinoline alkaloid, and 25 parts by weight of eremol were further added to 100 parts by weight of the methylsilicon nanopowder gel. After that, a method of manufacturing an air filter for neutralizing antibacterial and deodorizing harmful ingredients coated with metal silicon by adsorption, characterized in that further performing the step of low-speed stirring at 30-40 rpm.
 청구항 1 또는 2에 기재된 제조방법으로 제조된 것을 특징으로 하는 메탈실리콘이 흡착 도포된 항균 탈취 유해성분 중화용 에어필터.
An air filter for neutralizing antibacterial, deodorizing and harmful ingredients coated with metal silicon by adsorption, characterized in that it is manufactured by the manufacturing method according to claim 1 or 2.
KR1020190053205A 2019-05-07 2019-05-07 Method for Manufacturing air filter for neutralization of antimicrobial and deodorant harmful components coated with metal silicon and air filter manufactured that method KR102314720B1 (en)

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Citations (2)

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JP2011236070A (en) 2010-05-07 2011-11-24 National Institute Of Advanced Industrial Science & Technology Filter for warming fluid and method for manufacturing the same
JP2018027885A (en) 2016-08-18 2018-02-22 耀南 葉 Terahertz composite material and method for producing the same

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JP2018027885A (en) 2016-08-18 2018-02-22 耀南 葉 Terahertz composite material and method for producing the same

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