KR102259319B1 - Makeup powder cosmetic composition with excellent coverage effect and skin-affinity, and method of preparing the same - Google Patents

Abstract

The present invention relates to a cosmetic composition comprising coated boron nitride, sericite and a paste-like oil binder. The color powder cosmetic composition of the present invention has excellent adhesion and spreadability while naturally excellent coverage without cloudiness. In addition, the cosmetic has excellent molding stability and drop stability. The color powder cosmetic composition of the present invention does not cause makeup agglomeration due to agglomeration of oil and particles, and smooth and uniform makeup expression is possible because skin makeup is expressed smoothly.

Description

Color powder cosmetic composition with excellent coverage and adhesion, and a method for preparing the same

The present invention relates to a color powder cosmetic composition comprising coated boron nitride, sericite, and a paste oil binder, which has excellent coverage and adhesion and smooth skin expression will be.

Common base makeup cosmetics include liquid foundation or solid foundation. Liquid foundation is a water-in-oil type foundation and is widely used because it is strong against sweat, sebum, and makeup collapse. A solid foundation has better coverage than a liquid foundation, but there is a limit because it is heavy in wearability and spreadability when applied to the skin. There are compacts, two-way cakes, pressed powders or compressed pacts in which powder is the main ingredient, and the purpose of the product is to cover blemishes or blemishes, and to give skin coverage and express bright skin at the same time. will be.

The makeup cosmetics should have application properties, adhesion properties, and makeup durability. In particular, liquid foundation is advantageous for showing soft application and moist feeling, but it is somewhat lacking in durability, and solid foundation has technical limitations to improve to a level where you can feel the moist feeling of use, and makeup lifting caused by agglomeration of particles may occur. can

As a result of confirming the properties required for makeup cosmetics through consumer survey, the coverage and adhesion were in the highest ranking, and it was confirmed as the most required basic properties. This is a very important quality attribute when choosing a product.

In general, in powder makeup cosmetics, fine titanium oxide is blended as a method to improve coverage, which tends to cause stiffening of application and whitening of the skin. Since fine titanium oxide particles usually have a small average particle diameter of 0.2 to 0.3 μm, it is difficult to uniformly disperse them in a cosmetic and often exists in an aggregated state in a part of the cosmetic, so white is not conspicuous as an external color of the cosmetic. However, when the cosmetic is applied to the skin, the agglomeration of the fine particles is released and a strong white color appears, resulting in cloudiness.

In order to solve this disadvantage, Korean Patent Laid-Open Publication No. 10-2009-0069328 discloses a cosmetic film that does not float by supporting a group of particles made of titanium oxide on a flaky substrate, and coating the surface with a complex oxide including titanium and iron, and Although a method of imparting an appropriate hiding power has been proposed, the flaky powder used as the substrate has little covering power and the covering power varies depending on the amount and alignment of titanium oxide coated on the substrate, so there is a limitation in controlling the composite powder. In addition, there is a disadvantage in that it is difficult to provide a desired amount of coverage even when a large amount of the composite powder is blended into the cosmetic. In addition, Korean Patent No. 10-1648676 discloses that the porosity of porous polymethyl methacrylate (PMMA) is increased, and titanium dioxide nanoparticles are impregnated thereto to increase oil absorption, and a composite powder for cover pigments has been developed. However, since the average pore size of polymethyl methacrylate is 15 to 500 nm and the average particle size of titanium dioxide to be impregnated is 200 to 300 nm, theoretically, the impregnated composite powder can be easily manufactured, but it is usually The problem is that the yield of impregnated with is relatively low. In addition, a composite powder for skin cover pigment was developed by impregnating the content of titanium dioxide by 50% by weight relative to the total weight of the composite powder. There is a problem.

In addition, when titanium dioxide is used alone, it is very difficult to uniformly disperse it in the manufacturing process of cosmetics such as powder-like foundation as described above. The color tone of the makeup film at the time may be different. In addition, when the cosmetic is applied to the skin, a rough feeling peculiar to the fine titanium oxide is felt, so that the spreadability is lowered and the adhesion is not good. The rough feeling of titanium dioxide is also due to its shape, because most of titanium dioxide is composed of needle shape, rod shape, spindle shape, and the like.

In the case of powder foundation cosmetics, plate-shaped particles and spherical particles are appropriately mixed to control adhesion and spreadability. When the plate-shaped particles are mixed as much as possible, the adhesion is improved, the spreadability when applied to the skin is poor, and the cosmetics are not taken well by the cosmetic tools used when applying to the skin. In addition, a grazing phenomenon may occur when taking cosmetics using a cosmetic tool such as a puff or a brush. As another method, oil is used for molding in a powder-type foundation. There is a method of blending a high content of ester oil in the form of an oil binder as an oil binder, but there is a limit to blending ester oil because the total oil content is limited. have. In addition, various methods have been proposed, such as a method of modifying the surface of the powder with a natural wax or synthetic wax, and a formulation containing an oil-in-water emulsion binder including polyol, emulsion, starch or modified starch, etc. However, the methods are each has its limitations. When the powder surface is coated or modified with natural wax or synthetic wax, the effect is difficult to be sufficiently exhibited with a small amount, and when a large amount is coated, due to the unique stickiness and bonding strength of the wax, the surface is stained or the product is puffed. When the product is picked up with a brush or the like, a phenomenon in which the product is not taken, that is, a greasing or caking phenomenon may occur. In addition, a cosmetic of an oil-in-water emulsion formulation containing starch or modified starch and a mixture of polyol and emulsion takes a firing process to evaporate moisture in the formulation and improve stability. Since the remaining cosmetics become dry, adhesion may not be exhibited when applied to the skin. In addition, the plastic type makeup cosmetics have been tried to be formulated using a water dispersion binder, a water-in-oil type, or an oil-in-water emulsion binder, but there is a surface hardness and cracking peculiar to a plastic type cosmetic, and the drop stability is low and the color expression power is insufficient. There is one drawback.

As such, although coverage and adhesion are essential elements in makeup cosmetics, in particular, powder formulations have limitations in improving adhesion due to formulation characteristics. In addition, the powder-type compressed formulation may cause a caking phenomenon or a grazing phenomenon, and may result in a cosmetic clumping phenomenon or a cosmetic lifting phenomenon when the product is applied. As described above, various methods have been tried to improve the adhesion and coverage of the cosmetic, but the effectiveness is still insufficient and the effect enough to be perceived by the consumer has not been exhibited.

Under the above background, the present inventors have completed the present invention by confirming that by stabilizing and applying boron nitride to a cosmetic composition, coverage and adhesion are simultaneously improved and smooth skin makeup expression can be realized without makeup clumping.

It is an object of the present invention to provide a color powder cosmetic composition with improved coverage and adhesion, and a method for preparing the same.

A first aspect of the present invention provides a color powder cosmetic composition comprising coated boron nitride, sericite and a paste oil binder.

A second aspect of the present invention comprises the steps of: (a) stirring the coated boron nitride, a powder comprising sericite; (b) spraying the oil part into the powder part; and (c) mixing, pulverizing and filtering the product of step (b).

Hereinafter, the present invention will be described in detail.

The present inventors tried to increase the coverage except for the method of using titanium dioxide, which is usually mainly used in color cosmetics, and at the same time, studied and tried to improve the adhesion. As a result, it was found that when boron nitride is applied to a color powder cosmetic composition, it is possible to develop a cosmetic composition having excellent coverage, smooth application, and less cloudiness at the same time. However, in the prior art, when boron nitride is applied to a cosmetic composition to improve spreadability and feeling of use, there is a disadvantage that the product is easily damaged during a powder flying phenomenon and a drop impact, so there is a limit that it cannot be mixed in a large amount. The present inventors have confirmed that the moldability is improved by stabilizing and applying boron nitride to solve these disadvantages, and completed the present invention.

In one embodiment of the present invention, as a result of preparing and comparing a cosmetic composition to which a coating-treated boron nitride is applied, and a cosmetic composition to which titanium dioxide is generally used for the purpose of increasing coverage (Example 1 and Comparative Example 1), wet In the case of the cosmetic composition to which the coated boron nitride was applied, it was confirmed that the coverage and adhesion were excellent, there was no cloudiness, and the overall feeling of use was excellent.

In the present invention, boron nitride may be used as a coated powder with a surface property modified or coated to improve moldability. Specifically, by coating the film-forming agent on the surface of the powder, it is possible to improve the adhesion to the skin and at the same time enhance the mutual bonding force with the other powder. More specifically, the boron nitride may be coated with acrylates/stearyl acrylate/dimethicone methacrylated copolymer, dimethicone, or a mixture thereof. can

The boron nitride may be coated by a wet or dry method, and preferably wet coated boron nitride may be used.

The acrylate/stearyl acrylate/dimethicone methacrylate copolymer is a material used as a film former or hair conditioning agent, and includes acrylic acid, methacrylic acid, or a simple ester thereof ( ester), a copolymer of a monomer, ethylhexylacrylate, and dimethicone methacrylate. The dimethicone is a silicone material used to impart a water-repellent function.

In the present invention, the solvent used for coating the boron nitride may be any one or more selected from the group consisting of ethanol and isopropyl alcohol, but is not limited thereto.

By modifying or coating the surface properties of boron nitride using various coating materials in addition to the above compounds, physical properties such as feeling of use, spreadability or stability of the cosmetic composition may be affected.

The coating material of boron nitride is 0.1 to 2% by weight of the acrylate/stearyl acrylate/dimethicone methacrylate copolymer, specifically 0.5 to 1.5% by weight, more specifically 0.5 to 2% by weight relative to the total weight of the cosmetic composition. 1.0% by weight and 0.1 to 3% by weight of dimethicone, specifically 1 to 2% by weight, more specifically 0.5 to 1.0% by weight may be used. When boron nitride is coated with the compounds of the specific weight ratio and used, the adhesion and moldability of the cosmetic composition can be best exhibited.

In one embodiment of the present invention, when boron nitride is coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone (Example 2), and no coating treatment (Comparative Example 2) ), and as a result of comparing the cosmetic composition of the case of coating treatment with another coating material (Comparative Example 3), in the case of a composition coated with acrylate / stearyl acrylate / dimethicone methacrylate copolymer and dimethicone, It was confirmed that the coverage, adhesion, and feeling of use were excellent, and there was little appearance of makeup clumping or lifting (Table 8).

In the present invention, boron nitride is a powder having a lattice structure having a hexagonal plate structure, and the degree of moldability of the cosmetic composition may vary depending on the average particle diameter of the boron nitride. The average particle diameter of the boron nitride may be 3 to 24 μm, specifically 5 to 20 μm, and more specifically 6 to 12 μm.

The present inventors selected boron nitride having an optimal particle diameter through a moldability test according to the average particle diameter for three types of boron nitride (average particle diameters of 6 μm, 12 μm, and 16 μm), and mixed and used them. When boron nitride having an average particle diameter of about 16 μm was blended alone, the moldability was not good, so when the cosmetic was pressed on the plate, cracks occurred or cracks occurred on the surface. In terms of stability, poor results were also confirmed. When boron nitride having an average particle diameter of 6 μm and boron nitride having an average particle diameter of 12 μm was blended, it was confirmed that the most excellent moldability was exhibited, the feeling of use was smooth, and there was little powder flying when applied to the skin.

That is, when a cosmetic is prepared by mixing two types of boron nitride of 6 μm and 12 μm having different average particle diameters, it is possible to develop a cosmetic with excellent moldability and excellent coverage and adhesion. In addition, the most excellent formability can be exhibited when the coated boron nitride as presented above.

The boron nitride may be included in an amount of 5 to 50% by weight, specifically 10 to 45% by weight, more specifically 15 to 40% by weight, based on the total weight of the cosmetic composition. When the content of boron nitride is less than 5% by weight, the coverage and adhesion improvement are not sufficiently expressed or almost insignificant. If the content of boron nitride is more than 50% by weight, formability is lowered, resulting in product breakage and makeup aggregation when dropped, and powder when picking up products using makeup tools such as puffs and brushes. The phenomenon of powder flying in which a lot of hair is formed, and cosmetic lifting in which cosmetics are irregularly arranged in pores or irregularities were observed.

The cosmetic composition of the present invention contains sericite in order to exhibit a fine and soft feeling of use. The average particle diameter of the sericite applied to the composition of the present invention may be about 5 to 20 μm, specifically 6 to 16 μm, and more specifically 8 to 12 μm.

The sericite may be used without limitation, whether coated or uncoated. Specifically, the sericite may be coated with silicone, an emulsifier, or a mixture thereof. As the material used for the coating treatment, dimethylpolysiloxane, alkylsilane, or a mixture of two materials having water resistance and oil resistance properties may be used, but is not limited thereto.

Specifically, a coated sericite may be used, and more specifically, a coated sericite with dimethicone, alkylsilane, or a mixture thereof may be used.

The coating material of the sericite may be 0.5 to 2% by weight of dimethicone and 0.5 to 2% by weight of alkylsilane based on the total weight of the cosmetic composition. When the sericite is coated with dimethicone and alkylsilane in the specific weight ratio, the skin adhesion of the cosmetic composition can be best exhibited.

In the present invention, the sericite may be included in an amount of 1 to 25% by weight, specifically 2 to 20% by weight, more specifically 3 to 15% by weight, based on the total weight of the cosmetic composition. When the content of the sericite is less than 1% by weight, the effect of adhesion and soft application is not sufficiently exhibited or is almost insignificant. When the content of sericite is more than 25% by weight, makeup agglomeration occurs, and when the product is picked-up using a cosmetic tool such as a puff or brush, a lot of powder is formed, and there is a powdery phenomenon. There is a problem that stability is also reduced.

In one embodiment of the present invention, when boron nitride coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone is applied (Example 2) and when sericite is additionally included As a result of comparing (Example 3), it was confirmed that when sericite was additionally included in the coated boron nitride, a more excellent synergistic effect appeared in the evaluation of the cosmetic composition (Table 8).

The cosmetic composition of the present invention contains an oil binder to improve the moldability of boron nitride because it is a formulation made by molding a cosmetic on a regular plate as a compressed powder, compressed pact, powder foundation, or powder pact.

The oil binder may use one or more selected from ester-based oil, hydrocarbon-based oil, silicone oil, and the like. The oil is specifically dicaprylyl carbonate, diisostearyl malate, butylene glycol dicaprylated / dicaprate (butylene glycol dicaprylated / dicaprate), cetyl ethyl hexanoate ( cetyl ethylhexanoate), hexyl laurate, polyglyceryl-2 triisostearate, pentaerythrityl tetraisostearate, triethylhexanoin, etc. Hydrocarbon oils such as ester-based oils, polybutene, hydrogenated polyisobutene, and vegetable squalane, and phenyl trimethicone, dimethicone, etc. One or more or a mixture of two or more of silicone oils may be used, but the present invention is not limited thereto.

The oil binder is preferably ester oil in the form of a paste. The oil binder may include hydrogenated polyisobutene, or phytosteryl/isostearyl/cetyl/stearyl/behenyl dimer dilinoleate. and the two materials may be applied individually or may be mixed and used, but the present invention is not limited thereto.

In one embodiment of the present invention, a composition in which hydrogenated polyisobutene and phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate are applied together as an oil binder (Example 4), and silicone oil As a result of comparing the composition (Comparative Example 5) to which phosphorus phenyltrimethicone and dimethicone were applied, hydrogenated polyisobutene and phytosteryl/isostearyl/cetyl/stearyl/behenyl dimer dilinoleate as oil binders When applying , it was confirmed that it received an excellent evaluation in the evaluation of spreadability, adhesion, and dusting phenomenon (Table 9).

In the present invention, the type and content of the oil binder may be very important in order to provide adhesion and smooth application while improving the molding of boron nitride. In one embodiment of the present invention, an experiment was conducted according to the content and type of oil binder used in cosmetics such as powder foundation, compressed powder, and compressed pact to improve moldability, and a large amount of sericite was blended to improve adhesion. did. It was confirmed that the color powder cosmetic composition prepared as described above had excellent coverage and adhesion, and at the same time had a smooth cosmetic effect (Experimental Example 1 Table 9).

The oil binder may be included in an amount of 2.0 to 15% by weight, specifically 3 to 11% by weight, and more specifically 5 to 10% by weight, based on the total weight of the cosmetic composition. When the content of the oil binder is more than 15% by weight, when picking up the product using a cosmetic tool such as a puff or brush, caking phenomenon, in which the oil is agglomerated due to excess oil, and grazing ( greasing) may occur. When the content of the oil binder is less than 2.0% by weight, the moldability is poor, and there is a disadvantage in that the cosmetic cannot be made in a compressed formulation.

In the present invention, the boron nitride and sericite may be included in a weight ratio of 0.2:1 to 2:1 (boron nitride:sericite). When boron nitride and sericite are included in the above weight ratio, the coverage and adhesion of the cosmetic composition may be most excellently exhibited. Also, the boron nitride, sericite, and oil binder may be included in a weight ratio of 1:0.2 to 1:0.6 (boron nitride and sericite:oil binder). When boron nitride, sericite, and oil binder are included in the above weight ratio, the cosmetic composition has excellent coverage and adhesion, and a smooth cosmetic effect can be satisfied.

In the present invention, the term "powder" may refer to an aggregate of solid materials having a particle size of usually 1 mm or less. The powder that can be used in the composition of the present invention essentially includes boron nitride and sericite coated as described above, and is selected from the group consisting of extender pigments, color pigments and white pigments commonly used in the cosmetic field. It may include any one or more, and specifically may include an extender pigment.

The cosmetic composition of the present invention is an inorganic pigment containing talc, mica, kaolin, alumina, barium silicate, muscovite, synthetic mica, magnesium carbonate and zeolite as an extender pigment and an organic containing polyethylene powder, nylon powder, polystyrene powder, etc. It may include any one or more selected from the group consisting of pigments, etc., but is not limited thereto. An extender pigment commonly known in the art may be used, for example, the extender pigment described in [Modern Cosmetics, Jo Wan-gu, Lang Moon-jeong, Bae Deok-hwan, Korea Research Information Co., Ltd., 2007.02 publication].

The extender may further include talc coated with fatty acids, silicone, or a mixture thereof. Specifically, as the talc, dimethicone and talc coated with methicone may be used, and in this case, the cosmetic composition has excellent spreadability and adhesion, reduced dusting, and improved moldability and drop stability. However, it is not limited to dimethicone and talc coated with methicone, and may include talc coated with a material including fatty acid and amino acid-based or ester oil-based emulsifier.

The extender pigment may be preferably hydrophobized. Preferably, the extender pigment may be used after the surface is modified with at least one selected from the group consisting of silicones, hydrocarbons, fluorine, alkyl hydrogen polysiloxane, surfactants, and natural and synthetic waxes.

The extender pigment may be included in an amount of 5 to 40% by weight, preferably 10 to 30% by weight, more preferably 15 to 25% by weight, based on the total weight of the cosmetic composition. When the amount of the extender pigment is less than 5% by weight, the spreadability may be lowered, and when the amount of the extender is more than 40% by weight, powder agglomeration may occur.

In the cosmetic composition of the present invention, titanium dioxide or zinc oxide coated with any one or more selected from the group consisting of silicones, ester-based oils, aluminum hydroxide and stearic acid, etc. as a white pigment may be used. not limited

The composition of the present invention may further include any one or more selected from the group consisting of fragrances, colorants, preservatives, oxidation stabilizers, sunscreens and pearls, etc. within the range that does not reduce the effect of the composition in addition to the above components. . The composition may be in the form of a solid stick or cake, preferably in a powder form selected from the group consisting of pressed powder, pressed pact, powder pact, powder foundation, foundation pact, and pressed powder foundation. It is not limited thereto.

The composition of the present invention comprises 5 to 50% by weight, specifically 15 to 40% by weight of boron nitride coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone, based on the total weight of the cosmetic composition, 1 to 25% by weight of sericite treated with alkyl silane coating, specifically 3 to 15% by weight, 0.1 to 5% by weight of hydrogenated polyisobutene, specifically 0.5 to 2% by weight, phytosteryl/isostearyl/cetyl /stearyl/behenyldimerdilinoleate 0.1 to 5% by weight, specifically 0.5 to 2.5% by weight. Specifically, the cosmetic composition may additionally include talc coated with dimethicone or methicone. A cosmetic composition comprising a combination of ingredients having a specific weight ratio as described above has excellent coverage and adhesion with almost no cloudiness, smooth application is improved, and smooth skin makeup is possible.

In addition, the present invention comprises the steps of (a) stirring the coated boron nitride, a powder comprising sericite; (b) spraying the oil part into the powder part; and (c) mixing, pulverizing and filtering the product of step (b).

Specifically, (a) stirring an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and a powder portion comprising boron nitride coated with dimethicone, and sericite coated with alkyl silane; (b) spraying an oil containing hydrogenated polyisobutene and phytosteryl/isostearyl/cetyl/stearyl/behenyl dimer dilinoleate to the powder; and (c) mixing, pulverizing and filtering the product of step (b). More specifically, the step (a) may additionally include talc coated with fatty acids, emulsifiers, or mixtures thereof. In this case, the spreadability, adhesion, moldability and drop stability of the cosmetic composition will be remarkably improved. can

The color powder cosmetic composition according to the present invention has excellent coverage and adhesion, and there is no makeup clumping, so that the skin curves are not emphasized and the cosmetic composition is finished smoothly, thereby realizing excellent skin expressive power.

1 is a comparison of the skin condition before and after applying the cosmetic composition of Example 3.
2 shows the skin detachment rates of the pressed powders prepared in Examples 1 to 3 and Comparative Examples 1 to 4;

Hereinafter, the present invention will be described in more detail through examples. However, these embodiments may be modified in various other forms, and the scope of the present invention is not limited to these embodiments. These examples are provided to more fully explain the present invention to those of ordinary skill in the art.

Example 1-4 and Comparative example 1-5: Tint Powder cosmetic Produce

1-1. boron of nitride Formability and stability evaluation according to average particle diameter

The present inventors confirmed the optimum particle diameter of boron nitride suitable for cosmetic composition application through moldability and stability evaluation experiments according to the average particle diameter of boron nitride prior to the preparation of a color powder cosmetic containing boron nitride.

Three kinds of boron nitride having an average particle diameter of 6 μm, 12 μm, and 16 μm were targeted, and a composition including three kinds of boron nitride and a mixture thereof was prepared according to the composition ratio shown in Table 1 below. The moldability of each cosmetic A to E was compared by observing whether a cracking phenomenon or a cracking phenomenon on the surface was caused when this was pressed on a plate.

division A B C D E talc To 100 To 100 To 100 To 100 To 100 synthetic mica 5.0 5.0 5.0 5.0 5.0 6 μm boron nitride 40.0 - - - - 6 μm boron nitride and 12 μm boron nitride - 40.0 - - - 12 μm boron nitride - - 40.0 - - 12 μm boron nitride and 16 μm boron nitride - - - 40.0 - 16 μm boron nitride - - - - 40.0 iron oxide pigment 2.75 2.75 2.75 Hydrogenated polyisobutene 0.5 0.5 0.5 Phytosteryl/isostearyl/cetyl/stearyl/behenyldimer dilinoleate 2.0 2.0 2.0

The moldability evaluation of each cosmetic was evaluated on the basis of good:○, normal:Δ, and bad:X. As shown in Table 2 below, when boron nitride having an average particle diameter of 16 μm was mixed alone (E), the formability was not good, so cracking and cracking occurred, and the drop stability was also poor. When boron nitride having an average particle diameter of 6 μm and boron nitride having an average particle diameter of 12 μm is blended (B), it can be seen that the best formability is exhibited, the feeling of use is smooth, and there is little powder flying when applied there was. Accordingly, a mixture of boron nitride having an average particle diameter of 6 μm and 12 μm having the best moldability and stability was used for the preparation of the cosmetic composition in this experiment.

division A B C D E formability ○ ○ △ Ⅹ Ⅹ crack phenomenon does not occur does not occur occurred occurred occurred Hardness 28 25 20 15 13 fall stability
(time of breakage) 3rd time 3rd time Episode 2 1 time 1 time spreadability
(relative evaluation) 2nd place 1st place 3rd place 4th place 5th place

1-2. Example 1 and Comparative example One

The cosmetic compositions of Examples 1 to 4 and Comparative Examples 1 to 5 were prepared by the following common process. After putting the powder part into the Hensel mixer and mixing it for about 5 minutes at high speed (800~1200 rpm), the oil part was sprayed while stirring at a low speed (400~600 rpm). Subsequently, the mixture was mixed on a Hensel mixer at high speed (800-1200 rpm) for about 3 minutes, and then pulverized twice using an atomizer and filtered through 30 mesh. The semi-finished product through the above series of manufacturing processes was molded for 1 second to 3 seconds at a pressure of ^{30-50 kgf/cm 2 .} According to the content composition of the components shown in Tables 3 to 5 in the above manner, various composition ratios were applied to prepare color powder cosmetics.

As shown in Table 3 below, in Example 1 and Comparative Example 1, a cosmetic composition to which boron nitride wet coated with an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone was applied, and generally A cosmetic composition to which titanium dioxide used for the purpose of increasing coverage was applied was prepared.

division Example 1 Comparative Example 1 Alkylsilane and dimethicone coated talc To 100 To 100 synthetic mica 5.0 5.0 Silica 3.0 3.0 Sericite with alkyl silane coating 5.0 5.0 Boron nitride coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone 30.0 - titanium dioxide - 20.0 iron oxide pigment 2.75 2.75 Hydrogenated polyisobutene 0.5 0.5 Phytosteryl/isostearyl/cetyl/stearyl/behenyldimer dilinoleate 2.0 2.0 Dimethicone 1.0 1.0 Com Dior 0.5 0.5 Spices 0.12 0.12

1-3. Example 2-3 and Comparative example 2-4

According to the component ratios shown in Table 4 below, acrylate/stearyl acrylate/dimethicone methacrylate copolymer and a cosmetic composition to which boron nitride wet coated with dimethicone is applied (Example 2), acrylate/stearyl A cosmetic composition comprising boron nitride and sericite coated with acrylate/dimethicone methacrylate copolymer and dimethicone (Example 3), a cosmetic composition to which non-coating boron nitride is applied (Comparative Example 2), and a cosmetic composition to which boron nitride coated with another coating material is applied (Comparative Example 3), and A cosmetic composition (Comparative Example 4) to which uncoated boron nitride and diphenylsiloxyphenyltrimethicone were applied was prepared.

division Example 2 Example 3 Comparative Example 2 Comparative Example 3 Comparative Example 4 talc To 100 To 100 To 100 To 100 To 100 synthetic mica 5.0 5.0 5.0 5.0 10.0 Silica 3.0 3.0 3.0 3.0 3.0 Non-coating boron nitride - - 40.0 - 40.0 Trimethylsiloxysilicate coated boron nitride - - - 40.0 - Boron nitride coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone 40.0 40.0 - - - Sericite with alkylsilane coating - 10.0 - - - iron oxide pigment 2.75 2.75 2.75 2.75 2.75 Hydrogenated polyisobutene 0.5 0.5 0.5 0.5 - Phytosteryl/isostearyl/cetyl/stearyl/behenyldimer dilinoleate 2.0 2.0 2.0 2.0 - Octyldodecylstearoylstearate - - 3.0 3.0 3.0 Diphenylsiloxyphenyltrimethicone - - - - 2.0 Dimethicone 1.0 1.0 1.0 1.0 1.0 Com Dior 0.5 0.5 0.5 0.5 0.5 Spices 0.12 0.12 0.12 0.12 0.12

1-4. Example 4 and Comparative example 5

According to the component ratios shown in Table 5 below, a cosmetic composition (Example 4) in which hydrogenated polyisobutene and phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate were applied together as an oil binder (Example 4), oil A cosmetic composition (Comparative Example 5) was prepared in which phenyltrimethicone and dimethicone, which are common silicone oils, were applied together as binders.

division Example 4 Comparative Example 5 Alkylsilane and dimethicone coated talc To 100 To 100 synthetic mica 5.0 5.0 Silica 3.0 3.0 Sericite with alkyl silane coating 5.0 5.0 Boron nitride coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone 40.0 40.0 iron oxide pigment 2.75 2.75 Hydrogenated polyisobutene 1.0 - Phytosteryl/isostearyl/cetyl/stearyl/behenyldimer dilinoleate 2.0 - Phenyltrimethicone - 2.0 Dimethicone - 2.0 Com Dior 0.5 0.5 Spices 0.12 0.12

Experimental example 1: Tint Powder cosmetic coverage And feeling evaluation

The coverage and feeling of use of the pressed powders prepared in Examples 1 to 4 and Comparative Examples 1 to 5 were evaluated. For evaluation of coverage and feeling of use, a blind test was conducted on 34 professional panelists, single and married women aged 20-43 years, who had at least 2 years of makeup experience and who continuously applied makeup at least 5 times a week. The coverage and feel evaluation criteria are as shown in Table 6 below.

Evaluation standard 5 points very good 4 points Great 3 points usually 2 points Bad 1 point very bad

The evaluation of the coverage was quantified according to the degree of naturally covering skin defects, pores, and irregularities while showing natural hiding power, rather than being blurry and unnaturally expressed.

The feeling of use was evaluated after each application of the cosmetic composition to the female subject's face, and the feeling of use, in particular, adhesion, spreadability, fine feeling, makeup agglomeration, floating phenomenon, and powdery feeling were evaluated.

The scores evaluated by the 34 expert panel for coverage and feeling of use were statistically processed as the average for each item, and the scores are presented in Tables 7 and 8 below.

division Example 1 Comparative Example 1 coverage 4.4 4.2 adhesion 4.6 4.0 Spreadability 4.5 2.7 fine feeling 4.2 2.8 Make-up clumping and lifting 4.0 3.5

As shown in Table 7 above, Example 1 comprising an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and boron nitride coated with dimethicone and sericite treated with an alkyl silane coating is compared The coverage was superior to that of Example 1 without cloudiness, and it received excellent scores in the overall evaluation of the feeling of use, such as adhesion, spreadability, and fine feeling.

On the other hand, Comparative Example 1 containing titanium dioxide exhibited severe white turbidity, which is characteristic of titanium dioxide, and was given a low score in the evaluation of spreadability and fine feeling due to the presence of stiff application due to the unique structure of titanium dioxide. In addition, due to the coarse particles of titanium dioxide, it did not spread evenly on the skin, resulting in makeup agglomeration, which also resulted in cosmetic lifting.

division Example 2 Example 3 Comparative Example 2 Comparative Example 3 Comparative Example 4 coverage 4.2 4.6 3.9 3.8 3.9 adhesion 4.2 4.4 3.6 3.4 3.3 Spreadability 4.1 4.3 4.0 3.5 3.6 fine feeling 4.2 4.2 3.8 3.4 3.5 Make-up clumping and lifting 4.0 4.0 3.2 3.0 3.2 dusting phenomenon 4.1 4.2 3.6 3.5 3.3

As shown in Table 8, coverage and overall feeling of use were evaluated according to the presence or absence of the coating of boron nitride and the type of coating. Example 2 comprising an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and boron nitride coated with dimethicone is an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone. It was confirmed that it received somewhat lower evaluations in coverage, adhesion, and spreadability compared to Example 3 containing both boron nitride and sericite coated with an alkyl silane coating. As a result of comparing the skin condition before and after applying the cosmetic composition of Example 3, it was confirmed that the skin coverage and adhesion were excellent after application of the cosmetic composition, and excellent skin expression was realized without makeup clumping ( FIG. 1 ).

Through these results, a more excellent synergistic effect in a cosmetic composition comprising an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and boron nitride coated with dimethicone together with sericite treated with an alkyl silane coating (synergy effect) was confirmed.

In addition, in the case of those containing no boron nitride coated (Comparative Example 2) and trimethylsiloxysilicate coated boron nitride (Comparative Example 3), Examples 2 and 3 in the evaluation of coverage and adhesion It received a lower evaluation, and received relatively low evaluations in terms of spreadability, fine feeling, and makeup clumping and lifting.

This fact suggests that when coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone, the effect of adhering and adhering the powder to the skin is excellent. is considered to be given.

Based on these experimental results, cosmetics containing acrylate/stearyl acrylate/dimethicone methacrylate copolymer and boron nitride coated with dimethicone and sericite treated with alkyl silane coating are the conventional color powder cosmetics. Contrary to this, it was confirmed that there was no cloudiness, but the coverage was naturally excellent, and the adhesion and spreadability were also excellent.

division Example 4 Comparative Example 5 Spreadability 4.5 4.2 adhesion 4.6 4.2 dusting phenomenon 4.2 4.0

Additionally, as an oil binder, the spreadability of cosmetics using hydrogenated polyisobutene and phytosteryl/isostearyl/cetyl/stearyl/behenyl dimer dilinoleate together; Adhesiveness and dusting were evaluated.

As can be seen in Table 9 above, Example 4 in which hydrogenated polyisobutene and phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate were applied together as an oil binder is a comparison in which a general silicone oil is applied It received an excellent evaluation than Example 5 in the evaluation of spreadability, adhesion, and dusting.

From the above results, it was confirmed that applying the paste-like ester oil in the powder cosmetic composition sufficiently functions as a crosslinking between the skin and the powder and improves the adhesion. That is, in the cosmetic composition containing acrylate/stearyl acrylate/dimethicone methacrylate copolymer and boron nitride coated with dimethicone and sericite coated with alkylsilane in the powder cosmetic composition, ester oil in paste form It was confirmed that application was preferable as an oil binder for improving spreadability and adhesion.

Experimental example 2: Tint Powder cosmetic Formability and stability evaluation

The hardness and drop stability of the pressed powders prepared in Examples 2 and 4 and Comparative Examples 1 and 3 were evaluated, and greasing and caking phenomena caused by agglomeration of oil and fine particles, etc. was confirmed.

For hardness measurement, a JAL Type (JIS K 6301) penetration hardness tester of Japan Polymer Instruments Co., Ltd. was used, and the average values of each were shown in Table 10 below. For the measurement of drop stability, each of the molded Examples and Comparative Examples was vertically free-falling from a height of 70 cm onto a 3 mm rubber plate, and the breakage time was measured.

In addition, the grazing and caking phenomenon that appears on the surface of the product is a phenomenon that occurs when the surface of the product is taken about 100-120 times, assuming that 3 products that have been molded are actually used by women using a makeup tool (puff) evaluated.

division Example 2 Example 4 Comparative Example 1 Comparative Example 3 Hardness 25 28 40 35 fall stability
(time of breakage) 4.0 episodes 4.5 reps 6 episodes 5 times greasing
& caking clear clear occurred occurred

※ Pass Criteria: When the average value of 5 samples is 3 or more, the drop stability is stable

When looking at the results shown in Table 10, Examples 2 and 4 obtained high scores in main items such as coverage and adhesion, and at the same time, it was confirmed that the fall stability with appropriate hardness was 4 or more passing levels. In addition, it was confirmed that there was no abnormality in grazing and caking due to agglomeration of oil and particles.

On the other hand, when titanium dioxide was applied (Comparative Example 1), the hardness was very high, and the drop stability was at a good level, but grazing and caking occurred due to aggregation of fine particles. In other words, it was confirmed that the product was rejected and the quality of the product was not good.

In addition, in the case of including boron nitride coated with trimethylsiloxysilicate (Comparative Example 3), a hardness of an appropriate hardness level was formed, but grazing and caking phenomena were observed as in Comparative Example 1.

Through these results, in the case of a color powder cosmetic composition to which boron nitride coated with acrylate / stearyl acrylate / dimethicone methacrylate copolymer and dimethicone is applied, it has appropriate hardness and has excellent drop stability, At the same time, it was confirmed that grazing and caking did not occur.

Experimental example 3: Tint Powder cosmetic Make-up status evaluation

The cosmetic composition of Example 4 and Comparative Example 1 was applied to the actual skin to evaluate the cosmetic state, that is, a uniform cosmetic film, smooth makeup expression, and makeup durability. The evaluation target was 34 women aged 20 to 43 years, and the feeling and condition of applying the product and the persistence after makeup were checked.

The evaluation criteria of the makeup state are shown in Table 11 below.

Evaluation standard ◎ Optimum feel or feel of use ○ It feels almost optimal to use, but it is not at a very satisfactory level. △ is average. Ⅹ bad.

division uniform makeup film smooth makeup expression makeup persistence Example 4 ◎ ◎ ○ Comparative Example 1 Ⅹ Ⅹ △

From the results shown in Table 12, Example 4 prepared according to the present invention showed a very good cosmetic effect in a uniform makeup film and smooth makeup expression, and it was confirmed that the makeup durability evaluation was also excellent.

On the other hand, in the case of Comparative Example 1, it was evaluated at a very unsatisfactory level in the evaluation of a uniform makeup film and smooth makeup expression, and the evaluation of makeup durability was confirmed to be at a normal level. In the case of Comparative Example 1, it was determined that the makeup state was not smooth and uniform by directly applying titanium dioxide having a needle shape or a rod shape. In addition, it was confirmed that the cosmetic satisfaction was not excellent due to the rough feeling of use and the stiff feeling of use peculiar to titanium dioxide.

From the above results, the cosmetic composition of the present invention was coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone to improve moldability and adhesion, and boron nitride coated with dimethicone, and alkyl silane coating treatment By including sericite, it provides natural coverage without cloudiness, has excellent adhesion and spreadability, and forms a smooth and uniform makeup film in skin expression.

In addition, it was confirmed that the cosmetic composition of the present invention contains hydrogenated polyisobutene and phytosteryl/isostearyl/cetyl/stearyl/behenyl dimer dilinoleate, thereby remarkably improving moldability and drop stability.

Experimental example 4: Tint Powder cosmetic skin Bounce Rate evaluation

After the pressed powder prepared in Examples 1 to 3 and Comparative Examples 1 to 4 was applied to the skin, the skin detachment rate was evaluated to compare the degree of adhesion to the skin. The lower the skin release rate value of the cosmetic composition, the higher the skin adhesion of the cosmetic composition.

To measure the skin breakout rate, 10 mg of the sample is applied on the artificial skin in a 4x4 cm square, and then air is blown for about 20 seconds at a pressure of 20 psi from a distance of 15 cm, and then the amount remaining on the skin is measured. The dropout rate was calculated.

Skin breakout rate (%) Example 1 10.4 Example 2 10.2 Example 3 9.7 Comparative Example 1 15.6 Comparative Example 2 20.3 Comparative Example 3 16.4 Comparative Example 4 24.5

The skin breakout rate value of each composition is as shown in Table 13 above, and it is presented in FIG. 2 as a graph. The skin breakout rates of Examples 1 to 3 were 10.4, 10.2, and 9.7%, respectively, whereas the skin breakout rates of Comparative Examples 1 to 4 were all 15% or more. It was confirmed that one cosmetic composition had better adhesion to the skin than the cosmetic compositions of Comparative Examples 1 to 4 (FIG. 2).

Specifically, when non-coating boron nitride is applied (Comparative Example 2), the skin release rate is 20.3%, and when boron nitride coated with another coating material is applied (Comparative Example 3) is 16.4%, whereas in the case of a cosmetic composition comprising boron nitride and sericite coated with acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone together (Example 3), skin breakout rate It was measured as low as 9.7%, and it was confirmed that it has high skin adhesion.

Claims (17)

a powder portion comprising coated boron nitride and sericite; and
A color powder cosmetic composition comprising a paste-like oil binder,
Wherein the boron nitride is coated with acrylate / stearyl acrylate / dimethicone methacrylate copolymer and dimethicone, color powder cosmetic composition. The cosmetic composition of claim 1, wherein the composition further comprises talc coated with silicone, fatty acid, or a mixture thereof. The cosmetic composition of claim 1, wherein the composition does not contain titanium dioxide. The method according to claim 1, wherein the boron nitride is coated with 0.1 to 2% by weight of acrylate/stearyl acrylate/dimethicone methacrylate copolymer and 0.1 to 3% by weight of dimethicone based on the total weight of the cosmetic composition. The color powder cosmetic composition. The color powder cosmetic composition of claim 1, wherein the boron nitride is included in an amount of 5 to 50% by weight based on the total weight of the cosmetic composition. The cosmetic composition of claim 1, wherein the boron nitride has an average particle diameter of 3 to 24 μm. The cosmetic composition of claim 1, wherein the sericite is coated with silicone, an emulsifier, or a mixture thereof. The color powder cosmetic composition according to claim 7, wherein the sericite is coated with dimethicone, alkylsilane, or a mixture thereof. The color powder cosmetic composition of claim 1, wherein the sericite is included in an amount of 1 to 25% by weight based on the total weight of the cosmetic composition. The color powder cosmetic composition according to claim 1, wherein the sericite has an average particle diameter of 5 to 20 µm. The cosmetic composition of claim 1, wherein the weight ratio of boron nitride and sericite is 0.2:1 to 2:1 (boron nitride:sericite). According to claim 1, wherein the oil binder is ester-based oil, hydrocarbon-based oil, silicone oil, or a mixture thereof, color powder cosmetic composition. According to claim 1, wherein the weight ratio of boron nitride and sericite to the oil binder is 1:0.2 to 1:0.6 (boron nitride and sericite:oil binder), the color powder cosmetic composition. According to claim 1, 5 to 50% by weight of boron nitride coated with an acrylate/stearyl acrylate/dimethicone methacrylate copolymer and dimethicone, 1 to 1 to sericite treated with an alkyl silane coating, based on the total weight of the composition 25 wt%, hydrogenated polyisobutene 0.1-5 wt%, phytosteryl/isostearyl/cetyl/stearyl/behenyldimerdilinoleate 0.1-5 wt%, extender pigment 5-40 wt% and oil Containing 0.1 to 15% by weight, the color powder cosmetic composition. 15. The cosmetic composition of any one of claims 1 to 14, wherein the coating is a wet coating. (a) stirring the powder comprising the coated boron nitride and sericite;
(b) spraying the oil part into the powder part; and
(c) mixing, pulverizing and filtering the product of step (b)
As a method for producing a color powder cosmetic composition comprising:
Wherein the boron nitride is coated with acrylate / stearyl acrylate / dimethicone methacrylate copolymer and dimethicone, a method for producing a color powder cosmetic composition. The method of claim 16, wherein step (a) further comprises talc coated with silicone, fatty acid, or a mixture thereof.

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