KR102223300B1 - 입체 선택적 중합으로부터 1,4-cis/신디오택틱 1,2 구조를 가지는 입체 규칙적 이중블록 폴리뷰타디엔 - Google Patents

입체 선택적 중합으로부터 1,4-cis/신디오택틱 1,2 구조를 가지는 입체 규칙적 이중블록 폴리뷰타디엔 Download PDF

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KR102223300B1
KR102223300B1 KR1020167015090A KR20167015090A KR102223300B1 KR 102223300 B1 KR102223300 B1 KR 102223300B1 KR 1020167015090 A KR1020167015090 A KR 1020167015090A KR 20167015090 A KR20167015090 A KR 20167015090A KR 102223300 B1 KR102223300 B1 KR 102223300B1
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polybutadiene
stereoregular diblock
cis
phosphine
block
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KR20160084854A (ko
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지오바니 리치
쥬세페 리온
안나 소마치
프란체스코 마시
마리아 프란체스카 피리니
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베르살리스 에스.피.에이.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7095—Cobalt, nickel or compounds thereof
    • C08F4/7096—Cobalt or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
KR1020167015090A 2013-11-05 2014-11-03 입체 선택적 중합으로부터 1,4-cis/신디오택틱 1,2 구조를 가지는 입체 규칙적 이중블록 폴리뷰타디엔 Active KR102223300B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT001828A ITMI20131828A1 (it) 2013-11-05 2013-11-05 Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
ITMI2013A001828 2013-11-05
PCT/IB2014/065764 WO2015068094A1 (en) 2013-11-05 2014-11-03 Stereoregular diblock polybutadienes having a 1,4-cis/syndiotactic 1,2 structure from stereospecific polymerization

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KR20160084854A KR20160084854A (ko) 2016-07-14
KR102223300B1 true KR102223300B1 (ko) 2021-03-05

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US (1) US10093763B2 (https=)
EP (1) EP3066139B1 (https=)
JP (1) JP6574190B2 (https=)
KR (1) KR102223300B1 (https=)
CN (1) CN105683230B (https=)
BR (1) BR112016009097B1 (https=)
CA (1) CA2925263C (https=)
EA (1) EA031540B1 (https=)
ES (1) ES2726852T3 (https=)
HR (1) HRP20190874T1 (https=)
HU (1) HUE043431T2 (https=)
IT (1) ITMI20131828A1 (https=)
MX (1) MX377140B (https=)
MY (1) MY172664A (https=)
PL (1) PL3066139T3 (https=)
PT (1) PT3066139T (https=)
RS (1) RS58772B1 (https=)
SG (1) SG11201603260WA (https=)
TR (1) TR201907212T4 (https=)
TW (1) TWI678379B (https=)
WO (1) WO2015068094A1 (https=)

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ITMI20131830A1 (it) 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
IT201700059763A1 (it) 2017-05-31 2018-12-01 Versalis Spa Copolimeri butadiene-isoprene di-blocco e procedimento per la loro preparazione
IT202000028823A1 (it) 2020-11-27 2022-05-27 Consiglio Nazionale Ricerche Copolimeri dienici a stereoblocchi e relativo processo di preparazione.

Citations (1)

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KR100216718B1 (ko) * 1991-04-24 1999-09-01 마쯔모또 에이찌 폴리부타디엔의 제조방법

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US3522332A (en) 1967-06-02 1970-07-28 Japan Synthetic Rubber Co Ltd Process for the preparation of 1,2-polybutadiene
JPS4917667B1 (https=) * 1970-12-25 1974-05-02
JPS4917666B1 (https=) * 1970-12-25 1974-05-02
US3817968A (en) 1972-11-28 1974-06-18 Bridgestone Tire Co Ltd Method of producing equibinary (cis 1.4-1.2) polybutadiene
DE2447203C3 (de) 1974-10-03 1982-03-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Polybutadien
JPS53143685A (en) 1977-05-23 1978-12-14 Japan Synthetic Rubber Co Ltd Preparation of 1,2-polybutadiene
US4255296A (en) 1977-12-02 1981-03-10 Bridgestone Tire Company Limited Polybutadiene rubber composition
DE2911262A1 (de) 1979-03-22 1980-10-02 Bayer Ag Katalysator, dessen herstellung und verfahren zur polymerisation von butadien
DE3000708A1 (de) 1980-01-10 1981-07-16 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von reaktionsprodukten aus konjugierten diolefinen und aromatischen kohlenwasserstoffen
JPS56109204A (en) * 1980-01-31 1981-08-29 Japan Synthetic Rubber Co Ltd Preparation of polybutadiene
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IT1231774B (it) 1989-08-03 1991-12-21 Enichem Anic Spa Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine.
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ITMI20011813A1 (it) 2001-08-24 2003-02-24 Enichem Spa Complessi di cobalto utili nella polimerizzazione del 1,3-butadiene
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CA2925263C (en) 2021-11-30
HRP20190874T1 (hr) 2019-07-12
CA2925263A1 (en) 2015-05-14
JP6574190B2 (ja) 2019-09-11
US20160264707A1 (en) 2016-09-15
SG11201603260WA (en) 2016-05-30
MY172664A (en) 2019-12-09
HUE043431T2 (hu) 2019-08-28
RS58772B1 (sr) 2019-06-28
TW201522393A (zh) 2015-06-16
PL3066139T3 (pl) 2019-08-30
EP3066139B1 (en) 2019-02-20
EA201690625A1 (ru) 2016-12-30
JP2016536447A (ja) 2016-11-24
WO2015068094A1 (en) 2015-05-14
US10093763B2 (en) 2018-10-09
TR201907212T4 (tr) 2019-06-21
CN105683230B (zh) 2018-07-13
PT3066139T (pt) 2019-05-31
TWI678379B (zh) 2019-12-01
KR20160084854A (ko) 2016-07-14
MX377140B (es) 2025-03-07
ES2726852T3 (es) 2019-10-09
BR112016009097B1 (pt) 2021-09-14
MX2016005664A (es) 2016-12-07
EA031540B1 (ru) 2019-01-31
EP3066139A1 (en) 2016-09-14
ITMI20131828A1 (it) 2015-05-06
BR112016009097A2 (https=) 2017-08-01
HK1223386A1 (en) 2017-07-28

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