KR102288279B1 - Polymer concrete mortar composition for bridge deck thin facing pavement comprising methylmethacrylate resin and garnet fine aggregate and the construction method bridge deck thin facing pavement thereof - Google Patents

Polymer concrete mortar composition for bridge deck thin facing pavement comprising methylmethacrylate resin and garnet fine aggregate and the construction method bridge deck thin facing pavement thereof Download PDF

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KR102288279B1
KR102288279B1 KR1020210015388A KR20210015388A KR102288279B1 KR 102288279 B1 KR102288279 B1 KR 102288279B1 KR 1020210015388 A KR1020210015388 A KR 1020210015388A KR 20210015388 A KR20210015388 A KR 20210015388A KR 102288279 B1 KR102288279 B1 KR 102288279B1
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weight
parts
garnet
pavement
polymer concrete
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KR1020210015388A
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곽은구
한상일
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주식회사 씨큐알
곽은구
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    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
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    • C04B26/06Acrylates
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    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/26Carbonates
    • C04B14/28Carbonates of calcium
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    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0481Other specific industrial waste materials not provided for elsewhere in C04B18/00
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    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
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    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
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    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
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    • C08F2/00Processes of polymerisation
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    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06Unsaturated polyesters
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C23/00Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces
    • E01C23/06Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road
    • E01C23/09Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road for forming cuts, grooves, or recesses, e.g. for making joints or channels for markings, for cutting-out sections to be removed; for cleaning, treating, or filling cuts, grooves, recesses, or fissures; for trimming paving edges
    • E01C23/0966Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road for forming cuts, grooves, or recesses, e.g. for making joints or channels for markings, for cutting-out sections to be removed; for cleaning, treating, or filling cuts, grooves, recesses, or fissures; for trimming paving edges for filling or priming, with or without working the surface of the filling or applying particulate material thereto, e.g. for filling the joints of stone-sett paving
    • E01C23/0973Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road for forming cuts, grooves, or recesses, e.g. for making joints or channels for markings, for cutting-out sections to be removed; for cleaning, treating, or filling cuts, grooves, recesses, or fissures; for trimming paving edges for filling or priming, with or without working the surface of the filling or applying particulate material thereto, e.g. for filling the joints of stone-sett paving with liquid or semi-liquid materials, e.g. crack sealants
    • E01C23/098Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road for forming cuts, grooves, or recesses, e.g. for making joints or channels for markings, for cutting-out sections to be removed; for cleaning, treating, or filling cuts, grooves, recesses, or fissures; for trimming paving edges for filling or priming, with or without working the surface of the filling or applying particulate material thereto, e.g. for filling the joints of stone-sett paving with liquid or semi-liquid materials, e.g. crack sealants and working the surface of the filling or applying particulate material thereto, e.g. smoothing, gritting
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01DCONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
    • E01D19/00Structural or constructional details of bridges
    • E01D19/08Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
    • E01D19/083Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01DCONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
    • E01D22/00Methods or apparatus for repairing or strengthening existing bridges ; Methods or apparatus for dismantling bridges
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
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    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The present invention relates to a polymer concrete mortar composition for bridge deck thin layer pavement comprising a methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate and a construction method for bridge deck thin layer pavement using the same, and more specifically, to a polymer concrete mortar composition for bridge deck thin layer pavement comprising a methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate and a construction method for bridge deck thin layer pavement using the same, wherein the polymer concrete mortar composition includes: an organic binder; and an inorganic binder. The organic binder includes: a first subject (A) which is an acrylic copolymer resin comprising water, methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), a reactive emulsifier, a copolymerization initiator, an alkalizing agent, and a peroxide curing agent; a second subject (B) which is a reinforcing resin containing a unsaturated polyester resin and a peroxide curing agent; and a silane-based coupling agent which is a crosslinking agent to increase chemical adhesion of polymer concrete. The inorganic binder contains garnet fine aggregate with a particle size of 0.05 to 2 mm, which is recovered and recycled from garnet sludge for abrasive or garnet sludge for waterjet cutting, and a calcium carbonate filler. The polymer concrete mortar composition for bridge deck thin layer pavement according to the present invention has the effects of: making a thickness of bridge deck pavement thin so as to reduce a dead weight of the bridge deck pavement; enabling construction or repairing of the bridge deck pavement to be easily performed so as to reduce the construction costs and construction period; and exhibiting excellent waterproof performance even without a waterproof layer, such that durability of a bridge can be improved.

Description

메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물 및 이를 이용한 교면박층포장 시공공법{POLYMER CONCRETE MORTAR COMPOSITION FOR BRIDGE DECK THIN FACING PAVEMENT COMPRISING METHYLMETHACRYLATE RESIN AND GARNET FINE AGGREGATE AND THE CONSTRUCTION METHOD BRIDGE DECK THIN FACING PAVEMENT THEREOF}POLYMER CONCRETE MORTAR COMPOSITION FOR BRIDGE DECK THIN FACING PAVEMENT COMPRISING METHYLMETHACRYLATE RESIN AND GARNET FACING PAVEMENT COMPOSITION FOR BRIDGE DECK THIN FACING PAVEMENT COMPRISING METHYLMETHACRYLATE RESIN AND GARNET THE CONSTRUCTION METHOD BRIDGE DECK THIN FACING PAVEMENT THEREOF}

본 발명은 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물 및 이를 이용한 교면박층포장 시공공법에 관한 것으로, 보다 상세하게는 물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 반응성 유화제와, 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화폴리에스터수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 및 탄산칼슘 충전재를 포함하는 무기계 결합재;를 포함하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물 및 이를 이용한 교면박층포장 시공공법에 관한 것이다.The present invention relates to a polymer concrete mortar composition for thin layer pavement for bridges comprising a methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate, and a thin layer paving construction method for bridges using the same, and more particularly, to water, methyl methacrylate (MMA) ), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), a reactive emulsifier, a copolymerization initiator, an acrylic copolymer resin comprising an alkalizing agent and a peroxide curing agent, the first subject (A), An organic binder comprising a second subject (B), which is a reinforcing resin containing an unsaturated polyester resin and a peroxide curing agent, and a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete, and ; Garnet sludge for abrasives or garnet sludge for waterjet cutting is recovered and recycled from fine garnet aggregate with a particle size of 0.05 to 2 mm and an inorganic binder containing calcium carbonate filler; including methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate It relates to a polymer concrete mortar composition for thin-layer pavement for bridges and a construction method for thin-layer pavement for bridges using the same.

일반적으로 교량이란 하천, 해안, 도로 등의 상부를 지나갈 수 있도록 가설된 고가 구조물을 총칭하는 것으로, 이러한 교량의 표면에는 차량 등이 원활하게 통행할 수 있도록 포장공사를 함으로써 교면 포장층을 형성한다.In general, a bridge is a generic term for an elevated structure erected so that it can pass through the upper part of a river, coast, road, etc., and the pavement layer is formed on the surface of such a bridge by paving the bridge so that vehicles can pass smoothly.

특히, 교면 포장은 교통 하중을 직접 전달하는 부분으로서, 반복되는 교통하중에 적합한 강도 및 균열저항성을 가져야 하고 빗물 등의 수분에 노출되어 있는 관계로 방수 성능을 가질 것이 요구되며 특히, 염화물이온의 침투에 의해 철근이 부식되는 것을 방지하기 위하여 낮은 염소이온 투수성을 가질 것이 요구된다.In particular, the bridge pavement is a part that directly transmits the traffic load. It must have strength and crack resistance suitable for repeated traffic loads, and it is required to have waterproof performance because it is exposed to moisture such as rainwater. It is required to have low chloride ion permeability in order to prevent corrosion of the reinforcing bars.

그러나, 교면 포장은 중차량 통행에 따른 소성 변형과 충격에 따른 파손, 지역적 특성에 따른 기후 변화, 동결 융해에 대한 영향, 장대 교량의 경우 처짐 진동에 따른 영향, 우수 및 염소 이온 등의 침투로 인한 철근의 부식 및 이에 따른 교량 상판 콘크리트의 손상 촉진 등의 원인에 의해 손상이 일어나기 쉽다.However, bridge pavement is damaged by plastic deformation and impact due to heavy vehicle traffic, climate change according to regional characteristics, effects on freezing and thawing, effects of deflection vibration in the case of long bridges, and penetration of rainwater and chloride ions. Damage is likely to occur due to corrosion of reinforcing bars and accelerated damage to the concrete of the bridge deck.

이와 같이 교면 포장에 손상이 발생하는 경우, 파손된 부분을 제거하고 그 부분을 보수해야 하는데, 특히 교량의 보수에 있어서는 장기간 교량 폐쇄시 교통 체증이 발생하게 되므로 교량 보수 공사는 빠른 시간에 신속하게 이루어질 필요가 있다. In this way, when the pavement is damaged, the damaged part must be removed and repaired. In particular, in the case of bridge repair, when the bridge is closed for a long period of time, traffic jams occur. There is a need.

또한, 기존 포장과의 접합이 우수해야 하고, 장기 강도 및 내구성이 우수하여 보수 효과가 장기간 유지되어야 한다.In addition, the bonding with the existing pavement should be excellent, and long-term strength and durability should be excellent, so that the maintenance effect should be maintained for a long time.

그러나, 기존의 교량 보수 공법은 주로 아스팔트 덧씌우기, 폴리머 콘크리트 박층 포장 보수 공법 등이 이용되고 있으나 작업 시간이 오래 걸리고 기존 포장과의 접합이 열악하며 강도 및 내구성이 크지 않아 보수 효과가 장기간 유지되지 못하는 면이 있었다However, the existing bridge repair method mainly uses asphalt overlay and polymer concrete thin-layer pavement repair method. there was a side

이러한 문제점들을 해결하기 위하여, 최근에는 교량 상판에서 부식이나 침식이 많이 일어나는 부위에 적용되는 것으로, 보통 콘크리트 배합시에 SBR(Styrene Butadiene Rubber) 라텍스를 첨가한 초속경 폴리머 재질 콘크리트로서 라텍스 개질 콘크리트(LMC : Latex Modified Concrete), 아크릴 수지계 폴리머 콘크리트 등이 개발되어 사용되고 있다.In order to solve these problems, recently, it is applied to areas where corrosion or erosion occurs a lot on the bridge deck. Usually, it is a super-velocity polymer concrete with SBR (Styrene Butadiene Rubber) latex added during concrete mixing. Latex-modified concrete (LMC) : Latex Modified Concrete), acrylic resin polymer concrete, etc. have been developed and used.

종래 기술들을 살펴 보면, 한국등록특허 10-0403979(등록일자 2003년10월20일)에 초속경시멘트(Rapid Set Cement) 100중량부에 대하여 세골재 200중량부 내지 300중량부, 조골재 170중량부 내지 230중량부, 물 90중량부 내지 110중량부, 지연제 002중량부 내지 005중량부, 라텍스 수지 35중량부 내지 60중량부를 강제식믹서에 넣고 충분히 비비기를 수행하고, 여기에 소포제를 라텍스 수지 100중량부에 대하여 2중량부 내지 15중량부 첨가하여 약 1분간 다시 비비기를 한 후 1분간 공기중에 노출시켜 발생된 공기를 제거하고 다시 약 30초간 비비기를 수행하는 것을 특징으로 하는 초속경 라텍스 개질 콘크리트 조성물의 제조방법과 이를 교면포장의 긴급보수용으로 사용하는 기술이 제시되어 있다.Looking at the prior art, 200 parts by weight to 300 parts by weight of fine aggregate, 170 parts by weight of coarse aggregate to 100 parts by weight of Rapid Set Cement in Korean Patent Registration No. 10-0403979 (registration date October 20, 2003) 230 parts by weight, 90 parts by weight to 110 parts by weight of water, 002 parts by weight to 005 parts by weight of a retarder, 35 parts by weight to 60 parts by weight of a latex resin is placed in a forced mixer and sufficiently rubbed, and an antifoaming agent is added to the latex resin 100 After adding 2 to 15 parts by weight based on parts by weight, after rubbing again for about 1 minute, exposed to air for 1 minute to remove the generated air, and rubbing again for about 30 seconds. A method for preparing a composition and a technique for using it for emergency repair of bridge pavement are presented.

또한, 한국등록특허 10-1465446(등록일자 2014년11월20일)에는 염소이온침투저항성이 우수한 저발열 시멘트와 유황 미분말을 첨가하여 초속경 콘크리트의 염화물저항성 및 내약품성을 개선하기 위하여, 시멘트 혼화용 폴리머를 첨가함으로써 시멘트 혼합성, 인장강도, 부착력, 내구성 및 작업성을 개선하고 균열치유재를 첨가하여 균열에 대한 저항성을 높인 내염성 초속경 콘크리트 조성물 및 이을 이용한 교면 또는 포장면 보수방법에 관한 것으로, 내염성 초속경 결합재 10~30 중량%, 잔골재 23~55 중량%, 굵은골재 23~55 중량%, 시멘트 혼화용 폴리머 1~15 및 물 1~10 중량% 포함하는 내염성 초속경 콘크리트 조성물을 제공하는 특징에 의하여 초속경 콘크리트의 염화물저항성과 내약품성을 개선하고 혼합성, 인장강도, 부착력, 내구성, 작업성을 개선하며 균열에 대한 저항성을 높이고 또한, 균열, 중성화, 화학적 침식에 의해 열화된 콘크리트 도로와 교량의 구조를 개량하여 내구성을 증진하는 효과가 있는 내염성 초속경 콘크리트 조성물 및 이를 이용한 교면 또는 포장면 보수방법이 공지되어 있다.In addition, in Korea Patent No. 10-1465446 (registration date: November 20, 2014), low-heat cement with excellent chloride ion permeation resistance and fine sulfur powder are added to improve the chloride resistance and chemical resistance of ultra-fast concrete, cement admixture. It relates to a flame-resistant super-velocity concrete composition that improves cement mixability, tensile strength, adhesion, durability, and workability by adding a polymer for use in cement, and increases resistance to cracking by adding a crack healing material, and a method for repairing a bridge or pavement using the same. To provide a flame-resistant super-velocity concrete composition comprising 10 to 30% by weight of a flame-resistant binder, 23 to 55% by weight of fine aggregate, 23 to 55% by weight of coarse aggregate, 1 to 15% by weight of polymer for cement admixture, and 1 to 10% by weight of water According to its characteristics, it improves the chloride resistance and chemical resistance of ultra-velocity concrete, improves mixability, tensile strength, adhesion, durability, workability, and increases resistance to cracking. A salt-resistant super-fast concrete composition having the effect of improving durability by improving the structure of a bridge and a bridge and a method for repairing a bridge or pavement using the same are known.

또한, 한국등록특허 10-1665486(등록일자 2016년10월06일)에 통상의 교면포장 공법에 있어서, 1) 소디움 테트라피로포스페이트(sodium tetrapyrophosphate), 소디움 모노도데실설페이트(sodium monododecyl sulphate) 및 소디움 하이드록사이드(sodium hydroxide)를 포함한 유화제와 반응개시제 조성물(A), 2) 페닐에텐(phenylethene), 에틸-프로페노에이트(ethyl propenoate), 부틸-프로-2-에노에이트(butyl pro-2-enoate), 2-프로페넨나이트릴(2-propenenitrile) 및 디메틸암모노에틸메틸아크릴레이트(dimehtylamonoethylmethacrylate) 또는 프로-2-에노익산(pro-2-enonic acid)을 포함한 1차 및 2차 모노머 조성물(B), 및 3) 터셔리-부틸 하이드로 퍼옥사이드(tertiary-butyl hydro peroxide)와 소디움 하이드록시메탄 설피네이트(sodium hydroxymethane sulfinate)를 포함한 반응종결 조성물(C);을 포함하는 몰탈 및 콘크리트용 다중 폴리머 합성라텍스에 의해 개질된 혼입 콘크리트를 사용하는 것을 특징으로 하는 교면포장 공법이 공지되어 있다.In addition, in Korea Patent No. 10-1665486 (registration date October 06, 2016) in a conventional bridge paving method, 1) sodium tetrapyrophosphate, sodium monododecyl sulphate (sodium monododecyl sulphate) and sodium Emulsifier and reaction initiator composition including sodium hydroxide (A), 2) phenylethene, ethyl-propenoate, butyl-propenoate (butyl pro-2) -enoate), 2-propenenitrile (2-propenenitrile) and dimethyl ammonoethyl methyl acrylate (dimehtylamonoethylmethacrylate) or pro-2-enoic acid (pro-2-enonic acid) primary and secondary monomer compositions containing (B), and 3) a tertiary-butyl hydro peroxide (tertiary-butyl hydro peroxide) and sodium hydroxymethane sulfinate (C) terminating composition comprising sodium hydroxymethane sulfinate; Multi for mortar and concrete containing; A bridge paving method is known, which is characterized by using mixed concrete modified by polymer synthetic latex.

또한, 한국등록특허 10-1710300(등록일자 2017년02월20일)에 (a) 교면 포장 보수용 모르타르 조성물을 준비하는 단계로서, 상기 교면 포장 보수용 모르타르 조성물은 (1) 시멘트 50~100중량부, 클링커 0.5 내지 10 중량부, 플라스터 0.5 내지 10 중량부, 알파형 반수석고 0.5 내지 10 중량부, 실리카퓸 0.1 내지 5 중량부, 플라이애쉬 0.01 내지 5 중량부, 석회석 0.5 내지 10 중량부, 고로슬래그 1 내지 20 중량부, 하소포졸라나 0.01 내지 10 중량부 및 마이크로실리카 0.01 내지 10 중량부를 포함하는 제1분말 성분 10~70 중량%; 및 규산질계 방수제 2 ~ 7중량부, CSA계 팽창재 5 ~ 15중량부, 점도증강제 0.05 ~ 0.2중량부, 유동화제 0.3 ~ 1.1중량부, 경화촉진제 0.1 ~ 0.5중량부, 지연제 0.1 ~ 0.4중량부 및 규사 42 ~ 64중량부를 포함하는 제2분말 성분 30~90 중량%로 이루어진 것을 특징으로 하는 분체 성분 100 중량부; (2) EVA(Ethylene-vinyl acetate) 수지, NR(Natural rubber) 수지, NBR(Natural rubber-Butadiene rubber) 수지 및 SBR(Styrene-Butadiene Rubber) 수지 중에서 선택되는 1종 또는 2종 이상의 분말 또는 액상 고무 수지에 초속경시멘트와 카본블랙 및 섬유를 혼합하여 얻어진 개질 라텍스 성분 1~20 중량부; (3) 메틸메타아크릴레이트 1 내지 7 중량부, 스티렌모노머 5 내지 20 중량부, 노말부틸아크릴레이트 1 내지 10중량부, 메틸아크릴레이트 0.1 내지 10 중량부, 이소보닐아크릴레이트 0.1 내지 10 중량부, 개시제 0.05 내지 5중량부 및 유화제 0.05 내지 5 중량부를 포함하는 액상 성분 1~20 중량부; (4) 친수성 폴리비닐알코올 단섬유 성분 1~10 중량부; (5) 방부제, 소포제, 습윤제의 혼합물로 이루어진 첨가제 성분 1~5 중량부; 및 (6) 물 10 ~ 50중량부;를 포함하여 구성되는 교면 포장 보수제에, 충전재 및 골재를 혼합하되, 상기 교면 포장 보수제 5 ~50 중량부, 충전재 10~40 중량부 및 골재 20~70 중량부를 혼합하여 구성되는 교면 포장 보수용 모르타르 조성물을 준비하는 단계; (b) 교면 포장의 파손된 부분을 파쇄하되, 내부 배근이 손상되지 않도록 배근의 상부만을 부분적으로 파쇄하며, 상기 배근의 설치 위치를 교면 포장의 상면에 표시하고 표시된 지점을 피하면서 파쇄 작업을 수행하고, 배근의 상부가 파쇄되면 워터젯 장비를 이용하여 고압 살수하여 파쇄된 부분을 절삭해 냄으로써 교면 포장의 파손된 부분을 파쇄하는 단계; (c) 상기 파쇄된 부분을 고압 살수로써 절삭해내고 절삭면에 존재하는 이물질을 제거하되, 진공 흡입 차량을 이용하여 교량의 길이 방향으로 이동하면서 청소 및 이물질 제거를 수행하고 표면 건조 작업을 동시에 수행하는 단계; (d) 상기 이물질이 제거된 절삭면에 상기 (a)에서 준비된 교면 포장 보수용 모르타르 조성물을 타설하는 단계; 및 (e) 상기 타설된 교면 포장 보수용 모르타르 조성물을 양생시키고 표면을 마무리하는 단계;를 포함하여 구성되며, 상기 (1)의 하소포졸라나는 천연 포졸라나 100 중량부에 칼슘 1~20 중량부를 혼합한 혼합물을 1000~1200℃에서 0.5~1 시간 동안 소성한 후 평균입도가 10~20 ㎛가 되도록 분쇄한 것을 특징으로 하고, 상기 교면 포장 보수용 모르타르 조성물이 양생된 후에 코팅제를 도포하는 것을 더 포함하되, 상기 코팅제는 에폭시 수지 10~50중량%, 폴리메틸메타크릴레이트 수지 5~40 중량%, 희석제 1~25중량%, 응집제 0.1~15중량%, 무기물 충전재 1~20중량%, 촉진제 0.1~5중량%, 유화제 0.05~20중량% 및 물 10~80중량%를 혼합하여 얻어지는 주재 성분 100 중량부에 대하여, 수용성 오일 1~20 중량%, 유화제 1~10중량%, 촉진제 5~20 중량% 및 물 50~90 중량%를 혼합하여 수용액을 제조하고, 상기 얻어진 수용액 100 중량부를 기준으로 폴리아미드 5~50중량부 및 아민 화합물 0.1~40중량부를 혼합하여 얻어지는 경화제 성분을 5~50 중량비로 혼합한 에폭시 코팅제를 사용하는 것을 특징으로 하는 교면 포장 보수 공법이 공지되어 있다.In addition, in Korean Patent Registration No. 10-1710300 (registration date February 20, 2017), (a) preparing a mortar composition for repairing a bridge pavement, the mortar composition for repairing a bridge pavement is (1) 50 to 100 weight of cement parts, 0.5 to 10 parts by weight of clinker, 0.5 to 10 parts by weight of plaster, 0.5 to 10 parts by weight of alpha hemihydrate gypsum, 0.1 to 5 parts by weight of silica fume, 0.01 to 5 parts by weight of fly ash, 0.5 to 10 parts by weight of limestone, blast furnace 10 to 70% by weight of a first powder component comprising 1 to 20 parts by weight of slag, 0.01 to 10 parts by weight of calcinar slag, and 0.01 to 10 parts by weight of microsilica; and 2 to 7 parts by weight of a siliceous waterproofing agent, 5 to 15 parts by weight of a CSA-based expansion material, 0.05 to 0.2 parts by weight of a viscosity enhancer, 0.3 to 1.1 parts by weight of a fluidizing agent, 0.1 to 0.5 parts by weight of a curing accelerator, 0.1 to 0.4 parts by weight of a retarder and 100 parts by weight of a powder component comprising 30 to 90% by weight of a second powder component including 42 to 64 parts by weight of silica sand; (2) One or more types of powder or liquid rubber selected from EVA (Ethylene-vinyl acetate) resin, NR (Natural rubber) resin, NBR (Natural rubber-Butadiene rubber) resin, and SBR (Styrene-Butadiene rubber) resin 1 to 20 parts by weight of a modified latex component obtained by mixing cement with ultra-velocity cement, carbon black, and fibers in a resin; (3) 1 to 7 parts by weight of methyl methacrylate, 5 to 20 parts by weight of styrene monomer, 1 to 10 parts by weight of normal butyl acrylate, 0.1 to 10 parts by weight of methyl acrylate, 0.1 to 10 parts by weight of isobornyl acrylate, 1 to 20 parts by weight of a liquid component comprising 0.05 to 5 parts by weight of an initiator and 0.05 to 5 parts by weight of an emulsifier; (4) 1-10 parts by weight of hydrophilic polyvinyl alcohol short fiber component; (5) 1-5 parts by weight of an additive component consisting of a mixture of a preservative, an anti-foaming agent, and a wetting agent; and (6) 10 to 50 parts by weight of water; a filler and aggregate are mixed with the bridge pavement repair agent comprising: 5 to 50 parts by weight of the bridge surface pavement repair agent, 10 to 40 parts by weight of the filler, and 20 to 70 weight of the aggregate Preparing a mortar composition for bridge pavement repair consisting of mixing parts; (b) Break the damaged part of the bridge pavement, but only partially crush the upper part of the reinforcement so that the internal reinforcement is not damaged, mark the installation location of the reinforcement on the upper surface of the bridge surface pavement, and perform the crushing operation while avoiding the marked point And, when the upper part of the reinforcement is crushed, using a waterjet device to spray the high pressure to cut the crushed part to crush the damaged part of the bridge surface pavement; (c) The crushed part is cut by high-pressure water spraying and foreign substances present on the cutting surface are removed, but cleaning and foreign substances are removed while moving in the longitudinal direction of the bridge using a vacuum suction vehicle, and the surface drying operation is performed simultaneously to do; (d) pouring the mortar composition for bridge pavement repair prepared in (a) on the cutting surface from which the foreign material is removed; and (e) curing the poured mortar composition for bridge pavement repair and finishing the surface; It is characterized in that the mixed mixture is calcined at 1000 to 1200° C. for 0.5 to 1 hour, and then pulverized to have an average particle size of 10 to 20 μm. Including, wherein the coating agent is an epoxy resin 10-50% by weight, polymethyl methacrylate resin 5-40% by weight, diluent 1-25% by weight, coagulant 0.1-15% by weight, inorganic filler 1-20% by weight, accelerator 0.1 To 100 parts by weight of the main ingredient obtained by mixing ~5% by weight, 0.05~20% by weight of an emulsifier, and 10~80% by weight of water, 1 to 20% by weight of a water-soluble oil, 1 to 10% by weight of an emulsifier, 5 to 20% by weight of an accelerator % and 50 to 90 wt% of water to prepare an aqueous solution, and 5 to 50 parts by weight of a curing agent component obtained by mixing 5 to 50 parts by weight of polyamide and 0.1 to 40 parts by weight of an amine compound based on 100 parts by weight of the obtained aqueous solution in a 5 to 50 weight ratio A bridge pavement repair method is known, characterized in that it uses a mixed epoxy coating agent.

또한, 한국등록특허 10-1825635(등록일자 2018년01월30일)에는 초속경 시멘트 15 w% 내지 19w%, 메타카올린 0.5w% 내지 1w%, 감수제 1w% 내지 2w%, 재료분리방지제 1w% 내지 2w%를 포함하는 무기계 결합재; 알루미나(Al2O3) 1w% 내지 2w%, 산화티탄(TiO2) 0.5w% 내지 1w%, 실리카(SiO2) 1 w% 내지 3w%, 산화칼슘(CaO) 1w% 내지 3w%, 탄화규소(silicon carbide,Sic) 0.5w% 내지 1w%, 질화붕소(Boron nitride,BN) 0.5w% 내지 1w%를 포함하는 무기계 충진재; 폴리머 결합재 4.5w% 내지 6.5w%를 포함하는 고분자 수지 조성물; 폴리프로필렌 섬유 0.5w% 내지 1w%를 포함하는 섬유조성물; 및 규사 65w% 내지 69w%를 포함하는 도로 또는 교면 포장조성물이 공지되어 있다.In addition, Korea Patent No. 10-1825635 (registration date January 30, 2018) has 15w% to 19w% of super-fast cement, 0.5w% to 1w% of metakaolin, 1w% to 2w% of water reducing agent, 1w% of material separation preventing agent to 2w% of an inorganic binder; Alumina (Al2O3) 1w% to 2w%, titanium oxide (TiO2) 0.5w% to 1w%, silica (SiO2) 1w% to 3w%, calcium oxide (CaO) 1w% to 3w%, silicon carbide, Sic) 0.5w% to 1w%, boron nitride (Boron nitride, BN) 0.5w% to 1w% inorganic filler containing; A polymer resin composition comprising 4.5w% to 6.5w% of a polymer binder; A fiber composition comprising 0.5w% to 1w% of polypropylene fibers; And a road or bridge pavement composition comprising 65w% to 69w% of silica sand is known.

또한, 한국등록특허 10-1931321(등록일자 2018년12월14일)에는 메타크릴산메틸(Methyl Methacrylate) 구조와 불포화 폴리에스테르 구조를 구비하는 수지상의 MMA폴리머를 포함하는 A부; 및 상기 A부와 혼합되어 보수재를 이루고, 혼합된 후에 설정 시간 내에 경화되도록 세라믹 파우더 형태로 이루어지며, 탄산칼슘, 마이크로 실리카, 고강도 규사6호, 고강도 규사5호, 무기질 증점제 및 경화개시제를 포함하여 이루어지는 B부를 포함하고, 상기 A부는, 12~18중량부로 혼합되는 상기 MMA폴리머를 포함하고, 상기 B부는, 32~28중량부로 혼합되는 상기 탄산칼슘, 2~8중량부로 혼합되는 상기 마이크로 실리카, 32~38중량부로 혼합되는 상기 고강도 규사6호, 7~13중량부로 혼합되는 상기 고강도 규사5호, 01~05중량부로 혼합되는 상기 무기질 증점제 및 03~09중량부로 혼합되는 경화개시제를 포함하고, 상기 무기질 증점제는, 벤토나이트 파우더를 포함하고, 상기 경화개시제는, 과산화망간 또는 과산화벤조일(benzoyl peroxide)을 포함하고, 상기 A부는, 무색투명하며, 30~35cps의 점도를 이루어지고, 106±002의 비중을 갖으며, 44±2중량부의 불휘발분을 갖는 2액형 액상 아크릴 변성 불포화 폴리에스테르 수지로 이루어지는 초속경 교량 상판 보수재 조성물에 있어서, 상기 A부는, 수지 형태로 이루어지고, 상기 B부는, 세라믹 파우더 형태로 이루어지므로 상기 A부와 상기 B부를 각각 별도로 수납하여 교량 상판 보수작업이 진행되는 현장으로 이동한 후에 현장에서 상기 A부와 상기 B부를 혼합하여 보수재를 제조하고, 상기 초속경 교량 상판 보수재 조성물은, 시공 가능온도 영하20℃~영상35℃와, 습도 10%이내와, 가사시간 10~15분과, 경화시간(20℃ 기준) 30~40분의 작업조건을 만족하는 것을 특징으로 하는 초속경 교량 상판 보수재 조성물이 공지되어 있다.In addition, Korean Patent No. 10-1931321 (registration date December 14, 2018) discloses a part A comprising a dendritic MMA polymer having a methyl methacrylate structure and an unsaturated polyester structure; And it is mixed with the A part to form a water retaining material, and is made in the form of ceramic powder to harden within a set time after mixing, including calcium carbonate, micro silica, high-strength silica sand No. 6, high-strength silica sand No. 5, inorganic thickener and curing initiator. Including part B consisting of, wherein part A contains the MMA polymer mixed in 12 to 18 parts by weight, and the B part, the calcium carbonate mixed in 32 to 28 parts by weight, the micro silica mixed in 2 to 8 parts by weight, The high-strength silica sand No. 6 mixed in 32 to 38 parts by weight, the high-strength silica sand No. 5 mixed in 7 to 13 parts by weight, the inorganic thickener mixed in 01 to 05 parts by weight, and a curing initiator mixed in 03 to 09 parts by weight, The inorganic thickener includes bentonite powder, the curing initiator includes manganese peroxide or benzoyl peroxide, and the A part is colorless and transparent, and has a viscosity of 30 to 35 cps, of 106 ± 002 In the super-velocity bridge top plate repair material composition comprising a two-component liquid acrylic modified unsaturated polyester resin having a specific gravity and having a nonvolatile content of 44±2 parts by weight, the A part is in the form of a resin, and the B part is a ceramic powder Since it is made in the form of, the A part and the B part are separately accommodated, and after moving to the site where the bridge deck repair work is in progress, the repair material is prepared by mixing the A part and the B part at the site, and the super-velocity bridge top plate repair material composition Silver, which is characterized in that it satisfies the working conditions of a workable temperature of -20°C to +35°C, a humidity of less than 10%, a pot life of 10 to 15 minutes, and a curing time of 30 to 40 minutes (based on 20°C). A bridge deck repair material composition is known.

또한, 한국등록특허 10-1982186(등록일자 2019년05월20일)에는 바이오 폴리머를 포함한 초속경 개질 모르타르 조성물을 이용한 교면 포장보수방법에 있어서, 교면 보수 대상 표면의 이물질을 제거한 후 청소하는 보수 대상 표면 청소단계; 청소된 보수 대상 표면에 프라이머층을 형성하는 프라이머층 형성 단계; 바이오 폴리머를 포함한 초속경 개질 모르타르 조성물을 포설하는 조성물 포설 단계; 바이오 폴리머를 포함한 초속경 개질 모르타르 조성물을 양생하는 양생단계; 조성물 포설 단계와 양생 단계 사이에는 표면 보호제를 분무하는 표면 보호제 분무단계; 프라이머층 형성 단계에 적용되는 프라이머층은 우레탄메타아크릴레이트수지, 에폭시메타아크릴레이트수지 또는 폴리에스테르메타아크릴레이트 수지 중에서 1종 이상의 메타아크릴레이트 수지, 중합성 불포화단량체 및 경화제를 포함하는 1액형 또는 2액형 프라이머 조성물을 포함하는 것; 표면 보호제는 수용성 폴리우레탄, 스티렌-부타디엔 라텍스, 아크릴 에멀젼, 에틸비닐 아세테이트, 실란계 화합물 및 변성 규산나트륨 화합물 중 선택된 1종 이상의 물질을 포함하는 것; 바이오 폴리머는 분말화 단계를 거쳐 분말화된 괭생이모자반으로 형성되는 것; 상기 분말화 단계는 괭생이모자반 수거단계, 괭생이모자반 세척단계, 세척된 괭생이모자반 염도 측정단계, 괭생이모자반 건조단계, 건도된 괭생이모자반 방부단계, 괭생이모자반 분쇄단계로 이루어지는 것; 상기 괭생이모자반 세척단계는 세척수의 염분이 0.1%이하에서 이루어지는 것; 괭생이모자반 건조단계는 건조기에서 건조온도 60~80℃로 형성되는 것;을 포함하는 것을 특징으로 하는 바이오폴리머를 포함한 초속경 개질 모르타르 조성물을 이용한 교면 포장 보수방법이 공지되어 있다.In addition, Korean Patent No. 10-1982186 (registration date, May 20, 2019) discloses a method for repairing a bridge pavement using a super-fast diameter modified mortar composition including a biopolymer, a repair target that removes foreign substances from the surface of the bridge surface and then cleans it surface cleaning step; A primer layer forming step of forming a primer layer on the cleaned surface to be repaired; A composition installation step of installing a super-fast diameter modified mortar composition including a biopolymer; Curing step of curing the ultra-fast diameter modified mortar composition including the biopolymer; Between the composition installation step and the curing step, a surface protection agent spraying step of spraying the surface protection agent; The primer layer applied in the primer layer forming step is a one-component or two-component type comprising at least one methacrylate resin, a polymerizable unsaturated monomer, and a curing agent among urethane methacrylate resin, epoxy methacrylate resin, or polyester methacrylate resin. comprising a liquid primer composition; The surface protecting agent includes at least one material selected from water-soluble polyurethane, styrene-butadiene latex, acrylic emulsion, ethylvinyl acetate, silane-based compound, and modified sodium silicate compound; The biopolymer is formed into a powdered hoesaengi hat through a powdering step; The powdering step is a hoesaeng hat collecting step, a hoesaeng hat washing step, a washed hoesaeng hat salinity measurement step, a hoesaeng hat drying step, a dried hoesaeng hat preserving step, What consists of a grinding step; The hoesaengi hat washing step is made in less than 0.1% of the salinity of the washing water; A method of repairing a bridge pavement using a modified mortar composition containing a biopolymer comprising a;

또한, 한국등록특허 10-2075365(등록일자 2020년02월04일)에는 시멘트 결합제 100 중량부에 대하여 골재 100 내지 500 중량부, 물 1 내지 20 중량부, 아크릴 라텍스 결합제 1 내지 20 중량부 및 케나프 섬유와 폴리유산 섬유가 5 내지 7 : 3 내지 5 중량비로 혼합된 섬유보강재 1 내지 20중량부를 포함하며, 상기 케나프 섬유는 섬도가 30 내지 100 dtex이며, 섬유장이 1 내지 10㎝이며, 표면을 폴리도파민을 포함하는 코팅액으로 코팅한 것을 특징으로 하는 교면 포장용 조성물이 공지되어 있다.In addition, Korean Patent No. 10-2075365 (registration date, February 04, 2020) describes 100 to 500 parts by weight of aggregate, 1 to 20 parts by weight of water, 1 to 20 parts by weight of an acrylic latex binder, and 1 to 20 parts by weight of an acrylic latex binder based on 100 parts by weight of a cement binder. Naph fiber and polylactic acid fiber 5 to 7: contains 1 to 20 parts by weight of a fiber reinforcement mixed in a 3 to 5 weight ratio, the kenaf fiber has a fineness of 30 to 100 dtex, the fiber length is 1 to 10 cm, the surface A composition for paving a bridge is known, characterized in that it is coated with a coating solution containing polydopamine.

또한, 본 출원인이 츨원하여 특허받은 것으로, 한국등록특허 10-2105860(등록일자 2020년04월23일)에는 초속경시멘트 100중량부에 대하여, 고로슬래그분말 15~20중량부와; 플라이애시 5~20중량부와; 무수황산나트륨(Na2SO4), 무수황산칼슘(CaSO4)를 각각 동일중량비로 혼합한 무기자극제 5-10중량부와; 칼슘설포알루미네이트(3CaO·3Al2O3·CaSO4) 5~10중량부와; 도데카칼슘헵타알루미네이트(12CaO·7Al2O3) 3~5중량부와; 물 30~50중량부와; 에피클로로히드린(epichlorohydrine) 및 비스페놀A(bisphenol-A)에폭시수지를 1 : 1 중량비로 포함하는 주제와 폴리아마이드 경화제를 혼합한 에폭시수지 조성물을 접착, 방수, 균열방지, 내마모성, 내후성 보강제로 5중량부; 포함하는 것을 특징으로 하는 고로슬래그분말 및 플라이애시를 사용한 초속경 콘크리트 교면포장 조성물이 공지되어 있다.In addition, the present applicant filed a patent application, and the Korean Patent Registration No. 10-2105860 (registration date, April 23, 2020) has 15 to 20 parts by weight of blast furnace slag powder with respect to 100 parts by weight of cement per second; 5 to 20 parts by weight of fly ash; 5-10 parts by weight of an inorganic irritant prepared by mixing anhydrous sodium sulfate (Na2SO4) and anhydrous calcium sulfate (CaSO4) in the same weight ratio; 5 to 10 parts by weight of calcium sulfoaluminate (3CaO·3Al2O3·CaSO4); 3 to 5 parts by weight of dodecacalcium heptaaluminate (12CaO·7Al2O3); 30-50 parts by weight of water; An epoxy resin composition mixed with a polyamide curing agent and a main agent containing epichlorohydrine and bisphenol-A epoxy resin in a 1:1 weight ratio is used as an adhesive, waterproof, crack prevention, abrasion resistance, and weather resistance reinforcing agent 5 parts by weight; There is known a super-velocity concrete bridge pavement composition using blast furnace slag powder and fly ash, characterized in that it comprises.

또한, 본 출원인이 츨원하여 역시 특허받은 것으로, 한국등록특허 10-2105862(등록일자 2020년04월23일)에는 초속경시멘트 100중량부와; 입자크기 12~25mm로 분급된 페로니켈슬래그 잔골재 200~250중량부와; 셀룰로오스계 증점제, 아크릴계 증점제 및 폴리에틸렌 옥사이드계 증점제가 각각 동일중량비로 혼합된 혼합증점제 5~20중량부와; 물 50~80중량부와; 칼슘설포알루미네이트(3CaO·3Al2O3·CaSO4) 10~20중량부와; 도데카칼슘헵타알루미네이트(12CaO·7Al2O3) 3~5중량부와; 에피클로로히드린(epichlorohydrine) 및 비스페놀A(bisphenol-A)에폭시수지를 1 : 1 중량비로 포함하는 주제와 폴리아마이드 경화제를 혼합한 에폭시수지 조성물을 접착, 방수, 균열방지,내마모성, 내후성 보강제로 5중량부;포함하는 것을 특징으로 하는 분급된 페로니켈 슬래그 잔골재를 사용한 초속경 콘크리트 교면포장 조성물이 공지되어 있다.In addition, the present applicant filed a patent application, and Korean Patent Registration No. 10-2105862 (registration date April 23, 2020) includes 100 parts by weight of cement per second; 200 to 250 parts by weight of ferronickel slag fine aggregate classified into a particle size of 12 to 25 mm; 5-20 parts by weight of a mixed thickener in which a cellulose-based thickener, an acrylic-based thickener, and a polyethylene oxide-based thickener are each mixed in the same weight ratio; 50 to 80 parts by weight of water; 10-20 parts by weight of calcium sulfoaluminate (3CaO·3Al2O3·CaSO4); 3 to 5 parts by weight of dodecacalcium heptaaluminate (12CaO·7Al2O3); An epoxy resin composition mixed with a polyamide curing agent and a main agent containing epichlorohydrine and bisphenol-A epoxy resin in a 1:1 weight ratio is used as an adhesive, waterproof, crack prevention, abrasion resistance, and weather resistance reinforcing agent 5 Part by weight; Concrete bridge pavement composition is known per second using classified ferronickel slag fine aggregate, characterized in that it comprises.

또한, 한국등록특허 10-2127329(등록일자 2020년06월22일)에는 초속경 교면포장 및 보수용 콘크리트 조성물에 있어서, 포틀랜드 시멘트 100중량부, 초속경 시멘트 60 중량부 내지 80중량부, 칼슘설포알루미네이트계 팽창제 3중량부 내지 30중량부, 수축저감제 5중량부 내지 20중량부, 석고 1중량부 내지 20중량부 및 고로 슬래그 미분말 10중량부 내지 50중량부로 구성되는 무기결합재와, 무기결합재 100중량부에 대하여, 잔골재 100 중량부 내지 200중량부, 굵은골재 100중량부 내지 200중량부, 물 10중량부 내지 50중량부 및 라텍스 5중량부 내지 30중량부와 무기상변화 물질 01중량부 내지 5중량부로 구성되는 것; 상기 라텍스 5중량부 내지 30중량부에는 나프탈렌, 프로필라마이트, 아세트아마이드, 폴리글리콜, 글리세롤, 사이안아마이드, 에틸렌다이아민, 펜타에리트리콜 중 어느 하나 이상의 조합으로 구성된 유기 상변화 물질 0.1중량부 내지 5중량부가 별도로 혼합되는 것; 상기 라텍스에 표면장력 저감제를 혼합하며, 상기 표면장력 저감제는 글리콜 에테르, 에톡시프로폭시화 알코올 및 첨가제로 형성되며, 상기 표면장력 저감제는 라텍스 5중량부 내지 30중량부에 0.5중량부 내지 3중량부로 혼합되는 것; 상기 무기 상변화 물질 1중량부와 유기 상변화 물질 1중량부로 나뉘어 각각 무기 결합제와 라텍스에 혼합되는 것; 상기 표면장력 저감제는 라텍스0.5중량부 내지 3중량부가 별도로 혼입되며, 라텍스에 포함되는 표면장력 저감제는 글리콜 에테르, 에톡시프로폭시화 알코올 및 첨가제로 형성되며, 상기 표면장력 저감제는 80 내지 90 중량%의 글리콜 에테르, 5 내지 15 중량%의 에톡시프로폭시화 알코올 및 5 중량% 미만의 첨가제로 형성되는 것;을 포함하는 초속경 교면포장 및 보수용 콘크리트 조성물이 공지되어 있다.In addition, Korean Patent No. 10-2127329 (registration date, June 22, 2020) discloses that in the concrete composition for paving and repairing a bridge with an ultra-high speed, 100 parts by weight of Portland cement, 60 parts by weight to 80 parts by weight of cement with an ultra high speed, calcium sulfo An inorganic binder consisting of 3 parts by weight to 30 parts by weight of an aluminate-based expanding agent, 5 parts by weight to 20 parts by weight of a shrinkage reducing agent, 1 part by weight to 20 parts by weight of gypsum, and 10 parts by weight to 50 parts by weight of fine blast furnace slag powder, and an inorganic binder. With respect to 100 parts by weight, 100 parts by weight to 200 parts by weight of fine aggregate, 100 parts by weight to 200 parts by weight of coarse aggregate, 10 parts by weight to 50 parts by weight of water, and 5 parts by weight to 30 parts by weight of latex and 01 parts by weight of inorganic phase change material to Consisting of 5 parts by weight; 5 to 30 parts by weight of the latex contains 0.1 parts by weight of an organic phase change material consisting of a combination of any one or more of naphthalene, propylamide, acetamide, polyglycol, glycerol, cyanamide, ethylenediamine, and pentaerythricol. 5 parts by weight are separately mixed; A surface tension reducing agent is mixed with the latex, and the surface tension reducing agent is formed of glycol ether, ethoxypropoxylated alcohol and additives, and the surface tension reducing agent is 0.5 parts by weight to 5 to 30 parts by weight of latex to be mixed in 3 parts by weight; divided into 1 part by weight of the inorganic phase change material and 1 part by weight of the organic phase change material and mixed with an inorganic binder and latex, respectively; The surface tension reducing agent is 0.5 parts by weight to 3 parts by weight of latex is mixed separately, the surface tension reducing agent contained in the latex is formed of glycol ether, ethoxypropoxylated alcohol and additives, the surface tension reducing agent is 80 to Concrete compositions for bridging and repair are known, comprising: 90% by weight of glycol ether, 5 to 15% by weight of ethoxypropoxylated alcohol and less than 5% by weight of additives.

그러나, 종래의 상기 개질 콘크리트 또는 폴리머 콘크리트 교면포장재 조성물들은 초속경성, 균열발생 억제효과, 방수성, 부착성능의 향상에는 효과가 있으나, 일정 두께의 시멘트 콘크리트 또는 폴리머 콘크리트 층을 확보하여야 하므로 재료비 상승 등 공사 비용이 증가하거나, 교면포장 보수시 일정 두께의 교면포장을 박리하여야 하는 등 경제성 문제가 있으며, 교면포장의 사하중이 증가할 수 밖에 없어 교량의 내구성이 취약하며, 특히, 별도의 방수층을 시공해야 하는 등 여러 문제점이 있었다.However, the conventional modified concrete or polymer concrete bridge surface paving material compositions are effective in super-fast hardness, cracking suppression effect, waterproofness, and improvement of adhesion performance, but a certain thickness of cement concrete or polymer concrete layer must be secured, so material cost increases, etc. There are economic problems such as increased cost or the need to peel off the bridge pavement of a certain thickness when repairing the bridge pavement. There were several problems such as

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본 발명은 상기 종래 문제점을 해결하기 위한 것으로, 물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 반응성 유화제와, 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 및 탄산칼슘 충전재를 포함하는 무기계 결합재;를 포함하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물 및 이를 이용한 교면박층포장 시공공법을 제공하는 것을 해결하고자 하는 과제로 한다.The present invention is to solve the above conventional problems, water, methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), a reactive emulsifier, a copolymerization initiator, The first subject (A), which is an acrylic copolymer resin containing an alkalizing agent and a peroxide curing agent, and a second subject (B), which is a reinforcing resin containing an unsaturated polyester resin and a peroxide curing agent, and the chemical composition of polymer concrete an organic binder comprising a silane-based coupling agent (C) which is a crosslinking agent for increasing adhesion; Garnet sludge for abrasives or garnet sludge for waterjet cutting is recovered and recycled from fine garnet aggregate with a particle size of 0.05 to 2 mm and an inorganic binder containing calcium carbonate filler; including methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate It is a task to solve to provide a polymer concrete mortar composition for thin layer pavement for bridges and a construction method for thin layer pavement for bridges using the same.

본 발명은 상기 과제를 해결하기 위하여, 물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 반응성 유화제와, 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 및 탄산칼슘 충전재를 포함하는 무기계 결합재;를 포함하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 과제의 해결수단으로 한다.In order to solve the above problems, the present invention provides water, methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), a reactive emulsifier, a copolymerization initiator, and an alkalizing agent And the first subject (A), which is an acrylic copolymer resin containing a peroxide curing agent, and the second subject (B), which is a reinforcing resin containing an unsaturated polyester resin and a peroxide curing agent, and the chemical adhesive strength of polymer concrete an organic binder comprising a silane-based coupling agent (C), which is a crosslinking agent for increasing; Garnet sludge for abrasives or garnet sludge for waterjet cutting is recovered and recycled from fine garnet aggregate with a particle size of 0.05 to 2 mm and an inorganic binder containing calcium carbonate filler; including methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate Polymer concrete mortar composition for thin layer pavement for bridges is a solution to the problem.

상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은, 물 100중량부에 대하여, 메틸메타크릴레이트(MMA) 40~50중량부, 2-에틸헥실아크릴레이트(2-EHAM) 50~70중량부 및 메타크릴산(MAAC) 10~20중량부와, 반응성 유화제 5~20중량부와, 공중합 개시제 5~7중량부와, 알칼리화제 1~2중량부 및 과산화물 경화제 3~5중량부를 포함하는 아크릴계 공중합수지인 제1주제(A) 20~30중량부와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 10~30중량부 및 과산화물 경화제 2~7중량부를 포함하는 보강수지인 제2주제(B) 5~10중량부와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C) 5~7중량부를 포함하여 조성되는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 50~70중량부 및 탄산칼슘 충전재 10~20중량부를 포함하여 조성되는 무기계 결합재;를 포함하는 것을 과제의 해결수단으로 한다.The methyl methacrylate (MMA)-based acrylic resin and the polymer concrete mortar composition for thin layer pavement for bridges containing fine garnet aggregate is, based on 100 parts by weight of water, 40-50 parts by weight of methyl methacrylate (MMA), 2-ethylhexyl 50 to 70 parts by weight of acrylate (2-EHAM) and 10 to 20 parts by weight of methacrylic acid (MAAC), 5 to 20 parts by weight of a reactive emulsifier, 5 to 7 parts by weight of a copolymerization initiator, and 1 to 2 parts by weight of an alkalizing agent 20-30 parts by weight of the first main (A), which is an acrylic copolymer resin containing parts and 3-5 parts by weight of a peroxide curing agent, 10-30 parts by weight of an unsaturated polyester resin, and 2-7 parts by weight of a peroxide curing agent An organic binder composed of 5 to 10 parts by weight of the second main agent (B), which is a reinforcing resin, and 5 to 7 parts by weight of a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete; Inorganic binder composed of 50 to 70 parts by weight of fine garnet aggregate having a particle size of 0.05 to 2 mm and 10 to 20 parts by weight of calcium carbonate filler; do it by means

상기 반응성 유화제는 음이온계 반응성 유화제인 소듐도데실벤젠설포네이트(Sodium dodecylbenzene sulfonate ; SDBS), 소듐폴리옥시에틸렌알킬페닐에테르설페이트(Sodium polyoxyethylene alkyl phenyl ether sulfate ; SPAS), 비이온계 반응성 유화제인 폴리옥시에틸렌노닐페닐에테르(Polyoxyethylene nonylphenyl ether ; POENPE)로 선택되는 어느 하나인 것을 과제의 해결수단으로 한다. The reactive emulsifier is an anionic reactive emulsifier sodium dodecylbenzene sulfonate (SDBS), sodium polyoxyethylene alkyl phenyl ether sulfate (SPAS), a nonionic reactive emulsifier polyoxy Ethylene nonylphenyl ether (Polyoxyethylene nonylphenyl ether; POENPE) to be any one selected as a means of solving the problem.

상기 공중합 개시제는 과황산암모늄(Ammonium persulfate ; APS) 및 메타중아황산나트륨(Sodium metabisulfite ; SMBS)을 1:1 중량비율로 혼합된 것을 과제의 해결수단으로 한다.The copolymerization initiator uses ammonium persulfate (APS) and sodium metabisulfite (SMBS) in a 1:1 weight ratio to solve the problem.

상기 알칼리화제는 탄산수소나트륨(Sodium bicarbonate)인 것을 과제의 해결수단으로 한다.The alkalizing agent is sodium bicarbonate as a means of solving the problem.

상기 과산화물 경화제는 벤질퍼옥사이드(Benzoyl Peroxide), 터셔리부틸하이드로퍼옥사이드(Tert-butyl hydroperoxide : t-BHP) 또는 메틸에틸케톤퍼옥사이드(Methyethylketoneperoxide ; MEKPO)인 것을 과제의 해결수단으로 한다.The peroxide curing agent is benzyl peroxide (Benzoyl Peroxide), tert-butyl hydroperoxide (t-BHP) or methyl ethyl ketone peroxide (Methyethylketoneperoxide; MEKPO) as a means of solving the problem.

상기 실란계 커플링제는 3-메틸아크릴옥시비닐실란(3-methylacryloxyviny1 silane ; MAOS)인 것을 과제의 해결수단으로 한다.The silane-based coupling agent is 3-methylacryloxyviny1 silane (MAOS) as a means of solving the problem.

상기 회수 재활용되는 가넷 잔골재는 비중 3.4~3.9g/cm, 모스(MOHS)경도 6.0~8.0인 것을 과제의 해결수단으로 한다.The collected and recycled garnet fine aggregate has a specific gravity of 3.4 to 3.9 g/cm and a Mohs (MOHS) hardness of 6.0 to 8.0 as a means of solving the problem.

상기 탄산칼슘 충전재는 그 사용량의 50중량%를 고로슬래그분말 또는 플라이애시분말로 대체 사용하는 것을 과제의 해결수단으로 한다.As a means of solving the problem, 50% by weight of the calcium carbonate filler used is replaced with blast furnace slag powder or fly ash powder.

상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은 경화시간이 1~2시간, 압축강도는 20-40MPa, 휨강도 5-15MPa인 것을 과제의 해결수단으로 한다.The methyl methacrylate (MMA)-based acrylic resin and the polymer concrete mortar composition for thin layer pavement for bridges comprising fine garnet aggregate has a curing time of 1 to 2 hours, a compressive strength of 20-40 MPa, and a flexural strength of 5-15 MPa. do it with

한편, 본 발명은, 신규 교면포장을 위한 교면표면을 청소하거나, 기존 교면포장의 열화부, 손상부 또는 오염부를 제거하는 전처리 단계와; 상기 전처리된 교면표면에 상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 물에 10~20중량% 농도로 희석한 것을 프라이머로 도포하는 프라이머 도포단계와; 상기 도포된 프라이머 도포면에 상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 타설하여 경화시켜 교면박층포장하는 단계;를 포함하는 교면박층포장 시공공법을 과제의 해결수단으로 한다.On the other hand, the present invention, cleaning the bridge surface for a new bridge surface pavement, or a pre-treatment step of removing the deteriorated, damaged or contaminated portion of the existing bridge surface pavement; A primer application step of diluting the polymer concrete mortar composition for thin layer paving of bridges containing the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate in water to a concentration of 10 to 20% by weight on the pretreated bridge surface as a primer. Wow; The step of pouring and curing the polymer concrete mortar composition for thin layer paving of bridges including the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate on the coated surface of the primer, and curing it to pave the bridges in thin layers; as a means of solving the problem.

본 발명의 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모크타르 조성물 및 이를 이용한 교면박층포장 시공공법은, 물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 반응성 유화제와, 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화폴리에스터수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 및 탄산칼슘 충전재를 포함하는 무기계 결합재;를 포함하는 폴리머 콘크리트 모크타르 조성물로 시공되어 교면포장 두께를 얇게 하여 교면포장의 사하중을 감소시키고, 교면포장의 시공 또는 보수가 간편하여 공사비용절감 및 공사기간을 단축할 수 있으며, 방수층이 없어도 방수성능이 우수하여 교량의 내구성을 향상시키는 효과가 있다.The polymer concrete mochtar composition for thin layer pavement for bridges comprising methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate of the present invention and the construction method for thin layer paving for bridges using the same include water, methyl methacrylate (MMA), 2-ethyl Hexyl acrylate (2-EHAM) and methacrylic acid (MAAC), a reactive emulsifier, a copolymerization initiator, an acrylic copolymer resin comprising an alkalizing agent and a peroxide curing agent, the first main agent (A), and an unsaturated polyester resin ( Unsaturated polyester resin) and an organic binder comprising a second main agent (B) as a reinforcing resin containing a peroxide curing agent, and a silane-based coupling agent (C) as a crosslinking agent for increasing the chemical adhesion of polymer concrete; Garnet sludge for abrasives or garnet sludge for waterjet cutting is recovered and recycled from fine garnet aggregate with a particle size of 0.05 to 2 mm and an inorganic binder including calcium carbonate filler. It reduces the dead weight of the pavement, and the construction or repair of the bridge pavement is easy to reduce the construction cost and shorten the construction period.

도 1은 연마재용 가넷슬러지로부터 회수 재활용된 가넷 잔골재 입자사진
도 2는 워터젯커팅용 가넷슬러지로부터 회수 재활용된 가넷 잔골재 입자사진
1 is a photograph of garnet fine aggregate particles recovered and recycled from garnet sludge for abrasives;
2 is a photograph of garnet fine aggregate particles recovered and recycled from garnet sludge for water jet cutting.

본 발명은, 물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 반응성 유화제와, 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 및 탄산칼슘 충전재를 포함하는 무기계 결합재;를 포함하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 기술구성의 특징으로 한다.The present invention includes water, methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), a reactive emulsifier, a copolymerization initiator, an alkalizer and a peroxide curing agent. The first subject (A) which is an acrylic copolymer resin, the second subject (B) which is a reinforcing resin containing an unsaturated polyester resin and a peroxide curing agent, and silane which is a crosslinking agent for increasing the chemical adhesion of polymer concrete an organic binder comprising a coupling agent (C); Garnet sludge for abrasives or garnet sludge for waterjet cutting is recovered and recycled from fine garnet aggregate with a particle size of 0.05 to 2 mm and an inorganic binder containing calcium carbonate filler; including methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate A polymer concrete mortar composition for thin-layer paving of bridges is characterized by its technical configuration.

상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은, 물 100중량부에 대하여, 메틸메타크릴레이트(MMA) 40~50중량부, 2-에틸헥실아크릴레이트(2-EHAM) 50~70중량부 및 메타크릴산(MAAC) 10~20중량부와, 반응성 유화제 5~20중량부와, 공중합 개시제 5~7중량부와, 알칼리화제 1~2중량부 및 과산화물 경화제 3~5중량부를 포함하는 아크릴계 공중합수지인 제1주제(A) 20~30중량부와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 10~30중량부 및 과산화물 경화제 2~7중량부를 포함하는 보강수지인 제2주제(B) 5~10중량부와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C) 5~7중량부를 포함하여 조성되는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 50~70중량부 및 탄산칼슘 충전재 10~20중량부를 포함하여 조성되는 무기계 결합재;를 포함하는 것을 기술구성의 특징으로 한다.The methyl methacrylate (MMA)-based acrylic resin and the polymer concrete mortar composition for thin layer pavement for bridges containing fine garnet aggregate is, based on 100 parts by weight of water, 40-50 parts by weight of methyl methacrylate (MMA), 2-ethylhexyl 50 to 70 parts by weight of acrylate (2-EHAM) and 10 to 20 parts by weight of methacrylic acid (MAAC), 5 to 20 parts by weight of a reactive emulsifier, 5 to 7 parts by weight of a copolymerization initiator, and 1 to 2 parts by weight of an alkalizing agent 20-30 parts by weight of the first main (A), which is an acrylic copolymer resin containing parts and 3-5 parts by weight of a peroxide curing agent, 10-30 parts by weight of an unsaturated polyester resin, and 2-7 parts by weight of a peroxide curing agent An organic binder composed of 5 to 10 parts by weight of the second main agent (B), which is a reinforcing resin, and 5 to 7 parts by weight of a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete; An inorganic binder composed of 50 to 70 parts by weight of fine garnet aggregate having a particle size of 0.05 to 2 mm and 10 to 20 parts by weight of a calcium carbonate filler; characterized.

상기 반응성 유화제는 음이온계 반응성 유화제인 소듐도데실벤젠설포네이트(Sodium dodecylbenzene sulfonate ; SDBS), 소듐폴리옥시에틸렌알킬페닐에테르설페이트(Sodium polyoxyethylene alkyl phenyl ether sulfate ; SPAS), 비이온계 반응성 유화제인 폴리옥시에틸렌노닐페닐에테르(Polyoxyethylene nonylphenyl ether ; POENPE)로 선택되는 어느 하나인 것을 기술구성의 특징으로 한다. The reactive emulsifier is an anionic reactive emulsifier sodium dodecylbenzene sulfonate (SDBS), sodium polyoxyethylene alkyl phenyl ether sulfate (SPAS), a nonionic reactive emulsifier polyoxy Ethylene nonylphenyl ether (Polyoxyethylene nonylphenyl ether; POENPE) is characterized in that any one selected from the technical configuration.

상기 공중합 개시제는 과황산암모늄(Ammonium persulfate ; APS) 및 메타중아황산나트륨(Sodium metabisulfite ; SMBS)을 1:1 중량비율로 혼합된 것을 기술구성의 특징으로 한다.The copolymerization initiator is characterized in that it is a mixture of ammonium persulfate (Ammonium persulfate; APS) and sodium metabisulfite (SMBS) in a 1:1 weight ratio.

상기 알칼리화제는 탄산수소나트륨(Sodium bicarbonate)인 것을 기술구성의 특징으로 한다.The alkalizing agent is characterized in that the technical configuration is sodium bicarbonate (Sodium bicarbonate).

상기 과산화물 경화제는 벤질퍼옥사이드(Benzoyl Peroxide), 터셔리부틸하이드로퍼옥사이드(Tert-butyl hydroperoxide : t-BHP) 또는 메틸에틸케톤퍼옥사이드(Methyethylketoneperoxide ; MEKPO)인 것을 기술구성의 특징으로 한다.The peroxide curing agent is benzyl peroxide (Benzoyl Peroxide), tert-butyl hydroperoxide (T-BHP) or methyl ethyl ketone peroxide (Methyethylketoneperoxide; MEKPO) is characterized in the technical configuration.

상기 실란계 커플링제는 3-메틸아크릴옥시비닐실란(3-methylacryloxyviny1 silane ; MAOS)인 것을 기술구성의 특징으로 한다.The silane-based coupling agent is characterized in that the technical configuration is 3-methylacryloxyviny1 silane (MAOS).

상기 회수 재활용되는 가넷 잔골재는 비중 3.4~3.9g/cm, 모스(MOHS)경도 6.0~8.0인 것을 기술구성의 특징으로 한다.The recovered and recycled garnet fine aggregate has a specific gravity of 3.4 to 3.9 g/cm and a Mohs (MOHS) hardness of 6.0 to 8.0.

상기 탄산칼슘 충전재는 그 사용량의 50중량%를 고로슬래그분말 또는 플라이애시분말로 대체 사용하는 것을 기술구성의 특징으로 한다.The calcium carbonate filler is characterized in that 50% by weight of the amount used is replaced with blast furnace slag powder or fly ash powder.

상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은 경화시간이 1~2시간, 압축강도는 20-40MPa, 휨강도 5-15MPa인 것을 기술구성의 특징으로 한다.The polymer concrete mortar composition for thin layer pavement for bridges comprising the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate has a curing time of 1 to 2 hours, a compressive strength of 20-40 MPa, and a flexural strength of 5-15 MPa. do it with

또한, 본 발명은, 신규 교면포장을 위한 교면표면을 청소하거나, 기존 교면포장의 열화부, 손상부 또는 오염부를 제거하는 전처리 단계와; 상기 전처리된 교면표면에 상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 물에 10~20중량% 농도로 희석한 것을 프라이머로 도포하는 프라이머 도포단계와; 상기 도포된 프라이머 도포면에 상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 타설하여 경화시켜 교면박층포장하는 단계;를 포함하는 교면박층포장 시공공법을 기술구성의 특징으로 한다.In addition, the present invention, cleaning the bridge surface for a new bridge pavement, or a pre-treatment step of removing the deteriorated, damaged or contaminated part of the existing bridge pavement; A primer application step of diluting the polymer concrete mortar composition for thin layer paving of bridges containing the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate in water to a concentration of 10 to 20% by weight on the pretreated bridge surface as a primer. Wow; The step of pouring and curing the polymer concrete mortar composition for thin layer paving of bridges including the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate on the coated surface of the primer, and curing it to pave the bridges in thin layers; It is characterized by the technical composition.

이하에서는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 본 발명의 실시예 및/또는 도면을 통하여 상세히 설명한다. 그러나 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며, 여기에서 설명하는 실시예 및/또는 도면에 한정되지 않는다.Hereinafter, embodiments and/or drawings of the present invention will be described in detail so that those of ordinary skill in the art can easily carry out the present invention. However, the present invention may be embodied in many different forms, and is not limited to the embodiments and/or drawings described herein.

우선, 본 발명의 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은, 물 100중량부에 대하여, 메틸메타크릴레이트(MMA) 40~50중량부, 2-에틸헥실아크릴레이트(2-EHAM) 50~70중량부 및 메타크릴산(MAAC) 10~20중량부와, 반응성 유화제 5~20중량부와, 공중합 개시제 5~7중량부와, 알칼리화제 1~2중량부 및 과산화물 경화제 3~5중량부를 포함하는 아크릴계 공중합수지인 제1주제(A) 20~30중량부와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 10~30중량부 및 과산화물 경화제 2~7중량부를 포함하는 보강수지인 제2주제(B) 5~10중량부와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C) 5~7중량부를 포함하여 조성되는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 50~70중량부 및 탄산칼슘 충전재 10~20중량부를 포함하여 조성되는 무기계 결합재;를 포함하여 조성된다.First, the polymer concrete mortar composition for thin layer pavement for bridges containing the methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate of the present invention is, based on 100 parts by weight of water, 40 to 50 parts by weight of methyl methacrylate (MMA), 50 to 70 parts by weight of 2-ethylhexyl acrylate (2-EHAM) and 10 to 20 parts by weight of methacrylic acid (MAAC), 5 to 20 parts by weight of a reactive emulsifier, 5 to 7 parts by weight of a copolymerization initiator, and an alkalizing agent 20-30 parts by weight of the first main (A), which is an acrylic copolymer resin containing 1-2 parts by weight and 3-5 parts by weight of a peroxide curing agent, 10-30 parts by weight of an unsaturated polyester resin, and a peroxide curing agent 2 An organic-based composition comprising 5 to 10 parts by weight of the second main agent (B), which is a reinforcing resin containing ~7 parts by weight, and 5 to 7 parts by weight, a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete. a binder; An inorganic binder composed of 50 to 70 parts by weight of fine garnet aggregate having a particle size of 0.05 to 2 mm and 10 to 20 parts by weight of a calcium carbonate filler;

이때, 상기 아크릴계 공중합수지 조성물에 사용되는 메틸메타아크릴레이트(methylmethacrylate; MMA) 수지는 무색 투명한 액체로 C4 유분을 원료로 하여 제조된 터트-부틸 알코올(Tert-Butyl Alcohol; TBA)을 기체상태에서 산화시켜 메타아크릴산을 제조한 후, 메탄올로 에스테르화하여 제조한 것으로서, 즉, 아크릴산과 메타크릴산 에스테르의 중합반응공정을 거쳐 이중 탄소결합을 갖도록 만든 반응형 수지이며, CH2=C(CH3)CO2CH3의 화학식을 갖는다. At this time, the methyl methacrylate (MMA) resin used in the acrylic copolymer resin composition is a colorless and transparent liquid that oxidizes tert-butyl alcohol (TBA) prepared from C4 oil as a raw material in a gaseous state. It is a reactive resin made to have double carbon bonds through a polymerization reaction process of acrylic acid and methacrylic acid ester, which is produced by esterification with methanol after preparing methacrylic acid, CH 2 =C(CH 3 ) It has the chemical formula of CO 2 CH 3 .

이러한, 메틸메타아크릴레이트(MMA) 수지는 경질 타입이면서 유연성이 있고, 저온에서 라디칼 중합하면 고분자 사슬구조가 연속된 규칙성을 나타내는 신디오탁틱(Syndiotactic) 구조의 비율이 증가하는 특성을 나타내므로 내구성, 내열성, 내화학성, 내마모성, UV안전성 등 물성이 뛰어나며, 햇빛 등의 날씨 및 기후에 견디는 성질인 내후성이 우수하여 외부 환경 변화(날씨 및 기후 변화)에 의한 부식 등을 억제함과 동시에 콘크리트 구조체로 침투하여 일체화 시켜줌으로써 부착강도 및 인성을 개선하고, 안료 등에 의한 착색성이 좋은 특성이 있으며, 높은 열팽창 계수를 갖지만, 안정성이 매우 높은 수지이므로 투명성, 내후성, 착색성이 우수하여 많은 분야에서 사용되고 있다. This methyl methacrylate (MMA) resin is a hard type and flexible, and when radical polymerization at low temperature, the ratio of the syndiotactic structure showing continuous regularity of the polymer chain structure is increased, so it is durable. It has excellent physical properties such as heat resistance, chemical resistance, abrasion resistance, UV safety, etc. By penetrating and integrating, it improves adhesion strength and toughness, has good colorability by pigments, etc., has a high coefficient of thermal expansion, but is a highly stable resin, so it is used in many fields because of its excellent transparency, weather resistance, and colorability.

그러나, 상기 메틸메타아크릴레이트(MMA) 수지는 수지량의 2~5% 정도 소량의 경화제를 첨가하면 경화를 시작하는데, 경화 개시 후 1시간 이내에 완전히 경화가 완료되는 초속경성 수지이고, 통상 작업 가능시간은 20분 내외로서 작업성이 우수하여 넓은 면적에 포설 및 마무리를 수행할 수 있으며, 이러한 MMA수지는 경화 후 그 강도가 대단히 우수하나 내균열성 및 휨추종성이 부족할 뿐만 아니라 바탕체와의 열팽창 특성이 상이함으로 인해, 실내가 아닌 야외에서 사용할 경우 균열이 발생하기 쉽다는 문제점이 있었다.However, the methyl methacrylate (MMA) resin starts curing when a small amount of curing agent is added about 2 to 5% of the resin amount. The time is about 20 minutes and it has excellent workability, so it can be installed and finished in a large area. This MMA resin has very good strength after hardening, but it lacks crack resistance and warpage followability, as well as thermal expansion characteristics with the substrate. Due to this difference, there is a problem that cracks are easy to occur when used outdoors rather than indoors.

이에 따라 본 발명에서는 상기 메틸메타아크릴레이트(MMA) 수지의 단점을 보완하기 위하여 물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 반응성 유화제와, 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재를 가넷 잔골재 및 탄산칼슘 충전재와 혼합하여 모르타르로 조성한 것이 특징적 구성이다.Accordingly, in the present invention, water, methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), A first main agent (A), which is an acrylic copolymer resin containing a reactive emulsifier, a copolymerization initiator, an alkalizing agent, and a peroxide curing agent, and a reinforcing resin containing an unsaturated polyester resin (Unsaturated polyester resin) and a peroxide curing agent The second main agent ( B) and an organic binder including a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete, is mixed with fine garnet aggregate and calcium carbonate filler to form a mortar.

여기서, 상기 아크릴계 공중합수지인 제1주제(A)는 물 100중량부에 대하여, 메틸메타크릴레이트(MMA) 40~50중량부, 2-에틸헥실아크릴레이트(2-EHAM) 50~70중량부 및 메타크릴산(MAAC) 10~20중량부와, 반응성 유화제 5~20중량부와, 공중합 개시제 5~7중량부와, 알칼리화제 1~2중량부 및 과산화물 경화제 3~5중량부를 포함하는 조성물이 공중합되는 것으로 상기 각 성분 함량범위를 벗어나는 경우에는 경화물성에 영향이 있으므로 상기 각 성분 함량범위가 유지되는 것이 바람직하다.Here, the first subject (A), which is the acrylic copolymer resin, is based on 100 parts by weight of water, 40 to 50 parts by weight of methyl methacrylate (MMA), 50 to 70 parts by weight of 2-ethylhexyl acrylate (2-EHAM) And 10 to 20 parts by weight of methacrylic acid (MAAC), 5 to 20 parts by weight of a reactive emulsifier, 5 to 7 parts by weight of a copolymerization initiator, 1 to 2 parts by weight of an alkalizing agent, and 3 to 5 parts by weight of a peroxide curing agent. When the content of each component is out of the range of the copolymerization, it is preferable that the content of each component is maintained because the cured properties are affected.

이때, 상기 반응성 유화제는 음이온계 반응성 유화제인 소듐도데실벤젠설포네이트(Sodium dodecylbenzene sulfonate ; SDBS), 소듐폴리옥시에틸렌알킬페닐에테르설페이트(Sodium polyoxyethylene alkyl phenyl ether sulfate ; SPAS), 비이온계 반응성 유화제인 폴리옥시에틸렌노닐페닐에테르(Polyoxyethylene nonylphenyl ether ; POENPE)로 선택되는 어느 하나인 것을 사용한다.At this time, the reactive emulsifier is an anionic reactive emulsifier sodium dodecylbenzene sulfonate (SDBS), sodium polyoxyethylene alkyl phenyl ether sulfate (SPAS), a nonionic reactive emulsifier Use any one selected from polyoxyethylene nonylphenyl ether (POENPE).

또한, 상기 공중합 개시제는 과황산암모늄(Ammonium persulfate ; APS) 및 메타중아황산나트륨(Sodium metabisulfite ; SMBS)을 1:1 중량비율로 혼합한 것을 사용하는 것이 바람직하다.In addition, as the copolymerization initiator, it is preferable to use a mixture of ammonium persulfate (APS) and sodium metabisulfite (SMBS) in a 1:1 weight ratio.

또한, 상기 알칼리화제는 탄산수소나트륨(Sodium bicarbonate)을 사용하는 것이 바람직하다.In addition, it is preferable to use sodium bicarbonate as the alkalinizing agent.

한편, 상기 아크릴계 공중합수지인 제1주제(A)에 혼합되는 보강수지인 제2주제(B)는 불포화 폴리에스터 수지(Unsaturated polyester resin) 10~30중량부 및 과산화물 경화제 2~7중량부를 포함하여 조성되는 것으로 5~10중량부 사용한다.On the other hand, the second subject (B), which is a reinforcing resin mixed with the first main (A), which is the acrylic copolymer resin, includes 10 to 30 parts by weight of an unsaturated polyester resin and 2 to 7 parts by weight of a peroxide curing agent. 5 to 10 parts by weight is used as a composition.

이때, 상기 불포화 폴리에스터 수지(Unsaturated polyester resin)는 여러 수지에 비해 기계적, 내약품성이 우수하고, 경화성이 뛰어나며, 상온에서도 자유롭게 경화시킬 수 있으므로 본 발명의 제1주제(A)인 아크릴계 공중합수지의 물성보강과 시공속도향상을 위한 보강수지로 혼합사용한다.At this time, the unsaturated polyester resin (Unsaturated polyester resin) has excellent mechanical and chemical resistance, excellent curability, and can be freely cured even at room temperature compared to other resins. It is mixed and used as a reinforcing resin for reinforcing physical properties and improving construction speed.

또한, 본 발명의 폴리머 콘크리트 모르타르 조성물의 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 5~7중량부 사용하며, 이때 상기 실란계 커플링제(C)는 3-메틸아크릴옥시비닐실란(3-methylacryloxyviny1 silane ; MAOS)인 것을 사용하는 것이 바람직하다.In addition, 5 to 7 parts by weight of a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete of the polymer concrete mortar composition of the present invention, is used, wherein the silane-based coupling agent (C) is 3-methyl It is preferable to use acryloxyvinylsilane (3-methylacryloxyviny1 silane; MAOS).

또한, 상기 아크릴계 공중합수지인 제1주제(A)와, 보강수지인 제2주제(B)에 사용되는 상기 과산화물 경화제는 벤질퍼옥사이드(Benzoyl Peroxide), 터셔리부틸하이드로퍼옥사이드(Tert-butyl hydroperoxide : t-BHP) 또는 메틸에틸케톤퍼옥사이드(Methyethylketoneperoxide ; MEKPO)인 것을 사용하는 것이 바람직하다.In addition, the peroxide curing agent used in the first subject (A), which is the acrylic copolymer resin, and the second main (B), which is a reinforcing resin, is benzyl peroxide, tert-butyl hydroperoxide : t-BHP) or methyl ethyl ketone peroxide (MEKPO) is preferably used.

아울러, 상기 회수 재활용되는 가넷 잔골재는 비중 3.4~3.9g/cm, 모스(MOHS)경도 6.0~8.0인 것을 사용한다.In addition, the collected and recycled garnet fine aggregate uses a specific gravity of 3.4 to 3.9 g/cm and a Mohs (MOHS) hardness of 6.0 to 8.0.

특히, 가넷은 규산염광물로서 다양한 성분으로 구성되고 규사를 포함하는 잔골재보다 높은 경도 및 비중을 가지고 있어 다음 [표 1] 및 [도 1]에 나타난 바와 같이, 샌드블라스팅 등의 연마재용으로 사용되거나, 또는 다음 [표 2] 및 [도 2]에 나타난 바와 같이, 워터젯 커팅용으로 사용되므로, 본 발명에서는 상기 가넷의 높은 경도 및 비중에 의한 교면박층포장의 강도 보강 및 교면박층포장의 내구성을 향상시키기 위해 사용한다.In particular, as a silicate mineral, garnet is composed of various components and has a higher hardness and specific gravity than fine aggregates containing silica sand, so as shown in the following [Table 1] and [Fig. 1], it is used for abrasives such as sandblasting, Or, as shown in the following [Table 2] and [Fig. 2], since it is used for waterjet cutting, in the present invention, the strength of the bridge-face thin-layer pavement is reinforced by the high hardness and specific gravity of the garnet and the durability of the bridge-face thin-layer pavement is improved. use for

Figure 112021014014951-pat00001
Figure 112021014014951-pat00001

Figure 112021014014951-pat00002
Figure 112021014014951-pat00002

이때, 상기 가넷은 유기계 결합재 사용량의 약 2배인 50~70중량부 사용하는 것이 바람직한데, 상기 범위 미만이면 가넷이 유기계 결합재 내에 침전될 가능성이 있으며, 상기 범위를 초과하면 수지함량이 적어 탈리 또는 소실될 우려가 있다.At this time, it is preferable to use 50 to 70 parts by weight of the garnet, which is about twice the amount of the organic binder used, if it is less than the above range, the garnet may be precipitated in the organic binder. there is a risk of becoming

또한, 상기 탄산칼슘 충전재는 10~20중량부 사용할 수 있으며, 이때, 그 사용량의 50중량%를 고로슬래그분말 또는 플라이애시분말로 대체 사용하는 것도 가능하다.In addition, 10 to 20 parts by weight of the calcium carbonate filler may be used, and at this time, 50% by weight of the amount used may be replaced with blast furnace slag powder or fly ash powder.

여기서, 고로슬래그는 용광로 제선과정 중에서 발생하는 것으로서 통상 Ca, Si, Al 등의 이온을 포함할 수 있어 시멘트 대체체로 사용될 수 있는데, 고온 용융 상태의 고로슬래그를 냉각하여 분쇄한 비결정질 분말이며, 플라이애시는 미분탄을 연소하는 보일러의 연도 가스로부터 집진기로 채취한 석탄재를 말하는데, 구상인 입자 크기는 시멘트와 같은 정도이고, 알루미나(Al2O3)와 실리카(SiO2)가 주성분이며, 콘크리트의 혼화재로 사용되므로 본 발명에서는 탄산칼슘 충전재를 대체하는 대체충전재로 사용된다.Here, the blast furnace slag is generated during the ironmaking process of the blast furnace and may contain ions such as Ca, Si, and Al, and thus can be used as a substitute for cement. refers to the coal ash collected by a dust collector from the flue gas of a boiler that burns pulverized coal. The spherical particle size is about the same as that of cement, and alumina (Al2O3) and silica (SiO2) are the main components, and it is used as an admixture for concrete. It is used as an alternative filler to replace calcium carbonate filler.

상기와 같은, 본 발명의 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은 경화시간이 1~2시간, 압축강도는 20-40MPa, 휨강도 5-15MPa의 물성을 발휘하여 교면포장에서 요구하는 물성을 만족할 수 있다.As described above, the polymer concrete mortar composition for bridge surface thin-layer pavement comprising the methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate of the present invention has a curing time of 1 to 2 hours, a compressive strength of 20-40 MPa, and a flexural strength of 5-15 MPa It can satisfy the physical properties required for bridge pavement by exhibiting the physical properties of

한편, 본 발명의 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 이용한 교면박층포장 시공공법은, 신규 교면포장을 위한 교면표면을 청소하거나, 기존 교면포장의 열화부, 손상부 또는 오염부를 제거하는 전처리 단계와; 상기 전처리된 교면표면에 상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 물에 10~20중량% 농도로 희석한 것을 프라이머로 도포하는 프라이머 도포단계와; 상기 도포된 프라이머 도포면에 상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 타설하여 경화시켜 교면박층포장하는 단계;를 포함하는 공법에 의하여 시공될 수 있다.On the other hand, the thin-layer bridge pavement construction method using the polymer concrete mortar composition for thin-layer bridge pavement comprising the methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate of the present invention is to clean the bridge surface for a new bridge surface pavement, or to clean the bridge surface for the existing bridge surface. A pretreatment step of removing the deteriorated, damaged or contaminated portion of the packaging; A primer application step of diluting the polymer concrete mortar composition for thin layer paving of bridges containing the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate in water to a concentration of 10 to 20% by weight on the pretreated bridge surface as a primer. Wow; It can be constructed by a method comprising; pouring a polymer concrete mortar composition for thin layer paving of bridges containing the methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate on the coated surface of the primer, hardening it and paving the bridges in thin layers; there is.

[본 발명의 교면박층포장용 폴리머 콘크리트 모르타르 조성물의 제조][Production of polymer concrete mortar composition for bridge surface thin-layer pavement of the present invention]

물 100kg, 메틸메타크릴레이트(MMA) 50kg, 2-에틸헥실아크릴레이트(2-EHAM) 60kg, 메타크릴산(MAAC) 20kg, 소듐도데실벤젠설포네이트 10kg, 과황산암모늄(APS) 2.5kg, 메타중아황산나트륨(SMBS) 2.5kg, 탄산수소나트륨(Sodium bicarbonate) 1kg, 터셔리부틸하이드로퍼옥사이드(t-BHP) 3kg을 포함하는 아크릴계 공중합수지 제1주제(A) 25kg과, 불포화 폴리에스터 수지(Unsaturated polyester resin) 2~6kg 및 MEKPO 0.7kg을 포함하는 보강수지인 제2주제(B) 7kg와, 3-methylacryloxyviny1 silane(MAOS) 5kg를 혼합한 유기계 결합재와; 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재(대구 유진텍) 60kg와; 탄산칼슘 충전재 10kg;를 혼합한 무기계 결합재;를 혼합하여 본 발명의 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 제조하였다.100 kg of water, 50 kg of methyl methacrylate (MMA), 60 kg of 2-ethylhexyl acrylate (2-EHAM), 20 kg of methacrylic acid (MAAC), 10 kg of sodium dodecylbenzenesulfonate, 2.5 kg of ammonium persulfate (APS), 25 kg of the first main acrylic copolymer resin (A) containing 2.5 kg of sodium metabisulfite (SMBS), 1 kg of sodium bicarbonate, and 3 kg of tert-butyl hydroperoxide (t-BHP), and an unsaturated polyester resin ( Unsaturated polyester resin) 2~6kg and MEKPO 0.7kg of reinforcing resin (B) 7kg, 3-methylacryloxyviny1 silane (MAOS) 5kg organic binder mixed; 60 kg of fine garnet aggregate (Daegu Eugene Tech) with a particle size of 0.05 to 2 mm that is recovered and recycled from garnet sludge for waterjet cutting; A polymer concrete mortar composition for bridge surface thin-layer paving of the present invention was prepared by mixing 10 kg of calcium carbonate filler and an inorganic binder mixed with it.

[물성측정][Measurement of physical properties]

KS F 2425 "시험실에서 콘크리트 시료를 만드는 방법"에 따라, 콘크리트 바닥판을 제작하였다. 그리고, 그 상면에 위에서 본 발명의 프라이머 조성물을 도포하고, 상기 [실시예 1]의 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 15mm 두께로 도포하고 경화시켜 시험체를 제조하고, 다음 [표 3]의 각 시험방법에 따라 물성을 측정하고 그 결과를 나타내었다.According to KS F 2425 "Method for making concrete samples in a laboratory," a concrete floor plate was manufactured. Then, the primer composition of the present invention is applied from above on the upper surface, and the polymer concrete mortar composition for bridge surface thin-layer pavement of [Example 1] is applied to a thickness of 15 mm and cured to prepare a test body, and each test in the following [Table 3] The physical properties were measured according to the method and the results are shown.

함목ship 기준값reference value 실시예 1Example 1 시험방법Test Methods 압축강도(MPa)Compressive strength (MPa) 21 이상over 21 33.533.5 KS F 2405KS F 2405 휨강도(MPa)Flexural strength (MPa) 4.5 이상4.5 or higher 12.512.5 KS F 2408KS F 2408 부착강도(MPa)Adhesive strength (MPa) 1.4 이상1.4 or later 4.34.3 KS F 2762KS F 2762

상기 [표 3]의 시험결과에 나타난 바와 같이, 본 발명의 교면박층포장용 폴리머 콘크리트 모르타르 조성물은 모든 물성에 있어서 기준값을 모두 훨씬 초과하여 만족하는 것을 알 수 있다.As shown in the test results in [Table 3], it can be seen that the polymer concrete mortar composition for thin layer pavement for bridge bridges of the present invention far exceeds the reference values in all physical properties and satisfies them.

[방수성능측정][Waterproof performance measurement]

KS F 4932 "교면용 도막 방수재"에 따라 방수성능을 측정하기 위해 상기 [실시예 1]에서 제조한 교면박층포장용 폴리머 콘크리트 모르타르 조성물의 인장강도, 전단접착강도, 인장접착강도, 내투수 성능을 측정하였다.In order to measure the waterproof performance in accordance with KS F 4932 "Paint waterproofing material for bridge surfaces", the tensile strength, shear adhesion strength, tensile adhesion strength, and permeability resistance of the polymer concrete mortar composition for thin layer pavement for bridge surfaces prepared in [Example 1] were measured. did.

그 결과, 본 발명의 교면박층포장용 폴리머 콘크리트 모르타르 조성물은 인장강도, 전단접착강도, 인장접착강도, 내투수 성능이 우수함을 확인할 수 있었다.As a result, it was confirmed that the polymer concrete mortar composition for thin layer paving for bridges of the present invention was excellent in tensile strength, shear adhesive strength, tensile adhesive strength, and water permeation resistance.

이상의 설명은 본 발명의 기술사상을 예시적으로 설명한 것에 불과한 것으로서, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 다양한 수정 및 변형이 가능할 것이다. 따라서, 본 발명에 개시된 실시예 및/또는 도면들은 본 발명의 기술 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 이러한 실시예 및/또는 도면에 의하여 본 발명의 기술 사상의 범위가 한정되는 것은 아니다. 본 발명의 보호 범위는 아래의 청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술 사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 할 것이다.The above description is merely illustrative of the technical idea of the present invention, and various modifications and variations will be possible without departing from the essential characteristics of the present invention by those skilled in the art to which the present invention pertains. Accordingly, the embodiments and/or drawings disclosed in the present invention are for explanation rather than limiting the technical spirit of the present invention, and the scope of the technical spirit of the present invention is not limited by these embodiments and/or drawings. . The protection scope of the present invention should be construed by the following claims, and all technical ideas within the scope equivalent thereto should be construed as being included in the scope of the present invention.

Claims (11)

물, 메틸메타크릴레이트(MMA), 2-에틸헥실아크릴레이트(2-EHAM) 및 메타크릴산(MAAC)과, 음이온계 반응성 유화제인 소듐도데실벤젠설포네이트(Sodium dodecylbenzene sulfonate ; SDBS), 소듐폴리옥시에틸렌알킬페닐에테르설페이트(Sodium polyoxyethylene alkyl phenyl ether sulfate ; SPAS), 비이온계 반응성 유화제인 폴리옥시에틸렌노닐페닐에테르(Polyoxyethylene nonylphenyl ether ; POENPE)로부터 선택되는 어느 하나의 반응성 유화제와, 과황산암모늄(Ammonium persulfate ; APS) 및 메타중아황산나트륨(Sodium metabisulfite ; SMBS)을 1:1 중량비율로 혼합한 공중합 개시제와, 알칼리화제 및 과산화물 경화제를 포함하는 아크릴계 공중합수지인 제1주제(A)와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 및 과산화물 경화제를 포함하는 보강수지인 제2주제(B)와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C)를 포함하는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 및 탄산칼슘 충전재를 포함하는 무기계 결합재;를 포함하는 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
Water, methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHAM) and methacrylic acid (MAAC), anionic reactive emulsifier sodium dodecylbenzene sulfonate (SDBS), sodium Any one reactive emulsifier selected from sodium polyoxyethylene alkyl phenyl ether sulfate (SPAS) and polyoxyethylene nonylphenyl ether (POENPE), which is a nonionic reactive emulsifier, and ammonium persulfate (Ammonium persulfate; APS) and sodium metabisulfite (Sodium metabisulfite; SMBS) a copolymerization initiator mixed in a weight ratio of 1:1, an acrylic copolymer resin comprising an alkalizing agent and a peroxide curing agent The first subject (A) and unsaturated An organic binder comprising a second main agent (B), which is a reinforcing resin containing unsaturated polyester resin and a peroxide curing agent, and a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete; Methyl methacrylate (MMA)-based acrylic resin and Polymer concrete mortar composition for bridge surface thin-layer pavement containing fine garnet aggregate
제1항에 있어서,
상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은, 물 100중량부에 대하여, 메틸메타크릴레이트(MMA) 40~50중량부, 2-에틸헥실아크릴레이트(2-EHAM) 50~70중량부 및 메타크릴산(MAAC) 10~20중량부와, 반응성 유화제 5~20중량부와, 공중합 개시제 5~7중량부와, 알칼리화제 1~2중량부 및 과산화물 경화제 3~5중량부를 포함하는 아크릴계 공중합수지인 제1주제(A) 20~30중량부와, 불포화 폴리에스터 수지(Unsaturated polyester resin) 10~30중량부 및 과산화물 경화제 2~7중량부를 포함하는 보강수지인 제2주제(B) 5~10중량부와, 폴리머 콘크리트의 화학적 접착력을 증대시키기 위한 가교제인 실란계 커플링제(C) 5~7중량부를 포함하여 조성되는 유기계 결합재와; 연마재용 가넷슬러지 또는 워터젯 커팅용 가넷슬러지로부터 회수 재활용되는 입자크기 0.05~2mm의 가넷 잔골재 50~70중량부 및 탄산칼슘 충전재 10~20중량부를 포함하여 조성되는 무기계 결합재;를 포함하는 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
According to claim 1,
The methyl methacrylate (MMA)-based acrylic resin and the polymer concrete mortar composition for thin layer pavement for bridges containing fine garnet aggregate is, based on 100 parts by weight of water, 40-50 parts by weight of methyl methacrylate (MMA), 2-ethylhexyl 50 to 70 parts by weight of acrylate (2-EHAM) and 10 to 20 parts by weight of methacrylic acid (MAAC), 5 to 20 parts by weight of a reactive emulsifier, 5 to 7 parts by weight of a copolymerization initiator, and 1 to 2 parts by weight of an alkalizing agent 20-30 parts by weight of the first main (A), which is an acrylic copolymer resin containing parts and 3-5 parts by weight of a peroxide curing agent, 10-30 parts by weight of an unsaturated polyester resin, and 2-7 parts by weight of a peroxide curing agent An organic binder composed of 5 to 10 parts by weight of the second main agent (B), which is a reinforcing resin, and 5 to 7 parts by weight of a silane-based coupling agent (C), which is a crosslinking agent for increasing the chemical adhesion of polymer concrete; An inorganic binder composed of 50 to 70 parts by weight of fine garnet aggregate having a particle size of 0.05 to 2 mm and 10 to 20 parts by weight of a calcium carbonate filler, which is recovered and recycled from garnet sludge for abrasives or garnet sludge for waterjet cutting; Polymer concrete mortar composition for bridge surface thin-layer paving comprising methyl methacrylate (MMA)-based acrylic resin and fine garnet aggregate
삭제delete 삭제delete 제2항에 있어서,
상기 알칼리화제는 탄산수소나트륨(Sodium bicarbonate)인 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
3. The method of claim 2,
The alkalizing agent is sodium bicarbonate (sodium bicarbonate), characterized in that the methyl methacrylate (MMA)-based acrylic resin and a polymer concrete mortar composition for thin layer pavement bridges comprising fine garnet aggregate
제2항에 있어서,
상기 과산화물 경화제는 벤질퍼옥사이드(Benzoyl Peroxide), 터셔리부틸하이드로퍼옥사이드(Tert-butyl hydroperoxide : t-BHP) 또는 메틸에틸케톤퍼옥사이드(Methyethylketoneperoxide ; MEKPO)인 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
3. The method of claim 2,
The peroxide curing agent is benzyl peroxide (Benzoyl Peroxide), tert-butyl hydroperoxide (T-BHP) or methyl ethyl ketone peroxide (Methyethylketoneperoxide; MEKPO), characterized in that methyl methacrylate (MMA) Polymer concrete mortar composition for thin layer pavement for bridges containing )-based acrylic resin and fine garnet aggregate
제2항에 있어서,
상기 실란계 커플링제는 3-메틸아크릴옥시비닐실란(3-methylacryloxyviny1 silane ; MAOS)인 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
3. The method of claim 2,
The silane-based coupling agent is 3-methylacryloxyviny1 silane (MAOS), characterized in that the methyl methacrylate (MMA)-based acrylic resin and a polymer concrete mortar composition for thin layer pavement bridges comprising garnet fine aggregate
제2항에 있어서,
상기 회수 재활용되는 가넷 잔골재는 비중 3.4~3.9g/cm, 모스(MOHS)경도 6.0~8.0인 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
3. The method of claim 2,
The recovered and recycled garnet fine aggregate has a specific gravity of 3.4 to 3.9 g/cm and a Mohs (MOHS) hardness of 6.0 to 8.0. composition
제2항에 있어서,
상기 탄산칼슘 충전재는 그 사용량의 50중량%를 고로슬래그분말 또는 플라이애시분말로 대체 사용하는 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
3. The method of claim 2,
The calcium carbonate filler is a polymer concrete mortar composition for thin layer pavement for bridges comprising a methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate, characterized in that 50% by weight of the amount used is replaced with blast furnace slag powder or fly ash powder.
제2항에 있어서,
상기 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물은 경화시간이 1~2시간, 압축강도는 20-40MPa, 휨강도 5-15MPa인 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물
3. The method of claim 2,
The methyl methacrylate (MMA)-based acrylic resin and the polymer concrete mortar composition for thin layer pavement for bridges comprising the fine garnet aggregate has a curing time of 1 to 2 hours, a compressive strength of 20-40 MPa, and a flexural strength of 5-15 MPa. Polymer concrete mortar composition for bridge surface thin-layer pavement comprising methacrylate (MMA)-based acrylic resin and fine garnet aggregate
신규 교면포장을 위한 교면표면을 청소하거나, 기존 교면포장의 열화부, 손상부 또는 오염부를 제거하는 전처리 단계와; 상기 전처리된 교면표면에 제1항 내지 제2항, 제5항 내지 제10항중 어느 한 항에 따른 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 물에 10~20중량% 농도로 희석한 것을 프라이머로 도포하는 프라이머 도포단계와; 상기 도포된 프라이머 도포면에 제1항 내지 제2항, 제5항 내지 제10항중 어느 한 항에 따른 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 타설하여 경화시켜 교면박층포장하는 단계;를 포함하는 것을 특징으로 하는 메틸메타크릴레이트(MMA)계 아크릴수지 및 가넷 잔골재를 포함하는 교면박층포장용 폴리머 콘크리트 모르타르 조성물을 이용한 교면박층포장 시공공법A pretreatment step of cleaning the bridge surface for the new bridge pavement or removing the deteriorated, damaged or contaminated part of the existing bridge pavement; A polymer concrete mortar composition for thin layer pavement of a bridge comprising the methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate according to any one of claims 1 to 2 and 5 to 10 on the pretreated bridge surface. A primer application step of applying a primer diluted to a concentration of 10 to 20% by weight in water as a primer; A polymer concrete mortar composition for thin layer pavement for bridges comprising the methyl methacrylate (MMA)-based acrylic resin and garnet fine aggregate according to any one of claims 1 to 2 and 5 to 10 on the applied primer surface. A thin layer paving construction method for bridges using a polymer concrete mortar composition for thin layer pavement for bridges, comprising the step of pouring, curing and paving the bridges in thin layers;
KR1020210015388A 2021-02-03 2021-02-03 Polymer concrete mortar composition for bridge deck thin facing pavement comprising methylmethacrylate resin and garnet fine aggregate and the construction method bridge deck thin facing pavement thereof KR102288279B1 (en)

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