KR102199390B9 - 질소가 도핑된 메탄 산화이량화 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법 - Google Patents

질소가 도핑된 메탄 산화이량화 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법

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Publication number
KR102199390B9
KR102199390B9 KR1020190064546A KR20190064546A KR102199390B9 KR 102199390 B9 KR102199390 B9 KR 102199390B9 KR 1020190064546 A KR1020190064546 A KR 1020190064546A KR 20190064546 A KR20190064546 A KR 20190064546A KR 102199390 B9 KR102199390 B9 KR 102199390B9
Authority
KR
South Korea
Prior art keywords
methane
coupling reaction
oxidative coupling
nitrogen
doped catalyst
Prior art date
Application number
KR1020190064546A
Other languages
English (en)
Other versions
KR20200137737A (ko
KR102199390B1 (ko
Inventor
김희연
김태우
오장원
유지행
이대근
Original Assignee
한국에너지기술연구원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 한국에너지기술연구원 filed Critical 한국에너지기술연구원
Priority to KR1020190064546A priority Critical patent/KR102199390B1/ko
Publication of KR20200137737A publication Critical patent/KR20200137737A/ko
Application granted granted Critical
Publication of KR102199390B1 publication Critical patent/KR102199390B1/ko
Publication of KR102199390B9 publication Critical patent/KR102199390B9/ko

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/30Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/34Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • B01J31/0254Nitrogen containing compounds on mineral substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32Manganese, technetium or rhenium
    • C07C2523/34Manganese
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
KR1020190064546A 2019-05-31 2019-05-31 질소가 도핑된 메탄 산화이량화 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법 KR102199390B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020190064546A KR102199390B1 (ko) 2019-05-31 2019-05-31 질소가 도핑된 메탄 산화이량화 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020190064546A KR102199390B1 (ko) 2019-05-31 2019-05-31 질소가 도핑된 메탄 산화이량화 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법

Publications (3)

Publication Number Publication Date
KR20200137737A KR20200137737A (ko) 2020-12-09
KR102199390B1 KR102199390B1 (ko) 2021-01-08
KR102199390B9 true KR102199390B9 (ko) 2023-03-23

Family

ID=73787316

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020190064546A KR102199390B1 (ko) 2019-05-31 2019-05-31 질소가 도핑된 메탄 산화이량화 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법

Country Status (1)

Country Link
KR (1) KR102199390B1 (ko)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101039604B1 (ko) 2009-06-04 2011-06-09 한국과학기술연구원 실리카 에어로젤 담지 촉매 및 이를 이용한 메탄 전환 방법
KR102038042B1 (ko) 2017-04-06 2019-10-30 한국과학기술연구원 금속이 첨가된, 실리카-담지 나트륨 텅스테이트 촉매, 이의 제조방법 및 이를 이용한 메탄의 산화이량화 반응방법

Also Published As

Publication number Publication date
KR20200137737A (ko) 2020-12-09
KR102199390B1 (ko) 2021-01-08

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G170 Re-publication after modification of scope of protection [patent]