KR102189512B1 - Package type biogas purification system capable of simultaneous removal of ammonia and hydrogen sulfide - Google Patents

Package type biogas purification system capable of simultaneous removal of ammonia and hydrogen sulfide Download PDF

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KR102189512B1
KR102189512B1 KR1020200132168A KR20200132168A KR102189512B1 KR 102189512 B1 KR102189512 B1 KR 102189512B1 KR 1020200132168 A KR1020200132168 A KR 1020200132168A KR 20200132168 A KR20200132168 A KR 20200132168A KR 102189512 B1 KR102189512 B1 KR 102189512B1
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biogas
ammonia
hydrogen sulfide
circulating water
wet
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정헌회
강광남
허문수
신명석
송장환
이종웅
오동윤
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에이티이 주식회사
한국환경공단
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • B01D47/063Spray cleaning with two or more jets impinging against each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/14Packed scrubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/002Removal of contaminants
    • C10K1/003Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004Sulfur containing contaminants, e.g. hydrogen sulfide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/20Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/105Removal of contaminants of nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/05Biogas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

Disclosed is a package type biogas purification system capable of simultaneous removal of ammonia and hydrogen sulfide. The package type biogas purification system comprises: a wet-type reactor for receiving biogas downward to exhaust the received biogas upward, and for spraying circulating water downward through a spray nozzle installed at an inner top portion to remove ammonia and hydrogen sulfide by dissolution mechanism and chemical mechanism with respect to the received biogas; a dry-type reactor for receiving the biogas firstly processed by the sup-type reactor downward to exhaust the biogas upward, being filled with a hybrid media manufactured by mixing 20 to 25 wt% of cellulose, 40 to 59.99 wt% of calcium carbonate, 5 to 10 wt% of magnesium carbonate, and 15 to 34.99 wt% of iron hydroxide, and 0.01 to 0.5 wt% of nutrients, so that the firstly processed biogas passes through the hybrid media to secondly remove ammonia and hydrogen sulfide by chemical mechanism and biological mechanism due to microbe; and a condensed water introduction part for introducing condensed water including sulfuric acid of high density from the dry reactor to the spray nozzle to improve removal efficiency of the ammonia in the wet-type reactor by increasing sulfuric acid density in the circulation water.

Description

암모니아와 황화수소의 동시 제거가 가능한 패키지형 바이오 가스 정제시스템 {PACKAGE TYPE BIOGAS PURIFICATION SYSTEM CAPABLE OF SIMULTANEOUS REMOVAL OF AMMONIA AND HYDROGEN SULFIDE}Package type biogas purification system capable of simultaneously removing ammonia and hydrogen sulfide {PACKAGE TYPE BIOGAS PURIFICATION SYSTEM CAPABLE OF SIMULTANEOUS REMOVAL OF AMMONIA AND HYDROGEN SULFIDE}

본 발명은 바이오가스 내 유해성분인 암모니아와 황화수소를 제거할 수 있는 바이오가스 정제시스템에 관한 것으로서, 더욱 상세하게는 공정 응축수를 이용한 습식공정과 하이브리드 메디아를 적용한 건식공정으로 구성되어 암모니아 및 황화수소의 동시제거 가능한 안정적이고 경제성 있는 바이오가스 정제시스템에 관한 것이다. The present invention relates to a biogas purification system capable of removing ammonia and hydrogen sulfide, which are harmful components in biogas, and more specifically, a wet process using process condensate and a dry process using hybrid media, so that ammonia and hydrogen sulfide are simultaneously combined. It relates to a removable, stable and economical biogas purification system.

최근, 가축분뇨와 음식물쓰레기 등을 혼합, 유입하여 처리하는 통합바이오가스화 사업들이 진행되고 있으며, 단백질 분해과정에서 암모니아의 농도가 높게 나타나고 있어 탈황설비와 동시에 암모니아의 동시제거에 대한 고려가 필요한 실정이다. Recently, integrated biogasification projects that mix and treat livestock manure and food waste are in progress, and the concentration of ammonia is high in the process of protein decomposition, so it is necessary to consider simultaneous removal of ammonia with desulfurization facilities. .

바이오가스 조성물 중에 황화수소(H2S)와 암모니아(NH3)성분은 악취를 유발시킬 뿐만 아니라 후단 설비의 부식 등에 악영향을 끼칠 우려가 있어 필연적으로 바이오가스 생산시설은 유해성분을 제거할 수 있는 바이오 가스 정제설비가 중요한 공정 중에 하나이다. In the biogas composition, hydrogen sulfide (H 2 S) and ammonia (NH 3 ) components not only cause odor, but also have a risk of adversely affecting the corrosion of downstream facilities, inevitably, biogas production facilities can remove harmful components. The gas purification facility is one of the important processes.

황화수소제거에 대한 기술은 연구개발 및 적용실적이 확대되어 적정 성능을 유지하도록 운영되고 있으나, 유지관리 비용 과다 및 교체시에 발생되는 환경적인 측면의 안전성 확보 등 다양한 문제가 대두되고 있으며, 반면 암모니아 제거관련 연구는 많지 않은 상황으로 적정 제거기술에 대한 자료조차 충분하지 않은 상태이다. The technology for hydrogen sulfide removal is being operated to maintain proper performance due to the expansion of R&D and application performance, but various problems such as excessive maintenance cost and environmental safety security that occur during replacement are emerging. On the other hand, ammonia removal There are not many related studies, and data on appropriate removal techniques are not sufficient.

한편, 기존 기술로서 암모니아와 황화수소를 동시에 제거하고자 부착 미생물 담체를 이용한 시도가 있었으나, 각 반응단계별 약품과의 반응을 유지시키기 위한 공정구성이 복잡하고 미생물 성장을 위한 별도의 영양분 등을 공급해야 하는 어려움이 있다. On the other hand, as an existing technology, attempts have been made to use an attached microbial carrier to simultaneously remove ammonia and hydrogen sulfide, but the process configuration to maintain the reaction with the drug for each reaction step is complicated, and it is difficult to supply additional nutrients for microbial growth There is this.

또한 수세공정(water scrubbing) 방법이 있으나 암모니아는 물에 대한 용해도가 매우 높지만 황화수소의 경우 중성pH에서 용해도가 매우 낮아 pH를 높게 유지해야 주어야 하며, 또한 수세정에 막대한 양의 물이 소요되고 사용된 수용액의 2차 처리 문제가 발생하는 단점이 있었다. There is also a water scrubbing method, but ammonia has a very high solubility in water, but hydrogen sulfide has a very low solubility at neutral pH, so the pH must be kept high.In addition, a large amount of water is required for water washing There was a disadvantage in that the problem of secondary treatment of the aqueous solution occurred.

등록특허 10-1444186호Registered Patent No. 10-1444186 등록특허 10-0485961호Registered Patent No. 10-0485961 등록특허 10-1751207호Registered Patent No. 10-1751207 등록특허 10-0948334호Registered Patent No. 10-0948334

본 발명은 상기한 바와 같은 종래의 문제점을 해결하고자 창안된 것으로서, 공정내 발생되는 응축수의 순환을 통해 용해기작과 화학반응에 의한 황화수소 및 암모니아를 동시에 제거할 수 있는 습식반응조와 하이브리드 메디아와의 화학반응과 미생물 기작에 의한 황화수소 및 암모니아를 동시에 제거할 수 있는 건식반응조로 구성되어, 바이오가스내 암모니아와 황화수소를 효과적이고 안정적으로 동시에 제거할 수 있도록 개선된 형태를 갖는 암모니아와 황화수소의 동시 제거가 가능한 패키지형 바이오 가스 정제시스템을 제공하는데 목적이 있다. The present invention was invented to solve the conventional problems as described above, and the chemistry between the hybrid media and a wet reactor capable of simultaneously removing hydrogen sulfide and ammonia due to a dissolution mechanism and a chemical reaction through circulation of condensed water generated in the process It is composed of a dry reaction tank that can simultaneously remove hydrogen sulfide and ammonia caused by reaction and microbial mechanisms, and it is possible to simultaneously remove ammonia and hydrogen sulfide having an improved form to effectively and stably remove ammonia and hydrogen sulfide in biogas at the same time. An object is to provide a packaged biogas purification system.

다만, 본 발명의 목적은 이에만 제한되는 것은 아니며, 명시적으로 언급하지 않더라도 과제의 해결수단이나 실시 형태로부터 파악될 수 있는 목적이나 효과도 이에 포함됨은 물론이다. However, the object of the present invention is not limited thereto, and objects or effects that can be grasped from the solutions or embodiments of the problem are also included therein even if not explicitly mentioned.

상기한 목적을 달성하기 위한 본 발명의 암모니아와 황화수소의 동시 제거가 가능한 패키지형 바이오 가스 정제시스템은, 바이오가스가 하부로 유입되어 상부로 배출되며, 내측 상부에 설치된 분사노즐을 통해 순환수를 하향되게 분사하여 유입된 바이오가스에 대한 용해기작과 화학기작에 의해 암모니아와 황화수소를 제거하는 습식반응기; 상기 습식반응기에서 1차 처리된 바이오가스가 하부로 유입되어 상부로 배출되며, 내부에 셀룰로오스 20~25W%, 탄산칼슘 40~59.99W%, 탄산마그네슘 5~10W% 및 수산화철 15~34.99W%, 영양염류 0.01~0.5W%를 혼합하여 제조된 하이브리드 메디아가 충진되어, 상기 1차 처리된 바이오가스가 상기 하이브리드 메디아를 통과하면서 화학기작과 미생물에 의한 생물학적 기작에 의해 2차적으로 암모니아와 황화수소를 제거하는 건식반응기; 상기 건식반응기에서 생성된 고농도 황산이 포함된 응축수를 상기 분사노즐에 유입시켜, 상기 순환수의 황산농도를 증가시켜 상기 습식반응기에서의 암모니아 제거효율이 향상되게 하는 응축수 도입부;를 포함하는 것을 특징으로 한다. In the packaged biogas purification system capable of simultaneously removing ammonia and hydrogen sulfide to achieve the above object, the biogas is introduced into the lower portion and discharged to the upper portion, and the circulating water is lowered through the injection nozzle installed on the inner upper portion. A wet reactor for removing ammonia and hydrogen sulfide by a chemical mechanism and a dissolution mechanism for the introduced biogas by spraying so as to be sprayed; The biogas, which has been primarily treated in the wet reactor, flows into the lower portion and is discharged to the upper portion, and cellulose 20-25W%, calcium carbonate 40-59.99W%, magnesium carbonate 5-10W%, and iron hydroxide 15-34.99W%, inside. A hybrid media prepared by mixing 0.01 to 0.5 W% of nutrients is filled, and the first treated biogas passes through the hybrid media, and ammonia and hydrogen sulfide are secondarily removed by a chemical mechanism and a biological mechanism by microorganisms. A dry reactor; And a condensed water introduction unit configured to increase the sulfuric acid concentration of the circulating water by introducing condensed water containing high-concentration sulfuric acid generated in the dry reactor into the spray nozzle to improve the ammonia removal efficiency in the wet reactor. do.

상기 습식반응기는, 하부 외주면 일측에 바이오가스가 유입되는 제1유입구와 상단에 상기 1차 처리된 바이오가스가 배출되는 제1배출구가 형성된 습식반응조; 상기 습식반응조의 내측 상부에 배치되며 하부로 순환수를 분사하는 분사노즐부; 상기 습식반응조의 저부에 형성되어, 상기 분사노즐부로부터 분사되어 상기 습식반응조 저부에 수집되는 순환수를 흡입하는 흡입노즐부; 상기 흡입노즐부와 상기 분사노즐부를 연결하며 상기 흡입노즐부를 통해 흡입된 순환수 및 상기 건식반응기에서 생성된 응축수를 연결하여 상기 분사노즐부에 공급하여 순환수의 순환이 이루어지도록 하는 순환수공급부; 상기 습식반응조의 내부에 설치되어 상기 바이오가스와 상기 순환수의 접촉효율을 증대시키는 폴리머 재질의 폴링제로 이루어진 충진재;를 포함하도록 구성될 수 있다. The wet reactor includes: a wet reactor having a first inlet through which biogas flows into one side of a lower outer circumferential surface and a first outlet through which the first processed biogas is discharged; A spray nozzle part disposed on the inner upper part of the wet reaction tank and spraying circulating water downward; A suction nozzle part formed at the bottom of the wet reaction tank and for sucking circulating water injected from the spray nozzle part and collected at the bottom of the wet reaction tank; A circulating water supply unit connecting the suction nozzle unit and the injection nozzle unit and supplying the circulating water sucked through the suction nozzle unit and the condensed water generated in the dry reactor to supply the circulating water to the injection nozzle unit to circulate the circulating water; It may be configured to include; a filler made of a polling agent made of a polymer material that is installed inside the wet reaction tank to increase the contact efficiency between the biogas and the circulating water.

상기 건식반응기는, 내부에 상기 하이브리드 메디아가 충진되며, 하부에는 상기 1차 처리된 바이오가스가 유입되는 제2유입구가 형성되고, 상부에는 최종 처리된 바이오가스가 배출되는 제2배출구가 형성된 건식반응조; 상기 건식반응조의 내측 하부에 결합되어 상기 1차 처리된 바이오가스를 상기 하이브리드 메디아 측으로 균등하게 분배하여 공급하는 가스분산 플레이트;를 포함하도록 구성될 수 있다. The dry reactor is a dry reactor in which the hybrid media is filled therein, a second inlet through which the first treated biogas is introduced is formed in the lower part, and a second outlet through which the finally treated biogas is discharged is formed in the upper part. ; It may be configured to include a; gas distribution plate coupled to the lower inner side of the dry reaction tank to evenly distribute and supply the first-treated biogas to the hybrid media side.

상기한 바에 따르면, 1차 습식공정과 2차 건식공정에 의한 연속적인 다단 제거반응으로 바이오가스내 암모니아와 황화수소의 제거가 이루어지기 때문에 공정이 매우 안정적이고 고효율의 제거가 가능하게 되며, 특히, 1차 습식공정에서 1차적으로 암모니아와 황화수소의 제거가 이루어지기 때문에 2차 건식공정에서 하이브리드 메디아의 폐색, 배관 폐색 등의 문제를 개선할 수 있게 된다. According to the above, since ammonia and hydrogen sulfide in the biogas are removed through a continuous multi-stage removal reaction by the first wet process and the second dry process, the process is very stable and highly efficient removal is possible. Since ammonia and hydrogen sulfide are firstly removed in the secondary wet process, problems such as clogging of hybrid media and pipe clogging in the secondary dry process can be improved.

또한, 건식반응조에서 발생되는 응축수를 활용하여 습식반응조의 순환수로 이용함으로써, 습식반응조에서 암모니아가 용해기작과 더불어 화학반응에 의한 제거가 촉진되어 암모니아의 제거효율을 크게 높일 수 있고, 습식반응조에 별도의 산을 공급할 필요가 없어 운용상 매우 경제적인 운용을 달성할 수 있다. In addition, by utilizing the condensed water generated in the dry reaction tank as circulating water in the wet reaction tank, ammonia is dissolved in the wet reaction tank and the removal by chemical reaction is promoted, greatly increasing the removal efficiency of ammonia. Since there is no need to supply a separate acid, very economical operation can be achieved.

또한 본 발명은 건식반응조에서 바이오가스내 황화수소와 암모니아를 동시에 제거하여 안정적인 운영을 이루어지게 하며, 메디아 내 영영분을 함유하여 별도 추가 설비가 필요없는 경제적인 설비를 구축할 수 있으며, 아울러, 약품 공급 등 설치가 필요없고 유지관리비가 절감되는 효과가 있다. In addition, the present invention enables stable operation by simultaneously removing hydrogen sulfide and ammonia in biogas in a dry reaction tank, and contains zero nutrients in the media, so that an economical facility that does not require additional equipment can be constructed, and also supplies drugs. There is no need to install the lamp, and the maintenance cost is reduced.

도 1은 본 발명의 일 실시 예에 따른 암모니아와 황화수소의 동시제거가 가능한 패키지형 바이오 가스 정제시스템을 나타낸 도면이고,
도 2는 도 1의 가스 분산플레이트의 다른 예를 나타낸 확대단면도이고,
도 3은 본 발명의 또 다른 형태의 가스 분산플레이트를 나타낸 확대단면도이고,
도 4는 본 발명의 또 다른 형태의 가스 분산플레이를 나타낸 확대단면도이다.
도 5는 도 4의 가스분리부재를 상부에서 바라본 상태를 나타낸 도면이다.
1 is a view showing a packaged biogas purification system capable of simultaneously removing ammonia and hydrogen sulfide according to an embodiment of the present invention,
2 is an enlarged cross-sectional view showing another example of the gas distribution plate of FIG. 1,
3 is an enlarged cross-sectional view showing another type of gas distribution plate of the present invention,
4 is an enlarged cross-sectional view showing another form of gas dispersion play according to the present invention.
5 is a view showing the gas separation member of FIG. 4 viewed from above.

이상의 본 발명의 목적들, 다른 목적들, 특징들 및 이점들은 첨부된 도면과 관련된 이하의 바람직한 실시 예들을 통해서 쉽게 이해될 것이다. 그러나 본 발명은 여기서 설명되는 실시 예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 오히려, 여기서 소개되는 실시 예들은 개시된 내용이 철저하고 완전해질 수 있도록 그리고 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 하기 위해 제공되는 것이다. The above objects, other objects, features, and advantages of the present invention will be easily understood through the following preferred embodiments related to the accompanying drawings. However, the present invention is not limited to the embodiments described herein and may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosed content may be thorough and complete, and the spirit of the present invention may be sufficiently transmitted to those skilled in the art.

본 명세서에서, 어떤 구성요소가 다른 구성요소 상에 있다고 언급되는 경우에 그것은 다른 구성요소 상에 직접 형성될 수 있거나 또는 그들 사이에 제 3의 구성요소가 개재될 수도 있다는 것을 의미한다. 또한, 도면들에 있어서, 구성요소들의 두께는 기술적 내용의 효과적인 설명을 위해 과장된 것이다. In the present specification, when a component is referred to as being on another component, it means that it may be formed directly on the other component or that a third component may be interposed between them. In addition, in the drawings, the thickness of the components is exaggerated for effective description of the technical content.

본 명세서에서 기술하는 실시 예들은 본 발명의 이상적인 예시도인 단면도 및/또는 평면도들을 참고하여 설명될 것이다. 도면들에 있어서, 막 및 영역들의 두께는 기술적 내용의 효과적인 설명을 위해 과장된 것이다. 따라서 제조 기술 및/또는 허용 오차 등에 의해 예시도의 형태가 변형될 수 있다. 따라서 본 발명의 실시 예들은 도시된 특정 형태로 제한되는 것이 아니라 제조 공정에 따라 생성되는 형태의 변화도 포함하는 것이다. 예를 들면, 직각으로 도시된 식각 영역은 라운드지거나 소정 곡률을 가지는 형태일 수 있다. 따라서 도면에서 예시된 영역들은 속성을 가지며, 도면에서 예시된 영역들의 모양은 소자의 영역의 특정형태를 예시하기 위한 것이며 발명의 범주를 제한하기 위한 것이 아니다. 본 명세서의 다양한 실시 예들에서 제1, 제2 등의 용어가 다양한 구성요소들을 기술하기 위해서 사용되었지만, 이들 구성 요소들이 이 같은 용어들에 의해 한정되어서는 안된다. 이들 용어들은 단지 어느 구성요소를 다른 구성요소와 구별시키기 위해서 사용되었을 뿐이다. 여기에 설명되고 예시되는 실시 예들은 그것의 상보적인 실시 예들도 포함한다. Embodiments described in the present specification will be described with reference to cross-sectional views and/or plan views, which are ideal exemplary views of the present invention. In the drawings, the thicknesses of films and regions are exaggerated for effective description of technical content. Accordingly, the shape of the exemplary diagram may be modified by manufacturing technology and/or tolerance. Accordingly, embodiments of the present invention are not limited to the specific form shown, but also include a change in form generated according to a manufacturing process. For example, the etched area shown at a right angle may be rounded or may have a shape having a predetermined curvature. Accordingly, the regions illustrated in the drawings have properties, and the shapes of the regions illustrated in the drawings are for exemplifying a specific shape of the region of the device and are not intended to limit the scope of the invention. In various embodiments of the present specification, terms such as first and second are used to describe various components, but these components should not be limited by these terms. These terms are only used to distinguish one component from another component. The embodiments described and illustrated herein also include complementary embodiments thereof.

본 명세서에서 사용된 용어는 실시 예들을 설명하기 위한 것이며, 본 발명을 제한하고자 하는 것은 아니다. 본 명세서에서, 단수형은 문구에서 특별히 언급하지 않는 한 복수형도 포함한다. 명세서에서 사용되는 '포함한다(comprises)' 및/또는 '포함하는(comprising)'은 언급된 구성요소는 하나 이상의 다른 구성요소의 존재 또는 추가를 배제하지 않는다. The terms used in this specification are for describing exemplary embodiments, and are not intended to limit the present invention. In this specification, the singular form also includes the plural form unless specifically stated in the phrase. As used in the specification, "comprises" and/or "comprising" does not exclude the presence or addition of one or more other elements.

아래의 특정 실시 예들을 기술하는데 있어서, 여러 가지의 특정적인 내용들은 발명을 더 구체적으로 설명하고 이해를 돕기 위해 작성되었다. 하지만, 본 발명을 이해할 수 있을 정도로 이 분야의 지식을 갖고 있는 독자는 이러한 여러 가지의 특정적인 내용들이 없어도 사용될 수 있다는 것을 인지할 수 있다. 어떤 경우에는, 발명을 기술하는데 있어서 흔히 알려졌으면서 발명과 크게 관련 없는 부분들은 본 발명을 설명하는데 있어 별 이유 없이 혼돈이 오는 것을 막기 위해 기술하지 않음을 미리 언급해 둔다. In describing the specific embodiments below, a number of specific contents have been prepared to explain the invention in more detail and to aid understanding. However, readers who have knowledge in this field to the extent that they can understand the present invention can recognize that it can be used without these various specific contents. In some cases, it is mentioned in advance that parts that are commonly known in describing the invention and are not largely related to the invention are not described in order to prevent confusion without any reason in describing the invention.

이하, 도 1을 참조하여, 본 발명의 일 실시 예에 따른 암모니아와 황화수소의 동시 제거가 가능한 패키지형 바이오가스 정제시스템에 대해 설명한다. Hereinafter, a packaged biogas purification system capable of simultaneously removing ammonia and hydrogen sulfide according to an embodiment of the present invention will be described with reference to FIG. 1.

본 발명의 바이오가스 정제시스템은, 바이오가스에 포함된 암모니아 및 황화수소를 순환수를 분사하여 용해기작과 화학기작에 의해 제거하는 습식반응기(10)와, 습식반응기(10)에서 1차 처리된 바이오가스를 하이브리드 메디아를 통과시켜 화학기작과 미생물에 의한 생물학적 기작에 의해 2차적으로 암모니아 및 황화수소를 제거하는 건식반응기(20) 및, 건식반응기에서 생성된 고농도 황산이 포함된 응축수를 습식반응기(10)에 개입시켜 순환수에 포함되게 하여 고농도 황산이 포함된 순환수를 분사하게 함으로써 습식반응기(10)에서의 암모니아 제거효율을 증대시키는 응축수 도입부(30)를 포함하도록 구성된다. The biogas purification system of the present invention includes a wet reactor 10 for removing ammonia and hydrogen sulfide contained in biogas by dissolving and chemical mechanisms by spraying circulating water, and biogas first treated in the wet reactor 10. A dry reactor (20) for secondary removal of ammonia and hydrogen sulfide by a chemical mechanism and a biological mechanism by microorganisms by passing gas through the hybrid media, and a wet reactor (10) for condensate containing high concentration sulfuric acid generated in the dry reactor. It is configured to include a condensed water introduction unit 30 for increasing the ammonia removal efficiency in the wet reactor 10 by intervening in the circulating water and spraying the circulating water containing high concentration sulfuric acid.

구체적으로, 본 발명의 바이오가스 정제시스템의 구성에 대해 설명한다. Specifically, the configuration of the biogas purification system of the present invention will be described.

습식반응기(10)는 습식반응조(11), 분사노즐부(12), 흡입노즐부(13), 순환수공급부(14), 충진재(15)를 포함하도록 구성된다. The wet reactor 10 is configured to include a wet reaction tank 11, an injection nozzle part 12, a suction nozzle part 13, a circulating water supply part 14, and a filler 15.

습식반응조(11)는 하부 일측에 바이오가스가 유입되는 제1유입구(11a)와 상측에 1차 처리된 바이오가스가 배출되는 제1배출구(11b)가 형성도며, 내부에 충진재(15)가 충진되도록 구성된다. The wet reaction tank 11 has a first inlet 11a through which biogas flows into the lower one side and a first outlet 11b through which biogas that has been first processed is discharged, and a filler 15 is formed therein. It is configured to be filled.

분사노즐부(12)는 습식반응조(11)의 내측 상부에 배치되어, 하부로 순환수(물)을 분사하도록 구성된다. 이렇게 분사된 순환수는 습식반응조(11) 내부로 유입된 바이오가스에 포함된 암모니와 황화수소를 용해기작과 화학기작에 의해 제거한다. The injection nozzle part 12 is disposed on the inner upper part of the wet reaction tank 11 and is configured to inject circulating water (water) to the lower part. The circulating water sprayed in this way removes ammonia and hydrogen sulfide contained in the biogas flowing into the wet reaction tank 11 through a dissolution mechanism and a chemical mechanism.

즉, 습식반응조(11)에 유입된 바이오가스는 분사노즐부(12)에서 분사된 순환수(물)과 접촉하면서 바이오가스에 포함된 암모니아와 황화수소가 제거된다. That is, ammonia and hydrogen sulfide contained in the biogas are removed while the biogas introduced into the wet reaction tank 11 is in contact with the circulating water (water) sprayed from the injection nozzle unit 12.

구체적으로, 바이오가스에 포함된 암모니아와 황화수소는 물에 대한 용해도가 높은 기체로서 순환수와 접촉하여 용해기작에 의해 암모니아와 황화수소가 제거될 수 있다. Specifically, ammonia and hydrogen sulfide contained in biogas are gases having high solubility in water, and ammonia and hydrogen sulfide may be removed by a dissolution mechanism by contacting circulating water.

아울러, 후술할 건식반응기(20)에서 공급된 응축수가 분사노즐부(12)에 합류되어 순환수로서 분사되게 되며, 이 응축수에 포함된 고농도 황산이 바이오가스에 포함된 암모니아와 화학적 반응기작을 일으켜 암모니아 제거효율이 상승하게 된다. In addition, the condensed water supplied from the dry reactor 20, which will be described later, is joined to the spray nozzle unit 12 and is sprayed as circulating water, and the high concentration sulfuric acid contained in the condensed water causes a chemical reaction with ammonia contained in the biogas. The ammonia removal efficiency increases.

응축수에 포함된 황산(H2SO4)과 암모니아의 화학반응은 다음과 같다. The chemical reaction between sulfuric acid (H 2 SO 4 ) and ammonia contained in condensed water is as follows.

H2SO4 + NH3 --> (NH4)2SO4 H 2 SO 4 + NH 3 --> (NH 4 ) 2 SO 4

흡입노즐부(13)는 분사노즐부(12)로부터 분사된 후 습식반응조(11) 저부에 수집된 순환수를 흡입하는 구성이며, 순환수공급부(14)는 흡입노즐부(13)와 분사노즐부(12)를 연결하도록 구성되어, 흡입노즐부(13)를 통해 습식반응조(11) 저부에 수집된 순환수의 흡입이 이루어지게 하고, 흡입된 순환수를 순환시켜 분사노즐부(12)에 공급하도록 한다. The suction nozzle part 13 is configured to suck the circulating water collected at the bottom of the wet reaction tank 11 after being injected from the injection nozzle part 12, and the circulating water supply part 14 is a suction nozzle part 13 and a spray nozzle. It is configured to connect the part 12, so that the circulating water collected in the bottom of the wet reaction tank 11 is sucked through the suction nozzle part 13, and the circulating water is circulated to the injection nozzle part 12. Supply.

순환수공급부(14)는 흡입노즐부(13)와 분사노즐부(12)를 연결하는 순환수를 순환시켜 공급하는 순환배관(14a)과, 이 순환배관(14a) 상에 설치되어 순환수를 이송시키는 순환펌프(14b)를 포함하도록 구성된다. The circulating water supply unit 14 is a circulation pipe 14a that circulates and supplies the circulating water connecting the suction nozzle unit 13 and the injection nozzle unit 12, and is installed on the circulation pipe 14a to supply circulating water. It is configured to include a circulation pump 14b for transferring.

충진재(15)는 습식반응조(21) 내에 설치되어 바이오가스와 순환수의 접촉효율을 증대시키는 것으로 폴리머 재질의 폴링제로 이루어진다.The filler 15 is installed in the wet reaction tank 21 to increase the contact efficiency between the biogas and the circulating water, and is made of a polling agent made of a polymer material.

여기서 폴링제는 와이어와 같은 선형 폴리머재질의 불규칙적인 형태로 이루어져 3차원 허니컴구조로 이루어진 것으로서, 습식반응조(11) 내에 채워지도록 구성되어, 습식반응조(11) 상부에서 분사되어 낙하하는 순환수와 바이오가스의 접촉효율을 증대시킴으로써, 바이오가스 내 암모니아와 황화수소의 제거효율이 향상될 수 있다. Here, the polling agent is composed of an irregular shape of a linear polymer material such as a wire and has a three-dimensional honeycomb structure, and is configured to be filled in the wet reaction tank 11, and the circulating water and biotechnology are sprayed from the top of the wet reaction tank 11 and dropped. By increasing the contact efficiency of the gas, the removal efficiency of ammonia and hydrogen sulfide in the biogas can be improved.

건식반응기(20)는 건식반응조(21), 하이브리드메디아(22), 가스분산 플레이트(25)를 포함하도록 구성된다. The dry reactor 20 is configured to include a dry reactor 21, a hybrid media 22, and a gas dispersion plate 25.

건식반응조(21)는 하부에 제2유입구(21a)가 형성되고, 상부에는 제2배출구가 형성된다. 제2유입구(21a)는 연결배관(p)을 통해 습식반응조(11)의 제1배출구(11b)와 연결되도록 구성되어, 습식반응조(11)로부터 배출되는 1차 처리된 바이오가스가 건식반응조(21)로 유입되게 하며, 제2배출구(21)는 건식반응조(21) 내부로 유입된 1차 처리된 바이오가스가 하이브리드 메디아(22)를 거쳐 2차적으로 암모니아와 황화수소가 제거되고, 최종 처리된 바이오가스가 배출되도록 한다. The dry reaction tank 21 has a second inlet 21a formed at the bottom and a second outlet 21a at the top. The second inlet 21a is configured to be connected to the first outlet 11b of the wet reaction tank 11 through a connection pipe p, so that the first treated biogas discharged from the wet reaction tank 11 is discharged from the dry reaction tank ( 21), and in the second outlet 21, ammonia and hydrogen sulfide are secondaryly removed from the first treated biogas flowing into the dry reactor 21 through the hybrid media 22, Allow biogas to be released.

하이브리드 메디아(22)는 건식반응조(21) 내에 충진되어 유입된 1차 처리된 바이오가스가 통과되면서 화학기작과 미생물에 의한 생물학적 기작에 의해 2차적으로 암모니아와 황화수를 제거하기 위한 메디아이다. The hybrid media 22 is a media for secondaryly removing ammonia and sulfide water by a chemical mechanism and a biological mechanism by microorganisms as the first treated biogas filled and introduced into the dry reaction tank 21 passes.

하이브리드 메디아(22)는 셀룰로오스 20~25W%, 탄산칼슘 40~59.99W%, 탄산마그네슘 5~10W% 및 수산화철 15~34.99W%, 영양염류 0.01~0.5W%를 혼합하여 펠릿타입으로 성형하여 제조된 것으로 이루어진다. Hybrid Media (22) is manufactured by mixing cellulose 20-25W%, calcium carbonate 40-59.99W%, magnesium carbonate 5-10W%, iron hydroxide 15-34.99W%, and nutrient salts 0.01-0.5W% to form pellets. Consists of

여기서, 셀룰로오스는 다공성 섬유의 구조로 되어있어 경량화 및 비표면적이 높을 뿐 아니라 메디아 지지체로서 내구성을 가지고 있다. 여기에 탄산칼슘과 탄산마그네슘등의 탄산염을 첨가하여 암모니아 제거시 생성된 산을 제거하도록 하였고, 황화합물을 제거하도록 수산화철(Fe(OH)3)입자를 첨가하였으며, 추가로 미량의 산화망간과 영양염류를 첨가하였다. Here, cellulose has a structure of a porous fiber, so it is lightweight and has high specific surface area, and has durability as a media support. Carbonates such as calcium carbonate and magnesium carbonate were added to remove the acid generated when removing ammonia, and iron hydroxide (Fe(OH) 3 ) particles were added to remove sulfur compounds, and trace amounts of manganese oxide and nutrients were added. Was added.

하이브리드 메디아(22)는 금속이온(Fe, Mg 등)과의 화학반응기작과 메디아에 서식하는 황산화 미생물, 질산화 및 탈질화 미생물을 이용한 생물반응기작에 의해 황화수소와 암모니아를 동시에 제거할 수 있는 팰랫타입의 메디아이다. Hybrid media (22) is a pallet capable of simultaneously removing hydrogen sulfide and ammonia by a chemical reaction mechanism with metal ions (Fe, Mg, etc.) and a bioreaction mechanism using sulfation microbes, nitrification and denitrification microbes living in the media. It is a median of type.

메디아 조성물 중 셀룰로오스는 높은 다공성을 유지할 뿐 아니라 일정 수분을 보유할 수 있게 하며, 황산화 미생물, 질산화 및 탈질화 미생물이 부착하여 서식할 수 있는 지지체를 형성한다. In the media composition, cellulose not only maintains a high porosity, but also allows it to retain a certain moisture, and forms a support in which sulfated microorganisms, nitrifying and denitrifying microorganisms can adhere to and inhabit.

바이오가스 중의 황화수소는 하이브리드 메디아(22)의 조성물인 수산화철과 반응하여 반응물(FeS)를 형성하여 제거되어지며 그 반응식은 다음과 같다.Hydrogen sulfide in the biogas reacts with iron hydroxide, which is a composition of the hybrid media 22, to form a reactant (FeS), and the reaction formula is as follows.

2Fe(OH)3 + 3H2S --------> 2FeS + S + 6H2O2Fe(OH) 3 + 3H 2 S --------> 2FeS + S + 6H 2 O

이러한 화학적 반응과 동시에 황화수소는 메디아에 서식하는 황산화 미생물에 의해 산화반응이 진행되어지는데 이는 바이오가스 내 존재하는 잔류 산소를 이용하여 이루어진다.Simultaneously with this chemical reaction, hydrogen sulfide undergoes an oxidation reaction by sulfation microorganisms living in the media, which is achieved by using residual oxygen present in the biogas.

H2S + 0.5O2 --------> S + H2OH 2 S + 0.5 O 2 --------> S + H 2 O

H2S + 2O2 --------> H2SO4 H 2 S + 2O 2 --------> H 2 SO 4

또한, 바이오가스 성분 중의 암모니아는 수분과 반응하여 암모니아 이온이 되어 호기성 조건하에서 질산화미생물에 의해 다시 아질산성 질소(NO2 --N)와 질산성 질소(NO3 --N)로 전환하게 된다. 화학독립영양미생물인 질산화미생물(Nitrosomonas, Nitrobacter)은 에너지원으로 암모니아를 이용하며 그 반응식은 다음과 같다.In addition, ammonia in the biogas component reacts with moisture to become ammonia ions, and is converted into nitrite nitrogen (NO 2 -- N) and nitrate nitrogen (NO 3 -- N) again by nitrifying microorganisms under aerobic conditions. Nitrosomonas, Nitrobacter, a chemical independent nutritional microorganism, uses ammonia as an energy source, and its reaction formula is as follows.

NH3 + H → NH4 NH 3 + H + → NH 4 +

2NH4 + 3O2 → 2NO2 - + 2H2O + 4H+ 2NH 4 + + 3O 2 → 2NO 2 - + 2H 2 O + 4H +

2NO2 - + O2 → 2NO3 - 2NO 2 - + O 2 → 2NO 3 -

한편, 상기와 같이, 바이오가스가 하이브리드 메디아(22)를 통한 화학기작과 미생물에 의한 생물학적 반응기작에 의해 황화수소와 암모니아가 제거되는 과정에서 황산(H2SO4)이 함유된 응축수가 발생되게 되며, 이 응축수는 건식반응조(21)의 저부에 고여 수집되게 된다. 이때, 건식반응조(21)의 하단에는 건식반응조(21)의 저부에 수집된 응축수를 배수시키기 위한 배수구(24)가 구비된다. On the other hand, as described above, condensate containing sulfuric acid (H 2 SO 4 ) is generated in the process of removing hydrogen sulfide and ammonia from biogas through a chemical mechanism through the hybrid media 22 and a biological reaction operation by microorganisms. , This condensed water is collected and collected in the bottom of the dry reaction tank 21. At this time, a drain port 24 for draining the condensed water collected at the bottom of the dry reaction tank 21 is provided at the lower end of the dry reaction tank 21.

도 1을 참조하면, 가스분산 플레이트(25)는 건식반응조(21)의 내측 하부에 설치되어, 습식반응기(10)로부터 공급되어 제2유입구(21a)를 통해 유입된 1차 처리된 바이오가스를 하이브리드 메디아(22) 측으로 균등하게 분배하여 공급하기 위한 수단이다. 가스분산 플레이트(25)는 일정크기를 가진 다수의 기공이 형성된 금속판재로 이루어질 수 있으며, 가스분산 플레이트(25)는 건식반응조(21)의 내부에 가로방향으로 배치되도록 구성되어, 기공들을 통해 바이오가스 분배되어 하이브리드 메디아(22)에 균등하게 분배되어 공급될 수 있다. 따라서, 바이오가스가 하이브리드 메디아(22)에 균등하게 분배되어 고르게 접촉될 수 있어 황화수소와 암모니아의 제거효율이 향상될 수 있다. Referring to Figure 1, the gas dispersion plate 25 is installed in the lower inner side of the dry reaction tank 21, the first processed biogas supplied from the wet reactor 10 and introduced through the second inlet (21a). It is a means for evenly distributed and supplied to the hybrid media 22 side. The gas distribution plate 25 may be made of a metal plate material having a plurality of pores having a predetermined size, and the gas distribution plate 25 is configured to be disposed in the interior of the dry reaction tank 21 in the horizontal direction. Gas may be distributed and evenly distributed and supplied to the hybrid media 22. Accordingly, the biogas can be evenly distributed to the hybrid media 22 and contacted evenly, so that the removal efficiency of hydrogen sulfide and ammonia can be improved.

상기와 같이 본 발명의 가스분산 플레이트(25)는 단일판 형태로 이루어지는 것이나, 이에 한정되는 것은 아니며 2개의 판재가 이중구조를 이루도록 구성될 수도 있다. As described above, the gas distribution plate 25 of the present invention has a single plate shape, but is not limited thereto, and two plates may be configured to form a double structure.

도 2를 참조하면, 가스분산 플레이트(25)는 제1분산플레이트(26)와 제2분산플레이트(27)로 이루어질 수 있다. Referring to FIG. 2, the gas distribution plate 25 may include a first distribution plate 26 and a second distribution plate 27.

제1분산플레이트(26)와 제2분산플레이트(27)는 건식반응조(21)에 상하로 일정간격 이격되게 배치되도록 구성될 수 있다. 제1분산플레이트(26)와 제2분산플레이트(27)는 건식반응조(21)의 면적에 대응되게 구비되어, 제2유입구(21a)를 통해 유입된 바이오가스의 이동경로상에 배치된다. The first dispersion plate 26 and the second dispersion plate 27 may be configured to be disposed vertically in the dry reaction tank 21 at regular intervals. The first dispersion plate 26 and the second dispersion plate 27 are provided to correspond to the area of the dry reaction tank 21 and are disposed on the movement path of the biogas introduced through the second inlet 21a.

제1분산플레이트(26)와 제2분산플레이트(27)는 금속판으로 이루어진다. 제1분산플레이트(26)의 판면에는 일정 간격으로 원형으로 된 복수개의 제1기공(26a)이 구비되고, 제2분산플레이트(27)에는 일정간격으로 원형으로 된 복수의 제2기공(27b)이 구비된다. The first dispersion plate 26 and the second dispersion plate 27 are made of metal plates. The plate surface of the first dispersion plate 26 is provided with a plurality of first pores 26a that are circular at regular intervals, and the second dispersion plate 27 has a plurality of second pores 27b that are circular at regular intervals. Is equipped.

이때, 복수의 제1기공(26a)은 복수의 제2기공(27b)과 동일 수직축 상에 배치지 않고, 서로 어긋나도록 형성된다. In this case, the plurality of first pores 26a are not disposed on the same vertical axis as the plurality of second pores 27b, but are formed to shift from each other.

이에 의해, 제2유입구(21a)를 통해 유입된 바이오가스는 복수의 제1기공(26a)을 통과한 후, 제2분산플레이트(27)의 벽면에 부딛쳐 바이오가스가 분산되고, 양측에 배치된 제2기공(27b)을 통해 분배된다. Thereby, the biogas introduced through the second inlet 21a passes through the plurality of first pores 26a, and then hits the wall surface of the second dispersion plate 27 to disperse the biogas, and is disposed on both sides. It is distributed through the second pore (27b).

이와 같이, 복수의 제1기공(26a)으로 분배되어 공급되는 바이오가스가 제2분산플레이트(27)의 벽면에 부딛친 후 복수의 제2기공(27a)으로 다시 분산되어 공급되므로, 건식반응조(21)의 전영역에 균등하게 분배되어 공급되게 된다. 따라서, 바이오가스가 하이브리드 메디아(22)에 균등하게 분배되어 고르게 접촉될 수 있어 황화수소와 암모니아의 제거효율이 더욱 향상될 수 있다. In this way, since the biogas distributed and supplied to the plurality of first pores 26a hits the wall surface of the second dispersion plate 27 and is distributed and supplied again to the plurality of second pores 27a, the dry reaction tank ( It is distributed evenly and supplied to all areas of 21). Accordingly, the biogas can be evenly distributed to the hybrid media 22 and contacted evenly, so that the removal efficiency of hydrogen sulfide and ammonia can be further improved.

한편, 도시하지는 않았지만, 제1분산플레이트(26)에는 다수의 제1기공(26)들 사이에 장홀 형태로 이루어진 다수의 제1슬릿홀이 형성되고, 제2분산플레이트(27)에는 다수의 제2기공(27)들 사이에 장홀 형태로 이루어진 다수의 제2슬릿홀이 형성되도록 구성되며, 다수의 제1슬릿홀과 다수의 제2슬릿홀은 수직방향에 대해 상호 "+"자 형태로 크로스되게 교차되는 형태로 배치되도록 구성될 수 있다. On the other hand, although not shown, a plurality of first slit holes formed in a long hole shape between a plurality of first pores 26 are formed in the first dispersion plate 26, and a plurality of first slit holes are formed in the second dispersion plate 27. It is configured to form a plurality of second slit holes formed in the form of long holes between the two pores 27, and the plurality of first slit holes and a plurality of second slit holes cross each other in a "+" shape in the vertical direction. It can be configured to be arranged in a form that is intersecting.

또한, 도 3을 참조하면, 다른 형태의 가스분산플레이트는 제1분산플레이트(26)에 형성된 복수의 제1기공(26a) 각각의 내주면에 제1나선홈(26aa)이 형성되고, 제2분산플레이트(27)에 형성된 복수의 제2기공(27a) 각각의 내주면에는 제2나선홈(27aa)이 형성되도록 구성되며, 제1나선홈(26aa)과 제2나선홈(27aa)은 나선방향이 서로 반대되는 형태로 이루어진다. In addition, referring to FIG. 3, in the gas distribution plate of another type, a first spiral groove 26aa is formed on the inner circumferential surface of each of the plurality of first pores 26a formed in the first distribution plate 26, and the second dispersion A second spiral groove (27aa) is formed on the inner circumferential surface of each of the plurality of second pores (27a) formed in the plate (27), and the first spiral groove (26aa) and the second spiral groove (27aa) have a spiral direction. They are made in opposite forms.

바이오가스가 제1기공(26a)을 통과할 때, 제1나선홈(26aa)에 안내되어 일방향의 선회와류가 형성되며, 상승되는 선회와류는 제2분산플레이트(27)의 천정벽면에 부딛쳐서 분산된 후, 복수의 제2기공(27a)을 통과할 때 제1나선홈(26aa)과 반대되는 나선방향으로 된 제2나선홈(27aa)에 의해 타방향의 선회와류가 형성되면서 하이브리드 메디아(22)에 분배되어 공급되므로 더욱더 메디아와의 접촉효율을 높여서 황화수소와 암모니아 제거효율을 향상시킬 수 있다. When the biogas passes through the first pore (26a), it is guided to the first spiral groove (26aa) to form a swirling vortex in one direction, and the rising swirling vortex hits the ceiling wall of the second dispersion plate (27) After being dispersed, when passing through the plurality of second pores 27a, a vortex vortex in the other direction is formed by the second helical groove 27aa in a helical direction opposite to the first helical groove 26aa. As it is distributed and supplied to 22), the efficiency of removing hydrogen sulfide and ammonia can be improved by further increasing the contact efficiency with the media.

아울러, 도 4 및 도 5를 참조하면, 제1분산플레이트(26)에는 제1기공(26a)의 상단에 "+"자 형태의 가스분리부재(29)가 구성되어, 바이오가스가 제1기공(26a)에 유입된 후 제1나선홈(26aa)에 안내되어 일방향의 상승 선회와류가 형성된 후, 가스분리부재(29)에 부딛쳐 갈라지면서 가스의 분산이 증대된 후, 재차 제2분산플레이트(27)의 벽면에 다시 부딛혀 분산됨으로써 제2기공(27a)에 유입되기 전에 더욱더 분산된 바이오가스가 제2기공(27a)에 공급되어지게 함으로써 바이오가스의 균등한 분배가 더욱 향상될 수 있다. In addition, referring to FIGS. 4 and 5, the first dispersion plate 26 includes a gas separating member 29 in the shape of a “+” at the upper end of the first pore 26a, so that the biogas is the first pore. After flowing into (26a), it is guided to the first spiral groove (26aa) to form an upward swirling vortex in one direction, and after it is split by the gas separation member (29), the dispersion of gas is increased, and the second dispersion plate is again By hitting the wall surface of (27) again and being dispersed, the more dispersed biogas is supplied to the second pore (27a) before flowing into the second pore (27a), thereby further improving the even distribution of the biogas. .

응축수 도입부(30)는 건식반응조(21)의 배수구(24)와 순환수공급부(14)를 연결하며, 건식반응조(21)의 저부에 수집된 고농도 황산이 포함된 응축수를 순환수공급부(14)로 공급하여, 분사노즐(12)에 유입되게 하는 구성이다. The condensed water introduction unit 30 connects the drain 24 of the dry reaction tank 21 and the circulating water supply unit 14, and supplies condensed water containing high concentration sulfuric acid collected at the bottom of the dry reaction tank 21 to the circulating water supply unit 14 It is a configuration that is supplied to and flows into the injection nozzle 12.

응축수 도입부(30)는 배관으로 이루어질 수 있으며, 배수구(24)와 순환배관(14a)을 연결하는 형태로 이루어질 수 있다. The condensed water introduction part 30 may be formed of a pipe, and may be formed in a form that connects the drain port 24 and the circulation pipe 14a.

응축수 도입부(30)를 통해 건식반응조(21)에서 생성된 고농도 황산이 포함된 응축수가 순환수에 합류하여 분사노즐(12)을 통해 분사됨으로써, 충진재(15)를 통과하는 바이오가스 내 암모니아는 응축수에 포함된 황산(H2SO4)과 화학기작을 통해 제거되어짐으로써, 습식반응조(21)에서는 암모니아가 순환수과의 용해기작을 통해 제거될 뿐 아니라, 순환수에 합류된 응축수의 황산(H2SO4)과 암모니아가 화학기작을 통해 제거됨으로써 암모니아의 제거효율이 월등히 향상되게 된다. Condensed water containing high-concentration sulfuric acid generated in the dry reaction tank 21 through the condensed water introduction unit 30 merges with the circulating water and is sprayed through the spray nozzle 12, so that ammonia in the biogas passing through the filler 15 is condensed water. As sulfuric acid (H 2 SO 4 ) contained in the water is removed through a chemical mechanism, in the wet reaction tank 21, ammonia is not only removed through a dissolution mechanism with the circulating water, but also sulfuric acid (H 2) of the condensed water joined to the circulating water. As SO 4 ) and ammonia are removed through a chemical mechanism, the removal efficiency of ammonia is remarkably improved.

이상, 본 발명을 본 발명의 원리를 예시하기 위한 바람직할 실시 예와 관련하여 도시하고 또한 설명하였으나, 본 발명은 그와 같이 도시되고 설명된 그대로의 구성 및 작용으로 한정되는 것이 아니다. 오히려 첨부된 특허청구범위의 사상 및 범주를 일탈함이 없이 본 발명에 대한 다수의 변경 및 수정 가능함을 당업자들은 잘 이해할 수 있을 것이다. 따라서 그러한 모든 적절한 변경 및 수정과 균등물도 본 발명의 범주에 속하는 것으로 간주되어야 할 것이다. As described above, the present invention has been illustrated and described in connection with preferred embodiments for exemplifying the principles of the present invention, but the present invention is not limited to the configuration and operation as shown and described as such. Rather, it will be well understood by those skilled in the art that a number of changes and modifications can be made to the present invention without departing from the spirit and scope of the appended claims. Accordingly, all such appropriate changes and modifications and equivalents should be considered to be within the scope of the present invention.

10...습식반응기
11...습식반응조
12...분사노즐부
13...흡입노즐부
14...순환수공급부
15...충진재
20...건식반응기
21...건식반응조
22...하이브리드 메디아
24...배수구
25...가스분산 플레이트
30...응축수 도입부
10...wet reactor
11...wet reactor
12... injection nozzle part
13...Suction nozzle part
14...Circulating water supply
15...filling material
20...dry reactor
21...dry reactor
22...Hybrid Media
24... drain
25...gas dispersion plate
30... condensate introduction

Claims (3)

바이오가스가 하부로 유입되어 상부로 배출되며, 내측 상부에 설치된 분사노즐을 통해 순환수를 하향되게 분사하여 유입된 바이오가스에 대한 용해기작과 화학기작에 의해 암모니아와 황화수소를 제거하는 습식반응기;
상기 습식반응기에서 1차 처리된 바이오가스가 하부로 유입되어 상부로 배출되며, 내부에 셀룰로오스 20~25W%, 탄산칼슘 40~59.99W%, 탄산마그네슘 5~10W% 및 수산화철 15~34.99W%, 영양염류 0.01~0.5W%를 혼합하여 제조된 하이브리드 메디아가 충진되어, 상기 1차 처리된 바이오가스가 상기 하이브리드 메디아를 통과하면서 화학기작과 미생물에 의한 생물학적 기작에 의해 2차적으로 암모니아와 황화수소를 제거하는 건식반응기;
상기 건식반응기에서 생성된 고농도 황산이 포함된 응축수를 상기 분사노즐에 유입시켜, 상기 순환수의 황산농도를 증가시켜 상기 습식반응기에서의 암모니아 제거효율이 향상되게 하는 응축수 도입부;를 포함하는 것을 특징으로 하는 암모니아와 황화수소의 동시 제거가 가능한 패키지형 바이오가스 정제시스템.
A wet reactor in which the biogas is introduced into the lower part and discharged to the upper part, and the circulating water is injected downward through the injection nozzle installed at the inner upper part to remove ammonia and hydrogen sulfide by a dissolution mechanism and a chemical mechanism for the introduced biogas;
The biogas, which has been primarily treated in the wet reactor, flows into the lower portion and is discharged to the upper portion, and cellulose 20-25W%, calcium carbonate 40-59.99W%, magnesium carbonate 5-10W%, and iron hydroxide 15-34.99W%, inside. A hybrid media prepared by mixing 0.01 to 0.5 W% of nutrients is filled, and the first treated biogas passes through the hybrid media, and ammonia and hydrogen sulfide are secondarily removed by a chemical mechanism and a biological mechanism by microorganisms. A dry reactor;
And a condensed water introduction unit configured to increase the sulfuric acid concentration of the circulating water by introducing condensed water containing high-concentration sulfuric acid generated in the dry reactor into the spray nozzle to improve the ammonia removal efficiency in the wet reactor. Packaged biogas purification system capable of simultaneously removing ammonia and hydrogen sulfide.
제 1 항에 있어서,
상기 습식반응기는,
하부 외주면 일측에 바이오가스가 유입되는 제1유입구와 상단에 상기 1차 처리된 바이오가스가 배출되는 제1배출구가 형성된 습식반응조;
상기 습식반응조의 내측 상부에 배치되며 하부로 순환수를 분사하는 분사노즐부;
상기 습식반응조의 저부에 형성되어, 상기 분사노즐부로부터 분사되어 상기 습식반응조 저부에 수집되는 순환수를 흡입하는 흡입노즐부;
상기 흡입노즐부와 상기 분사노즐부를 연결하며 상기 흡입노즐부를 통해 흡입된 순환수 및 상기 건식반응기에서 생성된 응축수를 연결하여 상기 분사노즐부에 공급하여 순환수의 순환이 이루어지도록 하는 순환수공급부;
상기 습식반응조의 내부에 설치되어 상기 바이오가스와 상기 순환수의 접촉효율을 증대시키는 폴리머 재질의 폴링제로 이루어진 충진재;를 포함하는 것을 특징으로 하는 암모니아와 황화수소의 동시 제거가 가능한 패키지형 바이오가스 정제시스템.
The method of claim 1,
The wet reactor,
A wet reaction tank having a first inlet through which biogas flows into one side of the lower outer circumference and a first outlet through which the first processed biogas is discharged;
A spray nozzle part disposed on the inner upper part of the wet reaction tank and spraying circulating water downward;
A suction nozzle part formed at the bottom of the wet reaction tank and for sucking circulating water injected from the injection nozzle part and collected at the bottom of the wet reaction tank;
A circulating water supply unit connecting the suction nozzle unit and the injection nozzle unit and supplying the circulating water sucked through the suction nozzle unit and the condensed water generated in the dry reactor to supply the circulating water to the injection nozzle unit to circulate the circulating water;
A package-type biogas purification system capable of simultaneously removing ammonia and hydrogen sulfide, comprising; a filler made of a polymer material that is installed inside the wet reaction tank to increase the contact efficiency between the biogas and the circulating water. .
제 1 항에 있어서,
상기 건식반응기는,
내부에 상기 하이브리드 메디아가 충진되며, 하부에는 상기 1차 처리된 바이오가스가 유입되는 제2유입구가 형성되고, 상부에는 최종 처리된 바이오가스가 배출되는 제2배출구가 형성된 건식반응조;
상기 건식반응조의 내측 하부에 결합되어 상기 1차 처리된 바이오가스를 상기 하이브리드 메디아 측으로 균등하게 분배하여 공급하는 가스분산 플레이트;를 포함하는 것을 특징으로 하는 패키지형 바이오 가스 정제시스템.
The method of claim 1,
The dry reactor,
A dry reactor in which the hybrid media is filled therein, a second inlet through which the first processed biogas is introduced is formed in a lower portion, and a second outlet through which the finally processed biogas is discharged is formed in an upper portion;
A packaged biogas purification system comprising: a gas distribution plate coupled to an inner lower portion of the dry reactor to distribute and supply the primary treated biogas evenly toward the hybrid media.
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KR101333494B1 (en) * 2012-10-12 2013-11-28 허관 High-effiency and lost-cost and eco-friendly deodorizing system for sewage and waste water disposal plant
KR101444186B1 (en) 2013-06-21 2014-09-26 현대건설주식회사 Purification device of biogas and purification method thereof
KR101413908B1 (en) * 2014-02-17 2014-06-30 에이티이 주식회사 Dry type desulfuriation apparatus
KR101584942B1 (en) * 2015-07-24 2016-01-14 에이티이 주식회사 Dry type desulfuriation apparatus having reusing unit
KR101757118B1 (en) * 2016-06-16 2017-07-27 에이티이 주식회사 Multistage sulfur removal system
KR101751207B1 (en) 2016-11-29 2017-06-28 (주)제이에스엔 Double stage wet scrubbing de-sulfurization apparatus and process using liquid fertilizer at bio gas plant

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115518511A (en) * 2022-10-10 2022-12-27 南京信真环境科技有限公司 Mine environment harmful gas treatment and purification device
CN115518511B (en) * 2022-10-10 2023-11-10 安徽马钢矿业资源集团桃冲矿业有限公司 Mine environment harmful gas treatment and purification device

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