KR102306864B1 - Kits for disinfection using chlorine dioxide fumigation - Google Patents
Kits for disinfection using chlorine dioxide fumigation Download PDFInfo
- Publication number
- KR102306864B1 KR102306864B1 KR1020200171416A KR20200171416A KR102306864B1 KR 102306864 B1 KR102306864 B1 KR 102306864B1 KR 1020200171416 A KR1020200171416 A KR 1020200171416A KR 20200171416 A KR20200171416 A KR 20200171416A KR 102306864 B1 KR102306864 B1 KR 102306864B1
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- South Korea
- Prior art keywords
- acid
- kit
- sugar
- chlorine dioxide
- weight
- Prior art date
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 130
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 65
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 65
- 238000003958 fumigation Methods 0.000 title claims abstract description 47
- 238000004659 sterilization and disinfection Methods 0.000 title abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 39
- 229960002218 sodium chlorite Drugs 0.000 claims description 39
- 239000002253 acid Substances 0.000 claims description 25
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 21
- 239000008103 glucose Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 235000015165 citric acid Nutrition 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 claims description 2
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229930091371 Fructose Natural products 0.000 claims description 2
- 239000005715 Fructose Substances 0.000 claims description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 claims description 2
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 235000010323 ascorbic acid Nutrition 0.000 claims description 2
- 239000011668 ascorbic acid Substances 0.000 claims description 2
- 229960005070 ascorbic acid Drugs 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 235000012907 honey Nutrition 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 239000008101 lactose Substances 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001542 oligosaccharide Polymers 0.000 claims description 2
- 150000002482 oligosaccharides Chemical class 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 229940116269 uric acid Drugs 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 abstract description 19
- 239000008213 purified water Substances 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 239000002510 pyrogen Substances 0.000 description 7
- OEMUKJZHMHTYSL-UHFFFAOYSA-N [Na].OCl=O Chemical compound [Na].OCl=O OEMUKJZHMHTYSL-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 206010037660 Pyrexia Diseases 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 239000000411 inducer Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/02—Inorganic materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/02—Inorganic materials
- A61L2101/06—Inorganic materials containing halogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/32—Organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/32—Organic compounds
- A61L2101/36—Carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/32—Organic compounds
- A61L2101/46—Macromolecular compounds
- A61L2101/50—Polysaccharides or derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/11—Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/15—Biocide distribution means, e.g. nozzles, pumps, manifolds, fans, baffles, sprayers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/20—Targets to be treated
- A61L2202/25—Rooms in buildings, passenger compartments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
- A61L2209/211—Use of hydrogen peroxide, liquid and vaporous
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- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
본 발명은 이산화염소 훈증소독용 키트에 관한 것이다.The present invention relates to a kit for fumigation of chlorine dioxide.
이산화염소(Chlorine Dioxide; ClO2)는 수용액의 상태나 기체 형태로 소독, 탈취, 표백 작용을 하는 물질로, 전염병 발생 공간, 환자의 입원 공간, 미생물 실험 공간, 대형의료장비, 실험동물 사육 공간 등 의료 관련 시설과 축사, 온실, 식품저장 창고, 동식물 검역시설 등 농축산 관련 시설 및 각종 교통수단의 내 외부의 등의 소독과 탈취에 사용할 수 있다.Chlorine Dioxide (ClO 2 ) is a substance that disinfects, deodorizes, and bleaches in the form of an aqueous solution or gas. It can be used for disinfection and deodorization of medical-related facilities, livestock houses, greenhouses, food storage warehouses, animal and plant-related facilities such as animal and plant quarantine facilities, and inside and outside of various means of transportation.
아염소산나트륨과 산을 혼합하면 이산화염소 기체가 발생하는 것은 알려져 있다. 대한민국 특허 제10-1500418호는 아염소산나트륨에 염산을 첨가하면 이산화염소 기체가 발생하는 젤타입의 이산화염소 살균장치를 개시한다. 또한, 대한민국 특허 제10-1628936호는 아염소산나트륨에 구연산을 첨가하여 이산화염소 기체를 발생시키는 이산화염소 생성장치를 개시한다. 그러나 상기 특허를 비롯하여 기존의 이산화염소 기체를 발생시키는 제품들은 이산화염소 기체가 발생하더라도 이산화염소 기체의 확산이 제대로 이루어지지 않고 용기의 주변으로만 이산화염소 기체가 발산되어 일정 공간 전체를 소독하기 위한 수단으로는 충분하지 않았다.It is known that when sodium chlorite and acid are mixed, chlorine dioxide gas is generated. Korean Patent No. 10-1500418 discloses a gel-type chlorine dioxide sterilizer that generates chlorine dioxide gas when hydrochloric acid is added to sodium chlorite. In addition, Korean Patent No. 10-1628936 discloses a chlorine dioxide generator for generating chlorine dioxide gas by adding citric acid to sodium chlorite. However, the existing products that generate chlorine dioxide gas, including the above patent, do not properly diffuse chlorine dioxide gas even if chlorine dioxide gas is generated, and chlorine dioxide gas is emitted only to the periphery of the container. was not enough.
본 발명자들은 이러한 한계점을 극복하기 위하여, 종래 기술과 같이 아염소산나트륨에 산을 첨가하는 대신, 당 희석액과 발열제(가열유도제)를 첨가하고, 발열제에 물을 가하면 이산화염소 기체 발생반응이 매우 활발하게 일어나면서 반응용기가 놓인 공간 전체를 효과적으로 소독할 수 있는 공간소독에 적합한 이산화염소 훈증소독 키트와 훈증소독 방법을 개발하였다(대한민국 특허 제10-2149117호). 그러나, 본 발명자들이 개발한 상기 이산화염소 훈증소독 키트는 보관 및 사용상의 안전성을 위하여 키트의 구성요소인 아염소산나트륨, 당 용액, 발열제(가열유도제), 및 발열제의 발열반응 개시용 물을 모두 별도로 포장하여야 했으므로 키트의 생산과 포장도 번거롭고, 키트를 사용하는 방법도 각 구성의 포장을 제거하고 혼합한 후에 물을 부어 넣어야 하는 등, 매우 번거롭다는 단점이 있었다.In order to overcome this limitation, the present inventors, instead of adding an acid to sodium chlorite as in the prior art, add a sugar diluent and a heat generating agent (heating inducer), and add water to the heat generating agent, so that chlorine dioxide gas generation reaction is very active. We developed a chlorine dioxide fumigation kit and fumigation method suitable for space disinfection that can effectively disinfect the entire space where the reaction vessel is placed (Korean Patent No. 10-2149117). However, in the chlorine dioxide fumigation kit developed by the present inventors, sodium chlorite, sugar solution, exothermic agent (heating inducer), and water for initiating exothermic reaction of the exothermic agent, which are components of the kit, are all separately separated for safety in storage and use. Since it had to be packaged, the production and packaging of the kit was cumbersome, and the method of using the kit had the disadvantage that it was very cumbersome, such as removing the packaging of each component and pouring water after mixing.
이에 따라, 기존의 훈증소독 키트와 같이 생산된 이산화염소 기체의 휘산성이 우수하여 일정 공간 전체를 소독할 수 있는 효과는 그대로 유지하면서도, 제조 및 사용법이 간편한 개선된 형태의 훈증소독 키트에 대한 개발에 대한 필요성이 제기되었다. Accordingly, development of an improved fumigation kit that is easy to manufacture and use while maintaining the effect of sterilizing the entire space due to excellent volatilization of chlorine dioxide gas produced like the existing fumigation kit The need has been raised for
본 발명자들은 종래보다 개선된 이산화염소 훈증을 이용한 소독용 키트를 개발하고자 예의 연구 노력하였다. 그 결과 발열제를 첨가하지 않고도 소량의 산과 당을 첨가하면 매우 간단한 방법으로 안전하게 고농도의 이산화염소 기체를 발생시킬 수 있으며, 제품의 생산과 포장까지도 간편해지는 것을 확인하고 본 발명을 완성하였다. The present inventors made intensive research efforts to develop a disinfection kit using chlorine dioxide fumigation, which is improved compared to the prior art. As a result, if a small amount of acid and sugar are added without adding a heating agent, a high concentration of chlorine dioxide gas can be safely generated in a very simple way, and it was confirmed that the production and packaging of the product is simplified, and the present invention was completed.
본 발명의 목적은 이산화염소 훈증소독용 키트를 제공하는 것이다. It is an object of the present invention to provide a kit for fumigation of chlorine dioxide.
본 발명의 다른 목적은 이산화염소 훈증소독용 키트의 사용방법을 제공하는 것이다. Another object of the present invention is to provide a method of using a kit for fumigation of chlorine dioxide.
본 발명의 또 다른 목적은 이산화염소 훈증소독용 키트의 제조방법을 제공하는 것이다.Another object of the present invention is to provide a method for manufacturing a kit for fumigation of chlorine dioxide.
본 발명의 일 양태에 따르면, 본 발명은 아염소산나트륨; 당; 산; 및 물을 포함하는 이산화염소 훈증소독용 키트를 제공한다.According to one aspect of the present invention, the present invention is sodium chlorite; Party; Mountain; And it provides a kit for fumigation of chlorine dioxide containing water.
본 명세서에서 용어, "훈증소독"은 유효 성분이 기체 상태로 공중으로 휘산하여 일정한 공간이나 지역을 소독(살균, 표백 및 탈취 등)하는 작용을 나타내는 과정을 의미한다.As used herein, the term "fumigation disinfection" refers to a process in which an active ingredient vaporizes in the air in a gaseous state to disinfect a certain space or area (sterilization, bleaching, deodorization, etc.).
본 명세서에 일 구현예에 나타낸 바와 같이, 본 발명의 아염소산나트륨을 당, 산, 및 물을 포함하는 용액에 첨가하여 혼합하면 이산화염소 기체가 매우 활발하게 발생하면서 반응이 일어나는 공간 전체로 이산화염소 기체가 발산된다. As shown in one embodiment herein, when sodium chlorite of the present invention is added to a solution containing sugar, acid, and water and mixed, chlorine dioxide gas is very actively generated and chlorine dioxide is absorbed into the entire space in which the reaction occurs. gas is emitted.
본 발명의 일 구현예에 있어서, 상기 당은 포도당, 설탕, 유당, 맥아당, 과당, 올리고당, 덱스트린 및 벌꿀로 이루어진 군으로부터 선택된 적어도 1 이상인 것을 특징으로 한다. In one embodiment of the present invention, the sugar is characterized in that at least one or more selected from the group consisting of glucose, sugar, lactose, maltose, fructose, oligosaccharide, dextrin and honey.
본 발명의 훈증소독 키트는, 본 발명자들이 이전에 개발한 발열제를 포함하는 훈증소독 키트와 비교하여 산 성분을 추가적으로 포함한다. The fumigation kit of the present invention additionally includes an acid component as compared to a fumigation kit including a pyrogen developed by the present inventors previously.
본 발명의 일 구현예에 있어서, 상기 산은 구연산, 젖산, 아세트산, 포름산, 시트르산, 주석산, 옥살산, 아스코르브산, 요산, 뷰티르산, 스테아르산, 및 프로피온산으로 이루어진 군으로부터 선택된 적어도 1 이상의 유기산일 수 있다.In one embodiment of the present invention, the acid may be at least one organic acid selected from the group consisting of citric acid, lactic acid, acetic acid, formic acid, citric acid, tartaric acid, oxalic acid, ascorbic acid, uric acid, butyric acid, stearic acid, and propionic acid. .
본 발명의 다른 구현예에 있어서, 상기 산은 염산, 질산, 인산, 황산, 붕산, 및 플루오린화 수소산으로 이루어진 군으로부터 선택된 적어도 1 이상의 무기산일 수 있다. In another embodiment of the present invention, the acid may be at least one inorganic acid selected from the group consisting of hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, boric acid, and hydrofluoric acid.
본 발명의 또 다른 구현예에 있어서, 상기 산은 상술한 유기산, 무기산, 또는 이들의 조합일 수 있다. In another embodiment of the present invention, the acid may be the above-described organic acid, inorganic acid, or a combination thereof.
본 발명의 일 구현예에 있어서, 상기 훈증소독 키트에 포함되는 당 및 물의 중량비는 10:0.1 내지 10일 수 있다.In one embodiment of the present invention, the weight ratio of sugar and water included in the fumigation kit may be 10:0.1 to 10.
본 발명의 구체적인 구현예에 있어서, 상기 훈증소독 키트에 포함되는 당 및 물의 중량비는 10:0.1 내지 100, 10:0.1 내지 90, 10:0.1 내지 80, 10:0.1 내지 70, 10:0.1 내지 60, 10:0.1 내지 50, 10:0.1 내지 40, 10:0.1 내지 30, 10:0.1 내지 20, 10:0.1 내지 10, 10:0.1 내지 5, 또는 10:0.1 내지 1일 수 있고, 10:0.5 내지 100, 10:0.5 내지 90, 10:0.5 내지 80, 10:0.5 내지 70, 10:0.5 내지 60, 10:0.5 내지 50, 10:0.5 내지 40, 10:0.5 내지 30, 10:0.5 내지 20, 10:0.5 내지 10, 10:0.5 내지 5, 또는 10:0.5 내지 1일 수 있고, 10:1 내지 100, 10:1 내지 90, 10:1 내지 80, 10:1 내지 70, 10:1 내지 60, 10:1 내지 50, 10:1 내지 40, 10:1 내지 30, 10:1 내지 20, 또는 10:1 내지 10일 수 있고, 보다 구체적으로는 10:0.1 내지 10, 10:0.1 내지 9, 10:0.1 내지 8, 10:0.1 내지 7, 10:0.1 내지 6, 10:0.1 내지 5, 10:0.1 내지 4, 10:0.1 내지 3, 10:0.1 내지 2, 10:0.1 내지 1이거나, 10:1 내지 10, 10:1 내지 9, 10:1 내지 8, 10:1 내지 7, 10:1 내지 6, 10:1 내지 5, 10:1 내지 4, 10:1 내지 3, 10:1 내지 2, 10:9, 10:8, 10:7, 10:6, 10:5, 10:4, 10:3, 10:2, 10:1, 10:0.5, 또는 10:0.1 일 수 있으나, 이에 한정되는 것은 아니다.In a specific embodiment of the present invention, the weight ratio of sugar and water included in the fumigation kit is 10:0.1 to 100, 10:0.1 to 90, 10:0.1 to 80, 10:0.1 to 70, 10:0.1 to 60 , 10:0.1 to 50, 10:0.1 to 40, 10:0.1 to 30, 10:0.1 to 20, 10:0.1 to 10, 10:0.1 to 5, or 10:0.1 to 1, 10:0.5 to 100, 10:0.5 to 90, 10:0.5 to 80, 10:0.5 to 70, 10:0.5 to 60, 10:0.5 to 50, 10:0.5 to 40, 10:0.5 to 30, 10:0.5 to 20 , 10:0.5 to 10, 10:0.5 to 5, or 10:0.5 to 1, 10:1 to 100, 10:1 to 90, 10:1 to 80, 10:1 to 70, 10:1 to 60, 10:1 to 50, 10:1 to 40, 10:1 to 30, 10:1 to 20, or 10:1 to 10, more specifically 10:0.1 to 10, 10:0.1 to 9, 10:0.1 to 8, 10:0.1 to 7, 10:0.1 to 6, 10:0.1 to 5, 10:0.1 to 4, 10:0.1 to 3, 10:0.1 to 2, 10:0.1 to 1 or 10:1 to 10, 10:1 to 9, 10:1 to 8, 10:1 to 7, 10:1 to 6, 10:1 to 5, 10:1 to 4, 10:1 to 3, 10:1 to 2, 10:9, 10:8, 10:7, 10:6, 10:5, 10:4, 10:3, 10:2, 10:1, 10:0.5, or 10:0.1 may be, but is not limited thereto.
본 발명의 일 구현예에 있어서, 상기 훈증소독 키트에 포함되는 상기 산은 물에 대하여 0.01 내지 10의 몰농도로 포함될 수 있다.In one embodiment of the present invention, the acid included in the fumigation kit may be included in a molar concentration of 0.01 to 10 with respect to water.
본 발명의 구체적인 구현예에 있어서, 상기 훈증소독 키트에 포함되는 상기 산은 물에 대하여 0.1 내지 10, 0.5 내지 10, 1 내지 10, 2 내지 10, 3 내지 10, 4 내지 10, 5 내지 10, 6 내지 10, 7 내지 10, 8 내지 10, 또는 9 내지 10의 몰농도로 포함될 수 있다. In a specific embodiment of the present invention, the acid contained in the fumigation kit is 0.1 to 10, 0.5 to 10, 1 to 10, 2 to 10, 3 to 10, 4 to 10, 5 to 10, 6 with respect to water. It may be included in a molar concentration of 10 to 10, 7 to 10, 8 to 10, or 9 to 10.
본 발명의 다른 구체적인 구현예에 있어서, 상기 훈증소독 키트에 포함되는 상기 산은 물에 대하여 0.1 내지 10, 0.1 내지 9, 0.1 내지 8, 0.1 내지 7, 0.1 내지 6, 0.1 내지 5, 0.1 내지 4, 0.1 내지 3, 0.1 내지 2, 0.1 내지 1, 또는 0.1 내지 0.5의 몰농도로 포함될 수 있다. In another specific embodiment of the present invention, the acid contained in the fumigation kit is 0.1 to 10, 0.1 to 9, 0.1 to 8, 0.1 to 7, 0.1 to 6, 0.1 to 5, 0.1 to 4, It may be included in a molar concentration of 0.1 to 3, 0.1 to 2, 0.1 to 1, or 0.1 to 0.5.
본 발명의 일 구현예에 있어서, 상기 훈증소독 키트에 포함되는 상기 아염소산나트륨; 및 당, 산, 및 물의 혼합용액의 중량비는 1:0.1 내지 1:10이다.In one embodiment of the present invention, the sodium chlorite included in the fumigation kit; And the weight ratio of the mixed solution of sugar, acid, and water is 1:0.1 to 1:10.
본 발명의 구체적인 구현예에 있어서, 상기 훈증소독 키트에 포함되는 상기 아염소산나트륨; 및 당, 산, 및 물의 혼합용액의 중량비는 1:0.1 내지 10, 1:0.5 내지 10, 1:1 내지 10, 1:2 내지 10, 1:3 내지 10, 1:4 내지 10, 1:5 내지 10, 1:6 내지 10, 1:7 내지 10, 1:8 내지 10, 또는 1:9 내지 10일 수 있다. In a specific embodiment of the present invention, the sodium chlorite included in the fumigation kit; and a weight ratio of the mixed solution of sugar, acid, and water is 1:0.1 to 10, 1:0.5 to 10, 1:1 to 10, 1:2 to 10, 1:3 to 10, 1:4 to 10, 1: 5 to 10, 1:6 to 10, 1:7 to 10, 1:8 to 10, or 1:9 to 10.
본 발명의 다른 구체적인 구현예에 있어서, 상기 훈증소독 키트에 포함되는 상기 아염소산나트륨; 및 당, 산, 및 물의 혼합용액의 중량비는 1:0.1 내지 10, 1:0.1 내지 9, 1:0.1 내지 8, 1:0.1 내지 7, 1:0.1 내지 6, 1:0.1 내지 5, 1:0.1 내지 4, 1:0.1 내지 3, 1:0.1 내지 2, 1:0.1 내지 1, 또는 1:0.1 내지 0.5 일 수 있다. In another specific embodiment of the present invention, the sodium chlorite included in the fumigation kit; and a weight ratio of the mixed solution of sugar, acid, and water is 1:0.1 to 10, 1:0.1 to 9, 1:0.1 to 8, 1:0.1 to 7, 1:0.1 to 6, 1:0.1 to 5, 1: 0.1 to 4, 1:0.1 to 3, 1:0.1 to 2, 1:0.1 to 1, or 1:0.1 to 0.5.
본 발명의 일 구현예에 있어서, 상기 훈증소독 키트는 아염소산나트륨 100 중량부에 대하여, 당을 20 내지 200 중량부 포함한다. 보다 구체적으로, 상기 훈증소독 키트는 아염소산나트륨 100 중량부에 대하여 당을 20 내지 200 중량부, 30 내지 200 중량부, 40 내지 200 중량부, 50 내지 200 중량부, 60 내지 200 중량부; 20 내지 180 중량부, 30 내지 180 중량부, 40 내지 180 중량부, 50 내지 180 중량부, 60 내지 180 중량부; 20 내지 160 중량부, 30 내지 160 중량부, 40 내지 160 중량부, 50 내지 160 중량부, 60 내지 160 중량부; 20 내지 140 중량부, 30 내지 140 중량부, 40 내지 140 중량부, 50 내지 140 중량부, 60 내지 140 중량부; 20 내지 120 중량부, 30 내지 120 중량부, 40 내지 120 중량부, 50 내지 120 중량부, 60 내지 120 중량부; 20 내지 100 중량부, 30 내지 100 중량부, 40 내지 100 중량부, 50 내지 100 중량부, 60 내지 100 중량부; 20 내지 80 중량부, 30 내지 80 중량부, 40 내지 80 중량부, 50 내지 80 중량부, 60 내지 80 중량부; 20 내지 70 중량부, 30 내지 70 중량부, 40 내지 70 중량부, 50 내지 70 중량부, 또는 60 내지 70 중량부, 20 중량부, 30 중량부, 40 중량부, 50 중량부, 60 중량부, 또는 70 중량부 포함할 수 있으나, 이에 한정되는 것은 아니다.In one embodiment of the present invention, the fumigation kit contains 20 to 200 parts by weight of sugar based on 100 parts by weight of sodium chlorite. More specifically, the fumigation kit contains 20 to 200 parts by weight, 30 to 200 parts by weight, 40 to 200 parts by weight, 50 to 200 parts by weight, 60 to 200 parts by weight of sugar based on 100 parts by weight of sodium chlorite; 20 to 180 parts by weight, 30 to 180 parts by weight, 40 to 180 parts by weight, 50 to 180 parts by weight, 60 to 180 parts by weight; 20 to 160 parts by weight, 30 to 160 parts by weight, 40 to 160 parts by weight, 50 to 160 parts by weight, 60 to 160 parts by weight; 20 to 140 parts by weight, 30 to 140 parts by weight, 40 to 140 parts by weight, 50 to 140 parts by weight, 60 to 140 parts by weight; 20 to 120 parts by weight, 30 to 120 parts by weight, 40 to 120 parts by weight, 50 to 120 parts by weight, 60 to 120 parts by weight; 20 to 100 parts by weight, 30 to 100 parts by weight, 40 to 100 parts by weight, 50 to 100 parts by weight, 60 to 100 parts by weight; 20 to 80 parts by weight, 30 to 80 parts by weight, 40 to 80 parts by weight, 50 to 80 parts by weight, 60 to 80 parts by weight; 20 to 70 parts by weight, 30 to 70 parts by weight, 40 to 70 parts by weight, 50 to 70 parts by weight, or 60 to 70 parts by weight, 20 parts by weight, 30 parts by weight, 40 parts by weight, 50 parts by weight, 60 parts by weight , or 70 parts by weight, but is not limited thereto.
본 발명의 다른 구현예에 있어서, 상기 훈증소독 키트에 포함되는 아염소산 나트륨은 물에 용해된 상태로 제공될 수 있다. 이 경우 본 발명의 훈증소독 키트는 아염소산 나트륨과 접촉시 이산화염소 생성 반응을 하는 구성물인 당 및 산을 분리하여 포함할 수 있다. In another embodiment of the present invention, sodium chlorite included in the fumigation kit may be provided in a dissolved state in water. In this case, the fumigation kit of the present invention may contain separately sugar and acid, which are components that react with sodium chlorite to produce chlorine dioxide.
본 발명의 다른 양태에 따르면, 본 발명은 다음 단계를 포함하는 이산화염소 훈증소독용 키트의 사용방법을 제공한다:According to another aspect of the present invention, the present invention provides a method of using a chlorine dioxide fumigation kit comprising the steps of:
i) 당; 산; 및 물을 혼합하여 용해시키는 단계; 및 i) sugar; Mountain; and mixing and dissolving water; and
ii) 상기 혼합물에 아염소산나트륨을 첨가하고 혼합하여 이산화염소 기체를 발생시키는 단계.ii) adding sodium chlorite to the mixture and mixing to generate chlorine dioxide gas.
본 발명의 상기 ii) 이산화염소 기체를 발생시키는 단계에서는 이산화염소 기체가 매우 활발하게 발생하면서 고농도의 이산화염소 기체를 발생시킨다.In the step ii) generating chlorine dioxide gas of the present invention, chlorine dioxide gas is generated very actively and chlorine dioxide gas of high concentration is generated.
또한, 상기 단계에서는 이산화염소 기체가 발생하는 반응이 일어나면서 100℃ 이상의 고열이 발생하여 이산화염소 기체가 반응이 일어나는 공간 주변으로 빠르고 쉽게 퍼져나가므로 넓은 공간을 빠르게 소독할 수 있다. In addition, in the above step, a reaction in which chlorine dioxide gas is generated occurs, and high heat of 100° C. or more is generated, so that chlorine dioxide gas spreads quickly and easily around the space where the reaction takes place, so that a large space can be disinfected quickly.
또한, 본 발명에서 사용되는 이산화염소 훈증소독용 키트는 발열제를 포함하지 않으므로, 발열제에 혼합된 불순물이 100℃ 이상의 고열에 의해 발생시킬 수 있는 제3의 성분이 발생하지 않으므로 보다 순도 높은 이산화염소 기체를 발생시킬 수 있다. In addition, since the chlorine dioxide fumigation kit used in the present invention does not contain a pyrogen, a third component that can be generated by high heat of 100° C. or higher does not occur when impurities mixed in the pyrogen do not generate higher purity chlorine dioxide gas can cause
상기 본 발명의 다른 양태에 따른 이산화염소 훈증소독용 키트의 사용방법은 상술한 이산화염소 훈증소독용 키트와 당, 산, 물 등의 구성 및 함량 등을 같이하는 것으로서, 양 발명 간에 중복되는 내용은 본 명세서의 복잡성을 피하기 위하여 기재를 생략한다. The method of using the chlorine dioxide fumigation kit according to another aspect of the present invention is the same as the above-described chlorine dioxide fumigation kit and the composition and content of sugar, acid, water, etc., and the overlapping content between the two inventions is In order to avoid the complexity of the present specification, descriptions are omitted.
본 발명의 또 다른 양태에 따르면, 본 발명은 다음 단계를 포함하는 이산화염소 훈증소독용 키트의 제조방법을 제공한다:According to another aspect of the present invention, the present invention provides a method for producing a chlorine dioxide fumigation kit comprising the steps of:
i) 당; 산; 및 물을 혼합한 후 용해시켜 제1 유닛을 제조하는 단계; 및i) sugar; Mountain; and mixing and dissolving water to prepare a first unit; and
ii) 아염소산나트륨을 포함하는 제2 유닛을 제조하는 단계.ii) preparing a second unit comprising sodium chlorite.
본 발명의 일 구현예에 있어서, 상기 제1 유닛은 산을 포함하는 것을 특징으로 한다. 또한, 상기 제1 유닛은 발열제를 포함하지 않으므로 아염소산나트륨을 제외한 나머지 성분을 미리 혼합하여 보관할 수 있으므로 본 발명자들이 개발한 종래 이산화염소 훈증소독용 키트 발명에 비하여 제조 및 보관이 용이하다.In one embodiment of the present invention, the first unit is characterized in that it comprises an acid. In addition, since the first unit does not contain a heat generating agent, the remaining components except sodium chlorite can be mixed and stored in advance, so it is easy to manufacture and store compared to the prior invention of the chlorine dioxide fumigation kit developed by the present inventors.
본 발명의 일 구현예에 있어서, 상기 제1 유닛과 상기 제2 유닛은 서로 접촉시 이산화염소 기체가 발생하여 사용자가 필요한 시점에 이산화염소 기체를 발생시킬 수 없으므로, 각각 별도로 포장된다. In one embodiment of the present invention, since chlorine dioxide gas is generated when the first unit and the second unit come into contact with each other, so that the user cannot generate chlorine dioxide gas at a time required by the user, they are packaged separately.
상기 본 발명의 또 다른 양태에 따른 이산화염소 훈증 소독용 키트의 제조방법은 상술한 이산화염소의 훈증소독용 키트와 당, 산, 물 등의 구성 및 함량을 같이하는 것으로서, 양 발명 간에 중복되는 내용은 본 명세서의 복잡성을 피하기 위하여 기재를 생략한다.The method for manufacturing a kit for fumigation of chlorine dioxide according to another aspect of the present invention is to have the same composition and content of sugar, acid, water, etc. as the kit for fumigation of chlorine dioxide described above, content overlapping between the two inventions In order to avoid the complexity of the present specification, description is omitted.
본 발명은 이산화염소 훈증소독용 키트, 이의 사용방법 및 제조방법에 관한 것이다. 본 발명의 이산화염소 훈증소독용 키트를 이용하는 경우, 기존의 소독 키트보다 생산과 포장이 간편하고, 사용법도 간편하며, 보다 안전하면서도 순도 높은 이산화염소 기체를 다량 생산하여 공간 소독에 유용하게 사용될 수 있다. The present invention relates to a kit for fumigation with chlorine dioxide, a method for using the same, and a method for manufacturing the same. When the kit for fumigation of chlorine dioxide of the present invention is used, production and packaging are simpler than conventional disinfection kits, and it is easy to use, and it can be usefully used for space disinfection by producing a large amount of safer and higher purity chlorine dioxide gas. .
도 1은 기존 키트의 사용방법을 순서대로 나타낸 도이다. (1. 포도당 용액에 아염소산나트륨 분말 첨가 2. 발열제 첨가 3. 정제수 첨가 4. 이산화염소 기체 발생)
도 2는 본 발명의 개선된 키트의 사용 방법을 순서대로 나타낸 도이다. (1. 포도당 및 구연산 용액에 아염소산나트륨 분말 첨가 2. 이산화염소 기체 발생)1 is a view sequentially showing a method of using an existing kit. (1. Addition of sodium chlorite powder to glucose solution 2. Addition of exothermic agent 3. Addition of purified water 4. Chlorine dioxide gas evolution)
2 is a view sequentially showing a method of using the improved kit of the present invention. (1. Addition of sodium chlorite powder to glucose and citric acid solution 2. Chlorine dioxide gas evolution)
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위한 것으로, 본 발명의 요지에 따라 본 발명의 범위가 이들 실시예에 의해 제한되지 않는다는 것은 당업계에서 통상의 지식을 가진 자에 있어서 자명할 것이다.Hereinafter, the present invention will be described in more detail through examples. These examples are only for illustrating the present invention in more detail, and it will be apparent to those skilled in the art that the scope of the present invention is not limited by these examples according to the gist of the present invention. .
실시예Example
본 명세서 전체에 걸쳐, 특정 물질의 농도를 나타내기 위하여 사용되는 "%"는 별도의 언급이 없는 경우, 고체/고체는 (중량/중량) %, 고체/액체는 (중량/부피) %, 그리고 액체/액체는 (부피/부피) %이다.Throughout this specification, "%" used to indicate the concentration of a specific substance is (weight/weight) % for solid/solid, (weight/volume) % for solid/liquid, and Liquid/liquid is (volume/volume) %.
실시예 1: 본 발명의 이산화염소 훈증소독 키트의 제조Example 1: Preparation of chlorine dioxide fumigation kit of the present invention
본 발명자는 이산화염소 발열제를 사용하지 않고도 이산화염소 훈증소독이 가능한 훈증소독 키트를 다음과 같이 제조하였다. 기존에 개발한 이산화염소 훈증소독 키트(대한민국 특허 제10-2149117호)와 비교하여 개선 정도를 확인하고자 표 1과 같은 구성으로 제조하여 비교하였다. The present inventors prepared a fumigation kit capable of fumigating chlorine dioxide without using a chlorine dioxide exothermic agent as follows. In order to check the degree of improvement compared to the previously developed chlorine dioxide fumigation kit (Korean Patent No. 10-2149117), the composition was prepared and compared as shown in Table 1.
나트륨(g)chlorous acid
Sodium (g)
포함된 정제수in sugar solution
Contains purified water
총량(g)Purified water
Total amount (g)
(당용액 포함 110g + 발열제에 첨가 60g )170
(110g including sugar solution + 60g added to the exothermic agent)
기존 키트와 본 발명의 개선된 키트의 포장 구성은 표 2에 나타내었다.The packaging configuration of the existing kit and the improved kit of the present invention is shown in Table 2.
표 1 및 표 2에 나타낸 바와 같이, 기존 키트는 아염소산나트륨, 포도당 용액, 발열제, 발열용 정제수를 모두 따로 포장하여야 하였다. 그러나, 본 발명의 개선된 키트는 포도당, 구연산, 정제수를 하나로 혼합하여도 되므로, 아염소산나트륨과 포도당+구연산+정제수 용액만 별도로 포장하면 되므로, 포장이 간편한 특징이 있다.As shown in Tables 1 and 2, in the existing kit, sodium chlorite, glucose solution, pyrogen, and purified water for fever had to be packaged separately. However, since the improved kit of the present invention may mix glucose, citric acid, and purified water into one, only sodium chlorite and glucose + citric acid + purified water solution need to be packaged separately, so packaging is easy.
또는 1. 아염소산나트륨 및 정제수 혼합액 포장, 2. 포도당 및 구연산 (선택적으로 정제수) 포장, 3. 전체 내용물 포장과 같이 구성할 수도 있다. Alternatively, it may consist of 1. packaging of sodium chlorite and purified water mixture, 2. packaging of glucose and citric acid (optionally purified water), and 3. packaging of whole contents.
실시예 2: 본 발명의 이산화염소 훈증소독 키트의 사용Example 2: Use of the chlorine dioxide fumigation kit of the present invention
2-1. 기존 키트의 사용 방법2-1. How to use your existing kit
기존 키트는 포도당 용액이 들어 있는 용기에 별도 포장된 아염소산나트륨 분말을 넣고 고루 혼합한 후, 발열제를 넣었다. 그 후 발열제 위에 정제수를 부어 발열반응을 일으켰다. 그 결과, 혼합물이 끓으면서 열이 발생하고, 이산화염소 기체가 생성됨을 확인하였다. 기존 키트의 사용방법은 표 3 및 도 1에 나타내었다. In the existing kit, separately packaged sodium chlorite powder was put in a container containing a glucose solution, mixed evenly, and a heating agent was added. After that, purified water was poured over the exothermic agent to cause an exothermic reaction. As a result, it was confirmed that heat was generated while the mixture was boiling, and chlorine dioxide gas was generated. The method of using the existing kit is shown in Table 3 and FIG. 1 .
2-2. 개선 키트의 사용 방법2-2. How to use the improvement kit
본 발명의 개선된 키트는 포도당 및 구연산이 들어있는 혼합액을 반응 용기에 넣고, 아염소산나트륨 분말을 넣었다. 그 결과, 혼합물이 끓어오르면서 100℃ 이상의 고열이 발생하고, 이산화염소 기체가 매우 빠르게 생성됨과 동시에 반응이 일어나는 공간 전체로 빠르게 확산됨을 확인하였다. 본 발명의 개선된 키트의 사용방법은 표 3 및 도 2에 나타내었다. In the improved kit of the present invention, a mixed solution containing glucose and citric acid was placed in a reaction vessel, and sodium chlorite powder was added. As a result, it was confirmed that as the mixture boils, high heat of 100° C. or higher is generated, and chlorine dioxide gas is generated very quickly and rapidly diffused throughout the space where the reaction takes place. The method of using the improved kit of the present invention is shown in Table 3 and FIG. 2 .
상기 표 3 및 도 1, 도 2에 나타낸 바와 같이, 기존에 발열제를 포함하는 키트는 i) 포도당 용액을 용기에 담은 후, ii) 아염소산 나트륨 첨가, iii) 발열제 첨가, 및 iv) 발열반응을 위한 정제수 첨가의 네 단계의 과정을 거쳐야 하였다.As shown in Table 3 and FIGS. 1 and 2, the conventional kit containing a pyrogen is i) a glucose solution in a container, ii) sodium chlorite is added, iii) a pyrogen is added, and iv) an exothermic reaction is performed. It was necessary to go through a four-step process of adding purified water for
그러나, 본 발명의 개선된 키트는 i) 포도당 및 구연산 혼합 용액을 용기에 담은 후, ii) 아염소산 나트륨을 첨가하면 되어 두 단계의 과정만을 통하여 이산화염소 기체를 발생시킬 수 있으므로 사용법도 매우 간편하다. However, the improved kit of the present invention is very easy to use because it is possible to generate chlorine dioxide gas only through a two-step process by i) putting a mixed solution of glucose and citric acid in a container and ii) adding sodium chlorite. .
상술한 바와 같이, 본 발명의 개선된 키트는 제품의 생산과 포장이 간편하고, 사용 방법도 간편할 뿐만 아니라, 발열제를 사용하지 않아도 되므로 발열제에서 발생할 수 있는 불순물이, 훈증되는 이산화염소 기체에 포함될 가능성이 없어 더욱 안전하다. As described above, in the improved kit of the present invention, the production and packaging of the product is simple, and the method of use is also simple. There is no possibility that it is safer.
또한, 본 발명의 개선된 키트는 이산화염소 기체를 매우 활발하게 발생시키면서 고농도의 이산화염소 기체를 생성하고, 반응이 일어나면서 100℃ 이상의 고열을 발생시켜 이산화염소 기체가 반응이 일어나는 공간 전체로 매우 빠르고 쉽게 확산되므로 넓은 공간을 빠르게 소독할 수 있었다. In addition, the improved kit of the present invention generates a high concentration of chlorine dioxide gas while very actively generating chlorine dioxide gas, and generates high heat of 100° C. or higher while the reaction occurs, so that chlorine dioxide gas is very fast throughout the space where the reaction takes place. Because it spreads easily, it was possible to quickly disinfect a large space.
따라서, 본 발명의 개선된 훈증소독용 키트는 공간 소독용도로 매우 유용하게 사용할 수 있다.Therefore, the improved fumigation kit of the present invention can be very usefully used for space disinfection.
Claims (10)
상기 아염소산나트륨; 및 당, 산, 및 물의 혼합용액의 중량비가 1:0.5 내지 1:10이고,
상기 아염소산나트륨 100 중량부에 대하여 당을 20 내지 200 중량부 포함하는 것인, 키트.
sodium chlorite; Party; Mountain; And in the kit for fumigation of chlorine dioxide comprising water,
the sodium chlorite; and a weight ratio of a mixed solution of sugar, acid, and water is 1:0.5 to 1:10,
The kit comprising 20 to 200 parts by weight of sugar based on 100 parts by weight of the sodium chlorite.
The kit of claim 1, wherein the sugar is at least one selected from the group consisting of glucose, sugar, lactose, maltose, fructose, oligosaccharide, dextrin, and honey.
The kit of claim 1, wherein the acid is at least one organic acid selected from the group consisting of citric acid, lactic acid, acetic acid, formic acid, citric acid, tartaric acid, oxalic acid, ascorbic acid, uric acid, butyric acid, stearic acid, and propionic acid.
The kit of claim 1 , wherein the acid is at least one inorganic acid selected from the group consisting of hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, boric acid, and hydrofluoric acid.
The kit according to claim 1, wherein the weight ratio of sugar and water is 10:0.1 to 10.
The kit according to claim 1, wherein the acid is contained in a molar concentration of 0.01 to 10 with respect to water.
ii) 상기 당, 산, 및 물의 혼합물에 아염소산나트륨을 첨가하고 혼합하여 이산화염소 기체를 발생시키는 단계;를 포함하며,
상기 아염소산나트륨; 및 당, 산, 및 물의 혼합용액의 중량비가 1:0.5 내지 1:10이고,
상기 아염소산나트륨 100 중량부에 대하여 당은 20 내지 200 중량부로 사용되는 것인, 이산화염소 훈증소독용 키트의 사용방법.
i) sugar; Mountain; and mixing and dissolving water; and
ii) adding sodium chlorite to the mixture of sugar, acid, and water and mixing to generate chlorine dioxide gas;
the sodium chlorite; and a weight ratio of a mixed solution of sugar, acid, and water is 1:0.5 to 1:10,
The method of using a kit for fumigation of chlorine dioxide, wherein the sugar is used in an amount of 20 to 200 parts by weight based on 100 parts by weight of sodium chlorite.
ii) 아염소산나트륨을 포함하는 제2유닛을 제조하는 단계;를 포함하며,
상기 아염소산나트륨; 및 당, 산, 및 물의 혼합용액의 중량비가 1:0.5 내지 1:10이고,
상기 아염소산나트륨 100 중량부에 대하여 당은 20 내지 200 중량부로 포함되는 것인, 이산화염소 훈증소독용 키트의 제조방법.
i) sugar; Mountain; and mixing and dissolving water to prepare a first unit; and
ii) preparing a second unit comprising sodium chlorite;
the sodium chlorite; and a weight ratio of a mixed solution of sugar, acid, and water is 1:0.5 to 1:10,
The method for producing a kit for fumigation of chlorine dioxide, wherein the sugar is contained in an amount of 20 to 200 parts by weight based on 100 parts by weight of the sodium chlorite.
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| KR1020200171416A KR102306864B1 (en) | 2020-12-09 | 2020-12-09 | Kits for disinfection using chlorine dioxide fumigation |
| CN202180009661.9A CN115003341A (en) | 2020-01-17 | 2021-01-15 | Reagent kit for chlorine dioxide fumigation |
| EP21741013.3A EP4091637A4 (en) | 2020-01-17 | 2021-01-15 | Kit for chlorine dioxide fumigation |
| US17/793,168 US20220401608A1 (en) | 2020-01-17 | 2021-01-15 | Kit for chlorine dioxide fumigation |
| JP2022544175A JP2023510985A (en) | 2020-01-17 | 2021-01-15 | Chlorine dioxide fumigation disinfection kit |
| PCT/KR2021/000619 WO2021145732A1 (en) | 2020-01-17 | 2021-01-15 | Kit for chlorine dioxide fumigation |
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| WO2024090774A1 (en) * | 2022-10-28 | 2024-05-02 | 에이비씨메디칼 주식회사 | Sustained-release chlorine dioxide gas generation kit and method |
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