KR102255292B1 - Thawless artificial snow composition using diatomite powder and manufacturing method thereof - Google Patents

Thawless artificial snow composition using diatomite powder and manufacturing method thereof Download PDF

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KR102255292B1
KR102255292B1 KR1020200176485A KR20200176485A KR102255292B1 KR 102255292 B1 KR102255292 B1 KR 102255292B1 KR 1020200176485 A KR1020200176485 A KR 1020200176485A KR 20200176485 A KR20200176485 A KR 20200176485A KR 102255292 B1 KR102255292 B1 KR 102255292B1
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mixing step
weight
diatomaceous earth
artificial snow
powder
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이지연
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주식회사 글로벌이지
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/24Materials not provided for elsewhere for simulating ice or snow
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25CPRODUCING, WORKING OR HANDLING ICE
    • F25C3/00Processes or apparatus specially adapted for producing ice or snow for winter sports or similar recreational purposes, e.g. for sporting installations; Producing artificial snow

Abstract

The present invention relates to non-melting artificial snow using diatomaceous earth powder, and a production method thereof. The non-melting artificial snow using diatomaceous earth powder comprises diatomaceous earth powder with a size of 10-500 mesh, water, an adhesive, a super absorbent polymer with a particle size of 300-600 mesh, fatty acid, a polymer coagulant, and an antibacterial agent. The method comprises a diatomaceous earth pulverizing step, a water mixing step, a coating step, a cooling step, an adhesive mixing step, a coagulant mixing step, a superabsorbent polymer mixing step, an antibacterial agent mixing step, and an artificial snow completion step. A production process is simple and a production cost is low. In particular, it is possible to prevent the shape or state of artificial snow from changing even if a constant temperature condition is not maintained after production. Therefore, various uses, such as for play or tree decoration, are possible. By further including a phosphorescent powder and pigment mixing step in which phosphorescent powder and a pigment are further mixed and applied, it is possible to realize improved usability and aesthetics in tree decorations and the like while emitting light of a certain illuminance in a dark place.

Description

규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법{Thawless artificial snow composition using diatomite powder and manufacturing method thereof}BACKGROUND TECHNICAL FIELD The insoluble artificial snow composition using diatomite powder and manufacturing method thereof

본 발명은 규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법에 관한 것으로서, 더욱 상세하게는 10~500메쉬 크기의 분말상태인 규조토가루, 물, 접착제, 300~600메쉬 크기의 입도를 갖는 고흡수성수지, 지방산, 고분자 응집제, 항균제를 포함하여 구성되되, 규조토 분쇄단계, 물 혼합단계, 코팅단계, 냉각단계, 접착제 혼합단계, 응집제 혼합단계, 고흡수성수지 혼합단계, 항균제 혼합단계 및 인공눈 완성단계를 통해 제조됨으로써 제조 과정이 간단하면서도 제조비용이 저렴하며, 특히 제조 후 일정한 온도 조건을 유지하지 않더라도 인공 눈의 형태 또는 상태가 변하지 않도록 할 수 있으며, 이를 통하여 놀이나 트리 장식용 등으로 다양한 활용이 가능하도록 하는 한편, 축광분말 및 안료가 더 혼합 적용되는 축광분말 및 안료 혼합단계를 더 포함함으로써 어두운 곳에서 일정 조도의 빛을 발하면서 트리 장식용 등에서의 더욱 향상된 활용성 및 심미감을 구현할 수 있도록 한 규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법에 관한 것이다.The present invention relates to insoluble artificial snow using diatomaceous earth powder and a method for manufacturing the same, and more particularly, diatomaceous earth powder in a powder state of 10 to 500 mesh, water, adhesive, and super absorbent having a particle size of 300 to 600 mesh. Consisting of resin, fatty acid, polymer flocculant, antibacterial agent, diatomaceous earth grinding step, water mixing step, coating step, cooling step, adhesive mixing step, coagulant mixing step, super absorbent polymer mixing step, antibacterial agent mixing step and artificial snow completion step The manufacturing process is simple and the manufacturing cost is inexpensive, especially after manufacturing, so that the shape or state of the artificial snow does not change, and through this, it can be used for various purposes such as play or tree decoration. On the other hand, by further including a step of mixing phosphorescent powder and pigment in which phosphorescent powder and pigment are further mixed and applied, diatomaceous earth powder that emits light of a certain illuminance in a dark place and realizes more improved usability and aesthetics in tree decoration, etc. It relates to an artificial snow that does not melt and a method of manufacturing the same.

일반적으로, 인공눈(artificial snow)은 겨울 스포츠인 스키, 스노우보드, 또는 눈썰매 등을 즐기기 위한 장소 등에서 천연 눈이 부족할 때 사용되거나, 또는 천연눈이 없는 장소에서 겨울 스포츠를 즐기기 위하여 천연 눈 대신 사용되어왔다.In general, artificial snow is used when natural snow is insufficient in places for enjoying winter sports such as skiing, snowboarding, or sledding, or used instead of natural snow to enjoy winter sports in places where there is no natural snow. Has been.

최근에는 이러한 기존의 소프트 스노우와 달리, 나아가 다양한 조형물 또는 미술 작품, 무대 장치 등에 다양하게 활용 및 응용되어 질 수 있는 하드 스노우가 개발되어 각광받고 있으며, 이러한 하드 스노우는 예를 들어 3D 벽화 또는 3D 액자와 같은 미술 혹은 조형 작품에도 응용될 수 있다.In recent years, unlike the existing soft snow, hard snow that can be used and applied in various ways such as various sculptures, art works, and stage devices has been developed and is in the spotlight. Such hard snow is, for example, a 3D mural or 3D picture frame. It can also be applied to art or sculptural works such as.

한편, 상기와 같은 인공눈을 제조하는 방법과 관련한 종래의 기술에 따르면, 인공눈 제조시 플라스틱 원료를 주원료로 하여 제조되기는 하나, 인공눈을 유지하기 위해서는 일정한 온도 조건(약 0 내지 6℃)을 유지하여야 하였기 때문에, 이를 위한 냉방 비용이 과다하게 지출되어 상업성이 결여된 문제점이 있었으며, 인공눈을 제조하는데 드는 비용도 고가이며, 제조 과정도 복잡한 등의 문제점이 있었다.On the other hand, according to the conventional technology related to the method of manufacturing artificial snow as described above, although it is manufactured using plastic raw materials as the main raw material when manufacturing artificial snow, a constant temperature condition (about 0 to 6°C) is applied to maintain artificial snow. Since it had to be maintained, there was a problem of lack of commerciality due to excessive expenditure of cooling costs for this, and there were problems such as high cost to manufacture artificial snow, and complicated manufacturing process.

그러므로 제조 과정이 간단하면서도 제조비용이 저렴하며, 특히 제조 후 일정한 온도 조건을 유지하지 않더라도 인공 눈의 형태 또는 상태가 변하지 않도록 할 수 있으며, 이를 통하여 놀이나 트리 장식용 등으로 다양한 활용이 가능하도록 한 녹지 않는 인공 눈 및 그의 제조방법에 대한 연구 및 개발이 요구되는 실정이다.Therefore, the manufacturing process is simple and the manufacturing cost is low. In particular, the shape or state of the artificial snow can be prevented from changing even if a constant temperature condition is not maintained after manufacturing. Research and development on artificial snow and its manufacturing method are required.

대한민국 공개특허 제1991-0021466호 1991.12.20. 공개.Republic of Korea Patent Publication No. 1991-0021466 1991.12.20. open. 대한민국 공개특허 제2002-0072148호 2002.09.14. 공개.Republic of Korea Patent Publication No. 2002-0072148 2002.09.14. open. 대한민국 공개특허 제2002-0074406호 2002.09.30. 공개.Republic of Korea Patent Publication No. 2002-0074406 2002.09.30. open. 대한민국 등록특허 제1767947호 2017.08.08. 등록.Republic of Korea Patent Registration No. 1767947 2017.08.08. Enrollment. 대한민국 공개특허 제2019-0101898호 2019.09.02. 공개.Republic of Korea Patent Publication No. 2019-0101898 2019.09.02. open.

상기와 같은 문제점을 해결하기 위하여, 본 발명은 10~500메쉬 크기의 분말상태인 규조토가루, 물, 접착제, 300~600메쉬 크기의 입도를 갖는 고흡수성수지, 지방산, 고분자 응집제, 항균제를 포함하여 구성되되, 규조토 분쇄단계, 물 혼합단계, 코팅단계, 냉각단계, 접착제 혼합단계, 응집제 혼합단계, 고흡수성수지 혼합단계, 항균제 혼합단계 및 인공눈 완성단계를 통해 제조됨으로써 제조 과정이 간단하면서도 제조비용이 저렴하며, 특히 제조 후 일정한 온도 조건을 유지하지 않더라도 인공 눈의 형태 또는 상태가 변하지 않도록 할 수 있으며, 이를 통하여 놀이나 트리 장식용 등으로 다양한 활용이 가능하도록 한 규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법을 제공하는 것을 목적으로 한다.In order to solve the above problems, the present invention includes a powdery diatomaceous earth powder having a size of 10 to 500 mesh, water, an adhesive, a super absorbent resin having a particle size of 300 to 600 mesh, a fatty acid, a polymer coagulant, and an antibacterial agent. Consisting of, however, the manufacturing process is simple and cost-effective as it is manufactured through the diatomaceous earth crushing step, water mixing step, coating step, cooling step, adhesive mixing step, coagulant mixing step, super absorbent polymer mixing step, antibacterial agent mixing step and artificial snow completion step. This is inexpensive, and in particular, it is possible to prevent the shape or state of artificial snow from changing even if it does not maintain a constant temperature condition after manufacture, and through this, artificial snow that does not melt using diatomaceous earth powder that can be used in various ways for play or tree decoration, etc. It is an object of the present invention to provide a method for producing the same.

본 발명에 따른 기술의 다른 목적은 축광분말 및 안료가 더 혼합 적용되는 축광분말 및 안료 혼합단계를 더 포함함으로써 어두운 곳에서 일정 조도의 빛을 발하면서 트리 장식용 등에서의 더욱 향상된 활용성 및 심미감을 구현할 수 있도록 함에 있다.Another object of the technology according to the present invention is to further include a photoluminescent powder and pigment mixing step in which the photoluminescent powder and pigment are further mixed and applied, thereby emitting light of a certain illuminance in a dark place, and further improving usability and aesthetics in tree decoration, etc. It is in making it possible.

전술한 목적을 달성하기 위한 본 발명은 다음과 같다. 즉, 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈은 규조토가루를 이용한 녹지 않는 인공 눈에 있어서, 10~500메쉬 크기의 분말상태인 규조토가루, 물, 접착제, 300~600메쉬 크기의 입도를 갖는 고흡수성수지, 지방산, 고분자 응집제, 항균제를 포함한다.The present invention for achieving the above object is as follows. That is, in the insoluble artificial snow using diatomaceous earth powder according to the present invention, in the non-melting artificial snow using diatomaceous earth powder, the diatomaceous earth powder, water, adhesive, 300-600 mesh size in powder state of 10 to 500 mesh is used. It contains super absorbent polymer, fatty acid, polymer flocculant, and antibacterial agent.

여기서, 상기 규조토가루를 이용한 녹지 않는 인공 눈 혼합물은 10~500메쉬 크기의 분말상태인 규조토가루 45~52중량%, 물 23.25~27.35중량%, 접착제 20~24중량%, 300~600메쉬 크기의 입도를 갖는 고흡수성수지 0.1~0.3중량%, 지방산 1~3중량%, 고분자 응집제 0.5~1.5중량%, 항균제 0.01~0.05중량%로 혼합되는 것이 바람직하다.Here, the insoluble artificial snow mixture using the diatomaceous earth powder is 45 to 52% by weight of diatomaceous earth powder in the form of a powder of 10 to 500 mesh, 23.25 to 27.35% by weight of water, 20 to 24% by weight of adhesive, and 300 to 600 mesh size. It is preferable to mix with 0.1 to 0.3% by weight of a superabsorbent resin having a particle size, 1 to 3% by weight of fatty acids, 0.5 to 1.5% by weight of a polymer coagulant, and 0.01 to 0.05% by weight of an antimicrobial agent.

이때, 상기 규조토가루를 이용한 녹지 않는 인공 눈 혼합물 100중량부에 대하여, 축광분말 0.1~0.3중량부 및 안료 0.1~0.3중량부를 더 포함하는 것이 양호하다.At this time, it is preferable to further include 0.1 to 0.3 parts by weight of the phosphorescent powder and 0.1 to 0.3 parts by weight of the pigment, based on 100 parts by weight of the insoluble artificial snow mixture using the diatomaceous earth powder.

더욱이, 상기 접착제는 글리세린으로 구성되는 한편, 상기 지방산은 탄소수 12개 이상으로 이루어진 스테아르산(stearic acid) 또는 팜유의 팔미트산(palmitic acid)로 구성되는 것이 바람직하다.Further, the adhesive is preferably composed of glycerin, while the fatty acid is composed of stearic acid having 12 or more carbon atoms or palmitic acid of palm oil.

한편, 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법은 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법에 있어서, 규조토를 일정온도 이상의 온도조건으로 가열로에서 가열하여 10~500메쉬 크기의 분말상태로 분쇄하는 규조토 분쇄단계; 규조토가루를 이용한 녹지 않는 인공 눈 전체 중량%에 대하여, 분쇄단계를 거쳐 분쇄된 규조토가루 45~52중량%에 물 23.25~27.35중량%를 투입 및 혼합하는 물 혼합단계; 물 혼합단계를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 일정 온도 온도로 가열하여 혼합물 외면을 코팅하는 코팅단계; 코팅단계를 거쳐 코팅 완료된 코팅 혼합물을 상온에서 냉각하는 냉각단계; 냉각단계를 거쳐 상온에서 냉각된 코팅 혼합물에 접착제 20~24중량%를 투입하여 혼합하는 접착제 혼합단계; 상기 접착제 혼합단계를 거쳐 접착제가 혼합된 혼합물에 고분자 응집제 0.5~1.5중량%를 투입한 후 일정시간 교반하여 혼합하는 응집제 혼합단계; 상기 응집제 혼합단계를 거쳐 고분자 응집제가 혼합된 혼합물에 고흡수성수지 0.1~0.3중량%를 투입하여 혼합하는 고흡수성수지 혼합단계; 상기 고흡수성수지 혼합단계를 거쳐 고흡수성수지가 혼합된 혼합물에 항균제 0.01~0.05중량%를 투입하여 혼합하는 항균제 혼합단계; 및 상기 항균제 혼합단계를 거쳐 항균제가 혼합된 혼합물을 상온에서 건조하여 규조토가루를 이용한 녹지 않는 인공 눈을 완성하는 인공눈 완성단계를 포함한다.On the other hand, in the method of manufacturing insoluble artificial snow using diatomaceous earth powder according to the present invention, in the manufacturing method of insoluble artificial snow using diatomaceous earth powder, the diatomaceous earth is heated in a heating furnace under a temperature condition of a certain temperature or higher to have a size of 10 to 500 mesh. Diatomaceous earth grinding step of grinding into a powder state of; A water mixing step of adding and mixing 23.25 to 27.35% by weight of water to 45 to 52% by weight of diatomaceous earth powder pulverized through the pulverization step, based on the total weight% of insoluble artificial snow using diatomaceous earth powder; A coating step of coating the outer surface of the mixture by adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step and heating the mixture to a predetermined temperature; A cooling step of cooling the coating mixture that has been coated through the coating step at room temperature; An adhesive mixing step of mixing by adding 20 to 24% by weight of the adhesive to the coating mixture cooled at room temperature through the cooling step; A coagulant mixing step of adding 0.5 to 1.5% by weight of a polymer coagulant to the mixture in which the adhesive is mixed through the adhesive mixing step and then stirring and mixing for a predetermined time; A super absorbent polymer mixing step of adding 0.1 to 0.3% by weight of a super absorbent polymer to the mixture in which the polymer coagulant is mixed through the coagulant mixing step and mixing; An antimicrobial agent mixing step of mixing by adding 0.01 to 0.05% by weight of an antimicrobial agent to a mixture in which the super absorbent polymer is mixed through the super absorbent polymer mixing step; And an artificial snow completion step of drying the mixture in which the antibacterial agent is mixed through the antibacterial agent mixing step at room temperature to complete an insoluble artificial snow using diatomaceous earth powder.

더욱이, 상기 물 혼합단계와 코팅단계 사이에는 물 혼합단계를 거쳐 혼합된 혼합물에 축광분말과 안료를 투입하여 혼합하는 축광분말 및 안료 혼합단계가 더 진행되되, 상기 축광분말 및 안료 혼합단계는 상기 인공눈 완성단계를 거쳐 완성되는 규조토가루를 이용한 녹지 않는 인공 눈 100중량부에 대하여, 축광분말 0.1~0.3중량부 및 안료 0.1~0.3중량부를 투입하여 혼합하는 과정으로 이루어지는 것이 바람직하다.Moreover, between the water mixing step and the coating step, a photoluminescent powder and pigment mixing step of adding and mixing a photoluminescent powder and a pigment into the mixed mixture through a water mixing step is further proceeded. With respect to 100 parts by weight of insoluble artificial snow using diatomaceous earth powder completed through the snow completion step, 0.1 to 0.3 parts by weight of phosphorescent powder and 0.1 to 0.3 parts by weight of pigment are preferably added and mixed.

또한, 상기 접착제 혼합단계에서의 접착제는 글리세린으로 제공되는 한편, 상기 코팅단계에서의 지방산은 탄소수 12개 이상으로 이루어진 스테아르산(stearic acid) 또는 팜유의 팔미트산(palmitic acid)로 제공되는 것이 양호하다.In addition, the adhesive in the adhesive mixing step is provided as glycerin, while the fatty acid in the coating step is preferably provided as stearic acid or palmitic acid of palm oil having 12 or more carbon atoms. Do.

그리고 상기 규조토 분쇄단계에서의, 가열로에서 가열하는 온도조건은 1000℃이상의 온도조건으로 적용되고, 상기 코팅단계에서의, 물 혼합단계를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 가열하는 온도조건은 80~100℃로 적용되되, 상기 온도조건으로 가열하는 시간은 20~30분으로 적용되며, 상기 접착제 혼합단계에서의, 냉각단계를 거쳐 상온에서 냉각된 코팅 혼합물과 접착제 20~24중량%의 혼합은 10~15분간 교반하여 혼합되는 한편, 상기 응집제 혼합단계에서의, 접착제 혼합단계를 거쳐 접착제가 혼합된 혼합물과 고분자 응집제 0.5~1.5중량%의 혼합은 10~15분간 교반하여 혼합되는 것이 바람직하다.And in the diatomaceous earth pulverization step, the temperature condition heated in the heating furnace is applied to a temperature condition of 1000°C or higher, and in the coating step, after adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step The heating temperature condition is applied at 80 to 100°C, and the heating time at the temperature condition is applied at 20 to 30 minutes, and in the adhesive mixing step, the coating mixture cooled at room temperature through the cooling step and the adhesive 20 to The mixture of 24% by weight is mixed by stirring for 10 to 15 minutes, while the mixture of 0.5 to 1.5% by weight of the polymer coagulant and the mixture in which the adhesive is mixed through the adhesive mixing step in the coagulant mixing step is stirred for 10 to 15 minutes. It is preferred to be mixed.

본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법의 효과를 설명하면 다음과 같다.The effect of the artificial snow that does not melt using diatomaceous earth powder according to the present invention and the method of manufacturing the same will be described as follows.

첫째, 10~500메쉬 크기의 분말상태인 규조토가루, 물, 접착제, 300~600메쉬 크기의 입도를 갖는 고흡수성수지, 지방산, 고분자 응집제, 항균제를 포함하여 구성되되, 규조토 분쇄단계, 물 혼합단계, 코팅단계, 냉각단계, 접착제 혼합단계, 응집제 혼합단계, 고흡수성수지 혼합단계, 항균제 혼합단계 및 인공눈 완성단계를 통해 제조됨으로써 제조 과정이 간단하면서도 제조비용이 저렴하며, 특히 제조 후 일정한 온도 조건을 유지하지 않더라도 인공 눈의 형태 또는 상태가 변하지 않도록 할 수 있으며, 이를 통하여 놀이나 트리 장식용 등으로 다양한 활용이 가능하다.First, it is composed of diatomaceous earth powder in powder form of 10 to 500 mesh, water, adhesive, super absorbent resin having a particle size of 300 to 600 mesh, fatty acid, polymer coagulant, antibacterial agent, diatomaceous earth grinding step, water mixing step , Coating step, cooling step, adhesive mixing step, coagulant mixing step, super absorbent polymer mixing step, antibacterial agent mixing step and artificial snow completion step, so that the manufacturing process is simple and the manufacturing cost is low. It is possible to prevent the shape or state of the artificial snow from changing even if it is not maintained, and through this, it can be used in a variety of ways for play or tree decoration.

둘째, 축광분말 및 안료가 더 혼합 적용되는 축광분말 및 안료 혼합단계를 더 포함함으로써 어두운 곳에서 일정 조도의 빛을 발하면서 트리 장식용 등에서의 더욱 향상된 활용성 및 심미감을 구현할 수 있다.Second, by further including the step of mixing the photoluminescent powder and the pigment in which the photoluminescent powder and the pigment are further mixed and applied, it is possible to realize more improved usability and aesthetics in tree decoration, etc., while emitting light of a certain illuminance in a dark place.

도 1은 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법을 단계별로 나타낸 블록도.
도 2 내지 3은 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법에 의해 제조된 인공 눈에 대한 사용예시를 나타낸 사용예시 사진들.
1 is a block diagram showing step-by-step a method of manufacturing non-melting artificial snow using diatomaceous earth powder according to the present invention.
2 to 3 are examples of use photos showing an example of use of artificial snow manufactured by the method of manufacturing insoluble artificial snow using diatomaceous earth powder according to the present invention.

이하, 첨부된 도면을 참조하여 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법의 바람직한 실시예를 상세히 설명한다.Hereinafter, a preferred embodiment of an insoluble artificial snow using diatomaceous earth powder and a method of manufacturing the same according to the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법을 단계별로 나타낸 블록도이며, 도 2 내지 3은 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법에 의해 제조된 인공 눈에 대한 사용예시를 나타낸 사용예시 사진들이다.1 is a block diagram showing a step-by-step method of manufacturing non-melting artificial snow using diatomaceous earth powder according to the present invention, and FIGS. 2 to 3 are manufactured by the manufacturing method of non-melting artificial snow using diatomaceous earth powder according to the present invention. These are example photos showing examples of use for artificial snow.

먼저, 본 발명의 바람직한 실시예에 따른 규조토가루를 이용한 녹지 않는 인공 눈은 규조토가루, 물, 접착제, 고흡수성수지, 지방산 등 다수의 성분을 일정순서에 따라 분쇄, 일정온도 조건 및 시간 조건으로 혼합, 냉각하여 구성된 혼합물로 완성되는 것으로 이하에서는, 규조토가루를 이용한 녹지 않는 인공 눈 및 규조토가루를 이용한 녹지 않는 인공 눈 혼합물을 동일한 의미로서 혼용하여 사용하기로 한다.First, in the insoluble artificial snow using diatomaceous earth powder according to a preferred embodiment of the present invention, a number of components such as diatomaceous earth powder, water, adhesive, super absorbent resin, fatty acid, etc. are pulverized in a certain order, and mixed under a certain temperature condition and time condition. Hereinafter, insoluble artificial snow using diatomaceous earth powder and insoluble artificial snow mixture using diatomaceous earth powder will be used interchangeably as the same meaning.

본 발명의 바람직한 실시예에 따른 규조토가루를 이용한 녹지 않는 인공 눈은 10~500메쉬 크기의 분말상태인 규조토가루, 물, 접착제, 300~600메쉬 크기의 입도를 갖는 고흡수성수지, 지방산, 고분자 응집제, 항균제를 포함하여 구성된다.Insoluble artificial snow using diatomaceous earth powder according to a preferred embodiment of the present invention is a powdery diatomaceous earth powder having a size of 10 to 500 mesh, water, an adhesive, a super absorbent polymer having a particle size of 300 to 600 mesh, fatty acid, and polymer coagulant , Comprising an antimicrobial agent.

특히, 상기와 같은 구성들의 혼합으로 구성되는 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈 혼합물은 10~500메쉬 크기의 분말상태인 규조토가루 45~52중량%, 물 23.25~27.35중량%, 접착제 20~24중량%, 300~600메쉬 크기의 입도를 갖는 고흡수성수지 0.1~0.3중량%, 지방산 1~3중량%, 고분자 응집제 0.5~1.5중량%, 항균제 0.01~0.05중량%로 혼합되는 것이 바람직하다.In particular, the insoluble artificial snow mixture using the diatomaceous earth powder according to the present invention composed of a mixture of the above components is 45 to 52% by weight of the powdery diatomaceous earth powder having a size of 10 to 500 mesh, 23.25 to 27.35% by weight of water, and an adhesive agent. It is preferable to be mixed with 20 to 24% by weight, 0.1 to 0.3% by weight of a superabsorbent resin having a particle size of 300 to 600 mesh, 1 to 3% by weight of fatty acid, 0.5 to 1.5% by weight of a polymer coagulant, and 0.01 to 0.05% by weight of an antimicrobial agent. Do.

전술한 바와 같은 구성으로 이루어진 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈은 특히, 상기 규조토가루를 이용한 녹지 않는 인공 눈 혼합물 100중량부에 대하여, 축광분말 0.1~0.3중량부 및 안료 0.1~0.3중량부를 더 포함하는 것이 더욱 바람직하다.The artificial snow that does not melt using the diatomaceous earth powder according to the present invention having the configuration as described above is, in particular, based on 100 parts by weight of the insoluble artificial snow mixture using the diatomaceous earth powder, 0.1 to 0.3 parts by weight of phosphorescent powder and 0.1 to 0.3 parts by weight of the pigment. It is more preferable to further include parts by weight.

이때, 상기 안료는 인공 눈의 색상을 백색으로 구현할 수 있도록 백색안료로 제공됨이 바람직하며, 물론 인공 눈의 색상을 다양한 컬러 중 어느 하나로 구현할 수 있도록 초록색, 빨간색, 파란색, 노란색 등의 안료 중 어느 하나의 컬러안료로 제공될 수도 있는 것이다.In this case, the pigment is preferably provided as a white pigment so that the color of artificial snow can be realized as white, and of course, any one of the pigments such as green, red, blue, and yellow so that the color of artificial snow can be realized in any one of various colors. It can also be provided as a color pigment of.

또한, 전술한 바와 같은 구성으로 이루어진 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈에서의, 상기 접착제는 글리세린으로 구성되는 한편, 상기 지방산은 탄소수 12개 이상으로 이루어진 스테아르산(stearic acid) 또는 팜유의 팔미트산(palmitic acid)로 구성되는 것이 바람직하다.In addition, in the artificial snow that does not melt using the diatomaceous earth powder according to the present invention having the configuration as described above, the adhesive is composed of glycerin, while the fatty acid is stearic acid or palm oil having 12 or more carbon atoms. It is preferably composed of palmitic acid.

도 1 내지 3을 참고하면, 전술한 바와 같은 혼합물로 제조되는 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법은 규조토가루를 이용하여 녹지 않는 인공 눈을 제조하는 방법으로서, 크게 분류하면 규조토 분쇄단계(S110), 물 혼합단계(S120), 코팅단계(S130), 냉각단계(S140), 접착제 혼합단계(S150), 응집제 혼합단계(S160), 고흡수성수지 혼합단계(S170), 항균제 혼합단계(S180) 및 인공눈 완성단계(S190)를 포함한다.Referring to Figures 1 to 3, the method of manufacturing insoluble artificial snow using diatomaceous earth powder according to the present invention prepared from the mixture as described above is a method of manufacturing artificial snow that does not melt using diatomaceous earth powder. Diatomaceous earth grinding step (S110), water mixing step (S120), coating step (S130), cooling step (S140), adhesive mixing step (S150), coagulant mixing step (S160), super absorbent polymer mixing step (S170), antibacterial agent It includes the mixing step (S180) and the artificial snow completion step (S190).

구체적으로, 상기 규조토 분쇄단계(S110)는 규조토를 일정온도 이상의 온도조건으로 가열로에서 가열하여 10~500메쉬 크기의 분말상태로 분쇄하는 과정으로 이루어진다.Specifically, the diatomaceous earth pulverization step (S110) consists of a process of pulverizing the diatomaceous earth into a powder having a size of 10 to 500 mesh by heating in a heating furnace under a temperature condition of a predetermined temperature or higher.

특히, 상기와 같은 규조토 분쇄단계(S110)에서의, 가열로에서 가열하는 온도조건은 1000℃이상의 온도조건으로 적용되는 것이 바람직하다.In particular, in the diatomaceous earth pulverization step (S110) as described above, the temperature condition for heating in the heating furnace is preferably applied to a temperature condition of 1000°C or higher.

이때, 상기와 같은 1000℃이상의 온도조건으로 규조토를 분쇄하는 이유는 규조토에 대한 분쇄작업이 용이하게 이루어질 수 있도록 하기 위함이다.At this time, the reason for pulverizing the diatomaceous earth under a temperature condition of 1000°C or higher as described above is to facilitate the pulverization operation of the diatomaceous earth.

한편, 상기 물 혼합단계(S120)는 규조토가루를 이용한 녹지 않는 인공 눈 전체 중량%에 대하여, 분쇄단계(S110)를 거쳐 분쇄된 규조토가루 45~52중량%에 물 23.25~27.35중량%를 투입 및 혼합하는 과정으로 이루어짐이 바람직하다.On the other hand, in the water mixing step (S120), 23.25 to 27.35% by weight of water is added to 45 to 52% by weight of the diatomaceous earth powder pulverized through the pulverization step (S110) with respect to the total weight% of insoluble artificial snow using diatomaceous earth powder. It is preferable that it consists of a process of mixing.

또한, 상기 코팅단계(S130)는 물 혼합단계(S120)를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 일정 온도 온도로 가열하여 혼합물 외면을 코팅하는 과정으로 이루어진다.In addition, the coating step (S130) comprises a process of coating the outer surface of the mixture by adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step (S120) and heating to a certain temperature.

특히, 상기 코팅단계(S130)에서의 지방산은 탄소수 12개 이상으로 이루어진 스테아르산(stearic acid) 또는 팜유의 팔미트산(palmitic acid)로 제공되는 것이 바람직하다.In particular, the fatty acid in the coating step (S130) is preferably provided as stearic acid having 12 or more carbon atoms or palmitic acid of palm oil.

더욱이, 상기와 같은 코팅단계(S130)에서의, 물 혼합단계(S120)를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 가열하는 온도조건은 80~100℃로 적용되며, 아울러 상기 온도조건으로 가열하는 시간은 20~30분으로 적용되는 것이 바람직한 것이다.Moreover, in the coating step (S130) as described above, after adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step (S120), the temperature condition for heating is applied at 80 to 100°C. It is preferable to apply the heating time in the temperature condition in 20 to 30 minutes.

상기와 같은 코팅단계(S130)에서의, 온도조건 및 가열시간은 가열 온도가 80℃ 이하의 온도에서는 너무 낮은 온도에 의해 상기 혼합물에 지방산이 쉽게 코팅되지 않기 때문이다.In the coating step (S130) as described above, the temperature conditions and the heating time are because fatty acids are not easily coated on the mixture due to too low a temperature at a heating temperature of 80° C. or less.

또한, 가열하는 가열 온도가 100℃ 이상의 온도에서는 상기 지방산이 쉽게 코팅될 수 있는 반면에 높은 온도에 의해 상기 혼합물에 코팅되는 지방산의 코팅두께가 얇아져 쉽게 벗겨지기 때문이다.In addition, this is because the fatty acid can be easily coated at a heating temperature of 100° C. or higher, whereas the fatty acid coating thickness of the fatty acid coated on the mixture is thinned due to the high temperature and thus easily peeled off.

그러므로 코팅단계(S130)에서의, 물 혼합단계(S120)를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 가열하는 온도조건과 가열시간은 80~100℃와 20~30분으로 적용됨이 바람직한 것이다.Therefore, in the coating step (S130), after adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step (S120), the temperature conditions and heating time are applied at 80 to 100°C and 20 to 30 minutes. This is desirable.

한편, 상기 냉각단계(S140)는 코팅단계(S130)를 거쳐 코팅 완료된 코팅 혼합물을 상온에서 냉각하는 과정으로 이루어진다.On the other hand, the cooling step (S140) consists of a process of cooling the coating mixture that has been coated through the coating step (S130) at room temperature.

그리고 상기 접착제 혼합단계(S150)는 상기 냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물에 접착제 20~24중량%를 투입하여 혼합하는 과정으로 이루어진다.And the adhesive mixing step (S150) consists of a process of mixing by adding 20 to 24% by weight of the adhesive to the coating mixture cooled at room temperature through the cooling step (S140).

상기와 같은 접착제 혼합단계(S150)에서의, 냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물과 접착제 20~24중량%의 혼합은 10~15분간 교반하여 혼합되는 것이 바람직하다.In the adhesive mixing step (S150) as described above, the mixing of the coating mixture cooled at room temperature through the cooling step (S140) and 20 to 24% by weight of the adhesive is preferably mixed by stirring for 10 to 15 minutes.

더욱이, 상기 접착제 혼합단계(S150)에서의 접착제는 글리세린으로 제공되는 것이 바람직한 것이다.Moreover, the adhesive in the adhesive mixing step (S150) is preferably provided with glycerin.

전술한 바와 같은 접착제 혼합단계(S150)는 냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물에 점성을 부여하기 위한 것으로, 냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물에 글리세린을 20중량% 미만으로 투입할 경우, 녹지 않는 인공 눈의 점성이 약하게 되어 천연 눈에서와 같은 뭉쳤다 풀어지는 과정을 반복할 수 없게 된다.The adhesive mixing step (S150) as described above is to impart viscosity to the coating mixture cooled at room temperature through the cooling step (S140), and 20 weight of glycerin is added to the coating mixture cooled at room temperature through the cooling step (S140). If the amount is less than %, the viscosity of artificial snow that does not melt becomes weak, and the process of lumping and releasing as in natural snow cannot be repeated.

또한, 글리세린을 25중량% 초과하여 투입할 경우에는 녹지 않는 인공 눈의 점성이 상대적으로 강하게 되어 천연 눈에서와 같은 뭉친 후에 풀어지는 과정이 원활하게 이루어지지 않게 된다.In addition, when more than 25% by weight of glycerin is added, the viscosity of the artificial snow that does not melt becomes relatively strong, so that the process of loosening after lumping as in natural snow does not occur smoothly.

그러므로 접착제 혼합단계(S150)는 냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물과 접착제인 글리세린 20~24중량%가 10~15분간 교반하여 혼합되는 것이 바람직한 것이다.Therefore, in the adhesive mixing step (S150), it is preferable that the coating mixture cooled at room temperature through the cooling step (S140) and 20 to 24% by weight of the adhesive glycerin are stirred for 10 to 15 minutes.

한편, 상기 응집제 혼합단계(S160)는 상기 접착제 혼합단계(S150)를 거쳐 접착제가 혼합된 혼합물에 고분자 응집제 0.5~1.5중량%를 투입한 후 일정시간 교반하여 혼합하는 과정으로 이루어진다.On the other hand, the coagulant mixing step (S160) consists of a process of mixing by adding 0.5 to 1.5% by weight of a polymer coagulant to the mixture in which the adhesive is mixed through the adhesive mixing step (S150), followed by stirring for a predetermined period of time.

특히, 상기와 같은 응집제 혼합단계(S160)에서의, 접착제 혼합단계(S150)를 거쳐 접착제가 혼합된 혼합물과 고분자 응집제 0.5~1.5중량%의 혼합은 10~15분간 교반하여 혼합되는 것이 바람직하다.In particular, in the coagulant mixing step (S160) as described above, the mixture of 0.5 to 1.5% by weight of the polymer coagulant and the mixture in which the adhesive is mixed through the adhesive mixing step (S150) is preferably mixed by stirring for 10 to 15 minutes.

한편, 상기 고흡수성수지 혼합단계(S170)는 상기 응집제 혼합단계(S160)를 거쳐 고분자 응집제가 혼합된 혼합물에 고흡수성수지 0.1~0.3중량%를 투입하여 혼합하는 과정으로 이루어진다.On the other hand, the super absorbent polymer mixing step (S170) consists of a process of mixing by adding 0.1 to 0.3% by weight of a super absorbent polymer to the mixture in which the polymer coagulant is mixed through the coagulant mixing step (S160).

상기와 같은 고흡수성수지 혼합단계(S170)를 통해 응집제 혼합단계(S160)를 거쳐 고분자 응집제가 혼합된 혼합물에 고흡수성수지 0.1~0.3중량%를 투입하여 혼합함으로써 고흡수성수지에 고분자 응집제가 혼합된 혼합물이 흡수되면서 인공 눈의 특성상 트리나 트리 주변의 바닥 등에 사용할 경우에는 흩뿌려진 상태에서 변형이 없게 하면서 손으로 일정량 들어올려 흩뿌릴 경우에도 끈적이지 않게 흩뿌릴 수 있게 되도록 할 수 있다.The polymer coagulant is mixed in the super absorbent polymer by adding 0.1 to 0.3% by weight of the super absorbent polymer to the mixture in which the polymer coagulant is mixed through the coagulant mixing step (S160) through the super absorbent polymer mixing step (S170) as described above. As the mixture is absorbed, when used on a tree or the floor around a tree, due to the nature of artificial snow, it can be scattered without being sticky even when a certain amount is lifted and scattered by hand while not being deformed in the scattered state.

또한, 상기 항균제 혼합단계(S180)는 상기 고흡수성수지 혼합단계(S170)를 거쳐 고흡수성수지가 혼합된 혼합물에 항균제 0.01~0.05중량%를 투입하여 혼합하는 과정으로 이루어진다.In addition, the antimicrobial agent mixing step (S180) consists of a process of mixing by adding 0.01 to 0.05% by weight of an antimicrobial agent to the mixture in which the super absorbent polymer is mixed through the super absorbent polymer mixing step (S170).

이때, 고흡수성수지라 함은 고흡수성폴리머를 의미한다.In this case, the term super absorbent polymer means a super absorbent polymer.

상기와 같은 항균제 혼합단계(S180)를 통해 고흡수성수지 혼합단계(S170)를 거쳐 고흡수성수지가 혼합된 혼합물에 항균제 0.01~0.05중량%를 투입하여 혼합함으로써 제조된 녹지 않는 인공 눈의 사용시에, 어린 아이들의 피부와 접촉하여도 전혀 해가 되지 않도록 하면서, 어린 아이들의 피부를 안정되게 보호할 수 있는 것이다.When using insoluble artificial snow prepared by mixing by adding 0.01 to 0.05% by weight of an antimicrobial agent to the mixture in which the super absorbent polymer is mixed through the super absorbent polymer mixing step (S170) through the antibacterial agent mixing step (S180) as described above, It is able to stably protect the skin of young children while preventing any harm even if they come into contact with the skin of young children.

그리고 상기 인공눈 완성단계(S190)는 상기 항균제 혼합단계(S180)를 거쳐 항균제가 혼합된 혼합물을 상온에서 건조하여 규조토가루를 이용한 녹지 않는 인공 눈을 완성하는 과정으로 이루어진다.In addition, the artificial snow completion step (S190) consists of a process of completing the insoluble artificial snow using diatomaceous earth powder by drying the mixture in which the antibacterial agent is mixed through the antibacterial agent mixing step (S180) at room temperature.

전술한 바와 같은 과정으로 이루어진 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법에서, 특히 각 단계에 적용되는 각 성분의 중량%로 기재된 양은 인공눈 완성단계(S190)를 통해 제조된 규조토가루를 이용한 녹지 않는 인공 눈에 대한 전체 중량%인, 즉 100중량%로 하였을 경우의 인공 눈 전체 중량%에 대한 상대적인 중량%의 양을 의미하는 것이다.In the method of manufacturing an insoluble artificial snow using diatomaceous earth powder according to the present invention, which is made of the above-described process, in particular, the amount described in weight percent of each component applied to each step is the diatomaceous earth prepared through the artificial snow completion step (S190). It means the amount of the relative weight% with respect to the total weight% of the artificial snow in the case of 100 weight %, which is the total weight% of the artificial snow that does not melt using powder.

아울러, 후술될 축광분말 및 안료 혼합단계(S120')에서의 축광분말과 안료의 혼합되는 양은 인공눈 완성단계(S190)를 통해 제조된 규조토가루를 이용한 녹지 않는 인공 눈에 대한 양 전체를 100중량부로 기준으로 하였을 경우에, 각각 0.1~0.3중량부로 적용되는 것을 의미한다.In addition, the amount of the phosphorescent powder and the pigment mixed in the phosphorescent powder and pigment mixing step (S120') to be described later is 100 weight of the total amount for insoluble artificial snow using the diatomaceous earth powder prepared through the artificial snow completion step (S190). When based on parts, it means that each is applied in an amount of 0.1 to 0.3 parts by weight.

다시 말하면, 전술한 바와 같은 과정으로 이루어진 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법은 상기 물 혼합단계(S120)와 코팅단계(S130) 사이에는 물 혼합단계(S120)를 거쳐 혼합된 혼합물에 축광분말과 안료를 투입하여 혼합하는 축광분말 및 안료 혼합단계(S120')가 더 진행될 수 있다.In other words, the manufacturing method of insoluble artificial snow using diatomaceous earth powder according to the present invention consisting of the above-described process is mixed through a water mixing step (S120) between the water mixing step (S120) and the coating step (S130). The photoluminescent powder and pigment mixing step (S120') of mixing by adding the photoluminescent powder and the pigment to the resulting mixture may be further performed.

이때, 상기 축광분말 및 안료 혼합단계(S120')는 상기 인공눈 완성단계(190)를 거쳐 완성되는 규조토가루를 이용한 녹지 않는 인공 눈 100중량부에 대하여, 축광분말 0.1~0.3중량부 및 안료 0.1~0.3중량부를 투입하여 혼합하는 과정으로 이루어지는 것이 바람직한 것이다.At this time, the phosphorescent powder and pigment mixing step (S120') is based on 100 parts by weight of insoluble artificial snow using diatomaceous earth powder completed through the artificial snow completion step 190, 0.1 to 0.3 parts by weight of phosphorescent powder and 0.1 parts by weight of pigment. It is preferable that it consists of a process of mixing by adding ~0.3 parts by weight.

더욱이, 상기 축광분말 및 안료 혼합단계(S120')에서의 안료는 인공 눈의 색상을 백색으로 구현할 수 있도록 백색안료로 제공됨이 바람직하며, 물론 인공 눈의 색상을 다양한 컬러 중 어느 하나로 구현할 수 있도록 초록색, 빨간색, 파란색, 노란색 등의 안료 중 어느 하나의 컬러안료로 제공될 수도 있는 것이다.Moreover, the pigment in the phosphorescent powder and pigment mixing step (S120') is preferably provided as a white pigment so that the color of the artificial snow can be realized as white, and of course, the color of the artificial snow is green so that the color of the artificial snow can be realized in any one of various colors. It may be provided as any one color pigment among pigments such as red, blue, and yellow.

이에 따라, 전술한 바와 같은 본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법에 대해 상기 축광분말 및 안료가 더 혼합 적용되는 축광분말 및 안료 혼합단계(S120')가 더 적용됨으로써 이에 의해 제조된 인공 눈을 통해 백색 또는 백색 이외의 다양한 컬러 중 어느 하나의 색이 구현됨과 동시에 어두운 곳에서 일정 조도의 빛을 발하면서 트리 장식용 등에서의 더욱 향상된 활용성 및 심미감을 구현할 수 있게 되는 것이다.Accordingly, by further applying the phosphorescent powder and pigment mixing step (S120') in which the phosphorescent powder and the pigment are further mixed and applied to the manufacturing method of insoluble artificial snow using diatomaceous earth powder according to the present invention as described above. Through the manufactured artificial snow, any one of a variety of colors other than white or white is realized, and at the same time, it emits light of a certain illuminance in a dark place, and more improved usability and aesthetics in tree decoration, etc. can be realized.

본 발명에 따른 규조토가루를 이용한 녹지 않는 인공 눈 및 그의 제조방법에 의하면, 10~500메쉬 크기의 분말상태인 규조토가루, 물, 접착제, 300~600메쉬 크기의 입도를 갖는 고흡수성수지, 지방산, 고분자 응집제, 항균제를 포함하여 구성되되, 규조토 분쇄단계, 물 혼합단계, 코팅단계, 냉각단계, 접착제 혼합단계, 응집제 혼합단계, 고흡수성수지 혼합단계, 항균제 혼합단계 및 인공눈 완성단계를 통해 제조됨으로써 제조 과정이 간단하면서도 제조비용이 저렴하며, 특히 제조 후 일정한 온도 조건을 유지하지 않더라도 인공 눈의 형태 또는 상태가 변하지 않도록 할 수 있으며, 이를 통하여 놀이나 트리 장식용 등으로 다양한 활용이 가능하다.According to the insoluble artificial snow using diatomaceous earth powder according to the present invention and a method for manufacturing the same, diatomaceous earth powder in a powder state of 10 to 500 mesh, water, adhesive, super absorbent resin having a particle size of 300 to 600 mesh, fatty acid, Consisting of a polymer coagulant and an antibacterial agent, it is manufactured through a diatomaceous earth crushing step, a water mixing step, a coating step, a cooling step, an adhesive mixing step, a coagulant mixing step, a superabsorbent resin mixing step, an antibacterial agent mixing step, and an artificial snow completion step. Although the manufacturing process is simple, the manufacturing cost is low. In particular, the shape or state of the artificial snow can be prevented from changing even if a constant temperature condition is not maintained after manufacturing, and through this, it can be used for various purposes such as play or tree decoration.

더욱이, 축광분말 및 안료가 더 혼합 적용되는 축광분말 및 안료 혼합단계를 더 포함함으로써 어두운 곳에서 일정 조도의 빛을 발하면서 트리 장식용 등에서의 더욱 향상된 활용성 및 심미감을 구현할 수 있는 것이다.Moreover, by further including the step of mixing the phosphorescent powder and the pigment in which the phosphorescent powder and the pigment are further mixed and applied, it is possible to realize more improved utility and aesthetics in tree decoration, etc., while emitting light of a certain illuminance in a dark place.

이상에서 본 발명의 구체적인 실시예를 상세히 설명하였으나, 본 발명은 이에 한정되는 것은 아니며, 본 발명은 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 다양한 변형의 실시가 가능하며, 이러한 변형은 본 발명의 범위에 포함된다.Although specific embodiments of the present invention have been described in detail above, the present invention is not limited thereto, and the present invention can be implemented in various modifications by those of ordinary skill in the art to which the present invention belongs. Is included within the scope of the present invention.

Claims (8)

삭제delete 삭제delete 삭제delete 삭제delete 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법에 있어서,
규조토를 일정온도 이상의 온도조건으로 가열로에서 가열하여 10~500메쉬 크기의 분말상태로 분쇄하는 규조토 분쇄단계(S110);
규조토가루를 이용한 녹지 않는 인공 눈 전체 중량%에 대하여, 분쇄단계(S110)를 거쳐 분쇄된 규조토가루 45~52중량%에 물 23.25~27.35중량%를 투입 및 혼합하는 물 혼합단계(S120);
물 혼합단계(S120)를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 일정 온도 온도로 가열하여 혼합물 외면을 코팅하는 코팅단계(S130);
코팅단계(S130)를 거쳐 코팅 완료된 코팅 혼합물을 상온에서 냉각하는 냉각단계(S140);
냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물에 접착제 20~24중량%를 투입하여 혼합하는 접착제 혼합단계(S150);
상기 접착제 혼합단계(S150)를 거쳐 접착제가 혼합된 혼합물에 고분자 응집제 0.5~1.5중량%를 투입한 후 일정시간 교반하여 혼합하는 응집제 혼합단계(S160);
상기 응집제 혼합단계(S160)를 거쳐 고분자 응집제가 혼합된 혼합물에 고흡수성수지 0.1~0.3중량%를 투입하여 혼합하는 고흡수성수지 혼합단계(S170);
상기 고흡수성수지 혼합단계(S170)를 거쳐 고흡수성수지가 혼합된 혼합물에 항균제 0.01~0.05중량%를 투입하여 혼합하는 항균제 혼합단계(S180); 및
상기 항균제 혼합단계(S180)를 거쳐 항균제가 혼합된 혼합물을 상온에서 건조하여 규조토가루를 이용한 녹지 않는 인공 눈을 완성하는 인공눈 완성단계(S190)를 포함하여 이루어진 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법.
In the manufacturing method of artificial snow that does not melt using diatomaceous earth powder,
Diatomaceous earth pulverization step (S110) of heating the diatomaceous earth in a heating furnace under a temperature condition of a predetermined temperature or higher to pulverize the powder into a powder having a size of 10 to 500 mesh;
Water mixing step (S120) of adding and mixing 23.25 to 27.35% by weight of water to 45 to 52% by weight of diatomaceous earth powder pulverized through the pulverization step (S110) with respect to the total weight% of artificial snow that does not melt using diatomaceous earth powder;
Coating step (S130) of coating the outer surface of the mixture by adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step (S120) and heating to a certain temperature;
A cooling step (S140) of cooling the coating mixture that has been coated through the coating step (S130) at room temperature;
An adhesive mixing step (S150) of mixing by adding 20 to 24% by weight of an adhesive to the coating mixture cooled at room temperature through the cooling step (S140);
Coagulant mixing step (S160) in which 0.5 to 1.5% by weight of a polymer coagulant is added to the mixture in which the adhesive is mixed through the adhesive mixing step (S150), followed by stirring for a predetermined period of time;
A super absorbent polymer mixing step (S170) of adding and mixing 0.1 to 0.3% by weight of a super absorbent polymer to the mixture in which the polymer coagulant is mixed through the coagulant mixing step (S160);
An antimicrobial agent mixing step (S180) of mixing by adding 0.01 to 0.05% by weight of an antimicrobial agent to the mixture in which the super absorbent polymer is mixed through the super absorbent polymer mixing step (S170); And
After the antibacterial agent mixing step (S180), the mixture in which the antibacterial agent is mixed is dried at room temperature to complete the artificial snow that does not melt using diatomaceous earth powder (S190). Manufacturing method.
제5항에 있어서,
상기 물 혼합단계(S120)와 코팅단계(S130) 사이에는 물 혼합단계(S120)를 거쳐 혼합된 혼합물에 축광분말과 안료를 투입하여 혼합하는 축광분말 및 안료 혼합단계(S120')가 더 진행되되,
상기 축광분말 및 안료 혼합단계(S120')는 상기 인공눈 완성단계(190)를 거쳐 완성되는 규조토가루를 이용한 녹지 않는 인공 눈 100중량부에 대하여, 축광분말 0.1~0.3중량부 및 안료 0.1~0.3중량부를 투입하여 혼합하는 과정으로 이루어지는 것을 특징으로 하는 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법.
The method of claim 5,
Between the water mixing step (S120) and the coating step (S130), a photoluminescent powder and pigment mixing step (S120') in which the photoluminescent powder and pigment are added to the mixture mixed through the water mixing step (S120) and mixed is further proceeded. ,
The phosphorescent powder and pigment mixing step (S120') is based on 100 parts by weight of insoluble artificial snow using diatomaceous earth powder completed through the artificial snow completion step 190, 0.1 to 0.3 parts by weight of phosphorescent powder and 0.1 to 0.3 parts by weight of pigment. Method for producing insoluble artificial snow using diatomaceous earth powder, characterized in that consisting of a process of mixing by adding a part by weight.
제5항에 있어서,
상기 접착제 혼합단계(S150)에서의 접착제는 글리세린으로 제공되는 한편,
상기 코팅단계(S130)에서의 지방산은 탄소수 12개 이상으로 이루어진 스테아르산(stearic acid) 또는 팜유의 팔미트산(palmitic acid)로 제공되는 것을 특징으로 하는 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법.
The method of claim 5,
While the adhesive in the adhesive mixing step (S150) is provided with glycerin,
The fatty acid in the coating step (S130) is a method for producing insoluble artificial snow using diatomaceous earth powder, characterized in that it is provided as stearic acid having 12 or more carbon atoms or palmitic acid of palm oil .
제5항에 있어서,
상기 규조토 분쇄단계(S110)에서의, 가열로에서 가열하는 온도조건은 1000℃이상의 온도조건으로 적용되고,
상기 코팅단계(S130)에서의, 물 혼합단계(S120)를 거쳐 혼합된 혼합물에 지방산 1~3중량%를 투입한 후 가열하는 온도조건은 80~100℃로 적용되되, 상기 온도조건으로 가열하는 시간은 20~30분으로 적용되며,
상기 접착제 혼합단계(S150)에서의, 냉각단계(S140)를 거쳐 상온에서 냉각된 코팅 혼합물과 접착제 20~24중량%의 혼합은 10~15분간 교반하여 혼합되는 한편,
상기 응집제 혼합단계(S160)에서의, 접착제 혼합단계(S150)를 거쳐 접착제가 혼합된 혼합물과 고분자 응집제 0.5~1.5중량%의 혼합은 10~15분간 교반하여 혼합되는 것을 특징으로 하는 규조토가루를 이용한 녹지 않는 인공 눈의 제조방법.
The method of claim 5,
In the diatomaceous earth grinding step (S110), the temperature condition for heating in the heating furnace is applied as a temperature condition of 1000°C or higher,
In the coating step (S130), after adding 1 to 3% by weight of fatty acids to the mixture mixed through the water mixing step (S120), the temperature condition for heating is applied at 80 to 100°C, and heating under the above temperature condition The time is applied in 20-30 minutes,
In the adhesive mixing step (S150), the coating mixture cooled at room temperature through the cooling step (S140) and 20 to 24% by weight of the adhesive are mixed by stirring for 10 to 15 minutes,
In the coagulant mixing step (S160), the mixture in which the adhesive is mixed through the adhesive mixing step (S150) and 0.5 to 1.5% by weight of the polymer coagulant are mixed by stirring for 10 to 15 minutes. Manufacturing method of artificial snow that does not melt.
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KR910021466A (en) 1990-02-02 1991-12-20 원본미기재 Snow composition and snow manufacturing method
KR20020072148A (en) 2001-03-09 2002-09-14 조미강 A manufacture method of human work snow
KR20020074406A (en) 2001-03-19 2002-09-30 고종문 Artificial snow and the preparation thereof
KR101767947B1 (en) 2016-03-14 2017-08-14 김은진 Manufacturing method of artificial snow
KR20190101898A (en) 2018-02-23 2019-09-02 테크노알팡 프랑스 Artificial Snow Making Method and Product For Implementing The Method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR910021466A (en) 1990-02-02 1991-12-20 원본미기재 Snow composition and snow manufacturing method
KR20020072148A (en) 2001-03-09 2002-09-14 조미강 A manufacture method of human work snow
KR20020074406A (en) 2001-03-19 2002-09-30 고종문 Artificial snow and the preparation thereof
KR101767947B1 (en) 2016-03-14 2017-08-14 김은진 Manufacturing method of artificial snow
KR20190101898A (en) 2018-02-23 2019-09-02 테크노알팡 프랑스 Artificial Snow Making Method and Product For Implementing The Method

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